Colloidal particle sols and methods for preparing the same

A method of preparing an organic sol of particles is provided. Steps include: a) providing a suspension of particles in an aqueous medium; b) adding an organic liquid to form an admixture where the concentration of particles in the admixture is less than or equal to 40 percent by weight; c) maintaining the admixture at a temperature and pressure and for a time sufficient to reduce the water content to less than 30 percent by weight while simultaneously adding a water-compatible organic liquid at a rate sufficient to maintain a concentration of particles in the admixture at less than or equal to 50 percent by weight; and d) adding at least one polymer while maintaining the admixture at a temperature and pressure and for a time sufficient to provide an organic sol of particles comprising 1 percent by weight or less of water.

(Meth)acrylate/aspartate amine curatives and coatings and articles comprising the same

... (Meth)acrylate/aspartate amine curatives comprising the reaction product of a polyamine, a dialkyl maleate and/or dialkyl fumarate, and a (meth)acrylate are disclosed, as are methods for making the same. A polyurea comprising the reaction product of the acrylate/aspartate amine curative and isocyanate is also disclosed, as are coatings comprising such a polyurea and substrates coated with the same.

COATING COMPOSITIONS HAVING IMPROVED ADHESION, COATED SUBSTRATES AND METHODS RELATED THERETO

Coating compositions are provided which include a polysiloxane comprising at least one reactive functional group, at least one material comprising at least one reactive functional group, and at least one boron- containing compound. Also provided are multi-layer composite coatings formed from a basecoat deposited from a pigmented coating composition and a topcoat applied over the basecoat, the topcoat deposited from the aforementioned coating composition. Methods for repairing a multi-layer composite coating and coated substrates are also provided. The compositions of the invention provide highly scratch resistant coatings, particularly highly scratch resistant color-plus-clear coatings, which have excellent intercoat adhesion to subsequently applied coating layers. © KIPO & WIPO 2007 ...

(METH)ACRYLATE/ASPARTATE AMINE CURATIVES AND COATINGS AND ARTICLES COMPRISING THE SAME

... (Meth)acrylate/aspartate amine curatives comprising the reaction product of a polyamine, a dialkyl maleate and/or dialkyl fumarate, and a (meth)acrylate are disclosed, as are methods for making the same. A polyurea comprising the reaction product of the acrylate/aspartate amine curative and isocyanate is also disclosed, as are coatings comprising such a polyurea and substrates coated with the same.

METHOD FOR PRODUCING BICYCLIC GUANIDINES BY USE OF A CYCLIC THIOUREA

The present invention is directed to a method producing bicyclic guanidine comprising heating a cyclic thiourea to a temperature ranging from >=140° C. in a substantially non-hydrocarbon solvent to form the bicyclic guanidine.

Coating compositions having improved scratch resistance, coated substrates and methods related thereto

Coating compositions are provided which are formed from components comprising (a) at least one polysiloxane comprising at least one reactive functional group; (b) at least one reactant comprising at least one functional group that is reactive with at least one functional group selected from the at least one reactive functional group of the at least one polysiloxane and at least one functional group of at least one reactant; and (c) a plurality of particles, wherein each component is different, and wherein the at least one reactive functional group of the at least one polysiloxane and the at least one functional group of the at least one reactant are substantially nonreactive with the particles. A multi-component composite coating composition formed from a basecoat and a topcoat deposited from the curable coating composition also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.

POLYUREA COATING COMPRISING AN AMINE/(METH)ACRYLATE OLIGOMERIC REACTION PRODUCT

Coating compositions comprising a polyurea formed from a reaction mixture comprising isocyanate and an acrylated amine are disclosed. The (meth)acrylated amine is the reaction product of a polyamine and a (meth)acrylate; when the (meth)acrylate comprises a poly(meth)acrylate, the reaction product further comprises a mono(meth)acrylate and/or a monoamine. Methods for using the coatings, and substrates coated therewith, are also disclosed. © KIPO & WIPO 2009 ...

Organic solvent-free film-forming compositions, multi-layer composite coatings, and related methods

Provided is a film-forming composition substantially free of organic solvent which includes an aqueous dispersion of polymeric microparticles prepared by emulsion polymerization of a monomeric composition containing (1) at least 10 percent by weight of one or more vinyl aromatic compounds; (2) 0.1 to 10 percent by weight of one or more carboxylic acid functional polymerizable, ethylenically unsaturated monomers; (3) 0 to 10 percent by weight of one or more polymerizable monomers having one or more functional groups capable of reacting to form crosslinks; and (4) one or more polymerizable ethylenically unsaturated monomers. Each of (1), (2), (3) and (4) are different one from the other and at least one of (3) and (4) is present in the monomeric composition. Multi-layer composite coatings and coated substrates also are provided.

TRIAMINE/ASPARTATE CURATIVE AND COATINGS COMPRISING THE SAME

The reaction product of a triamine and a dialkyl maleate and/or dialkyl fumarate, wherein the reaction product has a viscosity of less than 2000 cPs is disclosed. Polyurea coatings comprising this reaction product are also disclosed, as are substrates coated with the same. © KIPO & WIPO 2009 ...

COATING COMPOSITIONS WITH MODIFIED PARTICLES AND METHODS OF USING THE SAME

Liquid coating compositions having improved mar and scratch resistance are disclosed. The coatings generally comprise one or more particles that have been modified to render the particles more surface active. The improved resistance is achieved without affecting the appearance or mechanical performance of the coatings. Methods for using the coatings, and the substrates coated therewith, are also disclosed. © KIPO & WIPO 2007 ...

Organic solvent-free film-forming compositions, multi-layer composite coatings, and related methods

Provided is a film-forming composition substantially free of organic solvent which includes an aqueous dispersion of polymeric microparticles prepared by emulsion polymerization of a monomeric composition containing (1) at least 10 percent by weight of one or more vinyl aromatic compounds; (2) 0.1 to 10 percent by weight of one or more carboxylic acid functional polymerizable, ethylenically unsaturated monomers; (3) 0 to 10 percent by weight of one or more polymerizable monomers having one or more functional groups capable of reacting to form crosslinks; and (4) one or more polymerizable ethylenically unsaturated monomers. Each of (1), (2), (3) and (4) are different one from the other and at least one of (3) and (4) is present in the monomeric composition. Multi-layer composite coatings and coated substrates also are provided.

FLEXIBLE COATING COMPOSITIONS HAVING IMPROVED SCRATCH RESISTANCE, COATED SUBSTRATES AND METHODS RELATED THERETO

Coating compositions are provided which include a polysiloxane comprising at least one reactive functional group and at least one material comprising at least one reactive functional group. Also provided are multi-layer composite coatings formed from a basecoat deposited from a pigmented coating composition and a topcoat applied over the basecoat, the topcoat deposited from the aforementioned coating composition. A method for improving the scratch resistance of a coated substrate, as well as coated substrates also are provided. The compositions of the invention provide highly scratch resistant coatings, particularly highly scratch resistant color-plus-clearcoatings. © KIPO & WIPO 2007 ...

Polyurea coating comprising a polyamine/mono(meth)acrylate reaction product

Coating compositions comprising a polyurea formed from a reaction mixture comprising isocyanate and a (meth)acrylated amine are disclosed. The (meth)acrylated amine is the reaction product of a polyamine and a mono(meth)acrylate; the ratio of equivalents of isocyanate groups to equivalents of amine groups is greater than 1 and the isocyanate and the (meth)acrylated amine reaction product can be applied to a substrate at a volume mixing ratio of 1:1. Methods for using the coatings, and substrates coated therewith are also disclosed.

(METH)ACRYLATE/ASPARTATE AMINE CURATIVES AND COATINGS AND ARTICLES COMPRISING THE SAME

... (Meth)acrylate/aspartate amine curatives comprising the reaction product of a polyamine, a dialkyl maleate and/or dialkyl fumarate, and a (meth)acrylate are disclosed, as are methods for making the same. A polyurea comprising the reaction product of the acrylate/aspartate amine curative and isocyanate is also disclosed, as are coatings comprising such a polyurea and substrates coated with the same. COPYRIGHT KIPO & WIPO 2010 ...

