25-05-2017 дата публикации
Номер: US20170145253A1
Принадлежит:
The present application relates to a hard-coating resin composition including a siloxane resin, a preparing method of a siloxane cured hard-coating article using same and an optical film including the siloxane cured hard-coating article. 1. A hard-coating resin composition comprising a siloxane resin including an alicyclic epoxy group ,wherein the siloxane resin has a weight-average molecular weight in the range of from 1,000 to 4,000 and a molecular weight distribution of PDI ranging from 1.05 to 1.4.2. The hard-coating resin composition of claim 1 , wherein an epoxy equivalent of the siloxane resin is in the range of from 0.35 to 0.6 mol/100 g.3. The hard-coating resin composition of claim 1 , wherein the siloxane resin is prepared by hydrolysis and condensation of (i) an alkoxysilane alone represented by the following Chemical Formula 1 including an alicyclic epoxy group and an alkoxy group claim 1 , or (ii) an alkoxysilane represented by the following Chemical Formula 1 including an alicyclic epoxy group and an alkoxy group claim 1 , and an alkoxysilane compound represented by the following Chemical Formula 2 claim 1 , in the presence of water and a catalyst:{'br': None, 'sup': 1', '2, 'sub': n', '4-n, 'RSi(OR)[\u2003\u2003Chemical Formula 1]'}{'br': None, 'sup': 3', '4, 'sub': m', '4-m, 'RSi(OR)[\u2003\u2003Chemical Formula 2]'}wherein in the formulas,{'sup': '1', 'sub': 1', '6, 'Ris a straight or branched Cto Calkyl group including an alicyclic epoxy group,'}{'sub': 3', '6, 'the alicyclic epoxy group is a Cto Ccycloalkyl group having an epoxy group,'}{'sup': '2', 'sub': 1', '7, 'Ris a straight or branched Cto Calkyl group,'}{'sup': '3', 'sub': 1', '20', '3', '8', '2', '20', '2', '20', '6', '20, 'Ris selected from the group consisting of a Cto Calkyl group, a Cto Ccycloalkyl group, a Cto Calkenyl group, a Cto Calkynyl group, a Cto Caryl group, an acryl group, a methacryl group, a halogen group, an amino group, a mercapto group, an ether group, an ester group, a ...
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