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Небесная энциклопедия

Космические корабли и станции, автоматические КА и методы их проектирования, бортовые комплексы управления, системы и средства жизнеобеспечения, особенности технологии производства ракетно-космических систем

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Мониторинг СМИ

Мониторинг СМИ и социальных сетей. Сканирование интернета, новостных сайтов, специализированных контентных площадок на базе мессенджеров. Гибкие настройки фильтров и первоначальных источников.

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Поддерживает ввод нескольких поисковых фраз (по одной на строку). При поиске обеспечивает поддержку морфологии русского и английского языка
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Применить Всего найдено 3292. Отображено 100.
16-02-2012 дата публикации

Food preparations for cooking in micro-wave ovens, with solidified vegetable oil, and procedure for their elaboration

Номер: US20120040081A1
Автор: Juan Ramón DURAN VILA
Принадлежит: Borges Sau

Food preparations for cooking in micro-wave ovens, with solidified vegetable oil, and procedure for their elaboration. Food preparations are described containing vegetable oil solidified at room temperature, packed specially for cooking in micro-wave ovens, and a procedure for their elaboration. The composition of the food preparations comprises mainly popcorn, vegetable oil, oil solidifying agent and possibly other optional ingredients, such as sugar, salt, aromatics, flavourings, colours and preserving agents. The elaboration procedure is based on the batching of corn in a special wrapper for microwave cooking, and then the batching of the other ingredients, previously mixed consistently and according to the individual formulations of each food preparation, under thermal control at a temperature of 50-70° C.

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Номер записи: 1
15-03-2012 дата публикации

Methods for Production of Biodiesel

Номер: US20120065416A1
Автор: Alexander McCurdy, Bradley Wahlen, Lance Seefeldt, Robert Willis
Принадлежит: Utah State University USU

The present invention relates to methods useful for converting microbial lipids from an oleaginous microbial biomass into fatty acid alcohol esters, without prior extraction of the lipids from the biomass. The present invention also relates to fatty acid alcohol esters produced by the methods described herein. The fatty acid alcohol esters produced by the methods described herein may be useful as biodiesel, or a component thereof. In embodiments, the converting of microbial lipids to fatty acid alcohol esters may be accomplished by contacting an acid catalyst, an alcohol and an oleaginous microbial biomass containing microbial lipids under sufficient conditions and for a sufficient period of time for in situ transesterification reaction of at least some microbial lipids to their corresponding fatty acid alcohol ester.

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Номер записи: 2
10-05-2012 дата публикации

Process for Making Basestocks from Renewable Feedstocks

Номер: US20120115762A1
Автор: Alan Anthony Galuska, David Lawrence Stern, Kun Wang, Margaret May-Som Wu
Принадлежит: ExxonMobil Research and Engineering Co

A process for converting feedstock triglycerides to lube basestocks. The process has the steps of (a) metathesizing the feedstock triglycerides with ethylene in the presence of a metathesis catalyst to form alpha olefins and medium-chain triglycerides and (b) hydroisomerizing the medium-chain triglycerides in the presence of a hydroisomerization catalyst and hydrogen to form methyl-branched triglycerides. The alpha olefins may be oligomerized in the presence of an oligomerization catalyst to form poly(alpha olefins).

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Номер записи: 3
02-08-2012 дата публикации

Heterogenous enzymatic catalyst, preparation method, and use

Номер: US20120196337A1
Автор: Annick Babeau-Garcia, Clement Sanchez, Nicolas Brun, Renal Backov
Принадлежит: Individual

The invention relates to a heterogenous enzymatic catalyst that takes the form of a cellular monolith consisting of a silica or organically modified silica matrix, said monolith including macropores, mesopores, and micropores, said pores being interconnected, and wherein the inner surface of the macropores is functionalized by a coupling agent selected from among silanes, said inner surface moreover having an unpurified enzyme attached thereon by means of a covalent or electrostatic bond. The invention also relates to the method for preparing said catalyst, said method comprising: a first step for preparing a solid silica impression that takes the form of a cellular monolith such as defined above; a second step for functionalizing the inner surface of the macropores via a coupling agent, selected from among silanes, by vacuum-soaking the cellular monolith by dissolving the coupling agent in an organic solvent; and a third step for vacuum-soaking the thus-functionalized monolith by means of an aqueous solution or aqueous dispersion of at least one unpurified enzyme. Finally, the invention relates to the use of such catalyst to carry out catalyzed chemical reactions.

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Номер записи: 4
30-08-2012 дата публикации

Bio-based Wax Compositions and Applications

Номер: US20120216446A1
Автор: Andrew J. Clock, Eric Wisnefsky, Peter Frenkel
Принадлежит: Galata Chemicals LLC

Bio-based wax compositions contain at least one non-hydrogenated epoxy product and at least one wax component containing insect wax. The wax compositions can be used to produce candle compositions such as free-standing candles and container candles, and/or composite materials.

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Номер записи: 5
20-09-2012 дата публикации

Method for the enhanced recovery of catmint oil

Номер: US20120238768A1
Автор: David L. Hallahan, Mark A. Scialdone
Принадлежит: EI Du Pont de Nemours and Co

A high yielding method is described for recovery of catmint oil from catmint plants of the genus Nepeta by improved separation of a catmint oil containing phase from the condensed steam distillate of catmint plants. Catmint oil may be obtained in quantitative yields for use in insect repellent compositions.

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Номер записи: 6
25-10-2012 дата публикации

Enzyme interesterification process

Номер: US20120270283A1
Автор: Jeroen Maes, Marc Kellens, Vaida Petrauskaite, Veronique Gibon
Принадлежит: Desmet Ballestra Engineering NV SA

A fatty material enzyme interesterification process comprising the steps of: a) providing a fatty material that has optionally undergone at least one prior purification treatment; b) introducing soap into said fatty material to form a soap-containing fatty material mixture, c) homogenising said soap-containing fatty material mixture by mixing, d) contacting said soap-containing fatty material mixture with lipase to produce a soap-containing interesterified fatty material, e) removing soaps from said soap-containing interesterified fatty material to yield interesterified fatty material, wherein said soap is either formed in-situ by addition of aqueous alkali to said fatty material or said soap is introduced directly into said fatty material.

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Номер записи: 7
21-03-2013 дата публикации

Coating fat composition and particulate composition using the same

Номер: US20130071525A1
Автор: Akio Sakaki, Kento Kanaya, Masao Sato, Masayuki Abe
Принадлежит: Kaneka Corp

A particulate composition, wherein a hydrophilic substance is polydispersed in a matrix of a fat composition having a solid fat content at 25 C of 58% or more and a solid fat content at 37 C of 90% or less; and a coating fat composition containing 45% by weight or more of a triglyceride comprising at least both a saturated fatty acid having 6 to 12 carbon atoms and a saturated fatty acid having 14 or more carbon atoms as constituent fatty acids, wherein the proportion of the saturated fatty acid having 14 or more carbon atoms in the constituent fatty acids of the whole fat exceeds 50% by weight.

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Номер записи: 8
21-03-2013 дата публикации

MANUFACTURE OF HIGH PURITY STEARIN FROM HIGH OLEIC ACID AND LOW PALMITIC ACID SUNFLOWER OIL

Номер: US20130072705A1
Автор: Benson Robert Martin, DeAmicis Carl Vincent, Erickson Angela Lee, Flook Josh, Gerdes James Todd, Kahl Charles James, Patterson Thomas G., Syed Asim, Whiteker Gregory Todd
Принадлежит: DOW AGROSCIENCES LLC

This disclosure concerns methods for producing a high purity stearin comprising, for example, providing a sunflower oil comprising no more than about 4% total saturated fat and hydrogenating the sunflower oil. By way of further example, a method for producing a high purity tristearin may comprise providing sunflower oil comprising at least about 88% oleic acid and hydrogenating the sunflower oil. High purity stearin produced by methods, such as the foregoing, are also disclosed. 1. A method for producing a high purity tristearin , the method comprising:providing sunflower oil comprising no more than about 4% total saturated fat; andhydrogenating the sunflower oil.2. The method according to claim 1 , wherein the sunflower oil comprises at least about 88% oleic acid (18:1).3. The method according to claim 1 , wherein the sunflower oil comprises at least about 92% oleic acid (18:1).4. The method according to claim 1 , wherein the sunflower oil comprises less than about 3% combined 16:0 and 16:1 fatty acids.5. The method according to claim 1 , wherein the sunflower oil comprises less than about 4% palmitic acid (16:0).6. The method according to claim 1 , wherein the sunflower oil comprises less than about 3% palmitic acid (16:0).7. The method according to claim 1 , wherein the sunflower oil comprises at least about 90% oleic acid (18:1).8. The method according to claim 1 , wherein the sunflower oil comprises at least about 92% oleic acid (18:1).9. The method according to claim 1 , wherein the sunflower oil comprises less than or equal to about 4% total combined palmitic acid (16:0) and stearic acid (18:0).10. The method according to claim 1 , wherein the sunflower oil comprises less than or equal to about 3.3% total combined palmitic acid (16:0) and stearic acid (18:0).11. The method according to claim 1 , wherein the sunflower oil comprises up to about 94% oleic acid (18:1) and less than about 4% palmitic acid (16:0).12. The method according to claim 1 , wherein the ...

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Номер записи: 9
28-03-2013 дата публикации

Process For The Hydrogenation Of Fatty Acids Using A Promoted Supported Nickel Catalyst

Номер: US20130079535A1
Автор: Robert Johan Andreas Maria Terorde, Tjalling Rekker
Принадлежит: BASF Corp

The invention is directed to a process for the hydrogenation of unsaturated fatty acids to produce saturated fatty acids, said process comprising hydrogenating the unsaturated fatty acid in the presence of hydrogen and a supported nickel catalyst, said supported nickel catalyst comprising an oxidic support, 5 to 80 wt. % of nickel, calculated as metallic nickel on the weight of the catalyst, and 0.1 to 10 wt. % of a manganese promoter, calculated as MnO 2 on the weight of the catalyst.

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Номер записи: 10
18-04-2013 дата публикации

INTERESTERIFICATION OF LOW SATURATE SUNFLOWER OIL AND RELATED METHODS AND COMPOSITIONS

Номер: US20130096331A1
Автор: Flook Joshua, Gerdes James, Patterson Thomas G.
Принадлежит: DOW AGROSCIENCES LLC

A method of producing a interesterified oil includes providing sunflower oil comprising no more than about 4% total saturated fat and interesterifying the sunflower oil. Another method of producing a interesterified oil includes providing sunflower oil comprising about 3.3% or less total combined palmitic acid (16:0) and stearic acid (18:0), and interesterifying the sunflower oil. 1. A method of producing a interesterified oil , the method comprising:providing sunflower oil comprising no more than about 4% total saturated fat; andinteresterifying the sunflower oil.2. The method according to claim 1 , wherein the sunflower oil comprises at least about 88% oleic acid (18:1).3. The method according to claim 1 , wherein the sunflower oil comprises less than about 3% palmitic acid (16:0).4. The method according to claim 1 , wherein interesterifying the sunflower oil comprises the use of a chemical catalyst.5. The method according to claim 4 , wherein the chemical catalyst is selected from the group consisting of alkali metals claim 4 , alkalki metal alkylates claim 4 , alkali metal hydroxides claim 4 , alkali metal alcoholates claim 4 , alkali metal alloys claim 4 , Na/K alloys claim 4 , sodium methoxide claim 4 , sodium ethoxide claim 4 , and sodium stearate.6. The method according to claim 1 , wherein interesterifying the sunflower oil comprises the use of an enzymatic catalyst.7. The method according to claim 6 , wherein the enzymatic catalyst is a lipase.8. The method according to claim 6 , wherein the enzymatic catalyst is a 1 claim 6 , 3 specific lipase.9. An interesterified oil produced by the process of .10. The interesterified oil according to claim 9 , wherein at least 50% of the fatty acids at the 2 position of glycerol in the oil are unsaturated.11. The interesterified oil according to claim 9 , wherein at least 50% of the fatty acids at the 2 position of glycerol oil are oleic acid.12. An interesterified sunflower oil wherein wherein at least 50% of the ...

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Номер записи: 11
02-05-2013 дата публикации

Hydrogenation Of Fatty Acids Using A Promoted Supported Nickel Catalyst

Номер: US20130109875A1
Автор: Bouwman Hermanus Johannes, Terörde Robert Johan Andreas Maria
Принадлежит: BASF CORPORATION

The invention is directed to a process for the hydrogenation of unsaturated fatty acids to produce saturated fatty acids, said process comprising hydrogenating the unsaturated fatty acid in the presence of hydrogen and a supported nickel catalyst, said supported nickel catalyst comprising an oxidic support, 5 to 80 wt. % of nickel, calculated as atomic nickel on the weight of the catalyst, 0.1 to 10 wt. % of a copper promoter, calculated as atomic copper on the weight of the catalyst and 1 to 10 wt. % of a group II metal, calculated as metallic oxide on the weight of the catalyst. 1. A process for the hydrogenation of unsaturated fatty acids to produce saturated fatty acids , said process comprising hydrogenating the unsaturated fatty acid in the presence of hydrogen and a supported nickel catalyst , said supported nickel catalyst comprising an oxidic support , 5 to 80 wt. % of nickel , calculated as atomic nickel on the weight of the catalyst , 0.1 to 10 wt. % of a copper promoter , calculated as atomic copper on the weight of the catalyst and 1 to 10 wt. % of a group II metal , calculated as metallic oxide on the weight of the catalyst.2. The process of claim 1 , wherein the catalyst comprises 25 to 80 wt. % of nickel claim 1 , preferably>30 wt. % claim 1 , and even more preferably>60 wt. % claim 1 , calculated as atomic nickel on the weight of the catalyst.3. The process of claim 1 , wherein the catalyst comprises 0.5 to 5 wt. % of a copper promoter claim 1 , preferably 1.5 to 5 wt. % claim 1 , calculated as atomic copper on the weight of the catalyst.4. The process of claim 1 , wherein the support is an oxidic support claim 1 , the support preferably selected from silica claim 1 , alumina claim 1 , silica- alumina claim 1 , titania claim 1 , zirconia and combinations thereof.5. The process of claim 4 , wherein the oxidic support material of said catalyst is silica.6. The process of claim 1 , wherein said catalyst comprises 1 to 90 wt. % silica claim 1 , ...

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Номер записи: 12
25-07-2013 дата публикации

Polyetherester polyols and preparation thereof

Номер: US20130190418A1
Автор: Andreas Kunst, Berend Eling, Christian Koenig
Принадлежит: BASF SE

The present invention relates to novel polyetherester polyols and to a process for preparation thereof.

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Номер записи: 13
01-08-2013 дата публикации

Plastic Oil and Fat Composition, and Production Method and Usage Thereof

Номер: US20130196046A1
Автор: Aki Teraminami, Hiroshi Ito, Minako Hiraoka, Tadayoshi Sadakane, Takehiko Sekiguchi
Принадлежит: J Oil Mills Inc

A plastic oil and fat composition provides a plastic oil and fat food that has a good filling operability, keeps the feeling of melt-in-the-mouth after long preservation, and is excellent in spreadability, oil-off resistance and the like. In the plastic oil and fat composition, a content of PPP is from 5.5 to 12% by weight, a content of PPLi+PLiP is from 5.5 to 15.5% by weight, a content of PPO+POP is from 7 to 20% by weight, and a value of PPO/(PPO+POP) is from 0.55 to 0.7. A method for producing the plastic oil and fat composition is also provided.

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Номер записи: 14
08-08-2013 дата публикации

METHODS OF REFINING AND PRODUCING ISOMERIZED FATTY ACID ESTERS AND FATTY ACIDS FROM NATURAL OIL FEEDSTOCKS

Номер: US20130204022A1
Автор: Behrends, Beltran Leslie V., Bernhardt Randal J., Cohen Steven A., Gildon Demond L., JR. Raymond T., Kunz Linda A., Pals Tessa M., Quinn Jordan R., Snead Thomas E.
Принадлежит: ELEVANCE RENEWABLE SCIENCES, INC.

Methods are provided for refining natural oil feedstocks and producing isomerized esters and acids. The methods comprise providing a C4-C18 unsaturated fatty ester or acid, and isomerizing the fatty acid ester or acid in the presence of heat or an isomerization catalyst to form an isomerized fatty ester or acid. In some embodiments, the methods comprise forming a dibasic ester or dibasic acid prior to the isomerizing step. In certain embodiments, the methods further comprise hydrolyzing the dibasic ester to form a dibasic acid. In certain embodiments, the olefin is formed by reacting the feedstock in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters, separating the olefins from the esters in the metathesized product, and transesterifying the esters in the presence of an alcohol to form a transesterified product having unsaturated esters. 1. A method of making an isomerized ester or acid , comprising:providing a C4-C22 unsaturated fatty acid or unsaturated fatty acid ester; andisomerizing the unsaturated fatty acid or the unsaturated fatty acid ester in the presence of heat or an isomerization catalyst to form an isomerized acid or isomerized acid ester.2. The method of claim 1 , wherein the unsaturated fatty acid ester is derived from transesterifying a natural oil feedstock in the presence of an alcohol to form the unsaturated fatty acid ester.3. The method of claim 2 , further comprising claim 2 , prior to the isomerizing step claim 2 , hydrolyzing the unsaturated fatty acid ester to form the unsaturated fatty acid.4. The method of claim 1 , wherein the unsaturated fatty acid or the unsaturated fatty acid ester is selected from the group consisting of: pentenoic acid esters claim 1 , hexenoic acid esters claim 1 , heptenoic acid esters claim 1 , octenoic acid esters claim 1 , nonenoic acid esters claim 1 , decenoic acid esters claim 1 , undecenoic acid esters claim 1 , dodecenoic acid ...

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Номер записи: 15
14-11-2013 дата публикации

Method for Producing a Fatty Acid Ester

Номер: US20130302864A1
Автор: Shigeo Suzuki
Принадлежит: Ajinomoto Co Inc

A method for producing a fatty acid ester, which comprises: (a) incubating a culture of microalga at a mid-temperature, wherein the culture is obtained by culturing the microalga in a medium, (b) then adding an alcohol, allowing a reaction at a temperature lower than the mid-temperature, and (c) collecting a fatty acid ester from an obtained reaction product.

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Номер записи: 16
06-02-2014 дата публикации

Process for autocatalytic esterification of fatty acids

Номер: US20140039206A1
Автор: Bent Sarup, Susanne JONSSON
Принадлежит: ALFA LAVAL CORPORATE AB

The present invention relates to a process for isolation of micronutrients from deodorizer distillate comprising free fatty acids, the process comprises the following steps: (i) treating the deodorizer distillate in an esterification step with glycerol, which esterification step is autocatalysed, producing a feedstock of acyl glycerides, and discharging excess of glycerol and produced water; (ii) transferring the feedstock of acyl glycerides having a water content less than 1500 ppm and a free fatty acid content less than 3 wt % to a transesterification step and treating the feedstock of acyl glycerides with methanol to produce a crude biodiesel product; and (iii) refining the crude biodiesel product in a distillation step, and separating the crude biodiesel product into three fractions 1) fatty acid methyl esters, 2) micronutrient rich product comprising tocopherol, and 3) light hydrocarbons.

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Номер записи: 17
07-01-2021 дата публикации

SOLVENT EXTRACTION OF OIL FROM DISTILLERS DRIED GRAINS AND METHODS OF USING EXTRACTION PRODUCTS

Номер: US20210002583A1
Автор: Bruinsma Keith, Endres Donald, Furcich Steven J.
Принадлежит:

A process for extraction of crude oil from distillers dried grain solubles and/or distillers dried grains and producing corn distillers meal that may be used as a livestock supplement is disclosed. For example, the corn distillers meal may be used as a crude protein supplement for use in a livestock feed diet or a poultry feed diet. The solvent extracted crude oil may be suitable for oleochemical processing for personal care and home care products, biodiesel production, and/or renewable diesel production from hydro-treating the extracted oil to make green diesel fuel. 1. A method of producing renewable fuel from crude corn oil produced from at least one by-product of a dry-grind ethanol process , the method comprising:solvent extracting crude corn oil from at least one by-product produced in a dry-grind ethanol process, the at least one by-product comprising distillers dried grains with solubles, distillers dried grains, or a combination thereof, wherein the crude corn oil comprising free fatty acids in an amount ranging from about 1% to about 15% by weight of the crude corn oil, and the crude corn oil having a residual level of solvent in an amount from about 1 ppm to about 500 ppm;pretreating the crude corn oil prior to a conversion process, wherein the pretreatment comprises degumming the crude corn oil to separate and remove the gum portion from the crude corn oil portion; andsubjecting the crude corn oil portion to a conversion process to produce a renewable fuel.2. The method of claim 1 , wherein the pretreatment step further comprises hydrating the crude corn oil with at least one hydrating agent to provide a gum portion and a crude corn oil portion prior to the degumming process.3. The method of claim 2 , wherein the at least one hydrating agent comprises one or more acids claim 2 , water claim 2 , or a combination thereof.4. The method of claim 3 , wherein the at least one hydrating agent comprises one or more acids or a combination of one or more acids and ...

