INTERLAYER FOR ELECTRONIC DEVICES

As used in the present specification, terms OFET and FET the thin film transistors (TFTs) and organic thin film transistors (OTFTs) subsets of such a device known as subclasses which it will be appreciated that the frame contains, constitution: TFT or FET is specification of organic dielectric material and having a, OTFT or OFET of organic semiconductor material and said-mentioned organic dielectric material includes both.

As used in the present specification, the terms "intermediate layer", device 2 to different grain size ranges are present, layers or among components, for example gate dielectric and a dielectric layer such and a gate electrode is an electrode such as a an electronic or organic in an electronic device which means that layer will understand is.

Furthermore, terms "dielectric" and "insulating" the present specification the pixels include a loader is used it will be appreciated. Therefore, insulating layer to a dielectric layer, said layer including a mention of. Furthermore, as used in the present specification, the terms "organic electronic device", terms "organic semiconductor device" as defined and said FET and OFET, such includes such a device some of it includes a first unit is connected to the is it will be appreciated.

As used in the present specification, any pendant groups when used to described of expression "light reactive and/or cross-linkable" the, entering the crosslinking reaction reactive as a result a reaction actinic radiation, or actinic radiation crosslinked but insensitive to a crosslinking reaction in the presence of active agent group that an alarm is to be which means that will understood.

As used in the present specification, terms "polymer" one or more other type of repeat units (molecules minimum constituting unit) terms known and often sweep out a backbone of "oligomer", "copolymer", including "homopolymer" or the like a molecules will understood. Also, terms polymer, the polymer per se while addition, such for synthesis of hyperbranched polymer disclosure that are involved in sunscreens, catalysts, and other elements including residue from, will understood, where such residues covalently there does not integrated. understood. Furthermore, such components and other residues, after polymerization during purification processes normally are installed on the terminal, between the containers conventional solvents or dispersion polymer and when being transferred between whips together generally immiscible or mixed with polymer to remain on a..

As used in the present specification, terms "polymer composition" specification the at least one polymer at least one of polymers and polymer composition the provision or properties specifically for or reforming, at least one polymer one or more added to. different flows of material are. Polymer substrate polymer composition-bandwidth signal carrying a thereon to layers or structures called vehicle form a is it will be appreciated. An exemplary materials are solvents, oxide prevention agents , storehouse commencement system , photomultiplier dominations , sunscreens crosslinked or crosslinkable moiety which, are reactive diluent, acid [...] , level ring system and adhesion promoter includes but, as they are on. Furthermore, polymer composition exemplary materials referred to said addition, blend of at least one in addition 2 which may be encompasses is it will be appreciated.

The present specification as defined in the, terms "polycycloolefins", "polycyclic olefin", and "norbornene-type" is used can be interchangeably respect to one another, an addition polymerizable monomers, or hereinafter A1 or A2 structure of such as indicated by at least one norbornene site the resulting for inclusively refers to repeating units.. Simplest norbornene-type type or polycyclic olefin monomer bicyclo [2.2.1]-2-n (A1) is often norbornene called methylhept is referred.

However, as used in the present specification, terms "norbornene-type monomer" or "norbornene-type repeating units" the, norbornene self mixture by the addition of an initiator as well as any substituted norbornene, or its substituted or nonsubstituted higher order cyclic derivatives are also is understood referring to, for example in structures hereinafter wherein B1 and B2 of the m greater than 0.

Pendant supplied through a water pipe of the norbornene by replacing the, polymeric characteristics have respective first order to satisfy the need of applications can be customized. Producing the same and to the norbornene are the development procedure for polymerization of norbornene are method and a variety of designs that are of the gas at two different temperatures to regions and flexibility and against tooth exhibits tolerances. Specific contain a pendant in addition to polymerization of monomer with, a monomer having different functions to form a final materials are randomly can be polymerized and, wherein said monomers of types and ratios as a result polymer the overall bulk characteristics. by quantizing data.

As used in the present specification, the "hydrocarbyl", each carbon is one or more hydrogen atoms with the appropriately and containing carbon backbone refers to a radical or group to the compound, .. The terms "halo [...] ", hydrogen atom where at least one of halogen atoms hydrogen repeating part, but not all, but (F, Cl, Br, I) [...] hydroperoxide replaced by. referring to. Terms replaced by halogen hydrogen each [...] hydroperoxide [...]. referring to. Hydrocarbyl current examples, but not limited to, an, C₁-C₂₅ alkyl, C₂-C₂₄ alkenyl, C₂-C₂₄ alkynyl, C₅-C₂₅ cycloalkyl, C₆-C₂₄ aryl or C₇-C₂₄ aralkyl, which include but, as they are on. Representative alkyl are methyl, ethyl, propyl, isopropyl, butyl, isobutyl, sec-butyl, tert-butyl, neopentyl, neopentyl, cyclohexyl, [...] , octyl, nonyl, but includes and midifiers targeting, as they are on. Representative alkenyl group are vinyl, propenyl, butenyl and [...] include but, as they are on. Representative alkynyl are ethinyl, 1-propynyl, 2-propynyl, 1-2-butyrate and vinyl butyrate neel include but, as they are on. Representative group, a cycloalkyl group, an are cyclobutane, and R4 represents cyclopentyl, cyclohexyl, and octyl substituted but to the s, as they are on. Representative aryl are phenyl, biphenyl, naphthyl and do not sprout three Neel include but, as they are on. Representative C1 to C16 aralkyl are are benzyl, phenethyl and pen butyl dyssomnias, including but, as they are on.

The present specification the term as used in the "halo [...] " referred to include but regions that hydrocarbyl, wherein at least one hydrogen atoms in is replaced by halogen atom (e.g., fluoro methyl) from, perhalogenated, also referred to, on high fluidity hydrofluorocarbons all hydrogen atoms when replaced by halogen atom (e.g., trifluoromethyl or difluoromethyl) a halogen capable of same CS changes the degree of is present. For example, types of the present invention embodiment that may be useful in the formula are halogenated alkyl C_z X_2z+1 partially or completely halogenated alkyl element can be, wherein X in an independently halogen or hydrogen; the z is chosen from an integer from 1 to 25. In some embodiment, X independently from each other hydrogen, chlorine, fluorine, bromine and/or iodine is chosen from. In other embodiment, X independently from each other is hydrogen or fluorine. Therefore, representative halo- [...][...] and said-mentioned exemplary on hydrocarbyl which is exemplified by the, wherein number of suitable hydrogen atom are respectively halogen atoms, is replacement.

Furthermore, terms "hydrocarbyl", "halo [...] " and definition of " [...] ", O where at least one of carbon atoms, N, are independently selected from P or Si replaced by hetero-atoms in a at a portion including. These heteroatom containing the sites, for example, the engine thereby for reducing fuel consumption, ethers, epoxy current, glycidyl ethers, alcohol, carboxylic the luck thread it buys type , esters, low velocity turbulent current, amines, imine current, amides, phenol, amido-phenol, chlorosilanes with simple operation by allowing a, siloxane, phosphine current, phosphine oxide current, pos blood Knight type , phosphonite current, phosphite current, phosphonate current, pos [...] , including by the reaction with the expansion driving phosphate, "heteroatom-hydrocarbyl current" or "hetero [...] " can be, referred.

Including heteroatoms, another exemplary current hydrocarbyl, halo [...] and [...] , -(CH₂)_n-C (CF₃)₂-OH, -(CH₂)_n-C (CF₃) (CH₃)-OH, -(CH₂)_n-C (O) NHR*, -(CH₂)_n-C (O) Cl, -(CH₂)_n-C (O) OR*, -(CH₂)_n-OR*, -(CH₂)_n-OC (O) R* and-(CH₂)_n-C (O) R* dyssomnias, including but, do not limited to, wherein n independently and a structure represented by formula 10 to 0, are independently the atom of hydrogen R*, C₁-C₁₁ alkyl, C₁-C₁₁ or halogenated alkyl it ladled and it became the halogen , C₂-C₁₀ alkenyl, C₂ 888000144388 8₁₀ alkynyl, C₅-C₁₂ cycloalkyl, C₆-C₁₄ aryl, C₆-C₁₄ or halogenated it ladled and it became the halogen aryl, C₇-C₁₄ aralkyl or a halogenated or it ladled and it became the halogen C₇-C₁₄ aralkyl blades, presenting a.

An exemplary it ladled and it became the halogen alkyl are trifluoromethyl, trichloromethyl, -C₂ F₅, -C₃ F₇, -C₄ F₉, -C₇ F₁₅ and-C₁₁ F₂₃ dyssomnias, including but, as they are on. Exemplary or halogenated C1 to C16 aralkyl aryl and it ladled and it became the halogen formula are-(CH₂)_x-C₆ F_y H_5-y and-(CH₂)_x-C₆ F_y H_4-y-p C_z F_q H_2z+1-q and include a group that having, wherein x, y, q z and in an independently 0 to 5, 0 to 5, 0 to 9 and is selected respectively from 4 to 1. Specifically, to this exemplary it ladled and it became the halogenwith pen hit claw phenyl are aryl, pentafluorophenyl, [...] , 4-trifluoromethyl benzyl, [...] , [...] and [...] include but, as they are on.

In a preferred embodiment of the present invention, 2 norbornene-type polymer types of different grain size ranges are present, integrates a repeat units, wherein at least one the repeating units of this type some degree of latency (latency) having contains pendant crosslinkable dividers or regions that encompasses. According to "latency", in ambient conditions are such initial or polymers without cross-linked to the every, rather these reactions are such as by chemical vapor disclosure specifically by radiation or thermal when cross-linked to the which implies that the.. The (latent) at least cross-linking groups on this potent, at least cross-linking groups on pendant such for example (for example, maleimide containing pendant groups) encompasses one or more norbornene-type monomer are polymerization agent is supplied to the reaction mixture and by leading to polymerization of, is integrated in the polymer backbone.

In a preferred embodiment, the repeating units of I type polymer composition one or more of the types of number 1 having norbornene-type polymer, and formula II the repeating units of one or more of the types of number 2 is having norbornene-type polymer.

In another preferred embodiment, as-type norbornene composition, type I one or more of the repeating units of number 1 having of the types of norbornene-type polymer or containing only, or formula II the repeating units of number 2 having one or more of the types of norbornene-type polymer containing only..

In another preferred embodiment, I type composition one or more repeat units and formula II one or more repeat units with at least one support having two and comprising at norbornene-type polymers.

Wherein the Z-CH₂-, -CH₂-CH₂-graphical object is selected from O or-, the integer of 0 to 5 m, R¹, R², R³ and R⁴ and R⁵, R⁶, R⁷ and R⁸ each H, C₁ to C₂₅ hydrocarbyl, C₁ to C₂₅ halo [...] or C₁ to C₂₅[...] graphical object is selected from, such may hereinafter is defined said said and the greater the length of time and area as illustrated, number 1 number 2 polymer just one or more polymer repeat units and with a length longer than at least one type encompasses recurring structural units of.

Type I and II IIa and Ia type are each the repeating units of a corresponding norbornene-type monomer is formed by to, Z, m, R^1-4, and R^5-8 the is represented by the following.

Type I, Ia, II and in, and monomer repeat units of IIa, in a preferred embodiment of the present invention Z is-CH₂-and m is 0, 1 or 2 and, in another preferred embodiment Z is-CH₂-and m is 0 or 1 and, in another preferred embodiment Z is-CH₂-and is m is 0.

Specific to applications to produce desired characteristics, pendant groups of several different class, wherein a combination of monomer polymerized norbornene with a resulting polymer (are) flexibility of, adhesive, may exercise control over the solubility and the interface can be obtain. For example, backbone diffusibility of a movable ion attached the variation, glass transition temperature and modulus polymer (T_g) can be permitting the control of the. Furthermore, maleimide, cinnamate, coumarin, anhydride, alcohol, ester, and epoxy actuators are using pendant groups with selected from crosslinked polymer component solubility facilitate the. can reform characteristics. Polarity actuators are, epoxy and tree neighbouring layers device adjacent using [...] metals, silicon, and oxides is replaced with by using the mask pattern.. For example, fluorinated using effectively surface energy and that on the other modified of the solution materials, may affect an orthogonality.

