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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ

Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Форма поиска

Поддерживает ввод нескольких поисковых фраз (по одной на строку). При поиске обеспечивает поддержку морфологии русского и английского языка
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Применить Всего найдено 29017. Отображено 100.
27-02-2004 дата публикации

Тара для спиртосодержащих напитков

Номер: RU0000036102U1
Автор: ДОЛГОНОС Эл

1. Tapa для спиртосодержащих напитков, характеризующаяся тем, что представляет собой выполненный из алюминиевого сплава и окрашенный снаружи цельный корпус с открытым горлышком под крышку, причем внутренняя поверхность корпуса покрыта методом вакуумного впрыска водной дисперсией эпоксидной смолы, модифицированной акриловой кислотой или акрилатами с образованием непроницаемого и нейтрального для спиртосодержащих напитков защитного слоя толщиной 3-5 мкм. 2. Тара для спиртосодержащих напитков по п.1, отличающаяся тем, что имеет форму округлой фляги, а вакуумный впрыск водной дисперсии модифицированной эпоксидной смолы осуществлен в замкнутый объем фляги через горлышко перевернутой вверх дном тары. (19) RU (11) 36 102 (13) U1 (51) МПК B65D 85/72 (2000.01) C08L 67/00 (2000.01) РОССИЙСКОЕ АГЕНТСТВО ПО ПАТЕНТАМ И ТОВАРНЫМ ЗНАКАМ (12) ОПИСАНИЕ ПОЛЕЗНОЙ МОДЕЛИ К ПАТЕНТУ (21), (22) Заявка: 2003115855/20 , 03.06.2003 (24) Дата начала отсчета срока действия патента: 03.06.2003 (46) Опубликовано: 27.02.2004 (72) Автор(ы): ДОЛГОНОС Эл (US) (73) Патентообладатель(и): ЛОГСТОР ЭНТЕРПРАЙЗЕС Лимитед (CY) (74) Патентный поверенный: Раевская Ольга Маратовна U 1 3 6 1 0 2 R U Ñòðàíèöà: 1 U 1 (57) Формула полезной модели 1. Tapa для спиртосодержащих напитков, характеризующаяся тем, что представляет собой выполненный из алюминиевого сплава и окрашенный снаружи цельный корпус с открытым горлышком под крышку, причем внутренняя поверхность корпуса покрыта методом вакуумного впрыска водной дисперсией эпоксидной смолы, модифицированной акриловой кислотой или акрилатами с образованием непроницаемого и нейтрального для спиртосодержащих напитков защитного слоя толщиной 3-5 мкм. 2. Тара для спиртосодержащих напитков по п.1, отличающаяся тем, что имеет форму округлой фляги, а вакуумный впрыск водной дисперсии модифицированной эпоксидной смолы осуществлен в замкнутый объем фляги через горлышко перевернутой вверх дном тары. 3 6 1 0 2 (54) Тара для спиртосодержащих напитков R U Адрес для переписки: ...

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05-01-2012 дата публикации

Reinforced polyester resin composition

Номер: US20120004363A1
Принадлежит: Adeka Corp

The present invention provides a reinforced polyester resin composition having a high crystallization rate and superior moldability, from which a molded article having low shrinkage anisotropy and superior surface properties can be obtained. The reinforced polyester resin composition according to the present invention comprises, with respect to 100 parts by mass of a polyester resin, 0.01 to 400 parts by mass of an inorganic filler as component (A) and 0.001 to 10 parts by mass of a metal salt of a sulfonamide compound as component (B), the metal salt of the sulfonamide compound having a structure represented by the following Formula (1): (wherein, R 1 and R 2 independently represent a hydrogen atom or the like; R 1 and R 2 are also optionally linked together to form a cyclic group; n represents number of 1 or 2; when n is 1, M represents an alkali metal atom or the like; when n is 2, the plural R 1 s and R 2 s are each optionally different; M represents a divalent metal atom or linking group; and when M is the linking group, either of R 1 and R 2 is an alkali metal).

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26-01-2012 дата публикации

Polycarbonate/polyethylene terephthalate composite resin composition and molded article

Номер: US20120022190A1
Принадлежит: Mitsubishi Engineering Plastics Corp

A polycarbonate/polyethylene terephthalate composite resin composition is provided, which contains a resin component of 100 parts by weight and contains a phosphorus thermal stabilizer of 0.01 to 0.5 parts by weight and/or a hindered phenol thermal stabilizer of 0.01 to 1 parts by weight, the resin component containing a polycarbonate resin of 95 to 30 weight % and a polyethylene terephthalate resin of 5 to 70 weight %. The polyethylene terephthalate resin contains a deactivated polycondensation catalyst. The polycarbonate/polyethylene terephthalate composite resin composition can be prevented from being deteriorated resulting from being thermally preserved.

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16-02-2012 дата публикации

Method Of Improving Film Processing And Injection Molding Of Polyhydroxyalkanoate Polymers

Номер: US20120041109A1
Принадлежит: Metabolix Inc

Processing and improvements in processing of polyhydroxyalkanoate polymer films, sheet, injection moldings, thermoforms, and blow moldings are provided, by use of particular types of calcium carbonate. Methods for using the calcium carbonates in processing of polyhydroxyalkanoate polymers are also disclosed, as well as polyhydroxyalkanoate polymer compositions comprising the calcium carbonates, and articles made therefrom.

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16-02-2012 дата публикации

Resin composition and resin molded article

Номер: US20120041114A1
Принадлежит: Fuji Xerox Co Ltd

A resin composition includes a polylactic acid, a monocarbodiimide compound and a phosphazene.

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15-03-2012 дата публикации

Thermoplastic polymer composition and molded product

Номер: US20120065332A1
Принадлежит: Techno Polymer Co Ltd

A thermoplastic polymer composition capable of exhibiting excellent impact resistance, durability and destaticizing property containing (A) 50 to 95% by mass of an aliphatic polyester-based resin and (B) 5 to 50% by mass of a block copolymer of (B1) a hard segment block with at least one of a polyamide, polyester, polyolefin or polyurethane, and (B2) a soft segment block having an ether bond.

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05-04-2012 дата публикации

Bio-based material composition and optical device employing the same

Номер: US20120083560A1

The invention provides a bio-based material composition and an optical device employing the same. The composition can be a petroleum resin-free composition, including a polylactic acid resin, a filler, and a light diffusion agent. Further, the composition can be a composition with petroleum resin, including a polylactic acid resin, a petroleum resin, a light diffusion agent, and an antioxidant.

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26-04-2012 дата публикации

Composition, method for preparing same, and use thereof for improving the fluidity and temperature resistance of composite materials

Номер: US20120101192A1

A composition or master batch including at least one functionalized polyglycerol, at least one biopolymer, and a meal obtained from plant carbon, and its use for improving the fluidity in the molten state and the heat resistance of composite materials, in particular composites based on biopolymers that are optionally loaded with plant meal. Also, a process for the preparation of this composition, as well as the materials that integrate it.

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03-05-2012 дата публикации

Low temperature cure powder coating compositions

Номер: US20120107629A1
Автор: Luc Moens
Принадлежит: Individual

The present invention relates to a powder coating composition for low temperature cure which comprises a mixture of a carboxylic acid group containing first polyester; at least one of a second polyester having a glass transition temperature ≦45° C. and/or a crystalline polycarboxylic acid; a glycidyl group containing acrylic copolymer; a further compound and/or resin having functional groups readable with the carboxylic acid groups; and a thermosetting curing catalyst. These thermosetting powder coatings are designed for coating heat-sensitive substrates such as wood, fibre board and other materials which can not withstand the excessive heat/time conditions necessary to cure traditional coatings. The powder coatings of the invention, when cured at temperatures below 150° C., produce a finish which exhibits a high gloss, smooth surface along with an outstanding hardness and weatherability.

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24-05-2012 дата публикации

Thermoplastic Resin Composition and Molded Product Using the Same

Номер: US20120129989A1
Принадлежит: Cheil Industries Inc

Provided is a thermoplastic resin composition that includes (A) a base resin including (A-1) a polycarbonate resin and (A-2) a polyester resin, (B) a styrene-based polymer, (C) an impact-reinforcing agent and (D) a phenol-based antioxidant.

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07-06-2012 дата публикации

Process of Producing Thermoplastic Starch/Polymer Blends

Номер: US20120139154A1
Автор: Hongbo Li, Michel Huneault
Принадлежит: NATIONAL RESEARCH COUNCIL OF CANADA

A process of producing a thermoplastic starch/polymer blend involves introducing dry starch into a twin-screw extruder at a first location along the extruder, introducing a plasticizer into the twin-screw extruder at a second location along the extruder downstream of the first location to form a starch paste and then gelatinizing the starch paste in the extruder to form thermoplastic starch, and, introducing dry polymer at ambient temperature into the twin-screw extruder at a third location along the extruder downstream of the second location to form a blend with the thermoplastic starch in the extruder.

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21-06-2012 дата публикации

Thermoplastic Starch Compositions

Номер: US20120157582A1
Принадлежит: Procter and Gamble Co

The present invention relates to improvements in prevention of discoloration of thermoplastic starch materials and their blends with other thermoplastic materials.

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21-06-2012 дата публикации

Transparent and flame retarding polyester resin composition and preparation method thereof

Номер: US20120157607A1

A polyester resin composition having improved transparency, flame retardancy and hardness, and a method for preparation thereof are provided. The composition includes organo-modified nanoclay and a phosphorous-based flame retardant added to a polyester resin. The nanoclay is homogeneously dispersed in the polyester by melt compounding.

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19-07-2012 дата публикации

Polyester film for solar cells

Номер: US20120183792A1
Принадлежит: Toyobo Co Ltd

The invention provides a polyester film suitable for a back sheet for solar cells, which requires a high reflectance not only in the visible light region but also in the near-infrared region, and also requires a low reflection directivity. The polyester film is a cavity-containing polyester film having≈an average reflectance of 70-95% in a wavelength range of 400-1200 nm and an average transmittance of 5-30% in a wavelength range of 700-1200 nm.

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23-08-2012 дата публикации

Heat stable halogen-free flame retardant copolyester thermoplastic elastomer compositions

Номер: US20120211256A1
Принадлежит: EI Du Pont de Nemours and Co

Halogen-free flame retardant compositions exhibiting flame retardance and retention of mechanical properties, especially elongation at break, upon long-term high temperature exposure and comprising a) at least one copolyester thermoplastic elastomer, and b) from at or about 1 to at or about 30 weight percent, based on the total weight of the composition, of at least one flame retardant comprising a phosphinate, diphosphinate and/or polymers of these; c) from at or about 0.25 to at or about 15 weight percent, based on the total weight of the flame retardant composition, of one or more polyhydroxy polymers having a number average molecular weight of at least 2000 and selected from the group consisting of ethylene vinyl alcohol copolymers and poly(vinyl alcohol)s.

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30-08-2012 дата публикации

Methods Of Drug Loading A Hollow Stent With A High Viscosity Formulation

Номер: US20120216905A1
Автор: Stephen D. Pacetti
Принадлежит: Abbott Cardiovascular Systems Inc

A method of loading a composition into a structural element of a stent, where the structural element is defined by a lumen and at least one opening to access the lumen. The composition may include a therapeutic agent. In some embodiments, the composition has characteristics such that at a temperature of 20° C. to 30° C. and a pressure of one atmosphere, the viscosity of the composition is about 10 cP or greater than 10 cP.

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15-11-2012 дата публикации

Polylactic acid-based resin sheet

Номер: US20120288679A1
Принадлежит: TORAY INDUSTRIES INC

A polylactic acid-based resin sheet including polylactic acid and rubber particles and characterized by satisfying (1) to (3): (1): 0.01 μm≦|Ra1−Ra2|≦0.2 μm; (2): Ra1≦0.3 μm and (3): Ra2≦0.3 μm where Ra1 is a two-dimensional center line average roughness of one surface of the sheet, and Ra2 is a two-dimensional center line average roughness of a surface other than that subjected to measurement of Ra1.

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15-11-2012 дата публикации

Polyester (meth)acrylate resin composition, coated structure, and method for constructing the same

Номер: US20120289664A1
Принадлежит: DIC Corp

The present invention provides a polyester (meth)acrylate resin composition that is excellent in terms of compatibility with dicyclopentenyloxyethyl (meth)acrylate (B) and that has a suitability for spraying that means the composition is suitable for use in a spraying method in the field of civil engineering and construction and the like, a coated structure produced by coating the same, and a method for constructing the same by using, as an acid component of the polyester structure of a polyester (meth)acrylate resin (A), an alicyclic dibasic acid (A1) and/or an aliphatic dibasic acid (A2) in an amount of 40% by mole or more.

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22-11-2012 дата публикации

Compositions of polyesters and fibrous clays

Номер: US20120292812A1
Принадлежит: EI Du Pont de Nemours and Co

Compositions of thermoplastic polyesters containing dispersed nanoparticles of fibrous clay are made by polymerizing the polyester precursors in the presence of exfoliated fibrous clay that has not been organically modified. The compositions have good physical properties and can be melt molded into various articles. Many of these articles may be coated (painted) and are especially useful for appearance parts such as visible exterior automotive body parts.

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29-11-2012 дата публикации

Polyester adhesive composition

Номер: US20120301717A1
Принадлежит: Nitto Denko Corp

The present invention has an object to provide a solvent-free polyester-based adhesive composition having good coatability and capable of forming an adhesive that shows good adhesion performance. The present invention provides a polyester-based adhesive composition containing a polyester having Mw of from 1×10 3 to 20×10 3 as a main component and a trifunctional or more polyepoxy compound as a crosslinking agent, and containing substantially no organic solvent. The molar number, m OH , of hydroxyl group contained in a polyalcohol component constituting the polyester is from 0.5 to 0.98 times of the molar number, m COOH , of carboxyl group contained in a polycarboxylic acid component. The composition has a viscosity at 23° C. of at most 80 Pa·s.

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06-12-2012 дата публикации

Hyperbranched polyester with a hydrophobic nucleus for solubilizing poorly soluble active substances

Номер: US20120309626A1
Принадлежит: BASF SE

The invention provides a composition comprising an active ingredient with a maximum solubility in water at 20° C. of 10 g/l, and a hyperbranched polyester based on a hydrophobic dicarboxylic acid and a trifunctional alcohol. The invention further relates to the hyperbranched polyester mentioned, to a process for preparation thereof and to the use thereof for solubilizing an active ingredient with a maximum solubility in water at 20° C. of 10 g/l in aqueous solutions.

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06-12-2012 дата публикации

Polyesters with styrene copolymers

Номер: US20120309889A1
Принадлежит: BASF SE

A thermoplastic molding composition containing A) at least one polyester, B) optionally one polycarbonate, C) a copolymer made of c 1 ) styrene or of substituted styrenes of the formula I c 2 ) at least one unsaturated nitrile, D) a copolymer made of d 1 ) structural units deriving from one or more vinylaromatic monomers, d 2 ) structural units deriving from one or more vinyl cyanides, d 3 ) structural units deriving from one or more dicarboxylic anhydrides, and d 4 ) optionally structural units deriving from other copolymerizable monomers.

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27-12-2012 дата публикации

Method for producing liquid crystal polyester

Номер: US20120329975A1
Принадлежит: Sumitomo Chemical Co Ltd

Disclosed is a method for producing a liquid crystal polyester, which includes the following steps of: (1) melt-polycondensing a compound as a monomer in a polymerization tank to produce a prepolymer; (2) discharging the prepolymer from the polymerization tank in a molten state, and solidifying the prepolymer through cooling to produce a sheet in which a portion having a thickness of 1.6 to 2 mm accounts for 80% by mass or more (of 100% by mass of the entire sheet); (3) crushing the sheet; and (4) subjecting the crushed product to solid-phase polymerization through heating.

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10-01-2013 дата публикации

Elastomer blends containing polycarbonates and copolyetheresters derived from polyethylene terephthalate, method of manufacture, and articles therefrom

Номер: US20130012666A1
Принадлежит: General Electric Co

A composition comprising from 10 to 90 weight percent of a copolyetherester elastomer comprising: a modified, random polybutylene terephthalate copolymer block that is derived from a polyethylene terephthalate component selected from the group consisting of polyethylene terephthalate, polyethylene terephthalate copolymers, and combinations thereof; and that contains at least one residue derived from the polyethylene terephthalate component; and a polyalkylene oxide copolymer block that is derived from the polyethylene terephthalate component and a polyalkylene oxide glycol, and that contains polyalkylene oxide and at least one residue derived from the polyethylene terephthalate component; from 10 to 90 weight percent of a polycarbonate; and from 0 to 60 weight percent of a polyester.

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21-03-2013 дата публикации

RESIN COMPOSITION SHEET AND METHOD FOR MOLDING THEREOF

Номер: US20130069277A1
Принадлежит: SUMITOMO BAKELITE CO., LTD.

