29-09-2022 дата публикации
Номер: US20220306562A1
The disclosure relates to a method for producing levulinic acid in a molten salt hydrate from cellulose hydrolysis. An inorganic molten salt hydrate was prepared by mixing an inorganic salt with water, cellulose is added and stirred to dissolve, a solid catalyst is added and heated up for reaction to obtain a reactant, the reactant is cooled and subjected to a separation to obtain the levulinic acid, and the inorganic molten salt hydrate and the solid catalyst obtained after the separation are recycled, wherein the inorganic salt is one or more selected from the group consisting of LiCl, LiBr, CaBr, Ca(NO), LiNOand KNO. 1. A method for producing levulinic acid in a molten salt hydrate from cellulose hydrolysis , comprising preparing an inorganic molten salt hydrate by mixing water with an inorganic salt , adding cellulose and stirring to dissolve , adding a solid catalyst and heating up for reaction to obtain a reactant , cooling , and subjecting the cooled reactant to a separation to obtain the levulinic acid , and recycling the inorganic molten salt hydrate and the solid catalyst obtained after the separation , wherein the inorganic salt is one or more selected from the group consisting of LiCl , LiBr , CaBr , Ca(NO) , LiNOand KNO.2. The method for producing levulinic acid in a molten salt hydrate from cellulose hydrolysis according to claim 1 , wherein a molar ratio of the water to the inorganic salt is (1-6):1.3. The method for preparing levulinic acid in a molten salt hydrate from cellulose hydrolysis according to claim 1 , wherein 10-50 g of the cellulose is added to every 1 L of the inorganic molten salt hydrate.4. The method for producing levulinic acid in a molten salt hydrate from cellulose hydrolysis according to claim 1 , wherein the solid catalyst is one or two selected from the group consisting of Nb—Ce/SBA-15 and Nb—CeP/SBA-15.5. The method for producing levulinic acid in a molten salt hydrate from cellulose hydrolysis according to claim 1 , wherein a ...
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