Molecules having pesticidal utility, and intermediates, compositions, and processes, related thereto

This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula (“Formula One”).

Pesticidal compositions and processes related thereto

This document discloses molecules having the following formula (“Formula One”): and processes related thereto.

Pesticidal compositions and processes related thereto

This document discloses molecules having the following formula (“Formula One”): and processes related thereto.

Molecules having pesticidal utility, and intermediates, compositions, and processes, related thereto

This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula (“Formula One”).

Molecules having pesticidal utility, and intermediates, compositions, and processes, related thereto

This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula (“Formula One”). 2. A molecule according to wherein the carboxamido claim 1 , and the phenyl claim 1 , which are bonded to the cyclopropane claim 1 , are in the R claim 1 ,R configuration.3. A molecule according to wherein Ris selected from the group consisting of H claim 1 , F claim 1 , or Cl.4. A molecule according to wherein Ris selected from the group consisting of H claim 1 , F claim 1 , Cl claim 1 , Br claim 1 , CH claim 1 , and CF.5. A molecule according to wherein Ris selected from the group consisting of H claim 1 , F claim 1 , Cl claim 1 , Br claim 1 , CH claim 1 , CF claim 1 , and OCF.6. A molecule according to wherein Ris selected from the group consisting of H claim 1 , F claim 1 , Cl claim 1 , Br claim 1 , CH claim 1 , and CF.7. A molecule according to wherein Ris selected from the group consisting of H claim 1 , F claim 1 , and Cl.8. A molecule according to wherein Ris H.9. A molecule according to wherein Ris selected from the group consisting of Cl and Br.10. A molecule according to wherein Ris selected from the group consisting of Cl and Br.11. A molecule according to wherein Ris H.12. A molecule according to wherein Ris selected from the group consisting of H and CH.13. A molecule according to wherein Ris selected from the group consisting of H claim 1 , F claim 1 , Cl claim 1 , and CH.14. A molecule according to wherein Ris selected from the group consisting of H and Cl.15. A molecule according to wherein Qis O.16. A molecule ...

PESTICIDAL COMPOSITIONS AND PROCESSES RELATED THERETO

This document discloses molecules having the following formula (“Formula One”): 2. A composition according to wherein said molecule said A is A1.3. A composition according to wherein said molecule said A is A2.4. A composition according to wherein said molecule said R1 is H.5. A composition according to wherein said molecule said R2 is H.6. A composition according to wherein said molecule said R3 is selected from H claim 1 , or substituted or unsubstituted C-Calkyl.7. A composition according to wherein said molecule said R3 is selected from H or CH.8. A composition according to wherein said molecule when said A is A1 then A1 is A11.9. A composition according to wherein said molecule when said A is A1 claim 1 , and A1 is A11 claim 1 , then R4 is selected from H claim 1 , or substituted or unsubstituted C-Calkyl claim 1 , or substituted or unsubstituted C-Caryl.10. A composition according to wherein said molecule when said when A is A1 claim 1 , and A1 is A1 then R4 is selected from CH claim 1 , CH(CH) claim 1 , or phenyl.11. A composition according to wherein said molecule when said when A is A1 claim 1 , and A1 is A12 claim 1 , then R4 is CH.12. A composition according to wherein said molecule when said A is A2 then R4 is selected from H claim 1 , substituted or unsubstituted C-Calkyl claim 1 , substituted or unsubstituted C-Calkenyl claim 1 , substituted or unsubstituted C-Ccycloalkyl claim 1 , substituted or unsubstituted C-Caryl claim 1 , wherein each said R4 claim 1 , which is substituted claim 1 , has one or more substituents selected from F claim 1 , Cl claim 1 , Br claim 1 , or I.13. A composition according to wherein said molecule when said A is A2 then R4 is H or C-Calkyl.14. A composition according to wherein said molecule when said A is A2 then R4 is H claim 1 , CH claim 1 , CHCH claim 1 , CH═CH claim 1 , cyclopropyl claim 1 , CHCl claim 1 , CF claim 1 , or phenyl.15. A composition according to wherein said molecule when said A is A2 then R4 is Cl.16. A ...

Molecules having certain pesticidal utilities, and intermediates, compositions, and processes related thereto

This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Nematoda, Arthropoda, and/or Mollusca, processes to produce such molecules and intermediates used in such processes, compositions containing such molecules, and processes of using such molecules against such pests. These molecules may be used, for example, as nematicides, acaricides, insecticides, miticides, and/or molluscicides. This document discloses molecules having the following formula (“Formula One”).

PESTICIDAL COMPOSITIONS AND PROCESSES RELATED THERETO

This document discloses molecules having the following formula (“Formula One”): 2. A composition according to wherein said molecule said A is A1.3. A composition according to wherein said molecule said A is A2.4. A composition according to wherein said molecule said R1 is H.5. A composition according to wherein said molecule said R2 is H.6. A composition according to wherein said molecule said R3 is selected from H claim 1 , or substituted or unsubstituted C-Calkyl.7. A composition according to wherein said molecule said R3 is selected from H or CH.8. A composition according to wherein said molecule when said A is A1 then A1 is A11.9. A composition according to wherein said molecule when said A is A1 claim 1 , and A1 is A11 claim 1 , then R4 is selected from H claim 1 , or substituted or unsubstituted C-Calkyl claim 1 , or substituted or unsubstituted C-Caryl.10. A composition according to wherein said molecule when said when A is A1 claim 1 , and A1 is A11 then R4 is selected from CH claim 1 , CH(CH) claim 1 , or phenyl.11. A composition according to wherein said molecule when said when A is A1 claim 1 , and A1 is A12 claim 1 , then R4 is CH.12. A composition according to wherein said molecule when said A is A2 then R4 is selected from H claim 1 , substituted or unsubstituted C-Calkyl claim 1 , substituted or unsubstituted C-Calkenyl claim 1 , substituted or unsubstituted C-Ccycloalkyl claim 1 , substituted or unsubstituted C-Caryl claim 1 , wherein each said R4 claim 1 , which is substituted claim 1 , has one or more substituents selected from F claim 1 , Cl claim 1 , Br claim 1 , or I.13. A composition according to wherein said molecule when said A is A2 then R4 is H or C-Calkyl.14. A composition according to wherein said molecule when said A is A2 then R4 is H claim 1 , CH claim 1 , CHCH claim 1 , CH═CH claim 1 , cyclopropyl claim 1 , CHCl claim 1 , CF claim 1 , or phenyl.15. A composition according to wherein said molecule when said A is A2 then R4 is Cl.16. A ...

Processes for the preparation of pesticidal compounds

The present application provides processes for making pesticidal compounds and compounds useful both as pesticides and in the making of pesticidal compounds.

PROCESSES FOR THE PREPARATION OF PESTICIDAL COMPOUNDS

The present application provides processes for making pesticidal compounds and compounds useful both as pesticides and in the making of pesticidal compounds.

Pesticidal compositions and related methods

This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula I, or any agriculturally acceptable salt thereof, wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , X 1 , Q, and n are as described herein.