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Номер записи: 18
09-01-2020 дата публикации

High Stearic Acid Marinade

Номер: US20200008440A1
Автор: De Lima Christopher Mark, Ma Jun, Theron Karin Alicia
Принадлежит: Bunge Loders Croklaan B.V.

A fat composition comprises: greater than 70% by weight stearic acid; from 5% to 20% by weight oleic acid; and from 1% to 10% by weight palmitic acid; said percentages of acids referring to acids bound as acyl groups in glycerides in the fat composition and being based on the total weight of C8 to C24 fatty acids; and greater than 40% by weight of StStSt triglycerides and greater than 10% by weight of PSttriglycerides based on total triglycerides present in the composition, and a weight ratio of PSt:StStSt triglycerides of less than 0.5, wherein P is palmitic acid and St is stearic acid. The fat may be used in a marinade. 1. A fat composition comprising:greater than 70% by weight stearic acid;from 5% to 20% by weight oleic acid; andfrom 1% to 10% by weight palmitic acid;the percentages of the acids referring to acids bound as acyl groups in glycerides in the fat composition and being based on the total weight of C8 to C24 fatty acids; and{'sub': '2', 'greater than 40% by weight of StStSt triglycerides and greater than 10% by weight of PSttriglycerides based on total triglycerides present in the composition, and'}{'sub': '2', 'a weight ratio of PSt:StStSt triglycerides of less than 0.5,'}wherein P is palmitic acid and St is stearic acid.2. The fat composition as claimed in claim 1 , comprising from 8% to 18% by weight oleic acid.3. The fat composition as claimed in comprising from 70% to 80% by weight stearic acid.4. The fat composition as claimed in claim 1 , comprising from 2% to 8% by weight palmitic acid.5. The fat composition as claimed in any one of the preceding claim 1 , comprising from 45% to 65% by weight of StStSt triglycerides.6. The fat composition as claimed in claim 1 , having a weight ratio of PSt:StStSt triglycerides in the range of from 0.15 to 0.4.7. The fat composition as claimed in claim 1 , having a PSt content of from 0.5% to 2% by weight.8. The fat composition as claimed in claim 1 , which comprises or consists of a stearin fraction of an ...

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Номер записи: 19
18-01-2018 дата публикации

Method for Preparation of a Group 4 Metal Silicate and Use Thereof

Номер: US20180015447A1
Автор: Jim Aloysius Maria Brandts, Lorianne Wagemaker
Принадлежит: BASF Corp

The invention provides a method for the preparation of an amorphous silicate of at least one metal from the Group 4 of the Periodic Table of Elements with a total pore volume of at least 0.3 mL/g. The method of preparation involves the use of pore shaping conditions, which can be the use of a pore shaper and optionally an increased precipitation temperature, e.g. at least 60° C. The silicate of the invention is especially suitable in catalytic reactions such as esterifications, Michael additions, transesteritications, (ep)oxidations, hydroxylations, or in absorbance of small inorganic and organic molecules e.g. CO 2 or aromatic compounds.

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Номер записи: 20
17-01-2019 дата публикации

COMPOSITION CONTAINING EICOSAPENTAENOIC ACID ALKYL ESTER, AND METHOD FOR PRODUCING SAME

Номер: US20190015375A1
Автор: Arato Shingo, Doisaki Nobushige, FUKAE Takuro
Принадлежит:

Provided are: a composition containing 96-99 area % of eicosapentaenoic acid alkyl ester, the composition having an arachidonic acid alkyl ester content of 0.7 area % or less, and an eicosapentaenoic-acid-alkyl-ester mono-trans isomer content of 2.5 area % or less; and a method for producing a composition containing a high concentration of eicosapentaenoic acid alkyl ester, the method including performing precision distillation on a composition containing eicosapentaenoic acid alkyl ester, obtained by alkyl esterification of a raw material oil containing eicosapentaenoic acid, under a vacuum of 0.2 Torr or lower and a temperature of 190° C. or lower in the entire column, and performing a concentration treatment on the precision-distilled composition using chromatography. 1. An eicosapentaenoic acid alkyl ester-containing composition which , upon measurement by gas chromatography , comprises 96 to 99 area % of an eicosapentaenoic acid alkyl ester , wherein the composition satisfies at least one of the following (i)-(iii):(i) the content of a n-nonadecanoic acid (C19:0) alkyl ester is 0.1 area % or less,(ii) the content of an arachidic acid (C20:0) alkyl ester is 0.2 area % or less, and(iii) the content of an icosa-5,9,11,14,17-pentaenoic acid (C20:5 n-3(5,9,11,14,17)) alkyl ester is 0.2 area % or less.2. The composition of claim 1 , wherein the content of mono-trans forms of the eicosapentaenoic acid alkyl ester is 2.5 area % or less.3. The composition of claim 1 , wherein the sum of the contents of mono-trans forms and di-trans forms of the eicosapentaenoic acid alkyl ester is 2.5 area % or less.4. The composition of claim 1 , wherein the sum of the contents of mono-trans forms claim 1 , di-trans forms and tri-trans forms of the eicosapentaenoic acid alkyl ester is 2.5 area % or less.5. The composition of claim 1 , wherein the sum of the contents of mono-trans forms claim 1 , di-trans forms claim 1 , tri-trans forms and tetra-trans forms of the eicosapentaenoic acid ...

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Номер записи: 21
21-01-2016 дата публикации

Conjugated Diene Acids and Derivatives Thereof

Номер: US20160016882A1
Автор: Charles Coburn, Ryan LITTICH
Принадлежит: Elevance Renewable Sciences Inc

Conjugated diene acids and derivatives thereof, are disclosed herein. In some embodiments, the conjugated diene acids and derivatives thereof are derived from the metathesis of a natural oil followed by isomerization. Uses of conjugated diene acids and derivatives thereof in various compositions are also disclosed herein.

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Номер записи: 22
18-01-2018 дата публикации

Renewably Derived Aldehydes and Methods of Making and Using the Same

Номер: US20180016519A1
Автор: Beltran Leslie V., Cohen Steven A., Gildon Demond L., Snead Thomas E., Weitkamp Robin
Принадлежит: ELEVANCE RENEWABLE SCIENCES, INC.

Methods for making specialty chemical products and chemical intermediates using hydroformylation are generally disclosed. Further, compositions and compounds formed using such methods are also disclosed. In some embodiments, methods are disclosed for refining a renewably sourced material, such as a natural oil, to form compositions, which can be further reacted employing the methods disclosed herein to form certain specialty chemical products or chemical intermediates. 175-. (canceled)76. A method for refining a natural oil derivative , comprising:providing a reactant composition comprising olefins, which are derived from a natural oil; and{'sub': '2', 'reacting the olefins with Hand CO in the presence of a hydroformylation catalyst to form a product composition comprising aldehydes or alcohols.'}77. The method of claim 76 , wherein the product composition comprises hydroformylation catalyst residues.78. (canceled)79. The method of claim 77 , wherein the product composition comprises a polar phase and a nonpolar phase.80. The method of claim 79 , wherein the nonpolar phase comprises at least a portion of the aldehydes or alcohols.81. The method of claim 80 , wherein the polar phase comprises at least a portion of the hydroformylation catalyst residues.82. The method of claim 81 , further comprising separating at least a portion of the hydroformylation catalyst residues from other compounds from the product composition.83. The method of claim 82 , wherein the separating comprises carrying out a liquid-liquid extraction claim 82 , wherein the extraction comprises removing a polar phase that comprises the hydroformylation catalyst resides from a nonpolar phase that comprises other compounds from the product composition.84. The method of claim 83 , wherein the olefins in the reactant composition comprise terminal olefins.85. (canceled)86. The method of claim 76 , wherein the olefins in the reactant composition comprise internal olefins.87. (canceled)88. The method of ...

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Номер записи: 23
28-01-2021 дата публикации

Non-Hydrogenated Fat Composition, Use and Process

Номер: US20210022362A1
Автор: Ma Jun, Petrut Raul-Flaviu
Принадлежит: Bunge Loders Croklaan B.V.

A non-hydrogenated fat composition comprises: from 3.2% to 10% by weight of total caprylic acid (C8:0) and capric acid (C10:0); from 13% to 32% by weight lauric acid; and from 20% to 45% by weight stearic acid (C18:0) fatty acid residues; the percentages of acids referring to acids bound as acyl groups in glycerides in the fat composition and being based on the total weight of C8 to C24 fatty acids; and from 7% to 15% by weight CN46 triglycerides; from 4% to 30% by weight CN54 triglycerides; and from 15% to 28% by weight of total CN42 triglycerides and CN44 triglycerides; the percentages of triglycerides referring to the total triglycerides present in the composition. 1. A non-hydrogenated fat composition , comprising:from 3.2% to 10% by weight of total caprylic acid (C8:0) and capric acid (C10:0);from 13% to 32% by weight lauric acid (C12:0); andfrom 20% to 45% by weight stearic acid (C18:0);said percentages of acids referring to acids bound as acyl groups in glycerides in the fat composition and being based on the total weight of C8 to C24 fatty acids; andfrom 7% to 15% by weight CN46 triglycerides;from 4% to 30% by weight CN54 triglycerides; andfrom 15% to 28% by weight of total CN42 triglycerides and CN44 triglycerides;based on total triglycerides present in the composition.2. The composition according to claim 1 , wherein the composition has less than 12% by weight palmitic acid (C16:0).3. The composition according to claim 1 , wherein the composition has a weight ratio of stearic acid (C18:0) to palmitic acid (C16:0) of from 5:2 to 9:1.4. The composition according to claim 1 , wherein the composition has a weight ratio of lauric acid (C12:0) to stearic acid (C18:0) of from 1:3.5 to 2:1.5. The composition according to claim 1 , wherein the composition has:from 3.5% to 8% by weight of total caprylic acid (C8:0) and capric acid (C10:0); and/orfrom 14% to 30% by weight lauric acid (C12:0); and/orfrom 23% to 43% by weight stearic acid (C18:0).6. The composition ...

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Номер записи: 24
24-01-2019 дата публикации

SOLVENT EXTRACTION OF OIL FROM DISTILLERS DRIED GRAINS AND METHODS OF USING EXTRACTION PRODUCTS

Номер: US20190024017A1
Автор: Bruinsma Keith, Endres Donald, Furcich Steven J.
Принадлежит:

A process for extraction of crude oil from distillers dried grain solubles and/or distillers dried grains and producing corn distillers meal that may be used as a livestock supplement is disclosed. For example, the corn distillers meal may be used as a crude protein supplement for use in a livestock feed diet or a poultry feed diet. The solvent extracted crude oil may be suitable for oleochemical processing for personal care and home care products, biodiesel production, and/or renewable diesel production from hydro-treating the extracted oil to make green diesel fuel. 134.-. (canceled)35. A method of producing oleochemicals from crude corn oil produced from distillers dried grains with solubles in a dry-grind ethanol process , the method comprising:solvent extracting crude corn oil from distillers dried grains with solubles, the distillers dried grains with solubles produced in a dry-grind ethanol process, the crude corn oil comprising free fatty acids in an amount ranging from about 1% to about 15% by weight of the crude corn oil; nitrogen in an amount no more than about 0.5% by weight of the crude corn oil; and phosphorous in an amount no more than about 0.05%;splitting at least a portion of glycerides in the crude corn oil into a crude fatty acids portion and a crude glycerine portion; andprocessing the crude fatty acids portion and/or the crude glycerine portion into one or more oleochemicals;wherein the oleochemical processed from the crude corn oil is substantially free from non-native emulsifiers and flocculants.36. The method of claim 35 , wherein processing the crude glycerine portion comprises refining the crude glycerine portion to produce a refined glycerine.37. The method of claim 36 , further comprising conducting esterification on the refined glycerine followed by distillation processing to produce a distilled esters of glycerol.38. The method of claim 35 , wherein processing the crude fatty acids portion comprises distilling the crude fatty acids ...

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Номер записи: 25
29-01-2015 дата публикации

Mobile processing systems and methods for producing biodiesel fuel from waste oils

Номер: US20150031097A1
Автор: James M. Rethore, Julie E. Wheeler, Luca Zullo
Принадлежит: Revolution Fuels Inc

The present invention improves biodiesel production in several ways. Unique combinations of unit operations and flow configurations are disclosed in mobile processing units that are feedstock-flexible and can be dynamically deployed in a distributed way. In some embodiments, a process includes introducing a waste oil and an alcohol into a reactor with an esterification-transesterification enzymatic catalyst. Free fatty acids are reacted with alcohol to produce fatty acid alkyl esters, and glycerides are reacted with alcohol to produce fatty acid alkyl esters and glycerin. A membrane separator removes glycerin, water, and alcohol. Unreacted free fatty acids are then separated and recycled, to generate a product stream with fatty acid alkyl esters. A genset may be provided for combusting glycerin to produce electrical power and thermal heat as co-products. This biodiesel process may be energy self-sufficient, require no external utilities, and avoid direct discharge of wastewater.

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Номер записи: 26
24-04-2014 дата публикации

REDUCED COLOR EPOXIDIZED ESTERS FROM EPOXIDIZED NATURAL FATS AND OILS

Номер: US20140113999A1
Автор: Hagberg Erik, Howard Stephen, Poppe George
Принадлежит: ARCHER DANIELS MIDLAND COMPANY

Reduced color epoxidized fatty acid esters are provided which may be used as primary plasticizers for PVC, in replacement of phthalate plasticizers. The reduced color epoxidized fatty acid esters are prepared from natural fats or oils by transesterification and interesterification processes, whereby through the use of borohydride, materials having Pt-Co colors according to ASTM D1209 on the order of 50 and lower are possible. 1. An epoxidized fatty acid ester of a natural fat or oil , having a Pt-Co Hazen color of 90 or less as determined by ASTM D1209.2. An epoxidized fatty acid ester according to claim 1 , having a Pt-Co Hazen color of 50 or less.3. A plasticized polymer composition claim 1 , comprised of one or more polymers selected from the group consisting of halogenated polymers claim 1 , acid-functionalized polymers claim 1 , anhydride-functionalized polymers and nitrile rubbers claim 1 , and one or more epoxidized fatty acid esters characterized as in or .4. A plasticized polymer composition according to claim 3 , wherein the polymer is PVC.5. A plasticized polymer composition according to claim 3 , wherein the epoxidized fatty acid ester or esters comprises at least 20 percent by weight of the composition.6. A plasticized polymer composition according to claim 5 , wherein the ester or esters comprises at least 30 percent by weight of the composition.7. A plasticized polymer composition according to claim 6 , wherein the ester or esters comprises at least 50 percent by weight of the composition.8. A plasticized polymer composition according to claim 3 , which is at least substantially phthalate-free.9. A plasticized polymer composition according to claim 8 , which is phthalate-free.10. A process of making a reduced color epoxidized fatty acid ester from an epoxidized natural fat or oil claim 8 , comprising the steps of combining an alcohol claim 8 , an epoxidized natural fat or oil and borohydride with a transesterification catalyst claim 8 , under ...

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Номер записи: 27
01-02-2018 дата публикации

PRODUCTION METHOD FOR OIL AND FAT

Номер: US20180030485A1
Автор: WATANABE Shimpei
Принадлежит: FUJI OIL HOLDINGS INC.

The present invention provides a commercially-viable-level, highly efficient production method for oil and fat that are rich in USU. 1. A process for producing a fat composition containing USU , comprising:(1) a step of mixing (a) raw material fat containing 80% by weight or more of (S) saturated fatty acid with C16 to C24, wherein the (a) raw material fat contains 10 to 70% by weight of saturated fatty acid with C20 to C24 or 10 to 70% by weight of palmitic acid, and (b) raw material fatty acid or lower alcohol ester thereof containing (U) unsaturated fatty acid with C18 as major component;(2) a step of subjecting the mixture obtained in step (1) to an interesterification reaction using a 1,3-position-specific lipase;(3) a step of separating the fat composition containing 30% by weight or more of USU as a triglyceride fraction, and a fraction of fatty acid or lower alcohol ester thereof; and(4) a step of separating the unreacted (b) raw material fatty acid or lower alcohol ester thereof, to circulate a part or all of the recovered unreacted (b) raw material fatty acid or lower alcohol ester thereof as the (b) in step (1) for reuse,wherein USU is a triglyceride whose fatty acids at 1, 3-positions are U and fatty acid at 2-position is S.2. The process for producing the fat composition according to claim 1 , wherein at least one of the separations at step (3) and step (4) is performed by a distillation.3. The process for producing the fat composition according to claim 1 , wherein the (a) raw material fat contains 80% by weight or more of S and 10 to 70% by weight of the saturated fatty acid with C20 to 24 in the constituent fatty acid.4. The process for producing the fat composition according to claim 3 , wherein a part or all of the (a) raw material fat in step (1) is a fully hydrogenated oil of high erucic rapeseed oil claim 3 , and wherein the (b) raw material fatty acid or lower alcohol ester thereof contains 70% by weight or more of oleic acid.5. The process for ...

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Номер записи: 28
04-02-2021 дата публикации

COMPOSITION CONTAINING EICOSAPENTAENOIC ACID ALKYL ESTER, AND METHOD FOR PRODUCING SAME

Номер: US20210030707A1
Автор: Arato Shingo, Doisaki Nobushige, FUKAE Takuro
Принадлежит:

Provided are: a composition containing 96-99 area % of eicosapentaenoic acid alkyl ester, the composition having an arachidonic acid alkyl ester content of 0.7 area % or less, and an eicosapentaenoic-acid-alkyl-ester mono-trans isomer content of 2.5 area % or less; and a method for producing a composition containing a high concentration of eicosapentaenoic acid alkyl ester, the method including performing precision distillation on a composition containing eicosapentaenoic acid alkyl ester, obtained by alkyl esterification of a raw material oil containing eicosapentaenoic acid, under a vacuum of 0.2 Torr or lower and a temperature of 190° C. or lower in the entire column, and performing a concentration treatment on the precision-distilled composition using chromatography. 2. The composition of claim 1 , wherein the content of an arachidonic acid alkyl ester is 0.7 area % or less.3. The composition of claim 1 , wherein the content of the arachidonic acid alkyl ester is 0.1 area % or less.4. The composition of claim 1 , wherein the content of an eicosatetraenoic acid alkyl ester is 0.7 area % or less.5. The composition of claim 1 , wherein the content of an octadecatetraenoic acid alkyl ester is 0.4 area % or less.6. The composition of claim 1 , wherein the content of a nonadecapentaenoic acid alkyl ester is 0.2 area % or less.7. The composition of claim 1 , wherein the eicosapentaenoic acid alkyl ester is ethyl eicosapentaenoate or methyl eicosapentaenoate.8. The composition of claim 1 , wherein the content of a n-nonadecanoic acid (C19:0) alkyl ester is 0.1 area % or less.9. The composition of claim 1 , wherein the content of an arachidic acid (C20:0) alkyl ester is 0.2 area % or less.10. The composition of claim 1 , wherein the content of alkyl esters of saturated fatty acids is 0.5 area % or less.11. The composition of claim 1 , wherein the content of an icosa-5 claim 1 ,9 claim 1 ,11 claim 1 ,14 claim 1 ,17-pentaenoic acid (C20:5n-3(5 claim 1 ,9 claim 1 ,11 claim ...

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Номер записи: 29
04-02-2021 дата публикации

Process for the Decarboxylation, Isomerization, Hydrogenation, Dehydrogenation and Cyclization Aromatization of Fatty Acids Yielding Products with Significant Aromatic Content

Номер: US20210032565A1
Автор: Bryan R. Moser, Gerhard H. Knothe, Kenneth M. Doll
Принадлежит: US Department of Agriculture USDA

Disclosed herein are processes for the decarboxylation, isomerization, hydrogenation, dehydrogenation, and cyclization/aromatization of fatty acids involving contacting a starting material which is an unsaturated fatty acid, unsaturated fatty acid derivative, or an unsaturated triglyceride, in the presence of a catalyst at a temperature at which decarboxylation, isomerization, hydrogenation, dehydrogenation, and cyclization/aromatization occurs and recovering the unsaturated organic compound product; wherein the catalyst is chloro-1,5-cyclooctadiene iridium (I) dimer. The product may contain at least about 8% by volume aromatic content and less than about 25% by volume aromatic content, and wherein the product contains less than about 1% by volume of naphthalenes.

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Номер записи: 30
18-02-2021 дата публикации

PROCESS FOR THE PRE-TREATMENT OF FEEDS FOR THE PRODUCTION OF BIOFUELS BY HYDROLYSIS OF FATS AT HIGH TEMPERATURE AND PRESSURE

Номер: US20210047575A1
Автор: ZARLI Antonio
Принадлежит:

A hydrotreating and isomerization pre-treatment process in a biofuel production plant, which is characterized in that it occurs from a raw supply consisting of an organic feed comprising secondary materials such as frying oils, category 1 animal fats, residual oils or by-products consisting of monoglycerides, diglycerides, triglycerides and free fatty acids, which is added to a recycling stream consisting of a mixture of mono-, di- and triglycerides free of impurities and exiting an esterification unit, said process occurring by means of hydrolysis with excess water, under controlled pressure and temperature conditions, thus obtaining the partial or total conversion of the supply into glycerol and fatty acids, the excess water introduced into the hydrolysis process acting as a solvent for impurities of various nature present in ionic form, thus removing most of the heavy metals, as well as of the chlorides present in said supply. 1. A hydrotreating and isomerization pre-treatment process in a biofuel production plant , characterized in that it is fulfilled from a raw stream consisting of an organic feed comprising secondary materials such as frying oils , category animal fats , residual oils or by-products consisting of monoglycerides , diglycerides , triglycerides and free fatty acids , which is added to a recycling stream consisting of a mixture of mono- , di- and triglycerides free of impurities and exiting an esterification unit , said process taking place by means of hydrolysis with excess water , under controlled pressure and temperature conditions , thus obtaining the partial or total conversion of the incoming feed into glycerol and fatty acids , the excess water introduced into the hydrolysis process acting as a solvent for impurities of various nature present in ionic form , thus removing most of the heavy metals , as well as of the chlorides contained in said incoming feed.2. A process according to claim 1 , wherein the water sent to the pre-treatment is ...

