Air bag-containing cover
V i »e • l i AIR BAG-CONTAINING COVER FIELD OF THE INVENTION AND RELATED ART STATEMENT The present invention concerns a cover for containing an air bag which is actuated to expand and develop upon collision of* a vehicle by sensing impact shock> deformation or the like caused by the collision. The air bag-containing Cover of this kind is generally inserted with a reinforcing material such as nets (refer, for example, to Japanese Patent Laid-Open Sho 62-2376, Sho 50-127336, Japanese Utility Model Laid-Open Sho 52- ».. 80928, Sho 50-4354 and Sho 51-25342). The cover inserted with the net-like inserts is usually manufactured by preparing an entire cover with material of relatively low strength such as foamed polyurethane and *!"!* inserting the reinforcing nets for the entire cover. Lines not inserted with the reinforcing nets are generally provided so that the air bag can be developed smoothly ...*»; upon expansion to easily break the cover. On the other hand, Japanese Utility Model Laid-Open Sho 52-76042 proposes an air bag-containing cover compris¬ ing two layers, that is, a surface skin layer made of rigid urethane foams for finely finishing the surface and a core layer made of low density (high foaming ratio) - 1» urethana foams for softening the entire cover In which slits (lines for smoothly developing the air bag upon expansion) are disposed being extended from the core layer to a portion of the surface skin layer. Among the conventional air bag-containing covers described above, the air bag-containing cover provided with the net-like inserts involves a problem that its manufacture requires a number of steps and is troublesome manufacture at high accuracy is difficult even by the use, for example, of urethane foaming molding (RIM), the pro¬ duction yield is low and the cost is expensive since the net-like reinforcements are inserted* .♦ Further, the cover as disclosed in Japanese Utility Model Lald-Open Sho 52-76042 has a surface skin layer made of rigid urethane foams (ASTM-sD2240, Shore hardness: 30 - 40) an, accordingly, it cian not provide a soft feeling •!!!!• u* gies Unpleasant feeling when a portion of a driver's body is in contact therewith, for instance, during running of a vehicle. Furthermore, since the urethane material •»••• has low impaet shock strength and no reinforcing inserts are provided, broken pieces are scattered upon expansion of the air bag, OBJECT AND SUMMARY OF THE INVENTION The object of the present invention is to overcoma Jiwmjjj , 3 » the foregoing problems of the air bag-containing cover in the prior art and provide an air bag-containing cover of such a performance that a. surface skin layer is flexible and gives a soft feeling, a core layer retains a shape capable of withstanding external pressure, the cover is easily broken upon expanding operation of the air bag but is not scattered in broken pieces within a temperature range from -0*0 to +80*0, and also shows satisfactory breaking performance with scarce change of appearance at the above-specified temperature range even after being for «••• a long time at a high temperature of 110*0 and 1000 hours in view of actual mounting to a vehicle, which can be supplied by means of a simple molding process such as injection molding, at a high yield in a method of not resulting in failed products, at high accuracy, at high productivity and with satisfactory economical advantage. The air bag-containing cover according to the present *»* ** invention comprises: .••. f a surface skin layer made of thermoplastic polymer ♦.*..♦ containiftg the following ingredients A, B, C and D, ingredient A : a hydrogenated derivative of a block copolymer comprising styrene and conjugated diene, Ingredient B : an olefinic resin, ingredient C t a polyisobutylene with a viscosity avenge molecular weight of not greater than 70,000 and t *• - 3 ingredient D : a hydrocarbon series rubber softening agent with a kinetic viscosity at 40*C of not greater than 500 cSt and/or a polybutene with a number average molecular weight not greater than 2500, in v .ich the blending ration is: ingredient A = 40 to 80 % by weight. ingredient B '* 5 to 30 % by weight ingredient C = 2 to 30 % by weight ingredient p = 0-20 % by weight, and having JlS-A hardness in accordance with JIS-K63OI of from to 90, and a core layer made of an olefinic resin having a modulus in flexure in accordance with JIS-K7203 of from • /», 1000 to 7000 kg/cm , in which the core layer has a higher hardness than that of the surface skin layer and the core layer is provided vjith easily bursting or tearing portions upon initiation of the air bag operation.. The present inventors have made earnest studies for attaining the foregoing object and, as a result, have accomplished the present invention based on the finding that the above-mentioned object can be attained by using a specific sufrface skin layer