PROCESSES FOR THE PREPARATION OF PESTICIDAL COMPOUNDS

The present application provides processes for making pesticidal compounds and compounds useful both as pesticides and in the making of pesticidal compounds. 2. (canceled)6. (canceled)1719.-. (canceled)20. (canceled)2228.-. (canceled)31. (canceled) This application claims the benefit of the following U.S. Provisional patent applications: Ser. No. 62/042,554 filed Aug. 27, 2014; and Ser. No. 61/892,129 filed Oct. 17, 2013, the entire disclosures of which are hereby expressly incorporated by reference into this Application.This application relates to efficient and economical synthetic chemical processes for the preparation of pesticidal thioethers and pesticidal sulfoxides. Further, the present application relates to certain novel compounds necessary for their synthesis. It would be advantageous to produce pesticidal thioether and pesticidal sulfoxides efficiently and in high yield from commercially available starting materials.The following definitions apply to the terms as used throughout this specification, unless otherwise limited in specific instances.As used herein, the term “alkyl” denotes branched or unbranched hydrocarbon chains.As used herein, the term “alkynyl” denotes branched or unbranched hydrocarbon chains having at least one C≡C.Unless otherwise indicated, the term “cycloalkyl” as employed herein alone is a saturated cyclic hydrocarbon group, such as cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl.The term “thio” as used herein as part of another group refers to a sulfur atom serving as a linker between two groups.The term “halogen” or “halo” as used herein alone or as part of another group refers to chlorine, bromine, fluorine, and iodine.The pesticidal thioethers of formula 3cand the pesticidal sulfoxides of formula 3dwherein,In step a of Scheme 1, 3-hydrazinopyridine dihydrochloride is reacted with methyl acrylate in the presence of a base such as sodium methoxide or sodium ethoxide to yield 1-(pyridin-3-yl)pyrazolidin-3-one followed by ...

Molecules having pesticidal utility, and intermediates, compositions, and processes, related thereto

This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula (“Formula One”). 2. A molecule according to claim 1 , wherein Ris selected from the group consisting of H claim 1 , F claim 1 , and Cl.3. A molecule according to claim 1 , wherein Ris selected from the group consisting of H claim 1 , F claim 1 , and Cl.4. A molecule according to claim 1 , wherein Ris F or Cl.5. A molecule according to claim 1 , wherein R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , and Rare each independently H.6. A molecule according to claim 1 , wherein Ris selected from the group consisting of CI and Br.7. A molecule according to claim 1 , wherein Ris selected from the group consisting of CI and Br.8. A molecule according to claim 1 , wherein Ris selected from the group consisting of H claim 1 , Cl claim 1 , and CF.9. A molecule according to claim 1 , wherein Ris selected from the group consisting of H and CH.10. A molecule according to claim 1 , wherein Ris selected from the group consisting of CH claim 1 , CHCH claim 1 , CHCHCH claim 1 , CHCHCHCH claim 1 , CHCHCHOCHCH claim 1 , CH claim 1 , CHCH claim 1 , CHCHCH claim 1 , CHCHCHCH claim 1 , CHCHCHCHCH claim 1 , CHCHCHCHCHCH claim 1 , CHCH(CH) claim 1 , CHcyclopropyl claim 1 , CHCHcyclopropyl claim 1 , CHcyclobutyl claim 1 , CHphenyl claim 1 , CHCHphenyl claim 1 , CHC═CH claim 1 , CHC═CH claim 1 , CHCF claim 1 , CHCHF claim 1 , CHCHCF claim 1 , CHCFCF claim 1 , CHCHCHCF claim 1 , CHCHCFCF claim 1 , CHCFCFCF claim 1 , CHCHCHCHF claim 1 , CHCHSCH ...

Processes for the preparation of pesticidal compounds

The present application provides processes for making pesticidal compounds and compounds useful both as pesticides and in the making of pesticidal compounds.

Pesticidal compositions and processes related thereto

This document discloses molecules having the following formula (“Formula One”): and processes related thereto.

Molecules Having Pesticidal Utility, and Intermediates, Compositions, and Processes, Related Thereto

This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula (“Formula One”). 2. A molecule according to claim 1 , wherein Ris selected from the group consisting of H and Cl.3. A molecule according to claim 1 , wherein Ris selected from the group consisting of H claim 1 , Cl claim 1 , Br claim 1 , CH claim 1 , and CF.4. A molecule according to claim 1 , wherein Ris selected from the group consisting of H claim 1 , F claim 1 , Cl claim 1 , CH claim 1 , CF claim 1 , and OCF.5. A molecule according to claim 1 , wherein Ris selected from the group consisting of H claim 1 , F claim 1 , Cl claim 1 , Br claim 1 , CH claim 1 , and CF.6. A molecule according to claim 1 , wherein R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , and Rare H.7. A molecule according to claim 1 , wherein Ris Cl.8. A molecule according to claim 1 , wherein Ris Cl.9. A molecule according to claim 1 , wherein Ris selected from the group consisting of H claim 1 , Cl claim 1 , and CF.10. A molecule according to claim 1 , wherein Ris selected from the group consisting of H and CH.11. A molecule according to claim 1 , wherein Ris selected from the group consisting of cyclopropyl claim 1 , cyclobutyl claim 1 , cyclopentyl claim 1 , cyclohexyl claim 1 , azetidinyl claim 1 , morpholinyl claim 1 , oxetanyl claim 1 , pyranyl claim 1 , tetrahydrothiophenyl claim 1 , thietanyl claim 1 , thietanyl-oxide claim 1 , and thietanyl-dioxide claim 1 ,{'sub': 3', '3', '3, 'wherein each cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, ...

Molecules having pesticidal utility, and intermediates, compositions, and processes, related thereto

This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula (“Formula One”).

PESTICIDAL COMPOSITIONS AND PROCESSES RELATED THERETO

This document discloses molecules having the following formula (“Formula One”):

Molecules having pesticidal utility, and intermediates, compositions, and processes, related thereto

This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula (“Formula One”). 2. A molecule according to claim 1 , wherein Ris selected from the group consisting of H and Cl.3. A molecule according to claim 1 , wherein Ris selected from the group consisting of H claim 1 , Cl claim 1 , Br claim 1 , CH claim 1 , and CF.4. A molecule according to claim 1 , wherein Ris selected from the group consisting of H claim 1 , F claim 1 , Cl claim 1 , CH claim 1 , CF claim 1 , and OCF.5. A molecule according to claim 1 , wherein Ris selected from the group consisting of H claim 1 , F claim 1 , Cl claim 1 , Br claim 1 , CH claim 1 , and CF.6. A molecule according to claim 1 , wherein R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , and Rare H.7. A molecule according to claim 1 , wherein Ris Cl.8. A molecule according to claim 1 , wherein Ris Cl.9. A molecule according to claim 1 , wherein Ris selected from the group consisting of H claim 1 , Cl claim 1 , and CF.10. A molecule according to claim 1 , wherein Ris selected from the group consisting of H and CH.11. A molecule according to claim 1 , wherein Ris selected from the group consisting of cyclopropyl claim 1 , cyclobutyl claim 1 , cyclopentyl claim 1 , cyclohexyl claim 1 , azetidinyl claim 1 , morpholinyl claim 1 , oxetanyl claim 1 , pyranyl claim 1 , tetrahydrothiophenyl claim 1 , thietanyl claim 1 , thietanyl-oxide claim 1 , and thietanyl-dioxide claim 1 ,{'sub': 3', '3', '3, 'wherein each cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, ...