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Номер записи: 31
13-02-2020 дата публикации

TRANSESTERIFIED FAT OR OIL

Номер: US20200045991A1
Автор: Ishiwata Akiyuki, KANDA Nanako, SATO Yasuko, WATANABE Shimpei
Принадлежит: FUJI OIL HOLDINGS INC.

The present invention addresses the problem of providing a chocolate which has a reduced trans fatty acid content and yet shows a high compatibility with cocoa butter, excellent blooming resistance and high meltability in mouth. A transesterified fat or oil wherein, in the constituting fatty acid composition thereof, the content of unsaturated fatty acids is regulated to not more than 10 mass % and the composition of other fatty acids is controlled to a preset content. 1. An interesterified fat satisfying the following (A) to (J):(A) a content of saturated fatty acids having 6 to 18 carbon atoms in constituent fatty acid composition is 90 to 99.5% by mass;(B) a content of saturated fatty acids having 6 to 10 carbon atoms in constituent fatty acid composition is 6 to 18% by mass;(C) a content of saturated fatty acids having 16 to 18 carbon atoms in constituent fatty acid composition is 25 to 50% by mass;(D) a content of saturated fatty acids having 12 or less carbon atoms in constituent fatty acid composition is 35 to 60% by mass;(E) a content of saturated fatty acids having 20 or more carbon atoms in constituent fatty acid composition, is 1% by mass or less;(F) a content of lauric acid in constituent fatty acid composition is 20 to 50% by mass;(G) a content of palmitic acid in constituent fatty acid composition is 20 to 38% by mass;(H) a content of stearic acid in constituent fatty acid composition is 3 to 20% by mass;(I) a content of unsaturated fatty acids in constituent fatty acid composition is 0.5 to 10% by mass;(J) a content of trans fatty acids in constituent fatty acid composition is 5% by mass or less, wherein an analysis of the fatty acid composition is carried out after the fatty acid is propyl esterified.2. The interesterified fat according to claim 1 , wherein total content of (B) and (I) is 10% to 20% by mass claim 1 , a content of CN30 to CN38 is 20 to 50% by mass claim 1 , and a content of CN48 or more is 30% by mass or less claim 1 , and wherein ...

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Номер записи: 32
14-02-2019 дата публикации

EMULSIFIED OILS

Номер: US20190048148A1
Автор: Lalgudi Ramanathan S.
Принадлежит:

Emulsions for treating shingles, concrete, metallic substrates, mammalian skins, human hair or agricultural plants are described. The emulsions include soy alkyl and/or aryl ester; water; and a cationic surfactant to form the emulsion. Methods of using the emulsions are also described. Compositions including a modified oil alkyl and/or aryl ester comprising the transesterification reaction product of an oil and a surfactant having a hydroxyl group are described. Methods of using the compositions are also described. Methods of making a modified oil alkyl or aryl ester are described. The methods include transesterifying an oil with a surfactant having a hydroxyl group. 1. A composition comprising:a modified oil alkyl ester, modified oil aryl ester, or combinations thereof, the modified oil alkyl ester soy aryl ester comprising the transesterification reaction product of an oil and a surfactant having a hydroxyl group.2. The composition of wherein the surfactant comprises a cationic surfactant claim 1 , an anionic surfactant claim 1 , or a non-ionic surfactant.3. The composition of wherein the surfactant comprises the cationic surfactant.4. The composition of wherein the cationic surfactant comprises a benzalkonium salt claim 3 , a polyquaternirium compound claim 3 , poly(vinyl pyridine) co-N claim 3 ,N dimethyl ethyl methacrylate claim 3 , or combinations thereof.5. The composition of wherein the surfactant comprises the anionic surfactant.6. The composition of wherein the anionic surfactant comprises sodium dodecyl sulfate claim 5 , sodium lauryl benzene sulfonate claim 5 , poly acrylic acid claim 5 , an anionic sulfate-based surfactant claim 5 , an anionic sulfonate-based surfactant claim 5 , or combinations thereof.7. The composition of wherein the surfactant comprises the non-ionic surfactant.8. The composition of wherein the non-ionic surfactant comprises poly(ethylene oxide-b-propylene oxide) claim 7 , poly(ethylene oxide-b-butylene oxide) claim 7 , a sorbitol ...

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Номер записи: 33
14-02-2019 дата публикации

METHOD FOR PRODUCING MULTIPLE OIL/FAT COMPOSITIONS BY COMPLEX TRANSESTERIFICATION REACTION SYSTEM

Номер: US20190048370A1
Автор: WATANABE Shimpei
Принадлежит: FUJI OIL HOLDINGS INC.

The present invention addresses the problem of providing a method for effectively producing a target oil/fat that is rich in triglyceride, by using liberated by-products such as fatty acid ester originating from starting material oil/fat that is separated from the target oil/fat efficiently after the reaction when producing the target oil/fat that is rich in triglyceride by a transesterification reaction using, for example, oil/fat and fatty acid ester as starting materials. 1. A process for producing a plurality of fat compositions by a combined reaction system , wherein the combined reaction system comprises a plurality of reaction systems which produce a target fat composition rich in triglyceride by 1 ,3-position specific interesterification of raw material fat and raw material fatty acid or lower alcohol ester thereof , comprising:separating a fraction of fatty acid or lower alcohol ester thereof, which is liberated derived from 1,3-positions of the raw material fat, from a reaction product after the 1,3-position specific interesterification in each of the reaction systems; andusing the fraction as a part or all of raw material fatty acid or lower alcohol ester thereof in another reaction system.2. The process for producing a plurality of fat compositions according to claim 1 , wherein the combined reaction system comprises a first reaction system which produces a fat composition rich in USU and a second reaction system which produces a fat composition rich in SUS claim 1 , the first reaction system comprises the following steps (1) to (3) claim 1 , the second reaction system comprises the following steps (4) to (6) claim 1 , wherein a fraction obtained in step (6) is used for a part or all of raw material fatty acid or lower alcohol ester thereof (b) in step (1) claim 1 , and wherein a fraction obtained in step (3) is used for a part or all of raw material fatty acid or lower alcohol ester thereof (d) in step (4) claim 1 , (1) a step of mixing raw material fat ...

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Номер записи: 34
25-02-2021 дата публикации

METHOD OF PROCESSING A BIO-BASED MATERIAL AND APPARATUS FOR PROCESSING THE SAME

Номер: US20210054292A1
Автор: BOONSIT Nopporn, LAOHAKUNAKORN Winai, SIRIMITRTRAKUL Supakorn
Принадлежит: GREEN TECHNOLOGY RESEARCH CO., LTD.

The present invention relates to a method for processing a renewable bio-based material comprising the step of reacting the bio-based material with hydrogen in the presence of a catalyst on a support in a reactor to form a treated oil; (i) passing the treated oil through a distillation unit and an adsorption unit to form green diesel; and/or (ii) passing the treated oil through at least one distillation column to separate the treated oil into at least one component and passing the at least one component through an adsorption column; and wherein the reactor comprises a cooling function for controlling the temperature of the reactor, wherein the cooling function is at least one of an internal cooling function and an external cooling function. 1. A method of processing a renewable bio-based material comprising the step of:reacting the bio-based material with hydrogen in the presence of a catalyst on a support in a reactor to form a treated oil;(i) passing the treated oil through a distillation unit and an adsorption unit to form green diesel; and/or (ii) passing the treated oil through at least one distillation column to separate the treated oil into at least one component and passing the at least one component through an adsorption column;wherein the reactor comprises a cooling function for controlling the temperature of the reactor; wherein the cooling function is an internal cooling function.2. The method of claim 1 , wherein the support is alumina (AlO) claim 1 , silica (SiO) or alumina-silica (AlO—SiO).3. The method of claim 2 , wherein the support is AlOand the catalyst on AlOis selected from the group consisting of NiMo/AlOand NiW/AlO.4. The method of claim 3 , wherein the support is AlOand the catalyst on AlOis NiW/AlO.5. The method of claim 2 , wherein the support is AlOand the catalyst on AlOis selected from the group consisting of NiCoMo/AlO claim 2 , NiMoP/AlOand CoMo/AlO.6. The method of claim 5 , wherein the support is AlOand the catalyst on AlOis ...

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Номер записи: 35
25-02-2021 дата публикации

ANAPLEROTIC OIL PRODUCTION IN MICROBIALS

Номер: US20210054421A1
Автор: Amezquita Ernult Magdalena, Ganuza Taberna Eneko, Sellers Charles
Принадлежит:

Disclosed are techniques and systems for producing microbials having anaplerotic oils that are rich in odd-chain fatty acids, and other beneficial components, at higher concentrations than those present in other natural dietary sources of OCFA, at lower cost, and higher production yield. Such compositions can comprise pentadecanoic and heptadecanoic fatty acids. The techniques described herein include methods for producing and deriving such compositions rich in odd-chain fatty acids from microbials, including microalgae and yeasts/fungi. 1. A method for producing anaplerotic oil from microalgae , the method comprising:adding the microalgae to a culture medium, wherein the microalgae are from the family of thraustochytrids;adding propionate to the culture medium resulting in cultured microalgae with enhanced synthesis of saturated tridecanoic (C13:0), pentadecanoic (C15:0), and heptadecanoic (C17:0) odd-chain fatty acid (OFCA) and increased total amounts of tridecanoic (C13:0), pentadecanoic (C15:0), and heptadecanoic (C17:0) present in the microalgae; andproducing an anaplerotic oil from the cultured microalgae, wherein at least five percent of the total fatty acids (TFA) of the anaplerotic oil are saturated tridecanoic (C13:0), pentadecanoic (C15:0), and heptadecanoic (C17:0) OCFA and the saturated tridecanoic (C13:0), pentadecanoic (C15:0), and heptadecanoic (C17:0) make up at least one percent of the cell dry weight (CDW) of the microbial mass.2. The method of claim 1 , wherein adding propionate comprises adding the propionate to produce OCFAs in a range of 5 and 70% TFAs.3. The method of claim 1 , wherein the propionate is added with a carbon source at a weight to weight ratio below 0.1 of propionate to carbon source.4. The method of claim 1 , wherein adding propionate comprises adding the propionate in a batch system into the culture medium.5. The method of claim 1 , wherein adding propionate comprises adding the propionate in a fed-batch system into the ...

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Номер записи: 36
10-03-2022 дата публикации

MIXED TRIGLYCERIDES

Номер: US20220071942A1
Автор: Blanchard Carine, Cuenoud Bernard, Destaillats Frederic, Forbes-Blom Elizbeth, Oertling Heiko, PATIN AMAURY
Принадлежит:

A composition comprising a compound having the formula (1), (2), (3), (4) or combinations thereof, wherein n1, n2, n3, n4, n5 and n6 are independently 4 to 10. 2. A composition according to claim 1 , wherein the composition comprises the compound having formula (1) claim 1 , the compound having formula (2) claim 1 , the compound having formula (3) and the compound having formula (4).3. A composition according to claim 1 , wherein the compounds having formula (1) claim 1 , (2) claim 1 , (3) and (4) claim 1 , comprise at least 50% claim 1 , 60% claim 1 , 70% claim 1 , 80% claim 1 , 90% claim 1 , 95% or 99% by weight of the total triglycerides of the composition.5. A composition according to claim 4 , wherein the composition comprises the compound having formula (5) claim 4 , the compound having formula (6) claim 4 , the compound having formula (7) and the compound having formula (8).6. A composition according to claim 4 , wherein the compound having formula (5) comprises 20 to 30% by weight of the total triglycerides of the composition claim 4 , the compound having formula (6) comprises 15 to 25% by weight of the total triglycerides of the composition claim 4 , the compound having formula (7) comprises 10 to 20% by weight of the total triglycerides of the composition claim 4 , and the compound having formula (8) comprises 5 to 15% by weight of the total triglycerides of the composition.7. A composition according to claim 4 , wherein the compounds having formula (5) claim 4 , (6) claim 4 , (7) and (8) claim 4 , comprise at least 50 by weight of the total triglycerides of the composition.8. A composition according to claim 1 , wherein tributyrin comprises less than 10% by weight of the total triglycerides in the composition.910-. (canceled)1213-. (canceled)15. (canceled) The present invention relates to a dietary source of butyric acid containing triglycerides having improved organoleptic properties. The present invention also provides butyric acid containing ...

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Номер записи: 37
21-02-2019 дата публикации

TRANSESTERIFIED OIL AND PLASTIC OIL/FAT COMPOSITION USING SAME AS HARDSTOCK

Номер: US20190053510A1
Автор: HORI Katsuhito, Omori Hitomi
Принадлежит: FUJI OIL HOLDINGS INC.

The present invention addresses the problem of providing: transesterified oil which has reduced saturated fatty acids and transfat contents, and which provides good properties when used as hard stock for a plastic oil/fat composition; and a plastic oil/fat composition using the transesterified oil/fat. The present invention provides a non-selective transesterified oil/fat in which contents of saturated fatty acid, saturated fatty acid having 12 carbons, and unsaturated fatty acid in the constituent fatty acids are adjusted. 1. A non-selective transesterified oil in which a content of saturated fatty acids in constituent fatty acids is 70 to 85 weight % , a content of saturated fatty acids having 12 carbon atoms (hereinafter referred to as C12) is less than 10 weight % , and a content of unsaturated fatty acids in constituent fatty acids is 15 to 30 weight %.2. The non-selective transesterified oil according to claim 1 ,wherein a content of monounsaturated fatty acids having 18 carbon atoms (hereinafter referred to as C18:1) is 10 to 25 weight %.3. The non-selective transesterified oil according to claim 1 , [{'br': None, '0.2≤C16/C18≤2.0'}, {'br': None, '5.0≤C16/C22≤30.0'}, {'br': None, '5.0≤C_C18/C22.'}], 'wherein compositional ratios between saturated fatty acids having 16 carbon atoms (hereinafter referred to as C16), saturated fatty acids having 18 carbon atoms (hereinafter referred to as C18), and saturated fatty acids having 22 carbon atoms (hereinafter referred to as C22) satisfy all of the following formulae4. The non-selective transesterified oil according to claimwherein a rising melting point is 45 to 60° C.5. A plastic oil and fat composition claim 1 , containing 30 to 5 weight % of the non-selective transesterified oil according to claim 1 , and 70 to 95 weight % of a liquid oil.6. The plastic oil and fat composition according to claim 5 ,wherein a content of saturated fatty acids in the plastic oil and fat composition is 25 weight % or less.7. The ...

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Номер записи: 38
10-03-2022 дата публикации

SOLVENT EXTRACTION OF OIL FROM DISTILLERS DRIED GRAINS AND METHODS OF USING EXTRACTION PRODUCTS

Номер: US20220073824A1
Автор: Bruinsma Keith, Endres Donald, Furcich Steven J.
Принадлежит:

A process for extraction of crude oil from distillers dried grain solubles and/or distillers dried grains using a solvent extraction process and producing corn distillers meal that may be used as an animal feed supplement is disclosed. The corn distillers meal may be used as a crude protein supplement for use in a livestock feed diet, poultry feed diet, aquatic feed diet or the like. The solvent extracted crude oil may be suitable for other processes, including oleochemical processing for personal care and home care products, biodiesel production, and/or renewable diesel production from hydro-treating the extracted oil to make green diesel fuel. 125-. (canceled)26. A method of producing renewable fuel from crude corn oil produced from at least one by-product of a dry-grind ethanol process , the method comprising:solvent extracting crude corn oil from a by-product produced in a dry-grind ethanol process with a non-polar solvent, the at least one by-product comprising distillers dried grains with solubles, distillers dried grains, or a combination thereof, wherein the crude corn oil comprising free fatty acids in an amount ranging from about 1% to about 15% by weight of the crude corn oil, and the crude corn oil having a residual level of the non-polar solvent in an amount from about 1 ppm to about 500 ppm;pretreating the crude corn oil prior to a conversion process, wherein the pretreatment comprises degumming the crude corn oil to separate and remove a gum portion from the crude corn oil portion;drying the crude corn oil portion under vacuum to a desired water content; andsubjecting the dried crude corn oil portion to a conversion process to produce the renewable fuel.27. The method of claim 26 , further comprising washing the crude corn oil portion with water to remove one or more impurities from the crude corn oil portion prior to the drying process.28. The method of claim 26 , further comprising filtering the dried crude corn oil portion with one or more ...

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Номер записи: 39
10-03-2022 дата публикации

Processes and Systems for Catalytic Manufacture of Wax Ester Derivatives

Номер: US20220073957A1
Автор: Addy Jeff, BROWN James H., Daly Clay
Принадлежит:

Processes for transesterifying wax esters. Implementations may include: providing a feedstock including wax esters, contacting the feedstock with a lipase, and catalytically transesterifying the wax esters in the feedstock with the lipase to form a transesterified product. An oxidative stability index (OSI) of the transesterified product may be greater than an OSI of the feedstock. 1. A transesterified wax ester composition comprising:a mixture of jojoba wax esters and tocopherolswherein the composition comprises no methyl esters.2. The composition of claim 1 , wherein the mixture does not comprise free fatty alcohols.3. The composition of claim 1 , wherein the mixture comprises 98% by weight of jojoba wax esters.4. The composition of claim 1 , further comprising a skin conditioning agent selected from the group consisting of steryl esters claim 1 , sterols claim 1 , hydrocarbons claim 1 , and mixtures thereof.4. The composition of claim 1 , wherein the jojoba wax esters comprise hydrogenated wax esters.5. The composition of claim 1 , wherein an oxidative stability index of the mixture is greater than that of jojoba oil.6. The composition of claim 1 , wherein an composition comprises at least 98% by weight jojoba wax esters.7. A transesterified wax ester composition comprising:a mixture of jojoba wax esters, hydrogenated jojoba wax esters, and tocopherols;wherein 30%-50% by weight of the jojoba wax esters are monounsaturated wax esters.8. The composition of claim 7 , wherein the mixture does not comprise alcohols.9. The composition of claim 7 , further comprising a skin conditioning agent selected from the group consisting of steryl esters claim 7 , sterols claim 7 , hydrocarbons claim 7 , and mixtures thereof.10. The composition of claim 7 , wherein an composition comprises at least 98% by weight jojoba wax esters.11. The composition of claim 7 , wherein an oxidative stability index of the mixture is greater than that of jojoba oil.12. The composition of claim 7 , ...

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Номер записи: 40
10-03-2016 дата публикации

Non-lauric non-trans fat composition for chocolate coating

Номер: US20160066594A1
Автор: Hideki Motoike, Tomoko Fujita
Принадлежит: Fuji Oil Co Ltd

Provided is a non-lauric non-trans fat composition for chocolate coating that has the drying time, gloss, difficulty in peeling from a coated item, and sweating resistance required for chocolate coating use. Moreover, the non-lauric non-trans fat composition for chocolate coating enables a novel composite food having a soft texture that has not been obtainable by a conventional fat composition for chocolate coating to be obtained. The non-lauric non-trans fat composition for chocolate coating contains a fat having a specific fatty acid composition and having a rising melting point of 35° C. or higher, and has a specific triglyceride composition.

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Номер записи: 41
10-03-2016 дата публикации

Method for Preparation of a Group 4 Metal Silicate and Use Thereof

Номер: US20160067693A1
Автор: Brandts Jim Aloysius Maria, Wagemaker Lorianne
Принадлежит: BASF CORPORATION

The invention provides a method for the preparation of an amorphous silicate of at least one metal from the Group 4 of the Periodic Table of Elements with a total pore volume of at least 0.3 mL/g. The method of preparation involves the use of pore shaping conditions, which can be the use of a pore shaper and optionally an increased precipitation temperature, e.g. at least 60° C. The silicate of the invention is especially suitable in catalytic reactions such as esterifications, Michael additions, transesterifications, (ep)oxidations, hydroxylations, or in adsorbance of small inorganic and organic molecules e.g. COor aromatic compounds. 113-. (canceled)15. The method according to claim 14 , wherein the pore shaping conditions further consists of the use of a temperature of at least 60° C. during the precipitation in step (b).16. The method according to claim 14 , wherein the pore shaper is a soluble salt of M claim 14 , wherein M is selected from the group consisting of a proton claim 14 , ammonium claim 14 , a metal cation and combinations thereof.17. The method according to claim 16 , wherein M is selected from the group consisting of a proton claim 16 , ammonium claim 16 , Na claim 16 , Li claim 16 , K claim 16 , Cs claim 16 , Ca claim 16 , Mg claim 16 , Sr claim 16 , Ba claim 16 , Fe claim 16 , Sn claim 16 , Ce claim 16 , La claim 16 , Nb claim 16 , Ni claim 16 , V claim 16 , W claim 16 , Mo claim 16 , Al claim 16 , Ag claim 16 , Zn claim 16 , Cu claim 16 , Mn cations claim 16 , and combinations thereof.18. The method according to claim 14 , wherein said non-halide salt is selected from the group consisting of phosphate claim 14 , biphosphate claim 14 , phosphite claim 14 , biphosphite claim 14 , sulfate claim 14 , bisulfate claim 14 , sulfite claim 14 , bisulfite claim 14 , nitrate claim 14 , nitrite claim 14 , carbonate claim 14 , bicarbonate claim 14 , formate claim 14 , acetate and citrate.19. The method according to claim 14 , wherein T is selected from the ...

