Producing polychloroprene latices

The novel process provides latices of homo- and copolymers of chloroprene and of one or more further copolymerizable monomers at a higher reaction rate and hence in an improved space-time yield. The latices obtained have a high gel content, distinctly lower levels of by-products, in particular of chloroprene dimer, than prior art products, and are useful, if appropriate in concentrated form, for a wide variety of applications.

Method for producing polychloroprene latex, polychloroprene latex, and adhesive using the same

Provided is a polychloroprene latex extremely favorable in adhesive properties. The present invention relates to a method of producing a polychloroprene latex, comprising polymerizing chloroprene or a mixture of chloroprene and a monomer copolymerizable with chloroprene in an aqueous medium containing a surfactant at a concentration of lower than its critical micelle concentration (CMC) and a polymer dispersant of a metal salt of aromatic sulfonic acid formalin condensate added thereto. The polymer dispersant for use is preferably a metal salt of aromatic sulfonic acid formalin condensate. The polychloroprene latex obtained can be used as an adhesive.

ADHESIVE WITH BUFFER SYSTEM

An adhesive based on a polychloroprene dispersion is characterized in that a buffer system comprising at least one acid compound and glycerin is included in order to activate and stabilize the adhesive. A freeze-thaw stability of the adhesive is achieved by surprisingly high proportions of glycerin; however, a good initial adhesion is simultaneously ensured. The glycerin proportions range from 8-50 wt. %, preferably 14-40 wt. %, particularly preferably 22-30 wt. %. An organic acid is preferably used as the acid compound. 1. An adhesive based on a polychloroprene dispersion with a buffer system , including at least one acid compound and glycerol , for the activation and stabilization of the adhesive , wherein glycerol is present , based on the total weight of the adhesive , as a proportion of 8-50% by weight.2. The adhesive as claimed in claim 1 , in which glycerol is present claim 1 , based on the total weight of the adhesive claim 1 , as a proportion of 14-40% by weight claim 1 , particularly preferably 22-30% by weight.3. The adhesive as claimed in claim 1 , in which the polychloroprene dispersion additionally comprises polyacrylates claim 1 , in particular acrylic ester copolymers claim 1 , styrene/acrylate copolymers and/or mixtures thereof.4. The adhesive as claimed in claim 1 , in which the polychloroprene dispersion additionally comprises polymers and/or copolymers of vinyl acetate claim 1 , ethylene vinyl acetate claim 1 , vinyl butyral and/or urethane.5. The adhesive as claimed in claim 1 , in which the at least one acid compound exhibits a pKof 2-10.6. The adhesive as claimed in claim 1 , in which the at least one acid compound includes citric acid claim 1 , tartaric acid claim 1 , ascorbic acid claim 1 , maleic acid claim 1 , maleic anhydride claim 1 , malic acid claim 1 , amino acids claim 1 , in particular glycine claim 1 , monosodium dihydrogenphosphate and/or carbonic acid.7. The adhesive as claimed in claim 1 , in which the at least one acid compound ...

POLYCHLOROPRENE-BASED BONDING ADHESIVES

An adhesive composition comprising a solids component, said solids component including a rubber component that includes polychloroprene; and a solvent component, said solvent component including t-butyl acetate. 1. An adhesive composition comprising:i. a solids component, said solids component including a rubber component that includes polychloroprene; andii. a solvent component, where the solvent component includes from 150 to 500 parts by weight t-butyl acetate, from 50 to 300 parts by weight acetone, from 5 to 100 parts by weight methyl acetate, and where the solvent component further includes 5 to 300 parts by weight toluene per 100 parts by weight rubber.2. The composition of claim 1 , where the solvent component includes from 285 to 310 parts by weight t-butyl acetate claim 1 , from 170 to 190 parts by weight acetone claim 1 , and from 15 to 25 parts by weight methyl acetate claim 1 , per 100 parts by weight rubber.3. The composition of where the solvent component further includes 35 to 45 parts by weight toluene per 100 parts by weight rubber.4. The composition of claim 1 , where the rubber component further includes poly-(styrene-co-butadiene).5. The composition of claim 1 , where the rubber component is devoid of a complementary rubber claim 1 , and where the solids component includes an adhesion promoter.6. An adhesive composition comprising:i. a solids component, said solids component including a rubber component, a synthetic thermosetting resin, and a hydrocarbon resin, where the rubber component includes polychloroprene; andii. a solvent component, said solvent component including 150 to 500 parts by weight t-butyl acetate, from 50 to 300 parts by weight acetone, from 5 to 100 parts by weight methyl acetate, and where the solvent component further includes 5 to 300 parts by weight toluene per 100 parts by weight rubber per 100 parts by weight rubber.7. The adhesive composition of claim 6 , where the rubber component includes at least 70% by weight ...

Strip for reinforcement of a hose and a method of manufacture thereof

A strip (100) intended for the reinforcement of the wall of high pressure hoses or flexible pipes is presented. The strip (100) comprises multiple wires (102) arranged side-by-side and held together by means of a hardened adhesive (104) originating from a waterborne dispersion. Different embodiments are presented wherein the wires (102) are embedded in the hardened adhesive (104), or wherein only one side of the strip (100) is covered with hardened adhesive (104) or wherein the hardened adhesive (104) is present only between the wires (102) and not on the surfaces (S1, S2) delineating the strip (100). In one preferred embodiment the wires (102) are flattened with the flats being parallel to the surfaces (S1, S2) of the strips (100).

ADHESIVE COMPOSITION AND ADHERED ROOFING SYSTEM PREPARED USING THE ADHESIVE COMPOSITION

The invention is directed to an adhesive composition including at least one rubber component, a solvent, and at least one powdered superabsorber polymer. The invention also relates to a method for bonding a roofing membrane to a substrate using the adhesive composition as a contact adhesive, to fully adhered membrane roofing system, and to the use of adhesive composition for adhering roofing membranes to substrates by contact bonding. 1. An adhesive composition comprising:a) at least one rubber component,b) at least one organic solvent, andc) at least one powdered superabsorber polymer, wherein the total amount of powdered superabsorber polymers is 0.5-10.0% by weight, based on the total weight of the adhesive composition.2. The adhesive composition according to claim 1 , wherein the adhesive composition is a solvent-based solution adhesive claim 1 , wherein the at least one rubber component is dissolved in the organic solvent.3. The adhesive composition according to claim 1 , wherein the total amount of powdered superabsorber polymers is 1.0-6.0% by weight claim 1 , based on the total weight of the adhesive composition.4. The adhesive composition according to claim 1 , wherein the total amount of the rubber components is 5.0-60.0% by weight based on the total weight of the adhesive composition.5. The adhesive composition according to claim 1 , wherein the total amount of the organic solvents is 50.0-90.0% by weight based on the total weight of the adhesive composition.6. The adhesive composition according to claim 1 , wherein the rubber component is selected from the group consisting of chloroprene rubber claim 1 , butyl rubber claim 1 , halogenated butyl rubber claim 1 , acryl nitrile rubber claim 1 , natural rubber claim 1 , and mixtures thereof.7. The adhesive composition according to claim 1 , further comprising at least one hydrocarbon resin and/or a synthetic thermosetting resin claim 1 , and/or adhesion promoter.8. A method for bonding a roofing membrane to ...

ECO-FRIENDLY ADHESIVE COMPOSITION FOR RUBBER REINFORCING MATERIAL, AND METHOD FOR MANUFACTURING RUBBER REINFORCING MATERIAL USING SAME

One embodiment of the present invention provides an adhesive composition including, on the basis of the total weight thereof, 0.5 to 4.0% by weight of an epoxy compound, 1.0 to 8.0% by weight of an isocyanate compound, 1.7 to 22% by weight of a rubber latex, 1.0 to 8.0% by weight of a polyurethane dispersion (PUD) resin, 0.1 to 2.0% by weight of an amine compound, and 69 to 92% by weight of a solvent, wherein the epoxy compound and the isocyanate compound have a weight ratio of 1:1 to 1:10. 1. An adhesive composition comprising:an epoxy compound;an isocyanate compound;a rubber latex;a polyurethane dispersion (PUD) resin;an amine compound; anda solvent,wherein the epoxy compound and the isocyanate compound have a weight ratio of 1:1 to 1:10.2. The adhesive composition according to claim 1 , comprising claim 1 , on the basis of the total weight thereof:0.5 to 4.0% by weight of the epoxy compound;1.0 to 8.0% by weight of the isocyanate compound;1.7 to 22% by weight of the rubber latex;1.0 to 8.0% by weight of the polyurethane dispersion (PUD) resin;0.1 to 2.0% by weight of the amine compound; and69 to 92% by weight of the solvent.3. The adhesive composition according to claim 1 , wherein the mixture of the epoxy compound and the isocyanate compound claim 1 , and the rubber latex claim 1 , have a weight ratio of 1:3 to 1:18.4. The adhesive composition according to claim 1 , wherein the epoxy compound and the isocyanate compound claim 1 , and the rubber latex claim 1 , have a weight ratio of 1:1 to 1:8.5. The adhesive composition according to claim 1 , wherein the solvent includes water (HO).6. The adhesive composition according to claim 5 , wherein the water is included in the content of 69 to 80% by weight based on the total weight.7. The adhesive composition according to claim 1 , wherein the epoxy compound includes at least one of a glycidyl ether type of compound claim 1 , a novolac type of epoxy resin claim 1 , and a bisphenol type of epoxy resin.8. The adhesive ...

POLYCHLOROPRENE-BASED BONDING ADHESIVES

An adhesive composition comprising a solids component, said solids component including a rubber component that includes polychloroprene; and a solvent component, said solvent component including t-butyl acetate. 1. An adhesive composition comprising:i. a solids component, said solids component including a rubber component that includes polychloroprene; andii. a solvent component, where the solvent component includes from 150 to 500 parts by weight t-butyl acetate, from 50 to 300 parts by weight acetone, from 5 to 100 parts by weight methyl acetate, and where the solvent component further includes 5 to 300 parts by weight toluene per 100 parts by weight rubber.2. The composition of claim 1 , where the solvent component includes from 285 to 310 parts by weight t-butyl acetate claim 1 , from 170 to 190 parts by weight acetone claim 1 , and from 15 to 25 parts by weight methyl acetate claim 1 , per 100 parts by weight rubber.3. The composition of where the solvent component further includes 35 to 45 parts by weight toluene per 100 parts by weight rubber.4. The composition of claim 1 , where the rubber component further includes poly-(styrene-co-butadiene).5. The composition of claim 1 , where the rubber component is devoid of a complementary rubber claim 1 , and where the solids component includes an adhesion promoter.6. An adhesive composition comprising:i. a solids component, said solids component including a rubber component, a synthetic thermosetting resin, and a hydrocarbon resin, where the rubber component includes polychloroprene; andii. a solvent component, said solvent component including 150 to 500 parts by weight t-butyl acetate, from 50 to 300 parts by weight acetone, from 5 to 100 parts by weight methyl acetate, and where the solvent component further includes 5 to 300 parts by weight toluene per 100 parts by weight rubber per 100 parts by weight rubber.7. The adhesive composition of claim 6 , where the rubber component includes at least 70% by weight ...

Expandable Tacky Tape

In the manufacture of composite product, raw composite is layered on a shape or form and cured at a higher temperature. With some shapes, it is difficult or impossible to apply sufficient pressure to force and consolidate the composite material to adequately conform to the desired final shape during the curing process. The expandable tacky tape of this invention is comprised of a viscous medium incorporating thermally expandable material. Applied over the raw composite, the expandable tacky tape effectively forces the composite to conform to the desired shape during curing. 1. A viscous material containing a dispersion of thermally expandable material and applied to the outer surface of composite material overlaying a mandrel or form.2. The viscous material containing thermally expandable material of when the expandable material is microspheres from about 0.1 to about 60 percent by weight.3. The viscous material containing thermally expandable material of when the viscous material is selected from the group: butyl rubber claim 1 , latex claim 1 , urethane claim 1 , urea claim 1 , silicone claim 1 , neoprene.4. The viscous material containing thermally expandable material of when the viscosity allows the mixture to be poured claim 1 , sprayed claim 1 , or applied as caulking.5. The viscous material containing thermally expandable material of when the thermally expandable material is exfoliating graphite at a concentration of 0.1 percent to about 70 percent by weight.6. The method of manufacturing a composite product comprised of the following steps:a. Coating a mandrel or form with raw composite plastic,b. Applying a viscous material containing thermally expandable material on the surface side of the raw composite plastic,c. Placing the coated mandrel or form with applied viscous material containing thermally expandable material into a sealable bag, evacuating air from the bag and sealing the bag, andd. Heating the assembly and curing the composite material. This ...