Therefore, another preferred embodiment of the present invention in, in particular, R^1-4 and when H and the other one only R^5-8 H and the other only one embodiment of such when the types, R^1-4 any one, or R^5-8 at least one formula-(CH₂)_x-C₆ F_y H_5-y and-(CH₂)_x-C₆ F_y H_4-y-p C_z F_q H_2z+1-q of, including those laden with but not limited to aryl or it ladled and it became the halogen or halogenated C1 to C16 aralkyl exhibiting, wherein x, y, q, and in an independently z 0 to 5, 0 to 5, 0 to 9, and respectively from integer of 1 to 4 is selected. Specifically this way the with pen hit claw phenyl , pentafluorophenyl, [...] , 4-trifluoromethyl benzyl, [...] , [...] , and [...] , including but not limited to.

Furthermore, the embodiment of the present invention a some preferred, in particular, R^1-4 and when H and the other one only R^5-8 H and the other only one embodiment of such when the types, end hydroxy, carboxyl, or oligonucleotides ethylene jade city site, e.g. end hydroxyalkyl, alkyl, plural second hardwares (for example, acetyl), hydroxy-oligonucleotides ethylene jade city , alkyloxy-oligonucleotides ethylene jade city -oligomer conjugates, plural second hardwares or alkyl ethylene jade city having parts coated with a polar group encompasses groups and the other H and, wherein " ethylene jade city oligonucleotides" the-(CH₂ CH₂ O)_s-(s heterocomplexes the 1, 2 or 3); for example 1-(bicyclo [2.2.1] n-2-methylhept-5-one) (NBTODD)-2, 5, 8, 11-tetra jade apostle space (3 randomly choosing the s) and 5-( (88800008 76888-(2-methoxyethoxy) ethoxy) methyl) bicyclo [2.2.1] methylhept-2-n (NBTON) mixture by the addition of an initiator (2 randomly choosing the s) it. understood.

Furthermore, R^1-4 and when H and the other one only R^5-8 H and the other only one embodiment of such when the types, a preferred embodiment the optical reactive or cross-linkable due encompasses groups. Preferably an array of light responsive or crosslinkable may L and functional linking portion encompasses a F. Preferably the L C₁-C₁₂ alkyl are, aralkyl are, biting field or a heteroatom analogues selected from or included a indicates. The F preferably in addition, means of a bridge or a 2+2 that can react crosslinked, maleimide, 3-3, 4-mono alkyl or[...] , epoxy, vinyl, acetylenically, cinnamate, indenyl or coumarin site includes or represent at least one.

Optical pendant such as from those described said reactive or cross-linkable groups II and I type including a desired suitable the repeat units, formula from the group consisting of selected, including but not limited to one or more norbornene-type monomer is formed by.

Wherein the n being integers, of 8 to 1, Q¹ and Q² each independently of each other-H or-CH₃ and, R '-H or-OCH₃ is.

Formula as are discussed in said I and II of recurring units another exemplary of the hereinafter-Rh receptors, of the formula of 1 to 5 expressed in one or more norbornene-type monomer is derived from.

Said respect to formula 1, m being integers, of the 0 to 3, the-A-R, (CZ₂)_n, (CH₂)_n-(CH=CH)_p-(CH₂)_n, (CH₂)_n-O, (CH₂)_n-O-(CH₂)_n, (CH₂)_n-C₆ Q₄-(CH₂)_n, selected from O-C (O) and a connecting, spacer or bridging-A having contains pendant group; the R end groups H, CZ₃, (CZ₂)_n CZ₃, OH, O-(O) CCH₃, (CH₂ CH₂ O)_n CH₃, (CH₂)_n-C₆ Q₅, an or [...] or p-methoxy-cinnamate, coumarin, phenyl-3-indene, epoxide, CCSi (C₂ H₅)₃ or CCSi (i-C₂ H₅)₃ are selected from, wherein each n independently being integers, of 0 to 12, the p 1-6 being integers, of, Q in an independently H, F, CH₃, CF₃ or OCH₃ and, Z in an independently H or F and, R ' in an independently H or CH₃ is. Formula 2-5 to, -A has formula 1 is defined for the.

A monomer of formula 1-5 according to exemplary chemical save and an available CAS numbers, 5-butyl bicyclo [2.2.1]-2-methylhept-2-n (BuNB) CAS # 22094-81-1, 5-n (HexNB) CAS # 22094-83-3, 5-methylhept [...][...] [2.2.1] [2.2.1] bicyclo [2.2.1] midifiers targeting n (OctNB) CAS# 22094-84-4, 5-methylhept-2-methylhept-2-n (DecNB) CAS # 22094-85-5, 5-(2-phenylethyl) bicyclo [2.2.1]-2-n (PENB) methylhept CAS # 29415-09-6, 1, 2, 3, 4, 4a, 5, 8, 8a-octahydro -1, 4:5, 8-(TD) CAS # 21635-90-5 d meta Roh naphthalene , methylhept-5-bicyclo [2.2.1] bicyclo [2.2.1] n-2-ylmethyl acetate (MeOAcNB) CAS # 10471-24-6, 2 888000155 3888 methylhept-5-n-2-ylmethoxy)-ethyl acetate (NBCH₂ GlyOAc), 2-(bicyclo [2.2.1] methylhept-5-n-2-ylmethoxy)-ethanol (NBCH₂ GlyOH) CAS #754231-21-5, 5-[ [2-(2-methoxyethoxy) ethoxy] methyl]-bicyclo [2.2.1] bicyclo [2.2.1] n (NBTON) CAS # 544716-19-0, 1-methylhept-2-methylhept-5-n-2-one -2, 5, 8, 11-tetra jade apostle space (base Oro butyl purple) (NBTODD) CAS # 307923-40-6, 5-methylhept-2-n-bicyclo [2.2.1] (NBC₄ F₉) CAS #118777-97-2, 5-( (base Oro phenyl purple) methyl)-bicyclo [2.2.1]-2-methylhept n (NBMeC₆ F₅) CAS #848781-71-5, 5-( base Oro phenyl purple) bicyclo [2.2.1]-2-methylhept n (NBC₆ F₅), 5-(3, 4--1, 4 content difluorobenzyl) bicyclo [2.2.1]-2-methylhept n (NBCH₂ C₆ H₃ F₂),

5-(4-(trifluoromethyl) phenyl) bicyclo [2.2.1]-2-methylhept n (NBCH₂ C₆ H₄ CF₃), 2, 2, 3, 3, 3- [...] bicyclo [2.2.1] methylhept-5-n-2-carboxylate (FPCNB) CAS # 908372-02-1, 3, 3, 4, 4, 5, 5, 6, 6, 6-bicyclo [2.2.1] [...] methylhept-5-n-2-carboxylate (FHCNB) CAS # 944462-77-5, 2, 2, 3, 3, 4, 4, 5, 5. [...] octahydro methylhept-5-n-bicyclo [2.2.1]-2-carboxylate (FOCHNB) CAS # 99807-26-8, 2, 2, 3, 3-tetra [...] methylhept-5-n-bicyclo [2.2.1]-2-carboxylate (FPCHNB), bicyclo [2.2.1] [...] purple ylmethyl-2-methylhept-5-n (C₈ PFAcNB) CAS #908372-04-3, 5-( (1, 1, 2-trifluoro-2-(purple base Oro pro width city)-ethoxy) methyl) bicyclo [2.2.1] methylhept-2-n (PPVENB), 2-(6-bicyclo [2.2.1]-2-methylhept-5-n [...])-oxiranyl (EONB) CAS # 950896-95-4, 2-[ (bicyclo [8880001015 888] methylhept-5-n-2-ylmethoxy) methyl] (MGENB) CAS # 3188-75-8-oxiranyl, (4-(bicyclo [2.2.1] methylhept-5-n-2-one)-1- [...] boot-1-one) (AkSiNB) [...] tree, ((4-(2-(bicyclo [2.2.1] methylhept-5-n-2-one) ethyl) phenyl) ethinyl) [...] tree (ArSiNB), (E)-1-(4-(bicyclo [2.2.1] methylhept-5-n-2-ylmethoxy) phenyl)-3-(4-methoxyphenyl) prop-2-n-1-on (MCHMNB), (E)-1-(888 0001039888-(bicyclo [2.2.1] methylhept-5-n-2-ylmethoxy) phenyl)-3-(naphthalene-2-one) prop-2-n-1-on (NPCHMMNB), 1-(bicyclo [2.2.1] methylhept-5-n-2-ylmethyl)-3, 4-dimethyl -1H-pyrrole -2, 5-dione (DMMIMeNB) CAS # 1031898-89-1, 1-(2-(bicyclo [2.2.1]-2-methylhept-5-n one) ethyl)-3, 4-dimethyl -1H-pyrrole -2, 5-dione (DMMIEtNB) CAS # 1031898-91-5, 1-(4-(bicyclo [2.2.1]-2-methylhept-5-n one) 8880000 397888 butyl)-3, 4-dimethyl -1H-pyrrole -2, 5-dione (DMMIBuNB),

1-(bicyclo [2.2.1] methylhept-5-n-2-ylmethyl)-3-methyl -1H-pyrrole -2, 5-dione (MMIMeNB), 1-(bicyclo [2.2.1] methylhept-5-n-2-ylmethyl)-1H-pyrrole -2, 5-dione (MIMeNB) CAS # 442665-16-9, 1-(2-(bicyclo [2.2.1]-2-methylhept-5-n one) ethyl)-1H-pyrrole -2, 5-dione (MIEtNB), 1-(6-(bicyclo [2.2.1]-2-methylhept-5-n one) cyclohexyl)-3, 4-dimethyl -1H-pyrrole -2, 5-dione (DMMIHxNB), 8 880001102888-(4-(2-(bicyclo [2.2.1]-2-methylhept-5-n one) ethyl) phenyl)-3, 4-dimethyl -1H-pyrrole -2, 5-dione (EtPhDMMIiNB), 2-(bicyclo [2.2.1] methylhept-5-n-2-ylmethyl)-4, 5-dihydro -1H-[ e] isoindol -1, 3 (2H)-dione (DHNMINB), (E) methylhept-5-n-bicyclo [2.2.1]-2-ylmethyl 3-(4-methoxyphenyl) acrylate (MeOCinnNB) CAS # 1059706-16-8, bicyclo [2.2.1] (CinnNB) CAS # 185827-76-3 cinnamate ylmethyl-2-methylhept-5-n, (E)-2-(bicyclo [2.2.1]-2-methylhept-5-n one) ethyl 3-(4-methoxyphenyl) acrylate (EtMeOCinnNB), 7-(bicyclo [2.2.1] methylhept-5-n-2-ylmethoxy)-2H-chromen-2-on (MeCoumNB) CAS # 192633-28-6, 7-(2-(bicyclo [2.2.1] n-2-methylhept-5-one) ethoxy)-2H-chromen-2-on (EtCoumNB), 7-(4-(bicyclo [2.2.1]-2-methylhept-5-n one) butoxy)-2H-chromen-2-on (BuCoumNB), 2-(4-(2-(bicyclo [2.2.1]-2-methylhept-5-n one) ethyl) phenyl)-1H-inden (EtPhIndNB), 2-(4-(bicyclo [2.2.1]-2-methylhept-5-n one) phenyl)-1H-inden (PhIndNB), which include but, as they are on. Material from said designated for each of acronyms (acronym) is provided because, with certain of these after when to look up an chemicals, is made through use word acronyms of chemicals will be a to significantly different.

In particular said formula as are discussed in a desired suitable I and II the repeat units, formula from the group consisting of selected, including but not limited to one or more norbornene-type monomer is formed by.