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Номер записи: 42
10-03-2016 дата публикации

Preparation of lactylates directly from oil

Номер: US20160068783A1
Автор: KOK Symone, Verkuijl Bastiaan Jeroen Victor
Принадлежит:

A process includes the transesterification of a fatty acid triglyceride ester with a salt of hydroxycarboxylic acid without making use of organic solvents. The process can carried out with natural oils as starting material and produces a mixture of medium chain mono and diglycerides and medium chain esters of hydroxycarboxylic acid. 1. A process for the preparation of a salt of a fatty acid ester of hydroxycarboxylic acid which comprises heating an oil , comprising a triglyceride fatty acid ester in admixture with a salt of hydroxycarboxylic acid and a catalyst at a temperature at or above the melting temperature of the salt of hydroxycarboxylic acid and subjecting the mixture to ester interchange.2. The process according to wherein the temperature is kept between 150 and 220° C.3. The process of wherein the temperature is kept between 180 and 200° C.4. The process of wherein said hydroxycarboxylic acid is lactic acid.5. The process of wherein the salt of hydroxycarboxylic acid is sodium lactate.6. The process of wherein said catalyst is alkaline-OR wherein R is H or Mc.7. The process of wherein said catalyst is alkaline-OR wherein R is Me.8. A process according to wherein the natural oil is coconut oil.9. A process according to wherein the natural oil is palm kernel oil.10. The process of wherein the molar ratio of salt of hydroxycarboxylic acid to the triglyceride fatty acid ester is from 10-0.5.11. The process according to and further comprising adding a surfactant during the ester interchange a surfactant.12. The process according to wherein the surfactant is added in an amount ranging from 0-20% on a mass basis as compared to the starting materials.13. A process according to wherein in addition to the salt of a fatty acid ester of hydroxycarboxylic acid mono- and di-fatty acid esters of glycerol are produced.14. The process of and further comprising using the product prepared according to for home and personal care.15. The process according to and further ...

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Номер записи: 43
16-03-2017 дата публикации

Fat Composition and Fat Blend

Номер: US20170071224A1
Автор: Bhaggan Krishnadath, Dekker Willem, Ma Jun, Werleman Jeanine
Принадлежит: Loders Croklaan B.V.

A fat composition comprises: greater than 75% by weight palmitic acid and stearic acids; from 1 to 25% by weight oleic acid; and greater than 20% by weight of combined PSt and PSttriglycerides, wherein P is palmitic acid and St is stearic acid; wherein the fat composition has a weight ratio of PSt:PPP triglycerides of greater than 0.5. 1. A fat composition comprising:greater than 75% by weight palmitic acid and stearic acids;from 1 to 25% by weight oleic acid; and{'sub': '2', 'greater than 20% by weight of combined P2St and PSttriglycerides, wherein P is palmitic acid and St is stearic acid;'}{'sub': '2', 'wherein the fat composition has a weight ratio of PSt:PPP triglycerides of greater than 0.5.'}2. The fat composition as claimed in comprising greater than 55% by weight in total of the triglycerides PPP claim 1 , PSt and PSt2 claim 1 , wherein P is palmitic acid and St is stearic acid claim 1 , preferably greater than 58% by weight claim 1 , most preferably from 60 to 70% by weight.3. The fat composition as claimed in comprising from 10% to 60% by weight of stearic acid.4. The fat composition as claimed in comprising from 5 to 20% by weight of oleic acid.5. A fat blend comprising from 0.5 to 10% by weight of the fat composition of and from 90 to 99.5% by weight of one or more other fats.6. The fat blend as claimed in comprising at least 80% by weight of a lauric fat component.7. The fat blend as claimed in claim 6 , wherein the lauric fat component is selected from the group consisting of coconut oil claim 6 , palm kernel oil claim 6 , fractions of coconut oil claim 6 , fractions of palm kernel oil claim 6 , and mixtures thereof.8. The fat blend as claimed in comprising at least 30% by weight of one or more non-hydrogenated palm fractions.9. The fat blend as claimed in claim 8 , wherein the non-hydrogenated palm fraction is a palm olein.10. A process for making the fat composition of comprising the following steps:(a) providing a palm oil stearin having an iodine ...

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Номер записи: 44
05-06-2014 дата публикации

CONJUGATED LINOLEIC ACID RICH VEGETABLE OIL PRODUCTION FROM LINOLEIC RICH OILS BY HETEROGENEOUS CATALYSIS

Номер: US20140154393A1
Автор: Proctor Andrew, SHAH Utkarsh
Принадлежит: BOARD OF TRUSTEES OF THE UNIVERSITY OF ARKANSAS

The invention is generally directed to conjugated linoleic acid (CLA)-rich vegetable oil production from linoleic rich oils by heterogeneous catalysis. A heterogeneous catalytic vacuum distillation process is used under high temperature conditions to isomerize linoleic acid in triacylglyceride vegetable oils to CLA to produce CLA-rich oils. After processing, the catalyst may be removed by filtration or centrifugation to obtain high quality, CLA-rich oils. The CLA-rich oils may then serve as a potent and bioactive nutraceutical and can be incorporated into various food products, such as a CLA-rich dressing, margarine or chips. 1. A process for producing conjugated linoleic acid-rich oil , said process comprising the steps of:a. mixing a linoleic acid-rich oil with a catalytic amount of a transition metal to form an oil-catalyst mixture; andb. catalysis of said oil-catalyst mixture to produce said conjugated linoleic acid-rich oil.2. The process of further comprising the step of extracting said metal from said conjugated linoleic acid-rich oil.3. The process of further comprising the step of extracting said metal from said conjugated linoleic acid-rich oil via filtration or centrifugation.4. The process of wherein said linoleic acid-rich oil is a triacylglyceride vegetable oil.5. The process of wherein said triacylglyceride vegetable oil is selected from the group consisting of soy claim 4 , sunflower claim 4 , corn claim 4 , cottonseed or peanut oil.6. The process of wherein said transition metal is selected from the group consisting of ruthenium claim 44 , rhodium claim 44 , molybdenum claim 44 , palladium claim 44 , gold claim 44 , silver claim 44 , copper claim 44 , iron claim 44 , manganese or nickel.7. The process of wherein said transition metal is ruthenium or nickel.8. The process of wherein said catalysis step further comprises catalysis of said oil-catalyst mixture in low pressure conditions and high temperature conditions to produce said conjugated ...

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Номер записи: 45
12-06-2014 дата публикации

Hydroconversion of renewable feedstocks

Номер: US20140163249A1
Автор: Alexander E. Kuperman, Cong-Yan Chen, Theodorus Ludovicus Michaael Maesen, William James Cannella
Принадлежит: Chevron USA Inc

A hydroconversion process comprises contacting a feedstock comprising renewable materials under hydroprocessing conditions with a promoted catalyst selected from a self-supported catalyst, a supported catalyst and combinations thereof, wherein the reaction conditions can be tailored to directly convert the renewable feedstock to the desired product(s) including fatty alcohols, esters, normal paraffins, or combinations thereof. The catalyst comprising at least a Group VIB metal selected from molybdenum and tungsten, a Group VIII metal selected from cobalt and nickel to convert the feedstock into any of fatty alcohols, esters, and normal paraffins. In some embodiments, the process further comprising additional steps to generate various desirable products, including α-olefins (or PAO, by dehydrating the fatty alcohol products), lubricants and bright stocks (from the oligomerizing of the PAO), and Group 3 lubricants (from co-oligomerizing of the PAO with some short chain olefins).

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Номер записи: 46
12-03-2020 дата публикации

PROCESSES FOR PRODUCING INDUSTRIAL PRODUCTS FROM PLANT LIPIDS

Номер: US20200080022A1
Автор: El Tahchy Anna, Leita Benjamin Aldo, Liu Qing, Petrie James Robertson, Reynolds Kyle, Singh Surinder Pal, Vanhercke Thomas
Принадлежит: Commonwealth Scientific and Industrial Research Organisation

The present invention relates to methods of producing industrial products from plant lipids, particularly from vegetative parts of plants. In particular, the present invention provides oil products such as biodiesel and synthetic diesel and processes for producing these, as well as plants having an increased level of one or more non-polar lipids such as triacylglycerols and an increased total non-polar lipid content. In one particular embodiment, the present invention relates to combinations of modifications in two or more of lipid handling enzymes, oil body proteins, decreased lipid catabolic enzymes and/or transcription factors regulating lipid biosynthesis to increase the level of one or more non-polar lipids and/or the total non-polar lipid content and/or mono-unsaturated fatty acid content in plants or any part thereof. In an embodiment, the present invention relates to a process for extracting lipids. In another embodiment, the lipid is converted to one or more hydrocarbon products in harvested plant vegetative parts to produce alkyl esters of the fatty acids which are suitable for use as a renewable biodiesel fuel. 2. The process of claim 1 , which is characterised by one or more or all of:(i) the vegetative plant parts have a dry weight of at least 1 kg,(ii) the vegetative plant parts have a total non-polar lipid content of at least 10%, at least 15%, at least 20%, about 25%, about 30%, about 35%, or between 30% and 75% on a dry weight basis,(iii) the composition has a solids concentration between 5% and 90%(iv) the catalysts comprises NaOH or KOH or both, preferably at a concentration of 0.1M to 2M,(v) the treatment time is between 1 and 60 minutes, preferably between 10 and 60 minutes, preferably between 15 and 30 minutes,(vi) if the solvent is water the process produces a yield of the oil product between a minimum of 36%, 37%, 38%, 39% or 40% and a maximum of 55% or 60% by weight relative to the dry weight of the vegetative plant parts,(vii) if the ...

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Номер записи: 47
05-05-2022 дата публикации

Hydroxy fatty acid synthesis

Номер: US20220135902A1
Автор: Benjamin A. LOWERY, Steven C. Cermak, Terry ISBELL
Принадлежит: US Department of Agriculture USDA

The invention relates to methods for the synthesis of hydroxy fatty acids from unsaturated fatty acids via epoxidation and catalytic hydrogenation.

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Номер записи: 48
26-03-2020 дата публикации

METHOD FOR PREPARING LOW-SULFUR BIODIESEL

Номер: US20200095511A1
Автор: JI Jianbing, LIANG Xiaojiang, LU Meizhen, NIE Yong, SU Yanbin, XIA FAN, XIE Qinglong
Принадлежит: Zhejiang University of Technology

The present invention relates to a method for preparing low-sulfur biodiesel. The method includes the following steps: subjecting raw crude oil to heat exchange, preheating, glycerol esterification reaction, flashing, cooling, transesterification, dealcoholization, sedimentation, and methyl ester rectification to obtain low-sulfur biodiesel up to the standard, where in the heat exchange process, the raw crude oil exchanges heat with flashed oil to recycle some heat, and glycerol and fatty acids in a distilled product subjected to flashing are reused for the glycerol esterification reaction; the dealcoholization process removes methanol in a system after the transesterification, and refined methanol recycled by methanol rectification is reused for the transesterification reaction; crude glycerol generated in the sedimentation process does not need to be treated and is directly used for glycerol rectification to obtain refined glycerol, and the refined glycerol is reused for the glycerol esterification reaction. 1. A method for preparing low-sulfur biodiesel , comprising the following steps: subjecting raw crude oil to heat exchange , preheating , glycerol esterification reaction , flashing , cooling , transesterification , dealcoholization , sedimentation , methyl ester rectification to obtain low-sulfur biodiesel up to the standard , wherein in the heat exchange process , the raw crude oil exchanges heat with flashed oil to recycle some heat , and glycerol and fatty acids in a distilled product subjected to flashing are reused for the glycerol esterification reaction; the dealcoholization process removes methanol in a system after the transesterification , and refined methanol recycled by methanol rectification is reused for the transesterification reaction; crude glycerol generated in the sedimentation process is subjected to glycerol rectification to obtain refined glycerol , and the refined glycerol is reused for the glycerol esterification reaction;wherein in ...

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Номер записи: 49
21-04-2016 дата публикации

METHOD OF PRODUCING ESTOLIDE USING LINKING AGENT

Номер: US20160108343A1
Автор: Jeon Hee Jung, Kim Yong Woo, Lee Jong Su
Принадлежит:

Disclosed is a method of producing an estolide, including a) converting biomass-derived oil into a fatty acid mixture, b) separating the fatty acid mixture into a C16 saturated fatty acid and a C18 unsaturated fatty acid, c) converting the C16 saturated fatty acid into a C15 or C16 linear internal olefin, d) subjecting the C15 or C16 linear internal olefin to an estolide reaction using a linking agent, thus obtaining an estolide A, e) subjecting the C18 unsaturated fatty acid to partial hydrogenating to increase the amount of oleic acid, and f) subjecting the oleic acid to an estolide reaction using a linking agent and then esterification, thus obtaining an estolide B. 1. A method of producing an estolide , comprising:a) converting biomass-derived oil into a fatty acid mixture;b) separating the fatty acid mixture into a C16 saturated fatty acid and a C18 unsaturated fatty acid;c) converting the C16 saturated fatty acid into a C15 or C16 linear internal olefin;d) subjecting the C15 or C16 linear internal olefin to an estolide reaction using a linking agent thus obtaining an estolide A;e) subjecting the C18 unsaturated fatty acid to partial hydrogenating to increase an amount of oleic acid; andf) subjecting the oleic acid to an estolide reaction using a linking agent and then esterification, thus obtaining an estolide B.2. The method of claim 1 , wherein the linking agent is dicarboxylic acid claim 1 , tricarboxylic acid claim 1 , or polycarboxylic acid.3. The method of claim 1 , wherein the linking agent is linear dicarboxylic acid or branched dicarboxylic acid.4. The method of claim 1 , wherein the linking agent is oxalic acid claim 1 , malonic acid claim 1 , succinic acid claim 1 , glutaric acid claim 1 , adipic acid claim 1 , pimelic acid claim 1 , suberic acid claim 1 , azelaic acid claim 1 , sebacic acid claim 1 , or 1-decanoic acid.5. The method of claim 1 , wherein the subjecting the C18 unsaturated fatty acid to partial hydrogenating comprises converting ...

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Номер записи: 50
21-04-2016 дата публикации

PROCESS AND SYSTEM FOR PRODUCING A FATTY ACID ALKYL ESTER

Номер: US20160108344A1
Автор: BOFFITO DARIA CAMILLA, EDAKE MAHESH, NEAGOE CRISTIAN, Patience Gregory
Принадлежит:

A process and a system for producing a fatty acid alkyl ester from an alcohol and a feedstock containing transesterifiable lipids are provided. 2. The process of claim 1 , wherein the gaseous alcohol and/or the gaseous ether and/or the gaseous feedstock are provided by atomization of the alcohol and/or the ether and/or the feedstock claim 1 , respectively claim 1 , preferably by atomization of a liquid mixture of the feedstock with the alcohol and/or the ether.3. The process of claim 2 , wherein the atomization is carried out using an atomizer nozzle and an inert atomization gas.4. The process of claim 3 , wherein the atomization gas is carbon monoxide and/or dioxide claim 3 , methane claim 3 , ethane claim 3 , water vapour claim 3 , nitrogen claim 3 , oxygen claim 3 , nitrous oxides claim 3 , hydrogen claim 3 , ethylene claim 3 , or a noble gas claim 3 , preferably nitrogen or argon.5. The process of any one of to claim 3 , wherein the alcohol and/or the ether and/or the feedstock or the liquid mixture is heated before atomization.6. The process of claim 5 , wherein the alcohol and/or the ether and/or the feedstock or the liquid mixture is at a temperature between about 25 and about 500° C. claim 5 , preferably between about 40 and about 70° C. claim 5 , before atomization.7. The process of any one of to claim 5 , wherein the alcohol is a Caliphatic linear or branched alcohol optionally substituted by an aryl or heteroaryl group.8. The process of claim 7 , wherein the alcohol is one or more of methanol claim 7 , ethanol claim 7 , propanol claim 7 , butanol claim 7 , hexanol claim 7 , heptanol claim 7 , octanol claim 7 , nonanol claim 7 , decanol claim 7 , benzyl alcohol claim 7 , iso-butyl alcohol claim 7 , n-butyl alcohol claim 7 , 2-ethyl hexanol claim 7 , furfuryl alcohol claim 7 , iso-propyl alcohol claim 7 , or n-propyl alcohol claim 7 , preferably methanol or ethanol claim 7 , and more preferably methanol.9. The process of any one of to claim 7 , wherein the ...

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Номер записи: 51
10-07-2014 дата публикации

Method for preparing high purity biodiesel

Номер: US20140194634A1
Автор: Lu Xinuo
Принадлежит: BEIJING QINGYANLIHUA PETROLEUM CHEMISTRY CO., LTD.

Disclosed is a method for preparing high purity biodiesel from crude oils. The method comprises the steps of: pre-treating the crude oil raw material to remove impurities; pre-esterifying the pre-treated crude oil raw material under the effect of a catalyst of concentrated sulfuric acid; and then carrying out an ester exchange reaction in the presence of an alkali catalyst; recycling methanol, and separating glycerol, so as to obtain a crude fatty acid methyl ester; and subjecting the obtained fatty acid methyl ester to purification, distillation and segmentation to obtain a high-purity fatty acid methyl ester. 1. A method for preparing biodiesel from crude oils , comprising:1) providing crude oil raw material, and pre-treating the crude oil raw material to remove impurities;2) adding the pre-treated raw material into a reaction kettle;3) pre-esterification step: adding methanol and 0.1-2 wt % concentrated sulfuric acid by the weight of the pre-treated raw material into the reaction kettle, and maintaining at 70-100° C., preferably 70-80° C., for 30 min-2 h, wherein the weight ratio of methanol to the pre-treated raw material is (1:1)-(1:20);4) esterification step of vapor phase: heating the above reaction system to 110-130° C., supplementing vapor phase methanol from the bottom of the reaction kettle under atmospheric pressure, reacting under the temperature until the acid value of liquid phase system is ≦2, and stopping supplementing methanol;5) ester exchange step: cooling the reaction material obtained in the step 4) to below 70° C., adding mixture of potassium hydroxide and sodium hydroxide withequal weight ratio in the same reaction kettle to maintain pH of the reaction material in the reaction kettle at 8-9, and then reacting at 70-90° C., preferably 70-80° C., for 2-3 h;6) recycling methanol, and separating glycerol via gravity settling, so as to obtain a crude fatty acid methyl ester; and7) subjecting the crude fatty acid methyl ester obtained in the step 6 ...

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Номер записи: 52
27-04-2017 дата публикации

A Process For The Preparation of Fatty Acid Alkyl Esters

Номер: US20170113996A1
Автор: Ketav Kulkarni, Patrick Perlmutter, Reno Emilio Beltrame
Принадлежит: Southern Biofuel Technology Pty Ltd

The present invention broadly relates to a process for preparing fatty acid alkyl esters from fat-containing feedstocks using sulfonated fatty acid catalysts.

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Номер записи: 53
13-05-2021 дата публикации

INTERESTERIFIED HIGH OLEIC VEGETABLE OILS

Номер: US20210139812A1
Автор: Goertz Marvin, Pan Shawn
Принадлежит:

The present invention provides for interesterified high oleic vegetable oil and vegetable fat characterized by low trans fat content and characteristics suitable for use in baking, frying and icing applications. 1. A composition comprising interesterified high oleic vegetable oil and vegetable fat wherein the interesterified high oleic vegetable oil and vegetable fat has a Mettler drop point of from 40° C. to 53° C. and a trans fat content of no more than 1% , wherein the interesterified high oleic vegetable oil and vegetable fat is characterized by a solid fat content as measured by AOCS Cd 16b-93 of one or more of:(i) a solid fat content at 10° C. of from about 30 to about 48;(ii) a solid fat content at 21.1° C. of from about 20 to about 35;(iii) a solid fat content at 26.7° C. of from about 12 to about 22;(iv) a solid fat content at 33.3° C. of from about 6 to about 14; and(v) a solid fat content at 40° C. of from about 2 to about 8.2. The composition of wherein the composition is a shortening.3. The composition of wherein the shortening is any of icing shortening claim 2 , cake and icing shortening claim 2 , all purpose shortening claim 2 , cookie shortening claim 2 , or pie shortening.4. The composition of having a Mettler drop point of from 40° C. to about 50° C.56-. (canceled)7. The composition of further comprising at least one other oil claim 1 , wherein the composition is a blend of: (i) the interesterified high oleic vegetable oil and vegetable fat; and (ii) at the least one other oil claim 1 ,wherein the at least one other oil is selected from hard fats, liquid oils, and combinations thereof, wherein the hard fat content is from about 0.1 to about 10 wt. %,wherein the hard fat is selected from fully hydrogenated cotton, fully hydrogenated soy, fully hydrogenated palm, palm stearine, and combinations thereof, andwherein the liquid oil is selected from soy, high oleic soy, canola, high oleic canola, palm, and combinations thereof, and wherein the liquid ...