SOLVENT COMPOSITION, ADHESIVE COMPOSITION, AND METHOD OF BONDING SURFACES

In an embodiment a solvent composition can comprise, based on the total volume of the solvent composition, 10 to 95 volume percent of a first solvent, wherein the first solvent has Hansen solubility parameters of: 15 MPa≤δ≤17 MPa, 4≤δ≤10.5 MPa, and 7≤δ≤10 MPa; 5 to 95 volume percent of a second solvent, wherein the second solvent has Hansen solubility parameters of: 16 MPa≤δ≤17.5 MPa, 0≤δ≤3 MPa, and 0≤δ≤3 MPa; and 0 to 85 volume percent parachlorobenzotrifluoride; wherein the amounts of the first solvent, the second solvent, and parachlorobenzotrifluoride sum to at least 85 volume percent. The first solvent can comprise methyl acetate, acetone, dimethyl carbonate, ethyl acetate, n-butylamine, propyl acetate, tetrahydrofuran, or a combination thereof. The second solvent can comprise cyclohexene, cyclohexane, cyclopentane, methylcyclohexane, or a combination thereof. The solvent compositions are particularly useful in an adhesive composition. An adhesive composition includes the solvent composition, a rubber, and a tackifying resin. A method of bonding two surfaces is also described. 1. A solvent composition comprising , based on the total volume of the solvent composition , {'sup': 0.5', '0.5', '0.5', '0.5, 'sub': D', 'P', 'H, '15 MPa≤δ≤17 MPa, 4≤δ≤10.5 MPa, and 7≤δ≤10 MPa;'}, '10 to 95 volume percent of a first solvent, wherein the first solvent has Hansen solubility parameters of {'sup': 0.5', '0.5', '0.5', '0.5, 'sub': D', 'P', 'H, '16 MPa≤δ≤17.5 MPa, 0≤δ≤3 MPa, and 0≤δ≤3 MPa; and'}, '5 to 95 volume percent of a second solvent, wherein the second solvent has Hansen solubility parameters of0 to 85 volume percent parachlorobenzotrifluoride;wherein the amounts of the first solvent, the second solvent, and parachlorobenzotrifluoride sum to at least 85 volume percent.2. A solvent composition comprising , based on the total volume of the solvent composition ,10 to 95 volume percent of a first solvent, wherein the first solvent consists essentially of methyl acetate, ...

CHLOROPRENE RUBBER-BASED POLYMER LATEX COMPOSITION AND USE THEREOF

It is an object of the invention to provide a chloroprene rubber-based polymer latex that has a good balance between initial adhesion and storage stability and is suitable for one-component aqueous adhesive applications. The invention relates to a chloroprene rubber-based polymer latex composition containing a mixture of a chloroprene rubber-based polymer latex and a latex of an acrylic or styrene-acrylic resin-based polymer obtained by copolymerization of a specific carboxyl group-containing unsaturated monomer, in which the specific carboxyl group is neutralized with an alkali. 13.-. (canceled)4. A chloroprene rubber-based polymer latex composition , comprising a mixture of (A) a chloroprene rubber-based polymer latex and (B) an acrylic resin-based polymer latex and/or a styrene-acrylic resin-based polymer latex , wherein the acrylic resin-based polymer latex and/or the styrene-acrylic resin-based polymer latex (B) contains an acrylic resin-based polymer having a unit derived from itaconic acid and/or a styrene-acrylic resin-based polymer having a unit derived from itaconic acid , an alkali is added to the acrylic resin-based polymer latex and/or the styrene-acrylic resin-based polymer latex (B) , the chloroprene rubber-based polymer latex (A) contains an anionic surfactant having a carboxyl group , and satisfying formula (1):{'br': None, '[Mathematical Formula 1]'}{'br': None, 'sub': 1', '2, 'pKa≧pKa+0.6\u2003\u2003(1)'}wherein pKa1 represents the pKa of the anionic surfactant at 25° C., and pKa2 represents the pKa of itaconic acid at 25° C.53. The chloroprene rubber-based polymer latex composition according to claim , wherein the anionic surfactant is abietic acid.6. A one-component aqueous adhesive comprising the chloroprene rubber-based polymer latex composition according to .7. The chloroprene rubber-based polymer latex composition according to claim 4 , wherein pKa2 is at most 4.0.8. The chloroprene rubber-based polymer latex composition according to claim 4 ...

AQUEOUS-BASED POLYCHLOROPRENE CONTACT ADHESIVE

Aqueous-based adhesive composition comprising a mixture of polycholorprenes, at least one self-crosslinkable agent of alkyd type and at least one filler, 2) use of such a composition as contact adhesive, 3) multilayer structure assembled with the aid of the adhesive composition 1). 110-. (canceled)12. The adhesive composition of claim 11 , wherein the mixture of polychloroprenes A) comprises:A1) at least one polychloroprene in aqueous dispersion having a hardness greater than or equal to 85 Shore A, and/orA2) at least one polychloroprene in aqueous dispersion having a hardness less than or equal to 55 Shore A.13. The adhesive composition of claim 11 , wherein the self-crosslinkable agent of alkyd type comprises:(i) at least one alkyd resin comprising at least one 5-membered cyclocarbonate function (Y), and(ii) at least one alkyd resin comprising at least one primary amine function (X) salified by an acid having a pKa ranging from 1 to 14, having a carbon-based chain comprising from 1 to 6 carbon atoms.14. The adhesive composition of claim 11 , wherein the mineral filler is selected from the group consisting of calcium carbonate claim 11 , silica claim 11 , a composite based on silica and kaolinite claim 11 , sepiolite claim 11 , and the mixture thereof.15. The adhesive composition of claim 11 , wherein the emulsifier comprises a system of at least two emulsifiers selected from the group consisting of the following emulsifiers:oxyethylenated unsaturated acyclic fatty alcohols having an HLB ranging from 15 to 18,oxyethylenated unsaturated cyclic fatty alcohols having a cloud point ranging from 63 to 67° C.,mixtures of mono- and dialkylphenoxybenzenedisulfonate salts, the linear or branched alkyl portion of which comprises from 10 to 14 carbon atoms,oxyethylenated sulfosuccinic acid and alcohol hemiester salts comprising from 10 to 14 carbon atoms,oxyethylenated alkyl ether sulfate salts, the linear or branched alkyl portion of which comprises from 12 to 14 carbon ...

Aqueous dispersion, and laminate, adhesive for footwear, and footwear made using same

An aqueous dispersion including an acid-modified polyolefin resin (A) having a content of an unsaturated carboxylic acid component of 0.1 to 10% by mass, a rubber component (B), a tackifier component (C) and an aqueous medium, wherein in relation to 100 parts by mass of the acid-modified polyolefin resin (A), the content of the rubber component (B) is 5 to 1900 parts by mass, and in relation to 100 parts by mass of the total amount of the acid-modified polyolefin resin (A) and the rubber component (B), the content of the tackifier component (C) is 5 to 300 parts by mass.

POLYCHLOROPRENE-BASED CONTACT ADHESIVES CONTAINING ETHYLENE-VINYL ACETATE COPOLYMER

Contact adhesive compositions comprising polychloroprene and, based on the polychloroprene content, 10 to 99 wt % of ethylene-vinyl acetate copolymer exhibit outstanding adhesion to substrates such as ethylene-vinyl acetate copolymers, thermoplastic elastomers or flexible PVC. The contact adhesive compositions of the invention are especially suitable for use in the bonding of articles, preferably articles in which at least part of the articles to be bonded consists of polyurethane, flexible PVC, ethylene-vinyl acetate copolymers and/or thermoplastic elastomers. This allows the adhesive composition to be employed widely in the footwear industry, for the bonding of roofing membranes containing flexible PVC, ethylene-propylene-diene rubber (EPDM) and/or ethylene-vinyl acetate copolymers, or for the bonding of synthetic leather based on flexible PVC. 1. Contact adhesive composition comprising:polychloroprene,10 to 99 wt %, based on polychloroprene content, of an ethylene-vinyl acetate copolymer having a vinyl acetate content of 18 to 90, and60-95 wt % of solvent, based on a total weight of the contact adhesive composition.2. (canceled)3. Contact adhesive composition according to claim 1 , comprising 60-95 wt % of solvent claim 1 , and also a total of 5-40 wt % of polychloroprene and ethylene-vinyl acetate copolymer claim 1 , based in each case on the total weight of the contact adhesive composition.4. Contact adhesive composition according to claim 1 , comprising 0.1-35 wt % claim 1 , of further components claim 1 , selected from resins claim 1 , magnesium oxide claim 1 , zinc oxide claim 1 , isocyanate-based crosslinkers claim 1 , and ageing inhibitors claim 1 , based on the total weight of the contact adhesive composition.5. Contact adhesive composition according to claim 1 , which is free from methyl methacrylate.6. Contact adhesive composition according to claim 1 , further comprising terpene phenolic resin claim 1 , alkyl-phenolic resin claim 1 , coumarone-indene ...

IMPROVED ADHESIVE COMPOSITION FOR BONDING RUBBER TO METAL

An adhesive composition is comprised of a film forming polymer, (ii) a lower crystallinity polynitroso compound, (e.g., poly-(1,4-phenylyenazine-N,N-dioxide)), (iii) a higher crystallinity polynitroso compound (e.g., poly-(1,4-phenylyenazine-N,N-dioxide)), and (iv) a carrier liquid. The composition is useful in bonding metal and rubber to make, for example, components to damp noise, vibration or harshness. 1. An adhesive composition comprising , (i) a film forming polymer , (ii) a lower crystallinity polynitroso compound having a crystallinity of less than 30% by weight as determined by X-ray diffraction and , (iii) a higher crystallinity polynitroso compound having a crystallinity of at least 35% by weight as determined by X-ray diffraction , and (iv) a carrier liquid.2. The composition of claim 1 , wherein the film forming polymer is a halogenated olefin polymer.3. The composition of claim 1 , wherein the film forming polymer is a halogenated substituted polydiene polymer.4. The composition of claim 1 , wherein (ii) and (iii) components of the composition are provided in a lower crystallinity/higher crystallinity weight ratio of 1/2 to 2/1.5. The composition of claim 4 , wherein the lower crystallinity/higher crystallinity weight ratio is 1.1/1 to 1/1.1.6. The composition of claim 1 , wherein the lower crystallinity polynitroso compound is a lower crystallinity poly-(1 claim 1 ,4-phenylyenazine-N claim 1 ,N-dioxide).7. The composition of claim 1 , wherein the higher crystallinity polynitroso compound is a higher crystallinity poly-(1 claim 1 ,4-phenylyenazine-N claim 1 ,N-dioxide).8. The composition of claim 1 , wherein the liquid carrier is comprised of water.9. The composition of claim 8 , wherein the adhesive composition is further comprised of a surfactant.10. The composition of claim 9 , wherein the surfactant is comprised of at least one of an anionic surfactant claim 9 , cationic surfactant claim 9 , nonionic surfactant and amphoteric surfactant.11. The ...

CHLOROPRENE COPOLYMER LATEX, METHOD FOR PRODUCING SAME, VULCANIZED PRODUCT, DIP MOLDED ARTICLE AND METHOD FOR PRODUCING SAME

A chloroprene copolymer latex containing a chloroprene copolymer having a structural unit derived from chloroprene and a structural unit derived from 2,3-dichloro-1,3-butadiene, in which a toluene insoluble content in the chloroprene copolymer is 50 to 95% by mass, and a modulus at 500% elongation of a film, which is obtained on a base material by dipping the base material in the chloroprene copolymer latex and then performing vulcanization at 100° C. for 30 minutes, according to JIS K 6251 is 4.0 MPa or less. 1. A chloroprene copolymer latex comprising a chloroprene copolymer having a structural unit derived from chloroprene and a structural unit derived from 2 ,3-dichloro-1 ,3-butadiene , whereina toluene insoluble content in the chloroprene copolymer is 50 to 95% by mass, anda modulus at 500% elongation of a film, which is obtained on a base material by dipping the base material in the chloroprene copolymer latex and then performing vulcanization at 100° C. for 30 minutes, according to JIS K 6251 is 4.0 MPa or less.2. The chloroprene copolymer latex according to claim 1 , wherein a modulus at 100% elongation of the film according to JIS K 6251 is 0.5 to 1.2 MPa.3. The chloroprene copolymer latex according to claim 1 , wherein the chloroprene copolymer provides a peak derived from abietic acid in gas chromatography of an extract extracted from the chloroprene copolymer using an ethanol/toluene azeotropic mixture.4. The chloroprene copolymer latex according to claim 1 , wherein a content of the structural unit derived from 2 claim 1 ,3-dichloro-1 claim 1 ,3-butadiene is more than 0% by mass and 35% by mass or less on the basis of a total amount of the structural unit derived from chloroprene and the structural unit derived from 2 claim 1 ,3-dichloro-1 claim 1 ,3-butadiene.5. The chloroprene copolymer latex according to claim 1 , wherein the chloroprene copolymer latex does not comprise a vulcanization accelerator.6. A vulcanizate of the chloroprene copolymer latex ...

METHOD FOR BONDING AND BONDING MIXTURE

A method for bonding and a bonding mixture for the bonding of a textile to a rubber component, wherein the bonding mixture comprises at least one latex and one formaldehyde-free crosslinker, wherein the crosslinker comprises at least one substance from at least one of oxazolidines, quinone dioximes, and/or maleinized polybutadienes. 1. A method for bonding a textile to a rubber component via a bonding mixture , the method comprising:providing the bonding mixture with at least one latex and one formaldehyde-free crosslinker, the crosslinker comprising at least one substance from at least one of the groups: oxazolidines, quinone dioximes, and/or maleinized polybutadienes; andapplying the bonding mixture to bond the rubber component to the textile.2. The method according to claim 1 , wherein the crosslinker is free of resorcinol resin.3. The method according to claim 1 , wherein the latex is a vinylpyridine latex claim 1 , styrene-butadiene latex claim 1 , nitrile-butadiene latex claim 1 , styrene-butadiene-vinylpyridine terpolymer claim 1 , chloroprene or natural rubber.4. The method according to claim 1 , wherein the bonding mixture further comprises a wax.5. The method according to claim 1 , wherein the bonding mixture further comprises a tackifier.6. The method according to claim 1 , wherein the rubber component is a tire claim 1 , a rubber chain for a crawler claim 1 , a V-belt claim 1 , a toothed belt claim 1 , a hose claim 1 , a molded hose claim 1 , a conveyor belt or a rubberized garment.7. A bonding mixture for bonding a textile to a rubber component claim 1 , wherein the bonding mixture comprises at least one latex and one formaldehyde-free crosslinker claim 1 , wherein the crosslinker comprises at least one substance from at least one of the groups: oxazolidines claim 1 , quinone dioximes claim 1 , and/or maleinized polybutadienes.8. The bonding mixture according to claim 7 , wherein the crosslinker is free from resorcinol resin.9. The bonding mixture ...

