Multidentate Ketoimine Ligands For Metal Complexes

The present invention is a plurality of metal-containing complexes of a multidentate ketoiminate.

NITROGEN FIXATION BY TITANIUM DIOXIDE

In various embodiments, the present disclosure provides a method of fixing nitrogen. An amount of titania catalyst is provided and contacted with a feed stream that includes nitrogen. The titania catalyst is heated. The heated titania catalyst fixes nitrogen in the feed stream to form nitrogen products, such as nitrates. The nitrogen products are then removed from the titania catalyst. In some examples, the titania catalyst is treated with a base. In further examples, the catalytic process is carried out in the absence of light for photochemically activating the titania catalyst. 1. A nitrogen fixation method , comprising:providing an amount of titania catalyst;contacting the titania catalyst with a feed stream comprising nitrogen;heating the titania catalyst to fix nitrogen from the feed stream to form nitrogen products; andremoving the nitrogen products from the titania catalyst.2. The nitrogen fixation method of claim 1 , wherein heating the catalyst comprises heating the catalyst at a temperature of between about 40° C. and about 600° C.3. The nitrogen fixation method of claim 1 , wherein heating the catalyst comprises heating the catalyst at a temperature of between about 150° C. and about 350° C.4. The nitrogen fixation method of claim 1 , wherein heating the catalyst comprises heating the catalyst at a temperature of between about 175° C. and about 275° C.5. The nitrogen fixation method of claim 1 , further comprising treating the titania catalyst with a base.6. The nitrogen fixation method of claim 1 , wherein heating the titania catalyst is carried out at least substantially in the absence of light for photochemically activating the titania catalyst.7. The nitrogen fixation method of claim 1 , wherein heating the titania catalyst is carried out in a reactor claim 1 , the reactor being at least substantially opaque.8. The nitrogen fixation method of claim 1 , wherein heating the titania catalyst is carried out for an average time of at least about 2 hours.9. ...

METHOD FOR CONVERTING NITROGEN (N2) INTO AMMONIA AND/OR NITRATE

The present invention relates to a method for converting nitrogen (N) into nitrate and/or ammonia comprising the steps of compressing air and separating nitrogen (N) and oxygen (O) therefrom, and either reacting earth alkaline metal with oxygen to produce earth alkaline metal oxide, using the high temperatures obtained to react Nand Oto NO, converting the NO with Oto NO, followed by the reaction of NOwith water to result in HNOand NO; or reacting the nitrogen obtained with earth alkaline metal to produce earth alkaline metal nitride and reacting thereof with water to result in earth alkaline metal hydroxide and ammonia. 2. Method according to claim 1 , wherein the earth alkaline metal is in the form of powder or billets.3. Method according to claim 1 , wherein an intense light glow obtained in the reaction in step b1) is transferred to photovoltaic cells for production of electricity.4. Method according to claim 1 , wherein the NO obtained in step c1) is heat exchanged with the compressed air used in step a) claim 1 , the compressed air is then expanded in a gas turbine that turns an electrical generator.5. Method according to claim 1 , wherein step b2) is carried out at a temperature of about 600-1.000° C.6. Method according to claim 1 , wherein the earth alkaline metal hydroxides obtained in step b2) are at least partly reacted with nitric acid obtained in step c1).7. Method according to claim 1 , wherein the earth alkaline metal hydroxides obtained in step b2) are at least partly reacted with hydrochloric acid according to the following equation{'br': None, 'sub': 2', '2', '2, 'Me(OH)+2HCl→MeCl+2HO'} {'br': None, 'sub': 2', '2, 'MeCl→Me+Cl,'}, 'wherein the earth alkaline metal chloride is then heated to its melting temperature and electrolyzed'} {'br': None, 'sub': 2', '2, 'H+Cl2HCl.'}, 'wherein optionally hydrochloric acid is then prepared by reacting the chlorine gas with hydrogen gas according to the following formula8. Method according to claim 7 , wherein ...

Conversion of Metal Carbonate into Metal Chloride

A method for producing metal chloride MClx− includes reacting metal carbonate in solid form using phosgene, diphosgene and/or triphosgene to form metal chloride MClx−, wherein the metal M is selected from the group containing alkali metals, alkaline earth metals, Al and Zn, Li and Mg, or Li, for example, and x corresponds to the valency of the metal cations. An apparatus for performing such method is also disclosed. 1. A method for producing metal chloride MCl , the method comprising:providing phosgene, diphosgene and/or triphosgene,{'sup': x+', '−, 'sub': 'x', 'reacting metal carbonate as solid with the phosgene, diphosgene and/or triphosgene to produce metal chloride MCl,'}wherein the metal M is selected from the group consisting of the alkali metals, alkaline earth metals, Al and Zn, Li and Mg, and Li, andwherein x indicates the valence of the metal cation.2. The method of claim 1 , further comprising adding M as an additional reactant.3. The method of claim 2 , wherein at least one of:the metal M is used together with the metal carbonate, orphosgene, diphosgene and/or triphosgene is prepared in situ by reaction of chlorine with carbon monoxide.4. The method of claim 1 , further comprising subsequently reacting the metal chloride to produce metal M.5. The method of claim 4 , further comprising reacting the produced metal M at least partly with carbon dioxide to produce metal carbonate claim 4 , to thereby form a metal circuit.6. The method of claim 1 , wherein the reaction is performed in a grid reactor or a mechanically moved fixed-bed reactor or in a cyclone reactor.7. The method of claim 1 , wherein the phosgene claim 1 , diphosgene and/or triphosgene is prepared by the reaction of carbon monoxide and chlorine.8. The method of claim 7 , wherein the carbon monoxide is produced by a reaction of metal carbonate with the metal M and/or from an electrolysis of carbon dioxide.9. An apparatus for reacting metal carbonate as solid with phosgene claim 7 , diphosgene ...

METHOD FOR PRODUCING COORDINATIVELY UNSATURATED METAL-ORGANIC FRAMEWORK AND COORDINATIVELY UNSATURATED METAL-ORGANIC FRAMEWORK

[OBJECT] To provide a metal-organic framework having high hygroscopicity under low humidity conditions, and a method for producing such a metal-organic framework. 1. A method for producing a coordinatively unsaturated metal-organic framework , comprising:providing a precursor metal-organic framework comprising a metal cluster, and a polycarboxylic acid ion and a monocarboxylic acid ion which are coordinated to the metal cluster, andallowing the precursor metal-organic framework and a metal salt having a Lewis acidity to coexist in a solvent to desorb at least a part of the monocarboxylic acid ion which is coordinated to the metal cluster, from the metal cluster.2. The method according to claim 1 ,{'sub': 6', '8-x', 'x, 'wherein the metal cluster is an MO(OH)-type metal cluster,'}wherein M is a group IV element ion or a rare earth ion,{'sub': '1-3', 'wherein the polycarboxylic acid ion and the monocarboxylic acid ion coordinated to the metal cluster are a polycarboxylic acid ion as a polydentate ligand and a Cmonocarboxylic acid ion as a monodentate ligand, respectively, and'}wherein less than six monocarboxylic acid ions are coordinated to each metal cluster.3. The method according to claim 2 , wherein M is at least one selected from the group consisting of Zr claim 2 , Hf claim 2 , and Ce.4. The method according to claim 1 , wherein the monocarboxylic acid ion is at least one selected from the group consisting of a formic acid ion claim 1 , an acetic acid ion claim 1 , and a propionic acid ion.5. The method according to claim 1 , wherein the metal salt having a Lewis acidity is a halide.6. A coordinatively unsaturated metal-organic framework claim 1 , comprising:{'sub': 6', '8-x', 'x, 'an MO(OH)-type metal cluster, and carboxylic acid ions coordinated to the metal cluster,'}wherein M is a tetravalent group IV element ion or a rare earth ion,wherein the carboxylic acid ions coordinated to the metal cluster comprise a polycarboxylic acid ion as a polydentate ligand ...

SYSTEM AND METHOD FOR GENERATING A PURIFIED CATALYST

Methods for generating a purified catalyst are provided. The method includes performing a reaction in a reaction vessel to generate a liquid catalyst and reaction products, purging the reaction products using an inert gas to form a purged catalyst, freezing the purged catalyst in the reaction vessel, and applying a vacuum to the reaction vessel while the purged catalyst thaws, wherein the vacuum removes residual reaction products to form a purified catalyst. Systems for generating a purified catalyst and a purified catalyst are also provided.

Process for precipitation of carnallite from aqueous solutions

There is provided a process for extracting Carnallite from an aqueous solution, the process comprising steps of pre-heating the solution comprising said Carnallite in a series of at least two heat exchangers, thereby obtaining a pre-heated solution; and concentrating said pre-heated solution in a series of at least two evaporation units, whereby forming a concentrated solution and hot vapors; wherein at least one of said evaporation units employs steam for indirect heating, and wherein at least one of said heat exchanger units employs the heat of said hot vapors formed in said evaporation units.

COMPOUNDS, COMPOSITIONS AND ASSOCIATED METHODS USING ZIRCONIUM-89 IN IMMUNO-POSITRON EMISSION TOMOGRAPHY

Disclosed are novel compounds, complexes, compositions and methods using Zirconium-89 combined with azamacrocyclic chelators in connection with PET. The compositions and methods should provide better diagnostic, prognostic and therapeutic oncology treatments relative to the presently available chelator compositions due to a variety of superior properties of the disclosed compositions. The present invention also relates to a superior method of making these compounds, complexes, compositions that allows one to make compounds/complexes (and thus, compositions) that were previously unattainable. 2. The composition of claim 1 , wherein the composition comprises both Zr and oxalic acid or salts thereof.4. The composition of claim 1 , wherein the compound of formula I and Zr form a complex.5. The composition of claim 4 , wherein the complex is further linked to one or more of a monoclonal antibody claim 4 , a peptide claim 4 , a protein claim 4 , or a nanoparticle.7. The composition of claim 4 , wherein the complex is formed by reacting the compound of formula I with ZrCl.8. The composition of claim 1 , further comprising a buffer.9. The composition of claim 8 , wherein the buffer is HEPES buffer.10. The composition of claim 7 , wherein the composition further comprises HEPES buffer.11. A kit comprising the compound of Formula I in claim 1 , and optionally claim 1 , HEPES buffer and monoclonal antibodies.13. The compound of wherein at least one of R claim 12 , R claim 12 , R claim 12 , Rare independently —CH—.14. The compound of claim 12 , wherein all of R claim 12 , R claim 12 , R claim 12 , Rare independently —CH—.15. The compound of claim 14 , wherein claim 14 , a is 1 or 2 and b is 1 or 2.16. The compound of claim 15 , wherein all of R claim 15 , R claim 15 , R claim 15 , R claim 15 , R claim 15 , R claim 15 , R claim 15 , and Rare —OH or all of R claim 15 , R claim 15 , R claim 15 , R claim 15 , R claim 15 , R claim 15 , R claim 15 , and Rare unsubstituted phenol.17. ...

Conversion of Metal Carbonate to Metal Chloride

A process for preparing metal chloride Mx+Clx−, in which metal carbonate in solid form is reacted with a chlorinating agent selected from chlorine and oxalyl chloride to give metal chloride Mx+Clx−, where the metal M is selected from the group of the alkali metals, alkaline earth metals, Al and Zn, Li and Mg, or Li, and x corresponds to the valency of the metal cation, and wherein metal M is additionally added as a reactant to the metal carbonate/chlorinating agent reaction. 1. A method for producing metal chloride MCl , comprising:providing a chlorinating agent,{'sup': x+', '−, 'sub': 'x', 'reacting metal carbonate as a solid with the chlorinating agent to form metal chloride MCl,'}wherein metal M being selected from the group of metals consisting of the alkali metals, alkaline earth metals, Al and Zn, Li and Mg, and Li, andwherein x corresponds to the valence of the metal cation, andadditionally adding metal M as a reactant to the reaction of metal carbonate with the chlorinating agent.2. The method of claim 1 , wherein the metal M added as a reactant with a metal/metal carbonate weight ratio of less than 5/10 in order to generate thermal energy.3. The method of claim 2 , wherein the metal M is used together with the metal carbonate for the reaction with the chlorinating agent.4. The method of claim 1 , wherein the chlorinating agent comprises chlorine or oxalyl chloride.5. The method of claim 1 , wherein the metal chloride is subsequently reacted to produce metal M.6. The method of claim 5 , wherein the metal M produced by the subsequent reaction of the metal chloride is reacted at least partly with carbon dioxide to produce metal carbonate claim 5 , to form a metal circuit.7. The method of claim 1 , wherein the reaction occurs in a grid reactor or a mechanically moved fixed-bed reactor or in a cyclone reactor.8. The method of claim 7 , wherein the reaction occurs in a grid reactor claim 7 , in which the chlorinating agent is added as a gas in cocurrent with the ...