Polyurea/polythiourea coatings

Polyurea/polythiourea compositions comprising the reaction product of a first component comprising isocyanate and a second component comprising an amine, wherein the first component further comprises an isocyanate functional polythioether-polyurethane and/or polythiourethane, and/or the second component further comprises an amine/hydroxy functional polythioether, are disclosed. Methods for using the coating, and substrates coated therewith, are also disclosed.

Film-forming compositions having improved scratch resistance

Multi-component composite coating compositions are provided which comprise a base coat deposited from a pigmented film-forming composition and a transparent top coat applied over the base coat in which the transparent top coat is deposited from a film-forming composition comprising one or more ungelled chain-extended organic polysiloxanes having reactive functional groups, and one or more curing agents having functional groups reactive with the functional groups of the polysiloxane. Additionally provided is a process for applying the multi-component composite coatings described above to a substrate. Substrates coated with the above-described multi-component composite coating compositions are also provided.

Coating compositions with modified particles and methods of using the same

Powder coating compositions having improved mar and scratch resistance are disclosed. The coatings generally comprise one or more particles that have been modified to render the particles more surface active. The improved resistance is achieved without affecting the appearance or mechanical performance of the coatings. Methods for using the coatings, and the substrates coated therewith, are also disclosed.

Multi-layer composites formed from compositions having improved adhesion, coating compositions, and methods related thereto

Improved multi-layer composites are provided. The multi-layer composites include at least a first polymeric layer and a second polymeric layer formed over the first polymeric layer thereby forming an interface region there between. At least one of the polymeric layers is formed from a thermosetting composition which contains an adhesion promoter composition. The adhesion promoter composition is formed from (1) at least one adhesion promoting component, and (2) at least one surface active component. The improvement is represented by the presence of the adhesion promoting component (1) at the interface region.

Coating composition of polyurea, polyurethane and flame retardant

The present invention is directed to a coating composition comprising polyurea and polyurethane. Further, the present invention is directed to a coating composition comprising polyurea or, polyurea and polyurethane, and flame retardant. The polyurea is formed from a reaction mixture comprising isocyanate and amine wherein the ratio of equivalents of isocyanate groups to equivalents of amine groups is greater than 1 and the isocyanate-functional component and the amine-functional component can be applied to a substrate at a volume mixing ratio of 1:1.

POLYUREA/POLYTHIOUREA COATINGS

Polyurea/polythiourea compositions comprising the reaction product of a first component comprising isocyanate and a second component comprising an amine, wherein the first and/or second component further comprises a sulfur-containing compound are disclosed. Methods for using the coating, and substrates coated therewith, are also disclosed.

POLYUREA COATING COMPRISING A POLYAMINE/MONO(METH)ACRYLATE REACTION PRODUCT

Coating compositions comprising a polyurea formed from a reaction mixture comprising isocyanate and a (meth)acrylated amine are disclosed. The (meth)acrylated amine is the reaction product of a polyamine and a mono(meth)acrylate; the ratio of equivalents of isocyanate groups to equivalents of amine groups is greater than 1 and the isocyanate and the (meth)acrylated amine reaction product can be applied to a substrate at a volume mixing ratio of 1:1. Methods for using the coatings, and substrates coated therewith are also disclosed. © KIPO & WIPO 2009 ...

Liquid coating of film-forming resin and particles chemically modified to lower surface tension

Liquid coating compositions having improved mar and scratch resistance are disclosed. The coatings generally comprise one or more particles that have been modified to render the particles more surface active. The improved resistance is achieved without affecting the appearance or mechanical performance of the coatings. Methods for using the coatings, and the substrates coated therewith, are also disclosed.

LOW TEMPERATURE APPLICATION COATING COMPOSITION COMPRISING POLYUREA AND A PHOSPHORUS-CONTAINING POLYOL AND FOOTWEAR COMPRISING POLYUREA

Coating compositions comprising a polyurea formed from a reaction mixture comprising: (a) a first component comprising an isocyanate, the first component having a viscosity of 2000 centipoise at a temperature 7° C.; and (b) a second component comprising an amine. Substrates coated at least in part with such a composition are also disclosed. Footwear coated at least in part with polyurea are also disclosed.

TRIAMINE/ASPARTATE CURATIVE AND COATINGS COMPRISING THE SAME

The reaction product of a triamine and a dialkyl maleate and/or dialkyl fumarate, wherein the reaction product has a viscosity of less than 2000 cPs is disclosed. Polyurea coatings comprising this reaction product are also disclosed, as are substrates coated with the same.

Multi-layer composites formed from compositions having improved adhesion, coating compositions, and methods related thereto

The present invention provides an improved multi-layer composite of two or more polymeric layers at least one of which is formed from a thermosetting composition. The composite includes at least a first polymeric layer formed on a substrate and a second polymeric layer over the first polymeric layer, wherein in the absence of a boron-containing compound, the first and second polymeric layers have poor interlayer adhesion. The improvement resides in the inclusion of at least one boron-containing compound in one or both of the first and second polymeric layers in an amount sufficient to improve the interlayer adhesion between the first and second polymeric layers. Also provided is an improved curable coating composition used to form a multi-layer composite coating of two or more cured coating layers, at least one of which is formed from the thermosetting composition. Related methods and coated substrates are also provided.

COATING COMPOSITIONS HAVING IMPROVED ADHESION, COATED SUBSTRATES AND METHODS RELATED THERETO

Coating compositions are provided which include a polysiloxane comprising at least one reactive functional group, at least one material comprising at least one reactive functional group, and at least one boron- containing compound. Also provided are multi-layer composite coatings formed from a basecoat deposited from a pigmented coating composition and a topcoat applied over the basecoat, the topcoat deposited from the aforementioned coating composition. Methods for repairing a multi-layer composite coating and coated substrates are also provided. The compositions of the invention provide highly scratch resistant coatings, particularly highly scratch resistant color-plus-clear coatings, which have excellent intercoat adhesion to subsequently applied coating layers. © KIPO & WIPO 2007 ...

SUBSTRATES COATED WITH A POLYUREA COMPRISING A (METH)ACRYLATED AMINE REACTION PRODUCT

A metallic substrate coated at least in part with a multilayer coating composite, comprising at least one of an electrocoat layer, a base coat layer, and a clearcoat layer; and a polyurea formed from a reaction mixture comprising isocyanate and a (meth)acrylated amine reaction product of a monoamine and a poly(meth)acrylate is disclosed. The ratio of equivalents of isocyanate groups to equivalents of amine groups in the polyurea is greater than 1 and the isocyanate functional component and the (meth)acrylated amine functional component can be applied to the substrate at a volume mixing ratio of 1:1. A building comprising a building component coated at least in part with such a polyurea is also disclosed, as is a substrate coated at least in part with such a polyurea, wherein the ratio of equivalents or isocyanate to equivalents of amine groups is greater than 1.3:1. © KIPO & WIPO 2009 ...

FILM-FORMING COMPOSITIONS SUBSTANTIALLY FREE OF ORGANIC SOLVENT, MULTI- LAYER COMPOSITE COATINGS AND RELATED METHODS

Film-forming compositions are disclosed that are substantially free of organic solvent. The film-forming compositions include a resinous binder and at least one water dilutable additive including the reaction product of (i) a reactant including at least one isocyanate functional group with (ii) an active hydrogen containing alkoxypolyalkylene compound. Also disclosed are multi-layer composite coatings that include such film- forming compositions and methods of applying such multi-component composite coatings to a substrate. © KIPO & WIPO 2007 ...

