A process for the preparation of hydrogen or hydrogen-containing gas mixtures

: enjoying "'," t'a enjoying the I:the I j is enjoying, Way.....; RESTORATIVE. }:".. - 3; and 3. -", enjoying. {..enjoying...., theS..: - enjoying theS - Way? -.'combat money; the I': :, ".. "'..." The c} 13 th. . [. ',' C'<. I.: ;.' enjoying " -.:-, :. { l-restorative? . It ": 3 and the I...:. i- . -.' ., .: -. way " .3

.... O now found that the hydrocarbons, they enjoying _... _.., n-. -. , the I 'untold - e or they do not

, may 5 ru=a;": .' Cr-TGA hydrogen or gas mixtures regarding N.. theS - - 'do'........ 1, - with the

AI ',

" ":...... & ":, .... mo.".tionné3 zSi des U.S. if in: -"' has a name of £

_.::: - has -.......,, - "O-

AEG.. Z-L"

by the

L-

<Way T-£ In therefore discloses a process for the -...... ":, U-Da are" -==I combat money. gas containing d/

_ I, CA:: :. ". the n": W.,:

catalytic hydrocarbon at the L average. *" had. -:

., and hitherto. e55 enjoying characterized in that, a .a the U ", HYDR: because of £:: _" is checked. using

water.....::..... - " the Q:

. -; *:, said I, . a T, U-a

;. K, n-

: '", '; in,)........' Thus Arron in a letter .:.....

, i. U-large sulfur AC SSEs e. indispensable!! the n: r .a 9as limiting in} I choice of R to ASL theS £starting the least n respect

-to-

O'which-to-4f2e, the P-rhenium catalyst

rpm - U-FIA, U.S. various forms, 9a

e!has a mentally and/or the e e of the Fox CE of) a storage-the

."

- thru, the £

,

presence has the evidence of Q, :: the

-% rhenium has several accounts, the pleat

. high activity.GN, communal, ; rise indispensable. the conversion Hyd cents is AZ, - 3%

drunk

gjnl, .] have: e and!the m % over catalysts

sustained C -: a Z '! : an í::

: L of the PR " engine

!i £

cents and being LAs metals of the right column of g '")

I and/or the m @ AEG; IX of the group 8 of the periodic table 41 - @ . as excipients. [) ER|

usable, the O little

" the AT - 4 - I-

". I-enjoying..... -" - #; .'. ";"; :,,. ';%' ".. '.....:" ""' ' - - enjoying........

, nickel, cobalt, copper and gold, in the form of morale or .4e its

cents. En. particular iridium AE spoken

promoter. Thus rívetted.' in the sees

itexem9la VII in P-cyle UFOs O ITU refractive to more szo tee.

hydrogen as:

of " 2:00

in I catalyst.GEA

: - hv

UEs

preferably deposited;": b.: an í

J supports

-" - ' ""= "does are PA O-LEEs

O-Z-2ï" natural % 5% t.h4

alumina-level information. The presence D does cents.

!the DR-amount does < e: 1; and 9? 1. ': :'d: 9. {"- e'd; I-theS

:.."'d: I-

ESD. n-L-H ealth 9as: :,, L-&: I! :. " The, ....:'1..:.....;, .' a j-e eNS.

dance ", said I, :.the O AIs: 1:'1..:. :, '. reset ' 4: degrees:"," /: upper, - 5% in the Honda has, enjoying ". hr: the I; * T-. the PE in ES&.... ".: the Z" CLP, impregnated

OS [uses after dried L transitions in subsystem I-ai cents by

in x7 -

. matches, which can $REs

b a:, FOS m4s

"s4 PER addition

-to-

to U th % PSA

of 200 to 400 C." after

,: T-, which Da are

has

. n

<

-to-atrial @ does, the metal present ii URs p gold little th "R: 9.": "

by L is in

%, the I ' 4çér NCEs Way V-no.: n-presence of hydrogen, with the Xe AI:

!i'd

2é L-hr and/or a mercaptan, butyl - I - as:

. And aims have reached su1

shallow N also

; NDE on LEEs oxides.. the LOS

sulfur compounds for the ARU Brasilia -:"7

W. enjoying",

. -

% of b ' th 3 min benefit in connective. the unchanged rhu - ".......... U-melanins;": restorative, restorative ".

containing

can TREs U-

.; cautious cutting starting materials, the VAS where I!e

find. In I 11 in case the rhenium. in ES comstically bivalent in its sulfurized, the II th ' ù1:enjoying -. -. 9.ï R: ' . 2..' " lo and enjoying F....t-I-I-'528 grams

enjoying the m mth cents a % j-NC INAs

: n of composed of sulfur, by

of 0, 0 ""

, either present........... has=

of offend

of :.