USE OF A KETAL AS A SOLVENT IN ADHESIVES AND KETAL-CONTAINING ADHESIVE COMPOSITION

The present invention relates to the use of a cyclic ketal, 2-methyl-2-ethyl-1,3-dioxolane as a solvent in adhesives, as well as an adhesive composition comprising said ketal. 2-Methyl-2-ethyl-1,3-dioxolane has high solubilization power of the polychloroprene polymer, forming solutions having high viscosity and having suitable drying time after application of a film onto a surface. Due to the good technical performance, the adhesive composition made according to the present invention is well accepted in the market, finding use to substitute compositions containing toluene or other aromatic and oxygenated solvents. 1. The use of a ketal as a solvent in adhesives , particularly for imparting suitable viscosity and drying time to adhesive compositions , characterized in that it is 2-methyl-2-ethyl-1 ,3-dioxolane ketal and it is present in a ratio in the range of 5 to 90% based on the total weight of the composition ,wherein the adhesive compositions are contact adhesive compositions and wherein the adhesive compositions comprising polychloroprene, synthetic resins, or mixtures thereof.2. The use of claim 1 , characterized in that the ketal is present in an amount of 60% based on the total weight of the composition.3. The use of claim 1 , characterized in that the synthetic resins are acrylic resin claim 1 , epoxy resin claim 1 , phenolic resin claim 1 , melamine resin or mixtures thereof.4. A ketal-containing adhesive composition claim 1 , characterized in that it comprises: from 10 to 30% of polychloroprene based on the total of the composition; from 2 to 10% synthetic resins; from 20 to 60% of 2-methyl-2-ethyl-1 claim 1 ,3-dioxolane; from 20 to 60% of one or more co-solvents; from 1 to 3% of magnesium oxide; from 1 to 3% of zinc oxide; and from 0.5 to 1% of an anti-oxidizing agent.5. The composition of claim 4 , characterized in that the co-solvents belong to the families of oxygenated solvents claim 4 , aliphatic hydrocarbons and/or cyclo-aliphatic hydrocarbons.67-. ...

CHLOROPRENE ADHESIVE SYSTEM

The chloroprene adhesive system according to the invention guarantees, even at high temperatures, improved stability of the adhesive bond compared to an adhesive bond produced using conventional multi-component adhesives. The chloroprene adhesive system comprises a first component (A), which contains inter alia an unsaturated elastomer, in particular chloroprene rubber. In addition, the first component (A) comprises an additive, in particular a metal oxide and preferably zinc oxide. Furthermore, the chloroprene adhesive system contains as a second component (B) a halogenated reactive curing resin and preferably a brominated reactive curing resin. 110-. (canceled)11. A chloroprene adhesive system comprising a first component (A) and a second component (B) ,wherein the first component (A) contains an unsaturated elastomer and a metal oxide additive;wherein the second component (B) contains a halogenated reactive curing resin; andwherein the stoichiometric ratio of the first component (A) to the second component (B) is 100/15 to 100/1.12. The chloroprene adhesive system of wherein the unsaturated elastomer is chloroprene rubber or a blend of chloroprene rubber with other unsaturated rubber mixtures.13. The chloroprene adhesive system of wherein the metal oxide additive is zinc oxide in the range of 10 Подробнее

Chloroprene graft copolymer latex, method for producing same, bonding agent and adhesive

Provided is a method for producing a chloroprene graft copolymer latex containing no organic solvent and exhibiting high adhesive strength even for soft polyvinyl chloride. A method for producing a chloroprene graft copolymer latex includes a chloroprene polymerization step of giving a chloroprene polymer latex and a graft copolymerization step of giving a chloroprene graft copolymer latex. The chloroprene polymerization step is a step of subjecting at least chloroprene (A-1) of chloroprene (A-1) and a monomer (A-2) copolymerizable with chloroprene (A-1) to emulsion radical polymerization. The graft copolymerization step is a step of adding, to the chloroprene polymer latex, a (meth)acrylate (B) and an organic peroxide (C) having an octanol/water partition coefficient of −2.0 or more and 3.0 or less to subject the chloroprene polymer to graft copolymerization with the (meth)acrylate (B) at a temperature of 10° C. or more and 40° C. or less.

CHLOROPRENE RUBBER LATEX ADHESIVE COMPOSITION

Provided is a chloroprene rubber latex adhesive composition superior in initial adhesive strength and normal adhesive strength and also in thermal creep resistance with adherend. A chloroprene rubber latex adhesive composition includes a carboxy-modified chloroprene-based copolymer latex (A) containing a copolymer of chloroprene monomer and an ethylenic unsaturated carboxylic acid and a polyvinylalcohol, a chloroprene-based polymer latex (B) containing a chloroprene homopolymer or a copolymer of chloroprene monomer and other monomer and a rosin acid metal salt and a chlorinated polyolefin resin emulsion (C), wherein the content ratio of the carboxy-modified chloroprene-based copolymer latex (A) to the chloroprene-based polymer latex (B) is 80:20 to 20:80 as solid matter. 1. A chloroprene rubber latex adhesive composition comprising a carboxy-modified chloroprene-based copolymer latex (A) containing a copolymer of chloroprene monomer and an ethylenic unsaturated carboxylic acid and a polyvinylalcohol ,a chloroprene-based polymer latex (B) containing a chloroprene homopolymer or a copolymer of chloroprene monomer and other monomers and a rosin acid metal salt anda chlorinated polyolefin resin emulsion (C), whereinthe content ratio of the carboxy-modified chloroprene-based copolymer latex (A) to the chloroprene-based polymer latex (B) is 80:20 to 20:80 as solid matter.2. The chloroprene rubber latex adhesive composition according to claim 1 , comprising the chlorinated polyolefin resin emulsion (C) in an amount of 1 to 50 parts by mass as solid matter with respect to 100 parts by mass as solid matter of the total content of the carboxy-modified chloroprene-based copolymer latex (A) and the chloroprene-based polymer latex (B).3. The chloroprene rubber latex adhesive composition according to claim 1 , comprising a tackifying resin in an amount of 1 to 100 parts by mass as solid matter and zinc oxide in an amount of 0.5 to 10 parts by mass as solid matter with respect to ...

LATEX FOR ADHESIVE COMPOSITION AND ADHESIVE COMPOSITION

The present invention relates to (1) a latex for an adhesive composition, the latex for an adhesive composition (A) containing a polymer of an ethylenic unsaturated monomer (al), a surfactant (a2), and an aqueous medium, the polymer of an ethylenic unsaturated monomer (al) having a carboxy group, the polymer of an ethylenic unsaturated monomer (al) having an average particle diameter of 0.30 to 5.00 μm, (2) a latex for an adhesive composition, the latex for an adhesive composition (A) containing a polymer of an ethylenic unsaturated monomer (al), a surfactant (a2), and an aqueous medium, the polymer of an ethylenic unsaturated monomer (al) having a carboxy group and a crosslinked structure, and (3) an adhesive composition containing the latex for an adhesive composition (A) and a chloroprene based polymer latex (B). 1. A latex for an adhesive composition , the latex for an adhesive composition (A) comprising a polymer of an ethylenic unsaturated monomer (a1) , a surfactant (a2) , and an aqueous medium , the polymer of an ethylenic unsaturated monomer (a1) having a carboxy group , the polymer of an ethylenic unsaturated monomer (a1) having an average particle diameter of 0.30 to 5.00 μm.2. The latex for an adhesive composition according to claim 1 , wherein the polymer of an ethylenic unsaturated monomer (a1) has an average particle diameter of 0.50 to 3.00 μm.3. The latex for an adhesive composition according to claim 1 , wherein the polymer of an ethylenic unsaturated monomer (a1) has a structural unit derived from an ethylenic unsaturated monomer having a carboxy group and a structural unit derived from an ethylenic unsaturated monomer having a functional group having reactivity with a carboxy group.4. The latex for an adhesive composition according to claim 1 , wherein the polymer of an ethylenic unsaturated monomer (a1) has a structural unit derived from a crosslinkable ethylenic unsaturated monomer having plural ethylenic unsaturated bonds in a molecule.5. The ...

ADHESIVE COMPOSITION AND USE THEREOF FOR PROVIDING A SELF-HEALING ADHERED ROOFING SYSTEMS

An adhesive composition and use thereof for providing self-healing adhered roofing systems. The adhesive composition includes at least one rubber component, at least one organic solvent, and 12.5-40 wt.-% of at least one powdered superabsorber polymer, based on the total weight of the adhesive composition. Further, a self-healing membrane composite, to a method for forming a self-healing adhered roofing system, to a self-healing adhered roofing system and to use of at least one powdered superabsorber polymer in an adhesive for providing a self-healing adhered roofing system. 2. The adhesive composition according to comprising 5-60 wt. % claim 1 , based on the total weight of the adhesive composition claim 1 , of the at least one rubber component.3. The adhesive composition according to claim 1 , comprising 40-90 wt. % claim 1 , based on the total weight of the adhesive composition claim 1 , of the at least one organic solvent.4. The adhesive composition according to claim 1 , wherein the at least one organic solvent has a Hildebrandt solubility parameter δ in the range of 5-40 MPa claim 1 , and/or a relative evaporation rate determined according to DIN 53170 standard of not more than 40.5. The adhesive composition according to claim 1 , wherein the at least one rubber component is selected from the group consisting of chloroprene rubber claim 1 , butyl rubber claim 1 , halogenated butyl rubber claim 1 , acryl nitrile rubber claim 1 , natural rubber claim 1 , polyisobutylene claim 1 , and polyurethane rubber.6. The adhesive composition according to claim 1 , further comprising 0.1-20.0 wt. % claim 1 , based on the total weight of the adhesive composition claim 1 , of non-hydrated cement particles.8. The membrane composite according to claim 7 , wherein the particles of the at least one superabsorber polymer are distributed throughout the entire volume of the layer of anhydrous adhesive composition.9. The membrane composite according to claim 7 , wherein the particles ...

Water-Based Adhesives

An adhesive includes a polymeric latex, a penetrant selected from the group consisting of: terpenes, polylimonene, limonene, carvone, a-pinene, citral, dipentene, 1,8-cineole, eucalyptol, citronellol, geraniol, citronellene, terpinen-4-ol, borneol, camphor, guayule resin, and combinations thereof; and a reinforcing filler. The adhesive has a solids content of 35-65% and a pH of 9 to 12. Articles of manufacture, such as tires and air springs incorporate the adhesive to join rubber interfaces. A method of making the adhesive is also is provided. 120-. (canceled)21. An adhesive comprising:a polymeric latex;a penetrant selected from the group consisting of: terpenes, limonene, polylimonene, carvone, α-pinene, citral, dipentene, 1,8-cineole, eucalyptol, citronellol, geraniol, citronellene, terpinen-4-ol, borneol, camphor, guayule resin, and combinations thereof;a reinforcing filler;wherein the adhesive has a solids content of 35-65% and a pH of 9 to 12.22. The adhesive of wherein the pH of the polymeric latex is within the range of about 7 to about 14.23. The adhesive of wherein the solids content of the polymeric latex is in the range of about 10% to about 90% by weight.24. The adhesive of wherein the reinforcing filler is carbon black and is present in an amount of 10 to 80 phr.25. The adhesive of further comprising a tackifier with a pH of about 2 to about 13 and a solids content of about 30 to about 80.26. The adhesive of wherein the reinforcing filler is carbon black and is selected from the following series: N100 claim 21 , N200 claim 21 , N300 claim 21 , N400 claim 21 , N500 claim 21 , N600 claim 21 , N700 claim 21 , N800 claim 21 , and N900.27. The adhesive of wherein the polymeric latex comprises water and a polymer selected from the group consisting of polychloroprene claim 21 , butyl rubber claim 21 , hevea or non-hevea natural rubber claim 21 , polyisoprene claim 21 , polybutadiene claim 21 , nitrile rubber claim 21 , poly(styrene-butadiene) claim 21 , and ...

