25-06-2020 дата публикации
Номер: US20200201085A1
Принадлежит:
A structure is provided and includes (i) a substrate having a surface, the surface comprising a ternary or quaternary oxide having a first lattice parameter, the first lattice parameter being a lattice parameter of the ternary or quaternary oxide as it is present at the surface; and (ii) a layer of a perovskite oxide on the ternary or quaternary oxide, the perovskite oxide having a second lattice parameter, the second lattice parameter being a native lattice parameter of the perovskite oxide, wherein the first lattice parameter is larger than the second lattice parameter. A method for forming a perovskite oxide with an a-axis orientation is also provided. 1. A structure comprising:(i) a substrate having a surface, the surface comprising a ternary or quaternary oxide having a first lattice parameter, the first lattice parameter being a lattice parameter of the ternary or quaternary oxide as it is present at the surface, and(ii) a layer of a perovskite oxide on the ternary or quaternary oxide, the perovskite oxide having an a-axis orientation and being selected from perovskite oxides having a second lattice parameter, being a native lattice parameter, and being smaller than the first lattice parameter.2. The structure according to claim 1 , wherein the first lattice parameter is from 0.05% to 3% larger than the second lattice parameter.3. The structure according to claim 1 , wherein the first lattice parameter is from 0.1% to 1.5% larger than the second lattice parameter.4. The structure according to claim 1 , wherein the ternary oxide has a general chemical formula ABOwherein A is selected from the group consisting of Ba claim 1 , Sr claim 1 , and Ca claim 1 , and B is selected from the group consisting of Ti claim 1 , Zr claim 1 , and Hf.5. The structure according to claim 1 , wherein the quaternary oxide has a general chemical formula ABB′Owherein 0
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