Wherein the methyl means "Me", "Et" means ethyl has, the para- [...] "OMe-p" means, "Ph" and "C₆ H₅" means phenyl has, "C₆ H₄" the polyphenylene means, "C₆ F₅" the [...] means, lower type 9 and 11 in the acetate "OAc" means, "PFAc" lower type 25 in the-OC (O)-C₇ F₁₅ and mixture by the addition of an initiator, and 11-14, 16, 18, 19 and 54, including but not limited to, methylene bridging to (norbornene ring and the functional covalently linked to a both CH₂) having for each type lower said, methylene bridging to is a covalent bond or-(CH₂)_p-can be replaced with by the p is an integer of from 1 to 6 will understand.

54 but provided to standardize the are embodiments of two, a preferred embodiment of the present invention according to types and Ia type are different monomers comprises monomer represented to IIa, wherein R¹, R², R³ and R⁴ or R⁵, R⁶, R⁷ and R⁸ at least one of, -(CH₂)_n-C (CF₃)₂-OH, -(CH₂)_n-C (CF₃) (CH₃)-OH, (CH₂)_n-C (O) NHR*, (CH₂)_n-C (O) Cl, -(CH₂)_n-C (O) OR*, (CH₂)_n-OR*, -(CH₂)_n-OC (O) R* and-(CH₂)_n-C (O) R* including a, hetero atoms current hydrocarbyl, halo [...] , and [...] , wherein n independently and a structure represented by formula 10 to 88 80001172888, are independently the atom of hydrogen R*, C₁-C₁₁ alkyl, C₁-C₁₁ or halogenated alkyl it ladled and it became the halogen , C₂-C₁₀ alkenyl, C₂-C₁₀ alkynyl, C₅-C₁₂ cycloalkyl, C₆-C₁₄ aryl, C₆-C₁₄ or halogenated it ladled and it became the halogen aryl, C₇-C₁₄ aralkyl or a halogenated or it ladled and it became the halogen C₇-C₁₄ aralkyl to determining presence will in a significant in addition to. An exemplary it ladled and it became the halogen alkyl are trifluoromethyl, trichloromethyl, -C₂ F₅, -C₃ F₇, -C₄ F₉, -C₇ F₁₅ and-C₁₁ F₂₃ dyssomnias, including but, as they are on. Exemplary or halogenated C1 to C16 aralkyl aryl and it ladled and it became the halogen formula are-(CH₂)_x- C₆ F_y H_5-y and-(CH₂)_x-C₆ F_y H_4-y-p C_z F_q H_2z+1-q but includes having an elongate, do not limited to, x wherein, y, q z and in an independently 0 to 5, 0 to 5, 0 to 9, and respectively from integer of 1 to 4 is selected. Specifically, to this exemplary it ladled and it became the halogenwith pen hit claw phenyl are aryl, pentafluorophenyl, [...] , 4-trifluoromethyl benzyl, [...] , [...] , and [...] include but, as they are on.

Each type I, Ia, IIa and II, and to standardize the general formula and lower provided each of representing without indication of any stereochemistry but forming interlevel contact, a not exhibit alternatively, each monomers generally, when repeat units to be converted to their construction, as well as retaining the diastereomers mixtures is Image information acquired as. to significantly different. This part a stereoisomeric mixture of exo and endo isomers are slightly different in content is connected to a gate, a preferred embodiment of the present invention the, endo or exo isomers are enriched in the during or mixtures of isomers, or essentially pure glass isomers this activity sources are used for generating the monomers having an acid differences in addition provided an opening to take advantage of the. understanding. For example, reference the A16 and in the embodiment A7 of hereinafter.

Another preferred embodiment of the present invention a, type I in R^1-4 one, for example R¹ is said, the fluorinated or perfluorinated alkyl, aryl or aralkyl, R is an alkyl group containing R^1-4 a other of the I type including repeat units in H relates to polymer. Preferably R¹ 15-26 is selected from one the lower type and, more preferably is selected from lower type 16, 17, 18, 19 or 20.

Another preferred embodiment of the present invention a, type I in R^1-4 one, for example R¹ is optical, the reactive or cross-linkable group R^1-4 other of the a H having repeat units in formula I relates to polymer. Preferably R¹ the lower type 27-50 as defined in the group, more preferably lower type. as defined in 34, 35, 36, 37 and 38.

Another preferred embodiment of the present invention a, type I in R^1-4 one, for example R¹ is said, the hydroxy, carboxylic, acetoxy or oligomeric polar group and having parts coated with ethylene jade city R^1-4 other of the a H having repeat units in formula I relates to polymer. Preferably R¹ the lower type 9-14 the as defined in one group, generally lower type 9. double the as defined in.

Another preferred embodiment of the present invention a, said, the fluorinated a matrix selected from the repeating units number 1 types of repeat units and a in addition said cross-linkable, the a matrix selected from repeating units of repeating-unit-having types of number 2 relates to a polymer. Concentration of polymers is embodiment 16, 17, 18, 19 and 20 the lower type number 1 selected from types of repeat units and a lower type 34, 35, 36, 37 and 38 selected from polymer of repeating-unit-having types of number 2 including.

Another preferred embodiment of the present invention a, said, the fluorinated a matrix selected from the repeating units the repeating units of type number 1, in addition said cross-linkable, the number 2 a matrix selected from repeating units the repeating units of type, and in addition said a polar, the a matrix selected from repeating units of repeating-unit-having types of number 3 relates to a polymer. Concentration of polymers is embodiment 9 of the lower type number 1 repeating units, selected from lower type 34, 35, 36, 37 or 38 the repeating units of type number 2, and a lower type 16 selected from polymer of repeating-unit-having types of number 3 including.

Another preferred embodiment of the present invention form formula I or formula II according to 4 one or more different types of repeat units relates to a polymer having a. Another preferred embodiment of the present invention form formula I according to number 1 number 1 polymer and types of of repeating-unit-having, least number 1 types of repeat units and a type II according to number 2 number 2 types of of repeating-unit-having relates to polymer blends of polymer. Alternatively, formula are blend polymers, as well as non I according to 2 having at least one repeat units number 1 number 2 mixing-mentioned said polymer and can be for inclusively polymer. In addition preferably, such polymer blends are having formula II according to 3 types of repeat units alternate number 2 polymer, mixed with a quantity of said referred to an alternative number 1 can be for inclusively polymer.

Another preferred embodiment of the present invention form formula I according to at least one repeat units and a type II according to at least one of repeating-unit-having relates to a polymer, wherein this way I to type II and the ratio of the repeating units is 5:95 to 95:5. In another preferred embodiment, this way I to type II the ratio of repeat units is 20:80 to 80:20. Another preferred embodiment in, this way the ratio of repeat units I to type II is 40:60 to 60:40. In addition in another preferred embodiment, this way the ratio of repeat units I to type II is 55:45 to 45:55.

Another preferred embodiment of the present invention form at least 1 kind recurring structural units of formula I according to one or more polymers and norbornene-type repeating units tables for each nozzle are converted into one or more polymers having repeat units of encompasses blend polymer. These other polymers are, poly (methyl methacrylate) (PMMA), polystyrene (PS), poly-4-vinyl phenol, polyvinyl pyrrolidone, or its combinations, such as a PMMA-PS and-polyacrylonitrile (PAN), which include but, polymeric limited to it is preferred that a that are selected from alternative.

A desired suitable norbornene monomers, polymers method and their synthesis examples of the present specification is provided, in addition, that is adapted to be integrated application is as a reference, US 5,468,819, US 6,538,087, US 2006/0020068 A1, can be found in US 2008/0194740 A1 and US 2007/0066775 A1. For example, of catalysts, VIII group transition metal are polymerization processes employing said-mentioned US 2006/0020068 A1 are depicted in.

Embodiment polymer of the present invention the weight average molecular weight suitable for use (M_w) is is formed in. Generally, of 5,000 to 500,000 M_w embodiment some types while found suited for, other embodiment types and calculates the first recordable M_w. can be advantageously ranges. For example, in a preferred embodiment at least polymer of 30,000 M_w has a, in another preferred embodiment at least polymer of 60,000 M_w has a. In another preferred embodiment of M_wuntil which the upper limit of of 400,000, of another preferred embodiment in M_w to the upper limit of of 250,000. Suitable M_w has a cured polymer, films, layers or derived therefrom in structures that comprises a physical property that is desired because the functions of, suitable M_w and therefore increase selection option associated with the region is said design has provided within any M_w the torsion bar is within the of the present invention is will understand.

Preferably, said polymer compositions are referred to in an electronic device, in particular FET or OFET provided in contact with the insulating layer in an intermediate layer is used to form the. Preferably, the insulation layer gate insulator or gate insulator layer is a portion of the bed. In another preferred embodiment, insulating layer is a passivation layer or passivation a portion of the bed.

Preferably, polymer composition, one or more polycycloolefins olefinic polymer or polymer blends in addition to, perpendicular to the material insulating layer having in content solubility a casting solvent, and optionally, sunscreens crosslinked, reactive solvents, stabilizers, sunscreens increase/decrease UV, thermal gradient and number selected from including one or more additives.

The present invention refers to in addition, through use of the present invention according to polymer or polymer composition or polymer or polymer composition as they are acquired or as they relates to electronic device including. Such an electronic devices are, in particular, top gate or bottom gate transistors, integrated circuits (IC) and radio frequency identification (RFID; Radio Frequency Identification) tag which can be, field effect transistors (FETs) and organic field effect transistors (OFETs), thin film transistors (OTFTs) are and organic thin film transistor (TFT) includes. For example, through use of the present invention according to polymer composition also are transistor having 3, 4 also, also 5 and 6. is shown to coarse to.

Now hereinafter into accompanying drawing back surface, also according to prior art 1 and Figure 2, each tower ascent and organic bottom gate of field effect transistors may exhibits the approximate representation. Therefore, also 1 and of Figure 2 OFET a device has a substrate (1), device having source and drain electrodes in (2), semiconductor layer (3), gate dielectric layer (4), gate electrode (5), may be provided in the later and additional layers or devices for the second region number 2 as to shield the protective layer or insulator (6) includes.

Also now reverts to surface 3, according to a preferred embodiment of the present invention form multiplex device FET gate top portion it is intended to provide a presentation of. Such FET a device has a substrate (10), device having source and drain electrodes in (20), semiconductor layer (30), gate electrode (50), gate dielectric layer (40), said lateral sclerosis such as described hereinafter and polycycloolefins olefinic polymer or blends of olefinic polycycloolefins for inclusively and the intermediate layer that derived from from a polymer composition (70), insulating pipe and, protection, stabilization and adhesive function one or more of the gate electrode has a dielectric layer (50) and an intermediate layer (70) disposed on selected layer [...] layer (60) includes. Intermediate layer (70) the gate electrode (50) and/or on such additional coating layers, for example alternating layers of (60) to improved adhesion by using the mask pattern..

On the other side of the present invention, a) in an illustrated substrate (10) device having source and drain electrodes in on (20) to form a, b) substrate (10) and said device having source and drain electrodes in (20) on semiconductor layer of material (30) and depositing a, c) semiconductor layer (30) dielectric on layer of material (40) and depositing a, d) dielectric layer (40) on, said lateral sclerosis such as described hereinafter and polycycloolefins olefinic polymer, or olefinic polycycloolefins [...] polymer hardener includes at least one layer of intermediate layer material, including polymer composition that, (70) and depositing a, e) intermediate layer (70) on at least a portion of the gate electrode (50) to form a, and f) gate electrode (50) and an intermediate layer (70) on parts of, for example insulating and/or protecting and/or stabilizing and/or adhesive layer layer (60) by selectively depositing a, e.g. Figures 3 shown in a device, such as. is a process for making an.

4 also now returned to its surface, the present invention according to another preferred form FET embodiment to the gate top portion is shown coarse, gate electrodes (50) is gate dielectric layer (40) the in-between layer on the (70) and the first and second layer is deposited, the other ingredients, device is referred in Figure 3.

In a preferred embodiment of the present invention, e.g. Figures 4 a a device, such as shown in of Figure 3 device, the but formed by the process, gate electrode (50) this interlayer material (70) for forming concave 135 is formed prior to forming.

