05-09-2019 дата публикации
Номер: US20190273178A1
Принадлежит:
NANOSYS, INC.
The invention is in the field of nanostructure synthesis. Provided are highly luminescent nanostructures, particularly highly luminescent quantum dots, comprising a nanocrystal core and a thin inner shell layer. The nanostructures may have an additional outer shell layer. Also provided are methods of preparing the nanostructures, films comprising the nanostructures, and devices comprising the nanostructures. 1. A nanostructure comprising a nanocrystal core and at least one thin inner shell , wherein the at least one thin inner shell has a thickness of between about 0.01 nm and about 0.35 nm , and wherein the nanostructure exhibits an effective Stokes shift of between about 25 nm and about 125 nm.2. The nanostructure of claim 1 , wherein the nanocrystal core is selected from the group consisting of Si claim 1 , Ge claim 1 , Sn claim 1 , Se claim 1 , Te claim 1 , B claim 1 , C claim 1 , P claim 1 , BN claim 1 , BP claim 1 , BAs claim 1 , AlN claim 1 , AlP claim 1 , AlAs claim 1 , AlSb claim 1 , GaN claim 1 , GaP claim 1 , GaAs claim 1 , GaSb claim 1 , InN claim 1 , InP claim 1 , InAs claim 1 , InSb claim 1 , ZnO claim 1 , ZnS claim 1 , ZnSe claim 1 , ZnTe claim 1 , CdS claim 1 , CdSe claim 1 , CdSeZn claim 1 , CdTe claim 1 , HgS claim 1 , HgSe claim 1 , HgTe claim 1 , BeS claim 1 , BeSe claim 1 , BeTe claim 1 , MgS claim 1 , MgSe claim 1 , GeS claim 1 , GeSe claim 1 , GeTe claim 1 , SnS claim 1 , SnSe claim 1 , SnTe claim 1 , PbO claim 1 , PbS claim 1 , PbSe claim 1 , PbTe claim 1 , CuF claim 1 , CuCl claim 1 , CuBr claim 1 , CuI claim 1 , SiN claim 1 , GeN claim 1 , AlO claim 1 , AlCOand combinations thereof.3. (canceled)4. The nanostructure of claim 1 , wherein the at least one thin inner shell is selected from the group consisting of CdS claim 1 , CdSe claim 1 , CdO claim 1 , CdTe claim 1 , ZnS claim 1 , ZnO claim 1 , ZnSe claim 1 , ZnTe claim 1 , MgTe claim 1 , GaAs claim 1 , GaSb claim 1 , GaN claim 1 , HgO claim 1 , HgS claim 1 , HgSe claim 1 , HgTe claim 1 , ...
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