Sprayable Water-Based Adhesive

Water-based adhesive compositions are improved by the incorporation of hollow polymeric microspheres having outer surfaces coated with one or more barrier materials such as calcium carbonate particles. The adhesive compositions exhibit enhanced rheology, sprayability, drying time, tack and storage stability as compared to analogous adhesives that are not modified with coated hollow polymeric microspheres. Such compositions are useful as both contact adhesives as well as wet bonding one-way adhesives. 129.-. (canceled)30. A process for bonding a first substrate to a second substrate comprising:a) applying a water-based adhesive composition on a surface of the first substrate, wherein the water-based adhesive composition comprises a) at least about 30 weight percent of water; b) an adhesive polymer which is a homopolymer or copolymer of chloroprene having a glass transition temperature that is less than about 0° C.; and c) about 1 weight percent to about 3 weight percent of hollow, polymeric microspheres, based on the weight of the water-based adhesive composition, wherein the microspheres are coated with at least one barrier material which provides an outer coating;b) drying, at least partially, the water-based adhesive composition to form an adhesive film layer on the surface of the first substrate; andc) bonding the first substrate to the second substrate.31. The process of claim 30 , wherein bonding step c) comprises contacting the second substrate with the adhesive film layer on the surface of the first substrate.32. The process of claim 30 , further comprising:prior to bonding step c), applying the water-based adhesive composition on a surface of the second substrate; anddrying, at least partially, the water-based adhesive composition to form an adhesive film layer on the surface of the second substrate;wherein the bonding comprises contacting the adhesive film layer on the surface of the second substrate with the adhesive film layer on the surface of the first ...

WATER-BASED ADHESIVES

An adhesive includes a polymeric latex, a penetrant selected from the group consisting of: terpenes, polylimonene, limonene, carvone, a-pinene, citral, dipentene, 1,8-cineole, eucalyptol, citronellol, geraniol, citronellene, terpinen-4-ol, borneol, camphor, guayule resin, and combinations thereof; and a reinforcing filler. The adhesive has a solids content of 35-65% and a pH of 9 to 12. Articles of manufacture, such as tires and air springs incorporate the adhesive to join rubber interfaces. A method of making the adhesive is also is provided. 1. An article of manufacture comprising:an elastomeric rubber component comprising an elastomer selected from the group consisting of: polychloroprene, butyl rubber, natural rubber, guayule rubber, polyisoprene, polybutadiene, nitrile rubber, poly(styrene-butadiene), and combinations thereof;the elastomeric rubber component being joined at an interface with a second rubber component or another portion of the elastomeric rubber component;wherein the interface includes a layer of a water-based adhesive, the water-based adhesive comprising:a polymeric latex;a penetrant selected from the group consisting of: terpenes, polylimonene, limonene, carvone, α-pinene, citral, dipentene, 1,8-cineole, eucalyptol, citronellol, geraniol, citronellene, terpinen-4-ol, borneol, camphor, guayule resin, and combinations thereof; anda reinforcing filler in an amount of 10 to about 80 phr;wherein the adhesive has a solids content of 35-65% and a pH of about 9 to about 12;wherein the article of manufacture is a rubber air spring or a tire component.2. The article of manufacture of claim 1 , wherein the elastomeric rubber component or the second rubber component is uncured.3. The article of manufacture of claim 1 , wherein the article is a rubber air spring.4. The article of manufacture of claim 1 , wherein the article is a tire component.5. The article of manufacture of claim 4 , wherein the elastomeric rubber component is uncured and is joined at ...

POLYCHLOROPRENE-BASED BONDING ADHESIVES

An adhesive composition comprising a solids component, said solids component including a rubber component that includes polychloroprene; and a solvent component, said solvent component including t-butyl acetate. 1. An adhesive composition comprising:i. a solids component, said solids component including a rubber component that includes polychloroprene, where the solids component includes at least 20 parts by weight thermosetting resin per 100 parts by weight rubber, and where the rubber component includes at least 70% by weight polychloroprene; andii. a solvent component, where the solvent component includes at least 150 parts and less than 500 parts by weight t-butyl acetate, and at least 30 parts and less than 50 parts by weight toluene per 100 parts by weight rubber.2. The composition of claim 1 , where the rubber component further includes poly-(styrene-co-butadiene).3. The composition of claim 1 , where the rubber component is devoid of a complementary rubber claim 1 , and where the solids component includes an adhesion promoter.4. An adhesive composition comprising:i. a solids component, said solids component including a rubber component, a synthetic thermosetting resin, and a hydrocarbon resin, where the rubber component includes at least 70% by weight polychloroprene; andii. a solvent component, said solvent component including at least 150 parts and less than 500 parts by weight t-butyl acetate, and at least 30 parts and less than 50 parts by weight toluene per 100 parts by weight rubber.5. The adhesive composition of claim 4 , where the rubber component includes at least 70% by weight polychloroprene.6. The adhesive composition of claim 1 , where the polychloroprene includes a first polychloroprene characterized by a solution viscosity of from 70 to 215 mPa·s and a second polychloroprene characterized by a solution viscosity of from about 700 to about 1 claim 1 ,000 MPa·s.7. The adhesive composition of claim 6 , where the solids component includes at least ...

Article, in Particular Air Spring Bellows, a Metal-Rubber Element, or a Vibration Damper

The invention relates to an article having a single- or multi-layered main body having elastic properties, in particular an air spring bellows, a metal-rubber element or a vibration damper. 1. A rubber mixture comprising at least one carbon black having a BET surface area according to DIN-ISO 9277 between 35 and 140 m/g and an oil absorption number (OAN) according to ISO 4656 between 70 and 140 ml/100 g , a first aluminum trihydrate (ATH_1) and at least a further aluminum trihydrate (ATH_2) , wherein the first aluminum trihydrate (ATH_1) and the further aluminum trihydrate (ATH_2) each have a different particle size;{'sub': 50', '50, 'wherein the particle size dof the first aluminum trihydrate (ATH_1) determined by laser diffraction is between 0.1 and 0.6 μm and the further aluminum trihydrate (ATH_2) has a particle size ddetermined by laser diffraction of between 0.9 and 1.5 μm;'}wherein the amount of carbon black is 5 to 30 phr;wherein the first aluminum trihydrate (ATH_1) is incorporated in an amount of from 30 to 70 phr;wherein the at least one further aluminum trihydrate (ATH_2) is incorporated in an amount of from 60 to 150 phr; and,wherein the rubber mixture is free of halogen-containing flame retardants.2. The rubber mixture according to claim 1 , wherein the at least one carbon black is selected from N550 and N339 carbon blacks.3. The rubber mixture according to claim 1 , wherein the first aluminum trihydrate (ATH_1) or the at least a further aluminum trihydrate (ATH_2) is silanized.4. The rubber mixture according to claim 1 , wherein the first aluminum trihydrate (ATH_1) and the at least a further aluminum trihydrate (ATH_2) is silanized.5. The rubber mixture according to further comprising at least one further flame retardant selected from the group consisting of zinc stannate claim 1 , zinc hydroxystannate claim 1 , hydroxide claim 1 , calcium hydroxide claim 1 , melamine cyanurate claim 1 , zinc borate claim 1 , calcium borate claim 1 , resorcinol ...

LAMINATE, ADHESIVE KIT, LAMINATED STRUCTURE AND PRODUCTION METHOD THEREOF, AND CONTACT ADHESIVE COMPOSITION

A laminate comprising a substrate layer; a contact adhesive layer comprising a contact adhesive agent having at least one of chloroprene rubber or acrylic copolymers, as well as microspheres having an average particle size of 0.5 μm or greater in the contact adhesive layer, wherein the contact adhesive layer contains from 5 parts by mass to 500 parts by mass of the microspheres per 100 parts by mass of the contact adhesive agent, and the contact adhesive layer has a plurality of protruding portions because of the microspheres. 1. A laminate comprising:a substrate layer having a first and second major surface;a contact adhesive layer having a first and second major surface, the second major surface of the contact adhesive layer adhesively coupled to the first major surface of the substrate layer, the contact adhesive layer comprising a contact adhesive agent comprising at least one of chloroprene rubber or acrylic copolymers, and additionally comprising microspheres have an average particle size of 0.5 μm or greater; wherein the contact adhesive layer contains from 5 parts by mass to 500 parts by mass of the microspheres per 100 parts by mass of the contact adhesive agent, andthe first major surface of the contact adhesive layer comprises a plurality of protrusions corresponding to the locations of at least some of the microspheres.2. The laminate according to claim 1 , wherein the contact adhesive layer is substantially nontacky.3. The microspheres according to claim 1 , wherein the microspheres comprise cross-linked organic resin.4. The laminate according to any claim 1 , wherein the microspheres comprise solid microspheres of acrylic polymer or urethane polymer.5. The laminate according to claim 1 , wherein the microspheres are substantially nontacky.6. The laminate according to claim 1 , wherein a mass per unit area of the contact adhesive layer is from 5 g/mto 100 g/m.7. The laminate according to claim 1 , wherein a 60 degree gloss value of the first major ...

LATEX COMPOSITION AND ONE-PACK TYPE AQUEOUS ADHESIVE COMPOSED OF SAID LATEX COMPOSITION

A latex composition gives favorable initial adhesive strength after short drying period, shows storage stability and spray coating characteristics and gives a soft adhesive layer after drying and a one-pack type aqueous adhesive. The latex composition includes a chloroprene-based polymer latex (A) containing a chloroprene-based polymer in an amount of 50 to 85 mass % as solid matter and an acrylic polymer latex (B) having a glass transition temperature of −52 to −9° C. and containing an acrylic polymer containing a sodium alkylbenzenesulfonate having a structure represented by the Chemical Formula (1) in an amount of 15 to 50 mass % as solid matter, in a total amount of 100 parts by mass, and additionally at least one pH regulator (C) selected from boric acid, ammonium sulfate, and amino acids having an isoelectric point of 5.5 to 6.5 in an amount of 3 to 13 parts by mass as solid matter. 2. The latex composition according to claim 1 , wherein the sodium alkylbenzenesulfonate having a structure represented by the Chemical Formula (1) above is sodium dodecylbenzenesulfonate or a sodium alkyl diphenyl ether disulfonate.3. The latex composition according to claim 1 , wherein the content of the sodium alkylbenzenesulfonate having a structure represented by the Chemical Formula (1) is 1.5 to 5 parts by mass with respect to 100 parts by mass of the acrylic polymer.4. The latex composition according to claim 1 , wherein the chloroprene-based polymer is a chloroprene homopolymer claim 1 , a copolymer of chloroprene and 2 claim 1 ,3-dichloro-1 claim 1 ,3-butadiene claim 1 , or a mixture of a chloroprene homopolymer and a copolymer of chloroprene and 2 claim 1 ,3-dichloro-1 claim 1 ,3-butadiene.5. The latex composition according to claim 1 , wherein the chloroprene-based polymer latex (A) has a gel content (toluene insoluble fraction) of 5 to 30 mass % and the toluene soluble fraction has a number-average molecular weight of 200 claim 1 ,000 to 500 claim 1 ,000 and a ...

Acid resistant adhesive composition

This invention relates to an acid resistant adhesive composition, comprising at least one polychloroprene; at least one epoxy silane; at least one amine silane; at least one unsaturated silane; and at least one organic solvent. The acid resistant adhesive composition according to the present invention exhibits excellent initial peel strength and final peel strength after being soaked in electrolyte solution and shows good acid resistant property.

LOW PRESSURE 2-K HANDHELD SPRAY GUN

A low pressure limited overspray handheld aerosol spray gun for spraying a two-component adhesive, a method for spraying a two-component adhesive and a two-component adhesive obtainable by that method. In manufacturing of larger objects, such as matrasses and furniture, adhesives are often applied to fix parts of the large object together. Most adhesives are applied using either air-spray equipment or air-assisted spray equipment. 1. A low pressure limited overspray handheld aerosol spray gun for spraying a two-component adhesive comprising 80-97 wt. % of a first fluid and 3-20 wt. % of a second fluid , the wt. percentage calculated on a combined first and second fluid , comprising:(a) a first and second connection for supply of the first and second fluid, respectively,(b) a first nozzle and a second nozzle,(c) a separate fluid passageway for the first and second fluid between the connection and nozzle, respectively,(d) a first and second mechanism for opening and closing of the passage way of each fluid to the nozzle,(e) a trigger for simultaneous control of the mechanisms,(f) a third fluid passageway for providing air,(g) a chamber wherein the second and third passage ways enter and from which access to the second nozzle is provided, and(h) a first removable nozzle tip attached to the first nozzle, andwherein the first nozzle tip has a slit incorporated therein, andwherein the system is capable of withstanding a first fluid airless pressure of 200-800 kPa (2-8 Bar) and capable of withstanding a second fluid air-assisted pressure of 12-100 kPa (0.12-1.0 Bar).2. The aerosol gun according to claim 1 , wherein the second nozzle is directed such that the second fluid intimately mixes with the first fluid at a distance of 1-10 cm of the first nozzle.3. The aerosol spray gun according to claim 1 , wherein the first nozzle has an opening with a first area claim 1 , wherein the second nozzle has an opening with a second area claim 1 , wherein a ratio between the first area ...