and a specific core layer and providing the core layer with easily fowsting portions, for example, embrittled shapes. In thei air bag-containing tov&v according to the , A present invention, since the relatively rigid core layer is covered with th© soft surface skin layer, it provides softness and gives no unpleasant feeling when a driver's body is in contact with the cover. Further, since the core layer is rigid, the cover is neither deformed nor broken even when a certain external force is exerted. In the cover according to the present invention, when the air bag in the cover is expanded, for Instance, upon collision of a vehicle, within a temperature range from -40*C to +80*C, the cover is bursted along the coyer bursting embrittled shapes previously disposed to the core layer. Upon bursting of the cover, since the rigid core ;•» layer is covered with the soft surface skin layer in close t «• contact therewith, broken pieces of a cover upon bursting are not scattered. Furthermore, the cover according to the present **III* invention shows satisfactory breaking performance and *.»• I shows scarce change in the appearance within the above- .*>*, j mentioned temperature range (-lO'C - *8o"C) even after the elapse of 500 hours at IIO'C which are taken into consideration as actual mounting conditions to a vehicle. BRIEF DESCRIPTION OF THE DRAWINGS Fig. i is a schematic front elevational view partially in cross section illustrating an air bag-containing cover <" "i~ t as a preferred «mbodimedt accorcling to the present inven¬ tion in a state attached to an air bag and Fig. 2 is a rear elevational view of the air bag- containing cover, DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will now be described more in details. Fig. 1 is a schematic front elevational view partially in cjposs section illustrating an air bag-containing cover as a preferred embodiment according to the prQsent inven¬ tion in a state attached to an air bag and Fig. 2 is a rear elevational view of the air bag-containing cover. t •**# In the drawings, are shown an air bag-containing cover I, an air bag 2, an inflator 3, a ring retainer 4, a base retainer 5» a plate 6* a rivet 7, a surface skin layer 1A, ****** a core layer IB and continuous stitch-like slits 1C. As shown in the drawings,, the air bag-containing .* • cover according to the present invention uses, as the surface layer lA* a surface skin layer made of a thermo¬ plastic polymer (thermoplastic elastomer) containing the following ingredients A - D in the following blending ratio and having JIS-A hardness in accordance JIS-K63<5 of from 20 to 90; Ingredient A : a hydrogenated derivative of a block t *• Ingradiant B Ingredient G Ingredient D copolymer comprising styrene and conjugated = 48 to 80 % by weight, an olefinic resin = 5 to 30 % by weight, a polyisobutylene with a viscosity average molecular weight not greater than 70,000 =5 2 to 30 % by weight, a hydrocarbon series rubber softening agent with a kinetic viscosity at 40*0 of not greater than 500 cSt and/or a polybutehe with a number average, molecular weight not greater than 2500 - 0 to 20 % by weight. While on the other hand, a core layer made of an olefinic resin having a modulus inflexure in accordance with JTS-K7203 of from 1000 to ?000 kg/cm2 is used as the core layer IS. The core layer IB has a higher hardness than that of the surface skin layer 1A, and the core layer IB is pro¬ vided with embrittled shapes 1C, for example, notch-like reduced thickness shapes or stitch-like slit shapes as \,he easily bursting portions upon initiation of the air bag operation. In the present invention, as the ingredient k of the thermoplastic elastomer used as the constituent material for the surface skin laye*r 1A, there can be mentioned a - 7 hydrogenated derivative of a styrenic block copolymer typically represanted, for example, by the general formula: X-Y x4Y-x)n where X represents a styrene polymer block, Y represents a conjugated diene elatomeric polymer and n is an integer of 1 to 5. As the monomer of the conjugated diene for the polymer block Y in each of the formulae, butadiene or isoprene is ** s suitable and a mixture thereof may also be used. Further, **"# the ratio of the Ingredient A of the styrene polymer block •• X in the entire block copolymer is usually ranges from • •ft to 40 % by weight and, prefepably, from 10 to 35 % by weight. If the ratio is lesss than 5 % by weight, the surface; skin layer is deteriorated in the mechanical «••••, strength, easily broken upon expansion of the air bag and •""**• deformed by the external pressure to leave th© traces thereof. On the other hand, if it exceeds 40 % by weight, « • c • it is not practical since the soft feeling of the surface skin layer is poor. **•• It is preferred that the number average molecular weight of the pqlymei? block X is within a ranges from 5000 to 125000 and the number average