24-02-2022 дата публикации
Номер: US20220055022A1
Принадлежит:
Catalyst structures and corresponding methods are described for the desulfurization of sulfur-containing light oil or model compounds under a specified gas atmosphere. The sulfur-containing feedstock is effectively converted while producing valuable hydrocarbon products such as BTX and carbon disulfide, as well as utilizing methane or natural gas resources, providing an economical and environmental innovation in the petroleum industry. 1. A method for the desulfurization of a sulfur-containing feedstock , the method comprising introducing the sulfur-containing feedstock within a reactor in the presence of a gas atmosphere and a catalyst structure , wherein the catalyst structure comprises a porous support structure that includes one or more of the following materials: an aluminum oxide (AlO) , an aluminosilicate material such as a zeolite , a silicon oxide (SiO) , a silicon carbide (SiC) , and a titanium oxide (TiO).2. The method of claim 1 , wherein the sulfur-containing feedstock comprises light oils containing sulfur or compounds selected from the group consisting of thiophene claim 1 , benzothiophene claim 1 , dibenzothiophene and any combination and/or derivatives thereof.3. The method of claim 1 , wherein the gas atmosphere consists of pure gas or a mixture of gases selected from the group consisting of nitrogen claim 1 , helium claim 1 , methane claim 1 , and natural gas.4. The method of claim 1 , wherein the catalyst structure comprises one or more of the following metals loaded in the porous support structure: molybdenum claim 1 , nickel claim 1 , cobalt claim 1 , silver claim 1 , gallium claim 1 , cerium and zinc claim 1 , wherein each metal loaded in the porous support structure is present in an amount from about 0.1 wt % to about 20 wt % based upon the total weight of the catalyst structure.5. The method of wherein the one or more metals are loaded within the porous support structure in the form of one or more of the following salts: chlorides claim 4 , ...
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