5 also now returned to its surface, to the gate top portion the present invention according to another preferred form. is shown to coarse FET embodiment. Specifically, the of Figure 3 FET embodiment of Figure 5 FET but stabilization layer resembling the shape of a cotton (80) also to 3 shown in an do not go. Drive the discharge lamp, stabilization layer (80) an intermediate layer (70) be arranged on top, intermediate layer (70) and a gate electrode (50) is positioned between the. Advantageously, stabilization layer (80) the, of fluoropolymer electronic device T_g at the time of heating a at least, for example, for the intermediate layer on top of gate electrode may occur when providing a cracking or mgsn ring problems by reducing intermediate layer (70) of durability and structural integrity can be a function to improve the. Stabilization layer (80) curable (i.e., polymerizable or crosslinkable) or cured (i.e., polymerized or crosslinked) organic material can be for inclusively. Drive the discharge lamp, stabilization layer (80) the, said insulating as described, protection, stabilization and adhesive function having one or more of alternating layers of (60) the upper or disposed on a or selective layer (60) may be coated with an anti-..

Stabilization layer (80) suitable materials are silanol-functional polymer such as silicone resin their. A favorable material are suitable, for example US 5,861,235 [...] poly described, the commercially available poly [...] or their precursors, such as a HardSil^TM series of materials (Gelest Inc. Manufacturing, Morrisville, Pa, USA), e.g. HardSil^TM AM, alcohol mixture of an MSSQ resin 19-21% for manufacturing in, AS Hardcoat^TM or SHC^TM series of materials (Momentive Performance Materials Inc. Manufacturing, Wilton, CT, USA), e.g. AS4000 Hardcoat^TM, AS4700 Hardcoat^TM or SHC^TM 5020, or GR650F^TM (Techneglas Inc. Manufacturing, Perrysburg, OH, USA), which include but materials such as, as they are on.

Stabilization layer (80) curable or cured conventional material comprising a host material and a solvent, for example intermediate layer (70) material of the which are used for. dissolved in a solvent to orthogonal to solvent. Using this quadrature epoxypropanol and butanol examples of solvent include but, as they are on. Said solution then the greater the length of time and described hereinafter and devices such as deposited, selectively hardened is stabilization layer (80) is formed on.

Also now reverts to surface 6, according to another preferred embodiment of the present invention form it is shown bottom gate FET. Such FET the substrate (10), device having source and drain electrodes in (20), semiconductor layer (30), gate electrode (50), gate dielectric layer (40), provided on top of device such additional layers or devices device having source and drain electrodes in from (20) as to shield the passivation or protecting to the number 2 insulator layer (60), and said lateral sclerosis such as described hereinafter and polycycloolefins olefinic polymer or blends of olefinic polycycloolefins for inclusively derived from water from a polymer composition, said intermediate layer, the 888000 0678888 (70) includes. The aforementioned as, intermediate layer (70) a film forming thereon additional layer for improved adhesion by using the mask pattern..

For transistor is another said-mentioned processes of the present invention is particle diameter smaller.

The present invention according to FET OFET embodiment and types of layers and structures film forming (deposition) and/or shaping the, a solution treatment techniques are low processing such solutions is carried out by employing techniques it is preferable that the. For example, material agents or composition, conventional sweep out a at least one organic solvent, and the surface of, dip coating, spin coating, inkjet printing, relief printing, screen printing, doctor blade coating, roller printing, reverse-roller printing, offset lithography printing, flexographic printing, web printing, spray coating, brush coating, or pad printing, including but not limited to a preferred techniques are using as the additive may be formed or, these subsequent forming a solution of a is employed to. is subsequently formed between the tube body and the tube. For example, organic semiconductor material, each material organic dielectric intermediate layer material, and, a device formed to ordering suitable spin coating, flexographic printing, or film is deposited by techniques and inkjet printing can be formed.

Specifically, intermediate layer (70) film is deposited by processing the solution is one or more organic solvents of said lateral sclerosis such as described hereinafter and one or more polymers or polymer blend of detect the solution, the solvents such, organic ketones, such as methyl ethyl ketone (MEK), methyl n-amyl ketone (MAK), trimethylcyclohexanone and, ethers, e.g. butyl-biphenyl ether, chloroanisolein methyl 4-and aromatic hydrocarbons, e.g. cyclohexylbenzene ;, or mixtures is preferably chosen from not limited to but. Preferably a total concentration of carbon polymer material of formulation but different concentrations are 0.1 to 5 wt % in addition. as may be suitable for the waistbands. High boiling point are a state of the organic ketone solvent, inkjet and flexographic printing techniques are employed in particular when called preferred solvents suitable been discovered.

Intermediate layer (70) the device performance without negatively affecting the intermediate layer coated onto a any additional layer for maintaining sufficient wettability and resistance against and adhesive to give should applied at thickness. Device and the intermediate layer that used for producing a (70) thickness suitable manufacturing the specific device and use to the DMAC of such devices but function, in particular, general guide line as, 1 to 1000 nm range embodiment of the present invention is the desired thickness of some device types suitable high, while the other embodiment types is the desired thickness of 5 to 500 nm range for used to locate been discovered. However, different thickness that is suitable for ranges and therefore may be within range of the present invention is it will be appreciated that.

The OFET embodiment and the present invention according to FET, as disclosure to WO 03/052841, the dielectric material having dielectric constant (ε) of 3.0 hereinafter ("gate dielectric") ("low k dielectric") made of gate dielectric layer (40) preferably, via employing a. In a some preferred embodiment, to 1.1, preferably 1.7 to 3.0 range of used to locate is ε while the other a preferred embodiment been found in. is 2.0 to 3.0. The present invention according to another preferred and FET in OFET embodiment, 2.5 to 3.0, or 2.0 to 2.6 dielectric constants used to locate been discovered range.

Said as described, to gate dielectric layer, low k gate dielectric a preferred the present invention according to a material in FET and OFET embodiment, this material is fluoropolymer organic conventional. Suitable fluorine polymers are, for example CYTOP^TM series (Asahi Glass), Teflon AF^TM series (DuPont) or Hyflon AD^TM series (Solvay manufacturing), such as the from a high degree of soluble perfluoride includes the small Polymer. CYTOP polymers are, John Scheris, John Wiley & Sons Ltd. , 1997, Chapter "Modern fluoroplastics" edited by a:N. Sugiyama, by pages 541ff "Perfluoropolymers obtained by cyclopolymerisation" are depicted in. John Scheris the Teflon AF, John Wiley & Sons Ltd. , 1997, Chapter "Modern fluoroplastics" edited by a:P. R. Resnick, by pages 397ff "Teflon AF amorphous fluoropolymers" are depicted in. The Hyflon AD "High Performance Perfluoropolymer Films and Membranes" V. Arcella et. Al. , Ann. N. Y. Acad. Sci. 984, pages 226-244 (2003) are depicted in.

Typically, the interlayer material the greater the length of time and described hereinafter and said a polymer such as, polymer blend or polymer composition that, which encompasses, gate dielectric material harder than having high dielectric constant, a some preferred embodiment of the present invention in and surface may be in the range of 2.0 to 40, in another preferred embodiment range of 2.5 to 20 used to locate been discovered.

In a preferred embodiment of the present invention, cross-linkable or cross-linked polymer is intermediate layer material, as is or its use as a component. Such cross-or the crosslinked polymer network a, gate dielectric layer, and an electronic device structural integrity, durability, mechanically resistant and solvent resistance more characteristics of a selected from a function to improve the first. Well suited a desired cross-linkable polymer, for example, type I (wherein R^1-4 is at least one of cross-linkable groups difference from an) one or more repeat units are those having, very preferably selected from lower type 26-50 created by the one or more monomers having units is those.

For crosslinked, after film forming generally polymers, X ray, UV or visible with radiation such as electron beam or electromagnetic (chemical) or exposure radiation, or thermal crosslinkable groups. maintaining the fluid when it contains. For example, the 11 nm to 700 nm actinic radiation, e.g. by using a wavelength of 200 to 700 nm for imaging may be employed. For exposure dose of radiation generally 25 to 15000 mJ/cm² is. Suitable radiation sources mercury, mercury/xenon, mercury/halogen and xenon lamps, argon or xenon laser sources, . lines x. Flood exposed to light, and the exposure such that the ratio of these actinic radiation in. for causing the of a silicone material crosslinked and cured. Bridging other pendant groups the repeating units but can be provided, such the crosslinking hinders, maleimide pendent groups in the distribution case former, i.e. R¹ to R⁴ one of substituted or nonsubstituted maleimide region of the repeat units is provided by. Maleimide as a wavelength of out-of-band light absorbing [...] which uses a light source is desired, radiation sensitive can be conducted is added. If containing polymer in a thermally cross-linkable to, selectively, for example the crosslinking reaction has if a thermally disclosure, disclosure for disclosure a crosslinking reaction between the at may be added

In a preferred embodiment, intermediate layer for example 1 to 10 minutes at a temperature of 130 °C to 70 °C period is post exposure baking unit. A polymer post exposure baking unit exposure portion's crosslinkable inside the employed to promote more of a silicone material crosslinked and cured can be.

In another preferred embodiment, cross-linkable polymer composition, spontaneous, a crosslinking to prevent-aging of polymer composition to improve (shelf life) containing a material or stabilizer. Suitable stabilizers are, in ortho positions for phenolic OH, the bulky alkyl are one or more, for example to-butyl t a optionally contain pyrocatechole or phenol derivatives such as antioxidant procuce a.

The integrity physical electronic device, electro-optical flat for example, such as the backplane active matrix displays, more complicated production of is an important element for. Mounted above the interlayer insulating stack of layers (built-above) forming, for example air curtain drying or an organic solvent using wet-, such as treatment, further, a process must decide sufficiently strong to withstand a. Not sufficiently strong bonding thereof, when of dry air curtain for example, and a peeling tape is attached on the upper forming layer, or for example a wet processing in the case of solvent-stabilized zirconia when put under capillary between the, likely to be mobile over a substrate is connected to the semiconductor layer.. This untreated plastic surface of, and low in energy is substantially not having increased adhesion, plastic substrate are used much to. more important. These problems to overcome the in the prior art, proposed possible solutions are, for example as by performing O2 plasma treatment, or a surface of a substrate with-chemically modifying, or for example a plastic substrate for metal oxide layer such as, additional layer into using a previously coated substrate including method. However, e.g. chemical and modified method are dielectric polymers, such as dielectric e.g. solubility of polymers, dielectric polymers may adversely affect the characteristics of or or device may adversely affect the performance of is limited because there.

Therefore, in a preferred embodiment of the present invention, reactive adhesive accelerator is, intermediate layer for forming of cross-linkable polycycloolefins including cross-linkable polymer compositions is processed. Reactive adhesion promoter is, cross-linkable polycycloolefins polymers comprise as pendant crosslinkable functional groups and are capable of causing crosslinking, number 1, and adjacent device layer interact with, for example chemical bonding due surface activity capable of number 2 includes functional groups. Adjacent device layer are such, , for instance, from the upper by gate insulator layer is deposited by a lower functional devices or or substrate, a film is formed on a or intermediate is a function layer.

Number 1 types of is desirable in embodiment, intermediate layer cross-linkable to form a prior to film forming of polymer composition polycycloolefins, on top middle or intermediate ply is later formed on the active layer is deposited is adhesion promoters on substrates or. Adhesion promoter is, for example in a solution in a suitable solvent, and additionally containing adhesion promoter of immersing a substrate by removing the solvent by, is a film is formed on a substrate. Adhesion promoter is, selectively substrate upon formation of chemical bonding, onto the surface of a substrate to form thin. Furthermore, cross-linkable polymer composition adhesion promoter upper surface of covered of layers is deposited. After the removal of any solvent, adhesion promoter and cross-linkable polycycloolefins cross-linkable polymers comprise as for example, to UV crosslinks patterns to be exposed by the same.

