05-05-2023 дата публикации
Номер: CN116064033A
Принадлежит:
The invention discloses agglomeration-free nitride red fluorescent powder and a preparation method thereof.The method comprises the steps that Eu (NO3) 3, Si powder and AlN powder serve as raw materials, a precursor is prepared through precipitation, staticizing, cleaning and drying, the precursor is sintered for 3-6 h at the temperature of 1,300-1,500 DEG C in the N2 atmosphere and then crushed after being cooled, a certain amount of Ca3N2 and NH4Cl are added into a glove box, the mixture is fully ground and evenly mixed and then placed into a multifunctional sintering furnace, and the agglomeration-free nitride red fluorescent powder is obtained. The preparation method comprises the following steps of: sintering in N2 atmosphere at the pressure of 0.9 MPa at 1700-1900 DEG C for 2 hours, cooling, crushing, repeatedly washing by using a hot salpeter solution and deionized water respectively, and drying to obtain a final product. The fluorescent powder prepared by the invention emits red ...
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