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Номер записи: 54
13-05-2021 дата публикации

COMPOSITION CONTAINING HIGHLY UNSATURATED FATTY ACID OR ALKYL ESTER THEREOF AND A METHOD FOR PRODUCING THE SAME

Номер: US20210139813A1
Автор: Doisaki Nobushige, FURIHATA Kiyomi, YAMAGUCHI Hideaki
Принадлежит: NIPPON SUISAN KAISHA, LTD.

PROBLEM To provide a composition comprising highly enriched PUFA or its alkyl esters while containing fatty acid esters of 3-MCPD at adequately low concentrations and to provide an efficient method for producing the composition. 111.-. (canceled)12. A method for producing a composition containing a highly unsaturated fatty acid or an alkyl ester thereof , which comprises:(1) alkyl esterifying a raw material containing a triglyceride comprising a highly unsaturated fatty acid as constituent fatty acid to prepare a composition containing a highly unsaturated fatty acid alkyl ester;(2) at least one selected from among (a) reducing to less than 10,000 ppm the concentration of a monoacyl glycerol that comprises as constituent fatty acid a fatty acid that has 5 or more carbon atoms fewer than the highly unsaturated fatty acid that constitutes the highly unsaturated fatty acid alkyl ester to be enriched in the composition prepared in step (1), (b) reducing the iron concentration in the composition prepared in step (1) to less than 0.20 ppm, and (c) reducing the chlorine concentration in the composition prepared in step (1) to less than 10 ppm; and(3) distilling the composition resulting from step (2) and collecting the main distillate fraction.131. The method according to claim , wherein the concentration of 3-MCPD as found upon analyzing the main distillate fraction from step (3) by American Oil Chemists' Society official method Cd 29b-13 assay A is less than 1.80 ppm.141. The method according to claim , wherein step (2)(a) is performed by silica gel chromatography.15. The method according to claim 12 , wherein distillation in step (3) is rectification.16. The method according to claim 12 , wherein the concentration of monoacyl glycerol comprising as the constituent fatty acid a fatty acid that has 6 carbon atoms fewer than the highly unsaturated fatty acid that constitutes the highly unsaturated fatty acid alkyl ester to be enriched is reduced to less than 10 claim 12 , ...

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Номер записи: 55
04-05-2017 дата публикации

TRANS FREE AND LOW SATURATED FAT COCOA BUTTER ALTERNATIVE

Номер: US20170119008A1
Автор: Cruz Serna Adriana Fernanda
Принадлежит:

A cocoa butter alternative and the method of making thereof that includes 62-84% saturated fatty acid content having 20-40%) lauric acid content, 8-20% myristic acid content, 9-37% palmitic acid content, and 3-17% stearic acid content. The fat may include 16-38%) unsaturated fatty acid content including 15-30% oleic acid content, 10% linoleic acid content; and 4% linolenic acid content and 28-95%) of interesterified fat mixture of lauric and non-lauric vegetable oils. The fat mixture may include 40-60% of palm kernel oil, coconut oil, or fractions thereof and 40-60% of palm oil or fractions. The fat may include 2-40% of vegetable oil such as sunflower, safflower, low erucic rapeseed, canola, soy bean, high oleic sunflower, high oleic safflower, high oleic rapeseed, high oleic canola, high oleic soy bean, palm fractions, hybrid palm, or olive oils and 5-40% of lauric hard fat such as palm kernel or coconut oil or fractions thereof. 1. A fat comprising: (a) 20% to 40% lauric acid content,', '(b) 8% to 20% myristic acid content,', '(c) 9% to 37% palmitic acid content, and', '(d) 3% to 17% stearic acid content;, 'wherein the saturated fatty acid content of the fat comprises, '(i) 62% to 84% saturated fatty acid content, based on a total amount of fatty acids in the fat,'} (a) 15% to 30% oleic acid content,', '(b) 10% or less linoleic acid content; and', '(c) 4% or less linolenic acid content;, 'wherein the unsaturated fatty acid content of the fat comprises, '(ii) 16% to 38% unsaturated fatty acid content, based on the total amount of fatty acids in the fat,'} [ 'wherein the palm kernel oil, the one or more fractions of the palm kernel oil, the coconut oil, and the one or more fractions of the coconut oil have an iodine value of 9 or less, and', '(a) 40% to 60% of at least one of a palm kernel oil, one or more fractions of the palm kernel oil, coconut oil, or one or more fractions of the coconut oil, based on a total weight of the fat mixture,'}, 'wherein the palm′ oil ...

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Номер записи: 56
27-05-2021 дата публикации

USE OF HYPOPHOSPHOROUS ACID FOR THE ESTERIFICATION OF FREE FATTY ACIDS

Номер: US20210155870A1
Автор: Laffitte Jean-Alex
Принадлежит: Arkema France

The use of hypophosphorous acid as a corrosion inhibitor for esterification reactions of free fatty acids contained in a fatty substance is described, particularly in the presence of an organosulfonic acid. The invention also relates to a method for the esterification of fatty acids. 1. Use of hypophosphorous acid as a corrosion inhibiter for esterification reactions of free fatty acids , in the presence of an organosulfonic acid.2. Use according to claim 1 , wherein the organosulfonic acid is of formula R-503H claim 1 , wherein R represents a saturated hydrocarbon chain claim 1 , linear or branched claim 1 , including 1 to 4 carbon atoms claim 1 , or an aryl radical optionally substituted by a saturated hydrocarbon chain claim 1 , linear or branched claim 1 , including 1 to 4 carbon atoms claim 1 , and optionally substituted claim 1 , in whole or in part claim 1 , by one or more halogen atoms claim 1 , identical or different.3. Use according to claim 1 , wherein the organosulfonic acid is chosen from methanesulfonic acid claim 1 , paratoluenesulfonic acid and a mixture thereof.4. A composition comprisinghypophosphorous acid, andan organosulfonic acid,said acids being in a ratio by mass of hypophosphorous acid to organosulfonic acid ranging from 0.01 to 0.4, andoptionally an aqueous diluent, organic, or hydroorganic, andoptionally one or more additives.5. The composition according to claim 4 , comprising:from 1% to 20% by weight of the hypophosphorous acid with respect to the total weight of hypophosphorous acid and sulfonic acid, andfrom 80% to 99% by weight of the organosulfonic acid and derivatives thereof with respect to the total weight of hypophosphorous acid and organosulfonic acid.6. A method for the esterification of fatty acids claim 4 , comprising the following successive steps:(a) providing a fatty substance comprising from 1% to 100% by weight of at least one fatty acid;(b) adding at least one alcohol;{'claim-ref': {'@idref': 'CLM-00004', 'claim 4'}, '( ...

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Номер записи: 57
03-06-2021 дата публикации

Preparation method and system of low-carbon jet biofuel based on whole life cycle

Номер: US20210163876A1
Автор: Xiaoyi Yang, Ziyu Liu
Принадлежит: BEIHANG UNIVERSITY

Disclosed are a preparation method and a system of low-carbon jet biofuel based on whole life cycle. A low-carbon method and a system of using whole life cycle involving whole process from raw material acquisition, fuel preparation to fuel application are related. A prepared jet biofuel can be used in six types of aircrafts and engines thereof. Aircrafts using the jet biofuel can have a portion of greenhouse gas emission reduction of 50% to 80%.

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Номер записи: 58
26-05-2016 дата публикации

Process for Producing Biodiesel and Related Products

Номер: US20160145516A1
Автор: SCOTT Michael
Принадлежит: Argent Energy Group Limited

There is described a process for producing biodiesel and related products from mixtures. There is also described a process for producing precursors and feedstock materials for producing biodiesel and related products. The processes use esterification and trans-esterification, separation and purification. Other process steps such as acidification and distillation can also be used. 1. A process for producing biodiesel from a mixture , said process comprising the steps of:(i) providing the mixture to a trans-esterification reaction vessel;(ii) introducing trans-esterification conditions to the trans-esterification reaction vessel;(iii) trans-esterifying the triglycerides in the mixture; and 'wherein the first purification of the trans-esterified mixture comprises spraying an aqueous solution, optionally water, onto the surface of the mixture in the trans-esterification reaction vessel, the aqueous solution percolating the mixture and facilitating the removal of impurities therefrom.', '(iv) providing a first purification of the trans-esterified mixture;'}2. A process as claimed in claim 1 , wherein the process comprises the further step of heating the mixture to a reaction temperature for trans-esterification.3. A process as claimed in or claim 1 , wherein the process comprises the further step of maintaining the mixture at a reaction temperature for trans-esterification.4. A process as claimed in or claim 1 , wherein the trans-esterification reaction temperature is between approximately 48° C. and approximately 62° C. claim 1 , optionally between approximately 52° C. and approximately 58° C. claim 1 , optionally approximately 55° C.5. A process as claimed in any preceding claim claim 1 , wherein the amount of FFAs in the mixture before trans-esterification is approximately 3% by weight or less.6. A process as claimed in any preceding claim claim 1 , wherein introducing trans-esterification conditions comprises adding a trans-esterification catalyst claim 1 , ...

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Номер записи: 59
10-06-2021 дата публикации

PROCESS FOR THE PRODUCTION OF OLEFINIC COMPOUNDS AND A HYDROCARBON FUEL OR A FRACTION THEREOF

Номер: US20210171420A1
Автор: Bosetti Aldo, GIROTTI Gianni, Lombardini Sergio Francantonio
Принадлежит: Versalis S.p.A.

The present invention relates to a process for the production of olefinic compounds that can be used for the production of detergents, additives, lubricants and/or plastic materials, or components which can be used in the field of oil explorations and productions, and a hydrocarbon fuel or a fraction thereof, which comprises subjecting a mixture of glycerides having at least one unsaturated hydrocarbon chain, to metathesis reaction and, after separating the olefinic mixture obtained, effecting a hydrodeoxygenation and subsequently hydroisomerization process, so as to obtain the hydrocarbon fuel or a fraction thereof. 118-. (canceled)19. A process for producing olefinic compounds and a hydrocarbon fuel or a fraction thereof , the process comprising:{'sub': 2', '6', '6', '18, '(a) subjecting to metathesis reaction a mixture of glycerides having at least one unsaturated hydrocarbon chain with at least one C-Cmonoolefin in the presence of a metathesis catalyst, to obtain a mixture of glycerides having at least one unsaturated hydrocarbon chain with a carbon length less than an initial carbon length, and a mixture of C-Colefins;'}{'sub': 6', '18, '(b) separating the mixture of C-Colefins from the mixture of glycerides obtained by step (a);'}(c) subjecting the mixture of glycerides obtained by step (b) to a transesterification reaction with an alcohol selected from the group consisting of methanol, ethanol and mixtures thereof, to obtain a mixture of methyl esters, ethyl esters, or both, and glycerol;(c′) separating the glycerol from the mixture of methyl esters, ethyl esters, or both;and then (c″) separating a stream consisting essentially of methyl esters, ethyl esters, or both, having an unsaturated hydrocarbon chain from methyl esters, ethyl esters, or both, having a saturated hydrocarbon chain in the mixture; and(d) hydrodeoxygenating the stream of the methyl esters, ethyl esters, or both, having a saturated hydrocarbon chain, obtained by step (c″) to produce an ...

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Номер записи: 60
04-06-2015 дата публикации

PROCESS FOR THE PREPARATION OF COMPLEX OLIGOMERIC STRUCTURES

Номер: US20150152354A1
Автор: BORSOTTI Giampietro, Digioia Francesca
Принадлежит: Novamont S.p.A.

The invention relates to a process for the preparation of complex oligomeric structures obtained from vegetable oils. These structures comprise esters containing acid groups which are in turn esterified. 1. Process for the preparation of mixtures of triglyceride comprising one or more of the following oligomeric structures:{'br': None, 'sub': 4', '1', '2', '2', '2', 'n', '3, 'R—[O—C(O)—R—C(O)—O—CH—CH(OR)—CH]—O—R'}wherein{'sub': 1', '2', '22, 'Ris selected from C-Calkylenes,'}{'sub': 2', '6', '24', '6', '24, 'Ris selected from one or more of the following groups consisting of C-Cdicarboxylic acid residues and C-Cmonocarboxylic acid residues,'}{'sub': 3', '6', '24', '6', '24, 'Ris selected from one or more of the following groups consisting of H, C-Cdicarboxylic acid residues and C-Cmonocarboxylic acid residues,'}{'sub': '4', 'Ris an alkyl group,'}n is an integer equal to or greater than 2,{'sub': 6', '24', '2', '3, 'said C-Cdicarboxylic acids of Rand Rbeing esterified with monoalcohols and said mixture of triglycerides having a Number Average Molecular Weight (Mn) of between 800 and 10,000 Da,'}which comprises the step of esterification of a mixture of one or more triglycerides containing saturated dicarboxylic acids with alcohols at temperatures between 50 and 250° C. and which occurs in the absence of catalyst or in the presence of an acid catalyst consisting of one or more phosphorus compounds.2. Process according to claim 1 , wherein said esterification step occurs at temperatures between 60 and 180° C. and in presence of an acid catalyst consisting of one or more phosphorus compounds.3. Process according to claim 2 , wherein said esterification step occurs at temperatures between 80 and 140° C. and in the presence of an acid catalyst consisting of one or more phosphorus compounds.4. Process according to claim 1 , wherein the acid catalyst consisting of one or more phosphorus compounds is selected from: phosphorus containing mineral acids claim 1 , their organic ...

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Номер записи: 61
09-06-2016 дата публикации

CONJUGATED LINOLEIC ACID RICH VEGETABLE OIL PRODUCTION USING HETEROGENEOUS CATALYSIS

Номер: US20160160154A1
Автор: Proctor Andrew, Ruan Chuan Min
Принадлежит:

The invention is directed to CLA-rich vegetable oil production from linoleic rich oils by heterogeneous catalysis. The process produces conjugated PUFA in triglyceride form, preferably at least 20% CLA-rich, by isomerization of a non-conjugated PUFA in vegetable oils using a heterogeneous transition metal catalyst promoted by an organic acid and/or thiol-containing compound. The heterogeneous catalysis isomerization process can use steam/vacuum distillation, hydrogenation unit and/or deodorization to produce CLA-rich soy oil. After processing, any catalyst residue may be removed by filtration, beaching, deodorizing, adsorbents or centrifugation to obtain high quality, CLA-rich oils. 1. A process for producing conjugated linoleic acid-rich oil , said process comprising the steps of:heterogeneously catalyzing a linoleic acid-rich oil and a catalytic amount of a transition metal in the presence of a promoter to produce said conjugated linoleic acid-rich oil.2. The process of wherein said linoleic acid-rich oil is a triacylglyceride vegetable oil.3. The process of wherein said triacylglyceride vegetable oil is selected from the group consisting of soy claim 2 , sunflower claim 2 , corn claim 2 , cottonseed and peanut oil.4. The process of wherein said transition metal is selected from the group consisting of ruthenium claim 1 , rhodium claim 1 , platinum claim 1 , iridium claim 1 , osmium claim 1 , palladium and nickel.5. The process of wherein said transition metal is ruthenium or nickel.6. The process of wherein said nickel is metal nickel claim 5 , nickel sulfide (NiS) or nickel formate Ni(COO).7. The process of wherein said metal nickel is distributed on silica/alumina claim 6 , nickel alloys with iron claim 6 , aluminum claim 6 , chromium and carbon loaded on silica/alumina.8. The process of wherein said nickel is an organic amino or thiol compound self-assembly monolayer modified nickel catalyst.9. The process of wherein said catalytic amount of said nickel ...

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Номер записи: 62
18-06-2015 дата публикации

1,3-SPECIFIC INTRAESTERIFICATION

Номер: US20150164101A1
Автор: Dubinsky Eduardo Pedro, Grondona Martin Oscar, Leon Alberto Javier, Pan Lucas Guillermo, Zambelli Andrés Daniel
Принадлежит: ADVANTA INTERNATIONAL BV

The present invention relates to a method for increasing the SUS content in an oil or in an olein fraction, comprising performing 1,3-selective enzymatic intraesterification on a natural starting oil or olein fraction prepared therefrom wherein the ratio between SUS and SUU is at least 1:1.5 and the SSS content is low, in particular close to 0%. Further, the present invention relates to 1,3-Selective intraesterified oil or olein, obtainable by performing the present method. 1. Method for increasing the SUS content in an oil or in an olein fraction , comprising performing 1 ,3-selective enzymatic intraesterification on a natural starting oil or olein fraction prepared therefrom wherein the ratio between SUS and SUU is at least 1:1.5 and the SSS content is low , in particular close to 0%.2. Method as claimed in claim 1 , wherein the natural starting oil is a single oil extracted from an oil source and not blended with other oils.3. Method as claimed in or claim 1 , wherein the ratio between SUS and SUU is in order of increased preference at least 1:1.5 claim 1 , 1:2 claim 1 , 1:3.5 claim 1 , 1:5 claim 1 , 1:7.5 claim 1 , 1:10 claim 1 , 1:15.4. Method as claimed in or claim 1 , wherein the oil source is sunflower seed claim 1 , soybean claim 1 , cottonseed claim 1 , shea fruits claim 1 , rapeseed.54. Method as claimed in any one of the - claims 1 , wherein the starting oil or olein fraction is high stearic high oleic (HSHO) sunflower oil.64. Method as claimed in any one of the - claims 1 , wherein the starting oil or olein fraction is selected from high stearic high oleic soybean oil claims 1 , high stearic high oleic cottonseed oil and high stearic high oleic rapeseed (canola) oil.74. Method as claimed in any one of the - claims 1 , wherein the starting oil or olein fraction is a tropical oil selected from shea olein and palm olein.8. Method for increasing the stearin yield from a starting oil or starting olein fraction upon fractionation thereof claims 1 , comprising ...

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Номер записи: 63
22-09-2022 дата публикации

PREPARATION METHOD OF EMBEDDED ALKALINE EARTH METAL OXIDE SOLID ALKALI AND APPLICATION THEREOF IN BIODIESEL PRODUCTION

Номер: US20220297107A1
Автор: Cui Ping, Guo Min, LI Guoning, Li Hui, LU Wanpeng, MA Xiaoling, Wang Yongbo, YU Mingzhi, ZHOU Shoujun
Принадлежит:

A method for synthesizing and application embedded alkaline earth metal oxide solid alkali includes: firstly, synthesizing an alkaline earth metal organic skeleton with single or multiple alkaline earth metals (Mg, Ca and Sr) as central metal elements; and then controlling the heating process to carry out high-temperature pyrolysis in a non-oxidizing atmosphere, so that the alkaline earth metal oxide are embedded in the nano carbon sheet to obtain a solid alkali catalyst. Finally, the catalyst is used to catalyze the transesterification of palm oil and methanol to produce biodiesel. The active site of the solid alkali obtained by the method is anchored on the nano-like carbon sheet, so that the active site is directly exposed on the surface of the catalyst, the catalytic activity is improved, the loss of the active site is inhibited, and the stability of the solid alkali catalyst is enhanced. 1. A preparation method of embedded alkaline earth metal oxide solid alkali , characterized by comprising:synthesize an alkaline earth metal organic framework by taking single or multiple alkaline earth metal as that central metal elements;the alkaline earth metal organic framework is pyrolyzed at high temperature in a non-oxidizing atmosphere to form embedded alkaline earth metal oxide solid alkali.2. The preparation method of embedded alkaline earth metal oxide solid alkali according to claim 1 , characterized in that the specific steps of synthesizing alkaline earth metal organic framework include:{'sub': 3', '3', '2, 'uniformly mixing metal source and trimesic acid (HBTC) in the CHCOOH and HO, crystallizing at high temperature and high pressure, and cooling to room temperature to obtain a solid product;'}the solid product was washed for a plurality of time and dry it to obtain alkaline earth metal organic framework.3. The preparation method of embedded alkaline earth metal oxide solid alkali according to claim 1 , characterized in that the specific conditions of the high- ...

