29-09-2016 дата публикации
Номер: US20160280552A1
Принадлежит:
The present disclosure relates to methods for enhanced demetalyzation of an ultrahard material, such as polycrystalline diamond (PCD) or cubic boron nitride (CBN), using a thiourea solution. The thiourea solution may contain thiourea and an acid, such as a Bronstead acid suitable for leaching. The thiourea may contain thiourea or a substituted thiourea, including tautomers thereof. The ultrahard material may be exposed to the thiourea solution for a time and under conditions sufficient to remove at least a desired amount of a metal, such as a catalyst used during formation of the PCD or CBN, from at least a portion of the ultrahard material. 1. A method of removing a target metal from an ultrahard material , the method comprising:exposing the ultrahard material to a thiourea solution comprising at least one thiourea and at least one acid for a time and under conditions sufficient to remove at least 70% of the target metal from at least a portion of the ultrahard material.2. The method of claim 1 , wherein the ultrahard material comprises polycrystalline diamond (PCD).3. The method of claim 1 , wherein the target metal comprises a catalyst used during formation of the ultrahard material.4. The method of claim 3 , wherein the catalyst comprises a Group VIII metal or alloy thereof.5. The method of claim 3 , wherein the catalyst comprises cobalt claim 3 , a cobalt alloy claim 3 , nickel claim 3 , a nickel alloy claim 3 , or a combination thereof.6. The method of claim 3 , wherein the catalyst substantially lacks iron or an iron alloy.71010. The method of claim 1 , wherein the thiourea solution comprises between M and M thiourea.9. The method of claim 8 , wherein R claim 8 , R claim 8 , R claim 8 , and Rare independently an allyl claim 8 , an alkenyl claim 8 , an alkynyl claim 8 , a C-chain claim 8 , such as a C claim 8 , or a Cchain claim 8 , an alcohol claim 8 , an aldehyde claim 8 , a carbonate claim 8 , a carboxylate claim 8 , carboxylic acid claim 8 , an ester claim ...
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