POLYUREA COATING COMPRISING AN AMINE/(METH)ACRYLATE OLIGOMERIC REACTION PRODUCT

Coating compositions comprising a polyurea formed from a reaction mixture comprising isocyanate and an acrylated amine are disclosed. The (meth)acrylated amine is the reaction product of a polyamine and a (meth)acrylate; when the (meth)acrylate comprises a poly(meth)acrylate, the reaction product further comprises a mono(meth)acrylate and/or a monoamine. Methods for using the coatings, and substrates coated therewith, are also disclosed.

(METH)ACRYLATE/ASPARTATE AMINE CURATIVES AND COATINGS AND ARTICLES COMPRISING THE SAME

... (Meth)acrylate/aspartate amine curatives comprising the reaction product of a polyamine, a dialkyl maleate and/or dialkyl fumarate, and a (meth)acrylate are disclosed, as are methods for making the same. A polyurea comprising the reaction product of the acrylate/aspartate amine curative and isocyanate is also disclosed, as are coatings comprising such a polyurea and substrates coated with the same.

MULTI-LAYER COMPOSITES FORMED FROM COMPOSITIONS HAVING IMPROVED ADHESION, COATING COMPOSITIONS, AND METHODS RELATED THERETO

The present invention provides an improved multi-layer composite of two or more polymeric layers at least one of which is formed from a thermosetting composition. The composite includes at least a first polymeric layer formed on a substrate and a second polymeric layer over the first polymeric layer, wherein in the absence of a boron-containing compound, the first and second polymeric layers have poor interlayer adhesion. The improvement resides in the inclusion of at least one boron- containing compound in one or both of the first and second polymeric layers in an amount sufficient to improve the interlayer adhesion between the first and second polymeric layers. Also provided is an improved curable coating composition used to form a multi-layer composite coating of two or more cured coating layers, at least one of which is formed from the thermosetting composition. Related methods and coated substrates are also provided. © KIPO & WIPO 2007 ...

CURED COATINGS HAVING IMPROVED SCRATCH RESISTANCE, COATED SUBSTRATES AND METHODS RELATED THERETO

Cured coatings having particles at a surface region of the cured coating are provided. Also provided are multi- component composite coatings which include a cured basecoat deposited from a pigmented coating composition and a cured topcoat deposited from a topcoating composition. The multi-component composite coatings of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering. © KIPO & WIPO 2007 ...

COATING COMPOSITIONS HAVING IMPROVED SCRATCH RESISTANCE, COATED SUBSTRATES AND METHODS RELATED THERETO

Coating compositions are provided which are formed from components comprising (a) at least one polysiloxane comprising at least one reactive functional group; (b) at least one reactant comprising at least one functional group that is reactive with at least one functional group selected from the at least one reactive functional group of the at least one polysiloxane and at least one functional group of at least one reactant; and (c) a plurality of particles, wherein each component is different, and wherein the at least one reactive functional group of the at least one polysiloxane and the at least one reactive functional group of the at least one reactant are substantially nonreactive with the particles. A multi-component composite coating composition formed from a basecoat and a topcoat deposited from the curable coating composition also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining ...

COATING COMPOSITIONS COMPRISING POLYUREA AND A PHOSPHOROUS-CONTAINING POLYOL

The present invention is directed to a coating composition comprising polyurea formed from a reaction mixture comprising: (a) a first component comprising isocyanate, wherein said isocyanate comprises an isocyanate functional prepolymer formed from a reaction mixture comprising isocyanate and a material comprising a phosphorus-containing polyol; and (b) a second component comprising an amine.

Substrates coated with a polyurea comprising a (meth)acrylated amine reaction product

A metallic substrate coated at least in part with a multilayer coating composite, comprising at least one of an electrocoat layer, a base coat layer, and a clearcoat layer; and a polyurea formed from a reaction mixture comprising isocyanate and a (meth)acrylated amine reaction product of a monoamine and a poly(meth)acrylate is disclosed. The ratio of equivalents of isocyanate groups to equivalents of amine groups in the polyurea is greater than 1 and the isocyanate functional component and the (meth)acrylated amine functional component can be applied to the substrate at a volume mixing ratio of 1:1. A building comprising a building component coated at least in part with such a polyurea is also disclosed, as is a substrate coated at least in part with such a polyurea, wherein the ratio of equivalents or isocyanate to equivalents of amine groups is greater than 1.3:1.

MULTI-COMPONENT COATINGS THAT INCLUDE POLYUREA COATING LAYERS

A polyurea composition, a multi-component composite coating and articles formed therefrom, and methods of forming the same are disclosed. The coating composition is formed from a reaction mixture comprising an isocyanate-functional component and an amine-functional component. The ratio of equivalents of isocyanate groups to equivalents of amine groups is greater than 1 while the volume mixing ratio of the isocyanate-functional component to the amine-functional component is capable of being applied to a substrate at 1:1. © KIPO & WIPO 2007 ...

COATING COMPOSITIONS HAVING IMPROVED SCRATCH RESISTANCE, COATED SUBSTRATES AND METHODS RELATED THERETO

Coating compositions are provided which are formed from components comprising (a) at least one polysiloxane comprising at least one reactive functional group; (b) at least one reactant comprising at least one functional group that is reactive with at least one functional group selected from the at least one reactive functional group of the at least one polysiloxane and at least one functional group of at least one reactant; and (c) a plurality of particles, wherein each component is different, and wherein the at least one reactive functional group of the at least one polysiloxane and the at least one reactive functional group of the at least one reactant are substantially nonreactive with the particles. A multi-component composite coating composition formed from a basecoat and a topcoat deposited from the curable coating composition also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining ...

COATING COMPOSITIONS COMPRISING POLYUREA OR POLYUREA AND POLYURETHANE

The present invention is directed to a coating composition comprising polyurea and polyurethane. Further, the present invention is directed to a coating composition comprising polyurea or, polyurea and polyurethane, and flame retardant. The polyurea is formed from a reaction mixture comprising isocyanate and amine wherein the ratio of equivalents of isocyanate groups to equivalents of amine groups is greater than 1 and the isocyanate-functional component and the amine-functional component can be applied to a substrate at a volume mixing ratio of 1:1.

Polyurea coating comprising an amine/(meth)acrylate oligomeric reaction product

Coating compositions comprising a polyurea formed from a reaction mixture comprising isocyanate and an acrylated amine are disclosed. The (meth)acrylated amine is the reaction product of a polyamine and a (meth)acrylate; when the (meth)acrylate comprises a poly(meth)acrylate, the reaction product further comprises a mono(meth)acrylate and/or a monoamine. Methods for using the coatings, and substrates coated therewith, are also disclosed.

(Meth)acrylate/aspartate amine curatives and coatings and articles comprising the same

... (Meth)acrylate/aspartate amine curatives comprising the reaction product of a polyamine, a dialkyl maleate and/or dialkyl fumarate, and a (meth)acrylate are disclosed, as are methods for making the same. A polyurea comprising the reaction product of the acrylate/aspartate amine curative and isocyanate is also disclosed, as are coatings comprising such a polyurea and substrates coated with the same.

MULTI-COMPONENT COATINGS THAT INCLUDE POLYUREA COATING LAYERS

A polyurea composition, a multi-component composite coating and articles formed therefrom, and methods of forming the same are disclosed. The coating composition is formed from a reaction mixture comprising an isocyanate-functional component and an amine-functional component. The ratio of equivalents of isocyanate groups to equivalents of amine groups is greater than 1 while the volume mixing ratio of the isocyanate-functional component to the amine-functional component is capable of being applied to a substrate at 1:1. © KIPO & WIPO 2008 ...

Multi-component coatings that include polyurea coating layers

A polyurea composition, a multi-component composite coating and articles formed therefrom, and methods of forming the same are disclosed. The coating composition is formed from a reaction mixture comprising an isocyanate-functional component and an amine-functional component. The ratio of equivalents of isocyanate groups to equivalents of amine groups is greater than 1 while the volume mixing ratio of the isocyanate-functional component to the amine-functional component is capable of being applied to a substrate at 1:1.