ARTICLE, IN PARTICULAR AIR SPRING BELLOWS, A METAL-RUBBER ELEMENT, OR A VIBRATION DAMPER

The invention relates to an article having a single- or multi-layered main body having elastic properties, in particular an air spring bellows, a metal-rubber element or a vibration damper. 17-. (canceled)8. An article comprising at least a single-layered main body having elastic characteristics , wherein at least a layer D of the main body is constructed from a rubber mixture which is free from halogen-containing flame retardants , wherein the rubber mixture comprises at least one carbon black having a BET surface area according to DIN-ISO 9277 between 35 and 140 m/g and an oil absorption number (OAN) according to ISO 4656 between 70 and 140 ml/100 g , a first aluminum trihydrate (ATH_1) and at least a further aluminum trihydrate (ATH_2) , wherein the first aluminum trihydrate (ATH_1) and the further aluminum trihydrate (ATH_2) each have a different particle size; and ,{'sub': 50', '50, 'wherein the particle size dof the first aluminum trihydrate (ATH_1) determined by laser diffraction is between 0.1 and 0.6 μm and the further aluminum trihydrate (ATH_2) has a particle size ddetermined by laser diffraction of between 0.9 and 1.5 μm.'}9. The article as claimed in claim 8 , wherein the amount of carbon black is 5 to 30 phr.10. The article as claimed in claim 8 , wherein the first aluminum trihydrate (ATH_1) is incorporated in the layer D in an amount of from 30 to 150 phr.11. The article as claimed in claim 8 , wherein the at least one further aluminum trihydrate (ATH_2) is incorporated in the layer D in an amount of from 60 to 70 phr.12. The article as claimed in claim 8 , wherein the layer D comprises 100 phr of CR or 100 phr of a blend of CR and NR (CR/NR) as the rubber component.13. The article as claimed in claim 8 , wherein the article is an air spring bellows claim 8 , a metal-rubber element claim 8 , a vibration damper claim 8 , a damping element of a bearing of a bushing claim 8 , a damping element of a multilayered spring claim 8 , a damping element of a ...

WATERBASED ONE COAT ADHESIVE COMPOSITION

Disclosed is an aqueous adhesive composition which comprises an admixture of: (a) a first aqueous composition comprising, (i) one or more film forming polymers, (ii) one or more lower crystallinity polynitroso compounds, (iii) one or more higher crystallinity polynitroso compounds, and (iv) one or more bismaleimide-containing monomers; and (b) a second aqueous composition comprising (i) an aqueous dispersion of at least one phenolic resin which is a condensation product of a phenol and formaldehyde, wherein the aqueous dispersion is stabilized by at least one polyacrylate; (b) one or more latices formed from one or more halogenated polyolefins; and (c) one or more metal oxides. 2. The aqueous adhesive composition according to claim 1 , wherein the one or more film forming polymers are a halogenated olefin polymer.3. The aqueous adhesive composition according to claim 1 , wherein the one or more film forming polymers are a halogenated substituted polydiene polymer.4. The aqueous adhesive composition according to claim 1 , wherein the one or more lower crystallinity polynitroso compounds has a crystallinity of less than 30% by weight as determined by X-ray diffraction and the one or more higher crystallinity polynitroso compounds has crystallinity of greater than 40% by weight as determined by X-ray diffraction.5. The aqueous adhesive composition according to claim 4 , wherein the one or more lower crystallinity polynitroso compounds and the one or more higher crystallinity polynitroso compounds are poly-(1 claim 4 ,4-phenylyenazine-N claim 4 ,N-dioxide).6. The aqueous adhesive composition according to claim 1 , wherein a weight ratio of the one or more lower crystallinity polynitroso compounds to the one or more higher crystallinity polynitroso compounds is 1:2 to 2:1.8. The aqueous adhesive composition according to claim 1 , wherein the first aqueous composition comprises:(i) 2 wt. % to 75 wt. %, based on the total weight of the first aqueous composition, of the one ...

Polychloroprene adhesive latex composition

Polychloroprene latex adhesive compositions which comprise a) mercaptan-modified or xanthogen disulfide-modified 2-chloro-1,3-butadiene homopolymers having gel contents of 5-70 percent by weight, b) 1 to 75 parts by weight of rosin per 100 parts by weight of a), and c) sufficient water to provide a solids content of 25-65 weight percent based on the weight of component a) exhibit excellent heat resistance and green bond strength.

Polychloroprene composition

Crystalline polychloroprene compositions comprise mercaptan-modified or xanthogen disulfide-modified 2-chloro-1,3-butadiene homopolymers having gel contents of 5-70 percent by weight. The polymers are prepared by free radical emulsion polymerization at a temperature of 5 °C-20 °C to a conversion of 70-95 % in the presence of 1.5 x 10-4-2.5 x 10-4 moles of mercaptan or xanthogen disulfide modifier per mole of 2-chloro-1,3-butadiene.

ADHESIVE AND ADHESIVE COMPOSITION THAT IS USED.

Una composición adhesiva que comprende un látex de cloropreno (A), un plastificante de tipo éster de fosfato aromático (B) y un agente de ajuste del pH (C). An adhesive composition comprising a chloroprene latex (A), an aromatic phosphate ester type plasticizer (B) and a pH adjusting agent (C).

Polychloroprene composition

Crystalline polychloroprene compositions comprise mercaptan-modified or xanthogen disulfide-modified 2-chloro-1,3-butadiene homopolymers having gel contents of 5-80 percent by weight. The polymers are prepared by free radical emulsion polymerization at a temperature of 5°-20° C. to a conversion of 70-95 percent in the presence of 2.5×10 -4 -5.5×10 -4 moles of mercaptan or xanthogen disulfide modifier per mole of 2-chloro-1,3-butadiene.

FORMULATIONS BASED ON ANIONICALLY STABILIZED WATERPROOF POLYMER DISPERSIONS

La invencion se refiere a formulaciones basadas en dispersiones poliméricas acuosas anionicamente estabilizadas, que contienen policloropreno, a las que se ha anadido dioxido de carbono (CO2), a un procedimiento para su preparacion, a un dispositivo para incrementar el contenido de dioxido de carbono en las formulaciones basadas en dispersiones poliméricas acuosas anionicamente estabilizadas, y a su uso en la produccion de adhesivos, sellantes, piezas de gran volumen o recubrimientos. The invention relates to formulations based on anionically stabilized aqueous polymer dispersions, containing polychloroprene, to which carbon dioxide (CO2) has been added, to a process for its preparation, to a device for increasing the content of carbon dioxide in formulations based on anionically stabilized aqueous polymer dispersions, and their use in the production of adhesives, sealants, large volume parts or coatings.

Elastomer based adhesive compositions

A substantially solvent-free adhesive composition consists essentially of an elastomer and tackifier, a metal oxide and, optionally, a plasticizer. The elastomer is selected from the group consisting of polar elastomers and unsaturated elastomers which have at least 5 mole percent unsaturation, said elastomer being a non-crystalline elastomer or an elastomer which has a slow rate of crystallization such that after a time period of at least 100 hours has elapsed following subjecting the elastomer to a temperature of 70° C. for 30 minutes, the elastomer has a room temperature Shore A hardness of less than 60. The adhesive compositions can be formed into a shaped article, such as of a tape, film, sheet or tubular sleeve, if desired. The compositions have high adhesive strength for bonding together a variety of substrates. The adhesive is particularly useful with a dimensionally recoverable article, such as a shrinkable sleeve, to bond the recovered sleeve to a substrate such as an electric cable.

一种金属用粘结胶的配方及其应用

本发明涉及一种金属用粘结胶的配方及其应用，具体是氯丁橡胶与金属零件热硫化粘接底胶的配方，属于金属用粘结胶制备工艺领域。其金属用粘结胶的配方按重量份计配方比例如下：列克纳胶100份；氯化胶浆40~60份，氯化胶浆中包括氯化橡胶和溶剂；氯丁胶浆40~60份，氯丁胶浆中包括氯丁橡胶和溶剂。金属用粘结胶的应用步骤包括：（1）氯丁胶浆的制备，（2）氯化胶浆的制备，（3）复配，（4）涂覆，（5）硫化。本发明粘胶剂与金属硫化的粘接强度大大提高，粘结强度在10MPa左右，在提高粘接性能的同时，能够达到制备工艺简单易行的效果；本发明对应用环境要求小、使用限制少。

氯丁二烯接枝共聚物胶乳及其制造方法以及粘着剂、粘接剂

本发明提供不含有有机溶剂、并且即使对软质聚氯乙烯也呈现高粘接力的氯丁二烯接枝共聚物胶乳的制造方法。氯丁二烯接枝共聚物胶乳的制造方法具有得到氯丁二烯聚合物胶乳的氯丁二烯聚合工序、和得到氯丁二烯接枝共聚物胶乳的接枝共聚工序。氯丁二烯聚合工序为使氯丁二烯(A‑1)及能够与氯丁二烯(A‑1)共聚的单体(A‑2)中的至少氯丁二烯(A‑1)进行乳液自由基聚合的工序。接枝共聚工序为在氯丁二烯聚合物胶乳中添加(甲基)丙烯酸酯(B)和辛醇‑水分配系数在‑2.0以上且3.0以下的范围内的有机过氧化物(C)，在10℃以上且40℃以下的温度，使(甲基)丙烯酸酯(B)接枝共聚于氯丁二烯聚合物的工序。

Water-based adhesives

An adhesive includes a polymeric latex, a penetrant selected from the group consisting of: terpenes, polylimonene, limonene, carvone, α-pinene, citral, dipentene, 1,8-cineole, eucalyptol, citronellol, geraniol, citronellene, terpinen-4-ol, borneol, camphor, guayule resin, and combinations thereof; and a reinforcing filler. The adhesive has a solids content of 35-65% and a pH of 9 to 12. Articles of manufacture, such as tires and air springs incorporate the adhesive to join rubber interfaces. A method of making the adhesive is also is provided.

快速硬化的聚氯丁二烯接触型粘合剂

本发明涉及包括粘合剂组分和硼酸的储存稳定、快速硬化的水性接触型粘合剂组合物。该组合物还包括一种氨基酸，如甘氨酸。组合物对粘合家具工业的诸如泡沫材料的基材特别有用。

Composition for improving the adhesion of textile materials and related reinforced textile materials

本发明涉及一种用于纺织品材料的粘接性改进的组合物，包括：木质素磺酸盐、其醛类硬化剂和弹性体胶乳。所述木质素磺酸盐可以是木质素磺酸钠、木质素磺酸钾、木质素磺酸镁、木质素磺酸铵或木质素磺酸钙。本发明还涉及这种组合物赋予增强纺织品材料关于下列物质的粘接性能的用途：至少部分涂布和/或浸渍这种组合物的橡胶、增强纺织品，特别是纱线、线绳或纺织品结构，以及由橡胶制成或包括橡胶的部件，其中所述橡胶包括至少一种在该橡胶表面上和/或合并在该橡胶内部的增强纺织品。

Environmental fridendly adhesive composition for rubber reinforcing material and method for manufacturing rubber reinforcing material using the same

본 발명의 일 실시예는, 전체 중량에 대하여, 0.5 내지 4.0 중량%의 에폭시 화합물, 1.0 내지 8.0 중량%의 이소시아네이트 화합물, 1.7 내지 22 중량%의 고무 라텍스, 1.0 내지 8.0 중량%의 수분산 폴리우레탄(PUD), 0.1 내지 2.0 중량%의 아민 화합물 및 69 내지 92 중량%의 용매를 포함하며, 상기 에폭시 화합물과 상기 이소시아네이트 화합물은 1:1 내지 1:10의 중량비를 갖는 접착 조성물을 제공한다. An embodiment of the present invention, based on the total weight, 0.5 to 4.0% by weight of an epoxy compound, 1.0 to 8.0% by weight of an isocyanate compound, 1.7 to 22% by weight of rubber latex, 1.0 to 8.0% by weight of water-dispersed polyurethane (PUD), 0.1 to 2.0% by weight of an amine compound, and 69 to 92% by weight of a solvent, wherein the epoxy compound and the isocyanate compound have a weight ratio of 1:1 to 1:10.

Composite structure

Compositions of matter having among other desirable characteristics strong adhesive properties to various substrates, these compositions comprising blends of a graft copolymer of a high density polyethylene and at least one unsaturated fused ring carboxylic acid anhydride blended with a polyethylene resin of one or more homopolymers of ethylene, copolymers of ethylene and alpha-olefin, ethylene-ester copolymers and one or more elastomers such as homopolymers of isobutylene, copolymers of isobutylene with isoprene, chlorinated copolymers of isobutylene and isoprene, homopolymers of isoprene, copolymers of butadiene and styrene, block copolymers of dienes and styrene where the diene is butadiene or isoprene, homopolymers of butadiene, homopolymers of chloroprene, and copolymers of acrylonitrile and butadiene.

Waterproof agent and construction method using the agent

Provided are a method for constructing a waterproof coating to form a waterproof coating with excellent chemical resistance, ozone resistance and UV resistance and high recovery, and a waterproofing agent used in the method. The method comprises the steps of providing a waterproofing agent which comprises 15-50 wt% of an aqueous chloroprene rubber latex, 45-80 wt% of a nonionic emulsified asphalt or an anionic emulsified asphalt and 1.0-5.0 wt% of an additive and has a pH of 7-12; spraying the waterproofing agent on the surface of a product to be coated; spraying a mixing agent comprising purified water and a curing agent to the surface of a product to be coated simultaneously when the waterproofing agent is sprayed; and forming a waterproof coating on the product by the rapid curing reaction of the waterproofing agent and the mixing agent.