molecular weight of the polymer block Y is within a range from 15000 to 250000. Various methods have been proposed for the prepara¬ tion of the hydroganated derivative of the styrenic block copolymer represented by the general formula described above, and there can be mentioned typical methods as described, for example, in Japanese Patent Publications Sho 42-8704 and 43-6636. In the present invention, the hydrogenated derivative in which at least 50%, preferably, more than 80% of the olefinic double bonds in the polymer block Y are hydroge¬ nated and less than 25# of the double bonds in the polymer block Y are hydrogenated upon preparation are preferred as the ingredient A. As for thei blo£k polymer, commercially available polymer, for example, KRATON-G (Shell Chemical Co.), KL (Kurare. Co.) and TAFTEC (Asahi KasQi Co.) can be used. As the ingredient B, a homopolymer or copolymer of #**«.# o(-olefin such as ethylene, propylene and butene-1 is preferred. As thd ingredient C, a high molecular weight poly- isobutylne scarcely having double bonds in the molecular chain and having a bonding structurei • •c* 4 ft* 4:C(CH3,2-CH2n is preferred. The polyisobutylene for the ingredient C has a viscosity average molecular weight of not greater than rrj —-TfJ 70,000 and, preferably, not greater than 50,000. If the viscosity average molecular weight exceeds 70,000, it is not preferred since this brings about a disadvantage that the resultant surface skin layer is poor in the soft feeling and moldability. As a polyisobutylene suitable for the ingredient C, commercially available polymer, for example, TETRAX (Nippon Petrochemical Co J and BISTANEX (Exon Chemical Co.) can be used. The in&2*edient D is a hydrocarbon series rubber softening agent with.a kinetic viscosity at 4,0"C of not ** * greater than 500 cSt, specifically paraffinic or naphthenic ****# extender oil or process oil and/or a polybutene with a ,. number average molecular weight of not greater than 2500, • •• preferably, not greater than 2,000, suitably, mainly com- prising isobutylehe and partially copolymerized with n-butene. ,••••. If the kinetic viscosity of the hydrocarbon jferles •*••*• rubber softening agent for the Ingredient D exceeds 500 cSt, this result in a disadvantage that the moldability of the surface skin layer material is deteriorated. On the other hand, if the molecular weight of the polybutene •••• exceeds 2500, it also leads to a disadvantage of poor moldability. The ingredient D may be a mixture of a hydrocarbon series rubber softening agent and a polybutene. - t *" In the present invention, the blending ratio of the ingredients A - D is as shown below: Ingredient A 40 to 80 wt?, preferably, 60 tp 75 wtJS Ingredient B' 3 to 30 wt?f, preferably, 10 to 20 vit% Ingredient C - 2 to 30 wtJC-, preferably, 5 to 20 wt% Ingredient D « 0 to 20 wt?, preferably, 0 to 15 wt?, i If the styrenic block polymer of the ingredient A is less than 40 % by weight,, the resultant surface skin layer lacks in the soft feeling. On the other hand if it exceeds 80 % X>y weight, the resultant thermoplastic elas¬ tomer has poor moldability. If the olefinic resin of the ingredient B is less than 5: % by weight, the molding stability of the resultant • #• thermoplastic elastomer and the adhesion between the dur- face skin layer and the core layer are poor. On the other hand, if it exceeds 30 % by weight, the soft feeling of ••••# the resultant surface skim layer is poor. If the polyisobutylene as the ingredient C is less than 2 % by weight, the soft feeling and the moldability are poor. If it exceeds 30 % by weight, it is not pre¬ ferred since the surface becomes sticky and physical •**•' strength is deteriorated. If thtf Jiydrocarbon series rubber softening agent and/or polybutene m the ingredient D exceeds 20 % by weight, it leads to undesirable appearance (deformation) or the like after elapse of 1000 hours at 110*C and causes failure upon breaking, that is, breakage at the portions other than predetermined embrittled portions or scattering of broken pieces upon expansion of the air bag at -HO'C. In the present invention, a thermoplastic polymer constituting the surface skin layer 1A having JIS-A hardness of 20 to 90 is selected. If the hardness is less than the above-specified range, the moldability (for example, injection moldability) and mechanical strength are poor, which results in easy destruction although the flexibility is satisfactory. On the other hand, if the hardness exceeds the above-mentioned range, it is not practical although since the soft; feeling is poor, there is no problems in the moldability. The selected hardness within a range froni 20 to $0, although varying depending on the thickness of the surface skin layer, is preferably within ••• a range from 30 to 70 and, more preferably, from 40 to 65. The thermoplastic elastomer comprising the ingredients A - D for the surface skin layer lA in the; present invention can be prepared by a mechanical melt-kneading. Specifically, usual melt-kneaders such as banbury mixer, various kinds *•♦•*• of kneaders and extruders can be used. In the present inventioni the constituent materials for the surface skin layer may comprise in addition to the ingredients A - D, various kinds of other resins, elastomers, various kinds .