FOOD SALT PRODUCT

The invention provides a multi-component homogenous co-crystallized low sodium salt product for food and pharmaceutical use. The salt product of the invention is essentially segregation-free, has low hygroscopicity and is free-flowing. It has good microbial depression properties and good taste. It supplies the functionality of salt (NaCl) in processed foods and it also maintains the microbial safety, nutritional value and taste. The salt product of the invention includes an alkaline and alkaline earth metal chloride component and an ammonium chloride component. An alkaline metal is potassium (K), and optionally also sodium (Na). An alkaline earth metal is Magnesium (Mg) or Magnesium (Mg) and Calcium (Ca) having the sum of the molar ratios 1. The invention provides also a process to produce the salt products of the invention. 1. A homogenous co-crystallized salt product for food use said salt product having good microbial depression properties and being segregation-free , said salt product including an alkaline earth metal chloride component , at least one alkaline metal chloride component , an ammonium chloride component and optionally a second alkaline metal chloride component and having general Formula (I){'br': None, 'sub': a', 'b', 'c', '4', 'd', 'e', 'f', '2, 'MgCaK(NH)NaCl·zHO\u2003\u2003(I)'}whereina+b=1, 0 Подробнее

METAL COORDINATED COMPOSITIONS

A metal coordination complex of a biologically active moiety and a metal is disclosed. The complex confers to the biologically active moiety an improved performance which can include potency, stability, absorbability, targeted delivery, and combinations thereof. 147-. (canceled)48. A metal coordination complex of a biologically active moiety and a metal , wherein the biologically active moiety is selected from the group consisting of: metformin , omeprazole , famotidine , rabeprazole , theophylline , hydrochlorothiazide , alendronate , mitoxantrone , adefovir , acyclovir , clonidine , dipyramidole , atovaquone , idarubicin , etidronate , valganciclovir , saquinavir , fosamprenavir , retinoic acid , minoxidil , cyclosporine , fosphenytoin , atrial natriuretic peptide , abarelix , and heparin and their derivatives.49. The complex of claim 48 , wherein the metal is selected from the group consisting of: aluminum claim 48 , bismuth claim 48 , calcium claim 48 , iron claim 48 , strontium claim 48 , magnesium claim 48 , silicon claim 48 , and zinc.50. A metal coordination complex of a biologically active moiety and a metal claim 48 , wherein the biologically active moiety contains a β-diketone claim 48 , ketophenol or β-ketoalcohol claim 48 , functional group.51. The complex of claim 50 , wherein the metal is selected from the group consisting of: aluminum claim 50 , bismuth claim 50 , calcium claim 50 , iron claim 50 , strontium claim 50 , magnesium claim 50 , silicon claim 50 , and zinc.52. A metal coordination complex of a biologically active moiety and a metal claim 50 , wherein the biologically active moiety contains an azole functional group.53. The complex of claim 52 , wherein the metal is selected from the group consisting of: aluminum claim 52 , bismuth claim 52 , calcium claim 52 , iron claim 52 , strontium claim 52 , magnesium claim 52 , silicon claim 52 , and zinc.54. The complex of claim 48 , wherein the biologically active moiety is omeprazole.55. The ...

ACID/SALT SEPARATION

The invention provides a method for preparing a carboxylic acid, which method includes the steps of providing magnesium carboxylate, wherein the carboxylic acid corresponding with the carboxylate has a solubility in water at 20 ° C. of 80 g/100 g water or less; acidifying the magnesium carboxylate with HCl, thereby obtaining a solution comprising carboxylic acid and magnesium chloride (MgCl2); optionally a concentration step, wherein the solution comprising carboxylic acid and MgCl2 is concentrated; precipitating the carboxylic acid from the solution comprising the carboxylic acid and MgCl2, thereby obtaining a carboxylic acid precipitate and a MgCl2 solution. 1. Method for the recovery of a carboxylic acid , comprising the steps of:providing an aqueous solution or suspension of magnesium carboxylate, wherein the carboxylic acid corresponding with the carboxylate has a solubility in water at 20° C. of 80 g/100 g water or less;{'sub': '2', 'obtaining solid magnesium carboxylate from said solution or suspension and acidifying the magnesium carboxylate with a solution of hydrogen chloride (HCl), thereby obtaining a solution comprising carboxylic acid and magnesium chloride (MgCl);'}{'sub': '2', 'optionally a concentration step, wherein the solution comprising carboxylic acid and MgClis concentrated; and,'}{'sub': 2', '2, 'precipitating carboxylic acid from the solution comprising carboxylic acid and MgCl, thereby obtaining a carboxylic acid precipitate and a MgClsolution.'}2. Method according to claim 1 , wherein the carboxylic acid has a solubility in water at 20° C. that is lower than that of MgCl.3. Method according to claim 1 , wherein the carboxylic acid has a solubility in water of less than 30g /100g water.4. The method of claim 1 , wherein the carboxylic acid is selected from the group consisting of adipic acid claim 1 , itaconic acid claim 1 , 2 claim 1 ,5-furandicarboxylic acid claim 1 , fumaric acid claim 1 , oxalic acid claim 1 , maleic acid claim 1 , ...

Corrosion-resistant coolant salt and method for making same

This document describes a method for reducing the corrosivity of certain magnesium salts. The salt product resulting from the method exhibits reduced corrosion of steels that come into contact with the salt relative to salt compositions that are not so treated. This makes such treated salts more efficient coolant salts as they will require less equipment replacement over time. The method uses magnesium metal to reduce unwanted impurities in the salts the reduced impurities are then removed as either gas or precipitate from the now purified salt. Without being bound to one particular theory, it is believed that the reduction of the level of impurities in the salt results in a salt with substantially reduced corrosiveness to steel.

Phototunable metal-organic framework compositions, and methods of synthesis thereof

Some embodiments include a method of preparing a phototuned metal-organic framework by forming a first solution by dissolving ZrOCl 2 .8H 2 O in dimethylformamide (DMF) and formic acid, mixing and dissolving 1,4-phenylenediacrylic acid in a second solution of dimethylformamide (DMF) and trimethylamine, and at least partially mixing the first and second solutions to form a mixture. The method further includes sealing the mixture in an autoclave and heating the mixture to above ambient temperature for a specified period of time to prepare ZrPDA metal-organic framework, and extracting the ZrPDA metal-organic framework and at least partially reacting to a specified degree at least some of ZrPDA metal-organic framework through [2+2] cycloaddition reactions. The specified degree can be tunable based at least in part on at least one of the intensity of UV radiation, the exposure time, and the UV wavelength.

PROCESS FOR PREPARING AN IRON-CHROMIUM CATALYST WITH A PLATINUM PROMOTER, AND CATALYST CONSISTING OF IRON CHROMIUM WITH A PLATINUM PROMOTER

The present invention relates to catalysts of iron and chromium with a platinum promoter for use in water-gas shift reactions, both at low temperatures (LTS) and at high temperatures (HTS). Their characteristics of higher activity due to the addition of Pt compared to the conventional catalysts make them superior to the commercial catalysts in the same operating conditions. Because precursors of the active phase (FeO) are obtained in greater quantity per unit area, it was possible to prepare catalysts that are more promising with a smaller surface area. 1. Process for preparing an iron-chromium catalyst with a platinum promoter , wherein the process comprises the following steps:{'sub': 2', '3', '2', '3, '(a) synthesis of the iron and chromium oxides by the method of co-precipitation so as to obtain FeOand CrO; and'}(b) addition of platinum to the catalyst obtained in (a).2. Process according to claim 1 , wherein the co-precipitation provides FeOand CrOin a ratio of 85-95%:15-5% by weight.3. Process according to claim 1 , wherein the platinum is added in an amount of from 0.01 to 1.5 wt % of the catalyst.4. Process according to claim 1 , wherein the platinum is added by a method of dry impregnation of the catalyst.5. Process according to claim 4 , further comprising a step claim 4 , after the addition of the platinum claim 4 , of drying at a temperature from 110 to 130° C.6. Process according to claim 5 , wherein the step of drying is performed for 20 to 28 hours.7. Process according to claim 1 , wherein the process additionally comprises the step of calcination of the catalyst.8. Process according to claim 7 , wherein the step of calcination is performed at a temperature of from 440 to 460° C.9. Process according to claim 8 , wherein the step of calcination comprises maintaining the temperature between 440 and 460° C. for 1 to 3 hours.10. Process according to claim 9 , wherein the step of calcination comprises an initial heating step claim 9 , heating at a rate of ...

METHOD FOR PRODUCING ANHYDROUS CALCIUM NITRATE POWDER

The invention relates to a method for producing an anhydrous powder having a calcium nitrate content of between 92 and 99.9 weight %, a water content of between 0.1 and 8 weight %; and a particle size of between 0.05 and 1.5 mm, wherein the method comprises the step of subjecting a calcium nitrate solution having a water content of between 70 and 15 weight % and a calcium nitrate content of between 30 and 85 weight % to a drying step in an industrial turbo-dryer, resulting in the anhydrous calcium nitrate powder. The invention furthermore relates to such an anhydrous calcium nitrate powder and the use of an industrial turbo-dryer to produce such anhydrous calcium nitrate powder. 114-. (canceled)15. A method for producing an anhydrous powder , wherein the method comprises the step of subjecting a calcium nitrate solution having a water content of between 70 and 15 weight % of water and a calcium nitrate content of between 30 and 85 weight % to a drying step , wherein the industrial turbo-dryer comprises a drum having a horizontal axis and being closed at opposite ends that are provided with openings for the introduction of the solution and a stream of dry air travelling in the same direction, and further comprises a heating jacket for heating the internal wall of the tubular body to a predetermined temperature, and a bladed rotor rotatable supported in the drum, and', 'wherein the drying step produces the anhydrous calcium nitrate powder having, 'CHARACTERISED IN THAT the calcium nitrate solution is subjected to a drying step performed at a temperature of between 200 and 300° C. in an industrial turbo-dryer,'}a calcium nitrate content of between 92 and 99.9 weight %;a water content of between 0.1 and 8 weight %; anda particle size of between 0.05 and 1.5 mm.16. The method according to claim 15 , characterized in that the drying step is performed a temperature of between 240 and 280° C.17. The method according to claim 15 , characterized in that the calcium nitrate ...

Acid/salt separation

The invention provides a method for preparing a carboxylic acid, which method includes the steps of providing magnesium carboxylate, wherein the carboxylic acid corresponding with the carboxylate has a solubility in water at 20° C. of 80 g/100 g water or less; acidifying the magnesium carboxylate with HCl, thereby obtaining a solution comprising carboxylic acid and magnesium chloride (MgCl 2 ); optionally a concentration step, wherein the solution comprising carboxylic acid and MgCl 2 is concentrated; precipitating the carboxylic acid from the solution comprising the carboxylic acid and MgCl 2 , thereby obtaining a carboxylic acid precipitate and a MgCl 2 solution.

Synthesis of Zinc-Lysine Complex From Zinc Chloride

The disclosure provides an improved synthesis for a zinc-lysine complex having the formula [Zn(C 6 H 14 N 2 O 2 ) 2 Cl] + Cl − , in which zinc chloride is reacted with lysine, in aqueous solution. The disclosure also provides oral care and personal care compositions comprising the complex prepared by the synthesis, and methods of using these complexes and compositions.