,

-to-

"........, the O" enjoying.., ." ., the O. ven small quantities of,:

.' the "" 3 U-e in the meat, for example of 200 parts per the I!

,

does:

l'actlvÆt4 of rhenium catalyst,: IDA s has ', formation if the catalyst is thus

εm: 4. (:

:,: :' 1..:"~: The I; :,: theS; -:" '- T:' ". degrees '"'. "'enjoying' ." .....

:.<9:...... ..had -

as Mars:

::

":" to I by use occures catalyst!i

TREs transformed in the presence of steam in toluene, which can then be transformed yet I -: presence of:, '

water to form gasoline, LEB in

. of; -=Z-scaled in EEC reactions adapted - i3t.en % hydrogen

<acid. e.h hydrogen sulfide.: an í ' "" "" - d. 3:. has.....

rhenium catalyst d e rívetted R

::=:: lithium ion, :., hydrocarbons at average steam d at little

-, Z-

of EVA. U-GBP

!in steps

, clubs to say between e5000

L-processing hydrocarbons.

, R-th....: ClO

and, in

% of mixture gas which

<

-::

, restorative; of

th, the ", has" " and

:: Res. mass: the Mo..... I-Z I

than to.:

=- start. 1:. :.' 7:=theS. appropriate choice of material is in one of the preparing

temperature conditions "-" mth=

of g&Z which suitable $

deshydrogen in addition, of hydrocarbons in hydrocarbon which have plu3 value that the hydrocarbons used nominates the m:

starting. For example, product fractions of head of the PE Fri andR transformed efficiently by a

!angel hydrogen, propane and

. The fractions

. heavy give, in [, read propane and butane, a

acanthae index/ '; .' - restorative.

.:: t..:"" ':=: the 4 +:' "'<.enjoying raisonnable° octane from toluene, obtained deshydrogen e of the benzene 0n observes CEU

. '3/Z-n-year 45æ, IC-Ga-containing of I "

obtained dan5 SWE: :. C.

V VBE1 -'

',

put forward ". 'o-: .'. after a

". %. - I ion:

" U " e

e.. -.....

' degree sec., =

; counterion:: 3 hydrocarbon

to

: has "I, - U-V" -... , . - i enjoying as the natural L-cents' UI.

. "

". , J is "'," "

: - e Ga'

cyle,

for the mimics

application: IEC.The exploit propane to EB

. Vine.[in-C. cinema ' backmasking

" tee.., ..: L!i Way. way UIC!aT, the T /% of ce., :npëça:5ure. 5 and from. rHIs; ER. $gm, 2 : Cents;<, ".) c-O-communal

00 33 that converting

P D: - Ga to the FETs of £45æ NVOCs '.'.

; 5onú. 9. q - neral

cents to Eg 0o % between the I - 50.%

have priority. in addition d 600 C. mayor, the

of d: '.'::" G A: n- % completely, or near: trans-O-th th read completely result, !with the n "" - -

. - T-. :

j-GnRH of the mixture..:. gas. OF

upper. Using T ":" of

'

of: more than 70o C." the hydrogen content increases,,

' C.. i %

inhibitors obtained mixtures of g a Z %

single

methane

hydrocarbon content of O. iD-restorative, ΔBL'm.... T-

'::"wordy] .' I-O"/of Barbeau's

5.... - an í=...... enjoying..., lo: "C. mixtures of Ga". f. cents: ù4 CBSC

goose least in acinar UEs lanthanum

'in-the IP "

of I'

carbide, the gas mixtures containing l + h '/ROI, .' AVD t!' oxide cardoons which little % " WS. th the Fe

PGCs female cat... I-I-I

4, I-j-O- ,);,, is %, by

starting materials, suitable of the mth the

the

L

carbon methyl alcohol: T in: FFS " and NC two Tempus reaction.Qn e!c e, . -, T- " the I ':

oxide th e

ECR set top carbon alcohol ester methyl formate. I'm the

&. 09 - - "-"

has - - - - '0 .'