Molecules having pesticidal utility, and intermediates, compositions, and processes, related thereto

This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula (“Formula One”). 2. A molecule according to claim 1 , wherein Ris selected from the group consisting of H claim 1 , F claim 1 , and Cl.3. A molecule according to claim 1 , wherein Ris selected from the group consisting of H claim 1 , F claim 1 , and Cl.4. A molecule according to claim 1 , wherein Ris F or Cl.5. A molecule according to claim 1 , wherein R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , and Rare each independently H.6. A molecule according to claim 1 , wherein Ris selected from the group consisting of Cl and Br.7. A molecule according to claim 1 , wherein Ris selected from the group consisting of Cl and Br.8. A molecule according to claim 1 , wherein Ris selected from the group consisting of H claim 1 , Cl claim 1 , and CF.9. A molecule according to claim 1 , wherein Ris selected from the group consisting of H and CH.10. A molecule according to claim 1 , wherein Ris selected from the group consisting of CH claim 1 , CHCH claim 1 , CHCHCH claim 1 , CHCHCHCH claim 1 , CHCHCHOCHCH claim 1 , CH claim 1 , CHCH claim 1 , CHCHCH claim 1 , CHCHCHCH claim 1 , CHCHCHCHCH claim 1 , CHCHCHCHCHCH claim 1 , CHCH(CH) claim 1 , CHcyclopropyl claim 1 , CHCHcyclopropyl claim 1 , CHcyclobutyl claim 1 , CHphenyl claim 1 , CHCHphenyl claim 1 , CHC═CH claim 1 , CHC═CH claim 1 , CHCF claim 1 , CHCHF claim 1 , CHCHCF claim 1 , CHCFCF claim 1 , CHCHCHCF claim 1 , CHCHCFCF claim 1 , CHCFCFCF claim 1 , CHCHCHCHF claim 1 , CHCHSCH ...

PROCESSES FOR THE PREPARATION OF 4-ALKOXY-3-(ACYL OR ALKYL)OXYPICOLINAMDES

A fungicidal 4-methoxy-3-acetyloxypicolinamide may be conveniently prepared in processes that include the coupling together of 4-methoxy-3-acetyloxypicolinic acid or 4-methoxy-3-hydroxypicolinic acid with a key 2-aminopropanoate ester derived from a 1,1-bis(4-fluorophenyl)propane-1,2-diol. 2. The process of wherein the acylating agent is an alkyl chloroformate of the Formula ClCOR claim 1 , wherein R is a C-Calkyl or benzyl claim 1 , or an acid chloride of the Formula RCOCl claim 1 , wherein R is a C-Calkyl.3. The process of wherein the chlorinating agent is oxalyl chloride or thionyl chloride.4. The process of wherein the base may be selected from the group including triethylamine (TEA) claim 1 , diisopropylethylamine (DIPEA) claim 1 , pyridine claim 1 , potassium carbonate claim 1 , and mixtures thereof.5. The process of wherein the first mixture further comprises a solvent selected from the group including dichloromethane (DCM) claim 1 , 1 claim 1 ,2-dichloroethane (DCE) claim 1 , isopropyl acetate claim 1 , tetrahydrofuran (THF) claim 1 , 2-MeTHF claim 1 , acetonitrile (ACN) claim 1 , and mixtures thereof.7. The process of wherein the acylating agent is an alkyl chloroformate of the Formula ClCOR claim 6 , wherein R is a C-Calkyl or a benzyl.8. The process of wherein the first mixture further comprises a solvent selected from the group including dichloromethane (DCM) claim 6 , 1 claim 6 ,2-dichloroethane (DCE) claim 6 , acetonitrile (ACN) claim 6 , isopropyl acetate claim 6 , THF claim 6 , 2-MeTHF claim 6 , and mixtures thereof.9. The process of wherein the first base may be selected from the group including triethylamine (TEA) claim 6 , diisopropylethylamine (DIPEA) claim 6 , pyridine and potassium carbonate.10. The process of wherein about 3 equivalents of the first base and about 2 equivalents of the acylating agent are used.11. The process of wherein the alkali metal base may be selected from the group including LiOH claim 6 , NaOH claim 6 , KOH claim 6 , ...

MOLECULES HAVING CERTAIN PESTICIDAL UTILITIES, AND INTERMEDIATES, COMPOSITIONS, AND PROCESSES RELATED THERETO

This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Nematoda, Arthropoda, and/or Mollusca, processes to produce such molecules and intermediates used in such processes, compositions containing such molecules, and processes of using such molecules against such pests. These molecules may be used, for example, as nematicides, acaricides, insecticides, miticides, and/or molluscicides. This document discloses molecules having the following formula (“Formula One”). 2. A molecule according to wherein R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , R claim 1 , and Rare H.3. A molecule according to wherein Ris CF claim 1 , OCF claim 1 , or OCFCF.4. A molecule according to wherein L is a bond or —CH—.5. A molecule according to wherein Q is O.6. A molecule according to wherein Ris H claim 1 , CH claim 1 , CH(CH) claim 1 , OCH claim 1 , CHO(4-pyranyl) claim 1 , phenyl claim 1 , CH(phenyl) claim 1 , O(phenyl) claim 1 , or NH(phenyl) claim 1 , wherein each phenyl is optionally substituted with one or more substituents independently selected from F claim 1 , Cl claim 1 , CH claim 1 , OCH claim 1 , and OCHCH.7. A molecule according to wherein Ris H claim 1 , CH(CH) claim 1 , CHOCHCFCFH claim 1 , OCH claim 1 , OCHCH(CH) claim 1 , or O(phenyl).8. A molecule according to wherein Ris H claim 1 , CH claim 1 , OCH claim 1 , phenyl claim 1 , or O(phenyl).9. A molecule according to wherein Ris H or CH.10. A molecule according to wherein Rand Rtogether are —OCFO—.11. A molecule according to wherein Rand Rtogether are —OCFO—.12. A molecule according to wherein:{'sup': 1', '2', '3', '4', '5', '6', '7', '9', '10, 'sub': 1', '4', '1', '4, '(A) R, R, R, R, R, R, R, R, and Rare each independently selected from H, (C-C)haloalkyl, and (C-C)haloalkoxy;'}{'sup': '8', '(B) Ris H;'}{'sub': 1', '4, '(C) L is a bond or a (C-C)alkyl;'}{'sup': '11', '(D) Ris H;'}{'sup': '12', 'sub': 1', '4', '1', '4', ...