* TOffTlfl- of fillers such as glass fibers, talc, calcium carbonate, silica and mica, pigments and stabilizers filled by a customary method, so long as the hardness is Kept within the above-mentioned range. The thickness of the surface skin layer 1A usually varies depending on the portions of the cover 1 and it is not quite uniform over the entire area. In the present invention, it ia preferred that those portions of more than 70 %, preferably, more than 80 % of the surface area of the surface skin layer iA have a thickness of greater *•** • than 0.5 mm. Although there is no particular restriction •*•• for the upper limit of the thickness, it is appropriate to * ** keep the thickness to less than about 10 mm, for example « #» in view of the design, economical property, soft feeling, operation performance and moldability of the air bag. further, with an aim of improving the soft feeling *»***» arid deduction of the weight of the surface skin layer IA, ****** foaming at a ratio of less than about 3.0 times may be applied, In the present invention, for the olefinic resin used as the constituent material for,the core layer IB and ****** having a modulus in flexure according to JIS-K7203 of 1000 to 7000 kg/cm and having a higher hardness than of the thermoplastic polymer tor the surface skin layef IA is, preferably, a homopolymer or a copolymer of -olefins> IS - for example, ethylene and propylene. They may be use4 alone or as a blend of two or more of them. Furthermore, an elastomer,, for example, an olefinic rubber comprising ethylene and -olefin may be added to the olefinic resin with an aim of improving the softness, cold impact shock resistance or the like, so long as the modulus in flexure and the hardness are within the above specified range. Further, various kinds of other resins, elastomers, various kind of fillers such as talc, calcium carbonate, silica or mica, pigments and stabilizers may be filled by a customary method so long the modulus and hardness are within the above-mentioned range. In a case where the elastomer is contained in the material for the core layer IB, the coatent is preferably not greatesr than 60 % by weight. If the olefinic rubber *#•• olefinic resin and the elastomer, there rises a problem in ,*»$% the moldability and the shape ratainabillty. In the present invention, if the olefinic resin con¬ stituting the core layer IB has modulus flexure of not # r greater than 1000 kg/cm or hardness lower than that of %«*** the thermoplastic elastomer for the surface skin layer 1A, It can not provide sufficient shape and is easily deformed by external pressure and, accordingly, not suitable as an air bag-containing cover. On the other hand, if the modulus - ik -,T,.~»- lrr,r„-rrr-vr„rl„-„rr-rr-r. -.-bt-w-s-BaCfOTT-sx—jf-rr—«-m-t-w=-«-s t.jiLii.uti -«=r~ r-T.T-->-i - - -.-- , „ , , —s™*™raTO.rW|rTpi«]BmjJI- in flexure exceeds 7000 kg/cu\ , the entire softness of the dual layer air bag cover is roor and the failure is liable to occur upon air bag operation at -40*C. Accordingly, the modulus in flexure is preferably greater than 1000 kg/cm and less than 7000 kg/cm , particularly, 2000 t 5000 kg/cm in view of the soft feeling, operation characteristics and shape retainability of the entire cover. There is no particular limit to the thickness of the core layer IB and It is generally about 0.5 to 5 mm and, preferably, 1 to 3 ram- In the present invention, the core layer 1 constituted *••• with such a thermoplastic resin is provided with embrittled * •* shapes in order that the core layer IB is bursted upon initiation of the air bag operation. As the embrittled shapes, there can be used continuous stitch-like slit shapes 1C, as well as various kinds of shapes such as •«*• notch-liksi shapes of reduced thickness. Further, there **"#% is no particular restriction to the position or range for forming the shapes, which may properly be determined depending on the shape and the strength of the core lay&r IB and the stresses caused upon air bag operation. \?