RADIATION CURABLE COATING COMPOSITIONS, RELATED COATINGS AND METHODS

Radiation curable coating compositions are disclosed. The radiation curable coating composition comprises a) an organic film-forming binder comprising (i) a urethane (meth)acrylate comprising the reaction product of reactants comprising a polyol and a polyisocyanate comprising at least two (meth)acrylate functional groups per molecule; and (ii) a highly functional (meth)acrylate; and b) a (meth)acrylate functional silsesquioxane dispersed in the binder. Also disclosed are related methods for coating a substrate, coated substrates and cured coatings formed from the radiation curable coating compositions.

Colloidal particle sols and methods for preparing the same

A method of preparing an organic sol of particles is provided. Steps include: a) providing a suspension of particles in an aqueous medium; b) adding an organic liquid to form an admixture where the concentration of particles in the admixture is less than or equal to 40 percent by weight; c) maintaining the admixture at a temperature and pressure and for a time sufficient to reduce the water content to less than 30 percent by weight while simultaneously adding a water-compatible organic liquid at a rate sufficient to maintain a concentration of particles in the admixture at less than or equal to 50 percent by weight; and d) adding at least one polymer while maintaining the admixture at a temperature and pressure and for a time sufficient to provide an organic sol of particles comprising 1 percent by weight or less of water.

COATING COMPOSITIONS COMPRISING POLYUREA AND AN ANTI-OXIDANT COMPOUND

The present invention is directed to a coating composition comprising polyurea formed from a reaction mixture comprising: (a) a first component comprising isocyanate and (b) a second component comprising an amine; and wherein the reaction mixture comprises an anti-oxidant compound a hindered amine light stabilizing compound, or combinations thereof.

Triamine/aspartate curative and coatings comprising the same

The reaction product of a triamine and a dialkyl maleate and/or dialkyl fumarate, wherein the reaction product has a viscosity of less than 2000 cPs is disclosed. Polyurea coatings comprising this reaction product are also disclosed, as are substrates coated with the same.

Flexible coating compositions having improved scratch resistance, coated substrates and methods related thereto

Coating compositions are provided which include a polysiloxane comprising at least one reactive functional group and at least one material comprising at least one reactive functional group. Also provided are multi-layer composite coatings formed from a basecoat deposited from a pigmented coating composition and a topcoat applied over the basecoat, the topcoat deposited from the aforementioned coating composition. A method for improving the scratch resistance of a coated substrate, as well as coated substrates also are provided. The compositions of the invention provide highly scratch resistant coatings, particularly highly scratch resistant color-plus-clearcoatings.

POLYUREA COATING COMPRISING A POLYAMINE/MONO(METH)ACRYLATE REACTION PRODUCT

Coating compositions comprising a polyurea formed from a reaction mixture comprising isocyanate and a (meth)acrylated amine are disclosed. The (meth)acrylated amine is the reaction product of a polyamine and a mono(meth)acrylate; the ratio of equivalents of isocyanate groups to equivalents of amine groups is greater than 1 and the isocyanate and the (meth)acrylated amine reaction product can be applied to a substrate at a volume mixing ratio of 1:1. Methods for using the coatings, and substrates coated therewith are also disclosed.

Coating compositions comprising polyurea and a phosphorus-containing polyol

The present invention is directed to a coating composition comprising polyurea formed from a reaction mixture comprising: (a) a first component comprising isocyanate, wherein said isocyanate comprises an isocyanate functional prepolymer formed from a reaction mixture comprising isocyanate and a material comprising a phosphorus-containing polyol; and (b) a second component comprising an amine.

Organic solvent-free film-forming compositions, multi-layer composite coatings, and related methods

Provided is a film-forming composition substantially free of organic solvent which includes an aqueous dispersion of polymeric microparticles prepared by emulsion polymerization of a monomeric composition containing (1) at least 10 percent by weight of one or more vinyl aromatic compounds; (2) 0.1 to 10 percent by weight of one or more carboxylic acid functional polymerizable, ethylenically unsaturated monomers; (3) 0 to 10 percent by weight of one or more polymerizable monomers having one or more functional groups capable of reacting to form crosslinks; and (4) one or more polymerizable ethylenically unsaturated monomers. Each of (1), (2), (3) and (4) are different one from the other and at least one of (3) and (4) is present in the monomeric composition. Multi-layer composite coatings and coated substrates also are provided.

Multi-component coatings that include polyurea coating layers

A polyurea composition, a multi-component composite coating and articles formed therefrom, and methods of forming the same are disclosed. The coating composition is formed from a reaction mixture comprising an isocyanate-functional component and an amine-functional component. The ratio of equivalents of isocyanate groups to equivalents of amine groups is greater than 1 while the volume mixing ratio of the isocyanate-functional component to the amine-functional component is capable of being applied to a substrate at 1:1.

Method for producing bicyclic guanidines by use of a cyclic thiourea

The present invention is directed to a method producing bicyclic guanidine comprising heating a cyclic thiourea to a temperature ranging from ≧140° C. in a substantially non-hydrocarbon solvent to form the bicyclic guanidine.

Multi-layer composites formed from compositions having improved adhesion, coating compositions, and methods related thereto

The present invention provides an improved multi-layer composite of two or more polymeric layers at least one of which is formed from a thermosetting composition. The composite includes at least a first polymeric layer formed on a substrate and a second polymeric layer over the first polymeric layer, wherein in the absence of a boron-containing compound, the first and second polymeric layers have poor interlayer adhesion. The improvement resides in the inclusion of at least one boron-containing compound in one or both of the first and second polymeric layers in an amount sufficient to improve the interlayer adhesion between the first and second polymeric layers. Also provided is an improved curable coating composition used to form a multi-layer composite coating of two or more cured coating layers, at least one of which is formed from the thermosetting composition. Related methods and coated substrates are also provided.

Multi-component coatings that include polyurea coating layers

A polyurea composition, a multi-component composite coating and articles formed therefrom, and methods of forming the same are disclosed. The coating composition is formed from a reaction mixture comprising an isocyanate-functional component and an amine-functional component. The ratio of equivalents of isocyanate groups to equivalents of amine groups is greater than 1 while the volume mixing ratio of the isocyanate-functional component to the amine-functional component is capable of being applied to a substrate at 1:1.

Film-forming compositions having improved scratch resistance

Multi-component composite coating compositions are provided which comprise a base coat deposited from a pigmented film-forming composition and a transparent top coat applied over the base coat in which the transparent top coat is deposited from a film-forming composition comprising one ore more ungelled chain-extended organic polysiloxanes having reactive functional groups, and one or more curing agents having functional groups reactive with the functional groups of the polysiloxane. Additionally provided is a process for applying the multi-component composite coatings described above to a substrate. Substrates coated with the above-described multi-component composite coating compositions are also provided.

TRIAMINE/ASPARTATE CURATIVE AND COATINGS COMPRISING THE SAME

A coating composition is disclosed comprising polyurea formed from a reaction mixture comprising isocyanate and a triamine/aspartate reaction product resulting from a Michael addition reaction of a triamine with a dialkyl maleate and/or a dialkyl fumarate. The reaction product has a viscosity of less than 2000 cPs, and the triamine has the structure: wherein each n is the same or different and is any integer. Substrates coated with these polyurea coatings comprising this reaction product are also disclosed.

Coating compositions having improved scratch resistance, coated substrates and methods related thereto

Compositions are provided which contain (a) one or more polysiloxanes comprising at least one reactive functional group; a plurality of particles; and optionally, one or more curing agents comprising at least one functional group that is reactive with any reactive functional group of polysiloxane (a). Additionally, a process for applying the multi-component composite coatings described above to a substrate and coated substrates are provided. A process for preparing the coating compositions also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.

Method for producing bicyclic guanidines by use of a cyclic thiourea

The present invention is directed to a method producing bicyclic guanidine comprising heating a cyclic thiourea to a temperature ranging from = 140 DEG C in a substantially non-hydrocarbon solvent to form the bicyclic guanidine.