The object of the present invention is to provide a resin composition sheet that when used in the manufacture of product packaging such as carrier tapes, and the like, molding temperatures can be lowered from 260-280° C. to 200-250° C., even when heated to relatively high temperatures using a contact heating device with a mold-releasing film interposed therebetween, wherein poor appearance due to the replication of mold-releasing film features is unlikely to occur. The resin composition sheet relating to one aspect of the present invention comprises polycarbonate resin, amorphous polyester resin, and silicate compound filler. Furthermore, this resin composition sheet is suitable for use in the manufacture of product packaging such as carrier tapes, and the like. Furthermore, when an object that is vulnerable to static electricity is to be accommodated within product packaging, it is preferable to add a conductive filler to prevent the static charge in the accommodated product. 1. Resin composition sheet comprisinga polycarbonate resin;an amorphous polyester resin;and a silicate compound filler.2. The resin composition sheet as recited in claim 1 ,wherein the silicate compound filler is added as 1 part by weight or more and 3 parts by weight or less when the total amount of the polycarbonate resin and amorphous polyester resin is taken as 100 parts by weight.3. The resin composition sheet as recited in claim 1 ,wherein the polycarbonate resin is added as 30 parts by weight or more and 80 parts by weight or less when the total amount of the polycarbonate resin and amorphous polyester resin is taken as 100 parts by weight.4. The resin composition sheet as recited in claim 1 ,wherein the amorphous polyester resin is composed of at least 1 type of dicarboxylic acid-derived unit selected from the group comprising terephthalic acid-derived units and terephthalic acid derivative-derived units, and of glycol-derived units including-less than 50 mol % of 1,4- ...

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21-03-2013 дата публикации

Aliphatic-aromatic copolyesters and their mixtures

Номер: US20130071588A1
Принадлежит: Novamont SpA

This invention relates to an aliphatic-aromatic copolyester characterised in that it has appreciable workability properties even when mixed with other polymers, appreciable toughness and high values for ultimate tensile strength and elastic modulus. This invention also relates to mixtures of the said copolyester with other polymers.

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21-03-2013 дата публикации

RESIN PARTICLE AND METHOD FOR PRODUCING SAME

Номер: US20130071665A1
Принадлежит: SANYO CHEMICAL INDUSTRIES, LTD.

Disclosed is a resin particle having excellent low-temperature fusibility, having a sufficiently narrow size distribution, and that is obtained using a liquid or supercritical fluid. In the resin particle (C), which comprises a microparticle (A) containing a resin (a) being coated to or adhered to the surface of a resin particle (B) that contains another resin (b), the degree of swelling of the microparticle (A) resulting from liquid or supercritical carbon dioxide (X) at a temperature less than the glass transition temperature or the melting point of the microparticle (A) is no greater than 16%, and with the resin (a) as a constituent unit, the resin particle (C) contains 0.1-50 wt % of a non-crystalline non-halogen vinyl monomer (m1) of which the solubility parameter (SP value: (cal/cm)) is 7-9. 1. A resin particle (C) comprising a microparticle (A) containing a resin (a) being coated to or adhered to the surface of a resin particle (B) containing a resin (b) , wherein the degree of swelling of the microparticle (A) resulting from liquid or supercritical carbon dioxide (X) at a temperature less than the glass transition temperature or the melting point of the microparticle (A) is no greater than 16% , and the resin (a) contains , as a constituent unit , 0.1 to 50 wt % of a non-crystalline non-halogen vinyl monomer (m1) having a solubility parameter [SP value: (cal/cm)] of 7 to 9.2. The resin particle (C) according to claim 1 , wherein the non-crystalline non-halogen vinyl monomer (m1) is at least one kind of vinyl monomer selected from a silicone-containing vinyl monomer (m11) and a branched alkyl group-containing vinyl monomer (m12) having a carbon number of 8 to 30.3. The resin particle (C) according to claim 1 , wherein the resin (a) further contains claim 1 , as a constituent unit claim 1 , 30 to 99.9 wt % of a crystalline vinyl monomer (m2).4. The resin particle (C) according to claim 1 , wherein the particle diameter of the microparticle (A) is 0.01 to 1.0 μ ...

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21-03-2013 дата публикации

ANHYDROUS COMPOSITION AS A COATING AGENT FOR FUNCTIONAL LAYERS OF A MULTILAYER PAINT

Номер: US20130071668A1
Принадлежит: BASF COATINGS GMBH

Water-free composition comprising at least one saturated or unsaturated, epoxy-modified polyester as binder, at least one acrylate polymer or polyurethane polymer as further binder, polymer microparticles, at least one polymer which comprises functional groups consisting of blocked isocyanates and amino resins, as crosslinking agent, at least one pigment, at least one organic solvent, and at least one auxiliary or additive, the solids of the composition being at least 50% by weight. 1. A water-free composition comprisinga. a binder comprising at least one saturated or unsaturated, epoxy-modified polyester,b. a further binder comprising at least one acrylate polymer or plyurethane polymer,c. polymer microparticles,d. a crosslinking agent comprising at least one polymer comprising functional groups selected from the group consisting of blocked isocyanates and amino resins,e. at least one pigment,f. at least one organic solvent, andg. at least one auxiliary additive,the solids of the composition being at least 50% by weight and the composition being water-free.2. The water-free composition of claim 1 , wherein the polyester is present with a fraction of 5% to 20% by weight claim 1 , based on the total weight of the composition claim 1 , and the weight fractions of all of the constiuents add up to 100% by weight.3. The water-free composition of claim 2 , wherein the composition comprisesa. 5% to 30% by weight of at least one acrylate polymer or polyurethane polymer as further binder,b. 5% to 20% by weight of polymer microparticles,c. 5% to 15% by weight of at least one polymer which comprises functional groups selected from the group consisting of blocked isocyanates and amino resins, as crosslinking agent,d. 5% to 49.5% by weight of at least one pigment,e. 30% to 50% by weight of at least one organic solvent, andf. 0.5% to 40% by weight of at least one auxiliary or additive, based in each case on the total weight of the compsosition.4. The water-free composition of ...

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21-03-2013 дата публикации

ALCOHOL COMPOUND, A POLYESTER RESIN, AN UNSATURATED POLYESTER RESIN, A RESIN PARTICLE AND AN ELECTROPHOTOGRAPHIC TONER

Номер: US20130071785A1
Принадлежит: Japan U-Pica Company, Ltd.

It is an object of the present invention to provide a new alcohol compound, a polyester resin, an unsaturated polyester resin, a resin particle and an electrophotographic toner using the compound capable of using the renewable resources as a part of a raw material. 3. An unsaturated polyester resin wherein the compound according to claim 1 , is an essential component of an alcohol component.4. An unsaturated polyester resin wherein the compound according to is an essential component of an alcohol component and is contained at 20 percent by weight or more as a raw material of an unsaturated polyester.5. A premix molding compound comprising the unsaturated polyester resin according to .6. A premix molding compound according to claim 5 , wherein the compound is a sheet molding compound claim 5 , or a bulk molding compound.9. A polyester resin according to claim 5 , wherein the compound according to is contained at 20 percent by weight or more as a raw material of polyester.10. A resin composition for a powder coating comprising the polyester resin according to .11. A resin composition for an electrophotographic developer comprising the polyester resin according to .12. An urethane acrylate resin comprising the polyester resin according to that is modified by isocyanate.14. A resin particle according to claim 13 , wherein an average particle diameter of the resin particle is within a range from 0.01 to 1 μm.15. A resin particle according to claim 13 , wherein the resin particle is obtained by causing the phase inversion by means of adding a neutralizing agent and a water-based medium into a resin solution made by dissolving the polyester resin into an organic solvent claim 13 , and thereby forming an O/W emulsion of resin particle claim 13 , and further removing the organic solvent from a dispersion of an O/W emulsion of resin particle.17. A resin particle according to claim 13 , wherein the compound according to is contained at 20 percent by weight or more as a raw ...

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21-03-2013 дата публикации

Just-in-time compounding in an injection molding machine

Номер: US20130072627A1
Принадлежит: Rutgers State University of New Jersey

A plastication unit for an injection molding machine, combining a heated plastication barrel with an entrance port and an exit port on opposing ends of the barrel; a hopper positioned to deliver ingredients to be compounded for injection molding to the entrance port of the barrel; and a helical plastication screw rotatably carried within the barrel and running the length of the barrel between the entrance and exit ports, which is operable to rotate and transmit the ingredients along the length of the barrel; wherein the plastication screw has at least one axial fluted extensional mixing element segment and the ingredients include at least one polymer for injection molding. Methods for injection molding with the plastication unit of the present invention and articles formed by the inventive methods are also disclosed.

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28-03-2013 дата публикации

COPOLYESTER BLENDS WITH ENHANCED TEAR STRENGTH

Номер: US20130079440A1
Принадлежит: E I DU PONT DE NEMOURS AND COMPANY

This invention relates to aliphatic-aromatic copolyesters that can exhibit improved tear strength and improved rate of biodegradation. Particularly to an aliphatic-aromatic copolyester having a dicarboxylic acid component and a glycol component. The invention also relates to articles and blends using the copolyesters. 1. A blend comprising an aliphatic-aromatic copolyester consisting essentially of a. about 95 to 40 mole percent of terephthalic acid component;', 'b. about 5 to 60 mole percent of a linear aliphatic dicarboxylic acid component; and', 'c. about 0 to 30 mole percent of an alicyclic dicarboxylic acid component; and, 'I. a dicarboxylic acid component consisting essentially of, based on 100 mole percent total acid component a. about 100 to 76 mole percent of a linear aliphatic glycol component;', 'b. about 0 to 4 mole percent of a dialkylene glycol component; and', 'c. about 0 to 30 mole percent of an alicyclic glycol component;, 'II. a glycol component consisting essentially of, based on 100 mole percent total glycol componentwherein Ic+IIc>2 mole percent,and at least one other polymeric material.2. The blend of wherein said other polymeric material is a natural polymer.3. The blend of wherein said other polymeric material is selected from the group consisting of a natural polymer claim 2 , starch claim 2 , and poly(lactic acid).4. A shaped article comprising the blend of .5. A film comprising the blend of .6. The film of with tear strength greater than about 5000 g/mm according to ASTM D1922.7. The film of with tear strength greater than about 8000 g/mm according to ASTM D1922.8. The film of with tear strength greater than about 16000 g/mm according to ASTM D1922. This invention relates to blends containing aliphatic-aromatic copolyesters and other polymers. The blends can exhibit improved tear strength and improved rate of biodegradation.As population increases, resources become scarce and societal habits have a greater impact on our environment. ...

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28-03-2013 дата публикации

BIODEGRADABLE BIAXIALLY DRAWN FILM WITH CONTROLLED TEAR RESISTANCE

Номер: US20130079455A1
Принадлежит:

The invention relates to a film with controllable tear resistant properties, comprising at least one basic layer which contains at least one polymer I from at least one hydroxycarboxylic acid, and >0.1 wt. %, in relation to the weight of the layer, of a thermoplastic polymer II which is different from polymer I, and/or inorganic additives. 125-. (canceled)26. A method for improving the initial-tear and tear propagation behavior of a biaxially stretched film which comprises at least one polymer I comprising at least one hydroxycarboxylic acid , said method includes adding 0.2-5% by weight , based on the weight of the film of (i) a thermoplastic polymer II which is propylene homopolymer or a mixture thereof or (ii) a theromplastic polymer II which is polyethylene or a mixture thereof.27. The method according to claim 26 , wherein the polymer I is a polylactic acid.28. The method according to claim 26 , wherein wherein the polymer I is a polylactic acid which comprises 80-100% by weight of L-lactic acid units and from 0 to 20% by weight of D-lactic acid units or other polyhydroxycarboxylic acid units.29. The method according to claim 26 , wherein polymer I is in a base layer and said base layer additionally includes an inorganic additive.30. The method according to claim 26 , wherein said thermoplastic polymer II is propylene homopolymer or a mixture thereof.31. The method according to claim 26 , wherein said thermoplastic polymer II is polyethylene or a mixture thereof.32. The method according to claim 31 , wherein said polyethylene is an HDPE claim 31 , an LDPE or an MDPE.33. The method according to claim 28 , wherein said polyethylene is an HDPE claim 28 , an LDPE or an MDPE.34. The method according to claim 32 , wherein wherein the polymer I is a polylactic acid which comprises 80-100% by weight of L-lactic acid units and from 0 to 20% by weight of D-lactic acid units or other polyhydroxycarboxylic acid units.35. The method according to claim 28 , wherein said ...

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28-03-2013 дата публикации

PROCESS FOR PRODUCING POLYOL DISPERSIONS

Номер: US20130079473A1
Автор: SCHNORPFEIL Christoph
Принадлежит:

The present invention relates to polyol dispersions comprising at least one polyol and at least one polymer particle mixture comprising at least one thermoplastic polymer (P) and at least one block copolymer (B), wherein the block copolymer (B) has at least one block which is compatible with the thermoplastic polymer (P) and at least one block which is compatible with the polyol, a process for producing such polyol dispersions, their use for producing polyurethanes and a process for producing polyurethanes. 1. A process for producing a polyol dispersion , comprising:(a) heating a composition (I) comprising at least one thermoplastic polymer (P) of polystyrene, substituted polystyrenes, polyacrylates, polymethacrylates, polyolefins, polyvinylchloride, polyacrylonitrile, polyesters, polyamides and copolymers of said polymers, at least one polyol selected from the group consisting of polyetherols and polyesterols, and at least one block copolymer (B) selected from the group consisting of polyester-polyether block copolymers, polyamide-polyether block copolymers, polystyrene-polyether block copolymers and polyethylene-polyether block copolymers, comprising at least one block which is compatible with the thermoplastic polymer (P) and at least one block which is compatible with the polyol and forming a composition (II) comprising said at least one block copolymer (B), and (b) cooling the composition (II).2. The process according to claim 1 , wherein said at least one thermoplastic polymer (P) is selected from the group consisting of polystyrene claim 1 , polyethylene and polyethylene terephthalate.3. The process according to claim 1 , wherein the at least one block copolymer (B) is used in an amount of from 0.1 to 10% by weight claim 1 , based on the total weight of the thermoplastic polymer (P) used.4. The process according to claim 1 , comprising stirring.5. A process for producing a polyurethane claim 1 , comprising reacting a polyol dispersion obtainable by a process ...

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04-04-2013 дата публикации

Electrostatic image developing toner and manufacturing method of the same, electrostatic image developer, toner cartridge, process cartridge, image forming apparatus, and image forming method

Номер: US20130084520A1
Принадлежит: Fuji Xerox Co Ltd

An electrostatic image developing toner of the exemplary embodiment of the invention contains an amorphous first polyester resin of a polycondensation product of at least a carboxylic acid component and an alcohol component containing rosin, and a second polyester resin having the difference (absolute value) in parameter of solubility relative to the first polyester resin of from about 0.3 (cal/cm 3 ) 1/2 to about 3 (cal/cm 3 ) 1/2 .

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04-04-2013 дата публикации

Aqueous dispersions for use as toners

Номер: US20130084522A1
Принадлежит: Dow Global Technologies LLC

A compound that includes an aqueous dispersion, wherein the dispersion includes a thermoplastic resin and at least one stabilizing agent, and at least one selected from the group consisting of a colorant and a magnetic pigment, wherein the dispersion has an average volume diameter particle size from about 0.05 to about 10 microns is described.

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04-04-2013 дата публикации

KETAL LACTONES AND STEREOSPECIFIC ADDUCTS OF OXOCARBOXYLIC KETALS WITH TRIMETHYLOL COMPOUNDS, POLYMERS CONTAINING THE SAME, METHODS OF MANUFACTURE, AND USES THEREOF

Номер: US20130085201A1
Принадлежит: SEGETIS, INC.

Ketal lactones of and methods for making such ketal lactones are disclosed. Also described are methods for making isolated cis- and trans-stereoisomers of hydroxyester ketals of oxocarboxylic acids and polymers having ketal units of such stereoisomers within the polymer backbone. 4. A polymer composition comprising a polymer and a compound of .11. A polymer composition comprising a polymer and a compound of .14. A polymer composition comprising a polymer and a compound of .17. A polymer composition comprising a polymer and the combination of .21. A polymer of claim 18 , further comprising another polyester unit derived from a polyhydric alcohol having from 2 to 6 hydroxyl groups claim 18 , a C1-36 aliphatic or C6-36 aromatic dicarboxylic or tricarboxylic acid or its reactive derivative claim 18 , a hydroxylated carboxylic acid or its ester or lactone claim 18 , a hydroxyl-terminated linear or branched polyether claim 18 , a polyester polyol claim 18 , a polyurethane polyol claim 18 , a polysaccharide claim 18 , a poly(3-hydroxyalkanoate) claim 18 , a polylactate claim 18 , a polyglycolide claim 18 , a poly(co-lactate/glycolate) claim 18 , or a combination thereof.23. A polymer of claim 18 , comprising two to six of hydroxyl groups claim 18 , isocyanate groups claim 18 , (meth)acryloyl groups claim 18 , or (meth)allyl groups.24. A polymer of claim 18 , further comprising an additional claim 18 , different polymer claim 18 , a polymer additive claim 18 , or a combination thereof.25. An article comprising a polymer of .26. A foam comprising any of the polymers or compositions thereof of .31. A polymer composition of claim 30 , wherein the polymer further comprises units derived from the living polymerization in the further presence of another lactone claim 30 , a lactide claim 30 , glycolide claim 30 , bis-lactone claim 30 , dioxanone claim 30 , dioxepanone monomer claim 30 , trimethylene carbonate claim 30 , or dimethylene carbonate.32. An article comprising the ...

