23-08-2012 дата публикации
Номер: US20120211696A1
The present invention relates to diionic liquid salts of dicationic or dianionic molecules, as well as solvents comprising such diionic liquids and the use of such diionic liquids as the stationary phase in a gas chromatographic column. 164-. (canceled)65. A mixed stationary phase comprising at least one stationary phase material and at least one dicationic liquid salt comprising a dicationic species of Formula I:{'br': None, 'A-B-A′\u2003\u2003Formula I'}and at least one counter anion, wherein{'sub': 3', '2', '2', '3', '2, 'sup': +', '+', '+', '+', '+, 'A and A′ are mono-cationic groups independently selected from the group consisting of —[N(R)], —[N(R)H], —[S(R)], —[P(R)], —[As(R)], optionally substituted imidazolium, optionally substituted pyridinium, and pyrrolidinium, wherein each R is selected from the group consisting of alkyl, alkenyl, alkynyl, cycloalkyl, phenyl, and benzyl; and'}{'sub': 2', '40, 'B is an optionally substituted C-Chydrocarbon backbone, wherein the hydrocarbon backbone optionally contains at least one heteroatom selected from the group consisting of nitrogen, oxygen, sulfur, and silicon.'}66. The mixed stationary phase of claim 65 , wherein the at least one stationary phase material is selected from the group consisting of polysiloxane claim 65 , polyethyleneglycol claim 65 , methylpolysiloxane claim 65 , phenyl substituted methylpolysiloxane claim 65 , nitrile substituted methylpolysiloxane claim 65 , and carbowax.67. The mixed stationary phase of claim 65 , wherein the ratio of the diionic liquid salt and the stationary phase material is from about 1:9 to about 9:1.68. The mixed stationary phase of claim 65 , wherein the ratio of the diionic liquid salt and the stationary phase material is from about 1:2 to about 2:1.69. The mixed stationary phase of claim 65 , wherein the diionic liquid salt is (dibutyl imidazolium)(CH)and the stationary phase material is methylpolysiloxane.70. The mixed stationary phase of claim 69 , wherein the ratio of ...
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