#rf* Then, description will now be made to the method of manufacturing an air bag-containing cover according to the present invention. As the molding method for manufacturing the air bag- • r- » containing cover according to the present invention, usual molding methods adopted for thermoplastic resins can be mentioned and, in particular, injection molding method is preferred in view of the design or the like, As the injection molding method, there can t>e men¬ tioned, for example, a so-called insert injection method which comprises previously molding a core layer, placing the molding product to a die leaving a space for the surface skin layer and injection molding a surface skin material comprising a thermoplastic polymer to the surface skin layer portion, or a so-called double injection method which comprises molding a core layer, aparting a cavity die, putting a new cavity die having a space for a surface layer successively without taking the cofre molding product from the die and then injection molding the surface skin material * •«* In this case, it is necessary that the above-mentioned ••*•*• embrittled shapes, are formed t0 the core layer IB so that aii* bag is easily bursted upon initiation of the operation. As the embrittled shapes| there can be mentioned notch¬ like shapes of reduced thickness continuous stitch-like • • a t • • %••#* slit shape, etc* as described above. The shapes may be applied by molding the cover molding product with a die having such shape,s or by applying fabrication of provid¬ ing such shape and then laminating a surface skin layer thereover after molding the cover. In the air bag cover according to the present inven¬ tion, the surface skin layer 1A may be applied with coating, if necessary, for providing gorgeousness in a vehicle chamber and improving color matching with other interior parts and feeling. Coating of the surface skin layer 1A is also preferred in yiew of scratch resistance. AS has been described above specifically, since the surface layer in the air bag containing cover according to the present invention is soft, it provides a comfortable feeling due to its softness when a portion of a driver's .... body touches to the cover. Further, since the core layer is relatively hard, it is excellent in the shape retain-- ability and highly durable. Then4 upon operation of the air bag, the cover Is rapidly bursted due to the cover- bursting embrittled shapes. In addition, scattering of the core layer upon bursting of the cover can surely be prevented due to the soft surface skin layer and the evar Exhibits preferable breaking performance and it is excel- ,*•, * lent in endurance. ....•( In addition, the air bag-containing cover according to the present invention can be manufactured, for example, by a rationalized molding process such as a double Injec¬ tion method, simply, at high accuracy, with no occurrence of failed products, at high yield, effectively and effi- - 17 • at* • e • ciently, which enables remarkable cost down of the resul¬ tant products. The present invention will now be explained more specifically referring to examples and comparative examples, but it should be noted that the present invention is not restricted only to the following examples unless it goes beyond the scope of the invention. Examples 1-7, Comparative Examples 1-6 A core layer (1.0 - 3-0 mm thickness) applied with bursting stitch-like slits (29 slits, each of about 0.7 cm length) was molded from each of core materials shown in Table 1 by using an inline screw two-color injection :♦, molder with a die clamping pressure of 350 ton. Then, a S .•*. surface skin layer was injection molded by using each of a surface skin materials shown in Table 1 to a predetermined thickness on the core layer, to obtain a module cover 1 •!!!!* or air' t>a8 shovo in Fig. 1. In' Example 4, coating was applied on the surface skin ,••. ; layer. .♦*#*• The coating was applied by wiping the surface skin layer with isopropanol after injection molding of the cover, spray-coating a primer manufactured by Sakai Kagaku Co (MEX5440 and methyl ethyl ketone at 1:1 ratio) to 7 - urn thickness, drying them at a room temperature for V *• 4 * min, then coating a urathane top coat manufactured by Sakai Kagaku Co. (MEX-6047 : curing agent F-3I-': thinner 58u = 100 : 10 : 50) to 20 - 25 /im thickness, drying them at a room temperature for 10 min and then applying baking at 80*€ for 30 - 45 min. The resultant products were evaluated by the method to be described later and the results are shown in Table-2. The materials used shown in Table 1 and the manufac¬ turing methods are as follows. (Core Material) Pj-l ; Propylene-ethylene bloek copolymer res in (SPX 9800, manufactured by Mitsubushi Yuka Co.): MFR (23;OrC, 2.16 kg) = 1 g/10 min,. 1 ' ' 2 «• Modulus in flexure = OO kg/cm P»2 I Propylene-ethylene block copolymer resin (BC-8,. manufactured by Mitsubushi Yuka Co.): MFR (230*0, 2,16 kg) = 1.8 g/10 min, Modulus irt flexure = 10800 kg/cm2 P-3 : Ethylene-propylene rubber (Ep07p, manufactured by Nippon Synthetic Rubber Co.) * ML U00*C) = 70 Propylene conteht * 2y% T'd-W 1 Low pressure polyeithyletie resin (JX-20t manufactured by Mitsubushi Yuka Co.'