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11-04-2013 дата публикации

BIODEGRADABLE SHEET AND AN ARRAY OF SEPARABLE POUCHES FOR LIQUIDS

Номер: US20130087560A1
Принадлежит:

Disclosed is a biodegradable sheet prepared from biodegradable material, a process for preparing the biodegradable sheet and uses thereof. One of the disclosed uses of the biodegradable sheet is in the preparation of a flexible liquid receptacle. Disclosed also is a flexible liquid receptacle arranged as an array of several receptacle units that are attached to one another and that may be detached from one another by tearing along a perforated line created between each two receptacle units. The disclosed array may also include a hanger, thus allowing the array to be hung from any appropriate means. 1. (canceled)2. (canceled)3. (canceled)4. A single layered biodegradable sheet comprising PLA and PBS at a w/w ratio of between 2:1 to 0.5:1.5. The single layer of wherein the single layered biodegradable sheet further comprises Ecoflex.6. The single layer of claim 5 , wherein the single layered biodegradable sheet comprising about 33.3% w/w PLA claim 5 , 33.3% w/w PBS and 33.3% w/w Ecoflex.7. The single layer of claim 4 , wherein the single layered biodegradable sheet comprising about 20% w/w PLA and 80% w/w PBS.8. The single layer biodegradable sheet of claim 4 , wherein the biodegradable sheet comprising about 20% w/w PLA claim 4 , 40% w/w PBS and 40% w/w Novamont CF.9. A multi-layered biodegradable sheet comprising the three layers claim 4 , wherein the outer layers are identical and includes: PLA claim 4 , PBS and Ecoflex at a w/w ratio of between 2:1 to 0.5:1 or PLA claim 4 , PBSA and PBAT at a w/w ratio of between 2:1 to 0.5:1 and the inner layer includes 100% w/w PHA or PBAT.10. The multi-layered biodegradable sheet of claim 9 , comprising the three layers claim 9 , whereinLayer 1 comprises about 33.3% w/w PLA, 33.3% w/w PBS and 33.3% w/w Ecoflex;Layer 2 comprises 100% w/w PHA; andLayer 3 comprises 33.3% w/w PLA, 33.3% w/w PBS and 33.3% w/w Ecoflexwherein layer 2 is sandwiched between layers 1 and 3.11. The multi-layered biodegradable sheet of claim 9 , comprising ...

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25-04-2013 дата публикации

Stone Based Copolymer Substrate

Номер: US20130101774A1
Автор: Mathew D. MacLeod
Принадлежит: Green Folks and MacLeod LLC

A stone based copolymer substrate includes calcium carbonate (CaCO3) from approximately fifty to eighty-five percent (50-85%) by weight and varying in size generally from 1.0 to 3.0 microns, high-density polyethylene (HDPE) from approximately two to twenty-five percent (2-25%) by weight and a biopolymer from approximately two to twenty-five percent (2-25%) by weight. The substrate may include a biodegradation additive from approximately three fourths of a percent to two percent (0.75-2%) by weight. By selectively adjusting the ranges of the substrate's components, various products can be made to replace current tree-based and plastic-based products. The substrate can be configured to be tear proof, water proof, fade resistant and fire retardant while utilizing less energy and producing less waste during its manufacture. In an exemplary embodiment of the invention, the stone used in the substrate includes limestone.

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09-05-2013 дата публикации

POLYESTER RESIN COMPOSITION AND A PROCESS FOR MANUFACTURING THE SAME

Номер: US20130115402A1
Принадлежит: BASF SE

Co-polyester resin compositions and processes for manufacturing resin compositions are provided, said resin compositions being suitable for extrusion blow molding for the manufacture of containers with good color, clarity for both food, non-food applications and other applications such as profile extrusions and manufacture of blown films which require high melt strength polyester. 1. A process for preparing an extrusion-blow-moldable co-polyester resin composition; the process comprising: at least one pair of polyester-forming materials selected from the group of pairs consisting of a diol-dicarboxylic acid pair, a diol-dicarboxylic ester pair, and a diol-recycled PET pair, a co-monomer, and', 'at least one additive selected from the group consisting of an impact modifier, an antioxidant, a catalyst, an acetaldehyde inhibitor and a color toner, to obtain a reaction mixture;, 'a. charging in a reactor'}b. subjecting the reaction mixture to an esterification, an ester-interchange reaction, or glycolysation, to yield a pre-polymer;c. charging a chain extender, in a proportion of about 0.05 wt. % to about 2.0 wt. %, in the reaction mixture during (b) in at least one portion or in continuous manner at controlled dosing rate when the intrinsic viscosity of the reaction mixture is <0.20;d. subjecting the pre-polymer to polycondensation at a temperature in the range of about 270° C. to about 305° C. under pressure of less than 10 mb, to obtain amorphous chips having an I.V. in range 0.40 to 0.80;e. crystallizing the amorphous chips at a temperature in the range of about 110° C.-170° C. to obtain chips with a crystallinity of more than 30%; andf. processing the crystallized chips in a solid state polymerizer at a temperature in the range of about 190° C. to about 225° C. till the required I.V. of about 0.70 to about 2.0, is achieved, to obtain an EBM grade co-polyester resin composition.2. The process of claim 1 , wherein the diol is monoethylene glycol claim 1 , diethylene ...

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16-05-2013 дата публикации

Formaldehyde free binder compositions for fibrous materials

Номер: US20130123406A1
Принадлежит: JOHNS MANVILLE

Compositions for binding organic or inorganic fibers is described. The compositions may include an aqueous solution having a pH of about 4.5 or more. The aqueous solution may include a polycarboxy polymer that is about 10%, by wt., to 100%, by wt., of a butenedioic acid or butenedioic anhydride; and a polyol. The compositions can maintain a pH of about 5 or more after being cured into a thermoset plastic with the fibers. Processes for preparing a binder composition for organic or inorganic fibers are also described. The processes may include providing an aqueous solution of polycarboxylic acid polymers, where the polymers comprise about 10%, by wt., to 100%, by wt., of a butenedioic acid or butenedioic anhydride; adding a polyol to the aqueous solution; and maintaining the pH of the aqueous solution at about 5 or more.

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16-05-2013 дата публикации

Liquid Crystalline Polymer Composition for High Voltage Electronic Components

Номер: US20130123420A1
Автор: Kim Young Shin
Принадлежит: Ticona LLC

A liquid crystalline polymer composition having a relatively high comparative tracking index (“CTI”) is provided. The present inventors have discovered that high CTI values can be achieved through the use of inorganic particles in combination with a functional aromatic compound. While not fully understood, it is believed that the functional compound can react with the liquid crystalline polymer and create smaller degraded polymer chains. In combination with the inorganic particles, these smaller chains can potentially form insulated regions at the surface of the polymer that hinder the formation of conductive carbonaceous deposits during the tracking process, which could otherwise lead to failure during testing. 2. The polymer composition of claim 1 , wherein the functional aromatic compound includes a phenolic compound claim 1 , diphenolic compound claim 1 , naphthenic compound claim 1 , or a combination thereof.3. The polymer composition of claim 1 , wherein the functional aromatic compound includes an aromatic diol.4. The polymer composition of claim 3 , wherein the aromatic diol is 4 claim 3 ,4′-biphenol.5. The polymer composition of claim 1 , wherein the functional aromatic compound includes an aromatic carboxylic acid.6. The polymer composition of claim 1 , wherein the aromatic carboxylic acid is 2 claim 1 ,6-naphthelene dicarboxylic acid.7. The polymer composition of claim 1 , wherein the composition includes from about 0.01 wt. % to about 1 wt. % of at least one aromatic dial and from about 0.001 wt. % to about 0.5 wt. % of at least one aromatic dicarboxylic acid.8. The polymer composition of claim 1 , wherein the composition further includes at least one non-aromatic functional compound.9. The polymer composition of claim 8 , wherein the non-aromatic functional compound is a hydrate.10. The polymer composition of claim 1 , wherein the inorganic particles include titanium dioxide.11. The polymer composition of claim 1 , wherein the composition has a ...

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16-05-2013 дата публикации

Unsaturated Polyester Resins Modified by Substitution, with Lactic Acid, of an Acid and Alcohol Component of the Polyester

Номер: US20130123421A1
Принадлежит: Ccp Composites

The invention relates to an unsaturated polyester resin comprising a) a lactic acid-modified unsaturated polyester and b) a copolymerizable comonomer, with replacement, with lactic acid, in the composition of an initial polyester, of: i) up to 90 mol % of phthalic anhydride of the acid component of the initial polyester, the acid component comprising from 80 to 20 mol % of maleic anhydride (MA) or fumaric acid, and from 20 to 80 mol % of phthalic anhydride (PA), the polyol component of the initial polyester comprising from 50 to 100 mol % of propylene glycol (PG) and from 0 to 50 mol % of a polyol among ethylene glycol (EG), diethylene glycol (DEG), dipropylene glycol (DPG) and/or 1,3-butylene glycol and/or 1,4-butanediol and/or neopentyl glycol (NPG), ii) up to 100% of a polyol from DPG and DEG, present in an initial overall molar amount ranging up to 50% of the polyol component of the initial polyester and also comprising PG, with the acid component of the initial polyester being maleic anhydride (MA) or fumaric acid, optionally in the presence of up to 20 mol % of the phthalic anhydride (PA) acid component, and in this case with the initial phthalic anhydride (PA) also being up to 100% replaced with lactic acid and with the molar ratio of lactic acid relative to the acid component, without including the lactic acid, of said polyester a) being at most 1.75. The invention also relates to a thermosetting composition comprising the resin and to the uses of these resins and thermosetting compositions in moulding compositions or in general-purpose compositions.

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16-05-2013 дата публикации

AMORPHOUS HEAT-FUSIBLE FIBER, FIBER STRUCTURE, AND HEAT-RESISTANT MOLDED ARTICLE

Номер: US20130123437A1
Принадлежит: KURARAY CO., LTD.

Provided are a heat-fusible fiber having excellent heat resistance, flame retardancy and dimensional stability; a fiber structure comprising the heat-fusible fiber; and a molded article produced by applying a heat fusion treatment to the fiber structure and having excellent heat resistance. The heat-fusible fiber comprises an amorphous PES type polymer (A) not substantially having a melting point and an amorphous PEI type polymer (B) in the mixture ratio (weight) of (A)/(B)=5/95 to 95/5, the fiber having a single glass transition temperature in the range between 80° C. and 200° C., and being amorphous. The fiber structure comprises 10% by weight or higher of the amorphous heat-fusible fiber. The molded article comprises at least a fiber structure comprising 10% by weight or higher of the amorphous heat-fusible fiber, to be fusion-bonded at a temperature higher than the glass transition temperature of the amorphous heat-fusible fiber. 1: An amorphous heat-fusible fiber , comprising:(A) an amorphous polyester not substantially having a melting point; and(B) an amorphous polyetherimide,wherein:a weight ratio of (A)/(B) is 5/95 to 95/5; andthe fiber has a single glass transition temperature in a range between 80° C. and 200° C.2: The amorphous heat-fusible fiber of claim 1 , wherein the amorphous polyester (A) comprises a terephthalic acid component (D) and an isophthalic acid component (E) claim 1 , wherein a copolymerization ratio (mole % ratio) of (D)/(E) ranges from 70/30 to 40/60.4: The amorphous heat-fusible fiber of claim 1 , having a dry heat shrinkage percentage of 3% or less at a temperature of (glass transition temperature −10) ° C.5: The amorphous heat-fusible fiber of claim 1 , wherein the fiber is a melt-spun and un-drawn fiber.6: A fiber structure claim 1 , comprising 10% by weight or higher of the amorphous heat-fusible fiber of .7: A heat-resistant molded article claim 1 , comprising a fiber structure claim 1 , comprising 10% by weight or higher of the ...

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23-05-2013 дата публикации

BIOMATERIAL CONTAINING DEGRADATION STABILIZED POLYMER

Номер: US20130129666A1
Принадлежит: SCIL TECHNOLOGY GMBH

The invention provides a polymer based material comprising a water binding agent present in an amount sufficient to chemically and/or physically absorb and/or adsorb water to prevent degradation of the polymer. The invention also provides a polymer based material comprising a plasticizer or organic solvent as well as a multi-component material or composite including materials encompassing a second polymer and/or an active agent. The invention further provides a pharmaceutical composition comprising the aforesaid polymer based material, which can be used for treatment of bone, cartilage and/or periodontal defects. 1. A polymer-comprising material comprising(a) a plasticizer, which is a water soluble or water miscible organic solvent,(b) a water degradable and water insoluble polymer, wherein the polymer is soluble in the plasticizer and capable of solidifying in an aqueous medium or body fluid to form a solid or semi-solid implant upon removal of the plasticizer into the surrounding tissue, and(c) a water-binding agent, wherein the water-binding agent is present in an amount of 25 wt % or less, which amount is sufficient to physically absorb and/or adsorb or chemically adsorb water to prevent degradation of the polymer, wherein the water-binding agent is silica gel, zeolite, dewatered calcium sulfate dehydrate, calcium sulfate anhydrous, sodium sulfate anhydrous, magnesium sulfate anhydrous, magnesium ethanolate, calcium ethanolate, aluminum ethanolate, or a mixture thereof;wherein the polymer-comprising material is selected from the group consisting of a tissue regeneration material, a bone filler, a bone replacement, an in situ hardening implant, a porous implant, an osteoinductive material, and a periodontal regeneration material.2. The polymer-comprising material of claim 1 , which further comprises an inorganic filler claim 1 , a pore forming agent claim 1 , a pore initiating filler claim 1 , at least a second polymer claim 1 , or any combination thereof.3. The ...

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23-05-2013 дата публикации

Compositions comprising polymers prepared from 2-hydroxyalkyl acids

Номер: US20130131190A1
Принадлежит: UNIVERSITE DE GENEVE

Described herein are compositions comprising polymers prepared by melt polycondensation of 2-hydroxyalkyl acids. Methods of making and using the compositions are also disclosed.

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23-05-2013 дата публикации

Carbonate blend composition having improved resistance to environmental stress cracking

Номер: US20130131257A1
Принадлежит: Styron LLC

The present invention relates to carbonate blend compositions demonstrating improved environmental stress crack resistance in combination with an excellent blend of impact, thermal, and physical properties. Said carbonate blend composition comprises a polycarbonate, a polyester, and a silicon-containing graft (co)polymer having a core-shell morphology, comprising a shell that contains (co)polymerized alkyl(meth)acrylate and glycidyl methacrylate grafted to a composite rubber core that contains polyorganosiloxane and poly(meth)alkyl acrylate components and methods to make said compositions.

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23-05-2013 дата публикации

POLYHYDROXYALKANOATE COMPOSITION EXHIBITING IMPROVED IMPACT RESISTANCE AT LOW LEVELS OF IMPACT MODIFIER

Номер: US20130131272A1
Принадлежит: Arkema Inc.

The invention provides a composition exhibiting improved impact resistance at low levels of impact modifier. The composition comprises a polyhydroxyalkanoic acid and: 1. A composition comprising a polyhydroxyalkanoic acid and:(A) an elastomeric compound of core-shell type; and(B) and an olefinic copolymer comprising an ethylenic monomer bearing an epoxy function;wherein the amount of (B) is from 0.01 to 0.6% by mass of the composition and the mass ratio of (A)/(B) is from 85/15 to 99.5/0.5.2. The composition as claimed in claim 1 , wherein the ethylenic monomer bearing an epoxy function is glycidyl (meth)acrylate.3. The composition as claimed in claim 1 , wherein (B) is a copolymer of ethylene claim 1 , of glycidyl methacrylate and optionally of an alkyl (meth)acrylate in which the alkyl chain comprises from 1 to 30 carbon atoms.4. The composition as claimed in claim 1 , additionally comprising an additional olefinic polymer (C) other than the olefinic copolymer comprising an ethylenic monomer bearing an epoxy function.5. The composition as claimed in claim 4 , wherein the additional olefinic polymer (C) is a copolymer of ethylene and of an alkyl (meth)acrylate claim 4 , a copolymer of ethylene and a carboxylic acid vinyl ester claim 4 , a copolymer of ethylene and of a (meth)acrylic acid or an ionomer claim 4 , preferentially a copolymer of ethylene and of an alkyl acrylate with an alkyl chain ranging from 1 to 20.6. The composition as claimed in claim 4 , in which the mass ratio (B)/(C) is within the range from 90/10 to 10/90.7. The composition as claimed in claim 1 , wherein the mass ratio (A)/(B) is within the range from 89/11 to 96/4.8. The composition as claimed in claim 1 , wherein the amount of (A)+(B) is within the range from 0.5 to 6% by mass of the composition.9. The composition as claimed in claim 1 , in which the amount claim 1 , in polymerized form claim 1 , of ethylenic monomer comprising an epoxy function is within the range from 0.005% to 0.05% by ...

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30-05-2013 дата публикации

Biodegradable material and plant container

Номер: US20130133253A1
Автор: Greg S. Patterson
Принадлежит: Aspen Acquisition Corp

A biodegradable plant container made from a cellulosically derived polymer is coated with an enhancer to facilitate biodegradation of the container.

