06-12-2018 дата публикации
Номер: US20180346380A1
Автор:
Qingke Nie,
Wei Hu,
Baoshan Huang,
Tao Ai,
Qiang He,
Xiang Shu,
NIE QINGKE,
HU WEI,
HUANG BAOSHAN,
AI TAO,
HE QIANG,
SHU XIANG,
Nie, Qingke,
Hu, Wei,
Huang, Baoshan,
Ai, Tao,
He, Qiang,
Shu, Xiang
Принадлежит:
Red mud-based geopolymer compositions and methods of their preparation are described. The red mud-based geopolymer compositions can be cured at ambient temperatures using alkaline solutions of relatively low alkaline compound concentration compared to other geopolymer compositions. In particular, the use of a red mud previously utilized in a flue gas desulfurization process can provide high strength geopolymer compositions. 1. A geopolymer composition comprising a reaction product of a reaction mixture comprising an alkaline solution and a solids mixture , wherein the solids mixture comprises red mud and an alumina silicate material , wherein the alumina silicate material comprises at least about 10 weight % (wt %) CaO and is selected from the group consisting of Class C fly ash , lime-Class F fly ash , blast furnace slag , and combinations thereof , and wherein the alkaline solution comprises an aqueous solution comprising at least one alkali metal hydroxide , optionally in combination with one or more additional alkaline compound.2. The composition of claim 1 , wherein the alumina silicate material comprises Class C fly ash comprising between about 15 wt % and about 21 wt % CaO.3. The composition of claim 1 , wherein the aqueous solution comprises between about 1.5 moles per liter (mol/L) and about 6.5 mol/L of the alkali metal hydroxide.4. The composition of claim 3 , wherein the aqueous solution comprises between about 2.5 mol/L and about 3.5 mol/L of the alkali metal hydroxide.5. The composition of claim 1 , wherein the alkali metal hydroxide is sodium hydroxide (NaOH).6. The composition of claim 1 , wherein the reaction mixture comprises a weight ratio of alkaline solution to solids mixture of between about 0.4 and about 0.6.7. The composition of claim 1 , wherein the solids mixture has a weight ratio of red mud to alumina silicate material of between about 40:60 red mud:alumina silicate material and about 60:40 red mud:alumina silicate material.8. The ...
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