}: MFR (190'C, 2.16 kg) = 5.5 g/10 min. Modulus in flexure : 9000 kg/cm (Manufacturing method for core material) 100 parts by weight of the core material with the blending composition as shown in Table-1 was kneaded with addition of 0.2 parts of Illuganox 1010 manufactured by Ciba Geigy Co. as a stabilizer and 0.5 parts by weight of carbon black In a twine screw extruder at 200"C. (Surface skin material) Ingredient A A-l: Hydroganated derivative of styrene - butadiene block copolymer: ;% StyrenQ content =» 33 wt£ Number average moiecuiar weight = 180000 A-2: Hydrogenated derivative of styrene - Isoprane block copolymer: • Styrene content = 13 wt% Number average molecular weight * 60G00 Ingredient B B-l: The same material as Pjrf-l used the for core material B-2i Propylene - ethlen blodk copolymer BC1» manufactured by Mitsubishi YUka Co.) & MPR 1230*Cf 2.16 kg) = 30 g/10 min modulus in flexure * 10000 kg/cm a • » t 4 * • a Ingredient C C-l ; Polyisobutylene (TETBAX 3T, manufactured by Nippon Petrochemic&l Co t): Viscosity average molecular weight = 30000 C-2 : Polyisobutylene {TETRAX 5T, manufactured by Nippon Petrochemical Co.): Viscosity average molecular weight = 50000 C-3 : Polyisobutynene (VISTANEX MML-100, manufactured by Exon Chemical) : Viscosity average molecular weight = 90000 D-l: Paraffinic rubber softening agent (OIL) (pw380, manufactured by Idemitsu Kosan Co.): Kinetic viscosity at 4o"C = 380 cSt D-2: polybutena (Nlsseki Polybutene HV-100, manufactured by Nippon Petrochemical Co.) number average molecular weight = 970 * (Manufacturing method for surface skin material) 100 parts by weight of each of the ingredients in a *«# * blending composition shown In Tabia 1 was kneaded with **.*,? addition of 0*2 parts by weight of Illuganox 1010 and 0.5 parta by weight of carbon black used for th© core material in a banbUtfy type kneader at 180"C for 20 mln into a sheet-like foriUi which was then fabricated into square pallets by using a sheet cutter, Comparative Example 7 For the comparison> an air bag-containing cover comprising two layers, that is, a surface skin layer made of high density urethane foams and a low density urethane core layer was manufactured and evaluated. Molding was conducted by previously molding and curing a core layer at low foaming density by a RIM urethane molding process, placing the same in a die for forming a surface skin layer and, further, applying an insert molding process for molding a surface skin layer in the same method. Fron gas was used as the foaming material for the molding of the surface skin layers The method required two curing steps and the productivity was poor. . The resultant air bag-csmtaining cover was evaluated by the same method as in Example 1 and the results are shown in Table 2. Comparative Example 8 For further comparison, an air bag-containing cover provided with reinforcing nets was manufactured and ...#.: evaluated. In this net'-incdrporated rim urethane molding, poly- esteir fibers are braided into a net-lika shape, which was cut by welding along the bursting shape of the cover §.nd metal fixtures (hooks) were attached for molding two layers - 22 in the same way as in Comparative Example 7. They were plaped in a rim die and applied with rim molding with urethane. In this case, Ffron gas was used as the foaming material and, after mold releasing, cured at 100*C for min. This method involves drawbacks that preparation of a safety skin layei* by the insertion of nets is difficult and the molding cycle was not effective. The resultant air bag-containing cover was evaluated in the same method as in Example 1 and the results are shown in Table 2. As apparent from Table 2, the air bag-containing covers according to the present invention shown in Examples 1-7 were excellent for the soft feeling, shape retainability, davaloping test at -40*C, endurance test at llp*€ for 500 hours and productivity. c *»• « • iEvaluation Method) (1) Soft Feeling As shown in Fig. 1, a module cover incorporated with an air bag 2, an air bag-containing cover 1, retainers (attaching metal) lii 5 and an inflator 3, or a cover 1 alone was left at -20*G — 80oC such that the temperature of the sample reached atmospheric temperature and the covers ware evaluated by means of feeling of hands of persons. Evaluation was made by the number of persons who sensed soft feeling and indicated by "o" if ten out of ten persons felt soft and " a" if 8 out of 10 persons felt soft, "x" means that the number of persons who felt soft was less than 8. (2) Shape Retainabiiity A module cover attached with the air bag 2, the air bag-eontainihg cover 1 and the retainer (metal fixtures) 4, 5 and the inflator 3i as shown in Fig* 1 or the cover 1 alone was left in the following heat cycles, i«e., 100*C x 4 hr -* -40*0 x 4 hp -> 15*C x 98% (BH) 4 hr -40*C, 4hr for 10 cycles, and the state of deformation during or after the test was observed, (o) indicates suitability as the air bag-containing cover with scarce deformation and (x.) means insuitability as the air bag-c6ntaining cover with remarkable deformatioh. (3) Developing