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30-05-2013 дата публикации

Artificial hair made of flame-retardant polyester

Номер: US20130133676A1
Принадлежит: Kaneka Corp

The artificial hair of the present invention comprising a flame-retardant polyester-based fiber that is formed of a composition obtained by melt-kneading, the composition comprising: 100 parts by weight of polyester (A); 5 parts by weight to 30 parts by weight of a bromine-containing flame retardancy agent (B); and 0.5 parts by weight to 10 parts by weight of an antimony compound (C) having an average particle diameter ranging from 1.5 μm to 15 μm, wherein the polyester (A) is made of at least one polymer selected from the group consisting of polyalkylene terephthalate and copolyester, where the copolyester contains polyalkylene terephthalate as a main component, and 0.01% omf to 1% omf of a polyorganosiloxane-based fiber treating agent (E) is deposited on the flame-retardant polyester-based fiber. The artificial fiber has excellent combing smoothness, and the excellent flame retardancy.

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30-05-2013 дата публикации

POROUS FILM

Номер: US20130137788A1
Принадлежит:

The invention provides a porous film including a polylactic acid based resin (A), a thermoplastic resin (B) that is not a polylactic acid based resin, and a filler (C), wherein resin (A) and resin (B) account for 10 to 95 mass % and 5 to 90 mass %, respectively, of the sum total 100 mass % of resin (A) and resin (B), while the filler (C) accounts for 1 to 400 parts by mass of the sum total 100 parts by mass of resin (A) and resin (B), with the porosity being 1 to 80%. The present invention provides a polylactic acid based porous film that has high flexibility, moisture permeability, heat resistance, and bleed-out resistance. 1. A porous film including a polylactic acid based resin (A) , a thermoplastic resin (B) that is not a polylactic acid based resin , and a filler (C) , whereinresin (A) and resin (B) account for 10 to 95 mass % and 5 to 90 mass %, respectively, of the sum total 100 mass % of resin (A) and resin (B), while the filler (C) accounts for 1 to 400 parts by mass of the sum total 100 parts by mass of resin (A) and resin (B),with the porosity being 1 to 80%.2. A porous film as defined in wherein resin (A) is a mixture of a crystalline polylactic acid based resin and an amorphous polylactic acid based resin.3. A porous film as defined in wherein resin (B) is at least one resin selected from the group consisting of a block copolymer having a polyether segment and a polylactic acid segment claim 1 , a block copolymer having a polyester segment and a polylactic acid segment claim 1 , an aliphatic polyester based resin claim 1 , and an aliphatic-aromatic polyester based resin.4. A porous film as defined in wherein resin (B) is a combination of a one resin selected from the group consisting of a block copolymer having a polyether segment and a polylactic acid segment and a block copolymer having a polyester segment and a polylactic acid segment claim 3 , with at least one resin selected from the group consisting of an aliphatic polyester based resin and an ...

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30-05-2013 дата публикации

Resin composition

Номер: US20130137802A1
Принадлежит: Kao Corp

A resin composition containing: an ester compound including a carboxylic acid ester obtained by using (1) a monohydric alcohol having an alkyl group having 1 to 4 carbon atoms; (2) a dicarboxylic acid having an alkylene group having 2 to 4 carbon atoms; and (3) a dihydric alcohol having an alkylene group having 2 to 6 carbon atoms, the ester compound having an acid value of 1.00 mgKOH/g or less, a hydroxyl value of 5.0 mgKOH/g or less, and a number-average molecular weight of from 300 to 700; and an aliphatic polyester. Since the resin composition of the present invention inhibits the generation of volatile compounds, the resin composition can be suitably used in various industrial applications, such as daily sundries, household electric appliance parts, and automobile parts.

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30-05-2013 дата публикации

RESIN COMPOSITION COMPRISING ISOSORBIDE CONTAINING SATURATED POLYMER

Номер: US20130137823A1
Принадлежит:

The present invention relates to a resin composition comprising (a) an unsaturated polyester resin and/or a vinyl ester resin, (b) a reactive diluent and (c) a saturated polymer soluble in the reactive diluent, wherein the saturated polymer comprises isosorbide building blocks and has a molecular weight Mof at least 1500 Dalton. 1. A resin composition comprising (a) an unsaturated polyester resin and/or a vinyl ester resin , (b) a reactive diluent and (c) a saturated polymer soluble in the reactive diluent , characterized in that the saturated polymer comprises isosorbide building blocks and has a number-average molecular weight Mof at least 1500 Dalton.2. A resin composition according to claim 1 , characterized in that the saturated polymer soluble in the reactive diluent is a saturated polyester.3. A resin composition according to claim 2 , characterized in that the saturated polyester comprises claim 2 , next to the isosorbide building blocks claim 2 , saturated aliphatic dicarboxylic acid building blocks.4. A resin composition according to claim 3 , characterized in that the saturated aliphatic dicarboxylic acid has the following formula HOOC—(CH)—COOH claim 3 , in which x is an integer from 1 up to 20.5. A resin composition according to claim 4 , characterized in that x is 4.6. A resin composition according to claim 1 , characterized in that the resin composition comprises an unsaturated polyester resin.7. A resin composition according to claim 1 , characterized in that the saturated polymer has a bimodal molecular weight distribution obtained by chain extension.9. A resin composition according to claim 1 , characterized in that the composition comprises from 10 up to 70 wt. % of component (a) claim 1 , from 5 up to 50 wt. % of component (b) and from 2 up to 70 wt. % of component (c) (whereby the total amount of (a) claim 1 , (b) and (c) is considered 100 wt. %).11. An isosorbide containing polymer according to claim 10 , characterized in that P has a molecular ...

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06-06-2013 дата публикации

Use of an antimony-free polyester film for producing film bags and film tubes with high heat resistance

Номер: US20130142973A1
Принадлежит: Mitsubishi Polyester Film GmbH

Film bags or film tubes formed from biaxially oriented film including less than 10 ppm of antimony and having a haze of less than 10% are provided. The films have an ultimate tensile strength of more than 100 N/mm; have a difference in the ultimate tensile strength in MD and TD of less than 180 N/mm; have a tensile strain at break of more than 50%; a tensile strain at break of more than 260%; have a yellowness index b* of less than 2.5; have a lightness L*>85; include from 50 to 15000 ppm of free-radical scavenger; have an SV of at least 600 after ovening; have a tensile strain at break of >5% after ovening; have a film thickness of from 6 to 26 μm; and include more than 90% by weight of polyester. 1. Film bags or film tubes comprising a biaxially oriented film whicha) comprises less than 10 ppm of antimony;b) has a haze of less than 10%;{'sup': '2', 'c) has an ultimate tensile strength of more than 100 N/mmin every direction of the film;'}{'sup': '2', 'd) has a difference in the ultimate tensile strength in machine direction (MD) and transverse direction (TD) of less than 180 N/mm;'}e) has a tensile strain at break of more than 50% in every direction of the film;f) has a tensile strain at break of more than 260% in no direction of the film;g) has a yellowness index b* of less than 2.5;h) has a lightness L*>85;i) comprises from 50 to 15000 ppm of a free-radical scavenger;j) has a film SV value of at least 600 after the oven test;k) has a tensile strain at break of >5% in every direction of the film after the oven test;1) has a film thickness of from 6 to 26 μm; andm) is comprised of more than 90% by weight of a polyester.2. Film bags or film tubes as claimed in claim 1 , wherein the film comprises one or more free-radical scavengers selected from the group consisting of the compounds with the CAS number 1709-70-2 claim 1 , 3135-18-0 claim 1 , 6683-19-8 and 57569-40-1.3. A biaxially oriented polyester film whicha) comprises less than 2 ppm of antimony;b) has a haze ...

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13-06-2013 дата публикации

FLAME-RETARDANT COPOLYETHERESTER COMPOSITION AND ARTICLES COMPRISING THE SAME

Номер: US20130146330A1
Автор: NI YONG
Принадлежит: E I DU PONT DE NEMOURS AND COMPANY

Disclosed herein is a flame-retardant copolyetherester composition comprising: (a) at least one copolyetherester; (b) about 5-35 wt % of at least one halogen-free flame retardant; (c) about 0.1-20 wt % of at least one nitrogen-containing compound; (d) about 0.1-10 wt % of at least one aromatic phosphate and (e) about 0.1-10 wt % of at least at least one novolac resin. Further disclosed herein are articles comprising component parts formed of the flame-retardant copolyetherester composition. 2. The flame-retardant copolyetherester composition of claim 1 , wherein the at least one copolyetherester is present at a concentration of 25-94.7 wt % claim 1 , with the total wt % of all components of the copolyetherester composition totaling to 100 wt %.3. The flame-retardant copolyetherester composition of claim 1 , wherein the at least one copolyetherester is present at a concentration of 40-94.7 wt % claim 1 , with the total wt % of all components of the copolyetherester composition totaling to 100 wt %.4. The flame-retardant copolyetherester composition of claim 1 , wherein the at least one copolyetherester is present at a concentration of 40-90 wt % claim 1 , with the total wt % of all components of the copolyetherester composition totaling to 100 wt %.5. The flame-retardant copolyetherester composition of claim 1 , wherein in the at least one halogen-free flame retardant claim 1 , each of Rand Ris hydrogen.6. The flame-retardant copolyetherester composition of claim 1 , wherein the at least one halogen-free flame retardant is aluminum hypophosphite.7. The flame-retardant copolyetherester composition of claim 1 , wherein the at least one halogen-free flame retardant is present at a concentration of 5-30 wt % claim 1 , with the total wt % of all components of the copolyetherester composition totaling to 100 wt %.8. The flame-retardant copolyetherester composition of claim 1 , wherein the at least one halogen-free flame retardant is present at a concentration of 7.5-30 wt ...

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13-06-2013 дата публикации

ISOCYANATE-TERMINATED PREPOLYMER

Номер: US20130150534A1
Принадлежит: Rohm and Haas Company

An isocyanate-terminated prepolymer having three components. The first component is 30-60 wt % polymerized residues of a first polyol containing a substituent of formula (I) 2. The isocyanate-terminated prepolymer of in which the first polyol comprises from 3 wt % to 9 wt % of esterified residues of at least one C-Canhydride claim 1 , C-Cdiacid or C-Clactone.3. The isocyanate-terminated prepolymer of in which the first polyol comprises from 0.35 to 0.38 units of formula (I) per fatty acid hydrocarbyl group.4. The isocyanate-terminated prepolymer of in which the first polyol comprises from 15 wt % to 27 wt % polymerized residues of at least one C-Caliphatic diol and has a hydroxyl number from 100 to 125 mg KOH/g.5. The isocyanate-terminated prepolymer of comprising 4-14 wt % polymerized residues of a glycol having Mfrom 300 to 3500.7. The two-component urethane system of in which the first polyol comprises from 3 wt % to 9 wt % esterified residues of at least one C-Canhydride claim 6 , C-Cdiacid or C-Clactone.9. The two-component urethane system of in which polymerized residues of at least one C-Caliphatic diol are present in the second polyol in an amount from 15 wt % to 32 wt % and the second polyol has a hydroxyl number from 150 to 195 mg KOH/g.10. The two-component urethane system of in which the second polyol comprises 3 wt % to 9 wt % esterified residues of a C-Caromatic anhydride. This invention relates generally to an isocyanate-terminated prepolymer produced from biological materials.The use of triglycerides in preparation of alkyd resins is well known. Typically, these resins are produced without modifying the fatty acid chains, but rather by utilizing the triglyceride ester groups to react with acids and glycols to form polyesters. Such resins usually have high molecular weights and require solvent to deliver the resin in a coating application.Production of condensation products useful in paints from reaction of triglycerides with maleic anhydride, ...

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27-06-2013 дата публикации

HEAT-SHRINKABLE FILM, MOLDED PRODUCT AND HEAT-SHRINKABLE LABEL EMPLOYING THE FILM, AND CONTAINER EMPLOYING THE MOLDED PRODUCT OR HAVING THE LABEL FITTED THEREON

Номер: US20130164468A1
Принадлежит: MITSUBISHI PLASTICS, INC.

A heat-shrinkable film having a layer made of a mixed resin containing a polylactic acid resin and a polyolefin resin as the main components, wherein the mass ratio of the polylactic acid resin and the polyolefin resin is 95/5 to 50/50, the polylactic acid resin is a copolymer of D-lactic acid and L-lactic acid or a mixed resin of the copolymer, the D/L ratio of D-lactic acid and L-lactic acid is 3/97 to 15/85 or 85/15 to 97/3, the storage elastic modulus of the polyolefin resin or the soft acrylic resin at 20° C. is ≦ MPa as measured at an oscillation frequency of Hz and a strain of 0.1%, the film is stretched in at least one direction, and the heat shrinkage ratio of the film in the main shrinking direction is ≧20% as measured after the film is immersed in 80° C. water for 10 seconds. 15-. (canceled)6. A heat-shrinkable film consisting of a layer or comprising at least one layer , wherein the layer is made of a mixed resin containing a polylactic acid resin and a soft acrylic resin as the main components , wherein mass ratio of the polylactic acid resin and the soft acrylic resin is 95/5 to 50/50 by mass , the polylactic acid resin being a copolymer of D-lactic acid and L-lactic acid or a mixed resin of the copolymer , the storage elastic modulus (E′) of the soft acrylic resin at 20 degree C. being 100 MPa or less as measured at an oscillation frequency of 10 Hz and a strain of 0.1% , the film being stretched in at least one direction , and the heat shrinkage ratio of the film in the main shrinking direction being 20% or more as measured after the film is immersed in hot water of 80 degree C. for 10 seconds.7. The heat-shrinkable film according to claim 6 , wherein D/L ratio of D-lactic acid and L-lactic acid is 3/97 to 15/85 or 85/15 to 97/3.8. The heat-shrinkable film according to claim 6 , wherein the soft acrylic resin comprises: at least one polymer block (A) composed of an acrylic acid ester (a); and at least one polymer block (B) composed of a (meth) ...

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04-07-2013 дата публикации

THERMOPLASTIC RESIN FOAM, METHOD OF PRODUCING THE SAME, AND LIGHT REFLECTING MATERIAL THEREOF

Номер: US20130172438A1
Принадлежит: FURUKAWA ELECTRIC CO., LTD.

{Problems} 1. A thermoplastic resin foam , prepared by using a thermoplastic resin composition containing a melt-type crystallization nucleating agent (B) in a crystalline thermoplastic resin (A) , which foam comprises a bubble having a mean bubble diameter of less than 1 μm in the inside thereof.2. The thermoplastic resin foam according to claim 1 , wherein the crystalline thermoplastic resin (A) is a crystalline polyester resin.3. The thermoplastic resin foam according to claim 1 , wherein the melt-type crystallization nucleating agent (B) is contained in an amount of 0.1 to 2.0 part(s) by mass claim 1 , with respect to 100 parts by mass of the crystalline thermoplastic resin (A).4. The thermoplastic resin foam according to claim 1 , wherein a total reflectivity at a light wavelength of 550 nm is 100% or more in terms of an aluminum oxide ratio.5. A light reflecting material claim 1 , which is molded by using the thermoplastic resin foam according to .6. A method of producing a thermoplastic resin foam claim 1 , comprising the steps of:impregnating a resin composition sheet containing a crystalline thermoplastic resin (A) and a melt-type crystallization nucleating agent (B) with an inert gas by maintaining the sheet in a pressurized inert gas atmosphere; andfoaming by heating the sheet impregnated with the inert gas under normal pressure.7. The method of producing a thermoplastic resin foam according to claim 6 , wherein the crystalline thermoplastic resin (A) is a crystalline polyester resin.8. The method of producing a thermoplastic resin foam according to claim 6 ,wherein the melt-type crystallization nucleating agent (B) is contained in an amount of 0.1 to 2.0 part(s) by mass, with respect to 100 parts by mass of the crystalline thermoplastic resin. The present invention relates to a thermoplastic resin foam having fine bubbles in the inside thereof, and a production method of the thermoplastic resin foam and a light reflecting material thereof.Synthetic resin ...

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04-07-2013 дата публикации

Copolyester blends with improved melt strength

Номер: US20130172456A1
Принадлежит: EI Du Pont de Nemours and Co

Blends comprising 65-95 wt % poly(trimethylene terephthalate-co-sebacate), 5 to 35 wt % polylactic acid and a chain extender are provided that exhibit greatly increased melt strength compared to that of poly(trimethylene terephthalate-co-sebacate) alone. Such improvements allow these compositions to be processed readily by melt-blowing, which is useful for packaging and for preparing items such as biodegradable garbage bags.

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04-07-2013 дата публикации

FLAME RETARDANT POLYALKYLENE TERPHTHALATE/POLYCARBONATE COMPOSITIONS

Номер: US20130172467A1
Принадлежит: Bayer Intellectual Property GmbH

The present invention relates to polyalkylene terephthalate/polycarbonate compositions, containing 1. A composition comprisingA) 49 to 70 parts by weight aromatic polycarbonate,B) 21 to 40 parts by weight polyalkylene terephthalate with more than 2 carbons in a diol component thereof,C) 6 to 25 parts by weight of a salt of a phosphinic acid.D) 0 to 24 parts by weight one or more additives,all parts by weight being standardised such that a sum of the parts by weight of components A+B+C+D in the composition adds up to 100.2. The composition according to claim 1 , wherein a quotient of component A) to B) is in a range of from 1.4 to 3.5.3. The composition according to claim 1 , wherein a quotient of component A) to B) is in a range of from 1.6 to 2.7.4. The composition according to claim 1 , comprising 53 to 61 parts by weight aromatic polycarbonate component A).5. The composition according to claim 1 , comprising 25 to 33 parts by weight polyalkylene terephthalate with more than 2 carbons in the diol component according to component B).6. The composition according to claim 1 , comprising 7 to 22 parts by weight of a salt of a phosphinic acid according to component C).7. The composition according to claim 1 , comprising 10 to 20 parts by weight of a salt of a phosphinic acid according to component C).8. The composition according to claim 1 , comprising 0 to 50 parts by weight conventional additives according to component D).9. The composition according to claim 1 , wherein component B is polybutylene terephthalate.11. The composition according to claim 10 , wherein the metal cation is Li claim 10 , Na claim 10 , K claim 10 , Mg claim 10 , Ca claim 10 , Sr claim 10 , Ba claim 10 , Al claim 10 , Zn claim 10 , Mn claim 10 , Fe and/or Fe.12. The composition according to claim 11 , wherein M=Ca and m=2.13. The composition according to claim 1 , wherein an average particle size dof the phosphinic acid salt (component C) is not more than 80 μm.14. The composition according to ...