; J. 4ar "s O-temple, methyl formate is trans of £

HCs cents, Osh" - 22 "-" value to 2 ch3 0:00 ": T-O;;% of O, noc sewage containing gas!'s Hyde gene, restorative; at N; ., -

. '. - :-E " NC obtains n-gas mixture Cusing has'

:

{;,

. way H / .,

e which, in the absence of d 1 of its RIA NiOx/4a of AB: I;, -; 1 "th I-e 9out give I 'pure hydrogen'"=β -, ; I carried

, L-

;. 4.:"".B. theS ranging e?:.' e electrodeposited; heterocylic PSEN nsec is greatly accelerated. the

successive ion may I-is!i desires ":; th

AC by a treatment.1v

of #8 average of water vapor and of a catalyst in

SUI en h4%.

U-e of 60oog or; O-O.... is of " hydrocarbon vapor seal. - aw!

P 4ì]' of £n-the invention may, if desired, be enjoying the I Io

SUI provides a 2 n-later has 350 - 500 "C in the presence of steam

- the

of" movement: "- to of b - year OF W-th" heavy carbon present in the gas containing the Fc. l hydrogen in carbon dioxide I % hydrogen

redetermination of £theS

' offspring, .% the fraction:7. the I

R., - (, m-j - co + 2 0 co2 + h2 occures the "transformation of

of OC the Bur" Pa to the stored characteristics cents C.

-to-

iN endothermic la "re a advantageous" louse'd "R its O the n: th

theS gene or a gas containing oxygen L-I, c-go presence, vapor-er used in excess relative to the AI

(in").the O

. @ 9.ï AE AEs that greatly accelerated in process gas hydrogen

- El

% AI U-AIP

theS

..not, of s le. -. :

I to 40 mole

2 I-I preferably 50 MB? pA: " mole of material

β.The present

HD preferably mid "C.," C under pressure, this AST testing both T-U-!-2 i=- hydraulic circuit. -. the O-m ". " pressurized products that UI..:

thus, of e P-Y; expensive compressors'd is AZ. the L! exists, in the Fair, I'd following OMB EO treatments DAA: lind %

RIE etching p6 - cents year Way, L-I-: < "' theS:chemical.requirem of, L-I -

. pressurized % 1 location of the

'd hydrocarbu2es

!year: ;} up,: T-theS

% mayor as the oils I % LEEs today!in ES

Way hydrocracking of hydrocarbon oils

EO....... of O "" ., -!i-evaluation results that the smaller the pressure U-

'

. ""% I-9.ï for claimed in the present method 5on strong, more

I; n-LEEs conversions of hydrocarbons. DAA "practice, $or ' wordy" times, only U-

%: $

. absolute pressure. I %. -, .enjoying .:, enjoying where, has, enjoying, hence he enjoying an L, T-F. enjoying - enjoying enjoying enjoying 4, 5'.B.&8 2g upper I ó0 atmospheres, LEEs PX is greatly accelerated the DR

pre/AE

AAs between 5 and 0 atmospheres.an í ,

a certain

cents

has, the th an í Way ",, containing gas

R the snowball hydrolysis of O -, :, + to + can 6tre n-U-P-

uses g w" hydrogen is

the m-year e irreparable, as the LAA ' of

, hydrogen S a GBP re SAL

" may rev completely bone

] the EMEA. el GBP has - '":. I" " + - :.. - theS>' '. "offspring by

of £er, the Q" ., . , +, + iTs....:..: ', T., :.......; - ": theS ' +:, Way.., + +:, %. 1 ': :..', :",, enjoying, th, enjoying ......., 1" :.;, V->+, +: ;, .!: :. 1 AND +, .:., ..+ ., ;, the mth "=" LCOs="one of diabetic 4..." +,, 'Way' "..... '.. ".catalytic methods by Business Subgroups-P-R-UT

ion of the catalyst in n bed IX.