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Номер записи: 64
18-06-2015 дата публикации

RANDOM INTRAESTERIFICATION

Номер: US20150166932A1
Автор: Dubinsky Eduardo Pedro, Grondona Martin Oscar, Leon Alberto Javier, Pan Lucas Guillermo, Zambelli Andrés Daniel
Принадлежит: ADVANTA INTERNATIONAL BV

The present invention relates to a method for modifying one or more types of triglycerides in a fat, comprising subjecting a single fat selected from the group consisting of high stearic high oleic sunflower oil, high stearic high oleic soybean oil, high stearic high oleic rapeseed oil, high stearic high oleic cottonseed oil, palm olein and shea olein to an intraesterification process in which the fatty acids of the triglycerides of said oil or fat are randomly redistributed between the triglycerides to obtain an oil or fat with a modified solid fat content (SFC) profile. Further, the present invention relates to the obtained fats and use thereof. 1. Method for modifying one or more types of triglycerides in a fat , comprising subjecting a single oil or fat selected from the group consisting of high stearic high oleic sunflower oil , high stearic high oleic soybean oil , high stearic high oleic rapeseed oil , high stearic high oleic cottonseed oil , palm olein fraction and shea olein fraction to an intraesterification process in which the fatty acids of the triglycerides of said oil or fat are randomly redistributed between the triglycerides to obtain an oil or fat with a modified solid fat content (SFC) profile.2. Method according to claim 1 , wherein the randomly redistribution is carried out by a temperature within the range of 60 to 90° C. claim 1 , preferably 75 to 85° C. claim 1 , in the presence of a sodium methoxide catalyst.3. Method according to claim 1 , wherein the randomly redistribution is carried out by an enzymatic process.4. Triglyceride obtainable by the method as claimed in any of the to .5. Fat obtainable by the method as claimed in any of the to .6. Use of the fat as claimed in in food.7. Use as claimed in claim 6 , wherein the food is selected from the group consisting of margarines claim 6 , spreads claim 6 , coatings claim 6 , fillings claim 6 , confectionery products and cooking oils. The present invention relates to the process of ...

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Номер записи: 65
14-06-2018 дата публикации

PROCESS FOR PRODUCING A SEED SLURRY AND APPARATUS THEREFORE

Номер: US20180160699A1
Автор: Andersen Morten Daugaard, Juul Bjarne
Принадлежит:

A process for producing a seed slurry (SSY) in a seed slurry apparatus (SSA) from solid seed particles (SSP) is disclosed, the seed slurry apparatus (SSA) comprising an input zone (IZ) and a heating zone (HZ), the input zone (IZ) feeding the heating zone (HZ) and the heating zone (HZ) comprising a heating arrangement (HA), said process comprising the steps of feeding the solid seed particles (SSP) from the input zone (IZ) into the heating zone (HZ), the solid seed particles having a seed composition, the seed composition comprising triglycerides, heating said seed composition in said heating zone (HZ) by means of said heating arrangement (HA) to obtain a seed slurry (SSY) at least partly on the basis of partly melted seed composition, wherein said heating involves measuring a seed slurry temperature representation of the seed slurry and said heating is at least partly controlled on the basis of the measured seed slurry temperature representation. Furthermore, a seed slurry apparatus (SSA) and use of a seed slurry (SSY) and a seed slurry apparatus (SSA) is disclosed. 150-. (canceled)51. A method for producing a seed slurry (SSY) in a seed slurry apparatus (SSA) from solid seed particles (SSP) , the seed slurry apparatus (SSA) comprising an input zone (IZ) and a heating zone (HZ) , the input zone (IZ) feeding the heating zone (HZ) and the heating zone (HZ) comprising a heating arrangement (HA) , said method comprising the steps of:feeding the solid seed particles (SSP) from the input zone (IZ) into the heating zone (HZ), the solid seed particles having a seed composition, the seed composition comprising triglycerides,heating said seed composition in said heating zone (HZ) by means of said heating arrangement (HA) to obtain a seed slurry (SSY) at least partly on the basis of partly melted seed composition,wherein said heating involves measuring a seed slurry temperature representation of the seed slurry and said heating is at least partly controlled on the basis of the ...

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Номер записи: 66
25-06-2015 дата публикации

Process for pretreatment of vegetable oils by heterogeneous catalysis of the esterification of fatty acids

Номер: US20150175932A1
Автор: Eszter Toth, Laurent Bournay, Sylvie Maury, Vincent Coupard
Принадлежит: IFP Energies Nouvelles IFPEN

The invention relates to a continuous process for pretreatment of an oil feedstock comprising at most 20% by weight of free fatty acids by esterification of free fatty acids in which a vertical liquid/liquid contactor containing an esterification catalyst in solid form is supplied in counter-current by an alcohol feedstock comprising at least 20% by weight of an alcohol and said oil feedstock, with said contactor being operated at a temperature of between 25 and 120° C., with said contactor performing the contact in liquid-liquid counter-current between a heavy phase and a light phase, with said heavy phase being able to be either an oil-rich phase or an alcohol-rich phase.

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Номер записи: 67
28-05-2020 дата публикации

HYDROGENATED VEGETABLE OIL WITHOUT ANY TRANS FATTY ACIDS

Номер: US20200163356A1
Автор: Keener Kevin Michael, YEPEZ Ximena
Принадлежит: PURDUE RESEARCH FOUNDATION

This present invention generally relates to a process for manufacturing hydrogenated vegetable oil without any significant amount of trans fatty acids for food and feed industry using high voltage atmospheric cold plasma (HVACP) in the presence of a working gas, and in particular to a process for manufacturing hydrogenated vegetable oil that meet the FDA's criteria of GRAS (generally considered as safe). A product of this process is also within the scope of this disclosure. 1. A process for manufacturing a hydrogenated vegetable oil without any significant amount of trans fatty acids using a high voltage atmospheric cold plasma (HVACP) , comprising the steps of:a. preparing vegetable oil;b. setting up a defined compartment filled with a working gas in the presence of water and an electric system for generating atmospheric cold plasma (ACP);c. generating ACP by applying a high electric voltage through a controller; andd. exposing said vegetable oil to said ACP in said defined compartment to afford said hydrogenated vegetable oil without any significant amount of trans fatty acids.2. The process of claim 1 , wherein said ACP is generated by applying an electric voltage from about 5 claim 1 ,000 volts to about 200 claim 1 ,000 volts between two dielectric barriers for a period of time.3. The process of claim 1 , wherein said ACP is generated by applying an electric voltage from about 30 claim 1 ,000 volts to about 120 claim 1 ,000 volts between two dielectric barriers for a period of time.4. The process of claim 1 , wherein said hydrogenated vegetable oil has an iodine value of 100 or lower.5. The process of claim 1 , wherein said working gas is a single or a mixture of combined gases.6. The process of claim 1 , wherein said working gas is air claim 1 , hydrogen claim 1 , nitrogen claim 1 , oxygen claim 1 , carbon dioxide claim 1 , noble gases claim 1 , water claim 1 , or a combination thereof.7. The process of claim 6 , wherein said working gas is air.8. The process ...

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Номер записи: 68
30-06-2016 дата публикации

SOLID, HETEROGENEOUS CATALYSTS AND METHODS OF USE

Номер: US20160185706A1
Автор: Mehta Manish, MISTRY Bharat, Otieno Peter Omolo, Patel Ritesh, SINGH Inder Pal, SINGH Shradha
Принадлежит:

Solid mixed catalysts and methods for use in conversion of triglycerides and free fatty acids to biodiesel are described. A batch or continuous process may be used with the catalysts for transesterification of triglycerides with an alkyl alcohol to produce corresponding mono carboxylic acid esters and glycerol in high yields and purity. Similarly, alkyl and aryl carboxylic acids and free fatty acids are also converted to corresponding alkyl esters. The described catalysts are thermostable, long lasting, and highly active. 1. A method for effecting esterification or transesterification of a starting material , comprising reacting the starting material with an alcohol in the presence of a solid , heterogeneous catalyst.2. The method as in claim 1 , wherein the starting material comprises an oil.3. The method as in claim 1 , wherein the starting material is selected from the group consisting of triglycerides claim 1 , free fatty acids claim 1 , and a mixture thereof.4. The method as in claim 1 , wherein the starting material comprises carboxylic acid.5. The method as in claim 1 , wherein biodiesel or a carboxylic acid ester is produced as a reaction product.6. The method as in claim 1 , wherein the method produces glycerol as a reaction product.7. The method as in claim 1 , wherein soap is not produced as a byproduct of the reaction.8. The method as in claim 1 , wherein the reaction is conducted at temperatures less than 250° C.9. The method as in claim 1 , wherein the reaction is conducted at pressures less than 1000 psi.10. The method as in claim 1 , wherein the reaction is conducted at pressures less than 2000 psi.11. The method as in claim 1 , wherein the reaction is conducted in a batch reactor.12. The method as in claim 1 , wherein the reaction is conducted continuously using a fixed bed reactor.13. The method as in claim 1 , wherein the reaction is conducted in one or more successive stages.14. The method as in as in claim 1 , wherein the reaction is conducted ...

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Номер записи: 69
14-07-2016 дата публикации

INTERESTERIFICATION CATALYST AND PROCESS

Номер: US20160201011A1
Автор: ELLIS Peter Richard, Evans Gary, Zwijnenburg Aalbert
Принадлежит:

A process for the production of an ester product from a mixture of at least two different ester compounds includes the steps of mixing together at least two different starting ester compounds to form a first ester mixture; and contacting the first ester mixture with a catalyst including from 30-60% of calcium oxide and at least one second metal oxide at a temperature of at least 180° C., for a duration of at least one hour, with mixing, to form a second ester mixture having a melting point which is lower than the melting point of the first ester mixture. 1. A process for the production of an ester product from a mixture of at least two different ester compounds comprises the steps of:a) mixing together at least two different starting ester compounds to form a first ester mixture; andb) contacting said first ester mixture with a catalyst comprising from 30-60% of calcium oxide and at least one second metal oxide to form a second ester mixture having a melting point which is lower than the melting point of said first ester mixture.2. A process as claimed in claim 1 , wherein at least one of the starting esters is a triglyceride.3. A process as claimed in claim 1 , wherein at least one of the starting ester compounds comprises an ester of a carboxylic acid containing from 12 to 24 carbon atoms.4. A process as claimed in claim 1 , wherein the catalyst is pre-dispersed in at least one of said starting ester compounds.5. A process as claimed in claim 1 , wherein the second metal oxide is selected from the group consisting of an oxide of a Group 2A metal other than calcium claim 1 , an oxide of a transition metal claim 1 , lanthana claim 1 , silica claim 1 , alumina and a metal aluminate.6. A process as claimed in claim 5 , wherein the second metal oxide comprises magnesium oxide.7. A process as claimed in claim 1 , wherein the catalyst further comprises from 1-5% of an alkali metal.8. A process as claimed in claim 1 , wherein the catalyst has a surface area less than 20 m ...

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Номер записи: 70
12-07-2018 дата публикации

Use of acid anhydride accelerants for the production of high purity polyol esters

Номер: US20180194712A1
Автор: John EUBANKS
Принадлежит: Cargill Inc

A method of producing high purity polyol esters comprises reacting a polyol with an excess amount of a linear or branched aliphatic monocarboxylic C3-20 acid to esterify less than the total amount of the polyol present to form an intermediate reaction composition having a hydroxyl value of from 7 to about 50 mg KOH/g. An anhydride of the corresponding linear or branched aliphatic monocarboxylic C3-20 acid is added to the intermediate reaction composition in an amount of from 1 to about 2.5 equivalents of available OH in the intermediate composition to form a reaction mixture. The reaction mixture is heated for 5-30 minutes or until all of the corresponding anhydride has reacted to form a reaction product. The reaction product is then de-acidified. No metal or acid catalyst or bleaching agents are present in any of the above reaction steps at a concentration above about 15 ppm.

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Номер записи: 71
30-07-2015 дата публикации

New fat blend composition

Номер: US20150208686A1
Автор: Eija Piispa, Gyorgy Karlovits
Принадлежит: Bunge Noevenyolajipari Zrt

Fat blend composition having 20% or less saturated fatty acids among which: 38% or less are palmitic acid; and 20% or more stearic acid; the fat blend being made at 5% to 100% hardstock containing 5% to 100% one or further hard fat and at least 5% stearic acid. Hardstock composition free of palm oil and its fractions having: 20% to 100% one or further hard fat being a fully hydrogenated oil, fractionated oil or fat, and/or interesterified oil or fat containing more than 15% stearic acid; and 0% to 80% of one or further natural or fractionated oil or fat chosen among canola, sunflower, low erucic acid rapeseed, high oleic sunflower, soybean, corn, peanut, olive, high oleic canola, low linolenic soybean, and high stearic sunflower oils, shea butter, cocoa butter and coconut fat, the natural or fractionated oil or fat being mixed and/or interesterified with the hard fat.

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Номер записи: 72
30-07-2015 дата публикации

METHODS OF MAKING HIGH-WEIGHT ESTERS, ACIDS, AND DERIVATIVES THEREOF

Номер: US20150210855A1
Автор: Firth Bruce, Ilseman Alexander D., Morie-Bebel Michelle, Murphy Timothy A., Pease Brian M., Weitkamp Robin, Zopp Garrett
Принадлежит: ELEVANCE RENEWABLE SCIENCES, INC.

Methods and compositions are provided for refining natural oils and for producing high-weight esters, high-weight acids, and/or high-weight derivatives thereof, wherein the compositions are made by cross-metathesizing low-weight unsaturated esters or low-weight unsaturated acids having hydrocarbon chain lengths less than or equal to C24 with an olefin feedstock, thereby forming a metathesized product composition including high-weight esters or high-weight acids having hydrocarbon chain lengths greater than C18, wherein at least a portion of the hydrocarbon chain lengths in the metathesized product are larger than the hydrocarbon chain lengths in the starting feedstock. 1. A method of making high-weight esters , high-weight acids , and/or high-weight derivatives thereof , comprising:providing a starting feedstock comprising unsaturated esters and/or unsaturated acids, wherein a majority of the hydrocarbon chain lengths in the feedstock are less than or equal to C24;optionally hydrolyzing the unsaturated esters in the starting feedstock to form a hydrolyzed feedstock;optionally transesterifying the starting feedstock or the hydrolyzed feedstock to form a transesterified feedstock; andcross-metathesizing the starting feedstock, hydrolyzed feedstock, or transesterified feedstock with an olefin feedstock in the presence of a metathesis catalyst, thereby forming a metathesized product comprising high-weight esters or high-weight acids having hydrocarbon chain lengths greater than C18, wherein at least a portion of the hydrocarbon chain lengths in the metathesized product are larger than the hydrocarbon chain lengths in the starting feedstock.2. The method of further comprising agitating at least a portion of the metathesized product as it is cooled from an elevated temperature to ambient temperature to thereby alter at least one property of the metathesized product.3. The method of claim 1 , further comprising reducing the high-weight esters to form a high-weight alcohol. ...

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Номер записи: 73
18-06-2020 дата публикации

COMPOSITION CONTAINING HIGHLY UNSATURATED FATTY ACID OR ALKYL ESTER THEREOF AND A METHOD FOR PRODUCING THE SAME

Номер: US20200190431A1
Автор: Doisaki Nobushige, FURIHATA Kiyomi, YAMAGUCHI Hideaki
Принадлежит: NIPPON SUISAN KAISHA, LTD.

To provide a composition comprising highly enriched PUFA or its alkyl esters while containing fatty acid esters of 3-MCPD at adequately low concentrations and to provide an efficient method for producing the composition. MEANS FOR SOLVING A composition that contains fatty acids or fatty acid alkyl esters as its major component, the composition containing highly unsaturated fatty acid or alkyl ester thereof, wherein the proportion of the highly unsaturated fatty acid in the constituent fatty acids of the composition is 50 area % or more and wherein the concentration of 3-MCPD as found upon analyzing the composition by American Oil Chemists' Society official method Cd 29b-13 assay A is less than 1.80 ppm. 1. A composition that contains fatty acids or fatty acid alkyl esters as its major component , the composition containing highly unsaturated fatty acid or alkyl ester thereof , wherein the proportion of the highly unsaturated fatty acid in the constituent fatty acids of the composition is 50 area % or more and wherein the concentration of 3-MCPD as found upon analyzing the composition by American Oil Chemists' Society official method Cd 29b-13 assay A is less than 1.80 ppm , and the concentration of trans-isomers in the composition is 0.01 area % or more.2. The composition according to claim 1 , wherein the proportion of the highly unsaturated fatty acid in the constituent fatty acids of the composition is 70 area % or more.3. The composition according to claim 1 , wherein the concentration of 3-MCPD as found upon analyzing the composition by American Oil Chemists' Society official method Cd 29b-13 assay A is less than a detection limit.4. The composition according to claim 1 , wherein the highly unsaturated fatty acid is eicosapentaenoic acid claim 1 , docosahexaenoic acid claim 1 , dihomo-γ-linolenic acid claim 1 , arachidonic acid claim 1 , or a combination thereof.5. The composition according to claim 1 , which is a distillation product.6. The composition ...

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Номер записи: 74
29-07-2021 дата публикации

BRANCHED FATTY ACIDS AND ESTERS THEREOF

Номер: US20210230505A1
Автор: LAMBIN Andreas, PACKET Dirk, Struelens Pieter
Принадлежит:

The present invention relates to a composition of branched fatty acids or esters thereof, the process for preparing such a composition and its use in various industrial fields, such as in lubricant, in cosmetics and in home care. More particularly, the present invention relates to a composition comprising at least 30% by weight of polybranched C-Cfatty acids or esters thereof, and a cyclic compound content ranging from 1% to 8% by weight, the weight percentage being given on the total weight of the composition. 1. A composition of branched C-Cfatty acids or esters thereof , comprising:{'sub': 10', '24, 'at least 30% by weight of polybranched C-Cfatty acids or esters thereof, and'}1 to 8% by weight of cyclic compounds,weight % being given on the total weight of the composition.2. The composition of claim 1 , wherein cyclic compounds comprise alicyclic carboxylic acid(s) or ester(s) thereof claim 1 , which content ranges from 0.5% to 6% by weight based on the total weight of the composition.3. The composition of claim 1 , comprising at least 15% by weight of monobranched C-Cfatty acids or esters thereof claim 1 , based on the total weight of the composition.4. The composition of claim 1 , wherein the weight ratio of monobranched/polybranched Cfatty acids or esters thereof claim 1 , ranges from 0.5 to 1.5.5. The composition of claim 1 , comprising at least 50% by weight of mono and polybranched C-Cfatty acids or esters thereof claim 1 , based on the total weight of the composition.6. The composition of claim 1 , further comprising 1-25% by weight of linear saturated C-Cfatty acid(s) or ester(s) thereof claim 1 , based on the total weight of the composition.7. A process for preparing a composition of branched C-Cfatty acids from a starting material comprising at least 70% by weight of linear monoethylenically unsaturated C-Cfatty acid(s) based on the total weight of the starting material claim 1 , comprising the following steps:{'sub': 10', '24, 'i) isomerizing the ...

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Номер записи: 75
28-07-2016 дата публикации

OIL OR FAT FOR TEMPERING TYPE CHOCOLATE

Номер: US20160213021A1
Автор: Aramaki Chika, Matsui Masayuki, Nagashima Chie, Okochi Masako
Принадлежит: FUJI OIL HOLDINGS INC.

An oil or fat for tempering type chocolate capable of enhancing and maintaining original flavors (milk taste, sweet taste, and cacao flavor, etc.) of chocolate is described, being obtained by blending therein 0.3 to 15% of a randomly transesterified oil of which a raw material is an oil or fat having a content of saturated fatty acids of 5 to 50% in the constituent fatty acids thereof and by further containing 5 to 50 ppm of malonyl isoflavone glycoside. A chocolate in which the oil or fat is blended is also described. 1. An oil or fat for tempering type chocolate , obtained by blending therein 0.3 to 15% of a randomly transesterified oil of which a raw material is an oil or fat having a content of saturated fatty acids of 5 to 50% in constituent fatty acids thereof.2. The oil or fat for chocolate of claim 1 , wherein the oil or fat as the raw material of the randomly transesterified oil is a palm fractionated soft-part oil or fat having an iodine value of 55 to 75.3. The oil or fat for chocolate of claim 1 , containing 5 to 50 ppm of malonyl isoflavone glycoside.4. A chocolate obtained by blending therein the oil or fat for chocolate of .5. A method of enhancing and maintaining a flavor of chocolate claim 1 , comprising blending in an oil or fat for tempering type chocolate claim 1 , wherein the oil or fat for tempering type chocolate is obtained by blending therein 0.3 to 15% of a randomly transesterified oil of which a raw material is an oil or fat having a content of saturated fatty acids of 5 to 50% in constituent fatty acids thereof.6. The oil or fat for chocolate of claim 2 , containing 5 to 50 ppm of malonyl isoflavone glycoside.7. A chocolate obtained by blending therein the oil or fat for chocolate of .8. A chocolate obtained by blending therein the oil or fat for chocolate of .9. A chocolate obtained by blending therein the oil or fat for chocolate of . The invention relates to an oil or fat for tempering type chocolate capable of enhancing and ...

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Номер записи: 76
26-07-2018 дата публикации

Natural Oil Metathesis Compositions and Methods

Номер: US20180208873A1
Автор: Bergmann Benjamin, Christensen S. Alexander, Cohen Steven A., DiBiase Stephen A., Ilseman Alexander D., Morie-Bebel M. Michelle
Принадлежит: ELEVANCE RENEWABLE SCIENCES, INC.