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04-07-2013 дата публикации

ANTI-WEAR MATERIAL OF MODIFIED POLYTETRAFLUOROETHYLENE

Номер: US20130172487A1
Принадлежит:

An anti-wear material of modified polytetrafluoroethylene resin is provided, which is prepared by mixing sufficiently a polyphenyl p-hydroxybenzoate polymer used as modifier with polytetrafluoroethylene resin in a certain weight ratio, and then carrying out cold-press sintering or hot-press sintering. The anti-wear material made from the modified polytetrafluoroethylene resin has very low average wear coefficient. 1. An anti-wear material of modified polytetrafluoroethylene resin , characterized in that it is prepared by mixing sufficiently a polyphenyl p-hydroxybenzoate polymer with polytetrafluoroethylene resin , and then carrying out cold-press sintering or hot-press sintering.2. The anti-wear material according to claim 1 , wherein the content of the polyphenyl p-hydroxybenzoate polymer is 15-50% by weight claim 1 , and the content of the polytetrafluoroethylene resin is 50-85% by weight.3. The anti-wear material according to claim 2 , wherein the content of the polyphenyl p-hydroxybenzoate polymer is 20-45% by weight claim 2 , and the content of the polytetrafluoroethylene resin is 55-80% by weight.4. The anti-wear material according to claim 3 , wherein the content of the polyphenyl p-hydroxybenzoate polymer is 25% by weight claim 3 , and the content of the polytetrafluoroethylene resin is 75% by weight. The invention relates to an anti-wear material, in particular, an anti-wear material of modified polytetrafluoroethylene resin.Currently, the anti-wear materials used in China mainly include phenolic resin, fiber glass, molybdenum disulfide and carbon fiber etc. However, the major deficiency of these materials is the severe grinding abrasion.Additionally, polytetrafluoroethylene is often modified in conventional methods by adding inorganic fillers such as fiber glass, graphite and molybdenum disulfide into it; however, due to high abrasion and short life span, these materials are apt to bring abrasion to the grinding mating-parts.The object of the invention is ...

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11-07-2013 дата публикации

POLYMER NANOCOMPOSITE COMPRISING POLYLACTIC ACID REINFORCED WITH THE MODIFIED PHYLLOSILICATE

Номер: US20130177723A1

Polymer nanocomposite having: a) a polylactic polymer; and b) a modified phyllosilicate composition having a modifying agent which includes hexadecyl trimethyl ammonium cations which are intercalated between the layers of the phyllosilicate; and preparation process of such a polymer nanocomposite. The polymer nanocomposite is particularly useful for packaging, particularly food and drink packaging. 1. A polymer nanocomposite comprising:a) a polylactic polymer; andb) a modified phyllosilicate composition comprising a modifying agent including hexadecyl trimethyl ammonium cations which are intercalated between the layers of the phyllosilicate.2. The nanocomposite according to claim 1 , wherein the phyllosilicate composition further comprises acetylcholine cations as a modifying agent.3. The nanocomposite according to claim 1 , wherein the phyllosilicate composition further comprises choline cations as a modifying agent.4. The nanocomposite according to wherein the ratio phyllosilicate composition/polylactic polymer is comprised between 0.5: 99.5 and 20:80 weight/weight ratio.5. The nanocomposite according to wherein the phyllosilicate is selected from the group consisting of sodium montmorillonite claim 1 , magnesium montmorillonite claim 1 , and calcium montmorillonite.6. The nanocomposite according to wherein the phyllosilicate is sodium montmorillonite.7. The nanocomposite according to wherein the amount of acetylcholine is 0.10-1.00 meq/100 g the value of the phyllosilicate CEC and the amount of hexadecyl trimethyl ammonium cation is 0.4-9.9 the value of the phyllosilicate CEC.8. A process for the preparation of the nanocomposite according to claim 1 , which comprises:a) drying the modified phyllosilicate and the polylactic polymer; andb) melt-blending the polymer and the modified phyllosillicate by an extruder.9. The process according to claim 8 , wherein the melt-blending operation is carried out at a temperature between 190° C.-210° C.10. The process according ...

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11-07-2013 дата публикации

STEREOCOMPLEX POLYLACTIC ACID FILM AND RESIN COMPOSITION

Номер: US20130178567A1
Принадлежит: TEIJIN LIMITED

A stereocomplex polylactic acid resin composition containing an amide compound represented by the following general formula (1) and a film composed thereof. A stereocomplex polylactic acid excellent in transparency and a resin composition can be provided. 3. The stereocomplex polylactic acid film according to claim 1 , wherein the crystallinity (C) is 90% or more.4. The stereocomplex polylactic acid film according to claim 1 , wherein the crystallinity (C) is 70% or less.5. The stereocomplex polylactic acid film according to claim 1 , wherein the stereocomplex crystallinity (S) is 90% or more.6. The stereocomplex polylactic acid film according to claim 1 , wherein the haze is 1% or less.7. The stereocomplex polylactic acid film according to claim 1 , wherein the absolute value of the out-of-plane retardation (Rth) is 20 nm or less.8. The stereocomplex polylactic acid film according to claim 1 , wherein the out-of-plane retardation (Rth) is −20nm or less. The present invention relates to a stereocomplex polylactic acid film especially excellent in transparency and a resin composition, more particularly to a stereocomplex polylactic acid film for which low retardation is required.As a transparent polymeric substrate for optical use, for example, for liquid display, touch panel, etc., a cellulosic film such as triacetyl cellulose, a polyester film such as polyethyleneterephthalate film, a polycarbonate film, etc. are known.However, since these resins originate from petroleum which is a finite resource as the starting material, a problem of depletion of the petroleum resource is concerned.In recent years, a polylactic acid polymer is drawing attention as a material with which the above-mentioned problem may be solved. As a fact, there have been a lot of studies and developments on this material. The problem of depletion of resource may be solved by using a polylactic acid polymer, since its starting material is a plant material, such as corn. However, since polylactic ...

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25-07-2013 дата публикации

BIOCOMPATIBLE HYDROPHILIC COMPOSITIONS

Номер: US20130190408A1
Принадлежит:

Durable hydrophilic compositions comprising aliphatic polyester, an anionic surfactant, and in some embodiments, a carrier. 1. A durable hydrophilic composition , comprising:at least one thermoplastic aliphatic polyester;one or more alkyl, alkenyl, aralkyl or alkaryl anionic surfactants having a melting point of less than 200° C.;wherein the surfactant is incorporated into the polyester.2. A durable hydrophilic composition comprising a blend of:at least one thermoplastic aliphatic polyester; andone or more alkyl, alkenyl, aralkyl or alkaryl anionic surfactants;wherein the surfactant is incorporated into the polyester, and wherein the composition remains hydrophilic after more than 10 days at 45° C.3. A durable hydrophilic composition comprising a blend of:at least one thermoplastic aliphatic polyester; andone or more alkyl, alkenyl, aralkyl or alkaryl anionic surfactants;wherein the composition remains hydrophilic after more than 10 days at 45° C.43. The composition of any of , , or , further comprising a surfactant carrier.54. The composition of any of , , , or , wherein the thermoplastic aliphatic polyester is selected from the group consisting of one or more poly(lactic acid) , poly(glycolic acid) , poly(lactic-co-glycolic acid) , polybutylene succinate , polyhydroxybutyrate , polyhydroxyvalerate , blends , and copolymers thereof.64. The composition of , , , or , further comprising a thermoplastic polymer distinct from the thermoplastic aliphatic polyester.7. The composition of any of the preceding claims , wherein the thermoplastic aliphatic polyester is present in an amount greater than 60% by weight of the thermoplastic polymer present in the composition.8. The composition of any one of the preceding claims , wherein the anionic surfactant is selected from the group consisting of one or more alkyl , alkenyl , alkaryl and arakyl sulfonates; alkyl , alkenyl , alkaryl and arakyl sulfates; alkyl , alkenyl , alkaryl and arakyl phosphonates; alkyl , alkenyl , ...

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01-08-2013 дата публикации

Synthesis of abietic acid-based macromer for polyester resin process

Номер: US20130196262A1
Принадлежит: Xerox Corp

An improved polycondensation method for bio-based polyesters synthesized from pre-formed macromers and the corresponding compositions, which are useful for producing binder polymers for imaging applications such as emulsion-aggregation (EA) toner.

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01-08-2013 дата публикации

Injection Molded Article Comprising Polypropylene and Polylactic Acid

Номер: US20130197161A1
Принадлежит: Fina Technology Inc

A film comprising a polylactic acid and polypropylene blend having a haze of from about 10% to about 95% and a gloss 45° of from about 50 to about 125. A method of producing an oriented film comprising blending polypropylene and polylactic acid to form a polymeric blend, forming the polymeric blend into a film, and orienting the film. A method of producing an injection molded article comprising blending polypropylene and polylactic acid to form a polymeric blend, injecting the polymeric blend into a mold, and forming the article.

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08-08-2013 дата публикации

HIGHLY THERMALLY CONDUCTIVE RESIN MOLDED ARTICLE, AND MANUFACTURING METHOD FOR SAME

Номер: US20130202882A1
Принадлежит: KANEKA CORPORATION

The present invention provides a highly thermally conductive resin molded article that satisfies all demands of a high thermal conductivity, an insulation property, a low density, a mechanical strength, a high flowability of a thin-walled molded article, less abrasion on a die used for manufacturing, and high whiteness. The highly thermally conductive resin molded article at least includes (A) thermoplastic polyester resin, (B) platy talc particles, and (C) a fiber reinforcement, and (B) platy talc particle content falls within a range between 10% by volume and 60% by volume, where the entire composition is 100% by volume, a number average particle size of the platy talc particles falls within a range between 20 μm and 80 μm, and the (B) platy talc particles are oriented in a surface direction of the highly thermally conductive resin molded article. 1. A highly thermally conductive resin molded article at least comprising:(A) thermoplastic polyester resin;(B) platy talc particles; and(C) a fiber reinforcement,(B) platy talc particle content falling within a range between 10% by volume and 60% by volume, where an entire composition is 100% by volume,a number average particle size of the (B) platy talc particles falling within a range between 20 μm and 80 μm, andthe (B) platy talc particles being oriented in a surface direction of said highly thermally conductive resin molded article.2. The highly thermally conductive resin molded article as set forth in claim 1 , wherein:said highly thermally conductive resin molded article has been molded by an injection molding method.3. The highly thermally conductive resin molded article as set forth in claim 1 , wherein:a volume ratio of the (B) platy talc particles is higher than that of the (C) fiber reinforcement.4. The highly thermally conductive resin molded article as set forth in claim 1 , wherein:a melt flow rate falls within a range between 5 g/10 min and 200 g/10 min under a condition that a temperature is 280° C. and ...

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08-08-2013 дата публикации

METHOD FOR PRODUCING AQUEOUS DISPERSION OF RESIN FINE PARTICLES AND METHOD FOR PRODUCING TONER

Номер: US20130202998A1
Принадлежит: CANON KABUSHIKI KAISHA

The present invention provides a method for producing an aqueous dispersion of resin fine particles wherein the particle size of the obtained resin particles is small and the aqueous dispersion is excellent in productivity, the production method including: mixing a resin having an acid group, a betaine surfactant and a solvent capable of dissolving the resin having an acid group to obtain a mixture; and emulsifying the mixture by placing the mixture in an aqueous medium and by applying shear force to the mixture under a condition of pH=7.0 or more to obtain an emulsion. 1. A method for producing an aqueous dispersion of resin fine particles , comprising the steps of:(A-1) preparing a mixture A by mixing a resin having an acid group, a betaine surfactant and a solvent capable of dissolving the resin; and(A-2) preparing an emulsion A by adding the mixture A into an aqueous medium, and applying shear force to the mixture A in the aqueous medium under a condition of pH=7.0 or more.2. The method for producing an aqueous dispersion of resin fine particles according to claim 1 , wherein the betaine surfactant comprises a carboxylate group.3. The method for producing an aqueous dispersion of resin fine particles according to claim 1 , wherein the betaine surfactant is an amide betaine.4. A method for producing an aqueous dispersion of resin fine particles claim 1 , comprising:(B-1) preparing a mixture B by mixing a resin having an acid group, a betaine surfactant and an aqueous medium; and(B-2) preparing an emulsion B by applying shear force to the resin in the mixture B under a condition of pH=7.0 or more and at a temperature equal to or higher than the glass transition temperature (Tg) of the resin.5. The method for producing an aqueous dispersion of resin fine particles according to claim 4 , wherein the betaine surfactant comprises a carboxylate group.6. The method for producing an aqueous dispersion of resin fine particles according to claim 4 , wherein the betaine ...

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08-08-2013 дата публикации

Polybutylene terephthalate resin composition

Номер: US20130203905A1
Принадлежит: WinTech Polymer Ltd

To provide a polybutylene terephthalate resin composition having excellent tracking resistance, mechanical strength, and low-hygroscopicity, and being flame-retarded by a non-halogen-containing flame retardant. A polybutylene terephthalate resin composition is prepared by compounding polyamide resin, an organic phosphorous flame retardant, and a nitrogen-containing flame retardant assistant into polybutylene terephthalate resin, wherein the content of the polyamide resin is not less than 1 part by mass and not more than 15 parts by mass to 100 parts by mass of the polybutylene terephthalate resin.

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08-08-2013 дата публикации

OUTER CASING FOR ELECTRIC DEVICE

Номер: US20130203923A1
Автор: Yamashita Takehiko
Принадлежит: Panasonic Corporation

An outer casing for an electric device is obtained by molding a flame-retarded resin composition including a resin component containing 50% by weight or more of poly(lactic acid) and/or a lactic acid copolymer, of which each is an environmental resin, and silica-magnesia catalyst particles and a polyphosphate salt as flame retardance-imparting components which impart flame retardancy, wherein the combined content of the silica-magnesia catalyst particles and the polyphosphate salt is 10% by weight or less of the total weight of the flame-retarded resin composition. 1. An outer casing for an electric device , which is obtained by molding a flame-retarded resin composition comprising a resin component containing 50% by weight or more of poly(lactic acid) and/or a lactic acid copolymer , and silica-magnesia catalyst particles and a polyphosphate salt as flame retardance-imparting components which impart flame retardancy , wherein the combined content of the silica-magnesia catalyst particles and the polyphosphate salt is 10% by weight or less of the total weight of the flame-retarded resin composition.2. The outer casing for an electric device according to claim 1 , wherein the content of the silica-magnesia catalyst particles is 0.3% or more and 9.70 or less by weight of the total weight of the flame-retarded resin composition.3. The outer casing for an electric device according to claim 1 , wherein the content of the polyphosphate salt is 0.3% or more and 9.7% or less by weight of the total weight of the flame-retarded resin composition.4. The outer casing for an electric device according to claim 1 , wherein the silica-magnesia catalyst particles do not have hydrogen atoms composing crystal water or a hydroxyl group in the molecule.5. A resin molded article claim 1 , which is obtained by molding a flame-retarded resin composition comprising a resin component containing 50% by weight or more of poly(lactic acid) and/or a lactic acid copolymer claim 1 , and silica- ...

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08-08-2013 дата публикации

Low temperature cure heat-curable powder coating composition comprising a crystalline polyester resin, an amorphous polyester resin, a crosslinking agent and a thermal radical initiator

Номер: US20130203938A1
Принадлежит: DMS IP Assets BV

The invention relates to a heat-curable powder coating composition comprising i) at least one crystalline polyester resin present in an amount of at most 90 wt %; and ii) at least one amorphous polyester resin; and iii) at least one crosslinking agent; and iv) at least one thermal radical initiator, wherein, the at least one crystalline polyester resin and/or the at least one amorphous polyester resin has di-acid ethylenic unsaturations; wherein the at least one crosslinking agent is either crystalline or amorphous; wherein the at least one crosslinking agent has reactive unsaturations that are reactable with the ethylenic unsaturations of the di-acid ethylenic unsaturations of the at least one crystalline polyester resin and/or the at least one amorphous polyester resin to be crosslinked, said unsaturations of the crosslinking agent are different from the unsaturations of the at least one crystalline polyester resin and the unsaturations of the at least amorphous polyester resin; wherein the wt % is based on the total amount of i)+ii)+iii). The compositions of the invention may be cured to an acceptable degree at low temperature of for example at most 130° C. for at most 20 minutes, said compositions may be ground, sieved and extrudable and said compositions can upon heat cure form powder coatings that may also exhibit a good balance of properties between good flexibility, good smoothness and good adhesion. In addition, the compositions of the invention can suitably be used on heat- and/or non heat-sensitive, even if the composition is highly pigmented.