Coating compositions having improved scratch resistance, coated substrates and methods related thereto

Coating compositions are provided which are formed from components comprising (a) at least one polysiloxane comprising at least one reactive functional group; (b) at least one reactant comprising at least one functional group that is reactive with at least one functional group selected from the at least one reactive functional group of the at least one polysiloxane and at least one functional group of at least one reactant; and (c) a plurality of particles, wherein each component is different, and wherein the at least one reactive functional group of the at least one polysiloxane and the at least one functional group of the at least one reactant are substantially nonreactive with the particles. A multi-component composite coating composition formed from a basecoat and a topcoat deposited from the curable coating composition also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.

Cured coatings having improved scratch resistance, coated substrates and methods thereto

Cured coatings having particles at a surface region of the cured coating are provided. Also provided are multi-component composite coatings which include a cured basecoat deposited from a pigmented coating composition and a cured topcoat deposited from a topcoating composition. The multi-component composite coatings of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.

Coating compositions comprising polyurea and a phosphorous-containing polyol

The present invention is directed to a coating composition comprising polyurea formed from a reaction mixture comprising: (a) a first component comprising isocyanate, wherein said isocyanate comprises an isocyanate functional prepolymer formed from a reaction mixture comprising isocyanate and a material comprising a phosphorus-containing polyol; and (b) a second component comprising an amine.

Polyurea/polythiourea coatings

Polyurea/polythiourea compositions comprising the reaction product of a first component comprising isocyanate and a second component comprising an amine, wherein the first component further comprises an isocyanate functional polythioether-polyurethane and/or polythiourethane, and/or the second component further comprises an amine/hydroxy functional polythioether, are disclosed. Methods for using the coating, and substrates coated therewith, are also disclosed.

Coating compositions having improved scratch resistance, coated substrates and methods related thereto

Coating compositions are provided which are formed from components comprising (a) at least one polysiloxane comprising at least one reactive functional group; (b) at least one reactant comprising at least one functional group that is reactive with at least one functional group selected from the at least one reactive functional group of the at least one polysiloxane and at least one functional group of at least one reactant; and (c) a plurality of particles, wherein each component is different, and wherein the at least one reactive functional group of the at least one polysiloxane and the at least one functional group of the at least one reactant are substantially nonreactive with the particles. A multi-component composite coating composition formed from a basecoat and a topcoat deposited from the curable coating composition also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.

ORGANIC SOLVENT-FREE FILM-FORMING COMPOSITIONS, MULTI-LAYER COMPOSITE COATINGS, AND RELATED METHODS

Provided is a film-forming composition substantially free of organic solvent which includes an aqueous dispersion of polymeric microparticles prepared by emulsion polymerization of a monomeric composition containing (1) at least 10 percent by weight of one or more vinyl aromatic compounds; (2) 0.1 to 10 percent by weight of one or more carboxylic acid functional polymerizable, ethylenically unsaturated monomers; (3) 0 to 10 percent by weight of one or more polymerizable monomers having one or more functional groups capable of reacting to form crosslinks; and (4) one or more polymerizable ethylenically unsaturated monomers. Each of (1), (2), (3) and (4) are different one from the other and at least one of (3) and (4) is present in the monomeric composition. Multi-layer composite coatings and coated substrates also are provided.

Low temperature application coating composition comprising polyurea and a phosphorus-containing polyol and footwear comprising polyurea

Coating compositions comprising a polyurea formed from a reaction mixture comprising: (a) a first component comprising an isocyanate, the first component having a viscosity of <= 2000 centipoise at a temperature >= 7 DEG C; and (b) a second component comprising an amine. Substrates coated at least in part with such a composition are also disclosed. Footwear coated at least in part with polyurea are also disclosed.

(Meth)acrylate/aspartate amine curatives and coatings and articles comprising the same

(Meth)acrylate/aspartate amine curatives comprising the reaction product of a polyamine, a dialkyl maleate and/or dialkyl fumarate, and a (meth)acrylate are disclosed, as are methods for making the same. A polyurea comprising the reaction product of the acrylate/aspartate amine curative and isocyanate is also disclosed, as are coatings comprising such a polyurea and substrates coated with the same.

LOW TEMPERATURE APPLICATION COATING COMPOSITION COMPRISING POLYUREA AND A PHOSPHORUS-CONTAINING POLYOL AND FOOTWEAR COMPRISING POLYUREA

Coating compositions comprising a polyurea formed from a reaction mixture comprising: (a) a first component comprising an isocyanate, the first component having a viscosity of ≦2000 centipoise at a temperature ≧7° C.; and (b) a second component comprising an amine. Substrates coated at least in part with such a composition are also disclosed. Footwear coated at least in part with polyurea are also disclosed. 1. A coating composition comprising a polyurea formed from a reaction mixture comprising:(a) a first component comprising an isocyanate, the first component having a viscosity of ≦2000 centipoise at a temperature ≧7° C., wherein the isocyanate comprises an isocyanate functional prepolymer formed from a reaction mixture comprising an initial isocyanate and a material comprising a phosphorus-containing polyol; and(b) a second component comprising an amine, wherein the second component has a viscosity of ≦1700 centipoise at a temperature ≧7° C.2. The coating composition according to claim 1 , wherein the initial isocyanate comprises a polyfunctional isocyanate resin comprising diphenylmethane diisocyanate claim 1 , toluene diisocyanate claim 1 , hexamethylene diisocyanate claim 1 , isophorone diisocyanate claim 1 , or combinations thereof.3. The coating composition according to claim 1 , wherein the isocyanate further comprises a non-prepolymer isocyanate that is substantially compatible with the isocyanate functional prepolymer.4. The coating composition according to claim 1 , wherein the phosphorus-containing polyol is a reaction product of reactants comprising a phosphorus-containing acid and an epoxy functional compound.5. The coating composition according to claim 4 , wherein the phosphorus-containing acid comprises phenyl phosphonic acid claim 4 , methyl phosphonic acid claim 4 , ethyl phosphonic acid claim 4 , propyl phosphoric acid claim 4 , butyl phosphonic acid claim 4 , or combinations thereof.6. The coating composition according to claim 4 , wherein the ...

Film-forming compositions having improved scratch resistance

Multi-component composite coating compositions are provided which comprise a base coat deposited from a pigmented film-forming composition and a transparent top coat applied over the base coat in which the transparent top coat is deposited from a film-forming composition comprising one ore more ungelled chain-extended organic polysiloxanes having reactive functional groups, and one or more curing agents having functional groups reactive with the functional groups of the polysiloxane. Additionally provided is a process for applying the multi-component composite coatings described above to a substrate. Substrates coated with the above-described multi-component composite coating compositions are also provided.

Coating compositions having improved scratch resistance, coated substrates and methods related thereto

Compositions are provided which contain (a) one or more polysiloxanes comprising at least one reactive functional group; a plurality of particles; and, optionally, one or more curing agents comprising at least one functional group that is reactive with any reactive functional group of polysiloxane (a). Additionally, a process for applying the multi-component composite coatings described above to a substrate and coated substrates are provided. A process for preparing the coating compositions also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.

Solvent-free film-forming compositions, coated substrates and method related thereto

An aqueous dispersion including polymeric microparticles which are prepared in a medium substantially free of organic solvent from a mixture of one or more reaction products of polymerizable, ethylenically unsaturated monomers, and one or more reactive organopolysiloxanes is provided. Pigmented film-forming compositions, curable compositions and topcoats of multi-component composite coating composition containing the above-described dispersions also are provided. The substantially solvent-free film-forming compositions of the invention are storage stable at room temperature and provide coatings with excellent application properties such as sag resistance and tack-free overspray, and excellent performance properties such as hardness and scratch resistance. The film-forming compositions are suitable for wet-on-wet application over a base coat with little or no mudcracking.