BIS AZAINOSITOL HEAVY METAL COMPLEXES FOR X-RAY IMAGING

The present invention describes a new class of trinuclear heavy metal complexes comprising two hexadentate azainositol tricarboxylic acid ligands, a method for their preparation and their use as X-ray contrast agents. 1. A trinuclear heavy metal complex comprising two hexadentate azainositol tricarboxylic acid ligands.7. The trinuclear heavy metal complex of claim 2 , selected from the group consisting of:{'sub': 3', '−3', '2', '3, 'sup': 2', '1', '3', '2', '3', '5', '2', '1', '5, '[Hf(Htacita)]=Bis {μ-[(all-cis)-2-{[(carboxy-1κO)methyl]amino-1κN}-4-{[(carboxy-2κO)methyl]amino-2κN}-6-{[(carboxy-3κO)methyl]amino-3κN}cyclohexane-1,3,5-triolate-1κO,O:2κO,O:3κO,O]}trihafnium(IV),'}{'sub': 3', '3', '−3', '2', '3, 'sup': 2', '1', '3', '2', '3', '5', '2', '1', '5, 'Na[Lu(Htacita)]=Trisodium bis {μ-[(all-cis)-2-{[(carboxy-1κO)methyl]amino-1κN}-4-{[(carboxy-2κO)methyl]amino-2κN}-6-{[(carboxy-3κO)methyl]amino-3κN}cyclohexane-1,3,5-triolate-1κO,O:2κO,O:3κO,O]}trilutetate(III),'}{'sub': 3', '3', '−3', '2', '3, 'sup': 2', '1', '3', '2', '3', '5', '2', '1', '5, 'Na[Gd(Htacita)]=Trisodium bis {μ-[(all-cis)-2-{[(carboxy-1κO)methyl]amino-1κN}-4-{[(carboxy-2κO)methyl]amino-2κN}-6-{[(carboxy-3κO)methyl]amino-3κN}cyclohexane-1,3,5-triolate-1κO,O:2κO,O:3κO,O]}trigadolinate(III),'}{'sub': 3', '3', '−3', '2', '3, 'sup': 2', '1', '3', '2', '3', '5', '2', '1', '5, 'Na[Ho(Htacita)]=Trisodium bis {μ-[(all-cis)-2-{[(carboxy-1κO)methyl]amino-1κN}-4-{[(carboxy-2κO)methyl]amino-2κN}-6-{[(carboxy-3κO)methyl]amino-3κN}cyclohexane-1,3,5-triolate-1κO,O:2κO,O:3κO,O]}triholmate(III),'}{'sub': 3', '3', '−3', '2', '3, 'sup': 2', '1', '3', '2', '3', '5', '2', '1', '5, 'Na[Er(Htacita)]=Trisodium bis {μ-[(all-cis)-2-{[(carboxy-1κO)methyl]amino-1κN}-4-{[(carboxy-2κO)methyl]amino-2κN}-6-{[(carboxy-3κO)methyl]amino-3κN}cyclohexane-1,3,5-triolate-1κO,O:2κO,O:3κO,O]}trierbate(III)'}{'sub': 3', '3', '−3', '2', '3, 'sup': 2', '1', '3', '2', '3', '5', '2', '1', '5, 'Na[Yb(Htacita)]=Trisodium bis {μ-[(all-cis)-2-{[( ...

METHOD OF PREPARING METAL OXIDE-SILICA COMPOSITE AEROGEL AND METAL OXIDE-SILICA COMPOSITE AEROGEL PREPARED BY USING THE SAME

Provided are a method of preparing a metal oxide-silica composite aerogel, which includes preparing metal oxide-silica composite precipitates by adding a metal salt solution to a silicate solution and performing a reaction, and drying the metal oxide-silica composite precipitates by irradiation with infrared rays in a wavelength range of 2 μm to 8 μm, and a metal oxide-silica composite aerogel having excellent physical properties, such as low tap density and high specific surface area, as well as excellent pore properties prepared by the method. 1. A method of preparing a metal oxide-silica composite aerogel , the method comprising:preparing metal oxide-silica composite precipitates by adding a metal salt solution to a silicate solution and performing a reaction; anddrying the metal oxide-silica composite precipitates by irradiation with infrared rays in a wavelength range of 2 μm to 8 μm.2. The method of claim 1 , wherein the drying is performed by irradiation with infrared rays in a wavelength range in which the infrared rays resonate with a water molecule or a hydroxy group in a solvent used during preparation of the silicate solution and the metal salt solution.3. The method of claim 1 , wherein the drying is performed by irradiation with infrared rays in a wavelength range of 2 μm to 4 μm.4. The method of claim 1 , wherein the drying is performed by irradiation with infrared rays at an intensity such that an ambient temperature becomes in a range of 130° C. to 300° C.5. The method of claim 1 , further comprising performing an additional drying process in an ambient temperature range of 130° C. to 300° C. claim 1 , after the drying by the infrared irradiation.6. The method of claim 1 , wherein the silicate solution is prepared by dissolving water glass at a concentration of 0.125 M to 3.0 M.7. The method of claim 1 , wherein the metal salt solution has a metal ion concentration of 0.125 M to 3.0 M.8. The method of claim 1 , wherein the metal salt comprises ...

ANION INSERTION ELECTRODE MATERIALS FOR DESALINATION WATER CLEANING DEVICE

A desalination battery includes a first electrode, a second electrode, an intercalation compound contained in the first electrode, a container configured to contain a saline water solution, and a power source. The intercalation compound includes at least one of a metal oxide, a metalloid oxide, a metal oxychloride, a metalloid oxychloride, and a hydrate thereof with each having a ternary or higher order. The first and second electrodes are configured to be arranged in fluid communication with the saline water solution. The power source is configured to supply electric current to the first and second electrodes in different operating states to induce a reversible intercalation reaction within the intercalation compound. The intercalation compound reversibly stores and releases target anions from the saline water solution to generate a fresh water solution in one operating state and a wastewater solution in another operating state. 1. An intercalation electrode for a desalination battery , comprising:an intercalation compound that contains at least one of a metal oxide, a metalloid oxide, a metal oxychloride, a metalloid oxychloride, and a hydrate thereof with each having a ternary or higher order, the intercalation compound configured to be at least partially immersed in a saline water solution and undergo a reversible intercalation reaction in which (i) anions from the saline water solution reversibly insert within the intercalation compound in a first condition of the electrode and (ii) the anions within the intercalation compound de-insert therefrom into the saline water solution in a second condition of the electrode.2. The intercalation electrode of claim 1 , wherein a voltage in which the anions insert into and de-insert from the intercalation compound in the first and second conditions claim 1 , respectively claim 1 , is within a voltage range of −0.5 to 1.5 V.3. The intercalation electrode of claim 2 , wherein the voltage exceeds the voltage range by up to 0. ...

Bridged Alkaline Earth Metal Alkylphenates

A bridged alkaline earth metal alkylphenate having reduced monomeric alkylphenol is prepared by reacting (a) a 4-alkylphenol, unsubstituted at the ortho positions, (b) an alkaline earth metal oxide or hydroxide, (c) a bridging agent comprising sulfur or a carbonyl compound of 1 to about 6, or to 4 or to 2, carbon atoms, and (d) a 2,6-dialkylphenol. The amount of the 2,6-dialkylphenol is 0.05 to 3 moles per 1 mole of the 4-alkylphenol; if there is a molar excess of the 2,6-dialkylphenol, then the excess is added after initial reaction. 2. The process of wherein the 4-alkylphenol comprises 4-dodecylphenol.3. The process of wherein the alkaline earth metal oxide or hydroxide comprises calcium hydroxide.4. The process of wherein the bridging agent comprises formaldehyde.5. The process of wherein the bridging agent comprises sulfur.6. The process of wherein the 2 claim 1 ,6-dialkylphenol comprises 2 claim 1 ,6-di-t-butylphenol.7. The process of wherein amount of the 2 claim 1 ,6-dialkylphenol is about 0.15 to about 0.5 moles per 1 mole of the 4-alkylphenol.8. The process of wherein the amount of the bridging compound is about 0.8 to about 4 moles per 1 mole of the 4-alkylphenol and wherein the amount of the alkaline earth metal oxide or hydroxide is about 0.1 to about 4 moles per 1 mole of the 4-alkylphenol.9. The process of wherein the components (a) through (d) are reacted at about 150° C. to about 230° C. for about 2 to about 10 hours.10. The process of wherein the 4-alkylphenol is reacted with at least a portion of the alkaline earth metal oxide or hydroxide and at least a portion of the bridging agent prior to addition of the 2 claim 1 ,6-dialkylphenol.11. The process of wherein claim 10 , in a first step claim 10 , about 0.1 to about 0.4 moles of calcium hydroxide and about 1 to about 3 moles of sulfur (as S) claim 10 , per mole of the 4-alkylphenol claim 10 , are reacted with the 4-alkylphenol at about 170 to about 230° C. for about 3 to about 7 hours claim 10 , ...

METHOD FOR PRODUCING CYCLOMETALATED IRIDIUM COMPLEX, AND NOVEL IRIDIUM COMPOUND PREFERABLY USED FOR THE METHOD

A method for producing a cyclometalated iridium complex by allowing an iridium compound and an aromatic bidentate ligand to react each other. In particular, the method is characterized by allowing a β-diketonate salt represented by General Formula (4) to coexist in a reaction system for reaction. By adding the β-diketonate salt into the reaction system, stability of a reaction intermediate product between the iridium compound and the aromatic bidentate ligand improves. Therefore, yield of the cyclometalated iridium complex can improve. The cyclometalated iridium complex produced in accordance with the present invention is useful as a phosphorescent material for use in an organic EL element, for example.

POROUS POLYMERS FOR THE ABATEMENT AND PURIFICATION OF ELECTRONIC GAS AND THE REMOVAL OF MERCURY FROM HYDROCARBON STREAMS

A porous material, including metal organic frameworks (MOFs) and porous organic polymer (POP), with reactivity with or sorptive affinity towards (a) electronic gas to substantially remove or abate electronic gas in an electronic gas-containing effluent, or (b) contaminants in a stream of electronic gas to substantially remove the contaminants from a stream of electronic gas and increase the purity of said electronic gas, or (c) trace mercury contaminant in a hydrocarbon stream to substantially remove said mercury contaminant and increase the purity of said hydrocarbon stream. MOFs are the coordination product of metal ions and multidentate organic ligands, whereas POPs are the product of polymerization between organic monomers. 1. A material configured for abatement of electronic gases comprising:a metal organic framework (MOF) comprising the coordination product of a plurality of metal clusters, each metal cluster comprising one or more metal ions, and a plurality of multidentate organic ligands that connect adjacent metal clusters, wherein the one or more metal ions and the organic ligand are selected to provide reactivity with or sorptive affinity toward electronic gas to substantially remove or abate electronic gas in an electronic gas-containing effluent; ora porous organic polymer (POP) comprising a polymerization product from at least a plurality of organic monomers, wherein the organic monomers are selected to provide reactivity with or sorptive affinity towards electronic gas to substantially remove or abate electronic gas in an electronic gas-containing effluent.2. The material of claim 1 , wherein the MOF or POP reacts with an electronic gas through a reaction mechanism of at least one of oxidation claim 1 , reduction claim 1 , hydrolysis claim 1 , or formation of dative bond claim 1 , and combinations thereof.3. The material of claim 1 , wherein the MOF or POP encapsulates chemical specie that are reactive towards the electronic gas.4. The material of ...

ORGANICALLY MODIFIED METAL OXIDE NANOPARTICLES, ORGANICALLY MODIFIED METAL OXIDE NANOPARTICLES-CONTAINING SOLUTION, ORGANICALLY MODIFIED METAL OXIDE NANOPARTICLES-CONTAINING RESIST COMPOSITION, AND RESIST PATTERN FORMING METHOD

Organically modified metal oxide nanoparticles containing two or more cores including a plurality of metal atoms and a plurality of oxygen atoms covalently bonded to the plurality of metal atoms; a first modifying group that is a ligand coordinated to each of the cores and selected from the group consisting of a carboxylic acid carboxylate, a sulfonic acid sulfonate, and a phosphonic acid phosphonate; and a second modifying group that is coordinated to each of the cores and is a ligand having a structure different from that of the first modifying group and/or an inorganic anion, in which organically modified metal oxide nanoparticles have a structure in which the cores are crosslinked through a coordinate bond by at least the first modifying group. 1. Organically modified metal oxide nanoparticles comprising:two or more cores including a plurality of metal atoms and a plurality of oxygen atoms covalently bonded to the plurality of metal atoms;a first modifying group (A1) that is a ligand coordinated to each of the cores and selected from the group consisting of a carboxylic acid carboxylate, a sulfonic acid sulfonate, and a phosphonic acid phosphonate; anda second modifying group (A2) that is coordinated to each of the cores and is at least one selected from the group consisting of a ligand having a structure different from that of the first modifying group (A1) and an inorganic anion,wherein the organically modified metal oxide nanoparticle has a structure in which the cores are crosslinked through a coordinate bond by at least the first modifying group (A1).3. The organically modified metal oxide nanoparticles according to claim 1 , wherein the first modifying group (A1) is a carboxylic acid carboxylate ligand.4. The organically modified metal oxide nanoparticles according to claim 1 , wherein the first modifying group (A1) is a carboxylic acid carboxylate ligand; andthe second modifying group (A2) is selected from the group consisting of a carboxylic acid ...