Test at -40*C ****** The assembled module in (l) and (2) above were attached to a steering wheel, left at 40*C for such a time as reaching the temperature of thei atmosphere and the • developing test was applied within onei min,. (x) means insuitability as the air bag, not operating normally as the air bag. Such as the module cover was cracked and scattered or the covet* was cracked into sharp shapes to tear the bag and to) means suitability showing that the c »« ,*-*„ f" air bag operated normally. (4) Endurance Test at 110*C for 1000 hours After aging the module cover under the above-mentioned conditions by a gear type thermal aging tester, -tO*C developing test was applied in accordance with the test method in (3) above and, further, the appearance of the module cover was compared between before and the after the aging, "x" means remarkable change such as warping, de¬ formation and bleeding of the softening agent to the core material, while "o" means with no such changes. (5) Productivity products were manufactured successively and checked for the moldability (for example, mold releasability, or j»t short shot), size an.d weight and, in particular, appearance of products for the surface skin layer (stickiness, dela- mination in the gate portion, appearance of weld, molding sink flow markr appearance of grain, unevenness in luster, » warping, or the like)., "o" means that the are the products passed * " A'* means that more than 90% of the products » passes and "x" means that less than 90$ of them passed the check. 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IV ri '. <U o o B 12a, e Ma¬ 1 g »& ui i> J ? 1J i e&uBiujo,] Jpd ingredient B ingredient C ingredient D wiiatjo olaihbd ic frhe claims defining the InvenBon are as follows: {%) An air bag-containing cover comprising: a surface skin layer made of a thermoplastic polymer containing the following ingredients A, B, C and D: ingredient A : a hydrogenated derivative of a block copolymer comprising styrene and conjugated diene, an olefihic resin, a polylsobutylene with a viscosity average molecular weight of not greater than 70,000, and a hydrocarbon series rubber softening agent „ with a kinetic viscosity at 40*C of not greater than 500 cSt and/or polybutene ith a number average molecular weight of not greater than 2500, in which blending ratio is : ingredient A » 40 to 80 % by weight, ingredient B « 5 to 30 % by weight, ingredient G 2 to 30 % by weight ingredient D * 0 to 20 38,by weight, and having &' JIS-A hardness according to JIS-K6301 of from to 90, and a core layar madd of an olefinic resin having a modulus iti flexure according to JIS-K7203 of from 1000 to n An air bag-containing cover comprises: a surface skin layer made of a thermoplastic polymer containing 40-80 weight % ingredient A: a hydrogenated derivative of a block copolymer comprising styrene and conjugated diene, 5 to 30 weight % ingredient B: an olefinic resin, 2 to 30 weight % ingredient C: polyisobutylene with a viscosity average molecular weight of not greater than 70,000, and 0 to 20 weight % ingredient D: a hydrocarbon series rubber softening agent with a kinetic viscosity at 40 DEG C of not greater than 500 cSt and/or polybutene with a number average molecular weight of not greater than 2500, in which the thermoplastic polymer has a JIS-A hardness according to JIS-K6301 of from 20 to 90, and a core layer comprising an olefinic resin having a modulus in flexure according to JIS-K7203 of from 1000 to 700 kg/cm<2>, in which the core layer has a higher hardness than that of the surface skinlayer, and the core layer has a portion (1c) for easily bursting the cover upon initiation of the air bag operation. <IMAGE> ingredient B ingredient C ingredient D wiiatjo olaihbd ic frhe claims defining the InvenBon are as follows:
{%) An air bag-containing cover comprising:
a surface skin layer made of a thermoplastic polymer containing the following ingredients A, B, C and D:
ingredient A : a hydrogenated derivative of a block copolymer comprising styrene and conjugated diene, an olefihic resin, a polylsobutylene with a viscosity average molecular weight of not greater than 70,000, and a hydrocarbon series rubber softening agent „ with a kinetic viscosity at 40*C of not greater than 500 cSt and/or polybutene ith a number average molecular weight of not greater than 2500, in which blending ratio is :
ingredient A » 40 to 80 % by weight, ingredient B « 5 to 30 % by weight, ingredient G 2 to 30 % by weight ingredient D * 0 to 20 38,by weight, and having &' JIS-A hardness according to JIS-K6301 of from to 90, and a core layar madd of an olefinic resin having a modulus iti flexure according to JIS-K7203 of from 1000 to n 7000 kg/cm2, in which said core layer has a higher hardness than that of said surface skin layer, and said core layer has a portion for easily bursting the cover upon initiation of the air hag operation.