SUBSTRATES COATED WITH A POLYUREA COMPRISING A (METH)ACRYLATED AMINE REACTION PRODUCT

A metallic substrate coated at least in part with a multilayer coating composite, comprising at least one of an electrocoat layer, a base coat layer, and a clearcoat layer; and a polyurea formed from a reaction mixture comprising isocyanate and a (meth)acrylated amine reaction product of a monoamine and a poly(meth)acrylate is disclosed. The ratio of equivalents of isocyanate groups to equivalents of amine groups in the polyurea is greater than 1 and the isocyanate functional component and the (meth)acrylated amine functional component can be applied to the substrate at a volume mixing ratio of 1:1. A building comprising a building component coated at least in part with such a polyurea is also disclosed, as is a substrate coated at least in part with such a polyurea, wherein the ratio of equivalents or isocyanate to equivalents of amine groups is greater than 1.3:1.

Coating compositions having improved adhesion, coated substrates and methods related thereto

Coating compositions are provided which include a polysiloxane comprising at least one reactive functional group, at least one material comprising at least one reactive functional group, and at least one boron-containing compound. Also provided are multi-layer composite coatings formed from a basecoat deposited from a pigmented coating composition and a topcoat applied over the basecoat, the topcoat deposited from the aforementioned coating composition. Methods for repairing a multi-layer composite coating and coated substrates are also provided. The compositions of the invention provide highly scratch resistant coatings, particularly highly scratch resistant color-plus-clear coatings, which have excellent intercoat adhesion to subsequently applied coating layers.

Film-forming compositions substantially free of organic solvent, multi-layer composite coatings and related methods

Film-forming compositions are disclosed that are substantially free of organic solvent. The film-forming compositions include a resinous binder and at least one water dilutable additive including the reaction product of (i) a reactant including at least one isocyanate functional group with (ii) an active hydrogen containing alkoxypolyalkylene compound. Also disclosed are multi-layer composite coatings that include such film-forming compositions and methods of applying such multi-component composite coatings to a substrate.

Method for producing bicyclic guanidines by use of a cyclic thiourea

POLYUREA/POLYTHIOUREA COATINGS

Polyurea/polythiourea compositions comprising the reaction product of a first component comprising isocyanate and a second component comprising an amine, wherein the first component further comprises an isocyanate functional polythioether-polyurethane and/or polythiourethane, and/or the second component further comprises an amine/hydroxy functional polythioether, are disclosed. Methods for using the coating, and substrates coated therewith, are also disclosed. 1. A coating composition comprising polyurea and polythiourea formed from a reaction mixture comprising:{'sub': 12', '3', '2', '6', '4', '3', '2, 'a first component comprising (i) an isocyanate selected from one or more of isophorone diisocyanate (IPDI), cyclohexylene diisocyanate, 4,4′-methylenedicyclohexyl diisocyanate (HMDI), tetramethylxylyl diisocyanate, OCN—C(CH)—CHC(CH)—NCO, 1,4-tetramethylene diisocyanate, 1,5-pentamethylene diisocyanate, 1,6-hexamethylene diisocyanate (HMDI), 1,7-heptamethylene diisocyanate, 2,2,4-trimethylhexamethylene diisocyanate, 2,4,4-trimethylhexamethylene diisocyanate, 1,10-decamethylene diisocyanate, 2-methyl-1,5-pentamethylene diisocyanate, phenylene diisocyanate, toluene diisocyanate (TDI), xylene diisocyanate, 1,5-naphthalene diisocyanate, chlorophenylene 2,4-diisocyanate, bitoluene diisocyanate, dianisidine diisocyanate, tolidine diisocyanate, alkylated benzene diisocyanates, methylenediphenyl diisocyanate, 3,3′-dimethyl-4,4′-diphenylmethane diisocyanate, the uretdione of 1,6-hexamethylene diisocyanate, the biuret of 1,6-hexanediisocyanate, the isocyanurate of 1,6-hexanediisocyanate, and the isocyanurate of isophorone diisocyanate; and (ii) an isocyanate functional compound comprising a polythioether-polyurethane and/or polythiourethane; wherein at least 1 percent by weight of the first component comprises at least one polyisocyanate monomer; and'}a second component comprising an amine and an amine/hydroxy functional polythioether that is different from the amine, wherein ...

Polyurea/polythiourea coatings

Polyurea/polythiourea compositions comprising the reaction product of a first component comprising isocyanate and a second component comprising an amine, wherein the first component further comprises an isocyanate functional polythioether-polyurethane and/or polythiourethane, and/or the second component further comprises an amine/hydroxy functional polythioether, are disclosed. Methods for using the coating, and substrates coated therewith, are also disclosed.

Radiation curable coating compositions, related coatings and methods

Radiation curable coating compositions are disclosed. The radiation curable coating composition comprises a) an organic film-forming binder comprising (i) a urethane (meth)acrylate comprising the reaction product of reactants comprising a polyol and a polyisocyanate comprising at least two (meth)acrylate functional groups per molecule; and (ii) a highly functional (meth)acrylate; and b) a (meth)acrylate functional silsesquioxane dispersed in the binder. Also disclosed are related methods for coating a substrate, coated substrates and cured coatings formed from the radiation curable coating compositions.

Flexible coating compositions having improved scratch resistance, coated substrates and methods related thereto

Coating compositions are provided which include a polysiloxane comprising at least one reactive functional group and at least one material comprising at least one reactive functional group. Also provided are multi-layer composite coatings formed from a basecoat deposited from a pigmented coating composition and a topcoat applied over the basecoat, the topcoat deposited from the aforementioned coating composition. A method for improving the scratch resistance of a coated substrate, as well as coated substrates also are provided. The compositions of the invention provide highly scratch resistant coatings, particularly highly scratch resistant color-plus-clearcoatings.

Coating compositions having improved scratch resistance, coated substrates and methods related thereto

Compositions are provided which contain (a) one or more polysiloxanes comprising at least one reactive functional group; a plurality of particles; and, optionally, one or more curing agents comprising at least one functional group that is reactive with any reactive functional group of polysiloxane (a). Additionally, a process for applying the multi-component composite coatings described above to a substrate and coated substrates are provided. A process for preparing the coating compositions also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.

Coating compositions having improved scratch resistance, coated substrates and methods related thereto

Compositions are provided which contain (a) one or more polysiloxanes comprising at least one reactive functional group; a plurality of particles; and, optionally, one or more curing agents comprising at least one functional group that is reactive with any reactive functional group of polysiloxane (a). Additionally, a process for applying the multi-component composite coatings described above to a substrate and coated substrates are provided. A process for preparing the coating compositions also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.

FLEXIBLE COATING COMPOSITIONS WITH IMPROVED SCRATCH RESISTANCE, COATED SURFACE, AND METHOD FOR THE PRODUCTION THEREOF

Cured coatings having improved scratch resistance, coated substrates and methods related thereto

Cured coatings having particles at a surface region of the cured coating are provided. Also provided are multi-component composite coatings which include a cured basecoat deposited from a pigmented coating composition and a cured topcoat deposited from a topcoating composition. The multi-component composite coatings of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.

COATING COMPOSITIONS BASED ON VINYL ADDITION RESINS AND AMINO-MODIFIED RESINS

Compositions de revêtement. Elles contiennent une résine filmogène consistant essentiellement en environ 15 % à environ 90 % d'une résine d'addition vinylique et en environ 10% à environ 85% d'une résine modifiée par une amine. La résine modifiée par une amine résulte de la réaction d'ouverture de cycle d'un groupe 1,2- époxy sur une résine polyépoxyde avec de l'ammoniaque, une amine primaire, une amine secondaire ou leurs mélanges. Application au revêtement intérieur des récipients métalliques pour aliments et boissons. Coating compositions. They contain a film forming resin consisting essentially of about 15% to about 90% of a vinyl addition resin and about 10% to about 85% of an amine modified resin. The amine modified resin results from the ring opening reaction of a 1,2-epoxy group on a polyepoxide resin with ammonia, a primary amine, a secondary amine, or mixtures thereof. Application to the interior lining of metal containers for food and drink.