A METHOD FOR PRODUCING A NANOSTRUCTURED COMPLEX (CFI-1), A PROTEIN-ASSOCIATED NANOSTRUCTURED COMPLEX (MRB-CFI-1) AND USE

Disclosed is a method of obtaining an inorganic nanostructured complex (CFI-1), a protein-associated nanostructured complex (MRB-CFI-1) and antitumor use. The main use is in treating urinary bladder cancer, both in animals arid humans. The complex has singular antitumor activity, and can potentially be used as a substitute and/or act as an adjuvant for other commercial antineoplastic drugs. 1: A process of obtaining a nanostructured complex (CFI-1) , by chemical synthesis , comprising the following steps:(a) Preparing ammonium phosphate dibasic [(NH4)2HPO4] in situ in the presence of ammonia and orthophosphoric acid, in a mechanical homogenizer with a minimum power of 500 W, at a temperature range between 25 and 55° C. up to neutralization;(b) Mixing two salts: magnesium chloride, at 1-3% (by mass) and the ammonium phosphate dibasic obtained in step (a) at concentration of 1-4% (by mass) and at a temperature between 22 and 30° C., preferably at 25° C. and pH 5-7, preferably 6, in a mechanical homogenizer with a minimum power of 500 W in a variable rotation range between 7000 and 15000 rpm, preferably 10000 rpm;(c) Applying a pressure level to the mixture obtained in step (b) in a high pressure homogenizer with a homogenization valve with variable pressure between 400 and 700 bar, preferably 600 bar, and in the second stage, the homogenizing valve with variable pressure between 50 and 70 bar, preferably 60 bar, for up to 1 to 3 cycles, preferably 2 cycles;(d) Cooling the suspension obtained at step (c) to a temperature of between 0 and 20° C., preferably 15° C.;(e) Precipitating crystals from the suspension obtained in step (d); and(f) Washing the crystals obtained in step (e) with distilled and sterile water and drying at a temperature between 30 and 40° C., preferably at 37° C., for a time between 24 and 72 hours, preferably 48 hours.2: The process claim 1 , according to claim 1 ,(a) is performed in a ultra-turrax mechanical homogenizer for a time between 20 and 30 ...

Strontium precursor, method for preparing same, and method for forming thin film by using same

Disclosed herein is a novel strontium precursor containing a beta-diketonate compound. Being superior in thermal stability and volatility, the strontium precursor can form a quality strontium thin film.

COMPLEX AND PROCESS FOR PREPARING COMPLEX

An object of the present invention is to provide a novel complex having at least one carbon-carbon double bond and/or carbon-carbon triple bond. The present invention provides a complex represented by formula (1): 1. A complex represented by a formula (1):{'br': None, 'sub': 8', '5', '2', 'n, '((RCOO)M(OH))\u2003\u2003(1)'}wherein in the formula (1), M is a metal atom, R is a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, an alkenyl group having 2 to 18 carbon atoms or an alkynyl group having 2 to 18 carbon atoms, a plurality of R may be identical to or different from each other, at least one of R is the alkenyl group having 2 to 18 carbon atoms or the alkynyl group having 2 to 18 carbon atoms, and n is an integer of 1 or more.2. The complex according to claim 1 , wherein in the formula (1) claim 1 , at least one of R is an alkenyl group having 2 to 8 carbon atoms and a carbon-carbon double bond at a terminal thereof claim 1 , or an alkynyl group having 2 to 8 carbon atoms and a carbon-carbon triple bond at a terminal thereof.3. The complex according to claim 1 , wherein the metal atom M is at least one metal atom selected from the group consisting of zinc claim 1 , beryllium claim 1 , lead claim 1 , magnesium claim 1 , nickel and copper.4. The complex according to claim 1 , wherein the metal atom M is zinc claim 1 , and R is —CH═CHor —C(CH)═CH.7. The complex according to claim 5 , wherein Mto Mare at least one metal atom selected from the group consisting of zinc claim 5 , beryllium claim 5 , lead claim 5 , magnesium claim 5 , nickel and copper.8. The complex according to claim 5 , wherein Rto Rare identical to or different from each other and represent the alkenyl group having 2 to 18 carbon atoms or the alkynyl group having 2 to 18 carbon atoms.9. The complex according to claim 5 , wherein Mto Mare zinc claim 5 , and Rto Rare —CH═CHor —C(CH)═CH.10. A process of preparing a complex claim 5 , comprising a step of reacting a compound represented by a ...

EUTECTIC SALTS

Some embodiments include a molten salt system comprising a reactor with a salt mixture. In some embodiments, the salt mixture includes uranium and a eutectic salt. The eutectic salt may include one or more of sodium fluoride, potassium fluoride, aluminum fluoride, zirconium fluoride, lithium fluoride, beryllium fluoride, rubidium fluoride, magnesium fluoride, calcium fluoride, sodium chloride, potassium chloride, aluminum chloride, zirconium chloride, lithium chloride, beryllium chloride, rubidium chloride, magnesium chloride, and calcium chloride. The eutectic salt may have a melting point less than about 800° C. 1. A eutectic salt comprising: uranium, and', 'one or more salts selected from the group consisting of sodium fluoride, potassium fluoride, aluminum fluoride, zirconium fluoride, lithium fluoride, beryllium fluoride, rubidium fluoride, magnesium fluoride, calcium fluoride, sodium chloride, potassium chloride, aluminum chloride, zirconium chloride, lithium chloride, beryllium chloride, rubidium chloride, magnesium chloride, and calcium chloride;, 'a salt mixture comprisingwherein the eutectic salt has a melting point less than about 800° C.2. The eutectic salt according to claim 1 , wherein the salt mixture comprises uranium fluoride.3. The eutectic salt according to claim 1 , wherein the salt mixture comprises uranium chloride.4. The eutectic salt according to claim 1 , wherein the salt mixture comprises sodium fluoride and potassium fluoride.5. The eutectic salt according to claim 1 , wherein the salt mixture comprises sodium fluoride with a molarity of 40-60 mol % and potassium fluoride with a molarity of 40-60 mol %.6. The eutectic salt according to claim 1 , wherein the salt mixture comprises sodium fluoride claim 1 , potassium fluoride claim 1 , and magnesium fluoride.7. The eutectic salt according to claim 1 , wherein the salt mixture comprises sodium fluoride with a molarity of 40-60 mol % claim 1 , potassium fluoride with a molarity of 40-70 mol % ...

ENHANCED SURFACTANT POLYMER FLOODING PROCESSES FOR OIL RECOVERY IN CARBONATE RESERVOIRS

A composition for use in surfactant polymer flooding processes in a carbonate reservoir, the composition comprising a surfactant, the surfactant operable to reduce interfacial tension, a polymer, the polymer operable to increase the viscosity of the composition, and a tailored water, the tailored water operable to alter a wettability of the in-situ rock, where the tailored water has a total dissolved solids of between 5,000 wt ppm and 7,000 wt ppm, where the total dissolved solids comprises a salt, where the composition has a viscosity between 3 cP and 100 cP. 1. A composition for use in surfactant polymer flooding processes in a carbonate reservoir , the composition comprising:a surfactant, the surfactant operable to reduce interfacial tension;a polymer, the polymer operable to increase a viscosity of the composition; and where the tailored water has a total dissolved solids of between 5,000 wt ppm and 7,000 wt ppm,', 'where the composition has a viscosity between 3 cP and 100 cP.', 'where the total dissolved solids comprises a salt,'}], 'a tailored water, the tailored water operable to alter a wettability of in-situ rock in the carbonate reservoir,'}2. The composition of claim 1 , where the surfactant is selected from the group consisting of betaine-type amphoteric surfactants claim 1 , anionic surfactants claim 1 , cationic surfactants claim 1 , non-ionic surfactants claim 1 , biosurfactants claim 1 , and combinations of the same.3. The composition of claim 1 , where the polymer is selected from the group consisting of polyacrylamides claim 1 , partially hydrolyzed polyacrylamides claim 1 , copolymers of acylamide and acrylate claim 1 , copolymers of acrylamide tertiary butyl sulfonate (ATBS) and acrylamides claim 1 , and copolymers of acrylamide claim 1 , acrylic acid and ATBS.4. The composition of claim 1 , where the surfactant is present at a concentration in a range between 0.05 wt % of the tailored water formulation and 2 wt % of the tailored water ...

METHOD FOR ELECTROCHEMICAL TRANSFORMATION OF AMORPHOUS MATERIAL TO CRYSTALLINE MATERIAL

A method for converting amorphous boron nitride to crystalline boron nitride, the method comprising immersing the amorphous boron nitride into anhydrous molten magnesium chloride maintained within a temperature range of 720° C.-820° C. while the amorphous boron nitride is cathodically polarized at a voltage within a range of −2.2V to −2.8V for a period of time of at least 2 minutes to result in conversion of the amorphous boron nitride to the crystalline form. Also described herein is a method for converting an amorphous carbon material to a crystalline carbon material, the method comprising immersing said amorphous carbon material into anhydrous molten magnesium chloride maintained within a temperature range of 780° C.-820° C. while the amorphous carbon material is cathodically polarized at a voltage within a range of −2.2V to −2.8V for a period of time of at least 2 minutes to result in conversion of the amorphous carbon material to the crystalline form. 1. A method for converting amorphous boron nitride to crystalline boron nitride , the method comprising immersing the amorphous boron nitride into anhydrous molten magnesium chloride maintained within a temperature range of 720° C.-820° C. while the amorphous boron nitride is cathodically polarized at a voltage within a range of −2.2V to −2.8V for a sufficient period of time to result in conversion of the amorphous boron nitride to the crystalline boron nitride.2. The method of claim 1 , wherein the crystalline boron nitride is hexagonal boron nitride.3. The method of claim 1 , wherein the anhydrous molten magnesium chloride is maintained within a temperature range of 750° C.-820° C.4. The method of claim 1 , wherein the anhydrous molten magnesium chloride is maintained within a temperature range of 750° C.-800° C.5. The method of claim 1 , wherein the amorphous boron nitride is cathodically polarized at said voltage for a period of time of at least 1 hour.6. The method of claim 1 , wherein the amorphous boron ...

UTILIZATION OF POLLUTANTS FROM INTERNAL COMBUSTION ENGINES

Nitrogen oxides formed in combustion engines are recycled such that the nitrogen oxides can be utilized for producing liquid or solid chemicals. The nitrogen oxides are recycled by a method including an adsorber material adsorbing nitrogen oxides from an exhaust-gas stream of the combustion engine, removing the adsorber material laden with nitrogen oxides, desorbing the adsorbed nitrogen oxides from the adsorber material, and converting the nitrogen oxides desorbed from the adsorber material into liquid or solid nitrogen-containing compounds. 110.-. (canceled)11. A method for the recycling of nitrogen oxides formed in a combustion engine , the method comprising:adsorbing, in an adsorber unit having an adsorber material including at least one zeolite, nitrogen oxides from an exhaust-gas stream of the combustion engineremoving the adsorber unit having the adsorber material laden with nitrogen oxides or removing the adsorber material laden with nitrogen oxides from the adsorber unit;desorbing the adsorbed nitrogen oxides from the adsorber material; andconverting the nitrogen oxides desorbed from the adsorber material into liquid or solid nitrogen-containing compounds.12. The method according to claim 11 , wherein the liquid or solid nitrogen-containing compounds include nitrates.13. The method according to claim 12 , wherein the nitrates include ammonium nitrates.14. The method according to claim 11 , wherein the at least one zeolite includes ZSM-5 claim 11 , zeolite Y claim 11 , or mordenite.15. The method according to claim 11 , whereinthe adsorber unit is an exchangeable cartridge provided in an exhaust tract of the combustion engine, andthe method comprises:removing the adsorber unit from the exhaust tract; andproviding another adsorber unit, having an adsorber material unladen with nitrogen oxides, in the exhaust tract of the combustion engine.16. The method according to claim 11 , whereinthe adsorber material is an exchangeable material provided in a container of ...

METHOD FOR PROVIDING A SUCCINIC ACID SOLUTION

The invention pertains to a method for providing a succinic acid solution, comprising the steps of—providing a first magnesium succinate containing medium with a magnesium succinate concentration of 18-23 wt. % to a first acidification reactor where it is contacted with hydrogen chloride to form a solution of succinic acid, magnesium chloride and hydrogen chloride,—providing a second magnesium succinate containing medium with a magnesium succinate concentration of 25-50 wt. %, and contacting it in a second acidification reactor with the solution of succinic acid, magnesium chloride and hydrogen chloride withdrawn from the first acidification reactor, to form an aqueous mixture comprising magnesium chloride and succinic acid with a succinic acid concentration of at least 18 wt. %. the method according to the invention makes it possible to obtain a solution comprising succinic acid and magnesium 20 chloride with an increased succinic acid concentration. 1. A method for providing a succinic acid solution , comprising the steps of:providing a first magnesium succinate containing medium with a magnesium succinate concentration of 18-23 wt. % to a first acidification reactor where it is contacted with hydrogen chloride to form a solution of succinic acid, magnesium chloride, and hydrogen chloride, andproviding a second magnesium succinate containing medium with a magnesium succinate concentration of 25-50 wt. %, and contacting it in a second acidification reactor with the solution of succinic acid, magnesium chloride, and hydrogen chloride withdrawn from the first acidification reactor, to form an aqueous mixture comprising magnesium chloride and succinic acid with a succinic acid concentration of at least 18 wt. %.2. The method of claim 1 , wherein the first magnesium succinate containing medium and/or the second magnesium succinate containing medium are obtained by subjecting an aqueous magnesium succinate solution with a magnesium succinate concentration in the range ...