A metathesized natural oil composition comprising (i) a mixture olefins and/or esters, or (ii) a metathesized natural oil, is disclosed. The metathesized natural oil composition has a number average molecular weight in the range from about 100 g/mol to about 150,000 g/mol, a weight average molecular weight in the range from about 1,000 g/mol to about 100,000 g/mol, a z-average molecular weight in the range from about 5,000 g/mol to about 1,000,000 g/mol, and a polydispersity index of about 1 to about 20. The metathesized natural oil composition is metathesized at least once. 116-. (canceled)17. A method of making a metathesized natural oil composition comprising one or more metathesis oligomers , the method comprising:{'sub': 2', '6, 'providing natural oil glycerides, wherein the natural oil glycerides comprise metathesized natural oil glycerides, which are formed by the cross-metathesis of a natural oil glycerides with C-Clow-molecular-weight olefins; and'}reacting the natural oil glycerides in the presence of a metathesis catalyst to form metathesis oligomers;wherein the metathesis oligomers have a weight average molecular weight in the range from 1,000 g/mol to 100,000 g/mol.18. The method of claim 17 , wherein the metathesis oligomers have a weight average molecular weight in the range from 2 claim 17 ,500 g/mol to 50 claim 17 ,000 g/mol.19. The method of claim 18 , wherein the metathesis oligomers have a weight average molecular weight in the range from 7 claim 18 ,000 g/mol to 35 claim 18 ,000 g/mol.201. The method of claim claim 18 , wherein the C-Clow-molecular-weight olefins are selected from the group consisting of ethylene claim 18 , propylene claim 18 , 1-butene claim 18 , 2-butene claim 18 , and isobutene. The present application is a continuation of U.S. patent application Ser. No. 13/922,626, filed Jun. 20, 2013, which claims the benefit of priority of U.S. Provisional Application No. 61/662,318, filed Jun. 20, 2012 and U.S. Provisional Application No ...

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Номер записи: 77
04-07-2019 дата публикации

PURIFICATION METHODS

Номер: US20190202767A1
Автор: Pohlers Gerhard, Rudenko Andrey
Принадлежит:

Provided are purification methods, comprising: (a) providing an organic solvent and a phenolic peroxide formation inhibitor, wherein the organic solvent has a first boiling point at standard atmospheric pressure (bp) and the phenolic peroxide formation inhibitor has a second boiling point at standard atmospheric pressure (bp) that satisfy the following inequality (I): 1. A purification method , comprising:{'sub': 1', '2, 'claim-text': {'br': None, 'i': bp', 'bp, 'sub': 2', '1, '≤(1.10)() \u2003\u2003(I); and'}, '(a) providing an organic solvent and a phenolic peroxide formation inhibitor, wherein the organic solvent has a first boiling point at standard atmospheric pressure (bp) and the phenolic peroxide formation inhibitor has a second boiling point at standard atmospheric pressure (bp) that satisfy the following inequality (I)(b) heating the organic solvent and the phenolic peroxide formation inhibitor to a temperature causing the organic solvent and phenolic peroxide formation inhibitor to vaporize, and (ii) condensing the vaporized organic solvent and phenolic peroxide formation inhibitor to provide a purified mixture of the organic solvent and phenolic peroxide formation inhibitor.2. The purification method of claim 1 , wherein the purification method is a distillation process.3. The purification method of claim 1 , wherein the purification method is performed under vacuum.4. The purification method of claim 1 , wherein the organic solvent and the phenolic peroxide formation inhibitor are mixed prior to the step of heating.5. The purification method of claim 1 , wherein the phenolic peroxide formation inhibitor has a second boiling point at standard atmospheric pressure (bp) that satisfies the following inequality (II):{'br': None, 'i': bp', 'bp, 'sub': 1', '2', '1, '(0.90)() Подробнее

Номер записи: 78
02-08-2018 дата публикации

TRIGLYCERIDE OILS HAVING ASYMMETRIC TRIGLYCERIDE MOLECULES

Номер: US20180216144A1
Автор: Rakitsky Walter
Принадлежит: Corbion Biotech, Inc.

Triglyceride oils having one or more populations of asymmetric triglyceride molecules are provided. Asymmetric triglyceride molecule populations are triglyceride molecules that consist of a C8:0 fatty acid or a C10:0 fatty acid at the sn-1 position and the sn-2 position, and C16:0 or C18:0 at the sn-3 position. Another population of asymmetric triglyceride molecules are triglyceride molecules that consist of a C16:0 fatty acid or a C18:0 fatty acid at the sn-1 position and the sn-2 position, and C8:0 or C10:0 fatty acid at the sn-3 position. Methods of producing triglyceride oils and using the same are provided using sucrose invertase and hydrogenation of the triglyceride oil. Triglyceride molecules are produced by using recombinant DNA techniques to produce oleaginous recombinant cells. 1. A method of preparing a triglyceride oil , the triglyceride oil comprising a first population of asymmetric triglyceride molecules and/or a second population of asymmetric triglyceride molecules , the first population comprising triglyceride molecules consisting of a C8:0 fatty acid or a C10:0 fatty acid at the sn-1 position and the sn-2 position , and C14:0 , C16:0 or C18:0 at the sn-3 position , the second population comprising triglyceride molecules consisting of a C14:0 , C16:0 fatty acid or a C18:0 fatty acid at the sn-1 position and the sn-2 position , and C8:0 or C10:0 fatty acid at the sn-3 position , the method comprising the steps of:a. obtaining a triglyceride oil isolated from a recombinant microalgal cell, wherein the recombinant microalgal cell comprises an exogenous gene encoding an active sucrose invertase; andb. hydrogenating the triglyceride oil to produce the asymmetric triglyceride molecules.2. The method of claim 1 , wherein the first population or the second population of triglyceride molecules is enriched by fractionation or preparative liquid chromatography.3. The method of claim 1 , wherein the first population of triglyceride molecules comprises at least ...

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Номер записи: 79
11-07-2019 дата публикации

Process For The Preparation of Fatty Acid Alkyl Esters

Номер: US20190210953A1
Автор: Beltrame Reno Emilio, Kulkarni Ketav, Perlmutter Patrick
Принадлежит:

The present invention broadly relates to a process for preparing fatty acid alkyl esters from fat-containing feedstocks using sulfonated fatty acid catalysts. 2. The process of claim 1 , wherein the fat-containing feedstock comprises at least 20% claim 1 , at least 40% claim 1 , at least 60% claim 1 , at least 70% claim 1 , at least 80% claim 1 , at least 90% claim 1 , or at least 95% claim 1 , by weight of free fatty acids.3. The process of or claim 1 , wherein the fat-containing feedstock is a triglyceride-containing feedstock.4. The process of any one of to claim 1 , wherein the alcohol is present in the mixture in an amount between about 10% and about 60% by weight.5. The process of claim 4 , wherein the alcohol is present in the mixture in an amount between about 15% and about 40% by weight.6. The process of any one of to claim 4 , wherein the sulfonated fatty acid derivative is present in the mixture in an amount between about 0.05% and about 5% by weight.7. The process of claim 6 , wherein the sulfonated fatty acid derivative is present in the mixture in an amount between about 0.5% and about 2.5% by weight.8. The process of any one of to claim 6 , wherein the mixture further comprises an acid.9. The process of claim 8 , wherein the acid is present in the mixture in an amount between about 0.5% and about 5% by weight.10. The process of or claim 8 , wherein the acid is sulfuric acid.11. The process of any one of to claim 8 , wherein the mixture further comprises water.12. The process of claim 11 , wherein the water is present in the mixture in an amount of up to about 10% claim 11 , or in an amount of up to about 5% claim 11 , or in an amount of up to about 2% claim 11 , or in an amount of up to about 1% claim 11 , by weight.13. The process of any one of to claim 11 , wherein the alcohol is a C-Calcohol claim 11 , or a mixture thereof.14. The process of claim 13 , wherein the alcohol is methanol claim 13 , ethanol claim 13 , propanol claim 13 , isopropanol ...

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Номер записи: 80
23-10-2014 дата публикации

SYNTHESIS OF LONG-CHAIN POLYUNSATURATED FATTY ACIDS BY RECOMBINANT CELL

Номер: US20140314727A1
Автор: Blackburn Susan Irene Ellis, Green Allan Graham, Nichols Peter David, Petrie James Robertson, Robert Stanley Suresh, Singh Surinder Pal, Zhou Xue-Rong
Принадлежит: Commonwealth Scientific and Industrial Research Organisation

The present invention relates to methods of synthesizing long-chain polyunsaturated fatty acids, especially eicosapentaenoic acid, docosapentaenoic acid and docosahexaenoic acid, in recombinant cells such as yeast or plant cells. Also provided are recombinant cells or plants which produce long-chain polyunsaturated fatty acids. Furthermore, the present invention relates to a group of new enzymes which possess desatorase or elongase activity that can be used in methods of synthesizing long-chain polyunsaturated fatty acids. 1. A recombinant cell which capable of synthesising a long chain polyunsaturated fatty acid(s) (LC-PUFA) , comprising one or more polynucleotides which encode at least two enzymes each of which is a Δ5/Δ6 bifunctional desaturase , Δ5 desaturase , Δ6 desaturase , Δ5/Δ6 bifunctional elongase , Δ5 elongase , Δ6 elongase , Δ4 desaturase , Δ9 elongase , or Δ8 desaturase , wherein the one or more polynucleotides are operably linked to one or more promoters that are capable of directing expression of said polynucleotides in the cell , wherein said recombinant cell is derived from a cell that is not capable of synthesising said LC-PUFA.2. A recombinant cell with an enhanced capacity to synthesize a long chain polyunsaturated fatty acid(s) (LC-PUFA) relative to an isogenic non-recombinant cell , comprising one or more polynucleotides which encode at least two enzymes each of which is a Δ5/Δ6 bifunctional desaturase , Δ5 desaturase , Δ6 desaturase , Δ5/Δ6 bifunctional elongase , Δ5 elongase , Δ6 elongase , Δ4 desaturase , Δ9 elongase , or Δ8 desaturase , wherein the one or more polynucleotides are operably linked to one or more promoters that are capable of expressing said polynucleotides in said recombinant cell.3. The cell of or , wherein at least one of the enzymes is a Δ5 elongase.4. The cell of claim 3 , wherein the Δ5 elongase also has Δ6 elongase activity claim 3 , and wherein the elongase is more efficient at synthesizing DPA from EPA than it is at ...

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Номер записи: 81
09-08-2018 дата публикации

Process for Isomerization and Decarboxylation of Unsaturated Organic Compounds with a Metal Catalyst or Catalyst Precursor

Номер: US20180222812A1
Автор: Kenneth M. Doll, Rex E. Murray, Zengshe Liu
Принадлежит: US Department of Agriculture USDA

Disclosed is the use of a metal catalyst or catalyst precursor that catalyzes the isomerization of an unsaturated fatty acid, unsaturated fatty acid derivative, or an unsaturated triglyceride. Also disclosed is the use of a metal catalyst or catalyst precursor that catalyzes the decarboxylation of an unsaturated organic compound. Also disclosed is the use of a catalyst or catalyst precursor for the dual function isomerization and decarboxylation of an unsaturated fatty acid to an unsaturated organic compound.

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Номер записи: 82
30-10-2014 дата публикации

Process For Producing Fatty Alcohols From Fatty Acids

Номер: US20140323773A1
Автор: Michael Anthony Wood, Paul Appleton, Robert Wild
Принадлежит: Davy Process Technology Ltd

In a process for the production of fatty alcohol(s) a fatty acid or fatty acid mixture is subjected to esterification with a lower alkanol to form a stream comprising the corresponding lower alkyl ester or esters. The stream is vaporised and subjected to hydrogenation to form a stream comprising fatty alcohol(s) and an amount of unconverted lower alkyl ester(s). This stream is subjected to transesterification in a wax ester reactor in the presence of a solid transesterification catalyst. Fatty alcohol(s) and wax ester(s) are then separated by distillation to yield a fatty alcohol(s) product and a stream comprising wax ester(s). The stream of wax ester(s) is passed to a second hydrogenation zone to effect hydrogenation in the liquid phase to revert the wax ester(s) to fatty alcohol(s), which are returned to the distillation separation step.

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Номер записи: 83
16-07-2020 дата публикации

COMPOSITION CONTAINING EICOSAPENTAENOIC ACID ALKYL ESTER, AND METHOD FOR PRODUCING SAME

Номер: US20200222356A1
Автор: Arato Shingo, Doisaki Nobushige, FUKAE Takuro
Принадлежит:

Provided are: a composition containing 96-99 area % of eicosapentaenoic acid alkyl ester, the composition having an arachidonic acid alkyl ester content of 0.7 area % or less, and an eicosapentaenoic-acid-alkyl-ester mono-trans isomer content of 2.5 area % or less; and a method for producing a composition containing a high concentration of eicosapentaenoic acid alkyl ester, the method including performing precision distillation on a composition containing eicosapentaenoic acid alkyl ester, obtained by alkyl esterification of a raw material oil containing eicosapentaenoic acid, under a vacuum of 0.2 Torr or lower and a temperature of 190° C. or lower in the entire column, and performing a concentration treatment on the precision-distilled composition using chromatography.

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Номер записи: 84
03-09-2015 дата публикации

Diene-Selective Hydrogenation of Metathesis Derived Olefins and Unsaturated Esters

Номер: US20150247107A1
Автор: Balakrishnan Chander, Cohen Steven A., Jr. Melvin L., Kunz Linda A., Luetkens, Pals Tessa M., Snyder Robert B.
Принадлежит: ELEVANCE RENEWABLE SCIENCES, INC.

Methods are provided for refining natural oil feedstocks and partially hydrogenating polyunsaturated olefins and polyunsaturated esters. The methods comprise reacting the feedstock in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters. In certain embodiments, the methods further comprise separating the polyunsaturated olefins from the polyunsaturated esters in the metathesized product. In certain embodiments, the methods further comprise partially hydrogenating the polyunsaturated olefins in the presence of a hydrogenation catalyst, wherein at least a portion of the polyunsaturated olefins are converted to monounsaturated olefins. In other embodiments, the methods further comprise partially hydrogenating the polyunsaturated esters in the presence of a hydrogenation catalyst, wherein at least a portion of the polyunsaturated esters are converted to monounsaturated esters. 1. A method of forming monounsaturated olefins , comprising:providing a feedstock comprising polyunsaturated olefins; andpartially hydrogenating the polyunsaturated olefins in the presence of a hydrogenation catalyst for 30-180 minutes at a temperature between 150° C. and 250° C. with a hydrogen gas pressure between 50 psig and 500 psig,wherein the hydrogenation catalyst is provided in an amount between 0.01-1.0 wt % of the polyunsaturated olefins, wherein the hydrogenating step has a conversion rate of at least 85% and a selectivity of at least 90%.2. The method of claim 1 , wherein the feedstock is treated prior to the hydrogenating step under conditions sufficient to diminish catalyst poisons in the feedstock claim 1 ,wherein the feedstock is treated with one or more of the following: heat, molecular sieves, alumina, silica gel, montmorillonite clay, fuller's earth, bleaching clay, diatomaceous earth, zeolites, kaolin, activated metals, acid anhydrides, activated carbon, soda ash, metal hydrides, metal sulfates, metal ...

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Номер записи: 85
25-08-2016 дата публикации

ENRICHMENT OF TRITERPINE ESTERS

Номер: US20160244480A1
Автор: ALANDER Jari, HED Krister, NORBERG Staffan
Принадлежит:

A new process for enriching triterpene esters comprising: providing a mixture comprising a non-distilled vegetable oil and/or a non-distilled vegetable fat, further comprising triterpene esters, performing a mild transesterification with a lower alcohol, removing lower alcohol esters by deodorization, physical refining, evaporation or distillation, and recovering the remaining fraction rich in triterpene esters. Triterpene esters enriched with the method as well as uses of the same are also provided. One advantage is that it is a more economically viable way of achieving higher concentration of triterpene esters. There is both the chance to fully keep the natural distribution of triterpene esters but in the other end also to replace the natural level of cinnamic and acetic acids-triterpene esters with a high level of long fatty acid triterpene-esters. 1. A process for enriching triterpene esters comprising:providing a mixture comprising at least one non-distilled vegetable oil or non-distilled vegetable fat, wherein the mixture further comprises at least one triterpene ester,performing a mild transesterification with at least one lower alcohol at a temperature equal to or lower than the boiling point of the mixture, to obtain lower alcohol esters,removing the lower alcohol esters by at least one procedure chosen from deodorization, physical refining, evaporation and distillation, andrecovering the remaining fraction rich in triterpene esters.2. The process according to claim 1 , wherein the mixture comprises at least one vegetable oil chosen from rice bran oil claim 1 , shea butter claim 1 , shea butter oil claim 1 , avocado oil claim 1 , olive oil claim 1 , soy bean oil claim 1 , rape seed oil claim 1 , mango butter claim 1 , argon oil claim 1 , palm oil claim 1 , red palm oil claim 1 , coconut oil claim 1 , palm kernel oil claim 1 , safflower oil claim 1 , cocoa butter claim 1 , almond oil claim 1 , sun flower oil claim 1 , peach kernel oil claim 1 , evening ...

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Номер записи: 86
01-09-2016 дата публикации

HUMAN MILK FAT SUBSTITUTES

Номер: US20160249665A1
Автор: Bar-On Zohar, Ben Dror Gai, BLINDER Gregory, HERZOG Yael, LAOUZ Hala, MEIRI-BENDEK Iris, Shulman Avidor, YAAKOBI Dov
Принадлежит: ENZYMOTEC LTD.

Disclosed are human milk fat (HMF) substitutes, processes for preparation thereof, uses thereof, and fat blends and formula containing the HMF substitutes. A fat base composition of the invention includes a mixture of vegetable-derived triglycerides, with less than 50% of the fatty acid residues bonded at the sn-2 position being saturated; and/or with the amount of saturated fatty acid residues bonded at the sn-2 position of the glycerol backbone less than about 43.5% of the total amount of the fatty acid residues. Typically, substantially all of the saturated fatty acids bonded at the sn-2 position of the glycerol backbone are palmitic acid residues. Also disclosed are substitute HMF compositions including a blend of at least 25% or at least 30% of the fat base composition of the invention with up to 75%, or respectively up to 70%, of at least one vegetable oil. Processes for preparing the fat base compositions and blend are also disclosed. Further disclosed are infant formulas including the fat base composition or substitute human milk fat composition. 1. An enzymatically prepared fat base composition comprising a mixture of vegetable-derived triglycerides , characterized in that:less than 50% of the fatty acid residues bonded at the sn-2 position are saturated; and/orthe amount of saturated fatty acid residues bonded at the sn-2 position of the glycerol backbone is less than about 43.5% of the total amount of saturated fatty acid residues.2. The fat base composition of claim 1 , wherein substantially all of the saturated fatty acids bonded at the sn-2 position of the glycerol backbone are palmitic acid residues.3. The fat base composition of claim 2 , wherein at least 60% claim 2 , preferably at least 75% claim 2 , more preferably at least 85% of the saturated fatty acids at the sn-2 position of the glycerol backbone are palmitic acid residues.4. The fat base composition of any one of to claim 2 , wherein at least 40% claim 2 , preferably 45-65% claim 2 , of the ...

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Номер записи: 87
08-09-2016 дата публикации

Acidic Methanol Stripping Process That Reduces Sulfur Content of Biodiesel From Waste Greases

Номер: US20160257908A1
Автор: Colin James Stacy, Megan Elizabeth Hums, Richard Allan Cairncross
Принадлежит: DREXEL UNIVERSITY, Environmental Fuel Research LLC

The present invention provides a method of producing fatty acid alkyl esters from a lipid, comprising steps of introducing a gas comprising vapor of an alcohol selected from methanol, ethanol, 1-propanol, iso-propanol and butanols, into the lipid in a form of bubbles to enable the bubbles to pass through the lipid and be discharged from the lipid. The product may then be subjected to a transesterification process catalyzed by a base catalyst. The present invention is robust with low quality feedstocks thus significantly reduce production cost for biodiesel.

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Номер записи: 88
08-08-2019 дата публикации

PROCESS OF PRODUCING BASIC BIOSOLVENTS USING HETEROGENEOUS CATALYSTS AND OBTAINED BASIC BIOSOLVENTS BY THIS PROCESS

Номер: US20190241837A1
Автор: Pham Anh Tai, Tran Thanh Hang Thi, Vu Thu Ha Thi
Принадлежит: National Key Laboratory For Petrochemical and Refinery Technnologies

The present invention relates to a process for the production of basic biosolvents derived from inedible vegetable oil or animal fat or waste fatty acid composition by one-pot reaction between inedible vegetable oil or animal fat or waste fatty acid, and at least one ester of short-chain organic acid having 2, 3 or 5 carbon atoms, derived from biomass, in the presence of heterogeneous catalysts. In addition, the invention also relates to basic biosolvents, comprising alkyl esters of fatty acid, trieste of glycerin, esters of short-chain organic acids having 2, 3 or 5 carbon atoms, suitable for preparing many types of biosolvents, depending on application requirements. 1. A process for production of basic biosolvents from inedible vegetable oil or animal fat or waste fatty acid , by one-pot reaction , using heterogeneous catalysts comprising the steps of:heating inedible vegetable oil or animal fat or waste fatty acid composition for the liquefying of raw materials;mixing the liquid material with one of the reactants, the alkyl ester of short-chain organic acids having 2, 3 or 5 carbon atoms, derived from biomass, in the mixing apparatus;conducting one-pot reaction including inter-esterification reaction or inter-esterification reactions simultaneously with hydrolysis and the above-mentioned esterification reaction in the presence of heterogeneous catalysts at the temperature ranges from 220° C. to 240° C., and the pressure is in the range of 4.5-5.0 MPa; andremoving water and short-chain organic acids having 2, 3 or 5 carbon atoms as by-products and components with low boiling point, in order to obtain the basic biosolvents, as components with high boiling point.2. The process of claim 1 , wherein the mixing ratio based on the volume of alkyl esters and inedible vegetable oil or animal fat or waste fatty acid composition is in the range of 2:10 to 6:10.3. The process of claim 1 , wherein water may be added to the mixer with the ratio of water and inedible vegetable ...

