17-01-2019 дата публикации
Номер: US20190017175A1
Автор:
Tang -Chieh Huang,
Chao-Chin Chuang,
Chia-Fu Hsu,
HUANG TANG -CHIEH,
CHUANG CHAO-CHIN,
HSU CHIA-FU,
Huang, Tang -Chieh,
Chuang, Chao-Chin,
Hsu, Chia-Fu
Принадлежит:
The present invention provides a method of forming a metal layer on a specific photosensitive resin. The method comprises the following steps: (i) pretreatment: cleaning and pre-activating a surface of the photosensitive resin by using an alkaline solution; (ii) surface modification: soaking the photosensitive resin in a surface modifier to form an organic modification layer; (iii) surface activation: adding catalytic metal ions to form a metal ion complex with the organic modification layer; (iv) reduction reaction: reducing the metal ion complex into a nano metal catalyst by using a reducing agent; (v) chemical plating: soaking the photosensitive resin in an chemical plating solution to form a conductive metal layer; (vi) heat treatment: baking the photosensitive resin at 100-250° C., and (vii) electroplating thickening: electroplating the baked photosensitive resin to thicken the conductive metal layer. 2. The method of claim 1 , wherein in the surface modification step (ii) claim 1 , the soaking time is 1-20 minutes claim 1 , the concentration of the amino compound in the surface modifier is 0.1-10 g/L claim 1 , and the temperature is 30-75° C.3. The method of claim 1 , wherein the catalytic metal ions added in the surface activation step (iii) is an acidic aqueous solution containing Cu claim 1 , Ni claim 1 , Ag claim 1 , Au claim 1 , or Pd ions.4. The method of claim 1 , wherein the reducing agent used in the reduction reaction step (iv) is sodium hypophosphite claim 1 , sodium borohydride claim 1 , dimethylamine borane or hydrazine aqueous solution.5. The method of claim 1 , wherein the chemical plating solution used in the chemical plating step (v) comprises copper ions claim 1 , nickel ions claim 1 , a chelating agent claim 1 , a reducing agent claim 1 , a pH buffer claim 1 , a surfactant claim 1 , and a pH adjuster.6. The method of claim 5 , wherein the source of the copper ions is copper nitrate claim 5 , copper sulfate claim 5 , copper chloride claim 5 , ...
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