METHOD FOR PRODUCING A NANOSTRUCTURED COMPLEX (CFI-1), A PROTEIN-ASSOCIATED NANOSTRUCTURED COMPLEX (MRB-CFI-1) AND USE

Disclosed is a method of obtaining an inorganic nanostructured complex (CFI-1) by chemical synthesis and antitumor use. The main use is in treating cancer, both in animals and humans. The complex has singular antitumor activity, and can potentially be used as a substitute and/or act as an adjuvant for other commercial antineoplastic drugs. 1. A process of obtaining a nanostructured complex (CFI-1) , by chemical synthesis , comprising the following steps:{'sub': 4', '4, '(a) Preparing ammonium phosphate dibasic [(NH)2HPO] in situ in the presence of ammonia and orthophosphoric acid, in a mechanical homogenizer with a minimum power of 500 W, at a temperature range between 25 and 55° C. up to neutralization;'}(b) Mixing two salts: magnesium chloride, at 1-3% (by mass) and the ammonium phosphate dibasic obtained in step (a) at concentration of 1-4% (by mass) and at a temperature between 22 and 30° C., preferably at 25° C. and pH 5-7, preferably 6, in a mechanical homogenizer with a minimum power of 500 W in a variable rotation range between 7000 and 15000 rpm, preferably 10000 rpm;(c) Applying a pressure level to the mixture obtained in step (b) in a high pressure homogenizer with a homogenization valve with variable pressure between 400 and 700 bar, preferably 600 bar, and in the second stage, the homogenizing valve with variable pressure between 50 and 70 bar, preferably 60 bar, for up to 1 to 3 cycles, preferably 2 cycles;(d) Cooling the suspension obtained at step (c) to a temperature of between 0 and 20° C., preferably 15° C.;(e) Precipitating crystals from the suspension obtained in step (d); and(f) Washing the crystals obtained in step (e) with distilled and sterile water and drying at a temperature between 30 and 40° C., preferably at 37° C.,]for a time interval between 24 and 72 hours, preferably 48 hours.2. The process claim 1 , according to claim 1 , wherein step(a) is performed in a ultra-turrax mechanical homogenizer for a time between 20 and 30 minutes.3. ...

METHOD FOR PRODUCING A NANOSTRUCTURED COMPLEX (CFI-1), A PROTEIN-ASSOCIATED NANOSTRUCTURED COMPLEX (MRB-CFI-1) AND USE

Disclosed is a method of obtaining a protein-associated nanostructured complex (MRB-CFI-1) by chemical synthesis and antitumor use. The main use is in treating cancer, both in animals and humans. The complex has singular antitumor activity, and can potentially be used as a substitute and/or act as an adjuvant for other commercial antineoplastic drugs. 1. A process of obtaining a protein-associated nanostructured complex (MRB-CFI-1) , by chemical synthesis comprising the steps of:{'sub': 4', '4, '(a) Preparing ammonium phosphate dibasic [(NH)2HPO] in situ in the presence of ammonia and orthophosphoric acid, in a mechanical homogenizer with a minimum power of 500 W, at a temperature between 25 and 55° C. up to neutralization;'}(b) Mixing two salts: magnesium chloride, at 1-3% (by mass) and the ammonium phosphate dibasic obtained in step (a) at a concentration of 1-4% (by mass) and at a temperature between 22 and 30° C., preferably at 25° C. and pH 5-7, preferably 6, in a mechanical homogenizer in a variable rotation speed between 7000 and 15000 rpm, preferably 10000 rpm to form a complex;(c) Adding protein in a concentration of 0.5 to 1.5% (mass/mass) to the complex obtained in step (b);(d) Applying a pressure level to the mixture obtained in step (c) in a high pressure homogenizer with a homogenization valve with variable pressure between 400 and 700 bar, preferably 600 bar, and in the second stage, the homogenizing valve with variable pressure between 50 and 70 bar, preferably 60 bar, for up to 1 to 3 cycles, preferably 2 cycles;(e) Cooling the suspension obtained at step (c) to a temperature range comprised between 0 and 20° C., preferably 15° C.;(f) Precipitating crystals from the suspension obtained in step (e); and(g) Washing the crystals obtained in step (f) with distilled and sterile water and drying at a temperature between 30 and 40° C., preferably at 37° C., for a time interval between 24 and 72 hours, preferably 48 hours.2. The process claim 1 , according ...

METHOD FOR PRODUCING A NANOSTRUCTURED COMPLEX (CFI-1), A PROTEIN-ASSOCIATED NANOSTRUCTURED COMPLEX (MRB-CFI-1) AND USE

Disclosed is a method for treating cancer in a subject by administering to the subject a compound selected from NHMgPO×6HO, (NH)2MgH(PO)×4HO, (NH)2Mg(HPO)×8HO and NHMgPO×HO associated or not to hydrolytic enzymes, which are known to have immunomodulatory activities. 1. A method for treating cancer in a subject , the method comprising administering to the subject a compound selected from the group consisting of NHMgPO×6 HO , (NH)2MgH(PO)×4HO , (NH)2Mg(HPO)×8HO and NHMgPO×HO associated or not to hydrolytic enzymes , which are known to have immunomodulatory activities.2. The method according to claim 1 , wherein the cancer is prostate claim 1 , bladder claim 1 , colorectal claim 1 , mastocytoma or lymphoma cancer.3. The method according to claim 1 , wherein the compound is administered in a pharmaceutically acceptable carrier therefor. This application is a divisional application of U.S. patent application Ser. No. 16/617,493, filed Nov. 26, 2019, the contents of which are incorporated herein by reference.The present invention refers to a process of obtaining an inorganic nanostructured complex (CFI-1), a protein-associated nanostructured complex (MRB-CFI-1) and use.The main technology application is the treatment of urinary bladder cancer, both in animals and in humans. Its antitumor activity is unique and a potentially substitute for other commercial antineoplastic drugs.All organs of the urogenital tract are potential spots for malignant tumors. The incidence and type vary from organ to organ. Urinary bladder cancer (CB) represents the second most common malignant disease of the urinary tract (Siegel et al., 2012; American Cancer Society, 2016).The American Cancer Society estimated about 76,960 new cases of CB in 2016 in the United States, being 58,950 in men and 18,010 in women. The estimate also predicted 16,390 deaths due to CB, being 11,820 in men and 4,570 in women (American Cancer Society, 2016). According to data from the National Cancer Institute (INCA, 2016 ...

BETA-KETOIMINE LIGAND, METHOD OF PREPARING THE SAME, METAL COMPLEX COMPRISING THE SAME AND METHOD OF FORMING THIN FILM USING THE SAME

The β-ketoimine ligand is represented by the following formula 1: 18-. (canceled)10. The metal complex compound as claimed in claim 9 , wherein the metal is strontium.11. The metal complex compound as claimed in claim 9 , wherein Rand Rare each independently a methyl group or an ethyl group.13. A metal precursor for forming a metal thin film claim 9 , the metal precursor including a metal complex compound as claimed in .14. The metal precursor as claimed in claim 13 , wherein the metal is strontium.1520-. (canceled) This is a divisional application based on pending application Ser. No. 13/435,760, filed Mar. 30, 2012, the entire contents of which is hereby incorporated by reference.This application is based on and claims priority from Korean Patent Application No. 10-2011-0030224, filed on Apr. 1, 2011 in the Korean Intellectual Property Office, the disclosure of which is incorporated herein in its entirety by reference.1. FieldEmbodiments relate to a β-ketoimine ligand, a method of preparing the same, a metal complex compound comprising the same and a method of forming a thin film using the same.2. Description of the Related ArtAmong thin film fabrication techniques, a metal organic chemical vapor deposition (MOCVD) process is used to fabricate various thin films. The MOCVD is advantageous in that it uses a relatively simple system, provides uniform step coverage, makes it easy to control components and is suitable for the fabrication of large-area thin films. In order to fabricate thin films using the MOCVD process, the development of precursors to be used in this process is desirable.According to an embodiment, there is provided a β-ketoimine compound represented by the following Formula 1:wherein Rand Rare each independently a C-Calkyl group.Rand Rmay each independently be a methyl group or an ethyl group.According to an embodiment, there is provided a method for preparing a β-ketoimine compound, the method including synthesizing an ether ester by converting a ...

UTILIZATION OF NITROGEN OXIDES FROM AMBIENT AIR

Utilization of nitrogen oxides contained in the ambient air including a system and a method with which the nitrogen oxides can be utilized for the production of liquid or solid chemicals. 110-. (canceled)11. A method for the utilization of nitrogen oxides contained in the ambient air , comprising the adsorption of nitrogen oxides from the ambient air in a stationary adsorbent unit which contains an adsorbent material , removing the adsorbent material loaded with nitrogen oxides from the adsorbent unit , collecting and temporarily storing the adsorbent material loaded with nitrogen oxides at a collecting site , transferring the adsorbent material loaded with nitrogen oxides to a desorption module , desorption of adsorbed nitrogen oxides from the adsorbent material and conversion of the nitrogen oxides into liquid or solid nitrogenous compounds.12. The method according to claim 11 , wherein the adsorbent material comprises at least one zeolite.13. The method according to claim 11 , wherein the liquid or solid nitrogenous compounds comprise nitrates.14. The method according to claim 13 , wherein the nitrogen oxides in the reaction unit are first converted into nitrous acid and the nitrous acid is then converted into nitrates.15. A system for the utilization of nitrogen oxides claim 13 , comprising a stationary adsorbent unit which is adapted for the adsorption of nitrogen oxides from the ambient air claim 13 , wherein the stationary adsorbent unit has a housing with at least one inflow and outflow opening in the housing wall claim 13 , a filter module in the interior of the housing which is fluidly connected to the inlet and outlet opening so that an air channel is formed claim 13 , and an air intake apparatus in order to draw air from the ambient air and to guide it through the filter module claim 13 , and wherein the adsorbent unit contains an adsorbent material which is adapted to bind nitrogen oxides in an adsorptive manner claim 13 , and the adsorbent unit is ...

ZIRCONIUM-BASED METAL-ORGANIC FRAMEWORK MATERIAL UIO-66(ZR), RAPID ROOM-TEMPERATURE PREPARATION METHOD AND APPLICATION THEREOF

A zirconium-based metal-organic framework material UiO-66(Zr) and a rapid room-temperature preparation method and application thereof are procided. The preparation method includes: (1) mixing a zirconium source and an organic ligand uniformly, then placing in methanol and stirring at room temperature, centrifuging and then discarding a supernatant to obtain a transparent gel-like intermediate product; and (2) heating and drying the intermediate product to obtain UiO-66(Zr). Compared with the prior art, the present invention excludes the use of N,N-dimethylformamide and other toxic organic solvents that are necessary in the traditional solvothermal method, and only needs to stir in methanol at room temperature and dry to obtain UiO-66(Zr). The method has mild conditions and a high yield. Moreover, the product purity is extremely high, and the product activation step can be omitted. The product has good adsorption to fluoride ion in water, and can be applied to the adsorption treatment of fluorine-containing wastewater. 1. A rapid room-temperature preparation method of a zirconium-based metal-organic framework material UiO-66(Zr) , comprising the following steps:(1) mixing a zirconium source and an organic ligand uniformly to obtain a mixture, then placing the mixture in methanol to obtain a mixed solution and stirring the mixed solution at room temperature, centrifuging the mixed solution to obtain a centrifuged product and then discarding a supernatant of the centrifuged product to obtain a transparent gel-like intermediate product; and(2) heating and drying the transparent gel-like intermediate product obtained in step (1) to obtain the zirconium-based metal-organic framework material UiO-66(Zr);wherein the zirconium source is zirconium oxychloride octahydrate.2. (canceled)3. The rapid room-temperature preparation method of the zirconium-based metal-organic framework material UiO-66(Zr) according to claim 1 , wherein the organic ligand is one selected from the ...

AGENTS AND METHODS FOR THE TEMPORARY SHAPING OF KERATIN-CONTAINING FIBERS

The invention relates to a cosmetic product, comprising a) a cosmetic preparation, including, in relation to its total weight, a1) 65 to 96 wt % of at least one polar solvent; a2) 0.1 to 34 wt % of at least one inorganic salt; b) a device for flash evaporation of the cosmetic preparation a), and to a method using corresponding products and to the use of the cosmetic preparation a) as process material in a device for flash evaporation.

