01-08-2012 дата публикации
Номер: CN102617587A
Принадлежит:
The invention discloses a synthesis method for 2,3,6,7-triptycene tetracarboxylic dianhydride. The method comprises the following steps of: 1) preparing 2,3,6,7-tetramethylanthracene from o-xylene and benzyl alcohol or methylene chloride under the catalysis of anhydrous aluminum trichloride; 2) diazotizing the 2,3,6,7-tetramethylanthracene, anthranilic acid and amyl nitrite to generate a crude product 2,3,6,7-tetramethyl triptycene; 3) performing chromatographic separation on the crude product 2,3,6,7-tetramethyl triptycene, and flushing the separated 2,3,6,7-tetramethyl triptycene by using a mixed eluting agent to obtain 2,3,6,7-tetramethyl triptycene; 4) oxidizing the 2,3,6,7-tetramethyl triptycene in a mixed solvent consisting of potassium permanganate, pyridine and water under a reflux condition to generate 2,3,6,7-triptycene tetracarboxylic acid; and 5) refluxing and dehydrating the 2,3,6,7-triptycene tetracarboxylic acid in acetic anhydride to generate the 2,3,6,7-triptycene tetracarboxylic ...
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