Coating compositions comprising polyurea and a phosphorus-containing polyol

The present invention is directed to a coating composition comprising polyurea formed from a reaction mixture comprising: (a) a first component comprising isocyanate, wherein said isocyanate comprises an isocyanate functional prepolymer formed from a reaction mixture comprising isocyanate and a material comprising a phosphorus-containing polyol; and (b) a second component comprising an amine.

Method for producing bicyclic guanidines by use of a cyclic thiourea

The present invention is directed to a method producing bicyclic guanidine comprising heating a cyclic thiourea to a temperature ranging from >= 140°C in a substantially non-hydrocarbon solvent to form the bicyclic guanidine.

Hardened coatings with enhanced scratch resistance and coated substrates.

Un recubrimiento curado que comprende una pluralidad de partículas en todo el recubrimiento, siendo la concentración de partículas dentro de la región superficial del recubrimiento superior a la concentración de partículas dentro de la región de volumen del recubrimiento, estando formado el recubrimiento curado a partir de una composición de recubrimiento curable que comprende: (a) al menos un material de formación de película que tiene al menos un grupo funcional reactivo; (b) una pluralidad de partículas; y (c) al menos un agente tensioactivo. A cured coating comprising a plurality of particles throughout the coating, the concentration of particles within the surface region of the coating being greater than the concentration of particles within the volume region of the coating, the cured coating being formed from a curable coating composition comprising: (a) at least one film forming material having at least one reactive functional group; (b) a plurality of particles; and (c) at least one surfactant.

Low temperature application coating composition comprising polyurea and a phosphorus-containing polyol and footwear comprising polyurea

POLYUREA / POLYTIOUREA COATINGS

Se describen composiciones de poliurea/politiourea que comprenden el producto de reaccion de un primer componente que comprende isocianato y un segundo componente que comprende una amina, donde el primer componente además comprende un politioéter-poliuretano y/o politiouretano isocianato funcional, y/o el segundo componente además comprende un politioéter amina/hidroxi funcional. También se describen métodos para utilizar el recubrimiento y los sustratos recubiertos con él. Polyurea / polythiourea compositions comprising the reaction product of a first component comprising isocyanate and a second component comprising an amine are described, wherein the first component further comprises a polythioether polyurethane and / or functional polythiourethane isocyanate, and / or the The second component also comprises a functional amine / hydroxy polythioether. Methods for using the coating and the substrates coated therewith are also described.

Cured coatings having improved scratch resistance, coated substrates and methods related thereto

Cured coatings having particles at a surface region of the cured coating are provided. Also provided are multi-component composite coatings which include a cured basecoat deposited from a pigmented coating composition and a cured topcoat deposited from a topcoating composition. The multi-component composite coatings of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.

Cured coatings having improved scratch resistance, coated substrates and methods related thereto

Cured coatings having particles at a surface region of the cured coating are provided. Also provided are multi-component composite coatings which include a cured basecoat deposited from a pigmented coating composition and a cured topcoat deposited from a topcoating composition. The multi-component composi te coatings of the invention provide highly scratch resistant color-plus- clearcoatings capable of retaining scratch resistance after weathering.</SDO AB>

Coating compositions having improved adhesion, coated substrates and methods related thereto

Coating compositions are provided which include a polysiloxane comprising at least one reactive functional group, at least one material comprising at least one reactive functional group, and at least one boron-containing compound. Also provided are multi-layer composite coatings formed from a basecoat deposited from a pigmented coating composition and a topcoat applied over the basecoat, the topcoat deposited from the aforementioned coating composition. Methods for repairing a multi-layer composite coating and coated substrates are also provided. The compositions of the invention provide highly scratch resistant coatings, particularly highly scratch resistant color-plus-clear coatings, which have excellent intercoat adhesion to subsequently applied coating layers.

Carboxylated amide polymers and coating compositions containing same

Abstract of the Disclosure Carboxylated amide polymers and coating compositions containing same are especially useful for the coating of food and beverage containers. The carboxylated amide polymers are the reaction product of (1) a compound of formula:

Triamine/aspartate curative and coatings comprising the same

The reaction product of a triamine and a dialkyl maleate and/or dialkyl fumarate, wherein the reaction product has a viscosity of less than 2000 cPs is disclosed. Polyurea coatings comprising this reaction product are also disclosed, as are substrates coated with the same.

Polyurea coating comprising an amine/(meth)acrylate oligomeric reaction product

Coating compositions comprising a polyurea formed from a reaction mixture comprising isocyanate and an acrylated amine are disclosed. The (meth)acrylated amine is the reaction product of a polyamine and a (meth)acrylate; when the (meth)acrylate comprises a poly(meth)acrylate, the reaction product further comprises a mono(meth)acrylate and/or a monoamine. Methods for using the coatings, and substrates coated therewith, are also disclosed.

Coating compositions comprising polyurea and a phosphorus-containing polyol

The present invention is directed to a coating composition comprising polyurea formed from a reaction mixture comprising: (a) a first component comprising isocyanate, wherein said isocyanate comprises an isocyanate functional prepolymer formed from a reaction mixture comprising isocyanate and a material comprising a phosphorus-containing polyol; and (b) a second component comprising an amine.

Solvent-free film-forming compositions, coated substrates and method related thereto

An aqueous dispersion including polymeric microparticles which are prepared in a medium substantially free of organic solvent from a mixture of one or more reaction products of polymerizable, ethylenically unsaturated monomers, and one or more reactive organopolysiloxanes is provided. Pigmented film-forming compositions, curable compositions and topcoats of multi-component composite coating composition containing the above described dispersions also are provided. The substantially solvent-free film-forming compositions of the invention are storage stable at room temperature and provide coating with excellent application properties such as sag resistance and tack-free overspray, and excellent performance properties such as hardness and scratch resistance. The film-forming compositions are suitable for wet-on-wet application over a base coat with little or no mudcracking.

Coating compositions comprising polyurea and a phosphorus-containing polyol

The present invention is directed to a coating composition comprising polyurea formed from a reaction mixture comprising: (a) a first component comprising isocyanate, wherein said isocyanate comprises an isocyanate functional prepolymer formed from a reaction mixture comprising isocyanate and a material comprising a phosphorus-containing polyol; and (b) a second component comprising an amine.

Coating compositions with modified particles and methods of using the same

Powder coating compositions having improved mar and scratch resistance are disclosed. The coatings generally comprise one or more particles that have been modified to render the particles more surface active. The improved resistance is achieved without affecting the appearance or mechanical performance of the coatings. Methods for using the coatings, and the substrates coated therewith, are also disclosed.

Cured coatings having improved scratch resistance and coated substrates

Cured coatings having particles at a surface region of the cured coating are provided. Also provided are multi-component composite coatings which include a cured basecoat deposited from a pigmented coating composition and a cured topcoat deposited from a topcoating composition. The multi-component composite coatings of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.

Polyurea/polythiourea coatings

Polyurea/polythiourea compositions comprising the reaction product of a first component comprising isocyanate and a second component comprising an amine, wherein the first and/or second component further comprises a sulfur-containing compound are disclosed. Methods for using the coating, and substrates coated therewith, are also disclosed.

Multi-component coatings that include polyurea coating layers

A polyurea composition, a multi-component composite coating and articles formed therefrom, and methods of forming the same are disclosed. The coating composition is formed from a reaction mixture comprising an isocyanate-functional component and an amine-functional component. The ratio of equivalents of isocyanate groups to equivalents of amine groups is greater than 1 while the volume mixing ratio of the isocyanate-functional component to the amine-functional component is capable of being applied to a substrate at 1:1.

(meth)acrylate/aspartate amine curatives and coatings and articles comprising the same

(Meth)acrylate/aspartate amine curatives comprising the reaction product of a polyamine, a dialkyl maleate and/or dialkyl fumarate, and a (meth)acrylate are disclosed, as are methods for making the same. A polyurea comprising the reaction product of the acrylate/aspartate amine curative and isocyanate is also disclosed, as are coatings comprising such a polyurea and substrates coated with the same.

