30-04-2015 дата публикации
Номер: US20150119532A1
Принадлежит:
Disclosed is a poly(ethylene-aliphatic diene) copolymer having superior miscibility, adhesivity, printability and scratch resistance, compared to conventional TPO based TPEs or SBC TPEs, by introducing a variety of functional groups to an end portion of the ethylene-aliphatic diene copolymer such that the poly(ethylene-aliphatic diene) copolymer may be utilized in a variety of fields, and a method thereof. 1. A poly(ethylene-aliphatic diene) copolymer comprising an ethylene block and aliphatic diene block , wherein a portion of the aliphatic diene block is modified by substituting with a functional group selected from the group consisting of a sulfide group , a hydroxyl group , an epoxy group , an amine group , a carboxylic acid group , a silane group and combinations thereof.3. The poly(ethylene-aliphatic diene) copolymer according to claim 1 , wherein the aliphatic diene block is polymerized with one monomer selected from the group consisting of 1 claim 1 ,3-butadiene claim 1 , isoprene claim 1 , 2 claim 1 ,3-dimethyl-1 claim 1 ,3-butadiene claim 1 , 1 claim 1 ,2-dimethyl-1 claim 1 ,3-butadiene claim 1 , 1 claim 1 ,4-dimethyl-1 claim 1 ,3-butadiene claim 1 , 1-ethyl-1 claim 1 ,3-butadiene claim 1 , 3-butyl-1 claim 1 ,3-octadiene claim 1 , 1 claim 1 ,3-hexadiene claim 1 , 4-methyl-1 claim 1 ,3-petadiene claim 1 , 1 claim 1 ,3-petadiene claim 1 , 3-methyl-1 claim 1 ,3-petadiene claim 1 , 2 claim 1 ,4-dimethyl-1 claim 1 ,3-petadiene claim 1 , 3-ethyl-1 claim 1 ,3-petadiene claim 1 , and combinations thereof.4. The poly(ethylene-aliphatic diene) copolymer according to claim 1 , wherein the aliphatic diene block is 5 to 50% substituted.5. The poly(ethylene-aliphatic diene) copolymer according to claim 1 , wherein an average molecular weight of the poly(ethylene-aliphatic diene) copolymer is 20 claim 1 ,000 to 3 claim 1 ,000 claim 1 ,000 and molecular weight distribution of the poly(ethylene-aliphatic diene) copolymer is 1.2 to 3.0.6. A method of preparing the poly( ...
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