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Номер записи: 89
06-09-2018 дата публикации

PHOSPHOLIPID NANOGEL FOR ENZYME STABILIZATION

Номер: US20180251752A1
Автор: Gattu Srikanth, HOLLAND LISA
Принадлежит:

Described herein are phospholipid nanogels that can contain a low concentration (less than about 250 μUnits/μL) of an exoglycosidase enzyme. Also described herein are systems and devices that can contain a phospholipid nanogel that can contain a low concentration (less than about 250 μUnits/μL) of an exoglycosidase enzyme. Also described herein are methods of using the phospholipid nanogels described herein and devices and systems that can contain a phospholipid nanogel described herein. 1. A phospholipid nanogel comprising:an amount of 1,2-dimyristoyl-sn-glycero-3-phosphocholine (DMPC);an amount of 1,2-dihexanoyl-sn-glycero-3-phosphocholine (DHPC);and an amount of an exoglycosidase enzyme that ranges from about 0.001 μUnits/μL of the phospholipid nanogel to about 250 μUnits/μL of the phospholipid nanogel.2. The phospholipid nanogel of claim 1 , wherein the ratio of DMPC to DHPC ranges from about 2.0 to about 3.0.31. The phospholipid nanogel of claim 1 , wherein the exoglycosidase enzyme can be selected from the group consisting of: α1-2 Fucosidase claim 1 , α1-6 Fucosidase claim 1 , α1-2 Mannosidase claim 1 , α1-2 claim 1 ,3 Mannosidase claim 1 , α1-2 claim 1 ,3 claim 1 ,4 claim 1 ,6 Fucosidase claim 1 , α1-2 claim 1 ,3 claim 1 ,6 Mannosidase claim 1 , α1-2 claim 1 ,4 claim 1 ,6 Fucosidase claim 1 , α1-2 claim 1 ,4 claim 1 ,6 Fucosidase O claim 1 , α1-3 claim 1 ,4 Fucosidase claim 1 , α1-3 claim 1 ,4 claim 1 ,6 Galactosidase claim 1 , α1-3 claim 1 ,6 Galactosidase claim 1 , α1-6 Mannosidase claim 1 , α2-3 Neuraminidase claim 1 , α2-3 Neuraminidase S claim 1 , α2-3 claim 1 ,6 Neuraminidase claim 1 , α2-3 claim 1 ,6 claim 1 ,8 Neuraminidase claim 1 , α2-3 claim 1 ,6 claim 1 ,8 claim 1 ,9 Neuraminidase claim 1 , α2-3 claim 1 ,6 claim 1 ,8 claim 1 ,9 Neuraminidase A claim 1 , α-N-Acetylgalactosaminidase claim 1 , β1-3 Galactosidase claim 1 , β1-3 claim 1 ,6 Galactosidase claim 1 , β1-4 claim 1 ,6 Galactosidase claim 1 , β-3 claim 1 ,4 Galactosidase claim 1 , β1-4 ...

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Номер записи: 90
24-09-2015 дата публикации

SINGLE STEP TRANSESTERIFICATION OF BIODIESEL FEEDSTOCK USING A GASEOUS CATALYST

Номер: US20150267145A1
Автор: Pottathil Raveendran
Принадлежит: Initio Fuels, LLC

Embodiments of the present application provide methods for processing biodiesel from feedstock using a single-step process. The methods can include, for example, use of a gaseous catalyst as part of the esterification/transesterification process. Embodiments of the present application also provide systems for the methods thereof. 1. A process for producing a biodiesel grade , fatty acid alkyl ester comprising:providing reaction agents comprising a feedstock, an alcohol and a gaseous catalyst; andcontacting the reaction agents,wherein the contacting results in formation of a reaction product comprising a first component comprising the transesterified fatty acid alkyl ester.2. The process of claim 1 , further comprising mixing the reaction agents.3. The process of claim 1 , wherein the gaseous catalyst is acidic.4. The process of claim 3 , wherein the gaseous catalyst comprises at least one catalyst selected from HBr claim 3 , HCl claim 3 , HCN claim 3 , HF claim 3 , and HS.5. The process of claim 4 , wherein the gaseous catalyst comprises HCl.6. The process of claim 1 , wherein the alcohol comprises at least one alcohol selected from methanol claim 1 , ethanol claim 1 , propanol claim 1 , butanol claim 1 , hexanol claim 1 , heptanol claim 1 , octanol claim 1 , nonanol claim 1 , or decanol.7. The process of claim 6 , wherein the alcohol comprises methanol.8. The process of claim 1 , wherein the feedstock comprises algal bodies.9. The process of claim 8 , wherein the feedstock comprises un-lysed algal bodies.10. The process of claim 1 , wherein the feedstock comprises a plant gum.11. The process of claim 10 , wherein the plant gum comprises at least one plant oil gum selected from artichoke oil gum claim 10 , canola oil gum claim 10 , castor oil gum claim 10 , Chinese tallow tree oil gum claim 10 , coconut oil gum claim 10 , corn claim 10 , cottonseed oil gum claim 10 , flaxseed oil gum claim 10 , hemp oil gum claim 10 , jatropha oil gum claim 10 , jojoba oil gum claim ...

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Номер записи: 91
15-09-2016 дата публикации

Installation and method for producing fatty acid esters usable as fuel

Номер: US20160264911A1
Автор: Maria Úrsula CHORNET SERRANO, Pau AZKARATE CAPELL
Принадлежит: Supercritical Ideas Sl

Installation and method for producing fatty acid esters usable as fuel for which the installation includes a tank ( 10 ) containing oils and/or fats to be treated, a tank ( 11 ) containing light alcohol, pumps ( 3 ) and ( 4 ) feeding the materials to a tubular reaction vessel ( 30 ) having a winding configuration provided with a heater for internally maintaining a supercritical temperature with respect to the alcohol used and a pressure provided by the pumps, suitable for producing esterification and transesterification reactions, without the presence of catalysts of the oils and/or fats and alcohol, a heat exchanger ( 8 ) for heating the affluents and cooling the reaction effluents and a reaction effluent depressurization tank ( 21 ). The installation further has a stirrer ( 22, 23, 28 ) for stirring the reaction product at the reaction temperature and pressure in one or more segments of the tubular vessel ( 30 ) covering a sector of the reactor before its end area for exit towards the depressurization tank ( 21 ).

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Номер записи: 92
21-09-2017 дата публикации

Process for Producing a Glyceride Composition

Номер: US20170267945A1
Автор: Bhaggan Krishnadath, Bouwer Sietze, Schweitzer Erik
Принадлежит: Loders Croklaan B.V.

A process for the production of a composition comprising 1,3-dioleoyl-2-palmitoyl glyceride (OPO) comprises: providing one or more palm oil stearin fractions comprising tripalmitoyl glyceride and having an iodine value between about 18 and about 40; interesterifying the one or more palm oil stearin fractions to form a randomly interesterified palm oil stearin; subjecting the randomly interesterified palm oil stearin to enzymic transesterification with oleic acid or a non-glyceride ester thereof using an enzyme having selectivity for the 1- and 3-positions of a glyceride; and separating palmitic acid or palmitic non-glyceride esters from the product obtained in (iii) to form a composition comprising OPO glyceride.

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Номер записи: 93
28-09-2017 дата публикации

METHOD FOR PREPARING HIGH-CONTENT CONJUGATED LINOLEIC ACID WITH VEGETABLE OIL

Номер: US20170275228A1
Автор: Peng Yongjian, Shao Bin, XU Xinde, ZHANG Lihua
Принадлежит: Zhejiang Medicine Co., Ltd., Xinchang Pharmaceutical Factory

A method for preparing high-content conjugated linoleic acid (CLA) through Purification of vegetable oil includes alcoholysis, purification and isomerization of vegetable oil. Alcoholysis is for preparing corresponding methyl ester or ethyl ester with glyceride; purification of methyl ester or ethyl ester is for obtaining methyl linoleate or ethyl linoleate of content over 85% through silver-based silica gel column chromatography; high-content CLA is obtained after alkali-catalyzed conjugation of methyl linoleate or ethyl linoleate, and CLA products are prepared as needed. This invention changes the status quo of preparing high-content CLA with safflower oil alone, expands sources of CLA, and develops an efficient technology for separation and purification of linoleic acid. The CLA obtained is of high purity and meets applications in pharmaceutical, health care products and other industries. 1. A method for preparing high-content conjugated linoleic acid (CLA) through purification of vegetable oil comprising the following steps:1) Alcoholysis of vegetable oil: stir vegetable oil, catalyst and alcohol solution at 50-75° C. for 0.5-2 h, and wash them layer by layer to obtain the product;2) Primary purification of alcoholysis product: conduct primary purification for the alcoholysis product by rectification or crystallization to remove low-boiling and high-melting impurities and obtain product of primary purification;3) Repurification: weigh an appropriate amount of product of primary purification, add it into silver-based silica gel column after moderate dilution, adsorb it in static state for 5-30 min in a dark place, conduct gradient elution with eluent, collect it section by section, remove the eluent, and measure the content of linoleate in each component;4) Mix the linoleate, base catalyst and alcohol solvent, inject nitrogen, stir at 100-190° C. for 1-8 h, add water to terminate the reaction, cool to room temperature, dropwise add acid until pH reaches 1-3, ...

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Номер записи: 94
18-12-2014 дата публикации

PRODUCTION OF DIHYDROSTERCULIC ACID AND DERIVATIVES THEREOF

Номер: US20140371477A1
Автор: Naim Fatima, Okada Shoko, Singh Surinder Pal, Wood Craig Christopher
Принадлежит:

The present invention relates to recombinant cells, particularly recombinant plant cells, which are capable of producing dihydrosterculic acid and/or derivatives thereof. The present invention also relates to methods of producing oil comprising dihydrosterculic acid and/or derivatives thereof. 1. A process for producing oil containing dihydrosterculic acid (DHS) and/or a fatty acid derivative thereof , the process comprisingi) obtaining plant cells, algal cells or fungal cells comprising DHS, and/or a fatty acid derivative thereof, the DHS or fatty acid derivative thereof being esterified in triacylglycerols in the cells, wherein at least about 3% of the total fatty acid in extractable oil in the cells is DHS and/or a fatty acid derivative thereof, and,ii) extracting oil from the cells so as to thereby produce the oil.2. The process of claim 1 , wherein the plants cells of step i) are obtained as a plant or part thereof comprising said cells claim 1 , such as a leaf or a stem.3. The process of claim 2 , wherein the part is a vegetative plant tissue.4. The process of claim 3 , wherein step i) comprises obtaining pieces of vegetative tissue from at least about 100 claim 3 , or at least about 1000 claim 3 , or at least about 10000 claim 3 , plants claim 3 , which on average comprise at least about 3% DHS as a percentage of the total fatty acids in the extractable oil in the vegetative plant tissues.5. The process according to any one of to claim 3 , wherein the cells have one or more of the following featuresi) at least about 5%, or preferably at least about 7%, or more preferably at least about 10%, or even more preferably at least about 12%, or most preferably at least about 15%, of the total fatty acid in the extractable oil in the cells is DHS and/or a fatty acid derivative thereof,ii) the ratio of oleic acid to DHS and/or fatty acid derivative thereof in the extractable oil in the cells is less than about 2:1, preferably less than about 1.5:1, more preferably less ...

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Номер записи: 95
25-12-2014 дата публикации

Direct method of producing fatty acid esters from microbial biomass

Номер: US20140373432A1
Автор: Joseph James ALISHUSKY, Paul Richard Weider, Pen-Chung Wang, Robert Lawrence Blackbourn
Принадлежит: Shell Oil Co

A method of producing fatty acid esters in situ from microbial biomass such as algae is provided by treating microbial biomass with a solution containing an alcohol and at least one α-hydroxysulfonic acid. Fatty acid ester can be directly recovered from the treated microbial biomass. The α-hydroxysulfonic acid can be easily removed from the treated microbial biomass and recycled.

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Номер записи: 96
15-10-2015 дата публикации

PROCESS FOR PRODUCING MONOBRANCHED FATTY ACIDS OR ALKYL ESTERS THEREOF

Номер: US20150291912A1
Автор: Bergen-Brenkman Tanja Van, Rashidi Negar, Wels Bastiaan
Принадлежит: Croda International PLC

A process for producing a composition having a ratio by weight of C-Cmonobranched fatty acids or alkyl esters thereof to C-Cpolybranched fatty acids or alkyl esters thereof of greater than 6 using a zeolite, preferably ferrierite, isomerisation catalyst. The zeolite catalyst is preferably the only isomerisation catalyst used. The zeolite catalyst can be reused many times after simple separation from the reaction products without having to be regenerated. 1. A process for producing monobranched fatty acids or alkyl esters thereof which comprises;{'sub': 10', '26, '(i) isomerising unsaturated C-Cfatty acids or alkyl esters thereof in the presence of a catalyst comprising zeolite,'}(ii) optionally removing polymeric fatty acids,(iii) optionally hydrogenating the reaction product of step (i) or (ii), and{'sub': 10', '26', '10', '26, '(iv) obtaining a composition from the reaction product of step (i), (ii) or (iii) having a ratio by weight of C-Cmonobranched fatty acids or alkyl esters thereof to C-Cpolybranched fatty acids or alkyl esters thereof of greater than 6.'}2. (canceled)3. A process for producing monobranched fatty acids or alkyl esters thereof which comprises;{'sub': 10', '26, '(A) (i) isomerising unsaturated C-Cfatty acids or alkyl esters thereof in the presence of a catalyst comprising zeolite,'}(ii) separating the reaction product of step (i) from the used zeolite,(iii) optionally removing polymeric fatty acids,(iv) optionally hydrogenating the reaction product of step (ii) or (iii),{'sub': 10', '26', '10', '26, '(v) obtaining a composition from the reaction product of step (ii), (iii) or (iv) having a ratio by weight of C-Cmonobranched fatty acids or alkyl esters thereof to C-Cpolybranched fatty acids or alkyl esters thereof of greater than 6, and'}(B) wherein the process steps (A)(i) to (v) are repeated more than once using zeolite comprising used zeolite which has been obtained from step (A)(ii) of the previous reaction cycle.4. The process according to ...

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Номер записи: 97
05-09-2019 дата публикации

SYNTHESIS AND USE OF OMEGA-HYDROXYLATED POLYUNSATURATED FATTY ACIDS

Номер: US20190270950A1
Автор: HAMMOCK Bruce, Hwang Sung Hee, WANG Weicang, Zhang Guodong
Принадлежит:

The present invention provides a synthetic chemical method for preparing ω-hydroxylated polyunsaturated fatty acids (PUFAs) including 20-hydroxyeicosatetraenoic acid (20-HETE), 20-hydroxyeicosapentaenoic acid (20-HEPE), and 22-hydroxydocosahexaenoic acid (22-HDoHE) and a method of use thereof for treating cancer and macular degeneration. 2. The method of claim 1 , wherein the transition-metal coupling agent comprises a copper ion.3. The method of claim 2 , wherein the copper ion is a copper (I) ion.4. The method of claim 3 , wherein the copper (I) ion is a copper (I) salt selected from the group consisting of CuI claim 3 , CuBr claim 3 , CuCl claim 3 , and Cu(OAc).5. The method of claim 1 , wherein the base is selected from the group consisting of a di-(C-Calkyl)amine claim 1 , a tri-(C-Calkyl)amine claim 1 , and an alkali carbonate.6. The method of claim 5 , wherein the alkali carbonate is potassium carbonate or cesium carbonate.7. The method of claim 1 , wherein the coupling reaction mixture further comprises an iodide salt selected from the group consisting of sodium iodide or potassium iodide.8. The method of any one of to claim 1 , wherein the coupling reaction mixture further comprises an aprotic solvent.9. The method of claim 8 , wherein the aprotic solvent is dimethylformamide.14. The method of claim 13 , wherein the deactivated palladium catalyst is Lindlar catalyst.15. The method of claim 13 , wherein the deactivating agent is selected from the group consisting of quinoline claim 13 , pyridine claim 13 , and ethylenediamine.16. The method of any one of to claim 13 , wherein the hydrogenation reaction mixture further comprises a C-Calkene.17. The method of claim 16 , wherein the C-Calkene is 2-methyl-2-butene.20. The method of or claim 16 , wherein the iodide salt is sodium iodide.21. The method of or claim 16 , wherein the alkali carbonate is cesium carbonate.22. The method of or claim 16 , wherein the aprotic solvent is dimethylformamide.23. The method of ...

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Номер записи: 98
06-10-2016 дата публикации

PROCESSES FOR PRODUCING FUELS FROM A RENEWABLE FEED

Номер: US20160289570A1
Автор: Ray Anjan
Принадлежит:

Processes for the production of hydrocarbons from a renewable feedstock in which the renewable feedstock is partially hydrogenated prior to being deoxygenated. The partially hydrogenation utilizes a lower pressure, lower purity or both hydrogen gas compared to the deoxygenation. The partially hydrogenated product may be stored in containers and transported to be deoxygenated. Prior to partially hydrogenation, the feedstock may be pretreated. After deoxygenation an isomerization zone may be used to increase the cold flow properties for a diesel fuel. 1. A process for producing a transportation fuel from a renewable feedstock , the process comprising:pretreating a renewable feedstock in a first pretreatment zone to provide a pretreated feedstock;pre-hydrogenating the pretreated feedstock in a pre-hydrogenation zone, the pre-hydrogenation zone comprising at least one reactor having a hydrogenation catalyst and being operated under conditions to partially hydrogenate the pretreated feedstock to provide a pre-hydrogenated feedstock;deoxygenating the pre-hydrogenated feedstock in a deoxygenation zone, the deoxygenation zone comprising at least one reactor having a catalyst capable of deoxygenating the pre-hydrogenated feedstock under deoxygenation conditions and providing a deoxygenated effluent; and,separating at least one transportation fuel stream from the deoxygenated effluent,wherein both the pre-hydrogenation zone and the deoxygenation zone receive a hydrogen gas stream, and wherein the hydrogen gas stream received by the pre-hydrogenation zone has a lower purity, a lower pressure or both compared to the hydrogen gas stream received by the deoxygenation zone.2. The process of and wherein the hydrogen gas stream received by the pre-hydrogenation zone has a lower purity and a lower pressure compared to the hydrogen gas stream received by the deoxygenation zone.3. The process of wherein the pressure of the hydrogen gas stream received by the deoxygenation zone is at ...

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Номер записи: 99
04-10-2018 дата публикации

Temperature Tolerant Chocolate Spread or Filling and Method of Preparation

Номер: US20180279640A1
Автор: Bhaggan Krishnadath, Manson Helga
Принадлежит: Loders Croklaan B.V.

Disclosed is a chocolate spread or chocolate filling composition comprising one or more of the ingredients selected from hazelnut paste, cocoa butter, cocoa mass, cocoa powder, milk fat, milk powder, vanilla, and lecithin; 2% to 40% by weight of a fat composition; and 30% to 50% by weight of sugar, wherein the fat composition comprises at least 40% by weight of interesterified shea olein having an oleic acid content of at least 50% by weight and a stearic acid content of at least 25% by weight, based on the total C12 to C20 fatty acids present in the interesterified shea olein, and wherein the interesterified shea olein has a solid fat content of at least 10% at 10° C., at least 6% at 20° C., and at least 3% at 30° C. 1. Chocolate spread and/or filling composition comprising:one or more ingredients selected from hazelnut paste, cocoa butter, cocoa mass, cocoa powder, milk fat, milk powder, vanilla, and lecithin;2% to 40% by weight of a fat composition; and30% to 50% by weight of sugar,wherein the fat composition comprises at least 40% by weight of interesterified shea olein and optionally up to 60% by weight of a liquid vegetable oil,wherein the interesterified shea olein hasan oleic acid content of at least 50% by weight anda stearic acid content of at least 25% by weight, based on the total C12 to C20 fatty acids present in the interesterified shea olein, andwherein the interesterified shea olein has a solid fat content of at least 10% at 10° C., at least 6% at 20° C., and at least 3% at 30° C.2. Chocolate spread according to claim 1 , wherein the fat composition comprises at least 80% claim 1 , by weight of interesterified shea olein.3. Chocolate spread according to claim 1 , wherein the fat composition comprises at least 99% by weight of interesterified shea olein and up to 1% by weight of a liquid oil.4. Chocolate spread according to claim 1 , wherein the composition comprises 100% by weight interesterified shea olein.5. Chocolate spread according to claim 1 , ...

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Номер записи: 100