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15-08-2013 дата публикации

Renewable Polyester Film having a Low Modulus and High Tensile Elongation

Номер: US20130209770A1
Принадлежит: Kimberly Clark Worldwide Inc

A film that is formed from a thermoplastic composition is provided. The thermoplastic composition contains a rigid renewable polyester and a polymeric toughening additive. The toughening additive can be dispersed as discrete physical domains within a continuous matrix of the renewable polyester. An increase in deformation force and elongational strain causes debonding to occur in the renewable polyester matrix at those areas located adjacent to the discrete domains. This can result in the formation of a plurality of voids adjacent to the discrete domains that can help to dissipate energy under load and increase tensile elongation. To even further increase the ability of the film to dissipate energy in this manner, the present inventors have discovered that an interphase modifier may be employed that reduces the degree of friction between the toughening additive and renewable polyester and thus reduces the stiffness (tensile modulus) of the film.

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15-08-2013 дата публикации

BIOABSORBABLE POLYMER COMPOSITIONS EXHIBITING ENHANCED CRYSTALLIZATION AND HYDROLYSIS RATES

Номер: US20130210310A1
Принадлежит: ETHICON, INC.

A bimodal bioabsorbable polymer composition. The composition includes a first amount of a bioabsorbable polymer polymerized so as to have a first molecular weight distribution; a second amount of said bioabsorbable polymer polymerized so as to have a second molecular weight distribution having a weight average molecular weight between about 10,000 to about 50,000 Daltons, the weight average molecular weight ratio of said first molecular weight distribution to said second molecular weight distribution is at least about two to one; wherein a substantially homogeneous blend of said first and second amounts of said bioabsorbable polymer is formed in a ratio of between about 50/50 to about 95/5 weight/weight percent. Also disclosed are a medical device, a method of making a medical device and a method of melt blowing a semi-crystalline polymer blend. 1. A bimodal polymer composition , comprising:(a) a first amount of a semi-crystalline bioabsorbable polymer having a first crystallization rate and a first hydrolysis rate and a first molecular weight distribution; and(b) a second amount of said semi-crystalline bioabsorbable polymer having a second crystallization rate and a second hydrolysis rate and a second molecular weight distribution having a weight average molecular weight between about 10,000 to about 50,000 Daltons, the weight average molecular weight ratio of said first molecular weight distribution to said second molecular weight distribution is at least about two to one;wherein a substantially homogeneous blend of said first and second amounts of said semi-crystalline bioabsorbable polymer is formed in a ratio of between about 50/50 to about 95/5 weight/weight percent, said substantially homogeneous blend having a crystallization rate greater than each of said first crystallization rate and said second crystallization rate and a hydrolysis rate greater than each of said first hydrolysis rate and said second hydrolysis rate.2. The bimodal polymer composition of ...

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15-08-2013 дата публикации

Polyurethane hot-melt adhesive produced from polyacrylates and polyesters

Номер: US20130210989A1
Автор: Michael Krebs, Uwe Franken
Принадлежит: Henkel AG and Co KGaA

A solvent-free moisture-curing polyurethane hot-melt adhesive composition, in which the adhesive comprises the following components: 20 to 85 wt % of a polyurethane prepolymer with free isocyanate groups produced from at least one polyol from the group of polyether polyols, polyester polyols, polyalkylene polyols and mixtures thereof with an excess of at least one polyisocyanate, the prepolymer having a monomeric diisocyanate content of below 1 wt %, 4 to 40 wt % of at least one acrylate copolymer with a molecular weight of below 60,000 g/mol, 3 to 35 wt % of a thermoplastic polyester with a number-average molecular weight (MN) of below 6000 g/mol, which comprises fewer than 1.4 NCO-reactive groups, and 0 to 25 wt % of at least one additive from the group of catalysts, resins, plasticizers, fillers, pigments, stabilizers or adhesion promoters, the sum of the constituents being equal to 100 wt %.

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22-08-2013 дата публикации

SECONDARY AQUEOUS DISPERSIONS OF BIODEGRADABLE DIBLOCK COPOLYESTERS, PROCESSES FOR PREPARATION THEREOF AND USE THEREOF

Номер: US20130214441A1
Принадлежит: PHILLIPS-UNIVERSITÄT MARBURG

The present invention provides aqueous stable suspensions of biodegradable diblock copolyesters and a method for their production. The diblock copolyesters comprise one block of an aliphatic polyester and one block of a polyethylene oxide. 2. The stable secondary aqueous suspension according to claim 1 , wherein Y is a linear claim 1 , branched or cyclic alkyl group and X a linear claim 1 , branched or cyclic alkyl group or a phenyl group.3. The stable secondary aqueous suspension according to claim 1 , wherein the aliphatic ester is an ester of an 1 claim 1 ,ω-alkane dicarboxylic acid selected from the group consisting of malonic acid claim 1 , succinic acid claim 1 , glutaric acid claim 1 , adipic acid claim 1 , pimelic acid claim 1 , suberic acid claim 1 , azelaic acid claim 1 , sebacic acid claim 1 , dodecanoic acid claim 1 , brassylic acid claim 1 , and tetradecanoic acid.4. The stable secondary aqueous suspension according to claim 1 , wherein the aliphatic ester is an ester of an alkanediol selected from the group consisting of 1 claim 1 ,2-propanediol claim 1 , 1 claim 1 ,3-propanediol claim 1 , 1 claim 1 ,4-butanediol claim 1 , 1 claim 1 ,5-pentanediol claim 1 , 1 claim 1 ,6-hexanediol claim 1 , 1 claim 1 ,7-heptanediol claim 1 , 1 claim 1 ,8-octanediol claim 1 , 1 claim 1 ,9-nonanediol claim 1 , 1 claim 1 ,10-decanediol claim 1 , 1 claim 1 ,11-undecanediol claim 1 , and 1 claim 1 ,12-dodecanediol.5. The stable secondary aqueous suspension according to claim 1 , wherein the size of the polyethylene glycol block amounts to 500 to 10 claim 1 ,000 dalton.6. The stable secondary aqueous suspension according to claim 1 , wherein polyester and polyethylene glycol blocks are present in a molar ratio of (polyester block:polyethylene glycol block) of 0.5 to 1.5:0.5 to 1.5.7. The stable secondary aqueous suspension according to claim 1 , wherein the solid content is at least 10 wt. % and a maximum of 30 wt. %.8. The stable secondary aqueous suspension according to ...

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22-08-2013 дата публикации

Polyester Composition And Method For Preparing Articles By Extrusion Blow Molding

Номер: US20130216753A1
Автор: Sequeira Clarence
Принадлежит: PEPSICO, INC.

Polyester compositions described herein have properties which are particularly suitable for extrusion blow molding (EBM). These properties relate primarily to the rate of crystallization and melt strength or melt viscosity. Articles prepared from the polyester compositions exhibit good clarity, aesthetics, and other physical properties. The polyester compositions also exhibit broad molecular weight distribution (MWD), resulting in improved processability and melt strength. The crystallization rate allows for good drying characteristics while also enabling the use of regrind. In addition, the compositions exhibit improved recyclability, such as in existing PET recycling streams. In one aspect, articles are prepared in an extrusion blow molding method by combining a dry first polyester copolymer component, a dry second polyester component, and a chain extender to form a feed material suitable for extrusion blow molding. In another aspect, a single component co-polyester and a chain extender are combined to form a feed material. 1. A process of extrusion blow molding an article comprising:combining a single component co-polyester and a chain extender to form a feed material suitable for extrusion blow molding; andfeeding the feed material to an extrusion blow molding machine to form an extruded article.2. The process of further comprising combining regrind material with the feed material.3. The process of wherein the regrind material is combined in an amount up to about 90 wt % based on the total weight of the feed material.4. The process of wherein the regrind material is combined in an amount up to about 50 wt % based on the total weight of the feed material.5. The process of wherein the regrind material comprises excess material recovered from the process of extrusion blow molding the article.6. The process of wherein the co-polyester comprises an unbranched or lightly branched polyethylene terephthalate copolymer of 1 claim 1 ,4-cyclohexane-dicarboxylic acid claim ...

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22-08-2013 дата публикации

PLA-CONTAINING MATERIAL

Номер: US20130217815A1
Принадлежит: Andersen Corporation

PLA-containing materials, and building components containing such materials, include: polylactic acid (PLA); one or more inorganic pigments; and one or more stabilizers that includes one or more carbodiimide groups. 1. A PLA-containing building component comprising:polylactic acid (PLA);{'sub': '2', 'at least 3 wt-% TiOpigment, based on the total weight of the PLA-containing building component; and'}at least 0.5 wt-% of one or more stabilizers comprising one or more carbodiimide groups, based on the total weight of the PLA-containing building component.2. The PLA-containing building component of wherein the polylactic acid is at least 90 wt-% L-polylactic acid (PLA) claim 1 , based on the total weight of the PLA.3. The PLA-containing building component of wherein the PLA claim 1 , TiOpigment claim 1 , and stabilizer are selected to provide a material that demonstrates no greater than 5ΔE Units (Hunter) of color change over a period of 1 year of South Florida exposure claim 1 , or simulation of 1 year of South Florida exposure through accelerated weathering.4. The PLA-containing building component of wherein the PLA claim 3 , TiOpigment claim 3 , and stabilizer are selected to provide a material that demonstrates at least 30% gloss retention over a period of 1 year of South Florida exposure claim 3 , or simulation of 1 year of South Florida exposure through accelerated weathering.5. The PLA-containing building component of wherein the PLA claim 3 , TiOpigment claim 3 , and stabilizer are selected to provide no less than a chalking rating of 8 or more over a period of 1 year of South Florida exposure claim 3 , or simulation of 1 year of South Florida exposure through accelerated weathering.6. The PLA-containing building component of wherein the PLA claim 3 , TiOpigment claim 3 , and stabilizer are selected to provide a material that demonstrates no greater than 5ΔE Units (Hunter) of color change over a period of 5 years of South Florida exposure claim 3 , or ...

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22-08-2013 дата публикации

COMPOSITION OF POLYMERS DERIVED FROM RENEWABLE RESOURCES

Номер: US20130217818A1
Автор: Coupin Thierry
Принадлежит: Futerro S.A.

The present invention relates to a polymer composition comprising polylactide and, based on the weight of this polymer, from 17 to 25 wt% of a chain modifier, from 30 to 55 wt% of an elastomeric polymer and from 20 to 45 wt% of a plasticizer. The invention also relates to the method of preparing said composition as well as to the method of manufacturing an article starting from said composition and the article per se. 1. Polymer composition comprising:a) polylactide, and based on the weight of this polymer,b) from 17 to 25 wt % of a chain modifier selected from copolymers and terpolymers comprising ethylene or styrene and an unsaturated monomer bearing at least one epoxide or carboxylic acid or carboxylic acid anhydride fraction and optionally a (meth)acrylate fraction,c) from 30 to 55 wt % of an elastomeric polymer selected from biodegradable polyesters, aliphatic copolyesters, aromatic copolyesters and mixtures thereof andd) from 20 to 45 wt % of a plasticizer.2. Composition according to claim 1 , characterized in that the polylactide has a number-average molecular weight between 50 claim 1 ,000 and 250 claim 1 ,000.3. Composition according to claim 1 , characterized in that the chain modifier is selected from copolymers and terpolymers comprising ethylene or styrene and an unsaturated monomer bearing a carboxylic acid anhydride fraction or bearing an epoxide fraction and a (meth)acrylate fraction.4. Composition according to claim 3 , characterized in that the chain modifier is selected from copolymers of ethylene or of styrene and of glycidyl (meth)acrylate or maleic anhydride and terpolymers of ethylene or of styrene claim 3 , of alkyl (meth)acrylate and of glycidyl (meth)acrylate or of maleic anhydride.5. Composition according to claim 4 , characterized in that the chain modifier is selected from the copolymer of ethylene and of glycidyl methacrylate and the terpolymers of ethylene or of styrene claim 4 , of alkyl acrylate and of glycidyl (meth)acrylate or of ...

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22-08-2013 дата публикации

POLYESTER/POLYCARBONATE BLEND HAVING EXCELLENT THERMAL STABILITY AND COLOR STABILITY

Номер: US20130217835A1
Принадлежит: SK Chemicals Co., Ltd.

A polyester/polycarbonate blend having superior thermal stability and superior color stability is disclosed. The polyester/polycarbonate blend comprises: (a) P(ET-CT) (poly(ethylene terephthalate-co-1,4-cyclohexylene dimethylene terephthalate) which is copolymerized with 1,4-cyclohexanedimethanol (CHDM) of 40 to 90 mol % with respect to total diol components; (b) polyethylene terephthalate (PET); (c) polycarbonate (PC); and (d) germanium of 1 to 100 ppm (weight ratio) with respect to total polyester/polycarbonate blend, wherein with respect to total polyester/polycarbonate blend, the amount of the P(ET-CT) and PET is 50 to 90 weight %, the amount of the PET is 1 to 6 times in weight ratio with respect to the P(ET-CT), and the amount of the PC is 10 to 50 weight %. 1. A polyester/polycarbonate blend comprising:(a) P(ET-CT) (poly(ethylene terephthalate-co-1,4-cyclohexylene dimethylene terephthalate) which is copolymerized with 1,4-cyclohexanedimethanol (CHDM) of 40 to 90 mol % with respect to total diol components;(b) polyethylene terephthalate (PET);(c) polycarbonate (PC); and(d) germanium of 1 to 100 ppm (weight ratio) with respect to total polyester/polycarbonate blend,wherein with respect to total polyester/polycarbonate blend, the amount sum of the P(ET-CT) and PET is 50 to 90 weight %, the amount of the PET is 1 to 6 times in weight ratio with respect to the P(ET-CT), and the amount of the PC is 10 to 50 weight %.2. The polyester/polycarbonate blend according to claim 1 , wherein the PET contains terephthalic acid claim 1 , ethylene glycol and/or alkylene glycol having 3 to 6 carbon atoms claim 1 , or the PET is polymerized with isophthalic acid claim 1 , 1 claim 1 ,4-CHDM or diethylene glycol of 1 to 10 mol % with respect to acid component or diol component.3. The polyester/polycarbonate blend according to claim 1 , wherein the germanium is contained as a catalyst in the P(ET-CT) polymerization claim 1 , and an amount of the catalyst is 20 to 200 ppm (weight ...

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22-08-2013 дата публикации

BIODEGRADABLE POLYESTER AND WRAPPING FILMS FOR PACKAGING PRODUCED THEREWITH

Номер: US20130217836A1
Принадлежит: Novamont S.p.A.

This invention relates to a biodegradable polyester which is particularly suitable for use for the manufacture of wrapping films for packaging, comprising units deriving from at least one diacid and at least one diol, characterised by a high static friction coefficient in comparison with conventional biodegradable polyesters. A further object of this invention is a wrapping film comprising the said biodegradable polyester. 1. Biodegradable polyester suitable for use for the manufacture of wrapping films , comprising units deriving from at least one diacid and at least one diol and having:Mn≧40000Mw/q≦90000,wherein“q”=weight percentage of polyester oligomers having molecular weight by GPC≦10000,a film of said polyester having a static friction coefficient of more than 10.2. Biodegradable polyester according to in which the polyester is selected from biodegradable aliphatic and aliphatic-aromatic polyesters.3. Biodegradable polyester according to claim 2 , in which the said aliphatic polyesters comprise at least one aliphatic diacid and at least one aliphatic diol.4. Biodegradable polyester according to claim 2 , in which the said aliphatic-aromatic polyesters have an aromatic part comprising at least one multifunctional aromatic acid and an aliphatic part comprising at least one aliphatic diacid and at least one aliphatic diol.5. Biodegradable polyester according to claim 4 , in which the multifunctional aromatic acids are aromatic dicarboxyl compounds of the phthalic acid type and heterocyclic dicarboxylic aromatic compounds of renewable origin and their esters claim 4 , and mixtures thereof.6. Biodegradable polyester according to claim 5 , in which the content of multifunctional aromatic acids is between 30-70% in moles with respect to the total content of dicarboxylic acids in moles.7. Biodegradable polyester according to claim 3 , in which the aliphatic diacids are aliphatic dicarboxylic acids having a number of between 2 and 22 carbon atoms in the main chain and ...