COMPOSITIONS AND METHODS FOR SELECTIVE SEPARATION OF HYDROCARBON ISOMERS

The present disclosure relates to novel metal-organic frameworks (MOFs) comprising tetratopic linkers with small pore apertures. In certain aspects, the disclosure provides Zr-MOFs, non-limiting examples include Zr(bptc), Zr(abtc), and Zr(tptc-(Me)). The present disclosure further relates to methods of utilizing the MOFs of the disclosure to separate hydrocarbons through adsorptive processes. The present disclosure further relates to the discovery that Ca(Htcpb) metal-organic framework (MOF) is capable of separating hydrocarbon isomers from one another through adsorptive processes. In one aspect, the disclosure provides a method of separating C5-C8 hydrocarbon isomers, such that straight chain, mono-branched, and/or multi-branched isomers are each separated from one another. This separation is achieved by taking advantage of the temperature dependent adsorptive properties of Ca(Htcpb) MOF. 2. The metal-organic framework of claim 1 , wherein M is a metal selected from the group consisting of Zr claim 1 , H and Ti.3. The metal-organic framework of claim 1 , wherein M is Zr.4. The metal-organic framework of claim 1 , wherein M is in the form of a (M)cluster.5. The metal-organic framework of claim 4 , wherein the (M)cluster (i) comprises at least one μ-O bridging ligand claim 4 , at least one μ-OH bridging ligand claim 4 , and at least one formate bridging ligand claim 4 , or (ii) is bound to 12 claim 4 , 8 claim 4 , or 4 tetratopic organic linkers of formula (I).6. (canceled)8. The metal-organic framework of claim 1 , wherein the framework has at least one of the following characteristics:(i) has a topology selected from the group consisting of ftw, scu and lvt,(ii) crystallizes in a space group selected from the group consisting of space group Im3, space group C2/m, and space group Imma,{'sup': 2', '2, '(iii) has a Brunauer-Emmett-Teller (BET) surface area from about 1,000 m/g to about 1,500 m/g,'}{'sup': 2', '2, '(iv) has a micropore volume from about 0.35 cm/g to ...

PROCESSES FOR PREPARING ALUMINA AND VARIOUS OTHER PRODUCTS

There are provided processes for preparing alumina. These processes can comprise leaching an aluminum-containing material with HCl so as to obtain a leachate comprising aluminum ions and a solid, and separating said solid from said leachate; reacting said leachate with HCl so as to obtain a liquid and a precipitate comprising said aluminum ions in the form of AlCl, and separating said precipitate from said liquid; and heating said precipitate under conditions effective for converting AlClinto AlOand optionally recovering gaseous HCl so-produced. These processes can also be used for preparing various other products such as hematite, MgO, silica and oxides of various metals, sulphates and chlorides of various metals, as well as rare earth elements, rare metals and aluminum. 1. A process for preparing alumina , said process comprising:leaching an aluminum-containing material with HCl so as to obtain a leachate comprising aluminum ions and a solid, and separating said solid from said leachate;{'sub': '3', 'reacting said leachate with HCl so as to obtain a liquid and a precipitate comprising said aluminum ions in the form of AlCl, and separating said precipitate from said liquid; and'}{'sub': 3', '2', '3, 'heating said precipitate under conditions effective for converting AlClinto AlOand optionally recovering gaseous HCl so-produced.'}2. The process of claim 1 , wherein said liquid comprises at least one iron chloride.3. The process of claim 2 , wherein said at least one iron chloride is FeCl claim 2 , FeClor a mixture thereof.4. The process of claim 3 , wherein said liquid is concentrated to a concentrated liquid having a concentration of said at least one iron chloride of at least 30% by weight; and then hydrolyzed at a temperature of about 155 to about 350° C.5. The process of claim 3 , wherein said liquid is concentrated to a concentrated liquid having a concentration of said at least one iron iron chloride of at least 30% by weight; and then said at least one iron ...

CARBOXYLIC ACID RECOVERY FROM MAGNESIUM CARBOXYLATE MIXTURE

The invention is directed to a method for recovering carboyxlic acid from an magnesium carboxylate containing aqueous mixture, including the steps of: contacting the aqueous mixture with an acidic ion exchanger, thereby forming a carboxylic acid mixture and an ion exchanger loaded with magnesium ions; contacting the ion exchanger loaded with magnesium ions with a hydrochloric acid solution, thereby forming a magnesium chloride solution; and thermally decomposing the magnesium chloride solution at a temperature of at least 300° C., thereby forming magnesium oxide (MgO) and hydrogen chloride (HCl). 1. Method for recovering carboyxlic acid from a magnesium carboxylate containing aqueous mixture , comprising the steps ofcontacting the aqueous mixture with an acidic ion exchanger, thereby forming a carboxylic acid mixture and an ion exchanger loaded with magnesium ions; andcontacting the ion exchanger loaded with magnesium ions with a hydrochloric acid solution, thereby forming a magnesium chloride solution; andthermally decomposing the magnesium chloride solution at a temperature of at least 300° C., thereby forming magnesium oxide (MgO) and hydrogen chloride (HCl).2. Method according to claim 1 , further comprisingdissolving the HCl in water, thereby obtaining a HCl solution; and{'sub': '2', 'bringing the MgO in contact with water, thereby obtaining Mg(OH).'}3. Method according to claim 2 , wherein the HCl solution is recycled for use in contacting the ion exchanger loaded with magnesium ions.4. Method according to claim 1 , wherein MgO and/or Mg(OH)is recycled for use in a fermentation process.5. Method according to claim 1 , wherein at least part of the carboxylic acid mixture is fed back to the aqueous mixture.6. Method according to claim 1 , wherein the ion exchanger loaded with magnesium ions is washed with water before contacting it with the hydrochloric acid solution.7. Method according to claim 1 , wherein the acidic ion exchanger is strongly acidic and ...

Acid/salt separation

The invention provides a method for preparing a carboxylic acid, which method includes the steps of providing magnesium carboxylate, wherein the carboxylic acid corresponding with the carboxylate has a solubility in water at 20° C. of 80 g/100 g water or less; acidifying the magnesium carboxylate with HCl, thereby obtaining a solution comprising carboxylic acid and magnesium chloride (MgCl 2 ); optionally a concentration step, wherein the solution comprising carboxylic acid and MgCl 2 is concentrated; precipitating the carboxylic acid from the solution comprising the carboxylic acid and MgCl 2 , thereby obtaining a carboxylic acid precipitate and a MgCl 2 solution.

CARBON DIOXIDE SEQUESTRATION WITH MAGNESIUM HYDROXIDE AND REGENERATION OF MAGNESIUM HYDROXIDE

Embodiments of the present disclosure are directed to systems and methods of removing carbon dioxide from a gaseous stream using magnesium hydroxide and then regenerating the magnesium hydroxide. In some embodiments, the systems and methods can further comprise using the waste heat from one or more gas streams to provide some or all of the heat needed to drive the reactions. In some embodiments, magnesium chloride is primarily in the form of magnesium chloride dihydrate and is fed to a decomposition reactor to generate magnesium hydroxychloride, which is in turn fed to a second decomposition reactor to generate magnesium hydroxide. 134.-. (canceled)35. A system for regenerating Mg(OH)in a process that reduces the amount of COcontained in a gas stream , comprising:{'sub': 2', '2', '2, 'a first decomposition reactor configured to react MgClcontaining material with steam to form first reactor products comprising Mg(OH)Cl and HCl, where the MgClcontaining material comprises a water to MgClratio of less than about 2.5:1;'}{'sub': '2', 'a second decomposition reactor configured to react Mg(OH)Cl from the first decomposition reactor with steam to form HCl and magnesium-containing products comprising mostly Mg(OH);'}{'sub': 2', '2', '2', '2', '3, 'a first absorption reactor configured to react Mg(OH)from the second decomposition reactor with CO, CaCl, and steam to form products comprising MgCland CaCO.'}36. The system of claim 35 , further comprising a gaseous feed line configured to pass a gaseous outflow from the second decomposition reactor to the first decomposition reactor claim 35 , where the gaseous outflow comprises HCl and steam to react with the MgClcontaining material.37. The system of claim 35 , further comprising a second absorption reactor claim 35 , wherein{'sub': 2', '2', '3', '2, 'the first absorption reactor is configured to admix Mg(OH)from the second decomposition reactor with COcontained in the gas stream and form MgCOand HO, and'}{'sub': 3', '2', '3', ...

Provision of inorganic powders with reduced hazard

Provision of inorganic powders with reduced hazard: acid chlorides which have use in polymer production can be incorporated into a masterbatch with the addition of a silane compound to reduce the corrosiveness of the masterbatch pellets and reduce variability of pellet size. This presents advantages in transport and handling costs and facilitates downstream processing.

Synthesis of Magnesium Dichloride Support For The AST Off-Line ZN Catalyst With a Plug Flow Reactor (PFR)

The various embodiments of the invention provide, a magnesium dichloride support and the magnesium titanium polymerization procatalyst made therefrom, and methods for making and using the same. 127-. (canceled)28. A method of making MgClcomprising{'sub': 2', '5-12', '2-8, 'combining MgRand reactive organic chloride or HCl and a solvent chosen from Calkanes in a PFR reactor, wherein each R is independently chosen from Calkyl radicals; and'}{'sub': '2', 'operating the reactor at conditions sufficient to create a disordered form of MgCl.'}29. The method of wherein the disordered form of MgClis characterized by having a peak in the GADDS spectrum at 15 2theta with a FWHM that is at least 10% greater than the FWHM of the peak at 15 2theta for MgClprepared in a STR.30. The method of wherein the disordered form of MgClis characterized by having a peak in the GADDS spectrum at 15 2theta with a FWHM that is at least 20% greater than the FWHM of the peak at 15 2theta for MgClprepared in a STR.31. The method of wherein the mole ratio of added Cl from the organic chloride or HCl and Mg from the MgRis from about 2.0 to about 3.0.32. The method of wherein the reactive organic chloride is tertiary-butylchloride (BuCl).33. The method of wherein RMg is chosen from butylethyl magnesium (BEM) claim 28 , dibutyl magnesium claim 28 , and butyloctyl magnesium (BOM).34. The method of wherein the solvent is selected from selected from Calkanes.35. The method of wherein the solvent is isohexane claim 28 , cyclohexane claim 28 , or decane.36. The method of wherein the Cl/Mg mole ratio is from about 2.15 to about 2.5.37. The method of wherein a STR is used in combination with the PFR.38. The method of wherein the PFR feeds into the STR.39. A method for making a Ziegler Natta catalyst comprising{'sub': 2', '5-12', '2-8, 'combining MgRand reactive organic chloride or HCl and a solvent chosen from Calkanes in a PFR reactor, wherein each R is independently chosen from Calkyl radicals;'}{'sub': '2 ...

Metal Compositions and Methods of Making Same

The present disclosure relates to a process for forming a refined metal-containing unit by reducing yield impurities with acidified deionized water. Another embodiment is a composition comprising the refined metal-containing unit. Yet another embodiment is a process for forming a patterned substrate by depositing a composition comprising the refined metal-containing unit on a substrate, drying the film comprising the refined metal-containing unit, exposing the film comprising the refined metal-containing composition to a source of actinic radiation, and transferring the pattern to substrate. The disclosed embodiments are useful in producing patterned substrates by direct or indirect pattern transfer from films comprising the refined metal-containing unit. 2. The process of wherein the MU is dissolved in a water miscible organic solvent and during step d the RMU is isolated as a precipitate.3. (canceled)4. The process of claim 1 , wherein the MU is dissolved in a water immiscible organic solvent claim 1 , and during step d the RMU is isolated as a solution by separating the MU solution from the acidified solution of deionized water in distinct layers claim 1 , and discarding the layer containing the acidified solution of deionized water.5. (canceled)6. (canceled)7. The process of wherein the isolated RMU contains yield impurities claim 1 , and the amount of each yield impurity in the isolated RMU is below 5000 parts per billion based on the total weight of the RMU.8. A composition comprising a refined metal-containing unit (RMU) comprising at least one member selected from the group consisting of a unit represented by Structure I{'br': None, 'sub': w', 'x', 'y, 'MABC\u2003\u2003Structure I'}{'sup': 1', '1, 'where M comprises at least one metal selected from the group consisting of Zr, Hf, Ge, Ti, Nb, Pb, Gd, Sn, Ce, Eu, In, Nd, Sb, Ga, Se, Cd, Ta, Co, Pt, Au, W, V, TI, Te, Sr, Sm, La, Er, Pd, In, Ba, As and Y; Ligand A contains a reactive functional group capable of ...