Coating compositions having improved adhesion, coated substrates and methods related thereto

Coating compositions are provided which include a polysiloxane comprising at least one reactive functional group, at least one material comprising at least one reactive functional group, and at least one boron-containing compound. Also provided are multi-layer composite coatings formed from a basecoat deposited from a pigmented coating composition and a topcoat applied over the basecoat, the topcoat deposited from the aforementioned coating composition. Methods for repairing a multi-layer composite coating and coated substrates are also provided. The compositions of the invention provide highly scratch resistant coatings, particularly highly scratch resistant color-plus-clear coatings, which have excellent intercoat adhesion to subsequently applied coating layers.

Polyurea/polythiourea coatings

Polyurea/polythiourea compositions comprising the reaction product of a first component comprising isocyanate and a second component comprising an amine, wherein the first component further comprises an isocyanate functional polythioether-polyurethane and/or polythiourethane, and/or the second component further comprises an amine/hydroxy functional polythioether, are disclosed. Methods for using the coating, and substrates coated therewith, are also disclosed.

Coating compositions with modified particles and methods of using the same

Liquid coating compositions having improved mar and scratch resistance are disclosed. The coatings generally comprise one or more particles that have been modified to render the particles more surface active. The improved resistance is achieved without affecting the appearance or mechanical performance of the coatings. Methods for using the coatings, and the substrates coated therewith, are also disclosed.

Substrates coated with a polyurea comprising a (meth)acrylated amine reaction product

A metallic substrate coated at least in part with a multilayer coating composite, comprising at least one of an electrocoat layer, a base coat layer, and a clearcoat layer; and a polyurea formed from a reaction mixture comprising isocyanate and a (meth)acrylated amine reaction product of a monoamine and a poly(meth)acrylate is disclosed. The ratio of equivalents of isocyanate groups to equivalents of amine groups in the polyurea is greater than 1 and the isocyanate functional component and the (meth)acrylated amine functional component can be applied to the substrate at a volume mixing ratio of 1:1. A building comprising a building component coated at least in part with such a polyurea is also disclosed, as is a substrate coated at least in part with such a polyurea, wherein the ratio of equivalents or isocyanate to equivalents of amine groups is greater than 1.3:1.

Film-forming compositions substantially free of organic solvent, multi-layer composite coatings and related methods

Film-forming compositions are disclosed that are substantially free of organic solvent. The film-forming compositions include a resinous binder and at least one water dilutable additive including the reaction product of (i) a reactant including at least one isocyanate functional group with (ii) an active hydrogen containing alkoxypolyalkylene compound. Also disclosed are multi-layer composite coatings that include such film-forming compositions and methods of applying such multi-component composite coatings to a substrate.

Coating compositions having improved scratch resistance, coated substrates and methods related thereto

Coating compositions are provided which are formed from components comprising (a) at least one polysiloxane comprising at least one reactive functional group; (b) at least one reactant comprising at least one functional group that is reactive with at least one functional group selected from the at least one reactive functional group of the at least one polysiloxane and at least one functional group of at least one reactant; and (c) a plurality of particles, wherein each component is different, and wherein the at least one reactive functional group of the at least one polysiloxane and the at least one reactive functional group of the at least one reactant are substantially nonreactive with the particles. A multi-component composite coating composition formed from a basecoat and a topcoat deposited from the curable coating composition also is provided. The multi-component composite coating compositions of the invention provide highly scratch resistant color-plus-clearcoatings capable of retaining scratch resistance after weathering.

Coating compositions comprising polyurea or polyurea and polyurethane

The present invention is directed to a coating composition comprising polyurea and polyurethane. Further, the present invention is directed to a coating composition comprising polyurea or, polyurea and polyurethane, and flame retardant. The polyurea is formed from a reaction mixture comprising isocyanate and amine wherein the ratio of equivalents of isocyanate groups to equivalents of amine groups is greater than 1 and the isocyanate-functional component and the amine-functional component can be applied to a substrate at a volume mixing ratio of 1:1.

Triamine/aspartate curative and coatings comprising the same

The reaction product of a triamine and a dialkyl maleate and/or dialkyl fumarate, wherein the reaction product has a viscosity of less than 2000 cPs is disclosed. Polyurea coatings comprising this reaction product are also disclosed, as are substrates coated with the same.

Flexible coating compositions having improved scratch resistance, coated substrates and methods related thereto

Coating compositions are provided which include a polysiloxane comprising at least one reactive functional group and at least one material comprising at least one reactive functional group. Also provided are multi-layer composite coatings formed from a basecoat deposited from a pigmented coating composition and a topcoat applied over the basecoat, the topcoat deposited from the aforementioned coating composition. A method for improving the scratch resistance of a coated substrate, as well as coated substrates also are provided. The compositions of the invention provide highly scratch resistant coatings, particularly highly scratch resistant color-plus-clearcoatings.

Coating compositions having improved adhesion, coated substrates and methods related thereto

Coating compositions are provided which include a polysiloxane comprising at least one reactive functional group, at least one material comprising at least one reactive functional group, and at least one boron-containing compound. Also provided are multi-layer composite coatings formed from a basecoat deposited from a pigmented coating composition and a topcoat applied over the basecoat, the topcoat deposited from the aforementioned coating composition. Methods for repairing a multi-layer composite coating and coated substrates are also provided. The compositions of the invention provide highly scratch resistant coatings, particularly highly scratch resistant color-plus-clear coatings, which have excellent intercoat adhesion to subsequently applied coating layers.

Polyurea/polythiourea coatings

Polyurea/polythiourea compositions comprising the reaction product of a first component comprising isocyanate and a second component comprising an amine, wherein the first component further comprises an isocyanate functional polythioether-polyurethane and/or polythiourethane, and/or the second component further comprises an amine/hydroxy functional polythioether, are disclosed. Methods for using the coating, and substrates coated therewith, are also disclosed.

Flexible coating compositions having improved scratch resistance, coated substrates and methods related thereto

Coating compositions are provided which include a polysiloxane comprising at least one reactive functional group and at least one material comprising at least one reactive functional group. Also provided are multi-layer composite coatings formed from a basecoat deposited from a pigmented coating composition and a topcoat applied over the basecoat, the topcoat deposited from the aforementioned coating composition. A method for improving the scratch resistance of a coated substrate, as well as coated substrates also are provided. The compositions of the invention provide highly scratch resistant coatings, particularly highly scratch resistant color-plus-clearcoatings.

Multi-component coatings that include polyurea coating layers.

Se describe una composicion de poliurea, un revestimiento de composicion de varios componentes y articulos y metodos formados a partir de ella. La composicion de revestimiento se forma mediante una mezcla de reaccion que comprende un componente isocianato funcional y un componente amino funcional. La relacion de equivalente de grupos isocianatos a equivalente de grupos aminos es mayor que uno mientras que la relacion de mezclado de volumen del componente isocianato funcional al componente amino funcional es capaz de ser aplicado a un sustrato a l:1.

Multi-component coatings that include polyurea coating layers

A polyurea composition, a multi-component composite coating and articles formed therefrom, and methods of forming the same are disclosed. The coating composition is formed from a reaction mixture comprising an isocyanate-functional component and an amine-functional component. The ratio of equivalents of isocyanate groups to equivalents of amine groups is greater than 1 while the volume mixing ratio of the isocyanate-functional component to the amine-functional component is capable of being applied to a substrate at 1:1.

Polyharnstoffbeschichtung mit einem oligomeren amin(meth)acrylat-reaktionsprodukt

Beschichtungszusammensetzungen mit verbesserter kratzfestigkeit und beschichtete oberflächen

Beschichtungszusammensetzungen mit verbesserter kratzfestigkeit, beschichtete oberfläche und verfahren zu deren herstellung

(meth)acrylat-/aspartatamin-heilmittel und beschichtungen und artikel damit

Composizione di rivestimento diresine di addizione viniliche e resine modificate con ammine.