27-03-2014 дата публикации
Номер: US20140088319A1
The present invention discloses a catalytic system for preparing highly branched alkane from olefin, which contains novel nickel or palladium complexes. In the presence of the catalytic system, highly branched oily alkane mixture can be efficiently obtained from olefins (such as ethylene) under mild conditions. The alkane mixture has a low bromine number, and can be used as a processing aid(s) and lubricant base oil with high-performance. Provides also was a method for preparing the catalyst and a method for preparing an oily olefin polymer. 2. The compound of claim 1 , wherein claim 1 , 1-3 substituent(s) of R claim 1 , R claim 1 , Rand Ris C-Calkyl claim 1 , C-Chaloalkyl or unsubstituted or substituted phenyl claim 1 , and 1-3 of substituent(s) is hydrogen or halogen.3. The compound of claim 1 , wherein claim 1 , Z and Y together with the adjacent carbon atom form unsubstituted or substituted acenaphthylene group.4. A complex claim 1 , wherein claim 1 , that is formed by the compound of and a salt(s) of divalent metal selected from the following group: nickel claim 1 , palladium or the combination thereof.6. A method for preparing the complex of claim 1 , wherein claim 1 , comprising a step of: in inert solvent claim 1 , reacting the compound of with a salt(s) of divalent metal as a metal precursor claim 1 , thereby forming the complex of claim 1 , wherein the metal precursor is divalent nickel compound or divalent palladium compound.7. The method of claim 6 , wherein claim 6 , the metal precursor contains NiCl claim 6 , NiBr claim 6 , NiI claim 6 , (DME)NiBr claim 6 , PdCl claim 6 , PdBr claim 6 , Pd(OTf) claim 6 , Pd(OAc)or the combination thereof.9. A method for preparing oily polyolefin claim 6 , wherein claim 6 , comprising a step of:{'claim-ref': {'@idref': 'CLM-00004', 'claim 4'}, '(a) in the presence of the complex(es) of as a catalyst for olefin polymerization, catalyzing olefin polymerization, thereby forming an oily polyolefin.'}10. The method of claim ...
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