PROCESSES FOR THE PREPARATION OF PESTICIDAL COMPOUNDS

The present application provides processes for making pesticidal compounds and compounds useful both as pesticides and in the making of pesticidal compounds. 23.-. (canceled)57.-. (canceled)931.-. (canceled) This Application claims the benefit of the following U.S. Provisional Patent Applications: Ser. No. 62/042,554 filed Aug. 27, 2014; and Ser. No. 61/892,129 filed Oct. 17, 2013, the entire disclosures of which are hereby expressly incorporated by reference into this Application.This application relates to efficient and economical synthetic chemical processes for the preparation of pesticidal thioethers and pesticidal sulfoxides. Further, the present application relates to certain novel compounds necessary for their synthesis. It would be advantageous to produce pesticidal thioether and pesticidal sulfoxides efficiently and in high yield from commercially available starting materials.The following definitions apply to the terms as used throughout this specification, unless otherwise limited in specific instances.As used herein, the term “alkyl” denotes branched or unbranched hydrocarbon chains.As used herein, the term “alkynyl” denotes branched or unbranched hydrocarbon chains having at least one C≡C.Unless otherwise indicated, the term “cycloalkyl” as employed herein alone is a saturated cyclic hydrocarbon group, such as cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl.The term “thio” as used herein as part of another group refers to a sulfur atom serving as a linker between two groups.The term “halogen” or “halo” as used herein alone or as part of another group refers to chlorine, bromine, fluorine, and iodine.The pesticidal thioethers of formula 3cand the pesticidal sulfoxides of formula 3dwherein,In step a of Scheme 1, 3-hydrazinopyridine dihydrochloride is reacted with methyl acrylate in the presence of a base such as sodium methoxide or sodium ethoxide to yield 1-(pyridin-3-yl)pyrazolidin-3-one followed by chlorination of 1-(pyridine-3-yl)pyrazolidin-3-one ...

PESTICIDAL COMPOSITIONS AND PROCESSES RELATED THERETO

This document discloses molecules having the following formula (“Formula One”): 2. A composition according to wherein said molecule said A is A1.3. A composition according to wherein said molecule said A is A2.4. A composition according to wherein said molecule said R1 is H.5. A composition according to wherein said molecule said R2 is H.6. A composition according to wherein said molecule said R3 is selected from H claim 1 , or substituted or unsubstituted C-Calkyl.7. A composition according to wherein said molecule said R3 is selected from H or CH.8. A composition according to wherein said molecule when said A is A1 then A1 is A11.9. A composition according to wherein said molecule when said A is A1 claim 1 , and A1 is A11 claim 1 , then R4 is selected from H claim 1 , or substituted or unsubstituted C-Calkyl claim 1 , or substituted or unsubstituted C-Caryl.10. A composition according to wherein said molecule when said A is A1 claim 1 , and A1 is A11 then R4 is selected from CH claim 1 , CH(CH) claim 1 , or phenyl.11. A composition according to wherein said molecule when said A is A1 claim 1 , and A1 is A12 claim 1 , then R4 is CH.12. A composition according to wherein said molecule when said A is A2 then R4 is selected from H claim 1 , substituted or unsubstituted C-Calkyl claim 1 , substituted or unsubstituted C-Calkenyl claim 1 , substituted or unsubstituted C-Ccycloalkyl claim 1 , substituted or unsubstituted C-Caryl claim 1 , wherein each said R4 claim 1 , which is substituted claim 1 , has one or more substituents selected from F claim 1 , Cl claim 1 , Br claim 1 , or I.13. A composition according to wherein said molecule when said A is A2 then R4 is H or C-Calkyl.14. A composition according to wherein said molecule when said A is A2 then R4 is H claim 1 , CH claim 1 , CHCH claim 1 , CH═CH claim 1 , cyclopropyl claim 1 , CHCl claim 1 , CF claim 1 , or phenyl.15. A composition according to wherein said molecule when said A is A2 then R4 is Br or Cl.16. A ...

PESTICIDAL COMPOSITIONS AND PROCESSES RELATED THERETO

This document discloses molecules having the following formula (“Formula One”): 2. A composition according to further comprising:(a) one or more compounds having acaricidal, algicidal, avicidal, bactericidal, fungicidal, herbicidal, insecticidal, molluscicidal, nematicidal, rodenticidal, or virucidal properties; or(b) one or more compounds that are antifeedants, bird repellents, chemosterilants, herbicide safeners, insect attractants, insect repellents, mammal repellents, mating disrupters, plant activators, plant growth regulators, or synergists; or(c) both (a) and (b).3. A composition according to wherein further comprising one or more compounds selected from: (3-ethoxypropyl)mercury bromide claim 1 , 1 claim 1 ,2-dichloropropane claim 1 , 1 claim 1 ,3-dichloropropene claim 1 , 1-methylcyclopropene claim 1 , 1-naphthol claim 1 , 2-(octylthio)ethanol claim 1 , 2 claim 1 ,3 claim 1 ,5-tri-iodobenzoic acid claim 1 , 2 claim 1 ,3 claim 1 ,6-TBA claim 1 , 2 claim 1 ,3 claim 1 ,6-TBA-dimethylammonium claim 1 , 2 claim 1 ,3 claim 1 ,6-TBA-lithium claim 1 , 2 claim 1 ,3 claim 1 ,6-TBA-potassium claim 1 , 2 claim 1 ,3 claim 1 ,6-TBA-sodium claim 1 , 2 claim 1 ,4 claim 1 ,5-T claim 1 , 2 claim 1 ,4 claim 1 ,5-T-2-butoxypropyl claim 1 , 2 claim 1 ,4 claim 1 ,5-T-2-ethylhexyl claim 1 , 2 claim 1 ,4 claim 1 ,5-T-3-butoxypropyl claim 1 , 2 claim 1 ,4 claim 1 ,5-TB claim 1 , 2 claim 1 ,4 claim 1 ,5-T-butometyl claim 1 , 2 claim 1 ,4 claim 1 ,5-T-butotyl claim 1 , 2 claim 1 ,4 claim 1 ,5-T-butyl claim 1 , 2 claim 1 ,4 claim 1 ,5-T-isobutyl claim 1 , 2 claim 1 ,4 claim 1 ,5-T-isoctyl claim 1 , 2 claim 1 ,4 claim 1 ,5-T-isopropyl claim 1 , 2 claim 1 ,4 claim 1 ,5-T-methyl claim 1 , 2 claim 1 ,4 claim 1 ,5-T-pentyl claim 1 , 2 claim 1 ,4 claim 1 ,5-T-sodium claim 1 , 2 claim 1 ,4 claim 1 ,5-T-triethylammonium claim 1 , 2 claim 1 ,4 claim 1 ,5-T-trolamine claim 1 , 2 claim 1 ,4-D claim 1 , 2 claim 1 ,4-D-2-butoxypropyl claim 1 , 2 claim 1 ,4-D-2-ethylhexyl claim 1 , 2 claim 1 ,4-D-3- ...

Molecules having pesticidal utility, and intermediates, compositions, and processes, related thereto

This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula (“Formula One”). 2. A process to control a pest claim 1 , said process comprising claim 1 , applying to a locus claim 1 , a pesticidally effective amount of a molecule according to . This Application is a continuation of, and claims the benefit of, U.S. nonprovisional application Ser. No. 15/679,415, which was filed Aug. 17, 2017, and which is now allowed; Ser. No. 15/679,415 is a divisional of, and claims the benefit of, U.S. nonprovisional application Ser. No. 15/092,650, which was filed Apr. 7, 2016, and is now U.S. Pat. No. 9,781,935; Ser. No. 15/092,650 claims the benefit of, and priority from, U.S. provisional application Ser. Nos. 62/148,809; 62/148814; 62/148818; 62/148824; 62/148830; and 62/148,837; all of which were filed on Apr. 17, 2015. The entire contents of all of the above-identified applications are hereby incorporated by reference into this Application.This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides.“Many of the most dangerous human diseases are transmitted by insect vectors” (Rivero et al.). “Historically, malaria, dengue, yellow ...

