11-12-2014 дата публикации
Номер: US20140361211A1
The composition and method for depositing and processing a solid transparent electrolyte polymerized by ultraviolet (UV) radiation are described. The electrolyte composition includes, at least, an ionic compound, a polymerizable material, a photoinitiator and a polar solvent. The electrolyte is deposited by printing techniques, such as inkjet printing. 1. Electrolyte solution , characterized by integrating:ionic compounds between 0.1 and 7% w/w, selected from the group consisting of lithium perchlorate, lithium triflate, lithium tetrafluoroborate and lithium hexafluorophosphate;monomers, oligomers or polymers with non-saturated sites, between 20 and 35% w/w, selected from the group consisting of poly(propylene glycol) diacrylate (PPGDA), trimethylolpropane triacrylate (TMPTA), and cyclic trimethylolpropane formal acrylate (CTFA);photoinitiators between 0.05% and 15% w/w selected from the group consisting of phenylbis(2,4,6-trimethylbenzoyl)phosphine oxide, 1-hydroxy-cyclohexyl-phenyl-ketone, and 2-hydroxy-2-methyl-1-phenyl propanone; andpolar solvents between 40 and 75% w/w, selected from the group consisting of ethylene carbonate, propylene carbonate, dimethyl carbonate and acetonitrile.2. Electrolyte solution claim 1 , according to claim 1 , characterized in that it additionally integrates ionic compounds selected from the group consisting of potassium triflate claim 1 , potassium hexafluorophosphate claim 1 , potassium tetrafluoroborate claim 1 , potassium perchlorate claim 1 , ammonium hexafluorophosphate and ammonium tetrafluoroborate.3. Electrolyte solution claim 1 , according to claim 1 , characterized in that it additionally integrates monomers claim 1 , oligomers or polymers with non-saturated sites claim 1 , selected from the group consisting of ethoxylated trimethylolpropane triacrylate (EO-TMPTA) claim 1 , propoxylated trimethylolpropane triacrylate (PO-TMPTA) claim 1 , and pentaerythritol tetraacrylate (PETA).4. Electrolyte solution claim 1 , according ...
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