The number 1, the intermediate layer according to types of a preferred embodiment form, a) on a substrate, or for example a gate insulator layer, an amorphous silicon layer, on the device layer electrode, selectively at least one organic solvent, and dissolved or dispersed in a, described hereinafter and said lateral sclerosis such as adhesion promoter and depositing a, b) in the presence of solvents, said solvent by eliminating, on the surface of a substrate that step forming a layer of adhesion promoter, c) including on the surface of a substrate that adhesion promoter layer, described hereinafter and said cross-linkable lateral sclerosis such as olefinic polycycloolefins and the solvent including the polymers, as well as selectively including crosslinkable polycycloolefins and depositing a layer of polymer composition, d) in the presence of solvents, said step for removal of solvents, and e) layer polymers comprise as polycycloolefins, adhesion promoters of crosslinkable and of cross-linkable polymers comprise as polycycloolefins crosslinked, which leads to the heat or exposed to actinic radiation by, to form a intermediate layer including is subjected to a process and consequently can be produced.

Number 2 types of is desirable in embodiment, intermediate layer, crosslinkable polycycloolefins olefinic polymer and cross-linkable polycycloolefins polymers comprise as crosslinkable and crosslinkable surface-active the bondable functionality a crosslinked adhesion promoter additive including functional groups including cross-linkable polymer composition formed from.

Types of number 2 is according to a preferred embodiment form, the intermediate layer, a) on a substrate, or for example a gate insulator layer, an amorphous silicon layer, on the device layer electrode, adhesion promoters, crosslinkable olefinic polycycloolefins including a polymer and a solvent and depositing a layer of composition cross-linkable polymer, b) for removal of solvents step, and c) layer of polymer composition, adhesion promoters of crosslinkable and of cross-linkable polymers comprise as polycycloolefins crosslinked, which leads to the heat or exposed to actinic radiation by, to form a intermediate layer including is subjected to a process and consequently can be produced.

Number 1 and number 2 types of a preferred embodiment in the form of in said process, e.g. Figures 3, 4 also, also said device of Figure 6 or 5 process as described, excellent in the device layer optionally additional is filmed.

In cross-linkable polymer of the present invention these reactive adhesion promoters use of sublayer advantageously formed from the compositions used for the objective compound. gluing of layer.

Therefore, layer, which are used to build a polymer modifying the off-the-performance of without being potentially without adversely affecting the intermediate layer for the adhesion of can be improved.

Reactive silane or the of surface active adhesion promoter it is preferred that a metal coordination homolysine residue. Desirably surface the activator formula-SiR¹² R¹³ R¹⁴ of silane, or formula-NH-SiR¹² R¹³ R¹⁴ of metal coordination remaining time and , wherein R¹², R¹³ and R¹⁴ independently from each other halogen, silazanes, C₁-C₁₂-alkoxy, C₁-C₁₂-alkylamino, selectively substituted C₅-C₂₀-phenoxy and selectively substituted C₂-C₂₀-heteroaryloxy graphical object is selected from, R¹², R¹³ and R¹⁴ in addition one or the 2 C₁-C₁₂-alkyl, selectively substituted C₅-C₂₀-aryl or selectively substituted C₂-C₂₀-hetero lithiumorganyl. which may be indicative of a.

Reactive adhesion promoters of crosslinkable the maleimide, 3-mono alkyl-maleimide, 3, 4- [...] , epoxy, vinyl, acetyl, indenyl, phosphorus coumarin or cinnamate and is preferably chosen from, or a substituted or unsubstituted portion the maleimides, epoxide portion, vinyl portion, coumarin portion or cinnamate includes portion.

Very preferably through an adhesive promoter is compounds of formula III.

G-A ' P III-

G wherein the, preferably said lateral sclerosis such as described hereinafter and, surface-active group, A ' a single bond or connected, spacer or bridging group, the P, preferably said lateral sclerosis such as described hereinafter and, . double cross-linkable.

G has formula-SiR¹² R¹³ R¹⁴ of or formula-NH-SiR¹² R¹³ R¹⁴ is preferably due of, wherein R¹², R¹³ and R¹⁴ independently from each other halogen, silazanes, C₁-C₁₂-alkoxy, C₁-C₁₂-alkylamino, selectively substituted C₅-C₂₀-phenoxy and selectively substituted C₂-C₂₀-heteroaryloxy graphical object is selected from, R¹², R¹³ and R¹⁴ in addition one or the 2 C₁-C₁₂-alkyl, selectively substituted C₅-C₂₀-aryl or selectively substituted C₂-C₂₀-hetero lithiumorganyl. which may be indicative of a.

Maleimide has P, 3-mono alkyl-maleimide, 3, 4- [...] , epoxy, vinyl, acetyl, indenyl, cinnamate or coumarin and is preferably chosen from phosphorus , substituted or nonsubstituted maleimide portion, epoxide portion, vinyl portion, coumarin portion or cinnamate includes portion.

Preferably A ' the (CZ₂)_n, (CH₂)_n-(CH=CH)_p-(CH₂)_n, (CH₂)_n-O, (CH₂)_n-O-(CH₂)_n, (CH₂)_n-C₆ Q₄-(CH₂)_n, (CH₂)_n-C₆ Q₁₀-(CH₂)_n and graphical object is selected from C (O)-O, wherein each n independently being integers, of 0 to 12, being integers, of the p 1-6, Z and in an independently H or F, C₆ Q₄ the Q is replaced by the processing result phenyl and, C₆ Q₁₀[...] -replaced by the Q, Q in an independently H, F, CH₃, CF₃ or OCH₃ is.

Suitable formula preferred compounds is chosen from A1.

Wherein SiR¹² R¹³ R¹⁴ as defined the thread column strangeness , A ' the and the greater the length of time and the same as the defined hereinafter, R¹⁰ and R¹¹ are each independently H or C₁-C₆ copyright 2000. DMMI-propyl-(Si (OEt)₃, DMMI-butyl-(Si (OEt)₃, DMMI-butyl-(Si (OMe)₃, DMMI-ethylhexyl-(Si (OMe)₃ is preferably in particular.

As used in the present specification, terms "spacer to", "connector" and the "to bridging" is publicly known to one skilled in the art (e.g., Pure Appl. Chem. 73 (5), 888 (2001) reference).

A to ' the, each or are not substituted with F, Cl, Br, I or CN with the single or multiple by, linear C₁ to C₃₀ alkylene or branched hydridosiloxane and a C₃ to C₃₀ alkylene or cyclic C₅ to C₃₀ WIPO it is preferred to set a, wherein O and/or S atoms such a way that they do not direct link each other, optionally one or more, non-contiguous CH₂ may, in each case independently, -O-, -S-, -NH-, -NR¹⁸-, -SiR¹⁸ R¹⁹-, -C (O)-, -C (O) O-, -OC (O)-, -OC (O)-O-, -S-C (O)-, -C (O)-S-, -CH=CH or-C≡C is replaced by.

R¹⁸ and R¹⁹ each independently a H, methyl, ethyl or C₃ to C₁₂ copyright 2000 linear or branched.

A preferred multiadder A ' the-(CH₂)_p-, -(CH₂ CH₂ O)_q-CH₂ CH₂-, -CH₂ CH₂-S-CH₂ CH₂-or-CH₂ CH₂-NH-CH₂ CH₂-or-(SiR¹⁸ R¹⁹-O)_p-and, wherein the p being integers, of 2 to 12, being integers, of 3 to 1 the q, R¹⁸ and R¹⁹. have the meanings given to standardize the.

A multiadder a preferred in addition ' has of methylene, ethylene, propylene, butylene, pentylene, cyclohexylene dimethylene terepthalate, [...] , [...] , [...] , alkylene midifiers targeting, [...] , use of Saccharomyces cerevisiae [...] , [...] octahydro, ethylene electrochromic element, methylene [...] , ethylene-thio ethylene, ethylene-N-methyl-imino ethylene, alkylene methyl 1-, stannylene ethenyl, [...] is selected from polyphenylene and profile.

Type A1 as adhesion promoters for example synthesis of US 4,565,873 to is disclosure.

In another preferred embodiment, the cross-linking intermediate layer having a reactive group one or more repeat units, preferably type I or II containing repeat units of polymers or polymer includes a, the gate insulator layer, polymer or polymer composition cross-linkable of repeating units said able to react with one or more crosslinkable actuators adapted 2 including. includes a crosslinker then, the frame is made up.

Function layer for processing, and an electronic device integrity is formed on the, formed on the active layer of, or improve the physical properties for holding the IC devices, at required around reduces the time it is preferable that the. This, subsequent layers and used when forming this layer regulated so as to have a solvent are quadrature the when without dissolving the each other and thus may be held in.. Using this quadrature-crosslinked, conventional on difficult cases is to obtain crosslinked UV, number 2 function layer polymer compositions such insoluble a method for producing an oil-layer number 1 number 1 which of the layer function the formation of different layers of one layer preventing any will.

Treated by for example coating process to tune required for the and can be made, while dielectric polymer chemical adjustment or process changes in UV crosslinked by both in a reduction of the time required for. can be realized.

However, UV sensitivity is composed of a polymer dielectric some characteristic of and related to, for example increased UV sensitivity toward variations solubility since the can also decreases a, is limited of chemical of polymer dielectric. High power, for example the temperature of the process using UV changing the, ozone clinker production can be increases the potential of the, thus polymer surface of dielectric and causes a change in unwanted in can be.

Therefore, in a preferred embodiment of the present invention, one or more crosslinked polymer composition includes additives number. Such additives the, intermediate layer, which are used to build a polycycloolefins polymers comprise as pendant crosslinkable groups that can react and 2 including least one functional group with at least two. Furthermore, such cross-number additive the use of cross-linking of the polymer referred to in addition said enhances will understand the torsion bar is used for.

UV radiation exposure due to cross-linking preferably by.

The use crosslinking agent, and a suitable wavelength is manner the images for the radiation UV dose (imagewise) exposure through use of a. enhances the ability patterning a the intermediate layer.

The cross-linkable crosslinking agent, maleimide, 3-mono alkyl-maleimide, 3, 4- [...] , epoxy, vinyl, acetyl, indenyl, phosphorus coumarin or cinnamate, or a substituted or unsubstituted portion the maleimides, epoxide portion, vinyl portion, including portion coumarin portion or cinnamate ground into it is preferable that the selected.

Very preferably, is chosen from IV2 or IV1 type crosslinking agent.

P-X-P IV1

H_4-m C (A "-P)_m IV2

Wherein the X "-X '-A" and A, X' the O, S, and single joined or NH, A " a single coupled, or (CZ₂)_n, (CH₂)_n-(CH=CH)_p-(CH₂)_n, (CH₂)_n-O, (CH₂)_n-O-(CH₂)_n, (CH₂)_n-C₆ Q₁₀-(CH₂)_n and C (O)-O selected from where it is desirable, connected, spacer or bridging 2,000., wherein each n independently being integers, of 0 to 12, being integers, of the p 1-6, Z and in an independently H or F, C₆ Q₁₀[...] -replaced by the Q, Q in an independently H, F, CH₃, CF₃ or OCH₃ and 8 880000879888 has formula III given to hereinafter and said or meaning of preferably has one of photopolymerization initiator represented by chemical, the m is 2, 3 or 4.

A desired suitable C1 is chosen from formula compounds.

Wherein R¹⁰ and R¹¹, independently one of the other are H or C₁-C₆, R is an alkyl group containing, A " has formula defined the same as the, the n is integer number of 1 to 10. DMMI-butyl-DMMI, DMMI-pentyl-DMMI and DMMI-hexyl-DMMI is preferably in particular.

Spacer A to " the, each or are not substituted with F, Cl, Br, I or CN with the single or multiple by, linear C₁ to C₃₀ alkylene or branched hydridosiloxane and a C₃ to C₃₀ alkylene or cyclic C₅ to C₃₀ WIPO it is preferred to set a, wherein O and/or S atoms such a way that they do not direct link each other, optionally one or more, non-contiguous CH₂ may, in each case independently, -O-, -S-, -NH-, -NR¹⁸-, -SiR¹⁸ R¹⁹-, -C (O)-, -C (O) O-, -OC (O)-, -OC (O)-O-, -S-C (O)-, -C (O)-S-, -CH=CH or-C≡C and replaced by, R¹⁸ and R¹⁹ each independently a H, methyl, ethyl or C₃ to C₁₂ copyright 2000 linear or branched.