PROCESSES FOR THE PREPARATION OF PESTICIDAL COMPOUNDS

The present application provides processes for making pesticidal compounds and compounds useful both as pesticides and in the making of pesticidal compounds. This application claims the benefit of the following U.S. Provisional Patent Application Ser. No. 62/042,554 filed Aug. 27, 2014; and Ser. No. 61/892,129 filed Oct. 17, 2013, the entire disclosures of which are hereby expressly incorporated by reference into this application.This application relates to efficient and economical synthetic chemical processes for the preparation of pesticidal thioethers and pesticidal sulfoxides. Further, the present application relates to certain novel compounds necessary for their synthesis. It would be advantageous to produce pesticidal thioether and pesticidal sulfoxides efficiently and in high yield from commercially available starting materials.The following definitions apply to the terms as used throughout this specification, unless otherwise limited in specific instances.As used herein, the term “alkyl” denotes branched or unbranched hydrocarbon chains.As used herein, the term “alkynyl” denotes branched or unbranched hydrocarbon chains having at least one C≡C.Unless otherwise indicated, the term “cycloalkyl” as employed herein alone is a saturated cyclic hydrocarbon group, such as cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl.The term “thio” as used herein as part of another group refers to a sulfur atom serving as a linker between two groups.The term “halogen” or “halo” as used herein alone or as part of another group refers to chlorine, bromine, fluorine, and iodine.The pesticidal thioethers of formula 3cand the pesticidal sulfoxides of formula 3dwherein,In step a of Scheme 1, 3-hydrazinopyridine dihydrochloride is reacted with methyl acrylate in the presence of a base such as sodium methoxide or sodium ethoxide to yield 1-(pyridin-3-yl)pyrazolidin-3-one followed by chlorination of 1-(pyridine-3-yl)pyrazolidin-3-one with phosphoryl chloride (POCl) in a two-step process ...

DICAMBA COMPOSITIONS WITH REDUCED SPRAY DRIFT POTENTIAL

Methods and compositions to reduce spray drift during application and/or volatility after application can be reduced by incorporating certain tertiary amine or tertiary amine oxide surfactants into an aqueous herbicidal spray mixture containing dicamba. The use of the choline salt of dicamba and the presence of 3,6-dichlorosalicylic acid (DCSA) or a salicylic acid derivative can further reduce drift and volatility. In some embodiments, the composition can contain one or more additional pesticides, such as glyphosate, glufosinate, or mixtures thereof. The concentration of 3,6-dichlorosalicylic acid or the salicylic acid derivative is typically greater than about 25 ppm by weight of the spray mixture. 2. The method of claim 1 , wherein the concentration of 3 claim 1 ,6-dichlorosalicylic acid of the salicylic acid derivative is at greater than about 50 ppm by weight of the spray mixture.3. The method of claim 1 , wherein the dicamba is a water-soluble salt of dicamba.4. The method of claim 3 , wherein the water-soluble salt of dicamba is selected from the group consisting of dicamba choline claim 3 , dicamba diglycoamine (DGA) claim 3 , dicamba N claim 3 ,N-Bis[aminopropyl] methylamine (BAPMA) claim 3 , dicamba potassium claim 3 , or mixtures thereof.5. The method of claim 1 , further comprising one or more additional pesticides.6. The method of claim 5 , wherein the one or more additional pesticides is selected from the group consisting of glyphosate claim 5 , glufosinate claim 5 , salts thereof claim 5 , or mixtures thereof.7. The method of claim 6 , wherein the one or more additional pesticides is glyphosate or a salt thereof selected from the group consisting of glyphosate dimethyl ammonium claim 6 , glyphosate isopropyl ammonium claim 6 , glyphosate potassium claim 6 , glyphosate choline claim 6 , glyphosate monoethanol amine (MEA) claim 6 , glyphosate ammonium claim 6 , or mixtures thereof.8. The method of claim 6 , wherein the ratio of glyphosate to dicamba is ...

PESTICIDAL COMPOSITIONS AND PROCESSES RELATED THERETO

This document discloses molecules having the following formula (“Formula One”): 2. A composition according to wherein said molecule said A is A1.3. A composition according to wherein said molecule said A is A2.4. A composition according to wherein said molecule said R1 is H.5. A composition according to wherein said molecule said R2 is H.6. A composition according to wherein said molecule said R3 is selected from H claim 1 , or substituted or unsubstituted C-Calkyl.7. A composition according to wherein said molecule said R3 is selected from H or CH.8. A composition according to wherein said molecule when said A is A1 then A1 is A11.9. A composition according to wherein said molecule when said A is A1 claim 1 , and A1 is A11 claim 1 , then R4 is selected from H claim 1 , or substituted or unsubstituted C-Calkyl claim 1 , or substituted or unsubstituted C-Caryl.10. A composition according to wherein said molecule when said A is A1 claim 1 , and A1 is A11 then R4 is selected from CH claim 1 , CH(CH) claim 1 , or phenyl.11. A composition according to wherein said molecule when said A is A1 claim 1 , and A1 is A12 claim 1 , then R4 is CH.12. A composition according to wherein said molecule when said A is A2 then R4 is selected from H claim 1 , substituted or unsubstituted C-Calkyl claim 1 , substituted or unsubstituted C-Calkenyl claim 1 , substituted or unsubstituted C-Ccycloalkyl claim 1 , substituted or unsubstituted C-Caryl claim 1 , wherein each said R4 claim 1 , which is substituted claim 1 , has one or more substituents selected from F claim 1 , Cl claim 1 , Br claim 1 , or I.13. A composition according to wherein said molecule when said A is A2 then R4 is H or C-Calkyl.14. A composition according to wherein said molecule when said A is A2 then R4 is H claim 1 , CH claim 1 , CHCH claim 1 , CH═CH claim 1 , cyclopropyl claim 1 , CHCl claim 1 , CF claim 1 , or phenyl.15. A composition according to wherein said molecule when said A is A2 then R4 is Br or Cl.16. A ...

Pesticidal compositions and processes related thereto

This document discloses molecules having the following formula (“Formula One”): and processes related thereto.