Adhesive composition

FIELD: manufacturing technology. SUBSTANCE: invention relates to chloroprene rubber-based adhesive compositions used in the rubber industry and in the tire industry when gluing vulcanized rubber based on different rubber, when attaching a rubber mixture based on polar rubber to a cord, rubberized with rubber mixture based on general-purpose rubber when making multilayer rubber and rubber-cord articles. Adhesive composition contains chloroprene rubber, zinc oxide, rosin, colloidal silicic acid, a solvent, magnesium oxide, as hardening agent and adhesion modifier N,N'-bis-n-nitrosophenylderivative of alkane-diamine (such as ethane-1,2-diamine, hexane-1,6-diamine). EFFECT: invention increases strength, oil-, benzo- and heat resistance of the adhesive joint. 1 cl, 4 tbl РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2 708 308 C1 (51) МПК C09J 111/00 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (52) СПК C09J 111/00 (2019.08) (21)(22) Заявка: 2018141308, 23.11.2018 (24) Дата начала отсчета срока действия патента: Дата регистрации: 05.12.2019 (45) Опубликовано: 05.12.2019 Бюл. № 34 2 7 0 8 3 0 8 R U (54) Клеевая композиция (57) Реферат: Изобретение относится к клеевым композициям на основе хлоропренового каучука, применяемым в резинотехнической и в шинной промышленности при склеивании вулканизованных резин на основе различных каучуков, при креплении резиновой смеси на основе полярных каучуков к корду, обрезиненному резиновой смесью на основе каучуков общего назначения, при изготовлении многослойных резиновых и резинокордных Стр.: 1 (56) Список документов, цитированных в отчете о поиске: RU 2463327 C1, 10.10.2012. JP 1053911 B2, 16.11.1989. GB 1440837 A, 30.06.1976. UA 27243 C2, 15.08.2000. SU 907031 A1, 23.02.1982. C 1 C 1 Адрес для переписки: 660037, г. Красноярск, пр. им. газеты Красноярский рабочий, 31, а/я 1075, СибГУ им. М.Ф. Решетнева, отдел интеллектуальной собственности (73) Патентообладатель(и): Федеральное ...

Method of obtaining polychloroprene-based polymer dispersion and installation for obtaining polychloroprene-based polymer dispersion

FIELD: chemistry. SUBSTANCE: invention relates to method and installation (10) for obtaining polychloroprene-based polymer dispersion. Method includes stages at which performed are: emulsion polymerisation of chloroprene into polychloroprene with maximal content w solid of dry substances by weight in obtained after polymerisation polychloroprene dispersion w solid ≤50%, and removal of chloroprene from polychloroprene dispersion in multi-stage tray stripping column (36) until content w CR,out of chloroprene by weight in purified polychloroprene dispersion after removal of chloroprene reaches w CR,out ≤50 ppm. Installation contains polymerisation installation (12) for polymerisation of chloroprene into polychloroprene and multi-stage tray stripping column (36), directly or indirectly connected with polymerisation installation (12) and serving for removal of chloroprene from polychloroprene dispersion. EFFECT: installation (10) and method make it possible to reduce relative content of monomer chloroprene in polychloroprene dispersions without necessity of considerable reduction of exploitation time of installation components. 13 cl, 1 dwg РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (51) МПК C08C 2/00 C08L 11/00 C08L 11/02 C08F 36/18 C09J 111/00 (13) 2 529 519 C2 (2006.01) (2006.01) (2006.01) (2006.01) (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ (21)(22) Заявка: ИЗОБРЕТЕНИЯ К ПАТЕНТУ 2011141903/05, 31.03.2010 (24) Дата начала отсчета срока действия патента: 31.03.2010 Приоритет(ы): (30) Конвенционный приоритет: (43) Дата публикации заявки: 27.05.2013 Бюл. № 15 (45) Опубликовано: 27.09.2014 Бюл. № 27 (73) Патентообладатель(и): ЛАНКСЕСС ДОЙЧЛАНД ГМБХ (DE) 0224825 A1, 28.03.2002. SU 649726 A1, 28.02.1979. DE 102006060378 A1, 19.07.2007. US 5407993 A1, 18.04.1995 (85) Дата начала рассмотрения заявки PCT на национальной фазе: 17.11.2011 2 5 2 9 5 1 9 (56) Список документов, цитированных в отчете о поиске: SU 1087532 A1, 23.04.1984. WO R U 17.04.2009 EP ...

Method for producing a polymer dispersion on the basis of polychloroprene and corresponding assembly

The method for the production of a polymer-dispersion based on polychloroprene, comprises carrying out a polymerization of chloroprene to polychloroprene in an emulsion up to a maximum solid material portion of W s o l i d= 30 wt.% in a polychloroprene dispersion existed after the polymerization, and separating chloroprene from polychloroprene dispersion in a multi-stage and/or multi-base stripper-column (36) up to a chloroprene portion of W(CR, out) = 10 ppm in a polychloroprene dispersion existed after the separation of chloroprene. The method for the production of a polymer-dispersion based on polychloroprene, comprises carrying out a polymerization of chloroprene to polychloroprene in an emulsion up to a maximum solid material portion of W s o l i d= 30 wt.% in a polychloroprene dispersion existed after the polymerization, and separating chloroprene from polychloroprene dispersion in a multi-stage and/or multi-base stripper-column (36) up to a chloroprene portion of W(CR, out) = 10 ppm in a polychloroprene dispersion existed after the separation of chloroprene. The polychloroprene dispersion brought to the stripper-column has total aqueous phase of polychloroprene dispersion existing directly after the polymerization. The polychloroprene dispersion is supplied before the supply into the stripper-column to aqueous phase and/or water. The polymerization is carried out predominantly through a batch-reaction in a batch reactor. The polychloroprene dispersion after the polymerization is continuously supplied into a buffer tank before the separation. The polychloroprene dispersion brought to the stripper-column has a chloroprene portion of 5000 ppm = W(CR, in) = 15000 ppm. After the polymerization and before the separation, the degassing of the polychloroprene dispersion is carried out. After the separation of the chloroprene, concentrating of the cleaned polychloroprene dispersion is carried out by a roughing process. In the stripper column, steam is fed with an over ...

Method for producing a polychloroprene-based polymer dispersion and system for producing a polychloroprene-based polymer dispersion

Disclosed are systems and methods for producing a polymer dispersion based on polychloroprene, comprising steps of polymerizing chloroprene to polychloroprene, adding the polycholoprene dispersion to a stripper column, and removing chloroprene from the polychloroprene dispersion.

Method for producing a polychloroprene-based polymer dispersion and system for producing a polychloroprene-based polymer dispersion

The invention relates to a system (10) and a method for producing a polychloroprene-based polymer dispersion, comprising the steps of carrying out a polymerization of chloroprene to polychloroprene in an emulsion up to a maximum solids content w solid in weight proportions of w solid ≤ 50%, particularly w solid ≤ 40%, preferably w solid ≤ 35% and particularly preferably w solid ≤ 30% in a polychloroprene dispersion present after polymerization, and separating chloroprene from the polychloroprene dispersion in a multi-stage and/or multi-tray stripper column (36) to a chloroprene content w CR,out in weight proportions of w CR,out ≤ 50ppm, particularly w CR,out ≤ 30ppm, preferably w CR,out ≤ 15ppm and particularly preferably w CR,out ≤ 10ppm in a purified polychloroprene dispersion present after separating chloroprene. The content of monomer chloroprene in polychloroprene dispersions can be reduced by means of said system (10) and said method without having to accept a significant decrease of the operating times of the system components used.

Adhesive composition

本发明属于改善的粘合剂组合物、所述组合物的用途和包含所述组合物的产品的领域。粘合剂组合物可以是单组分和双组分粘合剂，每种组分通常包含多种成分。本发明的粘合剂是基于水的分散体。

Latex composition

접착 강도 및 내수성이 우수한 수계 접착제 및 수계 프라이머의 베이스가 되는 라텍스 조성물을 제공한다. 폴리클로로프렌 라텍스 100질량부에 대하여 에틸렌의 질량비율이 40% 이상인 EVA 수지 1∼70질량부를 주성분으로 함유하는 라텍스 조성물. Provided is a latex composition that is a base of an aqueous adhesive and an aqueous primer having excellent adhesive strength and water resistance. A latex composition containing, as a main component, 1 to 70 parts by mass of EVA resin having a mass ratio of ethylene of 40% or more to 100 parts by mass of polychloroprene latex.

PREPARATIVE FORMS BASED ON ANION-STABILIZED AQUEOUS POLYMER DISPERSIONS

1. Препаративная форма на основе водной полимерной дисперсии, содержащая >20 мас.% анионно-стабилизированной полихлоропреновой дисперсии, в которой общую концентрацию твердого вещества устанавливают равной 100 мас.%, отличающаяся тем, что при значении рН от 6 до 10 доля растворенной угольной кислоты при равновесной диссоциации составляет от 0,0001 до 2 мас.% из расчета на дисперсию. ! 2. Препаративная форма по п.1, отличающаяся тем, что при значении рН от 6,5 до 9,5 доля растворенной угольной кислоты составляет от 0,001 до 1 мас.%. ! 3. Препаративная форма по п.1, отличающаяся тем, что концентрация щелочных ионов (Na++К+) составляет от 500 до 10000 ч./млн. ! 4. Препаративная форма по п.1, отличающаяся тем, что данные гидрофилированные полиизоцианаты предпочтительно содержат в основе алифатические изоцианаты. ! 5. Препаративная форма по п.1, отличающаяся тем, что препаративные формы данного типа содержат нанодисперсные суспензии кремниевой кислоты в воде. ! 6. Препаративная форма по п.1, отличающаяся тем, что препаративные формы данного типа обнаруживают стабильность значения рН в соответствии с DIN 53381, метод В, в течение >1 ч. ! 7. Способ получения препаративной формы по п.1, отличающийся тем, что к водной полимерной дисперсии, содержащей анионно-стабилизированную полихлоропреновую дисперсию, добавляют диоксид углерода при температуре от 1 до 100°С и давлении от 0,8 до 10 бар в количестве от 0,1 до 20 литров на литр препаративной формы. ! 8. Способ по п.7, отличающийся тем, что добавление объема диоксида углерода осуществляют посредством наложения дисперсии внутри эластичной емкости, и затем емкость встряхивают или перемешивают, или выдерживают до достижен� РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) 2011 112 648 (13) A (51) МПК C09J 111/02 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ЗАЯВКА НА ИЗОБРЕТЕНИЕ (71) Заявитель(и): БАЙЕР МАТИРИАЛЬСАЙЕНС АГ (DE) (21)(22) Заявка: 2011112648/05, 26.08.2009 Приоритет(ы): (30) Конвенционный приоритет: 05. ...

Water-based adhesive

本发明提供了一种粘合剂，其包含聚合物胶乳、渗透剂和增强填料，所述渗透剂选自萜烯、聚柠檬烯、柠檬烯、香芹酮、α‑蒎烯、柠檬醛、二戊烯、1,8‑桉树脑、桉叶油素、香茅醇、香叶醇、香茅烯、松油‑4‑醇、冰片、樟脑、银胶菊树脂，以及它们的组合。所述粘合剂具有35‑65％的固体含量和9至12的pH。本发明提供了引入所述粘合剂以结合橡胶界面的制造制品，如轮胎和空气弹簧。本发明也提供了一种制备所述粘合剂的方法。

PROCESS FOR MANUFACTURING A FREEZE-THAW-STABLE POLYCHLOROPRENE LATEX

Adhesive composition and method for its manufacture

FIELD: chemistry. SUBSTANCE: adhesive composition includes chloroprene rubber, zinc oxide, colloidal silicic acid, rosin, nefras and ethyl acetate, isocyanate, comprises a molecular complex ε-caprolactam with trimethylolpropane (TMPC) in the amount of 8.0-16.0 wt parts per 100.0 wt parts of adhesive rubber, prepared by reacting the complex components at a temperature of 80-100°C for 20-40 minutes at the following ratio, wt parts: 1.0 of ε-caprolactam, 2.0 of trimethylolpropane (TMP). EFFECT: increased adhesion and fixing strength of the rubber composition in multilayer products based on general-purpose rubbers, operated in corrosive environments. 2 cl, 2 tbl РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2 620 053 C2 (51) МПК C09J 4/06 (2006.01) C09J 111/00 (2006.01) C09J 119/00 (2006.01) B29D 30/00 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ФОРМУЛА (21)(22) Заявка: ИЗОБРЕТЕНИЯ К ПАТЕНТУ РОССИЙСКОЙ ФЕДЕРАЦИИ 2015147572, 05.11.2015 (24) Дата начала отсчета срока действия патента: 05.11.2015 Дата регистрации: Приоритет(ы): (22) Дата подачи заявки: 05.11.2015 (43) Дата публикации заявки: 10.05.2017 Бюл. № 13 Адрес для переписки: 644018, г. Омск, ул. 5-я Кордная, 4, ФГУП "НПП "Прогресс", А.В. Зубарев, генеральный директор предприятия, действующий на основании Устава (56) Список документов, цитированных в отчете о поиске: RU 2455330 C1, 10.07.2012. RU 2469060 C1, 10.12.2012. RU 2304603 C1, 20.08.2007. US 2014020809 A1, 23.01.2014. EP 2813376 A1, 17.12.2014. 2 6 2 0 0 5 3 (45) Опубликовано: 22.05.2017 Бюл. № 15 (73) Патентообладатель(и): Федеральное государственное унитарное предприятие "Федеральный научно-производственный центр "Прогресс" (ФГУП "ФНПЦ "Прогресс") (RU) R U 22.05.2017 (72) Автор(ы): Третьякова Наталья Александровна (RU), Абольская Инга Игоревна (RU), Ходакова Светлана Яковлевна (RU), Бобров Сергей Петрович (RU) ε-капролактам 1,0 триметилолпропан (ТМП) 2,0 2. Способ изготовления клеевой композиции по п. 1, заключающийся в последовательном ...

dispersions

Die Erfindung betrifft wässrige Polymerdispersionen auf Basis von Polychloropren, ein Verfahren zu deren Herstellung und Verwendung.