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29-08-2013 дата публикации

DEGRADABLE PLASTIC AND MANUFACTURING METHOD THEREOF

Номер: US20130225731A1
Автор: Yin Zhengfu
Принадлежит: JIANGSU JINHE HI-TECH CO., LTD

A degradable plastic and a manufacturing method thereof are provided. The degradable plastic is made by mixing plastic, dry crop straw scraps and additives and extruding the mixture into granules with a double-screw extruder. The weight fraction of the plastic, crop straw scraps and additives is 63-73 wt %, 23-33 wt % and 4-6 wt % based on the total weight of raw material. The obtained granules are even, stable and can be used to manufacture daily necessities such as dishware, containers, stationery and bags having smooth surface, high strength, excellent toughness and comfortable hand feeling. 1. A degradable plastic , wherein comprising degradable plastic , crop straw and plastic additives , the weight fraction of the degradable plastic , crop straw and additives is 63-73 wt % , 23-33 wt % and 4-6 wt % based on the total weight of raw material.2. A degradable plastic according to claim 1 , wherein the degradable plastic is poly lactic acid or poly butylenes succinate.3. A degradable plastic according to claim 2 , wherein the degradable plastic further includes polyhydroxyalkanoates or polycaprolactone.4. A degradable plastic according to claim 1 , wherein the crop straw is any of rice straw claim 1 , wheat straw claim 1 , wheat bran claim 1 , corn cob or corn stalk.5. A degradable plastic according to claim 1 , wherein the plastic additives are any of silane coupling agent claim 1 , aluminate/titanate complexing coupling agent claim 1 , ethylene bis-stearomide or titanium dioxide.6. A crop plastic manufacturing method according to claim 1 , wherein mix the crop straw scraps of 1.5˜2.0 mm in length after being dried claim 1 , the plastic and the plastic additives claim 1 , extrude the mixture into granules with a double-screw extruder; the weight fraction of the plastic claim 1 , crop straw scraps and additives is 63-73 wt % claim 1 , 23-33 wt % and 4-6 wt % based on the total weight of raw material.7. A degradable plastic according to claim 1 , wherein the crop ...

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29-08-2013 дата публикации

PROCESS FOR LATEX PRODUCTION BY MELT EMULSIFICATION

Номер: US20130225761A1
Автор: Whitehouse Robert S.
Принадлежит: Metabolix, Inc

A method for producing an aqueous PHA emulsion or latex comprising predominantly amorphous PHA polymers or copolymers with polymer dispersants or surfactants is described. 1. A method for producing an aqueous polyhydroxyalkanoate (PHA) emulsion from a biobased , biodegradable PHA polymer , copolymer or blends thereof , comprising the steps of:melting the PHA polymer, copolymer or blends thereof;lowering the temperature of the PHA polymer to about 20° C. to about 50° C. below the PHA polymer with the highest Tm;combining the PHA polymer, copolymer or blends thereof and an aqueous colloid stabilizer solution under high distributive mixing thereby forming a water-in-PHA emulsion;lowering the temperature by about 20° C. to about 50° C. of the water-in-PHA emulsion; andadding water and optionally one or more polymeric dispersants or surfactants producing an aqueous PHA emulsion.2. The method of claim 1 , wherein the aqueous PHA emulsion comprises a 3-hydroxybutyrate polymer claim 1 , copolymer or blends thereof.3. The method of or claim 1 , wherein the aqueous PHA emulsion comprises 4-hydroxybutyrate polymer claim 1 , copolymer or blends thereof.4. The method of claim 1 , wherein the aqueous PHA emulsion comprises a 3-hydroxybutyrate-co-4-hydroxybutyrate copolymer.5. The method of claim 1 , wherein the aqueous PHA emulsion comprises a poly(3-hydroxybutyrate) homopolymer claim 1 , a poly(3-hydroxybutyrate-co-4-hydroxybutyrate) claim 1 , a poly(3-hydroxybutyrate-co-3-hydroxyvalerate) claim 1 , a poly(3-hydroxybutyrate-co-5-hydroxyvalerate) claim 1 , or a poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) or blends thereof.6. The method of claim 1 , wherein the aqueous PHA emulsion comprises a poly(3-hydroxybutyrate) homopolymer claim 1 , a poly(3-hydroxybutyrate-co-4-hydroxybutyrate) with 5% to 15% 4-hydroxybutyrate content claim 1 , a poly(3-hydroxybutyrate-co-3-hydroxyvalerate) with 5% to 22% 3-hydroxyvalerate content claim 1 , a poly(3-hydroxybutyrate-co-5-hydroxyvalerate) ...

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05-09-2013 дата публикации

RESIST UNDERLAYER FILM FORMING COMPOSITION, AND METHOD FOR FORMING RESIST PATTERN USING THE SAME

Номер: US20130230809A1
Принадлежит: NISSAN CHEMICAL INDUSTRIES, LTD.

There is provided a composition for forming a resist underlayer film that has a high selectivity of dry etching rate even though the composition contains an aromatic ring such as a benzene ring, and that is useful in lowering LER that presents a large problem in EUV (wavelength 13.5 nm) lithography. Moreover, another object is to obtain a composition for forming a resist underlayer film that provides a resist pattern having a desired shape on the resist underlayer film. A resist underlayer film forming composition for lithography which includes a polymer and a solvent, wherein in the polymer, diphenyl sulfone or a derivative thereof is introduced in the main chain of the polymer through an ether bond. 2. (canceled)11. The resist underlayer film forming composition for lithography according to claim 1 , further comprising a cross-linkable compound.12. The resist underlayer film forming composition for lithography according to claim 11 , further comprising a compound for accelerating a cross-linking reaction.13. The resist underlayer film forming composition for lithography according to claim 11 , wherein the cross-linkable compound is a nitrogen-containing compound having 2 to 4 nitrogen atoms that are substituted with a methylol group or an alkoxymethyl group.14. The resist underlayer film forming composition for lithography according to claim 12 , wherein the compound for accelerating the cross-linking reaction is at least one selected from a sulfonic acid compound and a thermal acid generator.15. A method for forming a resist pattern for producing a semiconductor device claim 12 , the method comprising:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'applying the resist underlayer film forming composition for lithography according to onto a semiconductor substrate and baking the obtained substance to form a resist underlayer film;'}forming a resist film on the resist underlayer film;exposing the semiconductor substrate coated with the resist underlayer and the ...

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05-09-2013 дата публикации

MONOLAYER CARBON DIOXIDE BARRIER PET BOTTLES

Номер: US20130231422A1
Автор: Deshpande Girish N.
Принадлежит:

Disclosed herein are articles comprising polymer compositions that can provide a barrier to carbon dioxide diffusion. The disclosed polymer compositions can be utilized in packaging to retard or prevent the diffusion of carbon dioxide out of a carbonated liquid, inter alia, a carbonated soft drink. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention. 2. A composition according to claim 1 , wherein the substitutions are each independently chosen from:{'sub': 1', '12, 'i) C-Clinear, branched, or cyclic alkyl, alkenyl, and alkynyl;'}{'sub': 1', '12, 'ii) C-Clinear, branched, or cyclic alkoxy, alkenyloxy, and alkynyloxy;'}{'sub': 1', '12, 'iii) C-Clinear, branched, or cyclic haloalkyl, haloalkenyl, and haloalkynyl;'}{'sub': 6', '10, 'iv) Cor Caryl;'}{'sub': 6', '10, 'v) Cor Calkylenearyl;'}{'sub': 1', '9, 'vi) C-Cheterocyclic rings;'}{'sub': 1', '9, 'vii) C-Cheteroaryl rings;'}{'sup': 102a', '102b', '101, 'sub': 'z', 'viii) —(CRR)OR;'}{'sup': 102a', '102b', '101, 'sub': 'z', 'ix) —(CRR)C(O)R;'}{'sup': 102a', '102b', '101, 'sub': 'z', 'x) —(CRR)C(O)OR;'}{'sup': 102a', '102b', '101, 'sub': z', '2, 'xi) —(CRR)C(O)N(R);'}{'sup': 102a', '102b', '101, 'sub': z', '2, 'xii) (CRR)N(R);'}xiii) halogen;{'sup': 102a', '102b, 'sub': 'z', 'xiv) —(CRR)CN;'}{'sup': 102a', '102b, 'sub': z', '2, 'xv) —(CRR)NO;'}{'sub': j', 'k, 'xvi) —CHX; wherein X is halogen, the index j is an integer from 0 to 2, j+k=3; for example,'}{'sup': 102a', '102b', '101, 'sub': 'z', 'xvii) —(CRR)SR;'}{'sup': 102a', '102b', '101, 'sub': z', '2, 'xviii) —(CRR)SORand'}{'sup': 102a', '102b', '101, 'sub': z', '3, 'xix) —(CRR)SOR;'}{'sup': 101', '101', '102a', '102b, 'sub': 1', '6', '1', '4, 'wherein each Ris independently hydrogen, substituted or unsubstituted C-Clinear, branched, or cyclic alkyl, phenyl, benzyl, heterocyclic, or heteroaryl; or two Runits can be taken together to form a ring comprising 3-7 atoms; ...

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05-09-2013 дата публикации

WHOLLY AROMATIC LIQUID CRYSTALLINE POLYESTER RESIN COMPOUND HAVING IMPROVED FLUIDITY

Номер: US20130231434A1
Принадлежит: SAMSUNG FINE CHEMICALS CO., LTD.

Provided is a wholly aromatic liquid crystalline polyester resin compound. The wholly aromatic liquid crystalline polyester resin compound includes a wholly aromatic liquid crystalline polyester resin having a high melting point and mica having a predetermined size. 1. A wholly aromatic liquid crystalline polyester resin compound , the compound comprising 100 parts by weight of a wholly aromatic liquid crystalline polyester resin having a melting point of about 300° C. to about 450° C.; andabout 5 parts by weight to about 20 parts by weight of mica having an average particle diameter of about 20 μm to about 50 μm.2. The wholly aromatic liquid crystalline polyester resin compound of claim 1 , wherein the wholly aromatic liquid crystalline polyester resin compound further comprising an inorganic filler other than the mica.3. The wholly aromatic liquid crystalline polyester resin compound of claim 2 , wherein the inorganic filler is at least one selected from the group consisting of glass fiber claim 2 , talc claim 2 , calcium carbonate claim 2 , and clay.4. The wholly aromatic liquid crystalline polyester resin compound of claim 2 , wherein an amount of the inorganic filler is about 5 parts by weight to about 90 parts by weight based on 100 parts by weight of the wholly aromatic liquid crystalline polyester resin. The present disclosure relates to a wholly aromatic liquid polyester resin compound, and more particularly, to a wholly aromatic liquid crystalline polyester resin compound including a wholly aromatic liquid crystalline polyester resin having a high melting point and mica having a predetermined size.A wholly aromatic liquid crystalline polyester resin has excellent heat resistance, dimensional stability, and high fluidity when melted and thus, is widely used as a material for precision injection molding, particularly in the field of electronic parts. In particular, due to high dimensional stability and high electrical insulating characteristics, the use of ...

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12-09-2013 дата публикации

POLYLACTIC ACID-BASED FILM OR SHEET

Номер: US20130236723A1
Принадлежит: NITTO DENKO CORPORATION

Disclosed is a polylactic acid-based film or sheet as a resin film or sheet including a polylactic acid (A). The film or sheet has a melt endotherm ΔHc′ of J/g or more, where ΔHc′ is of a region crystallized upon film formation and specified by following Expression (): 1. A polylactic acid-based film or sheet as a resin film or sheet comprising a polylactic acid (A) , wherein the polylactic acid-based film or sheet has a melt endotherm ΔHc′ of 10 J/g or more , where the melt endotherm ΔHc′ is of a region crystallized upon film formation and specified by Expression (1) expressed as follows:{'br': None, 'i': 'Hc′=ΔHm−ΔHc', 'Δ\u2003\u2003(1)'}wherein ΔHc represents an exotherm (J/g) associated with crystallization of the film or sheet in a temperature rise process after film formation; and ΔHm represents an endotherm (J/g) associated with subsequent melting of the film or sheet, where ΔHc and ΔHm are determined by DSC; andthe polylactic acid-based film or sheet has a tear strength of 2.5 N/mm or more both in a machine direction (MD) and in a transverse direction (TD), the tear strength determined according to “Paper-Determination of tearing resistance-Elmendorf tearing tester method” specified in JIS P 8116.2. The polylactic acid-based film or sheet of claim 1 , further comprising a fluoropolymer (B) in an amount of 0.5 to 15 parts by weight per 100 parts by weight of the polylactic acid (A).3. The polylactic acid-based film or sheet of claim 2 , wherein the fluoropolymer (B) is a tetrafluoroethylene polymer.4. The polylactic acid-based film or sheet of claim 1 , further comprising a crystallization promoter (C) in an amount of 0.1 to 15 parts by weight per 100 parts by weight of the polylactic acid (A).5. The polylactic acid-based film or sheet of claim 1 , further comprising an acidic-functional-group-modified olefinic polymer (D) in an amount of 0.1 to 10 parts by weight per 100 parts by weight of the polylactic acid (A) claim 1 , the acidic-functional-group- ...

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12-09-2013 дата публикации

Novel Oligoester

Номер: US20130237672A1
Принадлежит: Croda International PLC

Novel polyglycerol oligoesters derived from reaction of polyglycerol with a mixture of mono and diacids and also combinations of these novel polyglycerol oligoesters with known polyol monoesters, particularly known polyglycerol monoesters are disclosed. The use of these novel polyglycerol oligoesters and combination of esters as emulsifiers, solubilisers and/or thickeners especially in personal care formulations is also disclosed. 1. A polyglycerol oligoester which is obtainable by reacting polyglycerol having from 3 to 20 glycerol units with a dicarboxylic acid or cyclic anhydride of such dicarboxylic acid having from 4 to 22 carbon atoms and a monocarboxylic acid having from 4 to 24 carbon atoms in a molar ratio from 1.5:1.0:0.1 to 3.0:1.0:3.0.2. A polyglycerol oligoester as claimed in claim 1 , wherein the polyglycerol has 4 to 10 claim 1 , preferably 4 to 6 glycerol units.3. A polyglycerol oligoester as claimed in either or claim 1 , wherein the dicarboxylic acid is represented by the formula HOOC—R—COOH where R is a group —(CH)n- where n is from 2 to 20 claim 1 , preferably 2 to 14 claim 1 , particularly 2 to 8.4. A polyglycerol oligoester as claimed in claim 1 , wherein the monocarboxylic acid is represented by the formula RCOOH and Ris a Cto C claim 1 , preferably Cto C claim 1 , more preferably Cto Calkyl claim 1 , alkenyl or alkadienyl group.5. A polyglycerol oligoester as claimed in claim 1 , wherein the ratio of polyglycerol to dicarboxylic acid to monocarboxylic acid is 1.5:1.0:0.5 to 2.5:1:1.2.6. A polyglycerol oligoester as claimed in claim 1 , having an HLB from 7 to 18 claim 1 , preferably from 10 to 18 claim 1 , more preferably from 12 to 16.7. A polyglycerol oligoester as claimed in claim 1 , further comprising a second polyglycerol oligoester wherein the ratio of the first polyglycerol oligoester to the second polyglycerol oligoester ranges from 9:1 to 1:9 claim 1 , preferably 3:1 to 1:3 and more preferably 1.5:1 to 1:1.5.8. A method of making of ...

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12-09-2013 дата публикации

Thermoplastic Composition, Method of Producing the Same, and Articles Made Therefrom

Номер: US20130237673A1
Принадлежит: Rohm ad Haas Company

The instant invention provides a thermoplastic composition, method of producing the same, and articles made therefrom. The thermoplastic composition according to present invention comprises the melt blending product of: (A) from 55 to 95 percent by weight of a thermoplastic matrix comprising one or more thermoplastic polymers; and (B) from 5 to 45 percent by weight of a dispersed phase which comprises a crosslinked (meth)acrylate copolymer, wherein the (meth)acrylate copolymer comprises at least 95 percent by weight derived from methyl methacrylate units and from greater than zero to less than 0.5 percent by weight derived from one or more multifunctional cross-linking monomers and/or graft-linking agents; wherein the difference in refractive index between components (A) and (B) is greater than 0.08. 1. A thermoplastic composition comprising:(A) from 55 to 95 percent by weight of a thermoplastic matrix comprising one or more thermoplastic polymers; and(B) from 5 to 45 percent by weight of a dispersed phase which comprises a crosslinked (meth)acrylate copolymer, wherein the (meth)acrylate copolymer comprises at least 95 percent by weight derived from methyl methacrylate units and from greater than zero to less than 0.5 percent by weight derived from one or more components selected from the group consisting of multifunctional cross-linking monomers and graft-linking agents;wherein the difference in refractive index between components (A) and (B) is greater than 0.08.2. A method for producing a thermoplastic composition comprising the steps of:selecting a thermoplastic matrix comprising one or more thermoplastic polymers;selecting a dispersed phase comprising a crosslinked (meth)acrylate copolymer, wherein the (meth)acrylate copolymer comprises at least 95 percent by derived from weight methyl methacrylate units and from greater than zero to less than 0.5 percent by weight derived from one or more components selected from the group consisting of multifunctional cross- ...