A preferred multiadder A " the-(CH₂)_p-, -(CH₂ CH₂ O)_q-CH₂ CH₂-, -CH₂ CH₂-S-CH₂ CH₂-or-CH₂ CH₂-NH-CH₂ CH₂-or-(SiR¹⁸ R¹⁹-O)_p-and, wherein the p being integers, of 2 to 12, being integers, of 3 to 1 the q, R¹⁸ and R¹⁹. have the meanings given to standardize the.

In addition a preferred multiadder A " has of methylene, ethylene, propylene, butylene, pentylene, cyclohexylene dimethylene terepthalate, [...] , [...] , [...] , alkylene midifiers targeting, [...] , use of Saccharomyces cerevisiae [...] , [...] octahydro, ethylene electrochromic element, methylene [...] , ethylene-thio ethylene, ethylene-N-methyl-imino ethylene, alkylene methyl 1-, stannylene ethenyl, [...] is selected from polyphenylene and profile.

Type C1 as crosslinked for example synthesis of the number is disclosure to US 3,622,321.

Electronic device functional other ingredients of layers, such as a substrate, gate and source and drain electrodes in, and the inorganic semiconductor layer (when used in the), can be selected and from standard material, standard method, which can be produced by can be applied to the device. These components and to either manufacturing method and a suitable material to is publicly known to one skilled in the art are, disclosed is literature. A film-forming method are exemplary, is the liquid coating method as well as chemical vapor deposition (CVD) or physical vapor deposition method includes.

Generally, the present invention according to an electronic device in some preferred embodiment, function layer, for example, gate dielectric or semiconductor layer has a thickness of from, 1 nm (in the case of single layer) to 10 micro m is. Different layer thicknesses or thickness range are taken into account and therefore but within range of the present invention, in another preferred embodiment, such thickness in the approximate range 1 nm to 1 micro m, another preferred embodiment is 500 nm to 5 nm in.

Embodiment electronic device of the present invention for the manufacture of form various substrates may be used. For example glass or plastic which the transferred material is most frequently is carried out by using an acidulous. A preferred plastic material are, alkyd resins, allyl ester current, benzocyclobutene current, butadiene-styrene, cellulose, cellulose acetate, epoxide, epoxy polymers, ethylene-chloro [...]nose Polymer ethylene, ethylene-tetra-fluoro ethylene nose Polymer , fiberglass enhanced plastic, fluorocarbon polymers, hexafluoropropylene vinylidene-fluoride copolymer, and density polyethylene, parylene, polyamide, polyimide, poly aramid, polydimethylsiloxane, polyether sulfone, poly-ethylene, polyethylene naphthalate, polyethylene terephthalate, polyketone, a group including polyester, cellulose triacetate, polypropylene, polystyrene, polysulfone, blends of polyamide blockpolymers and of copolymers, polyurethane current, polyvinyl chloride, silicone rubber are, and silicon includes but do not limited to, wherein polyethylene terephthalate, polyimide and polyethylene naphthalate which the transferred material is most used to locate been discovered. Additionally, some embodiment of the present invention a substrate against types the one or more materials listed in the coating any plastic, metal or glass material. The substrate of threads generated by, used for it order to enhance the carrier mobility of the organic semiconductor material being lower pre-aligned as well as provide a homogeneous extruded to provide surfaces for, stretch, rubbing or photochemically dispersion method, such as may be are employed will understand.

The present invention according to FET OFET and gate types of embodiment device, the device having source and drain electrodes in, spray-, dip-, web or spin-coating of liquids such as coating, or physical vapor deposition (PVD) or chemical vapor deposition (CVD) method by deposition or can be formed. Which an electrode section within a battery materials and film forming method are is publicly known to one skilled in the art. The materials which an electrode section within a battery, and without restriction, , inorganic or organic materials, includes the composite of both. Exemplary materials are the second electrode is located, polyaniline, polypyrrole, PEDOT or doped conjugated polymers, additional applying them with a dispersant having a paste of or graphite metals or dissociating metal particles, e.g. Au, Ag, cu, Al, Ni or their mixtures, and vaporized or sputter-coated metals, e.g. cu, Cr, Pt/Pd or metal oxides, e.g. includes indium tin oxide (ITO). In addition are organic metal precursor for RSSI measurement may be used, .may be film forming from liquid phase.

The present invention according to FET embodiment semiconductor layers types for applying the method and semiconductor materials, method and materials standard publicly known to one skilled in the art can be selected and from, disclosed is literature. Conventional uniform these materials, deposition of a doped amorphous silicon, microcrystalline silicon and polysilicon but selected from (polysilicon), a metal such as zinc oxide and cadmium oxides such as a selenate which the transferred material is. can be employed in addition. Semiconductor layers film and/or shaping an exemplary method are includes techniques are PVD and CVD.

In the case of types embodiment device of the present invention OFET, semiconductor layer and the organic semiconductor (OSC) layer, PVD, CVD or solution film forming method may be deposited by a n or OSC-type p can be. The OSC effective 1×10^-5 cm² V^-1 s^-1 FET exhibits and mobility greater than.

the present invention according to OSC embodiment, active channel OSC intended to be used as the material a OFET or OSC organic rectifying diode a layer of such organic component can be rectifying diodes (ORDs). A types such embodiment the OSC method film forming discussed prior film is deposited by any of but can be, OSC typically a semiconductor layer is formed on deposition or as blanket layer, spray-, dip-, web or spin-coating a solvent, such as coating method allows for processing ambient temperature are typically is adapted. However, any liquid coating technique the OSC, e.g. ink jet film forming or by PVD or CVD techniques are through. may be deposited.

The types a some preferred OFET embodiment, one or more 2 a semiconductor layer of different types of semiconductor same or can be composite of.. For example, p-type OSC material, layer for achieving reduction in doping effects, for example n-type material may be. Some preferred embodiment of the present invention in a, is carried out by using an acidulous multilayer semiconductors. For example, intrinsic semiconductor layer film formation on gate dielectric around the interface can be, highly doped regions adjacent the intrinsic layer such further can be coated with film.

The present invention according to embodiment electronic device used for OSC material types, any conjugated molecules, may include, e.g., at least 3 dispersed on the surface of the resultant aromatic ring of aromatic molecules in which can be. Some preferred embodiment of the present invention in a, the OSC 5-, 6 or 7-element aromatic ring selected from aromatic ring containing and, another preferred embodiment in the OSC 6-or 5 aromatic ring element selected from aromatic ring containing a. OSC material monomer, oligomer or polymer can be a, one or more monomers, oligomers or polymer mixtures, including and blend applying them dispersion.

Each of the aromatic ring of the OSC, Se, Te, P, Si, B, As, N, from S or O, N generally, O or S one or more pesticides selected from among optionally contain heteroatoms.. Furthermore, aromatic ring are alkyl, alkoxy, poly alkoxy, thio alkyl, acyl, aryl or substituted allyls , halogen, fluorine, cyano, nitro or-N (R¹⁵) (R¹⁶) and selectively permuted represented to a secondary or tertiary alkyl amine or arylamine selectively may be substituted, wherein R¹⁵ and R¹⁶ are each independently H, and selectively permuted alkyl or alternatively substituted aryl, alkoxy or poly the cock time which it will know procuce a. Furthermore, R¹⁵ and R¹⁶ when it will be biting and it is is or, they are selectively fluorinated may be.

Referred to said aromatic ring are, or can the ring condensed-C (T₁) =C (T₂)-, -C≡C-,^- N (R ')-, -N=N-, (R') =N-, -N=C (R ')-conjugated such as can be the user links the user's organizer link, wherein T₁ and T₂ independently from each other H, Cl, F, -C≡N or lower alkyl are, e.g. C_1-4 representing alkyl; R' the H, and selectively permuted alkyl or alternatively substituted lithiumorganyl exhibits. Furthermore, R ' the electrolyte optionally further comprises an additional light source device, which can be alkyl or agent which are included.

Some preferred embodiment of the present invention in an electronic device, OSC materials are that can be used, conjugated hydrocarbon polymers, such as poly polyacene, polyphenylene, poly (phenylene vinylene), their conjugated hydrocarbon polymers including of dimers and oligomers of polyfluorene or; condensation aromatic hydrocarbons, e.g. tetra pherocene, pherocene cleaning, pentacene, pyrene, perylene, group-containing norbornene film type inductor, or, their soluble substituted derivatives; oligomeric parameters substituted polyphenylene current, e.g. (p-4P) phenyl quarter-p, [...] -p (p-5P), [...] -p (p-6P), or their soluble substituted derivatives; conjugated heterocyclic polymers, such as poly (3-substituted thiophenes), poly (3, 4-disubstituted thiophene), selectively substituted polythieno [2, 3-b] thiophene, selectively substituted polythieno [3, 2-b] thiophene, poly 888000030388 8 (3-substituted selenophene), poly benzothiophene, poly [...] , poly (N-substituted pyrroles), poly (3-substituted pyrroles), poly (3, 4-disubstituted pyrroles), poly furan, poly pyridine, poly -1, 3, 4-oxadiazole current, poly [...] , poly (N-substituted aniline), poly (2-substituted aniline), poly (3-substituted aniline), poly (2, 3-disubstituted aniline), poly dibenzoazulenes, poly pyrene; pyrazoline compound are; poly selenophene; poly-benzofuran ; poly indole; poly dichloropyridazine; benzidine compounds; copolymers of stilbene; position type triazine; metal-free formyl substituted with orpin type , phthalocyanine current, fluoro phthalocyanine current, [...] or fluorocarbon [...] ; C₆₀ and C₇₀ fullerene; N, N '-dialkyl, substituted a dialkyl, diaryl or substituted diaryl -1, 4, 5, 8-naphthalene tetra carboxylic diimide layer and at least one fluoropolymer layer derivatives; N, N' -dialkyl, substituted a dialkyl, diaryl or substituted carbodiimide [...] diaryl 3, 4, 9, 10-perylene; vasopeptidase phenanthroline; [...] ; 1, 3, 4-oxadiazole current ;-2, 6-11, 11, 12, 12-tetra [...][...] ; α, α '-bis (structure of focusing electrode anode [3, 2-b2' , 3 '-d] thiophene); 2, 8-dialkyl, substituted a dialkyl, diaryl or substituted diaryl do not sprout the D mote five pen ; 2, 2' -dibenzo [1, 2-b:4, 5-b '] structure of focusing electrode cyanothiophene selected from the group consisting of compounds of compounds, oligomers and derivatives including. OSC and, if desired to liquid film forming techniques are, and derivatives thereof compounds from said list appropriate solvent or a mixture of a suitable solvent is limited by those are soluble in.

Furthermore, the present invention according to some in a highly desirable embodiment, OSC materials thiophene -2, 5-diyl, 3-substituted thiophenes -2, 5-diyl, selectively substituted thieno [2, 3-b] thiophene -2, 5-diyl, selectively substituted thieno [3, 2-b] thiophene -2, 5-diyl, selenophene -2, 5-diyl, or 3-substituted selenophene -2, 5-diyl-one of the aforementioned compounds in the distribution case former repeat units procuce a or copolymer polymers.

Other very desirable embodiment of the present invention in, OSC materials are pentacene, tetra pherocene or anthracene such as oligonucleotides substituted oh it counted, type , or its heterocyclic derivatives is. For example US 6,690,029 or WO 2005/055248 A1 or US 7,385,221 as disclosure to, bis (tree the alkyl it will be recorded Neel mote) oh it counted, type or bis (tree the alkyl it will be recorded Neel mote) hetero oh it counted, type oligonucleotides useful in addition. For example WO 2005/055248 A1 as described rheological properties to adjust where appropriate, or to program needs to be, some of the present invention embodiment for binders that includes at least one organic types including OSC. employ in composition.