COMPLEX AND PROCESS FOR PREPARING COMPLEX

An object of the present invention is to provide a novel complex having at least two carbon-carbon double bonds and/or carbon-carbon triple bonds. The present invention provides a complex represented by a structural formula (2): 1. A complex represented by a formula (1):{'br': None, 'sub': 4', '6', 'n, '[MO(RCOO)]\u2003\u2003(1)'}wherein in the formula (1), M is a metal atom, and R is a hydrogen atom, an alkyl group having 1 to 24 carbon atoms, an alkenyl group having 2 to 18 carbon atoms or an alkynyl group having 2 to 18 carbon atoms; and in the formula (1), a plurality of R may be identical to or different from each other, at least two of R are the alkenyl group having 2 to 18 carbon atoms or the alkynyl group having 2 to 18 carbon atoms, at least one of R is the alkyl group having 6 to 24 carbon atoms, and n is an integer of 1 to 8.2. The complex according to claim 1 , wherein in the formula (1) claim 1 , at least four of R are the alkenyl group having 2 to 18 carbon atoms or the alkynyl group having 2 to 18 carbon atoms claim 1 , and the rest of R is the alkyl group having 6 to 24 carbon atoms.4. The complex according to claim 3 , wherein Mto Mare at least one metal atom selected from the group consisting of zinc claim 3 , beryllium claim 3 , lead claim 3 , magnesium claim 3 , nickel and copper.5. The complex according to claim 3 , wherein at least four of Rto Rare the alkenyl group having 2 to 18 carbon atoms or the alkynyl group having 2 to 18 carbon atoms claim 3 , and the rest of Rto Ris the alkyl group having 6 to 24 carbon atoms.6. The complex according to claim 3 , wherein Mto Mare zinc claim 3 , at least two of Rto Rare —CH═CHor —C(CH)═CH claim 3 , and at least one of Rto Ris an alkyl group selected from the group consisting of heptyl group claim 3 , octyl group claim 3 , nonyl group claim 3 , decyl group claim 3 , undecyl group claim 3 , dodecyl group claim 3 , tridecyl group claim 3 , tetradecyl group claim 3 , pentadecyl group claim 3 , hexadecyl ...

Process to produce polymers from pyridyldiamido transition metal complexes and use thereof

Processes to produce ethylene copolymers using pyridyldiamido transition metal complexes, a chain transfer agent, and an activator are disclosed.

Preparation of metal amide complexes

A process for the preparation of a Group 4 metal amide complex comprising a monovalent or divalent Lewis base ligand the steps of the process comprising contacting a Group 4 metal amide with a neutral source of a monovalent or divalent, Lewis base ligand group and a solid Lewis acid scavenging agent under amine elimination conditions to form a Group 4 metal amide complex containing at least one less amide group per metal moiety than the initial Group 4 metal amide.

Method of preparing alkoxy-magnesium halides

It has surprisingly now been discovered that alkoxy-magnesium halides of the general formula ROMgX wherein R is an alkyl having from about 1 to 18 carbon atoms and X is a halide can be synthesized in an inert hydrocarbon in just one step process by reacting magnesium which has been preliminarily activated with small quantities (approximately 5 mol %) of magnesium alkyl with a substantially equimolar mixture of an alkyl halide and an alkanol. That is, the present invention provides a one step reaction process for preparing alkoxy-magnesium halides. This one step reaction process involves reacting magnesium metal which has been previously activated with a magnesium-alkyl compound, with an equimolar mixture of an alkyl halide and an alkanol. Yields in excess of 90% can be obtained by employing the inventive one step reaction process.

Synthesis of magnesium dichloride support for the ast off-line zn catalyst with a plug flow reactor (pfr)

The various embodiments of the invention provide, a magnesium dichloride support and the magnesium titanium polymerization procatalyst made therefrom, and methods for making and using the same.

Synthesis of magnesium dichloride support for the AST off-line ZN catalyst with a plug flow reactor (PFR)

The various embodiments of the invention provide, a magnesium dichloride support and the magnesium titanium polymerization procatalyst made therefrom, and methods for making and using the same.

Particules de chlorure de magnesium a structure tronc conique, composante catalytique supportee sur ces particules, polyolefines obtenues a partir de cette composante catalytique, procedes de fabrication de ces produits.

Enhanced solubility of magnesium halides and catalysts and polymerization process using same

A magnesium halide composition comprising and/or made from a magnesium halide, a solvent suitable for an electron donor compound and an electron donor compound. The composition is characterized by enhanced solubility whereby it has a solubility in the solvent that does not decrease as a function of temperature up to the boiling point of the solvent and the solubility of the magnesium halide in the solvent is greater than 0.7 mol/liter. A polymerization catalyst precursor composition can be made from magnesium halide composition by mixing the magnesium halide composition with a transition metal compound.

MAGNESIUM CHLORIDE PARTICLES WITH POLYHEDRAL STRUCTURE, CATALYTIC COMPONENT SUPPORTED ON THESE PARTICLES, METHODS OF MANUFACTURING THESE PRODUCTS AND POLYOLEFINS OBTAINED FROM THIS CATALYTIC COMPONENT.

无水卤化镁溶液和烯烃聚合的钛催化剂组分的制备方法

揭示了一种制备无水卤化镁溶液的方法。根据该方法制备的无水卤化镁几乎不含钙。还揭示了一种用上面方法制备的无水卤化镁制备用于烯烃聚合反应的固体钛催化剂组分的方法。由此方法制备的用于烯烃聚合的固体钛催化剂组分具有高的催化活性。

Production of halide-and alkoxy-containing magnesium compositions

Compositions having the formula X.sub.n Mg(OR).sub.2-n in which X is chloro, bromo or iodo; R is a C 1 -C 10 alkyl group and n is a value from about 0.2 to about 1.9 are produced by a process comprising preparing an alkanol adduct of a magneisum halide, reacting the product of this step with metallic magnesium, and drying the product. The compositions are useful as olefin polymerization catalyst components and supports.

生产氯化镁微粒的方法

MgCl 2 多孔微粒，在显微镜下呈基本规则的六面体或八面体形状。这类浸渗有过渡金属化合物的微粒可用作烯烃聚合的催化组分。

Olefin polymerization catalyst.

Alkanedioxy titanium chelates

Alkanedioxy titanium chelates have the formula: WHEREIN R2 is a radical selected from the group consisting of hydrogen, hydrocarbyl having not more than about 8 carbon atoms, carboxyalkyl and halohydrocarbyl having not more than about 8 carbon atoms and the total number of carbon atoms in the R2 and R6 substituted alkanedioxy radical is not more than about 18, R3 is a radical having not more than about 8 carbon atoms selected from the group consisting of hydrocarbyl, halohydrocarbyl and cyano lower alkyl, R6 can be selected from the same group as R2 and in addition can be halo, cyano, nitro, carboxy ester, acyl and hydrocarbly substituted by halo, cyano, nitro, carboxy ester and acyl, R7 is selected from the group consisting of hydrogen, hydrocarbyl, halohydrocarbyl, acyl, and taken together with R3 can form together with the carbon atoms to which they are attached cyclichydrocarbon substituents and chloro, nitro, acyl, cyano and carboxy ester substituted cyclic hydrocarbon substituents; X is a radical selected from the group consisting of hydrocarbyl, halohydrocarbyl, cyanoalkyl, alkoxy, haloalkoxy, cyanoalkoxy and amino, and n has a value of 0 to 8, and when X is methyl the alkanedioxy substituent is other than an ethanedioxy or a 2,2-dimethyl-1,3-propanedioxy substituent. When mixed with methyltrimethoxysilane and a silanol chainstopped polydiorganosiloxane fluid, these chelates catalyze the cure of the composition to a rubbery solid elastic state when exposed to atmospheric moisture.

Non-metallocenes fixed in a convex manner, process for their preparation and their use in the polymerization of olefins

Die vorliegende Erfindung betrifft ein Verfahren zur Herstellung von speziellen Übergangsmetallverbindungen, neue Übergangsmetallverbindungen und deren Verwendung zur Polymerisation von Olefinen. The present invention relates to a process for the preparation of special transition metal compounds, new transition metal compounds and their use for the polymerization of olefins.

Particules de chlorure de magnesium a structure polyedre, composante catalytique supportee sur ces particules, procedes de fabrication de ces produits et des polyolefines obtenues a partir de cette composante catalytique.

Particules poreuses de MgCl2 se présentant, au microscope, sous la forme de polyèdres sensiblement réguliers à six ou huit faces. Ces particules imprégnées de composé de métal de transition servent de composante catalytique dans la polymérisation des oléfines.

Particules de chlorure de magnesium a structure polyedre, composante catalytique supportee sur ces particules, procedes de fabrication de ces produits et des polyolefines obtenuesa partir de cette composante catalytique

L'invention concerne des particules poreuses de MgCl2 se présentant, au microscope, sous la forme de polyèdres sensiblement réguliers à six ou huit faces, dont les faces deux à deux symétriquement opposées sont sensiblement parallèles et dont deux grandes faces allongées formant la face du dessus et la face du dessous du polyèdre, sont, d'une part, telles que, dans chacune, la plus grande diagonale (D) soit supérieure à la plus petite distance (d) séparant deux côtés opposés, et sont, d'une part, entourées sensiblement perpendiculairement par les autres faces sensiblement rectangulaires formant les cotés dudit polyèdre, la longueur du plus petit côté (e) de chacune desdites faces sensiblement rectangulaires étant inférieure à la plus petite distance (d) séparant les deux côtés opposés des grandes faces allongées. Ces particules imprégnées de composé de métal de transition servent de composante catalytique dans la polymérisation des oléfines.

Process for polymerising ethylene to obtain a polymer with broad molecular weight distribution and process for preparing the catalyst component

Process for the polymerization of ethylene by which is obtained a wide molecular mass spectrum polymer. process for the treatment of the catalytic component

PRECIS DE LA DIVULGATION: L'invention concerne un procédé de polymérisation de l'éthylène ou de copolymérisation de l'éthylène avec une alpha-oléfine, en suspension ou en phase gazeuse, en présence d'un catalyseur constitué d'un cocatalyseur et d'une composante catalytique à base d'au moins Mg, Ti et Cl, la composante catalytique constituée d'au moins un dérivé du magnésium et d'un dérivé chloré du titane sous sa forme III et/ou IV ayant subi, dans une première étape, préalablement à sa mise en oeuvre, un traitement de réduction, le rapport molaire du métal réducteur/titane étant supérieur à 2, et dans une seconde étape un traitement par un composé chloré de métal de transition, ladite composante catalytique étant caractérisée en ce que le dérivé du magnésium se trouve sous la forme MgCl2,MgO. PRECISION OF DISCLOSURE: The invention relates to a polymerization process. ethylene or copolymerization of ethylene with a alpha-olefin, in suspension or in gas phase, in presence of a catalyst consisting of a cocatalyst and a catalytic component based on at least Mg, Ti and Cl, the catalytic component consisting of at least one derivative of magnesium and a chlorinated derivative of titanium in its form III and / or IV having undergone, in a first step, previously to its implementation, a reduction treatment, the ratio molar of the reducing metal / titanium being greater than 2, and in a second step treatment with a chlorinated compound of transition metal, said catalytic component being characterized in that the magnesium derivative is found under the form MgCl2, MgO.

PARTICLES COMPRISING MAGNESIUM CHLORIDE, THE PROCESS FOR OBTAINING THEM AND POLYOLEFIN PARTICLES

Particules de chlorure de magnesium a structure tronconique, composante catalytique supportee sur ces particules, polyolefines obtenues a partir de cette composante catalytique, procedes de fabrication de ce produit

Particules poreuses de MgCl2 se présentant, au microscope, sous la forme de sensiblement deux troncs de cône droit réunis par les plus grandes bases, incurvés, vers l'axe de symétrie perpendiculaire aux bases, à l'intersection de l'enveloppe des troncs de cône avec deux plans orthogonaux passant par ledit axe de symétrie. Ces particules imprégnées de composé de métal de transition servent de composante catalytique dans la polymérisation des oléfines. Les polyoléfines obtenues et plus particulièrement le polyéthylène, le polypropylène et leurs copolymères sont constituées de particules de structure particulière.

Magnesium chloride particles having a polyhedral shape, catalytic composition supported on these particles, process for the preparation of these products and process for obtaining polyolefines using these catalytic compositions

Olefin polymerization catalyst

采用塞流反应器(pfr)的ast离线zn催化剂用二氯化镁载体的合成

本发明的各种实施方案提供二氯化镁载体和从其制成的镁钛聚合主催化剂，和用于制备和使用它们的方法。

Pyridyldiamido transition metal complexes, production and use thereof

Pyridyldiamido transition metal complexes are disclosed for use in alkene polymerization, optionally with chain transfer agent.

Catalyst Compounds and Use Thereof

This invention relates to Group 4 dialkyl compounds supported by a pyridyl-amido-aryl (“PAA”), an anisole-amido-aryl (“AAA”), a phenoxy-amido-pyridyl (“PAPY”), an anisole-amido-phenoxy (“AAP”) or a anisole-amido-phenoxy (“AAP”) tridentate ligand. Such compounds can polymerize olefins, such as ethylene.