GLUE COMPOSITION AND METHOD FOR ITS MANUFACTURE

РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2015 147 572 A (51) МПК C09J 4/06 (2006.01) C09J 111/00 (2006.01) C09J 119/00 (2006.01) B29D 30/00 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ЗАЯВКА НА ИЗОБРЕТЕНИЕ (21)(22) Заявка: 2015147572, 05.11.2015 Адрес для переписки: 644018, г. Омск, ул. 5-я Кордная, 4, ФГУП "НПП "Прогресс", А.В. Зубарев, генеральный директор предприятия, действующий на основании Устава (72) Автор(ы): Третьякова Наталья Александровна (RU), Абольская Инга Игоревна (RU), Ходакова Светлана Яковлевна (RU), Бобров Сергей Петрович (RU) Приоритет(ы): (22) Дата подачи заявки: 05.11.2015 ε-капролактам 1,0 триметилолпропан (ТМП) 2,0 A R U 2. Способ изготовления клеевой композиции по п. 1, заключающийся в последовательном введении компонентов, отличающийся тем, что молекулярный комплекс ε-капролактама и триметилолпропана получают взаимодействием компонентов комплекса при температуре 80-100°С в течение 20-40 мин. Стр.: 1 A 2 0 1 5 1 4 7 5 7 2 (57) Формула изобретения 1. Клеевая композиция, включающая хлоропреновый каучук 100,0 мас. ч., окись цинка 4,0-6,0 мас. ч., коллоидную кремнекислоту 60,0-80,0 мас. ч., канифоль 40,0-60,0 мас. ч., нефрас и этилацетат 345-365 мас. ч., изоцианат 1,0-5,0 мас. ч., отличающаяся тем, что содержит молекулярный комплекс ε-капролактама с триметилолпропаном (ТМПК) в количестве 8,0-16,0 мас. ч. на 100,0 мас. ч. каучука клея, полученный взаимодействием компонентов комплекса при температуре 80-100°С в течение 20-40 мин. при следующем соотношении, мас. ч.: 2 0 1 5 1 4 7 5 7 2 (54) КЛЕЕВАЯ КОМПОЗИЦИЯ И СПОСОБ ЕЕ ИЗГОТОВЛЕНИЯ R U (43) Дата публикации заявки: 10.05.2017 Бюл. № 13 (71) Заявитель(и): Федеральное государственное унитарное предприятие "Научно-производственное предприятие "Прогресс" (ФГУП "НПП "Прогресс") (RU)

Building composite film

本发明公开了一种建筑复合膜，包括依次层叠的：ASA层、特种胶粘剂层和隔离膜层。本发明将ASA树脂以及ASA层的其他组分通过挤出机生产后可以作为一种耐候膜使用，兼具保色性佳、抗静电功能、自清洁功能，能够很好的应用在屋面维修领域或屋面装饰材料。本发明重点依靠特殊胶粘剂，使用耐候膜作为基材，重点解决材料粘结力不足、耐候性不佳、无阻燃和保色性问题。

Two-component type water-soluble adhesive composition for korean under-floor heating floor

본 발명은 온돌마루용 2액형 수성접착제 조성물에 관한 것으로, 특히 고무라텍스 또는 에멀젼 수지, 내열성 증강제, OH기 함유 고분자 수용액 또는 에멀젼, 무기충진제, 칙소제, 및 물을 함유하는 주제와 이소시아네이트 화합물을 함유하는 경화제를 포함하는 온돌마루용 2액형 수성접착제 조성물에 관한 것이다. 본 발명의 온돌마루용 2액형 수성접착제 조성물은 독성 방출, 오존 고갈, 가연성, 함불소 화합물 발생 등으로 환경파괴를 야기하던 포름알데히드 및 유기용제를 사용하지 않아 환경친화적이고 인체친화적일 뿐만 아니라, 온돌마루판 제조 및 온돌마루 시공시 상온 또는 가온시에도 내열성, 내수성, 및 내열수성의 물성이 우수하며, 접착성 및 작업성이 우수한 효과가 있다. 수성접착제, 온돌마루, 환경친화적, 인체친화적

A kind of aramid fiber fire retarding conveying band adhesive glue and preparation method thereof

一种芳纶阻燃输送带粘合胶及其制备方法，其粘合胶按重量比的组份为：氯丁橡胶40～80份，丁苯二烯10～20份，炭黑N220：15～40份，促进剂2～5份，软化剂2～15份，硫化剂2.5～4份，活性剂4～10份，白炭黑10～20份，粘合剂AS‑88 3～8份，防老剂1‑3份，阻燃剂20‑40份；制备方法：将氯丁橡胶、丁苯二烯、防老剂、活性剂、防老剂、白炭黑及促进剂加到密炼机中，密炼1～3分钟；再加入炭黑、软化剂和阻燃剂密炼3～4分钟；最后加入硫化剂密炼1～2分钟；排胶温度控制在120～130℃，排出的胶经过开炼机挤出6～8mm胶片。

METHOD FOR PRODUCING SOLID POLYMERIC MATERIALS

1. Способ получения твердых полимерных материалов, не содержащих вспомогательных эмульгаторов, из полимерных латексов (дисперсий), отличающийся тем, что исходный рН дисперсии полимеров, превышающий 9, путем добавления газообразного диоксида углерода доводят до значения рН 6-9, и дисперсию полимеров коагулируют сдвигом и/или вымораживанием.2. Способ по п.1, отличающийся тем, что задаваемое значение рН находится между 7 и 8.3. Способ по п.2, отличающийся тем, что дисперсия полимеров - это анионно-стабилизированная дисперсия полихлоропренов, в которой доля полимеризованного хлоропрена в твердом веществе всей дисперсии >50%.4. Способ по п.2 или 3, отличающийся тем, что полимерную дисперсию получают путем непрерывной полимеризации хлоропрена без добавления вспомогательных эмульгаторов.5. Способ по п.4, отличающийся тем, что введение подходящих количеств диоксида углерода в поток латекса осуществляют непрерывным способом.6. Способ по п.5, отличающийся тем, что ввод диоксида углерода в дисперсию полимеров регулируют так, чтобы выход диоксида углерода на реакцию нейтрализации был >20%, предпочтительно >40%, особо предпочтительно >50%.7. Способ по п.6, отличающийся тем, что ввод осуществляют при локальном давлении в месте ввода <80 бар, предпочтительно <60 бар, особо предпочтительно <20 бар.8. Не содержащие вспомогательных эмульгаторов твердые полимерные материалы, получаемые по одному из вышеуказанных пунктов.9. Не содержащие вспомогательных эмульгаторов твердые полимерные материалы по п.8, отличающиеся тем, что они содержат остаточные карбонаты натрия и калия в количествах <5 г, предпочтительно <2 г, особо предпочтительно <1 г на кг твердог� РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (51) МПК C08K 3/00 (13) 2011 141 702 A (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ЗАЯВКА НА ИЗОБРЕТЕНИЕ (21)(22) Заявка: 2011141702/05, 17.03.2010 (71) Заявитель(и): ЛЕНКСЕСС ДОЙЧЛАНД ГМБХ (DE) Приоритет(ы): (30) Конвенционный приоритет: 17.03.2009 ...

Adhesive composition for polyolefine thermoplastic elastomer

본 발명은 에폭시 수지, 염화폴리올레핀 수지, 클로로프렌 고무 및 열가소성 폴리우레탄 수지의 고분자 혼합물을 사용한 폴리올레핀계 열가소성 탄성체용 접착제 조성물에 관한 것으로, 비극성 및 난접착 특성을 갖는 소재인 폴리올레핀계 열가소성 탄성체의 접착시 버핑처리, 세척제, 프라이머 및 플라즈마처리와 같은 복잡한 전처리 공정이 생략되어 작업 공정이 간소화되어 생산성이 향상되고, 우수한 접착특성을 유지하고, 또한 톨루엔이나 자일렌 등과 같은 독성 유기용제를 전혀 사용하지 않지 않아 유독성 가스가 발생하지 않아 쾌적한 작업환경에 의해 작업자의 신체에 위해성이 없는 친환경적인 것이 장점이다. The present invention uses a polymer mixture of an epoxy resin, a chlorinated polyolefin resin, a chloroprene rubber and a thermoplastic polyurethane resin. The present invention relates to an adhesive composition for a polyolefin-based thermoplastic elastomer, wherein a complicated pretreatment process such as buffing, cleaning agent, primer, and plasma treatment is omitted during adhesion of a polyolefin-based thermoplastic elastomer having a non-polar and hard-adhesive property, thereby simplifying the work process. It is improved, maintains excellent adhesive properties, and does not use any toxic organic solvents such as toluene or xylene, so no toxic gas is generated, so it is an eco-friendly environment with no harm to the worker's body by a comfortable working environment. . 폴리올레핀계, 열가소성 탄성체, 접착제, 에폭시 수지, 염화폴리올레핀 수지, 클로로프렌 고무 및 열가소성 폴리우레탄 수지 Polyolefins, thermoplastic elastomers, adhesives, epoxy resins, chlorinated polyolefin resins, chloroprene rubbers and thermoplastic polyurethane resins

Adhesive with buffer system

An adhesive based on a polychloroprene dispersion is characterized in that a buffer system comprising at least one acid compound and glycerin is included in order to activate and stabilize the adhesive. A freeze-thaw stability of the adhesive is achieved by surprisingly high proportions of glycerin; however, a good initial adhesion is simultaneously ensured. The glycerin proportions range from 8-50 wt. %, preferably 14-40 wt. %, particularly preferably 22-30 wt. %. An organic acid is preferably used as the acid compound.

Seam glue for diving suit and manufacturing method thereof

本发明涉及一种潜水服用线缝涂胶及其制造方法，原料重量比如下，氯丁橡胶100份、着色剂2~5份、增粘剂10~20份、油膏8~16份、凡士林2~4份、分散剂2~3份、防老剂1~2份、硫化剂10~11份、甲苯100~150份、甲基环乙烷50~75份、乙酸乙酯50~75份、消泡剂3~5份、消光剂5~10份；将氯丁橡胶、着色剂、增粘剂、油膏、凡士林、分散剂、防老剂和硫化剂投入密炼机内分四次加压打料，升温到75℃下料；然后在开炼机中混炼至分散均匀，将辊距调至1毫米薄通六次，辊距调至3毫米出片并冷却2~3小时；将胶片分切成小胶块，投入溶剂中密封浸泡，低速搅拌高速分散，加入消泡剂搅匀后，加入消光剂搅匀，然后抽真空破壁物理消泡得到潜水服用线缝涂胶。该涂胶可以大幅度提高潜水服的各种性能指标。

Chloroprene graft copolymer latex, process for producing the same, adhesive, and adhesive

本发明提供不含有有机溶剂、并且即使对软质聚氯乙烯也呈现高粘接力的氯丁二烯接枝共聚物胶乳的制造方法。氯丁二烯接枝共聚物胶乳的制造方法具有得到氯丁二烯聚合物胶乳的氯丁二烯聚合工序、和得到氯丁二烯接枝共聚物胶乳的接枝共聚工序。氯丁二烯聚合工序为使氯丁二烯(A‑1)及能够与氯丁二烯(A‑1)共聚的单体(A‑2)中的至少氯丁二烯(A‑1)进行乳液自由基聚合的工序。接枝共聚工序为在氯丁二烯聚合物胶乳中添加(甲基)丙烯酸酯(B)和辛醇‑水分配系数在‑2.0以上且3.0以下的范围内的有机过氧化物(C)，在10℃以上且40℃以下的温度，使(甲基)丙烯酸酯(B)接枝共聚于氯丁二烯聚合物的工序。

Aqueous adhesive dispersions

本发明涉及基于聚氨酯的水性聚合物分散体，及其制备方法和用途。

Conventional adhesive waterproof glue and preparation method thereof

一种常规粘接性能防水胶，其制备原料包括橡胶、填料、凡士林、烷基羧酸、叔丁酚甲醛树脂、抗氧剂、锌白、促进剂、二乙基氨荒酸碲、三甲氧基(4‑乙烯基苯基)硅烷改性EPDM。

METHOD FOR PRODUCING POLYMERIC DISPERSION BASED ON POLYCHLOROPRENE AND A PLANT FOR PRODUCING POLYMERIC DISPERSION BASED ON POLYCHLOROPRENE

1. Способ получения полимерной дисперсии на основе полихлоропрена, включающий стадии на которых:осуществляют эмульсионную полимеризацию хлоропрена в полихлоропрен с максимальным содержанием wсухих веществ по весу в полученной после полимеризации дисперсии полихлоропрена w≤50%, в частности w≤40%, предпочтительно w≤35%, особо предпочтительно w≤30%, иудаляют хлоропрен из дисперсии полихлоропрена в многоступенчатой и(или) многоходовой тарельчатой выпарной колонне (36) до достижения содержания wхлоропрена по весу в очищенной дисперсии полихлоропрена после удаления хлоропрена w≤50 част/млн, в частности w≤30 част/млн, предпочтительно w≤15 част/млн, особо предпочтительно w≤10 част/млн.2. Способ по п.1, отличающийся тем, что подаваемая в выпарную колонну (36) дисперсия полихлоропрена содержит преимущественно всю водную фазу дисперсии полихлоропрена, образующейся сразу после полимеризации, при этом до подачи в выпарную колонну в дисперсию полихлоропрена, в частности, вводят дополнительную водную фазу и(или) воду.3. Способ по п.1, отличающийся тем, что полимеризацию осуществляют преимущественно посредством периодической реакции, по меньшей мере, в одном реакторе периодического действия, при этом дисперсию полихлоропрена, образующуюся после полимеризации, подают в буферную емкость до отделения в выпарной колонне (36) и преимущественно непрерывно подают дисперсию полихлоропрена из буферной емкости в выпарную колонну (36).4. Способ по п.1, отличающийся тем, что содержание Wхлоропрена по весу в подаваемой в выпарную колонну (36) дисперсии полихлоропрена составляет 200 част/млн≤w≤30000 част/млн, в частности 2000 част/млн≤w≤20000 част/млн, особ РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (51) МПК C08C 2/00 (13) 2011 141 903 A (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ЗАЯВКА НА ИЗОБРЕТЕНИЕ (21)(22) Заявка: 2011141903/05, 31.03.2010 (71) Заявитель(и): ЛАНКСЕСС ДОЙЧЛАНД ГМБХ (DE) Приоритет(ы): (30) Конвенционный приоритет: 17.04.2009 EP 09158147.0 (85) Дата начала ...