(2) A cover as defined in claim 1, wherein the portion for easily bursting the cover is notch-like thin walled portions or stitch-like slits disposed linearly.
(3) A cover as defined in claim 1, wherein the ** * ingredient A is a hydrogenated derivative of a styrenic a • • •u • * block copolymer typically represented, for example, by the •• general formula:
J .". - < X-Y, X4Y-X)ri or X4Y-XY } #***•* wherein X represents a polymer block of styrene, Y is an •****• elastomeric polymer block of conjugated diene and n is an integer of 1 to 5.
(4) A cover as defined in claim 3, wherein the monomer of the conjugated diene for the polymer block Y in each of the formulae described above is butadiene or isoprene.
A (16) A cover as defined in claim 14, wherein the ratio of the elastomer to the total amount of the olefinic resin and the elastomer is less than 60 % by weight.
(17) A cover as defined in claim 1, wherein the thickness of the core layer is from 0.5 to 5 mm.
(18) A covSr as defined in claim 1, wherein the surface of the surface skin layer isvapplied with coating.
•t »• (19) An air bag device comprising:
at base retainer to be attached with an sir bag, a folded air bag attached to said base retainer, an inflater attached to said base retainer so as to * inject a gas into the air bag so as to rapidly develop said air bag and a cover as defined in <?laim 1, covering the air bag and secured to the base retainer.
(20) An air bag-containing cover substantially as hereinbefore described with reference to the accompanying drawings.
DATED this FIFTH day pf DECEMBER 1990 Takata Corporation Patefit Attorneys for the Applicant SPftUSON & FERGUSON (5) A cover as defined in claim 3, wherein the ratio of the styrene block polymer X in the entire block copolymer of the ingredient A is from 5 to 40 % by weight.
(6) A cover as defined in claim 3i wherein the number average molecular weight of the polymer block X is from 5000 to 125000 and the number average molecular weight of the polymer block Y is from 15000 to 250000.
(7) A cover as defined in claim 1, wherein the e • • • t • * v ingredient B is a homopolymer or copolymer of (-olefin, fflP mminfU-frT \ethylene, propylene and butene-L (8) A cover as defined in claim 1, wherein the ingredient C is a high molecular weight polyisobutylene Svj.V>s.Vxv.ick\Vu r\o nnnppnly hinvTngXdouble bonds in the molecular chain and having a bonding structure:
.fc(CH3)2-CH2-*K (9) A cover as defined in claim 1, wherein the hydro¬ carbon series rubber softening agent for the ingredient D is a paraffinid or naphthenic extender oil or process oil.
(10) A eovGr as defined in claim 1, wherein the poly- butene with th# number average maleeular weight of not greater than 2500 for the ingredient D comprises mainly isobutylane and partially n-butene copolymerized therewith.
(11) A cover as defined in claim 1, wherein the surface skin layer 1A has a thickness from 0.5 mm to 10 mm for more than 70 % of the surface area of the surface skill layer 1A.
(12) A cover as defined in claim I, wherein the surface skin layer 1A is applied with foaming at a ratio of less than about 3.0 times with an aim of improving the soft feeling and reduction of the weight.
t* * it »• • r « *» (13) A cover as defined in claim 1, wherein the 2 *••',, olefinic resin for the core layer is a homopolymer or ccpolymer of -olefin -for-qxnmplfflmethylene and propylene * "#t**t (1) A cover as defined in claim lt wherein the core *, # layer further contains an elastomer.
(15) A cover as defined in claim 14, wherein the elastomer is an olefinic rubber comprising ethylene and [-Olefin.