MOLECULES HAVING PESTICIDAL UTILITY, AND INTERMEDIATES, COMPOSITIONS, AND PROCESSES, RELATED THERETO

This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula (“Formula One”). 2. A molecule according to wherein the carboxamido claim 1 , and the phenyl claim 1 , which are bonded to the cyclopropane claim 1 , are in the R claim 1 ,R configuration.3. A molecule according to wherein Xis a substituted or unsubstituted heterocyclyl claim 1 , wherein said heterocyclyl is selected from the group consisting of indolyl claim 1 , oxazolyl claim 1 , pyrazinyl claim 1 , pyrazolyl claim 1 , pyridazinyl claim 1 , pyridyl claim 1 , pyrimidinyl claim 1 , tetrazolyl claim 1 , thiadiazolyl claim 1 , thiazolyl claim 1 , thienyl claim 1 , triazinyl claim 1 , [1 claim 1 ,2 claim 1 ,4]triazolo[1 claim 1 ,5-c]pyrimidinyl claim 1 , triazolyl claim 1 , 2 claim 1 ,3-dihydrophthalazine-1 claim 1 ,4-dionyl claim 1 , indolinyl claim 1 , and pyrimidine-2 claim 1 ,4(1H claim 1 ,3H)-dionyl claim 1 ,{'sub': 2', '2', '1', '6', '1', '6', '1', '6', '1', '6', '2', '6', '3', '6', '3', '6, 'wherein substituents are selected from the group consisting of F, Cl, Br, I, H, CN, NH, NO, (C-C)alkoxy, (C-C)alkyl, (C-C)haloalkoxy, (C-C)haloalkyl, (C-C)haloalkenyl, (C-C)halocycloalkenyl, and (C-C)halocycloalkyl.'} This application is a continuation of, and claims the benefit of, U.S. nonprovisional application Ser. No. 16/203,690, which was filed Nov. 29, 2018, now allowed; Ser. No. 16/203,690, is a continuation of nonprovisional application Ser. No. 15/679,415, which was filed Aug. 17, 2017, and is now U.S. Pat. No. 10,219,516; Ser. No. 15/679,415 is a ...

PROCESSES FOR THE PREPARATION OF PESTICIDAL COMPOUNDS

The present application provides processes for making pesticidal compounds and compounds useful both as pesticides and in the making of pesticidal compounds. 2. (canceled)1719.-. (canceled)2228.-. (canceled)31. (canceled) This application claims the benefit of the following U.S. Provisional patent applications: Ser. No. 62/042,554 filed Aug. 27, 2014; and Ser. No. 61/892,129 filed Oct. 17, 2013, the entire disclosures of which are hereby expressly incorporated by reference into this application.This application relates to efficient and economical synthetic chemical processes for the preparation of pesticidal thioethers and pesticidal sulfoxides. Further, the present application relates to certain novel compounds necessary for their synthesis. It would be advantageous to produce pesticidal thioether and pesticidal sulfoxides efficiently and in high yield from commercially available starting materials.The following definitions apply to the terms as used throughout this specification, unless otherwise limited in specific instances.As used herein, the term “alkyl” denotes branched or unbranched hydrocarbon chains.As used herein, the term “alkynyl” denotes branched or unbranched hydrocarbon chains having at least one C≡C.Unless otherwise indicated, the term “cycloalkyl” as employed herein alone is a saturated cyclic hydrocarbon group, such as cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl.The term “thio” as used herein as part of another group refers to a sulfur atom serving as a linker between two groups.The term “halogen” or “halo” as used herein alone or as part of another group refers to chlorine, bromine, fluorine, and iodine.The pesticidal thioethers of formula 3cand the pesticidal sulfoxides of formula 3dwherein,In step a of Scheme 1, 3-hydrazinopyridine dihydrochloride is reacted with methyl acrylate in the presence of a base such as sodium methoxide or sodium ethoxide to yield 1-(pyridin-3-yl)pyrazolidin-3-one followed by chlorination of 1-(pyridine-3-yl) ...

PESTICIDAL COMPOSITIONS AND RELATED METHODS

This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula I, or any agriculturally acceptable salt thereof, wherein R, R, R, R, R, R, R, R, R, X, Q, and n are as described herein.

PESTICIDAL COMPOSITIONS AND PROCESSES RELATED THERETO

This document discloses molecules having the following formula (“Formula One”): 75. A composition according to any one of , , or , further comprising:(a) one or more compounds having acaricidal, algicidal, avicidal, bactericidal, fungicidal, herbicidal, insecticidal, molluscicidal, nematicidal, rodenticidal, or virucidal properties; or(b) one or more compounds that are antifeedants, bird repellents, chemosterilants, herbicide safeners, insect attractants, insect repellents, mammal repellents, mating disrupters, plant activators, plant growth regulators, or synergists; or(c) both (a) and (b).8. A composition according to further comprising a seed.95. A process comprising applying a composition according to one of claim 7 , claim 7 , or . This application is a continuation of, and claims the benefit of, U.S. patent application Ser. No. 13/788,736, which was filed on Mar. 7, 2013, and which claims priority from, and benefit of, U.S. provisional application Ser. No. 61/639,274, which was filed on Apr. 27, 2012. The entire content of these applications are hereby incorporated by reference into this application.This disclosure is related to the field of processes to produce molecules that are useful as pesticides (e.g., acaricides, insecticides, molluscicides, and nematicides), such molecules, and processes of using such molecules to control pests.Pests cause millions of human deaths around the world each year. Furthermore, there are more than ten thousand species of pests that cause losses in agriculture. The world-wide agricultural losses amount to billions of U.S. dollars each year.Termites cause damage to all kinds of private and public structures. The world-wide termite damage losses amount to billions of U.S. dollars each year.Stored food pests eat and adulterate stored food. The world-wide stored food losses amount to billions of U.S. dollars each year, but more importantly, deprive people of needed food.There is an acute need for new pesticides. Certain pests are ...

PROCESSES FOR THE PREPARATION OF 4-ALKOXY-3-(ACYL OR ALKYL)OXYPICOLINAMDES

A fungicidal 4-methoxy-3-acetyloxypicolinamide may be conveniently prepared in processes that include the coupling together of 4-methoxy-3-acetyloxypicolinic acid or 4-methoxy-3-hydroxypicolinic acid with a key 2-aminopropanoate ester derived from a 1,1-bis(4-fluorophenyl)propane-1,2-diol. 2. The process of wherein the acylating agent is an alkyl chloroformate of the Formula ClCOR claim 1 , wherein R is a C-Calkyl or benzyl claim 1 , or an acid chloride of the Formula RCOCl claim 1 , wherein R is a C-Calkyl.3. The process of wherein the chlorinating agent is oxalyl chloride or thionyl chloride.4. The process of wherein the base may be selected from the group including triethylamine (TEA) claim 1 , diisopropylethylamine (DIPEA) claim 1 , pyridine claim 1 , potassium carbonate claim 1 , and mixtures thereof.5. The process of wherein the first mixture further comprises a solvent selected from the group including dichloromethane (DCM) claim 1 , 1 claim 1 ,2-dichloroethane (DCE) claim 1 , isopropyl acetate claim 1 , tetrahydrofuran (THF) claim 1 , 2-MeTHF claim 1 , acetonitrile (ACN) claim 1 , and mixtures thereof.7. The process of wherein the acylating agent is an alkyl chloroformate of the Formula ClCOR claim 6 , wherein R is a C-Calkyl or a benzyl.8. The process of wherein the first mixture further comprises a solvent selected from the group including dichloromethane (DCM) claim 6 , 1 claim 6 ,2-dichloroethane (DCE) claim 6 , acetonitrile (ACN) claim 6 , isopropyl acetate claim 6 , THF claim 6 , 2-MeTHF claim 6 , and mixtures thereof.9. The process of wherein the first base may be selected from the group including triethylamine (TEA) claim 6 , diisopropylethylamine (DIPEA) claim 6 , pyridine and potassium carbonate.10. The process of wherein about 3 equivalents of the first base and about 2 equivalents of the acylating agent are used.11. The process of wherein the alkali metal base may be selected from the group including LiOH claim 6 , NaOH claim 6 , KOH claim 6 , ...