Context, do not appear clearly to gain on the rest a, used in the present specification are within the lead-in area in the form of an impact on an upper surface of specification including short-lived term must be analysis to form, is and vice versa.

Types of the present invention said embodiment of the present invention are for variants for consisting a that lie within the ranges may be will understand. The present specification to features each disclosure, is not referred alternatively, same, equivalent or similar goals alternate provided characteristics may be replaced by. Therefore, is not referred alternatively, disclosure each feature equivalent or similar series of general of features is one example only.

Disclosure to specification is both features, these features and/or steps at least a portion of such mutually exclusive except combination, any combination may be combination. In particular, features of the present invention applicable to all aspects of the present invention, any combination may be used. Similarly, in combination a non-essential substrate features may be main power (the envelope value is not under the combination).

Numerous said substrate only features of the present invention embodiment form rather than as part of their own rights in advanced is it will be appreciated that. Current claimed addition to or alternatively any invention features thereof as an independent protection is pursuit may be.

Hereinafter, in the embodiment to the present invention with respect to more rapidly and to reduce a memory reference to are respectively, which exemplary only this not limit the range of the present invention.

In said and hereinafter, is not referred alternatively, percent which percent weight are, . given [...] the temperatures. Dielectric constant ε ("dielectric constant") values are taken at 20 °C. referring to values.

Is not referred alternatively, surface energy values are, D. K. Owens, R. C. Wendt, "Estimation of the surface free energy of polymers", Journal of Applied Polymer Science, Vol. 13, 1741-1747, 1969 or "Surface and Interfacial Tension: Measurement, Theory, and Applications (Surfactant Science Series Volume 119)", (the editor to the) Stanley Hartland, & Francis Ltd Taylor; 2004 (ISBN: 0-8247-5034-9), chapter 7, p. 375: "Contact Angle and Surface Tension Measurement", is Kenji Katoh method according to polymer in their mutually contacting angle measurement computed from. refers to those.

In next in the embodiment, some exemplary such composite routines for a monomer polymerization of monomer is certification are method. These in the embodiment of the present invention according to embodiment never are without limiting an know the start of the or. Additionally, composite routines and for each polymerization, is not referred alternatively a generally anhydride (anhydrous) conditions are installed at a a to significantly different. I.e., any embodiment substracte reaction vessel as a solvent when indicative of filled with, and/or any anhydrous solvent to remove of dissolved oxygen in the qualities of inert gases such as nitrogen is. the spraying device and.

A. Monomer synthesis.

In the embodiment A1. Synthesis of PhIndNB

Chiens searching turning mg (4.0 g, 0.16 mol) and 4-bromo phenyl norbornene (5 g, 0.02 mol) of, cooling water funnel and added in nitrogen atmosphere to 1 with capacitor multi function cap round bottom neck 3-liters (multi function cap or RBF RB) was immersed in. Propanamines anhydride (100 ml) in 4-bromo phenyl norbornene (35 g, 0.14 mol) solution of, using funnel added gently adding contents of multi function cap RB during heating weakly during the addition. to hold the apparatus of cooker. Added after completion, the reflux time 1 reaction mixture. A re-determined shade 2-indanon (21.3 g, 0.16 mol) anhydrous diethyl ether (100 g) which, dropped solution Grignard said added manner. Added after completion, 3-4 reaction mixture at ambient temperature and then reflux time during night stirring section. Distilled hydrochloric acid (1:1, 300 ml) after dilution to 1 time, are added to the reaction mixture stirring section. Red-orange color organic layer separating from the water phase, calculates a crude product concentrated and the at a reduced pressure was (36 g, 74% yield). Crude product the¹ H NMR it came to erase characterized by. Crude product is toluene (400 g) which, potassium hydrogen sulfate (30 g, 0.2 mol) added to a mixture. A nitrogen ambient under reaction mixture was reflux during night. The n bit parallel data inputted removing at a reduced pressure solvent, obtained yellow-orange color solid ethyl acetate (150 ml) recrystallizing the from the yellow solid product were given the. Filtrate is colorless solid yellow until a yellow light coloured thermoplastics by a washing of ethyl acetate were given the solid (15 g, total yield 31%). The final product (PhIndNB) the¹ H NMR it came to erase characterized by.

In the embodiment A2. NBCH₂ C₆ F₅ synthesis of

DCPD (23.8 g, 0.18 mol) and allylpentafluorobenzene (150 g, 0.72 mol) of premix and, the transfer Wibro clay auto stainless steel. Closes the reactor, about 20 psig using nitrogen reaction pressurize the nitrogen and vent line 3 to a released of nitrogen/vent cycles is performed for all the. Furthermore, reaction mixture heated in 10 psig nitrogen blanket 20 and 200 °C to the system time, reaction mixture cooled to room temperature a high percentage conversion was the scanning lines is decided according to gas chromatography analysis. The reaction mixture desired product NBCH₂ C₆ F₅ of includes the 48%. Pressure sensitive by a distillation using total yield and about 25% greater than 98% were given the end products are degree of purity to.

In the embodiment A3. NBC₄ F₉ synthesis of

DCPD (66.1 g, 0.50 mol) and 3, 3, 4, 4, 5, 5, 6, 6, 6-nonafluoro-1-hexene (246 g, 1.0 mol) of premix and, stainless steel was transferred to the first vertical furnace Parr. Closes the reactor, about 20 psig using nitrogen reaction pressurize the nitrogen and vent line 3 to a released of nitrogen/vent cycles is performed for all the. Reaction mixture heated in nitrogen blanket 10 psig and 200 °C to 8, which has the time. Reaction mixture cooled to room temperature and conversion decided by gas chromatography analysis. The reaction mixture desired product NBC₄ F₉ of was includes 78%. Furthermore, reaction mixture about distillation at a reduced pressure and total yield 36% exceeds 98% were given the end products are in purities of at least.

In the embodiment A4. NBCH₂ -2, 3-dimethylmaleimide (DMMIMeNB) synthesis of

Dimethyl maleic anhydride (679 g, 5.39 mol) and 6L of toluene with a, mechanical stirrer, [...] trap (Dean-Stark trap), capacitor and 12L was the it is bitter the wool couple multi function cap is filled with. Dimethyl male from anhydride is toluene dissolved in a admixture during was cooled to 16 °C. Mechanically agitated mixture, 663 g of 99% amino [...] (5.39 mol) rinse with 600 ml of toluene added. Observation of immediately heat to 34 °C, reflux is observed with gradually heating the mixture until (in order to avoid the excessive by-bubble). (Heat-up) 1.5h approximately from the beginning of the hot, in 109 °C, been clear solution (cleared). 98 ml of water (100% > theoretical) of the n bit parallel data inputted recovery in trap [...] , reaction has been completed it is found out that by GC. Furthermore, cool to such an room temperature mixture, wherein the filtration of the slurry suspension, filtrate rotation in order to carry out the method 1656 g (> 100%)of brown liquid is multi-sided, 98.9% purity (GC) was calculated. This pre-disposed (previous batch) 128.2 g from raw material (crude material) adding an residue, the vacuum distillation. Rolling water for recovering and (forerun) 132.1 g, 96.8% purity product and unreacted dimethyl male from any it has been discovered that the anhydride. Furthermore, number 1 fraction of 281.3 g, 99.4% purity 146-149 ° C (0.78-1.15 Torr) product to recover the in, number 2 fraction of 920 g, 149 °C (1.15-1.55 Torr) product purity 99.8% that were in. In a combined product purity > 99% number 1 and number 2 fraction was 1201 g the on the yields at 87%.

In the embodiment A5. NBCH₂ CH₂ synthesis of (MIEtNB) maleimide

The is ground just the company from maleic anhydride (388.6 g, 3.96 mol) and 6300 ml xylene to, mechanically agitated, capacitor, [...] trap and it is bitter the wool couple mounting was is filled with a reaction container. 19 °C are observed to temperature and one to lower, was [...] during calculates a solution. Amino-ethyl [...] (90.1% purity, 600 g, 3.94 mol) for, agitated mixture by adding dripping period ingredient 20, to raised to 49.3 °C temperature, thick amber solution is obtained. And reflux heating solution, 5 time 40 minutes after recessing a of water into trap [...] is observed, the stalled essentially been; 48.2 ml (68% theoretical) the recovers water. Reaction mixture 6.3-6.45 PPM proton-NMR analysis indicates the signal as a bankruptcy amino energized with a very weak in, GC analysis exhibit 86.8% of desired product. Reaction cooled to room temperature and, filtering and removed the solid white 71.8 g. A 3500 ml half of the reaction mixture, silica gels (1280 g) loaded directly on columns of, a reaction solution are silica column from elution section. Initial 1000 ml of eluate are (2.5% methanol/dichloro methane having by TLC) but without product, second 1000 ml, mainly a class of novel xylene been indicating one spot on TLC, rotation is evaporated product of 60.7 g (A2) is obtained. Silica gel is dichloro methane at flush it becomes, , 150.2 g products [...] impurities containing 1000 ml fraction are two consecutive 3 (each A3, A4, and A5) is obtained. Remaining reaction solution, a 3500 ml like is xylene contained in containers on silica 1273 g, was flush the zinc oxide particle is mixed with xylene advantageously be recycled. First 3 of 1000 ml xylene current fraction are each (B1-B3) have been shown to one spot on TLC. A obtained using toluene as eluent, then 1000 ml fraction, the B4 but provides one spot on TLC, then 1000 ml of toluene fraction are 2 (B5 and B6) in the presence of a by-product other have been shown to level frangible product. Fraction are A2, B1, B2, B3, and B4 combining, in evaporating rotation, crystallizes when the composition is left for 223.6 g provides oil. This was 97.4% pure by GC. 150 ml to re-crystallize the same the hot heptane from 124.4 g was calculates a 99.9% in purity. Second harvest (crop) calculates a 22.24 g was in the 99.7% purity.

In the embodiment A6. NBCH₂ synthesis of (MIMeNB) maleimide

Mechanically agitated, [...] trap, capacitor and is filled with a reaction container mounting it is bitter the wool couple maleic anhydride (117.0 g, 1.19 mol) of, mixing and-xylene with 860 ml o, 16.5 °C temperature and one to lower, was [...] during calculates a solution. Aminomethyl-norbornene (98% purity, 1.17 mol) of which-xylene 144 ml o, agitated mixture adding dripping during-off 15, so as to raise the temperature the white 64.6 °C were given the slurry. 5 while reflux heating at a mechanical mixture is set in agitating section. After 4.5 h in trap [...][...] , stopping at a 13.5 ml was (64% theoretical). TLC (2.5% methanol/dichloro methane) and the NMR, the presence and product as a bankruptcy amino novel acyclic absence of identified. And cooled to room temperature reaction, filtration and removing a white solid, 600 ml of portions achieved by dividing the two 2. Independently respective portion on a silica 1000-1100 g contained in containers, of methane at 6000 ml was flush. Combination are rotation of an eluant for eluting, 89.1 g is recrystallized from 40 ml hot heptane provides crystalline product 80.49 g product layer on the basis in 99.4% purity. 5.7 mol % o product NMR analysis have been shown to been contains more by-xylene. Decisions under high vacuum 45 °C o and the rotation but removing-xylene, 1.8% NMR analysis subsequent presence of maleic anhydride have been shown (associated with the event and an earlier in analyte detection assays o-xylene by marked by was non-volatile memory elements is considered). Decisions under high vacuum 65-75 ° C NMR and the rotation again by products presenting maleic acid anhydride of less than 0.6 wt % layer on the basis. Purity 99.4% GC analysis, including, but not to a water-sensing and maleic anhydride have been shown to. Yield is 7.2 g (32.5% yield), mp 69.1-71.3 ° C (in glass are 66.1-68.6 ° C) was.