Precursors for chemical vapour deposition

Ti, Zr Hf and La precursors for use in MOCVD techniques have a ligand of the general formula OCR 1 (R 2 )CH 2 X, wherein R 1 is H or an alkyl group, R 2 is an optionally substituted alkyl group and X is selected from OR and NR 2 , wherein R is an alkyl group or a substituted alkyl group.

Precursors for chemical vapor deposition

Ti, Zr Hf and La precursors for use in MOCVD techniques have a ligand of the general formula OCR 1 (R 2 )CH 2 X, wherein R 1 is H or an alkyl group, R 2 is an optionally substituted alkyl group and X is selected from OR and NR 2 , wherein R is an alkyl group or a substituted alkyl group.

Catalyst compounds and use thereof

This invention relates to Group 4 dialkyl compounds supported by a pyridyl-amido-aryl (“PAA”), an anisole-amido-aryl (“AAA”), a phenoxy-amido-pyridyl (“PAPY”), an anisole-amido-phenoxy (“AAP”) or a anisole-amido-phenoxy (“AAP”) tridentate ligand. Such compounds can polymerize olefins, such as ethylene.

Pyridyldiamido transition metal complexes, production and use thereof

Modificazione cristallina del cloruro di magnesio anidro

Production of powder catalysts

A process for the production of a magnesium chloride powder for use in a catalyst, the process comprising vaporising magnesium chloride in a plasma torch and quenching the vapour with a liquid containing an electron donor to form a magnesium chloride-based powder catalyst wherein at least 80% by weight of the magnesium chloride is present as the hexagonal phase thereof. The invention also relates to a precursor for such a catalyst.

Magnesium chloride particles with a polyhedral structure, catalytic components supported on these particles, resultant catalyst systems, processes for fabricating these products, and polyolefins obtained from these catalytic components

Porous particles of MgCl 2 having the form of essentially regular polyhedrons with six or eight faces in which the paired symmetrically opposite faces are essentially parallel, two of which faces are large and elongated and form the top face and the bottom face of a polyhedron such that on each of them the longest diagonal (D) is larger than the shortest distance (d) separating two opposite sides, which large elongated faces are surrounded essentially perpendicularly by the other essentially rectangular faces that form the sides of the said polyhedron, the length of the smaller side (e) of each of the said essentially rectangular faces being less than the shortest distance (d) separating the two opposite sides of the large elongated faces, catalytic components supported on the particles, catalyst systems utilizing the catalytic products, process for making the particles, and polyolefins obtained utilizing the catalytic systems.

POLYISOCIANATE COMPOSITIONS AND PROCESS USING THESE COMPOSITIONS

De acuerdo con la invencion, la composicion de poliisocianatos comprende una composicion de titanio, zirconio o hafnio, con preferencia una composicion detitanio o zirconio, siendo dicha composicion un complejo de por lo menos un metal seleccionado del grupo formado por titanio, zirconio y hafnio y un éster deacetoacetato, en el cual la relacion molar de Ti, Zr, o Hf a éster de acetoacetato se encuentra en el rango de 1:2,5 a 1:10 y dicho éster de acetoacetato es unéster de un alcohol que contiene de 1 a 6 átomos de carbono. La invencion también comprende un proceso para aglutinar material lignocelulosico usando dichascomposiciones. According to the invention, the polyisocyanate composition comprises a composition of titanium, zirconium or hafnium, preferably a composition of detitanium or zirconium, said composition being a complex of at least one metal selected from the group consisting of titanium, zirconium and hafnium and an acetoacetate ester, in which the molar ratio of Ti, Zr, or Hf to acetoacetate ester is in the range of 1: 2.5 to 1:10 and said acetoacetate ester is an alcohol ester containing 1 at 6 carbon atoms. The invention also comprises a process for agglutinating lignocellulosic material using said compositions.

Magnesium chloride particles with a truncated structure, catalytic component supported on these particles, polyolefins obtained by employing this catalytic component, procedures for manufacturing these products

Porous particles of MgCl 2 which have essentially the shape of two truncated right cones connected by their larger bases, which truncated cones are incurved towards the axis of symmetry perpendicular to the bases, at the intersection of the envelope of the truncated cones with two orthogonal planes passing through the said axis of symmetry. These particles are impregnated with a transition metal compound and employed as a catalytic component in the polymerization of olefins. The resultant polyolefins, especially polyethylene, polypropylene and their copolymers, are comprised of particles with a distinctive structure.

Magnesium chloride particles with a polyhedral structure, catalytic components supported on these particles, resultant catalyst systems, processes for fabricating these products, and polyolefins obtained from these catalytic components

Porous particles of MgCl 2 having the form of essentially regular polyhedrons with six or eight faces in which the paired symmetrically opposite faces are essentially parallel, two of which faces are large and elongated and form the too face and the bottom face of a polyhedron such that on each of them the longest diagonal (D) is larger than the shortest distance (d) separating two opposite sides, which large elongated faces are surrounded essentially perpendicularly by the other essentially rectangular faces that form the sides of the said polyhedron, the length of the smaller side (e) of each of the said essentially rectangular faces being less than the shortest distance (d) separating the two opposite sides of the large elongated faces, catalytic components supported on the particles, catalyst systems utilizing the catalytic products, process for making the particles, and polyolefins obtained utilizing the catalytic systems.

Olefin polymerization catalyst

An improved high activity olefin polymerization catalyst which can be used to produce α-olefin polymers having good properties and a relatively narrow particle size distribution comprises an organoaluminum cocatalyst, a selectivity control agent and a novel olefin polymerization procatalyst which is obtainable by contacting a tetravalent titanium halide, a halohydrocarbon, an electron donor and a solid procatalyst precursor obtainable by heating an adduct of a carbonated magnesium ethoxide and a phenolic compound of enhanced acidity.

Method of forming metal films on a substrate by chemical vapor deposition

A method of forming on a substrate a metal film, comprising depositing said metal film on said substrate via chemical vapor deposition from a metalorganic complex of the formula: MA.sub.Y X wherein: M is a y-valent metal; A is a monodentate or multidentate organic ligand coordinated to M which allows complexing of MA y with X; y is an integer having a value of 2, 3 or 4; each of the A ligands may be the same or different; and X is a monodentate or multidentate ligand coordinated to M and containing one or more atoms independently selected from the group consisting of atoms of the elements C, N, H, S, O and F. The metal M may be selected from the group consisting of Cu, Ba, Sr, La, Nd, Ce, Pr, Sm, Eu, Th, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Bi, Tl, Y, Pb, Ni, Pd, Pt, Al, Ga, In, Ag, Au, Co, Rh, Ir, Fe, Ru, Sn, Li, Na, K, Rb, Cs, Ca, Mg, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, and W. A may be selected from the group consisting of β-diketonates, β-thioketonates, cyclopentadienyls, alkyls, perfluoroalkyls, alkoxides, perfluoroalkoxides, and Schiff bases. X may for example comprise a ligand such as tetraglyme, tetrahydrofuran, bipyridine, crown ether, or thioether.

Adducts magnesium dichloride - alcohol and catalytic components obtained therefrom

FIELD: chemistry. SUBSTANCE: adducts of the claimed invention, in particular, used as precursors in obtaining catalytic components for the polymerisation of olefins, which have the reduced size of particles and/or narrow distribution of particles by the size. The solid adducts contain: MgCl 2 , ROH alcohol, in which R represents a C 1 -C 10 hydrocarbon group, present in a molar ratio with MgCl 2 in the interval from 0.5 to 5, aliphatic carboxylic acid, which has from 8 to 22 carbon atoms, or its metal salt, present in the quantity of less than 15 wt % with respect to the total adduct weight. The method for obtaining the adducts includes: contact of MgCl 2 , ROH alcohol and aliphatic carboxylic acid in the quantity of less than 15 wt % with respect to the total weight of MgCl 2 and ROH and the said acid or salt; heating the system at such temperature that a liquid phase is obtained , which contains MgCl 2 , alcohol and the said acid or metal salt; emulsification of the said liquid phase in a liquid medium, which is non-mixable with it; fast cooling of thus obtained emulsion when it contacts with an inert cooling liquid with obtaining an emulsified phase in the form of spherical particles as a result of hardening. The invention also relates to catalytic components for the polymerisation of the olefins, which are obtained by the interaction of the adducts with the compound of the transition metal of one of groups IV-VI of the periodic system of elements, to the catalyst for the polymerisation of alpha-olefins and to a method for polymerisation. EFFECT: narrow distribution of particles by the size of the said adducts and simple method of obtaining thereof. 15 cl, 3 tbl, 20 ex РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (51) МПК C01F 5/00 C08F 10/06 C08F 4/634 C08F 4/654 C08F 4/631 C08F 4/651 (13) 2 576 523 C2 (2006.01) (2006.01) (2006.01) (2006.01) (2006.01) (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ (21)(22) Заявка: ИЗОБРЕТЕНИЯ К ПАТЕНТУ ...

溶解度提高的卤化镁以及使用它们的催化剂和聚合方法

本发明涉及提高卤化镁的溶解度的方法，包括提供电子给体溶剂，让卤化镁与该溶剂接触；和提供电子给体化合物，从而形成卤化镁组合物。该组合物特征在于在电子给体溶剂的沸点以内不降低的在溶剂中的溶解度。聚合催化剂前体组合物包括卤化镁组合物与过渡金属化合物混合的产物。还公开了由此类前体制备的活性催化剂和使用此类催化剂的聚合方法。

Enhanced solubility of magnesium halides and catalysts and polymerization processes using same

Catalyst for elkene oxide polymerization

Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom

Adducts comprising a MgC1 2, an alcohol ROH in which R is a C1 -C1O hydrocarbon group, present in a molar ratio with MgC1 2 ranging from 0.5 to 5 and less than 15% wt, based on the total weight of the adduct, of a metal salt of an aliphatic carboxylic acid having from 8 to 22 carbon atoms.

Enhanced solubility of magnesium halides and catalysts and polymerization processes using same

Support activation process based on magnesium chloride by a cyclic monoether.

Olefin polymerization catalyst

Olefin polymerization catalyst

Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom

Adducts comprising a MgCl 2 , an alcohol ROH in which R is a C1-C10 hydrocarbon group, present in a molar ratio with MgCl 2 ranging from 0.5 to 5 and less than 15% wt, based on the total weight of the adduct, of a metal salt of an aliphatic carboxylic acid having from 8 to 22 carbon atoms.

Process for making MgCl2 MgO with narrow granulometric distribution, catalytic components containing the same, process of using such supports to polymerize olefins, and resultant polyolefins

A process for the manufacture of MgCl 2 .MgO with narrow granulometric distribution by treatment of hydrated MgCl 2 with an alcohol followed by heat treatment after partial elimination of the alcohol, characterized in that the hydrated MgCl 2 is suspended in the alcohol, and that the molar ratio of the alcohol to the hydrated MgCl 2 is lower than the solutility ratio of these two substances at the temperature of the suspension. The resultant MgCl 2 .MgO can be employed as a support in catalytic components for the polymerization of olefins.

Enhanced solubility of magnesium halides and catalysts and polymerization processes using same

A method for increasing the solubility of a magnesium halide includes providing an electron donating solvent, contacting a magnesium halide with the solvent; and providing an electron donor compound to form a magnesium halide composition. The composition is characterized by solubility in the electron donor solvent that does not decrease up to the boiling point of the solvent. A polymerization catalyst precursor composition comprises the product of mixing the magnesium halide composition with a transition metal compound. Active catalysts prepared from such precursors and a method of polymerization using such catalysts are also disclosed.

Enhanced solubility of magnesium halides and catalysts and polymerization processes using same

A method for increasing the solubility of a magnesium halide includes providing an electron donating solvent, contacting a magnesium halide with the solvent; and providing an electron donor compound to form a magnesium halide composition. The composition is characterized by solubility in the electron donor solvent that does not decrease up to the boiling point of the solvent. A polymerization catalyst precursor composition comprises the product of mixing the magnesium halide composition with a transition metal compound. Active catalysts prepared from such precursors and a method of polymerization using such catalysts are also disclosed.

溶解度提高的卤化镁组合物以及使用它们的催化剂

本发明涉及提高卤化镁的溶解度的方法，包括提供电子给体溶剂，让卤化镁与该溶剂接触；和提供电子给体化合物，从而形成卤化镁组合物。该组合物特征在于在电子给体溶剂的沸点以内不降低的在溶剂中的溶解度。聚合催化剂前体组合物包括卤化镁组合物与过渡金属化合物混合的产物。还公开了由此类前体制备的活性催化剂和使用此类催化剂的聚合方法。