Molecules having pesticidal utility, and intermediates, compositions, and processes, related thereto

This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula (“Formula One”). 2. A process to control a pest claim 1 , said process comprising claim 1 , applying to a locus claim 1 , a pesticidally effective amount of a molecule according to . This Application is a divisional of, and claims the benefit of, U.S. nonprovisional application Ser. No. 15/092,650, which was filed Apr. 7, 2016, and is now allowed, and which claims the benefit of, and priority from, U.S. provisional applications Ser. Nos. 62/148,830; 62/148,837; 62/148,809; 62/148,814; 62/148,818; and 62/148,824; all of which were filed on Apr. 17, 2015. The entire contents of all of the above-identified applications are hereby incorporated by reference into this Application.This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides.“Many of the most dangerous human diseases are transmitted by insect vectors” (Rivero et al.). “Historically, malaria, dengue, yellow fever, plague, filariasis, louse-borne typhus, trypanomiasis, leishmaniasis, and other vector borne diseases were responsible for more human disease and death in the 17through the early 20centuries ...

Processes for the preparation of pesticidal compounds

This application relates to efficient and economical synthetic chemical processes for the preparation of pesticidal thioethers and pesticidal sulfoxides. Further, the present application relates to certain novel compounds necessary for their synthesis. It would be advantageous to produce pesticidal thioether and pesticidal sulfoxides efficiently and in high yield from commercially available starting materials.

Processes for the preparation of pesticidal compounds

MOLECULES WITH PESTICIDE UTILITY, THEIR INTERMEDIATES, COMPOSITIONS, AND PROCESS TO FIGHT PEST

a presente invenção refere-se ao campo de moléculas que têm utilidade pesticida contra pragas nos filos arthropoda, mollusca e nematoda, processos para produzir essas moléculas, intermediários usados nesses processos, composições pesticidas contendo essas moléculas, e processos de uso dessas composições pesticidas contra tais pragas. essas composições pesticidas podem ser usadas, por exemplo, como acaricidas, inseticidas, miticidas, moluscicidas e nematicidas. este documento divulga moléculas com a seguinte fórmula ("fórmula um"). the present invention relates to the field of molecules that have pesticidal utility against pests in the arthropoda, mollusca and nematoda phyla, processes for producing these molecules, intermediates used in these processes, pesticide compositions containing these molecules, and processes for using such pesticide compositions against such pests. such pesticidal compositions can be used, for example, as acaricides, insecticides, miticides, molluscicides and nematicides. this document discloses molecules with the following formula ("formula one").

Molecules having pesticidal utility, and intermediates, compositions, and processes, related thereto

of this disclosure This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, 5 and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula ("Formula One"). R12 R7 R8 R11 R13Ris RQ R6R R4 N N R16 R9 I Rio R14 Q2 R 3 R1 R2 10 Formula One

Pesticidal compositions and related methods

Molecules that have pesticide utility, and intermediaries, compositions and processes, related to them

Esta descripción se refiere al campo de moléculas que tienen utilidad plaguicida contra plagas en los filos Arthropoda, Mollusca y Nematoda, procesos para producir tales moléculas, intermediarios usados en tales procesos, composiciones plaguicidas que contienen tales moléculas y procesos para usar tales composiciones plaguicidas contra tales plagas. Estas composiciones plaguicidas pueden usarse, por ejemplo, como acaricidas, insecticidas, aracnicidas, molusquicidas y nematicidas. Este documento describe moléculas que tienen la siguiente fórmula (“Fórmula Uno”). Fórmula Uno This description refers to the field of molecules that have pesticide utility against pests in the Arthropoda, Mollusca and Nematoda edges, processes to produce such molecules, intermediates used in such processes, pesticide compositions containing such molecules and processes to use such pesticidal compositions against such pests These pesticidal compositions can be used, for example, as acaricides, insecticides, arachnicides, molluscicides and nematicides. This document describes molecules that have the following formula ("Formula One"). Formula One

Pesticidal compositions and related methods

Processes for the preparation of 4-alkoxy - (acyl or aquyl) oxy-picolinamide.

PROCESOS PARA LA PREPARACIÓN DE 4-ALCOXI-3-(ACIL O ALQUIL)-OXIPICOLINAMIDAS. PROCESSES FOR THE PREPARATION OF 4-ALCOXI-3- (ACIL OR ALQUIL) -OXIPICOLINAMIDAS.

MOLECULES PRESENTING PESTICIDE UTILITY, INTERMEDIATES, COMPOSITION, AND PROCESS TO CONTROL A PEST

MOLÉCULAS TENDO UTILIDADE PESTICIDA, E INTERMEDIÁRIOS, COMPOSIÇÕES E PROCESSOS RELACIONADOS ÀS MESMAS. A presente invenção refere-se ao campo de moléculas com utilidade pesticida contra pragas dos Filos Arthropoda, Mollusca e Nematoda, processos para produzir tais moléculas, intermediários usados em tais processos, composições pesticidas contendo tais moléculas, e processos de uso de tais composições pesticidas contra tais pragas. Essas composições pesticidas podem ser usadas, por exemplo, como acaricidas, inseticidas, miticidas, moluscicidas e nematicidas. Este documento divulga moléculas com a seguinte fórmula ("Fórmula Um").

PESTICIDE COMPOSITION AND ITS APPLICATION PROCESS

composições pesticidas e métodos relacionados. esta descrição refere-se ao campo de moléculas tendo utilidade pesticida contra pestes em phyla arthropoda, mollusca, e nematoda, processos para produzir tais moléculas, intermediários usados em tais processos, composições pesticidas contendo tais moléculas, e processos de uso de tais composições pesticidas contra tais pestes. estas composições pesticidas podem ser usadas, por exemplo, como acaricidas, inseticidas, miticidas, moluscicidas, e nematicidas. este documento descreve moléculas tendo a seguinte fórmula i, ou qualquer sal agricolamente aceitável das mesmas, i em que r1, r2, r3, r4, r5, r6, r7, r8, r9, x1, q, e n são como descritos aqui. pesticide compositions and related methods. this description relates to the field of molecules having pesticidal utility against pests in phyla arthropoda, mollusca, and nematoda, processes for producing such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes for using such pesticidal compositions against such pests. these pesticidal compositions can be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. this document describes molecules having the following formula i, or any agriculturally acceptable salt thereof, wherein r1, r2, r3, r4, r5, r6, r7, r8, r9, x1, q, and n are as described herein.

insecticidal compositions

MOLÉCULAS TENDO CERTAS UTILIDADES PESTICIDAS, E INTERMEDIÁRIOS, COMPOSIÇÕES, E PROCESSOS RELACIONADOS À ELAS. Esta invenção refere- se ao campo de moléculas tendo utilidade pesticide contra pestes em Phila Nematoda, Arthropoda, e/ou Mollusca, processos para produzir tais moléculas e intermediários usados em tais processos, composições contendo tais moléculas, e processos de uso de tais moléculas contra tais pestes. Estas moléculas podem ser usadas, por exemplo, como nematicidas, acaricidas, inseticidas, miticidas, e/ou moluscicidas. Este documento descreve moléculas tendo a seguinte fórmula ("Fórmula Um"). MOLECULES HAVING CERTAIN PESTICIDE UTILITIES, AND INTERMEDIATES, COMPOSITIONS, AND RELATED PROCESSES. This invention relates to the field of molecules having pesticide utility against pests in Phila Nematoda, Arthropoda, and/or Mollusca, processes for producing such molecules and intermediates used in such processes, compositions containing such molecules, and processes for using such molecules against such pests. These molecules can be used, for example, as nematicides, acaricides, insecticides, miticides, and/or molluscicides. This document describes molecules having the following formula ("Formula One").

