06-12-2012 дата публикации
Номер: US20120310025A1
Автор:
Gang Wang,
Sihan Wang,
Zhonghua Yang,
Jiabo Qu,
Baojun Zhang,
Qian Chen,
Deshun Zhang,
Libo Wang,
Yali Wang,
Buwei Yu,
Xiuhui Wang,
Fuling Huang,
Xuemei Han,
Dongmei Niu,
Shukun Sun,
Wenchao Zhang,
Hua Li,
Gongchen Yan,
WANG GANG,
WANG SIHAN,
YANG ZHONGHUA,
QU JIABO,
ZHANG BAOJUN,
CHEN QIAN,
ZHANG DESHUN,
WANG LIBO,
WANG YALI,
YU BUWEI,
WANG XIUHUI,
HUANG FULING,
HAN XUEMEI,
NIU DONGMEI,
SUN SHUKUN,
ZHANG WENCHAO,
LI HUA,
YAN GONGCHEN
A catalyst for synthesizing 1-hexene from ethylene trimerization and its application are provided. Said catalyst consists of (a) the compound containing P and N, (b) electron donor, (c) Cr compound, (d) carrier and (e) accelerator. The molar ratio of (a), (b), (c), (d) and (e) is 0.5-100:0.5-100:1:0.5-10:50-5000. The catalyst is prepared by mixing the components of (a)-(e) in an ethylene trimerization apparatus in situ and ethylene is introduced into the apparatus continuously. The prepared catalyst can be used to synthesize 1-hexene from ethylene trimerization in the inert solvents. The trimerization is performed at 30-150° C. and 0.5-10.0 MPa for 0.1-4 hours. The catalyst has high catalytic activity and high 1-hexene selectivity. During the process of ethylene trimerization, by-product polyethylene does not stick to the apparatus. 23-. (canceled)4: The catalyst of claim 1 , wherein the electron donor (b) is of 1 claim 1 ,4-dichlorobenzene claim 1 , 1 claim 1 ,1 claim 1 ,2-trichloroethane claim 1 , 1 claim 1 ,1 claim 1 ,2 claim 1 ,2-tetrachloroethane claim 1 , 1 claim 1 ,1 claim 1 ,2 claim 1 ,2-tetrabromoethane claim 1 , 1 claim 1 ,2-dichlorethane claim 1 , 1 claim 1 ,2-dimethoxyethane claim 1 , chlorobenzene claim 1 , 1 claim 1 ,2-dichlorobenzene claim 1 , 1 claim 1 ,3-dichlorobenzene claim 1 , and/or 1 claim 1 ,4-dichlorobenzene5: The catalyst of claim 1 , wherein the Cr compound (c) is chromium isooctoate claim 1 , chromium chloride tetrahydrofuran claim 1 , chromium 2-ethylhexanoate claim 1 , and/or chromium acetylacetonate6: The catalyst of claim 1 , wherein the carrier (d) is SiO.7: The catalyst of claim 1 , wherein the accelerator (e) is trimethyl aluminium claim 1 , triethyl aluminium claim 1 , tripropyl aluminium claim 1 , tributyl aluminium claim 1 , and/or triisobutyl aluminium8: The catalyst of claim 1 , wherein the molar ratio is 1-80:1-70:1:1-8:100-4000.10: The catalyst of claim 9 , wherein in compound (a) R claim 9 , R claim 9 , Rand Rare phenyl and ...
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