Fast-setting polychloroprene contact adhesives

The invention relates to a storage stable, fast-setting, aqueous contact adhesive composition comprising an adhesive component and boric acid. The composition can further include an amino acid, such as glycine. The composition finds particularly preferred use for bonding substrates, such as foam, in the furniture industry.

Nanomodified cold-curing electroconductive adhesive composition

FIELD: electricity.SUBSTANCE: invention relates to current-conducting elastic adhesive compositions which can be used as a sensor which transmits an electrical signal from one glued material to another, used in aviation and special-purpose vehicles of defense, local heater, composite intended for repair of car rear window heating threads, etc. Composition includes polychloroprene rubber nairit NT, butylphenol formaldehyde resin 101 K, zinc oxide, magnesium oxide, and electroconductive additive dispersed in a solvent, as an electroconductive additive contains carbon nanotubes "Taunit-M", previously modified by application on surface of hydroxyl and/or carboxyl groups, and the solvent used is a mixture of acetone and ethyl acetate in ratio ½ with following ratio of components, pts. wt.: polychloroprene rubber nairit NT 100, butylphenol formaldehyde resin 101 K 13, zinc oxide 5, magnesium oxide 8, acetone 24, ethyl acetate 46, carbon nanotubes "Taunit-M" modified 2–18.EFFECT: considerably improving quality of products connection due to increased electrical conductivity.3 cl, 4 tbl РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2 688 573 C1 (51) МПК C09J 111/00 (2006.01) B82B 3/00 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (52) СПК C09J 111/00 (2019.02); B82B 3/00 (2019.02) (21)(22) Заявка: 2018134008, 26.09.2018 (24) Дата начала отсчета срока действия патента: Дата регистрации: 21.05.2019 (73) Патентообладатель(и): ООО "НаноТехЦентр" (RU) (45) Опубликовано: 21.05.2019 Бюл. № 15 (56) Список документов, цитированных в отчете о поиске: RU 2479611 C1, 20.04.2013. RU 2 6 8 8 5 7 3 R U 2435817 C1, 10.12.2011. US 3399181 A, 24.10.1965. EP 1344857 A1, 17.09.2003. RU 2479612 C1, 20.04.2013. (54) НАНОМОДИФИЦИРОВАННАЯ ЭЛЕКТРОПРОВОДЯЩАЯ КЛЕЕВАЯ КОМПОЗИЦИЯ ХОЛОДНОГО ОТВЕРЖДЕНИЯ (57) Реферат: Изобретение относится к токопроводящим на поверхность гидроксильных и/или эластичным клеевым композициям, которые карбоксильных ...

Water-based single coat adhesive composition

披露了一种水性粘合剂组合物，所述水性粘合剂组合物包含以下各项的混合物：(a)第一水性组合物，所述第一水性组合物包含，(i)一种或多种成膜聚合物，(ii)一种或多种较低结晶度的聚亚硝基化合物，(iii)一种或多种较高结晶度的聚亚硝基化合物，以及(iv)一种或多种含有双马来酰亚胺的单体；和(b)第二水性组合物，所述第二水性组合物包含(i)至少一种酚醛树脂的水性分散体，所述酚醛树脂是苯酚和甲醛的缩合产物，其中所述水性分散体通过至少一种聚丙烯酸盐稳定；(b)由一种或多种卤代聚烯烃形成的一种或多种胶乳；以及(c)一种或多种金属氧化物。

Bonding means on wet substrates

(57)【要約】 本発明は、一種又は多種のポリアクリレートで安定化された水性分散系と、一種又は多種のフェノール樹脂、一種又は多種のハロゲン化ポリオレフィンを有する一種又は多種のラテックス及び一種又は多種の架橋剤を含む湿潤基体上の接着手段を記載する。本発明は、更に基板がプリマとしての接着手段でその後公知のカバー接合剤で被覆され、その後加硫状態下でゴムに接合される湿潤基体上の接着手段の使用を記載する。

Sprayable dispersion and method for elastic adhesion of two substrate surfaces.

Latex composition

우수한 내광 변색성을 갖는 폴리클로로프렌계 라텍스 조성물의 배합처방을 제공한다. 폴리클로로프렌계 라텍스에 특정 구조를 갖는 포름아미딘 화합물, 힌더드아민계 화합물, 페놀 화합물, 벤조트리아졸 화합물, 벤조페논 화합물에서 선택된 1 종 또는 이들을 조합한 것을 배합함으로써 우수한 내광 변색성을 갖는 폴리클로로프렌계 라텍스 조성물이 얻어진다. 이 조성물을 사용한 접착제는 접착물성을 손상시키지 않고 우수한 내광 변색성을 나타낸다. Provided is a formulation of a polychloroprene-based latex composition having excellent light discoloration resistance. Polychloroprene having excellent light discoloration resistance by blending polychloroprene-based latex with one or a combination of formamidine compounds, hindered amine compounds, phenol compounds, benzotriazole compounds, and benzophenone compounds having a specific structure A system latex composition is obtained. Adhesives using this composition exhibit excellent light discoloration resistance without compromising adhesive properties.

Nail-free glue and preparation method thereof

本发明公开了一种免钉胶及制备方法，主要成分为氯丁橡胶、氯磺化聚丙烯橡胶、乙丙橡胶、混合溶剂、300‑2500目云母粉、月桂酸、补强填料、补强纤维、活性氧化镁、增粘树脂、偶联剂、抗氧剂、防火剂。本发明的优点是：1.粘接强度高，固化快；2.混合溶剂体系采用的都是相对环保的溶剂，固含量高，VOC含量低，对生态环境和人体健康无害，符合环保要求；3.采用氯丁橡胶和氯磺化聚乙烯橡胶作为主体，耐老化性能优异，可满足户外使用的需求。

Chloroprene polymer composition

Adhesive composition

The present invention is in the field of an improved adhesive composition, use of said composition and products comprising said composition. The adhesive composition may be a one component and a two component adhesive, each component typically comprising various ingredients. The present adhesives are water-based dispersions.

Improved adhesive composition.

The present invention is in the field of an improved adhesive composition, use of said composition and products comprising said composition. The adhesive composition may be a one component and a two component adhesive, each component typically comprising various ingredients. The present adhesives are water-based dispersions.

Adhesive composition

本发明属于改善的粘合剂组合物、所述组合物的用途和包含所述组合物的产品的领域。粘合剂组合物可以是单组分和双组分粘合剂，每种组分通常包含多种成分。本发明的粘合剂是基于水的分散体。

Adhesive composition

The present invention is in the field of an improved adhesive composition, use of said composition and products comprising said composition. The adhesive composition may be a one component and a two component adhesive, each component typically comprising various ingredients. The present adhesives are water-based dispersions.

Adhesive composition

The present invention is in the field of an improved adhesive composition, use of said composition and products comprising said composition. The adhesive composition may be a one component and a two component adhesive, each component typically comprising various ingredients. The present adhesives are water-based dispersions.

Use of a one-component adhesive for cold adhesion of the components of a conveyor system

Use of a one-component adhesive for cold adhesion of the components of a conveyor system, is claimed.

Method for Producing Chloroprene Graft Copolymer Latex

Process for stabilizing chloroprene copolymer latex

AQUEOUS POLYCHLOROPRENE CONTACT GLUE

1) Composition adhésive à base aqueuse comprenant un mélange de polychloroprènes, au moins un agent autoréticulable de type alkyde et au moins une charge, 2) Utilisation d'une telle composition comme colle contact, 3) Structure multicouches assemblée à l'aide de la composition adhésive 1). 1) An aqueous-based adhesive composition comprising a mixture of polychloroprenes, at least one self-crosslinking agent of the alkyd type and at least one filler, 2) Use of such a composition as a contact adhesive, 3) Multilayer structure assembled using the adhesive composition 1).

Polychloroprene blend composition

氯丁二烯均聚物或共聚物与氯丁二烯/丙烯酸酯或氯丁二烯/甲基丙烯酸酯接枝共聚物的掺混物提供了一种特别适用于作乳液胶粘剂配方成分的组合物。

COAGULATION AGENT AND SOLUTION FOR THE MANUFACTURE OF BI OR MULTI-COMPONENT ADHESIVES, GLUING METHOD AND CORRESPONDING DEVICE

PROCESS FOR PREPARING A STABLE ADHESIVE SEALANT BASED ON NEOPRENE LATEX

Aqueous adhesive dispersions

The invention relates to polyurethane-based aqueous polymer dispersions, to a method for producing the same and to the use thereof.

ADHESIVE COMPOSITION FOR TEXTILE AND REINFORCING TEXTILE

L'invention concerne une composition d'adhérisation pour textile, comprenant un sel de lignosulfonate, un durcisseur aldéhyde de ce sel, et un latex d'élastomère. Le sel de lignosulfonate peut être un lignosulfonate de sodium, de potassium, de magnésium, d'ammonium ou de calcium. L'invention concerne aussi l'utilisation d'une telle composition pour conférer des propriétés d'adhésion à un textile de renfort, vis-à-vis d'un caoutchouc, un textile de renfort, notamment fil, câblé ou structure textile, au moins partiellement revêtu et/ou imprégné de cette composition, et une pièce en caoutchouc ou comportant un caoutchouc, dans laquelle le caoutchouc comprend au moins un textile de renfort, en surface et/ou intégré à l'intérieur du caoutchouc. The invention relates to a textile adhesion composition comprising a lignosulfonate salt, an aldehyde hardener of this salt, and an elastomer latex. The lignosulfonate salt may be a lignosulfonate of sodium, potassium, magnesium, ammonium or calcium. The invention also relates to the use of such a composition for imparting adhesion properties to a reinforcing textile, with respect to a rubber, a reinforcing textile, especially a yarn, a cord or a textile structure, at less partially coated and / or impregnated with this composition, and a rubber or rubber part, wherein the rubber comprises at least one reinforcing textile, surface and / or integrated inside the rubber.

AQUEOUS POLYCHLOROPRENE CONTACT GLUE

1) Composition adhésive à base aqueuse comprenant un mélange de polychloroprènes, au moins un agent autoréticulable de type alkyde et au moins une charge, 2) Utilisation d'une telle composition comme colle contact, 3) Structure multicouches assemblée à l'aide de la composition adhésive 1). 1) Water-based adhesive composition comprising a mixture of polychloroprenes, at least one self-crosslinkable agent of alkyd type and at least one filler, 2) Use of such a composition as contact adhesive, 3) Multilayer structure assembled using the adhesive composition 1).

Aqueous compositions based on polychloroprene

The present invention relates to water-containing compositions based on polychoroprene and zinc oxide, to processes for their production and to their use as adhesives.

Adhesive for polystyrene foam - contg polychloroprene a phenoplast and a metal oxide

Adhesive for polystyrene foam, contg, a solvent, a polychloroprene having a Mooney viscosity is not >50 after heating, an oil-soluble thermosetting phenol-aldehyde resin, and an alkaline earth metal oxide; the compsn. having is not >15% dry contents and a viscosity at 20 degrees C of is not 90 s with a Ford No:4 head, and the solvent having an evapn. rate of 0.8-1mm. The adhesive forms an even layer on the foam, and does not attack it.

Composition for adhesively bonding a textile coating onto plastic articles

Composition for adhesively bonding a textile coating onto polyolefin articles, made up of two parts intended to be mixed when used, characterised: -in that the first part, containing the active substances, consists of a first solvent system containing, in per cent by weight: from 3 to 10 % of polychloroprene rubber, from 3 to 10 % of terpenephenolic resin, from 5 to 15 % of a polyurethane plastomer, from 0.1 to 10 % of a chlorinated polyolefin containing from 20 to 35 % by weight of chlorine; - and in that the second past, containing the polymerising agent, consists of a second solvent system, miscible with the first solvent system, containing the agent for polymerising the polyurethane plastomer. Application: adhesive bonding of textile moquettes onto polypropylene moulded components for the motor vehicle industry.

Patent FR2164095A5

Injecting sealing mastic into joint using plunger - which moves in a cylinder and is driven by a double acting ram

A sealing mastic is injected into a broken joint through pref. a nozzle of a cylinder into which a charge of mastic is inserted, the mastic being forced through the nozzle by plunger moving in the cylinder and driven by a double acting ram. Once the first charge of mastic has been injected the ram acts to return the plunger allowing the cylinder to be refilled with mastic for a second injection operation. The assembly doesn't have to be demounted from the joint for re-filling.