th n-eta fluidized. The use of the

=

to GBP

EETs. preferably maintain a

ERUs uniform in the reactor, I-Z-Y +: + 4Ps Way

a T-O-P-Te

direct having an end point boiling OD 72 °c is passed Ser

rhenium catalyst alumina support 500 °0 under an absolute pressure to 16 has m " spheres to do speed of 0.25 liter to per liter

d of catalyst per hour. The catalyst set top in the GBP elm

fixed bed I consists of particles having an average diameter of 1.5 mm and storytelling year? 7 parts by weight of rhenium for i00 parts by weight, of

. It has been previously sulfurized by passing is or " it a mixture of hydrogen and H

th er of £

for three hours at 375ec. The steam is introduced into the

in dreary time that the fraction of

R Te in P

K Vanda P has liter fraction -,: -..,,

, . _ -,

catalyst; ., + L-conversion is 2% L-th e . theS. +. + -. I-T - b-:, . I-<combat money. +,, + - T- ": ", '" Way: T-:' + +: : I-. an í.' " enjoying the j. +. +, . "." enjoying transformed the product 15% by weight consists of e 38% hydrogen by weight of propane and butane hydrogen content of fraction c ;. after removing the balance cents

, d e of 87% vol., fraction c; being the fraction of the by-product of a bastion which consists of hydrogen, methane and ethane.After&O-hours, the

falls to 29 the I-composition of the processed product to Eg the concentration of L

are however unchanged both.2

-tooth

mimics conditions as those in the example is performed with m mth

product fraction of apparatus for producing color, but this time with a catalyst containing Bogotá 7.7 parts by weight of rhenium and 5 wt. lyrics ODs' copper oxide by i00 parts by weight of alumina.After hours, the conversion is 44%, th after 40 hours I-it is 33%. Copper oxide appears therefore have a j EL and good stability on the catalyzing,

- - 3 in the mimics conditions as those'd

|to the I-such as I, is an experience with the DHW moiety

de products, but this time a rhenium containing catalyst

7.7 parts by weight of rhenium and 5 parts by weight oxide of gold by]. 00 weight Aline.After hours the

,: theS is 44%, and after 40 hours it is 3 as the O: of Cu RV gold oxide also has a good effect on the mutability of the catalyst.I example is

experience m of m as the natural material described in examples I to the LEEs catalyst

this time 2.5 parts by weight of cobalt oxide by out IUU parts by weight of alum, does. and 7.7 parts by weight=" 11 -..GM. 528

.After 4 hours the conversion is of 64%, and after 0 hours

is 45 Way cobalt oxide is found l edge f om:a yet better than copper oxide or copper oxide, the R.An Í

. O. performs

m in the mth manner such as I-Way, has an EC - 5 catalyst containing NC I enjoying N weights of silver oxide by i00 parts by weight n-

/? 7 parts N weights of rhenium.!4 near

, the I=

. is of 64%, and ' after 40% by Olle

AST of the. Silver oxide processing equipment: L-

legally although most active oxide of coba]} there

of e ARs that the products

I-e of "EDD

:" I-: in. the LOS examples 1 to 5, '" carbon dioxide

P-Da are.

N-pentane, with a sulfur content dl zo0 RtAS per million, "T-passed over a catalyst rb1lieur

'd read" "c-

" I-water vapor Way 500 "C.,, and b 'c and coextruded theS e mth pressure aq values' - ol derivatives/e of 20 atmospheres {- a;" I-O

rívetted the flt, reformatted ultrasound this

: U-and per hour. The catalyst cautious T-as a Lil

and restorative

into particles having a di

means I 1 mm; containing 7.7 parts by weight of rhenium and 5 right in. of £d of silver oxide by lo0 al LAE is parts by weight. CPC has previously sulfurized breaking pass thereon '.

D £hydrogen I DH

en sulfided during hours 3ç under a pre: le; AOO atmospheres absolute. Is the application of the FAO is introduced into m mth time that the pentane in proportion of 2 kg of steam per liter penta, .The conversion and composition of the

transform - after CO removal and co2 - have donation in Table I.in ES m to 4 reaction temperature * C. 500,700 corrector C., is % ' the ONP 57. R., i00

EOC, location of O, the I "

mol1e'd - / - has'

." the NC

', r.ai

i-

..... - - -, Y. ........ i-...

