24-08-2017 дата публикации
Номер: US20170240676A1
A composition including at least one moisture-curable, semi-crystalline (meth)acrylic oligomer represented by the formula: 1. A composition comprising at least one moisture-curable, semi-crystalline (meth)acrylic oligomer represented by the formula:{'sub': 1', '16', '40, 'Ris independently a Cto Calkyl group;'}{'sub': 2', '16', '40, 'Ris independently a Cto Calkyl group;'}{'sub': '3', 'each Ris independently a methyl, ethyl, or isopropyl group;'}X is a chain transfer agent as defined further below;Y is independently selected to be a methyl, ethyl, or isopropyl group;a, b and c are each independently selected to be an integer of at least 10, and a+b+c≦1500;n≧1; andp is 0, 1, 2, or 3.wherein: This application is a continuation of U.S. Pat. No. 14/648,470, filed May 29, 2015, which is a national stage filing under 35 U.S.C. 371 of International Patent Application No. PCT/US2013/028519, filed Mar. 1, 2013, which claims priority to U.S. Provisional Patent Application No. 61/746,143, filed Dec. 27, 2012, the disclosures of which are incorporated by reference herein in their entirety.The present disclosure relates to moisture-curable, semi-crystalline (meth)acrylic oligomers, and more particularly to the use of such oligomers in the manufacture of construction articles, for example, roofing granules used in asphalt shingles.Moisture-curing polymer systems, including moisture-curing siloxane polymers (i.e. silicones), are known. Siloxane polymers have unique properties derived mainly from the physical and chemical characteristics of the siloxane bond. These properties include low glass transition temperature, thermal and oxidative stability, resistance to ultraviolet radiation, low surface energy and hydrophobicity, high permeability to many gases, and biocompatibility. The siloxane polymers, however, often lack tensile strength.The low tensile strength of the siloxane polymers can be improved by forming block copolymers. Some block copolymers contain a “soft” siloxane ...
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