MOLECULES THAT HAVE PESTICIDE PROFITS, INTERMEDIARIES, COMPOSITIONS AND PROCESSES RELATED TO SUCH MOLECULES

La presente descripción se refiere al campo de moléculas que poseen utilidad plaguicida contra plagas de artrópodos Fila, moluscos y nemátodos, procesos para producir tales moléculas, intermediarios utilizados en tales procesos,composiciones plaguicidas que contienen dichas moléculas, y procesos de uso de tales composiciones plaguicidas contra las plagas. Estas composiciones plaguicidas se pueden usar, por ejemplo, como acaricidas, insecticidas, miticidas,moluscocidas, y nematicidas. Este documento describe moléculas que poseen la siguiente fórmula (“Fórmula Uno”).

? Pesticide compositions and related methods ?.

La presente divulgación se refiere al campo de las moléculas de utilidad plaguicida contra plagas en Fila Artrópodos, Moluscos y Nemátodos, procesos para su producción, intermediarios utilizados en tales procesos, composiciones de las mismas, y p rocesos para utilizarlas contra las plagas mencio nadas. Estas composiciones se pueden usar como ac aricidas, insecticidas, miticidas, moluscocidas y nematicidas. Se describen moléculas que poseen la siguiente fórmula I, o cualquiera de sus sales a ceptables en la agricultura, en donde R1, R2, R3, R4, R5, R6, R7, R8, R9, X1, Q, y n son como se d escriben en la presente.

Molecules having pesticidal utility, and intermediates, compositions, and processes, related thereto.

Esta descripción se refiere al campo de moléculas que tienen utilidad plaguicida contra las plagas en los filos Arthropoda, Mollusca y Nematoda, procesos para producir tales moléculas, intermediarios usados en tales procesos, composiciones plaguicidas que contienen tales moléculas, y procesos para usar tales composiciones plaguicidas contra tales plagas. Estas composiciones plaguicidas pueden usarse, por ejemplo, como acaricidas, insecticidas, aracnicidas, molusquicidas y nematicidas. Este documento describe moléculas que tienen la siguiente fórmula ("Fórmula uno"). (ver Fórmula).

Pesticidal compositions and related methods

This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula I, or any agriculturally acceptable salt thereof, wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , X 1 , Q, and n are as described herein.

pesticidal utility molecules, and intermediates, compositions and processes

a presente invenção refere-se ao campo de moléculas com utilidade pesticida contra pragas dos filos arthropoda, mollusca e nematoda, processos para produzir tais moléculas, intermediários usados em tais processos, composições pesticidas contendo tais moléculas, e proces-sos de uso de tais composições pesticidas contra tais pragas. essas composições pesticidas podem ser usadas, por exemplo, como acaricidas, inseticidas, miticidas, moluscicidas e nematicidas. este do-cumento divulga moléculas com a seguinte fórmula ("fórmula um"). The present invention relates to the field of molecules with pesticide usefulness against the phylanthropoda, mollusca and nematoda pests, processes for producing such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes for using such compositions. pesticides against such pests. Such pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides and nematicides. This document discloses molecules of the following formula ("formula one").

Dicamba compositions with reduced spray drift potential

Methods and compositions to reduce spray drift during application and/or volatility after application can be reduced by incorporating certain tertiary amine or tertiary amine oxide surfactants into an aqueous herbicidal spray mixture containing dicamba. The use of the choline salt of dicamba and the presence of 3,6-dichlorosalicylic acid (DCSA) or a salicylic acid derivative can further reduce drift and volatility. In some embodiments, the composition can contain one or more additional pesticides, such as glyphosate, glufosinate, or mixtures thereof. The concentration of 3,6-dichlorosalicylic acid or the salicylic acid derivative is typically greater than about 25 ppm by weight of the spray mixture.

Cyclopropyl amide derivatives having pesticidal utility, and intermediates, compositions, and processes, related thereto

This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula ("Formula One").

Molecules having pesticidal utility, and intermediates, compositions, and processes, related thereto

This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula ("Formula One").

Molecules having pesticidal utility, and intermediates, compositions, and processes, related thereto

Abstract of this disclosure This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such 5 molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula ("Formula One"). R 7 RS Q1 X Formula One

Molecules having pesticidal utility, and intermediates, composition, and processes, related thereto

This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula ("Formula One").

Molecules having pesticidal utility, and intermediates, compositions, and processes, related thereto

This disclosure relates to the field of moiecuies having pesticida i utility against pests in Phyla Arthropoda, Moliusca, and hJematoda, processes to produce such moiecuies, intermediates used In such processes, pesticidai compositions containing such molecules, and processes of using such pesticidai compositions against such pests. These pesticidai compositions may be used, for example, as acaricldes, insecticides, miticides, moilusclcides, and nematicides. This document discloses moiecuies having the following formula ("Formula One").

Processes for the preparation of 4-alkoxy-3-(acyl or alkyl)oxypicolinamides

Dicamba compositions with reduced spray drift potential

Methods and compositions to reduce spray drift during application and/or volatility after application can be reduced by incorporating certain tertiary amine or tertiary amine oxide surfactants into an aqueous herbicidal spray mixture containing dicamba. The use of the choline salt of dicamba and the presence of 3,6-dichlorosalicylic acid (DCSA) or a salicylic acid derivative can further reduce drift and volatility. In some embodiments, the composition can contain one or more additional pesticides, such as glyphosate, glufosinate, or mixtures thereof. The concentration of 3,6-dichlorosalicylic acid or the salicylic acid derivative is typically greater than about 25 ppm by weight of the spray mixture.

農薬の効用を有する分子ならびに関連する中間体、組成物及びプロセス

【課題】節足動物門、軟体動物門、及び線形動物門の害虫に対して農薬の効用を有する分子と、かかる分子を生成するプロセスと、かかるプロセスで使用される中間体と、かかる分子を含有する農薬組成物と、かかる害虫に対してかかる農薬組成物を使用するプロセスを提供する。【解決手段】式１を有する分子を提供する。TIFF2023145722001742.tif54166（Ｒ１、Ｒ２、Ｒ３、Ｒ４及びＲ５は、各々独立にＨ、ハロゲン等；Ｒ６及びＲ９は、各々独立にＨ又はＣ１－Ｃ６アルキル；Ｑ１及びＱ２は、各々独立にＯ又はＳ）【選択図】なし

Cyclopropyl amide derivatives having pesticidal utility, and intermediates, compositions, and processes, related thereto

This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula ("Formula One").

Molecules having pesticidal utility, and intermediates, compositions, and processes, related thereto

This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula ("Formula One").