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26-09-2013 дата публикации

POLYESTER RESIN COMPOSITION AND MOLDED BODY OF SAME

Номер: US20130253145A1
Принадлежит: ADEKA CORPORATION

The present invention provides a polyester resin composition having improved physical properties and a molded body thereof. 2. The polyester resin composition according to claim 1 , wherein the content of said group represented by said Formula (1) is 0.001 to 1 part by mass with respect to a total of 100 parts by mass of said (A) polyester resin and said (B1) terminal-modified polyethylene terephthalate claim 1 , excluding said group represented by said Formula (1).4. The polyester resin composition according to claim 3 , wherein the content of said group represented by said Formula (1) is 0.001 to 5 parts by mass with respect to a total of 100 parts by mass of said (A) polyester resin and said (B2) terminal-modified polybutylene terephthalate claim 3 , excluding said group represented by said Formula (1).5. The polyester resin composition according to according to claim 1 , wherein said (A) polyester resin is at least one polyester resin selected from the group consisting of polyethylene terephthalate claim 1 , polybutylene terephthalate claim 1 , polytrimethylene terephthalate claim 1 , polyethylene naphthalate and polybutylene naphthalate.6. The polyester resin composition according to claim 1 , wherein said metal carboxylate is sodium carboxylate.7. A molded body claim 1 , which is characterized by being obtained by molding the polyester resin composition according to .8. A sheet claim 1 , which is obtained by molding the polyester resin composition according to claim 1 , said sheet not being subjected to an annealing treatment.9. The polyester resin composition according to according to claim 3 , wherein said (A) polyester resin is at least one polyester resin selected from the group consisting of polyethylene terephthalate claim 3 , polybutylene terephthalate claim 3 , polytrimethylene terephthalate claim 3 , polyethylene naphthalate and polybutylene naphthalate.10. The polyester resin composition according to claim 3 , wherein said metal carboxylate is sodium ...

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03-10-2013 дата публикации

POLAR SOLUBLE OXYGEN SCAVENGING COMPOSITIONS AND ARTICLES THEREOF

Номер: US20130256323A1
Принадлежит: CHEMTEX ITALIA, S.P.A.

This specification discloses a composition of a melt blend comprising a continuos polyester phase, a cobalt of manganese compound and a first scavenging compound wherein the first scavenging compound comprises at least one allylic group and at least one polar moiety and at least some of the first scavenging compound or the oligomer or the polymer comprising the first scavenging compound is not present in the continuous polyester phase. The partial insolubility is essential for oxygen scavenging and the solubility is essential for reducing haze. The composition is useful in preforms, container walls, and films for packaging. 1. A composition comprisinga melt blend comprising a continuous polyester phase selected from the group consisting of polyethylene terephthalate, copolymers of polyethylene terephthalate and poly lactic acid, a salt selected from the group consisting of cobalt and manganese compounds, and a first scavenging compound or an oligomer or a polymer or mixtures thereof comprising the first scavenging compound wherein the first scavenging compound comprises at least one allylic group and at least one polar moiety and at least some of the first scavenging compound or the oligomer or the polymer comprising the first scavenging compound is not present in the continuous polyester phase.2. The composition of claim 1 , wherein the composition further comprises a second scavenging compound or an oligomer or a polymer and mixtures thereof comprising the second scavenging compound and the second scavenging compound or the oligomer or the polymer and mixtures thereof comprises at least one double allylic group and at least one polar moiety.5. The composition of claim 1 , where the first scavenger compound is not an antimony reducing scavenger.6. The composition of claim 2 , wherein the ratio of moles of the second scavenger compound to moles of the first scavenger compound is greater than 1:20.7. The composition of claim 2 , wherein the ratio of moles of the ...

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03-10-2013 дата публикации

Low-bake powder coating composition

Номер: US20130261230A1
Принадлежит: US COATINGS IP CO LLC

The present invention provides a low-bake powder coating composition comprising A) 10 to 60 wt % of at least one glycidyl-functionalised (meth)acrylic resin, B) 40 to 90 wt % of at least one carboxyl functionalised polyester resin produced by reacting of at least one hydroxyl functionalised polyester resin with cyclic, aliphatic and/or aromatic dicarboxylic acids and/or their anhydrides, and C) 0.01 to 50 wt % of at least one coating additive, pigment and/or filler, Wherein the wt % based on the total weight of the powder coating composition. The powder coating composition of this invention provides compositions which are low-bake compositions providing coatings having high grade of flexibility for outdoor applications. Particularly and surprisingly, the powder coating composition of this invention furthermore provides no blooming of the coatings and excellent flow and appearance properties.

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03-10-2013 дата публикации

UNSATURATED POLYESTER RESIN COMPOSITION FOR USE IN LED REFLECTOR, AND LED REFLECTOR AND LED LUMINAIRE USING SAID COMPOSITION

Номер: US20130261243A1
Автор: Kubo Toshio, Nagaoka Sunao
Принадлежит: Panasonic Corporation

Provided are a resin composition for general-purpose LED reflectors, which discolors little through thermal deterioration and is excellent in heat discoloration resistance, which can provide an LED lamp using it and having a long life, which is relatively inexpensive and has good storage stability, and which is excellent in handleability and workability, and an LED reflector and an LED luminaire using the resin composition. 112-. (canceled)13. A dry-type unsaturated polyester resin composition containing at least an unsaturated polyester resin , a polymerization initiator , an inorganic filler , a white pigment , a release agent and a reinforcing material , wherein the unsaturated polyester resin is within a range of from 14 to 40% by mass relative to the entire amount of the composition , the total amount of the inorganic filler and the white pigment is within a range of from 44 to 74% by mass relative to the entire amount of the composition , the proportion of the white pigment to the total amount of inorganic filler and the white pigment is at least 30% by mass , and the unsaturated polyester resin is an unsaturated alkyd resin mixed with a crosslinking agent.14. The unsaturated polyester resin composition for LED reflectors according to claim 13 , wherein the inorganic filler is at least one selected from a group consisting of silica claim 13 , aluminium hydroxide claim 13 , aluminium oxide claim 13 , magnesium oxide claim 13 , barium sulfate claim 13 , magnesium carbonate and barium carbonate.15. The unsaturated polyester resin composition for LED reflectors according to claim 13 , wherein the white pigment is at least one selected from a group consisting of titanium oxide claim 13 , barium titanate claim 13 , strontium titanate claim 13 , aluminium oxide claim 13 , magnesium oxide claim 13 , zinc oxide claim 13 , barium sulfate claim 13 , magnesium carbonate and barium carbonate.16. The unsaturated polyester resin composition for LED reflectors according to ...

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10-10-2013 дата публикации

Molded structural body and motor having same

Номер: US20130264896A1
Принадлежит: Panasonic Corp

A molded structural body is obtained by mold forming of a magnet coil wound on an iron core with the use of a molding resin containing at least a thermosetting resin, a thermoplastic resin incompatible with the thermosetting resin, and a metal hydrate having an electrical insulation property, wherein the molding resin has a thermal conductivity of 1.5 W/m·K or more and an excellent frame retardancy of UL94V-0. The molded structural body can achieve a small-size, thin, and high-power device with flame retardancy achieved, without containing any substances with high environmental burdens in the molding resin.

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17-10-2013 дата публикации

Biodegradable resin composition

Номер: US20130274373A1
Принадлежит: Toyo Seikan Group Holdings Ltd

The present invention is a biodegradable resin composition comprising a sparingly hydrolyzing biodegradable resin (A) and an ester decomposition promoter (B), the ester decomposition promoter (B) being a copolymerized polyester that contains a segment (X) of a sparingly hydrolyzing polyester and a segment (Y) of an easily hydrolyzing polyester at a weight ratio of 10/90<X/Y<75/25. The biodegradable resin composition of the present invention features excellent biodegradability as well as excellent transparency.

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17-10-2013 дата публикации

Polycarbonates as nucleating agents for polylactides

Номер: US20130274422A1

The present invention discloses the use of polycarbonate to increase the crystallisation rate of polylactides while maintaining its the mechanical properties.

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24-10-2013 дата публикации

Cleaning Method

Номер: US20130276242A1
Принадлежит: Xeros LTD

The invention provides a method for the cleaning of a soiled substrate, the method comprising treating the substrate with a solid particulate cleaning material and wash water, the treatment being carried out in an apparatus comprising a drum comprising perforated side walls and having a capacity of between 5 and 50 litres for each kg of fabric in the washload, wherein said solid particulate cleaning material comprises a multiplicity of polymeric particles at a particle to fabric addition level of 0.1:1-10:1 by mass, each particle being substantially cylindrical or spherical in shape and having an average density in the range of 0.5-2.5 g/cm 3 and an average volume in the range of 5-275 mm 3 , and wherein said drum comprising perforated side walls is rotated at a speed which generates G forces in the range of from 0.05 to 900 G. The polymeric particles may comprise foamed or unfoamed polymeric materials which may comprise either linear or crosslinked polymers. Preferably, at least one detergent is employed in the cleaning process. The invention provides optimum cleaning performance as a result of improved mechanical interaction between substrate and cleaning media and is preferably used for the cleaning of textile fabrics. The method allows for significant reductions in the consumption of detergents, water and energy when compared with the conventional wet cleaning of textile fabrics, and also facilitates reduced washing-related textile fabric damage. The invention also envisages a cleaning composition comprising a solid particulate cleaning composition and at least one additional cleaning agent. In particular embodiments of the invention, the solid particulate cleaning material is separated and recovered and then re-used in subsequent cleaning processes. Typically, the solid particulate cleaning material is itself cleaned intermittently in order to maintain its efficacy.

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24-10-2013 дата публикации

POLYESTER COMPOSITION

Номер: US20130281560A1
Принадлежит: Novamont S.p.A.

This invention relates to a polymer composition comprising at least two polyesters having improved mechanical properties, in particular a good balance between ultimate tensile strength, elastic modulus and elongation on failure. This composition is particularly suitable for the production of manufactured articles such as for example films, moulded objects, thermoformed objects or expanded articles. 1. Polymeric composition characterized by comprising from 1 to 99% by weight of at least one aromatic polyester (AP) substantially comprising repeating units deriving from at least one heterocyclic polyfunctional aromatic acid of renewable origin and from 99 to 1% by weight of at least a second aliphatic-aromatic polyester (AAPE).2. Polymeric composition according to claim 1 , wherein said aromatic polyester substantially comprising repeating units deriving from at least one heterocyclic polyfunctional aromatic acid of renewable origin is of the diacid-diol type.3. Polymeric composition according to claim 2 , wherein said heterocyclic polyfunctional aromatic acid of renewable origin is 2 claim 2 ,5-furandicarboxylic acid.4. Polymeric composition according to claim 2 , wherein said diol is selected from 1 claim 2 ,2-ethanediol claim 2 , 1 claim 2 ,2-propanediol claim 2 , 1 claim 2 ,3-propanediol claim 2 , 1 claim 2 ,4-butanediol claim 2 , 1 claim 2 ,5-pentanediol claim 2 , 1 claim 2 ,6-hexanediol claim 2 , 1 claim 2 ,7-heptanediol claim 2 , 1 claim 2 ,8-octanediol claim 2 , 1 claim 2 ,9-nonanediol claim 2 , 1 claim 2 ,10-decanediol claim 2 , 1 claim 2 ,11-undecanediol claim 2 , 1 claim 2 ,12-dodecanediol claim 2 , 1 claim 2 ,13-tridecanediol claim 2 , 1 claim 2 ,4-cyclohexanedimethanol claim 2 , propylene glycol claim 2 , neo-pentylglycol claim 2 , 2-methyl-1 claim 2 ,3-propanediol claim 2 , dianhydro-sorbitol claim 2 , dianhydro-mannitol claim 2 , dianhydro-iditol claim 2 , cyclohexanediol claim 2 , cyclohexanemethanediol claim 2 , and mixtures thereof.5. Polymeric ...

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24-10-2013 дата публикации

FLAME RETARDANT RESIN COMPOSITION AND MOLDED ARTICLE THEREOF

Номер: US20130281585A1
Автор: Yamanaka Katsuhiro
Принадлежит:

A flame retardant resin composition which is obtained by using a plant-derived raw material and excellent in flame retardancy, heat resistance and impact resistance, and a molded article thereof. 2. The flame retardant resin composition according to claim 1 , wherein the polylactic acid (component A-1) is stereocomplex polylactic acid which contains poly(L-lactic acid) (component α-1) comprising not less than 90 mol % of an L-lactic acid unit and poly(D-lactic acid) (component β-1) comprising not less than 90 mol % of a D-lactic acid unit claim 1 , and the weight ratio of the component α-1 to the component β-1 is 10:90 to 90:10.3. The flame retardant resin composition according to claim 1 , wherein the component A-1 has a proportion of melting peaks at 195° C. or higher of not less than 80% of the total of all the melting peaks in the temperature elevation step in differential scanning calorimeter measurement.4. The flame retardant resin composition according to which comprises at least one resin (component A-2) selected from the group consisting of polyester resin (PEst) except for the component A-1 claim 1 , polyphenylene ether resin (PPE) claim 1 , polycarbonate resin (PC) claim 1 , polyamide resin (PA) claim 1 , polyolefin resin (PO) claim 1 , styrene-based resin claim 1 , polyphenylene sulfide resin (PPS) and polyether imide resin (PEI) as the resin component (component A).14. The flame retardant resin composition according to claim 1 , wherein the impact resistance modifier (component D) contains at least 50 wt % of a hydrogenated styrene-based thermoplastic elastomer.15. The flame retardant resin composition according to claim 1 , wherein the impact resistance modifier (component D) contains at least 50 wt % of at least one hydrogenated styrene-based thermoplastic elastomer selected from styrene-ethylene-butylene-styrene terpolymer (SEBS) claim 1 , styrene-ethylene-propylene-styrene terpolymer (SEPS) and styrene-ethylene-propylene-styrene terpolymer (SEEPS). ...

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24-10-2013 дата публикации

New impact modifier and impact modified thermoplastic composition

Номер: US20130281629A1
Принадлежит: Arkema France SA

The invention relates to an impact modified thermoplastic resin comprising a polymeric impact modifier with a core-shell structure comprising 2-octylacrylate.

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31-10-2013 дата публикации

Monovinylaromatic Polymer Composition Comprising a Polymer Made From Renewable Resources as a Dispersed Phase

Номер: US20130289208A1
Автор: Duc Michel
Принадлежит: TOTAL PETROCHEMICALS FRANCE

A monovinylaromatic polymer composition can include a bio-sourced polymer dispersed phase and optionally a rubber dispersed phase. The bio-sourced polymer dispersed phase can be predominantly made of particles having a size of less than 10 μm. The monovinylaromatic polymer composition can be made by admixing a monovinylaromatic monomer, bio-sourced polymer, and optionally rubber at conditions effective to polymerize at least a part of the monovinylaromatic monomer and generate a compatibilizer. The monovinylaromatic polymer composition can be made by admixing a monovinylaromatic monomer, functionalized bio-sourced polymer(s) or mixtures of bio-sourced polymer(s) and functionalized bio-sourced polymer(s), and optionally rubber at conditions effective to polymerize at least a part of the monovinylaromatic monomer. The monovinylaromatic polymer composition can be made by blending, in the molten state, functionalized bio-sourced polymer(s) or mixtures of bio-sourced polymer(s) and functionalized bio-sourced polymer(s) with monovinylaromatic polymer, and optionally rubber. 116-. (canceled)17. A process for the production of a polymer composition comprising: admixing a monovinylaromatic monomer; and at least one bio-sourced polymer; under conditions effective to polymerize at least a part of the monovinylaromatic monomer and generate a compatibilizer of the bio-sourced polymer and monovinylaromatic polymer; wherein the polymer composition comprises a bio-sourced polymer dispersed phase.18. The process of claim 17 , further comprising admixing rubber to the monovinylaromatic monomer and at least one bio-sourced polymer claim 17 , wherein the polymer composition comprises a rubber dispersed phase.19. The process of claim 17 , wherein the bio-sourced polymer dispersed phase is predominantly made of particles having a size of less than 10 μm.21. The process of claim 17 , wherein the monovinylaromatic polymer is a continuous phase.23. The process of claim 22 , wherein the bio- ...

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07-11-2013 дата публикации

STRAPS PRODUCED FROM RENEWABLE RAW MATERIALS

Номер: US20130291741A1
Автор: Eberle Ulrich
Принадлежит: Maschinenfabrik Gerd Mosca AG

An extruded strap is produced of a material containing renewable raw materials and the ends of which strap can be welded together. A method for producing the extruded strap and a method for strapping an article using the extruded strap are also provided. 1. An extruded strapping tape which is weldable with itself and which is made of a material which contains renewable raw material.2. The strapping tape as recited in claim 1 , wherein the renewable raw material is selected from the group of cellulose claim 1 , aliphatic polyesters claim 1 , polyamide claim 1 , aliphatic polyester amide claim 1 , polyhydroxyalkanoate claim 1 , polyvinyl alcohol claim 1 , polyalkylenglycol claim 1 , lignin or a copolymer which contains at least one of the compounds claim 1 , or mixtures or derivatives thereof.3. (canceled)4. The strapping tape as recited in claim 1 , wherein the renewable raw material is modified with a coupling reagent which is selected from the group of maleic acid derivatives claim 1 , glycidylmethacrylate derivatives claim 1 , methacrylic acid derivatives claim 1 , organosilicon compounds claim 1 , vinyl acetate derivatives or mixtures thereof5. The strapping tape as recited in claim 1 , wherein the material contains at least 10 wt. % renewable raw materials.6. The strapping tape as recited in claim 6 , wherein the strapping tape is stretched.7. The strapping tape as recited in claim 1 , wherein a weight average of the molar mass of the renewable raw material is in a range of 20 claim 1 ,000 g/mol to 300 claim 1 ,000 g/mol.8. The strapping tape as recited in claim 1 , wherein a fiber content is a maximum of 10 wt. %.9. A method for manufacturing a strapping tape claim 1 , comprising:melting and extruding a material which contains a renewable raw material;cooling the molten material in a fluid to produce an obtained tape; andstretching, fixing or cooling the obtained tape.10. A method for strapping an object with a strapping tape comprising:placing the strapping ...

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