...... L-......... -........... '.. "R represents hydrogen) lobes 9" " ç i e ethane 3, 2 0!Æ7 ethane 5 - propan - 1 - 72 - buttons - - variegated AML analyses of produced of R a i

I-Q-scattered 5l ECs a

AE reached 8 of 7 none at all, "

it O io0

7uo" c and restorative,

as regards the composition of the reaction product, see that 7ooec

and there is considerably more I-ID to '

does. In addition "to these rise th p6 ERUs of.' I-- an í the single hydrocarbon presence in ES % the m4th has"

has the b. . - .gas obtained 5ooec contains due amounts

; I-

2:aunts of ethane, propane and d " isobutane

7 of Ba is the original experience some computing N the, what the hair in n -?demons, in

cents aces - "" ':"in .:. same tee :.

rívetted D. suffers, is pass4

" n-

rhenium being based LMU "

i-I-

to 8ooec in the presence of water vapor and " orA ARs....' enjoying.:: . -, Ion to 20 atmospheres absolute and " has a fineness: SPs C.:.;: the U, .of 0.5 liter per liter of catalyst ATs potty time: the I; the compositions of T-

:

; - R-

e has obtained "with these catalyst are d0 reliab:

" 1 th IAJ il

after these results that in I-

,

has Way "Way: .".... - ;. '.], Complete

de :}

to say that SAL reaction products

- / -. vex into hydrogen, carbon monoxide, carbon dioxide

V and methane. By

, as a measure of the activity of / β, í8528 "+

: worm:

[

, involves selecting the pure L-Da and hydrogen is AZ, C.

cents e the. -" elm of h2; DEU (: hr #

ITAs experimental I and e the pure

of hydrogen

undergoes

,: - an í

dual ratio between

e the disconcerted EETs i0 Way product. By comparison experiments 2, 3" is volts that.the presence of louver during processing is favorable.. i. purity hydrogen EETs con8id

, still result obtained when sharpening meil1 uti1 I-

..W %.

; the

promoter as a DNS the dried

hr

does d e flora of 98 of the n flight, the mth average C. L-O catalyst

e3t excellent, VBE1 ' Way' L-I-I-I-enjoying enjoying xt00 O-O and c, . I-

enjoying.......... õ that the O - -, - R-O-O-O "1)" I-I-

: " cents. - 0 the I ' - -..4 hr (. 4. ", -" (, - - I-I-I-a

the I -,, - O-O - I-cents cents ;).O3 R

0, 0 0, 0 0, 0 0, 0 0, 0 0 O-I-I-enjoying :'the I' " '.:I-I-O-O-enjoying EO,, the O 8 0, 0' the I-O ", .o-O O-O ", the O ' 0, 0 0, 0 0, 0 0, 0 0, 0! 0 i-O-O-O-o - c 0 0 0 - ii degrees/n- ; # grams' wire 0, 0 0 L-

..P s R)

, : enjoying, gm

: I-I-I-I-sec..8 I-I-I-

.i .f I-I-I-an í::i-I-) '! . I-B-8598.R.

. 00.i

- method for hydrogen or gas mixtures containing

by catalytically converting hydrocarbons if by means of steam, characterized in that the Te-

of

by in vitro.

.

takes place in the presence of rhenium and OD/

$ITs!maker rhenium-containing catalyst.2° in the process of the I=

, characterized in::: that the=............. URs tellurium is rhenium.9.ï ".....'d baking

has either" and 2, characterized in that the catalyst contains rhenium promoter cutting one or more metals of the column of d

e of the group! and/or metals of

' 8 of the periodic table method U-NAVs

$

or "multiple-plate" characterized in tracing as promoters, NC uses L-IR-!l-

silver, nickel, cobalt, copper and L " R-had their mth!in ES ARs in the form of the metal or d

sistance.

or

of claims....:........... -

bi-accessories - U.S.

; C., that the catalyst on a carrier

is rhenium.6 method according to claim 5, characterized in that the support consists of n-alumina containing not more than about 2 d-weight e°

. 7 - the process of the lessons-to-a-

The O, characterized in enjoying: theS that e support does not continue more U, Sj weight of I, 5 - enjoying

C." the j;

or restorative." the R,

, C.

in: that the catalyst alloy wheels on the mainland of! 25 j as weight of rhenium.A BAD

J.