In the embodiment A7. exo-N-NBCH₂ CH₂ -2, 3-dimethylmaleimide (exo-DMMIEtNB) synthesis of

Dimethyl male from anhydride (18.75 g, 0.149 mol) for, mechanically agitated, [...] trap, capacitor and the n bit parallel data inputted is filled with a reaction container mounting it is bitter the wool couple , dissolving in 120 ml fluorotoluene, the cooled to 18 °C solution. Solid exo-(aminoethyl) norbornene slurry toluene (20.4 g, 0.149 mol) dimethyl a metal added to the anhydride male from the n bit parallel data inputted, has come about, immediately and precipitation of solid white. A circulated response mechanically the reaction mixture during is set in agitating section. In 102 °C, the n bit parallel data inputted begins and to the position of the reflux, been clear solution. Reflux 17 minutes after, of theoretical amount that were in trap [...]. Additional reaction after reflux heating time 2, the cooled to 9 °C. Furthermore, solid removed and to filter out mixture, filtrate was calculates a 43.7 g and the rotation. Kugelrohr distilled in an oven to a same 175-185 ° C in 17.9 g (46% yield) was for recovering (< 1 mbar). Exhibit purity 99.0% GC analysis.

In the embodiment A8. NBCH₂-3-synthesis of (MMIMeNB) encapsulated polishing agents methyl

Citraconic anhydride (352 g, 3.15 mol) and 1500 ml of the toluene for, mechanical stirrer, [...] trap, capacitor, and the 5 L was it is bitter the wool couple multi function cap is filled with. Citraconic anhydride is toluene dissolved in a admixture during the cooled to 16 °C for monitoring a. Mechanically agitated mixture, [...] amino 99% (387g, 3.15 mol) and added, a 600 ml toluene. Been is a solid material immediate mixture, have been shown to heating to 39 °C. Heated attention mixture (excessive to avoid-bubble) the reflux. Hot start of approximately from 1.5 h, in 110 °C, been becomes clear solution, 56 ml water (100% > theoretical) of that were in trap [...]. GC analysis have been shown to been reaction is completed. Mixture was cooled to room temperature and filter the. Furthermore, filtrate rotation and the 672 g (98.2%)of brown liquid was calculated is multi-sided (97.9% pure by GC). Won in the vacuum distillation are exemplified 125-128 ° C obtained a 624 g purity 99.1% (1.15-1.2 Torr).

In the embodiment A9. Endo-/ exo-NBCH₂ CH₂ CH₂ CH₂ DMMI (DMMIBuNB) synthesis of:

it is bitter the wool well , capacitor opening nitrogen, added funnel and a mechanical agitator the 1L, 4 neck RBF to 200 ml of the toluene which contains then, potassium DMMI (35g, 0.21 mol) and 18-crown-6 (1, 4, 7, 10, 13, 16 hexa jade strabismus claw jade other D n, 5.7g, 0.021 mol, 10 mol %)was filling and while stirring the. 200 ml to funnel added endo-/ exo-NBBuBr fluorotoluene (45 g, 0.20 mol) which contains, added over factor 5. The same circuit, is heated to 100 °C mixture, has been observed on slurry hwang white (off white). Mixture further 100 °C it is under, stirring the processed by 6.5, as the observed first color from a turbid green then hwang whitereddish brown color had changed into. The monitored by GC reaction, unreacted 15.6% product and 73.6% reaction having an oxygenative or a hydrogenative endo-NBBuBr-/ exo showed been completed. Furthermore, after cooled to room temperature reaction mixture, and the emergent via addition of 250 ml, then the dilution in 150 ml toluene. Aqueous layer (2 × 200 ml) CH₂ Cl₂ and extraction of, and a washing of brine organic layers, Na₂ SO₄ through the dry, wherein the filtration of the slurry suspension, in order to carry out the method brown oil as crude product of 55.3g layer on the basis. Crude product for 55g SiO₂ and adhered on a, cyclopentane (3L), 2% EtOAc (5L) in cyclopentane, heptane in 3% EtOAc (3L) in heptane and 4% EtOAc (2L) having SiO₂ eluting 330g is chromatograph through. The fraction purified concentrate, purity 99.3% by HPLC a colorless viscous phase is an oil (yield 57.8%)as its product and 31g 99.09% purity by HPLC a 7.0g product (13.1% yield) was calculates a. Was 70.9% yield is for combined reaction.¹ H NMR DMMIBuNB the MS and data processing apparatus in in accord.

In the embodiment A10. NBCH₂ O₂ CCH=CHC₆ H₄ OMe (MeOCinnNB) synthesis of

4- [...]chloride:

First 3L, multi function cap round bottom neck 4 (RBF) mechanical agitator, it is bitter the wool well , and nitrogen adapter mounted is a condenser. Drying 2 L RBF to 0.1 ml pyridine and drying [...] 4-fluorotoluene (175 g, 982 mmol) was for filling. Added funnel to 107.2 ml (1.473 mol) SOCl₂ charging a same to the reaction mixture to room temperature then added gradually increases. Reaction mixture heated reflux and, was monitored by GC analysis (portion samples (aliquots) periodically fraction is concentrated to and, MeOH be quenched and, fixed human power by operating all systems). 5 process has been completed, GC analysis reaction is completed indicating purchases the passenger, the cooling room temperature reaction mixture. Excess SOCl₂ rotating and toluene on the evaporator, which comprises purifying an crude product distillation, 98.9% purity by GC 182 g of 4- [...] chloride (yield 94%)provides.

NBCH₂O₂CCH=CHC₆H₄OMe (MeOCinnNB): second 3L, it is bitter the wool well the RBF neck 4, a condenser adapter nitrogen, added funnel, and mechanical stirrer been, NBCH₂ OH (100 g, 805 mmol), dimethylamino pyridine (DMAP) (4.92 g, 40.2 mmol, 5 mol %)8 880000497888, 563 ml triethylamine (4.03 mol) and 1.2 L dichloro methane was for filling. Mixture it is under, stirring 45 minutes at room temperature, to funnel added while thereof, dissolved in 400 ml dichloro methane, obtained as said 4- [...] chloride (174 g, 0.885 mol) was to charge the. At room temperature a subsequent filtration step to a novel process of 4- [...] , in 25 °C mixture during night stirring section. Upon validation completion reactor GC, 1L dichloro methane at dilution and reaction mixture, the resulting solution (2 × 2L) NaHCO₃ solution, (2 × 1L) NH₄ Cl solution, (2 × 2L) after cleaning the brine to, Na₂ SO₄ and dried using, which filtering, 208g and the filtrate was recover the products in a jaw of. Furthermore, 200 g silica and adhered on a same, 0% to 30% EtOAc in cyclohexane having 600 g silica gel eluted adaptation chromatograph through. The fraction purified concentrate, GC purity 98.1% by a colorless viscous phase is an oil (58.3% yield) was calculated as product of 133 g. The that are combinations of additional fraction, another device having > 96% purity by GC a are obtained product 71.5 g, total yield 88% (205 g) layer on the basis.

In the embodiment A11, MeCoumNB synthesis of

NBCH₂OTs: mechanical stirrer, it is bitter the wool well , added funnel, and nitrogen adapter a first expressable mounting a condenser 3L, 4 neck RBF to, drying dichloro methane in 800 ml maltosyl chloride (376.5 g, 1.93 mol) and NBCH₂ OH (200 g, 1.61 mol) was for filling. 270 ml (1.93 mol) added funnel to the support member, and filling the triethylamine, 0 °C in its filling added the reaction mixture. TLC/GC reaction monitoring a room temperature reaction mixture by stirring section. TLC after 48 h monitoring have been shown to been reaction is completed. Furthermore, reaction mixture and then 1L dichloro methane at dilution, water 1L, (2 × 1L) NaHCO₃ solution, (2 × 1L) and a washing of brine, Na₂ SO₄ and dried using, was filtering. Furthermore, 463 g of filtrate and the overcoat and then also in the vacuum products, and adhered on a silica 450 g, 0% to 10% EtOAc in cyclohexane having 1600 g eluted through silica gel chromatograph section. Chromatography concentrated purified fraction are, by GC purity 95.3% colorless naturally tacky, and an oil (95% yield) as the n bit parallel data inputted calculating product of 427 g; proton NMR the in accord.

MeCoumNB:it is bitter the wool well , nitrogen adapter a condenser, is coupled to a second mounted a mechanical agitator and 3L, 4 neck RBF to, 7-hydroxycoumarin (168 g, 1.04 mol), potassium polycarbonate (179 g, 1.29 mol), NBCH₂ OTs (300 g, 1.08 mol) which contains, NMP drying 1.5L rinsed with section. Reaction TLC/¹ H NMR by monitoring a mixture adaptation and agitating the heated to 100 °C. Proton NMR the 54 h indicating purchases the passenger after reaction is completed, then the cooling room temperature reaction mixture. Furthermore, the n bit parallel data inputted be quenched 24L 1N HCl reaction mixture, a the resulting hwang white solid filtered, rinsed with water and 4L, 268 g of drying the crude product is obtained. Charged up on the product with a 5L RBF, 2 L (3:1 ratio) heptane: toluene which, 26.8 g of charcoal (charcoal) and recirculating a, the through an pad silica. Filtrate concentrated within, excess heptane: toluene (3:1 ratio) by HPLC added to a bright white crystalline product which has a purity 98.2% 158 g (57% yield) is obtained.

In the embodiment A12. NBCH₂ CH₂ O₂ CCH=CHC₆ H₄ OMe (EtMeOCinnNB) synthesis of

5-norbornene-2-ethanol (NBCH₂CH₂OH): 19 liters 611 g (4.6 mol) reactor Parr DCPD ene and charging the 2000 g (27.7 mol) 3-butene-1-ol. With stirring, in a, reactor after flush times 3 nitrogen, nitrogen 10 psi was sealing under pressure. Reaction time 2 220 °C period minutes 17 and to be brought into, 185 psi maximum for monitoring a pressure got to the top of. Reaction 4 in 220 °C it is under, stirring time, predetermined voltage to 130 psi pressure. Furthermore, reaction mixture cooled to room temperature and, , and drain water and, that were the reaction mixture of 2603g. GC analysis, and excretions containing organics and apparatus therefor is 65.6% NBEtOH by GC isomers are have been shown to containing a (3-butene-1-ol also in addition present invention is also directed to, it is solvent front therefore not calculated). Excess 3-butene-1-ol 1260 g for 50 °C remove the rotate by evaporation. The resulting citrus, glass helix 14 having packing " under high vacuum the through a column was purified by distillation. The 5 and 4 are fraction is pure 95.6% and 96.1% been found, been recovery. In each fraction, DCPD, F5 3.5% and F4 3.4% in addition solvent containing the triac has been found to exist. (F4+F5) = 721.8 g. total yield has a > 95% purity % Yield = 56.5%.

NBCH₂CH₂O₂CCH=CHC₆H₄OMe (EtMeOCinnNB):it is bitter the wool well , added funnel, and a mechanical agitator the 100 ml, 3 neck RBF to, NBCH₂ OH (2 g, 14.47 mmol), DMAP (88.4 mg, 0.72 mmol, 888 0001203888, 10.1 ml triethylamine (72.35 mmol) and 25 ml dichloro methane was for filling. In 4-5 ml dichloro methane from funnel added [...] chloride (3.13 g, 15.92 mmol) addition of 45 minutes begins mixture to room temperature stirring section. After complete added, stirring during night in 25 °C mixture adaptation. Upon validation completion reactor GC, reaction mixture dilution and then 20 ml dichloro methane at, (2 × 25 ml) NaHCO₃ solution, (2 × 15 ml) NH₄ Cl solution, (2 × 25 ml) and a washing of brine, Na₂ SO₄ and dried using, was filtering. Filtrate for concentrating by the GC purity bath 96% colorless naturally tacky, and an oil (yield bath 93%)as 3.9 g of crude product is obtained.

In the embodiment A13. Nor [...] (EtCoumNB) synthesis of

NBCH₂CH₂OTs: mechanical stirrer, it is bitter the wool well , added funnel, and nitrogen adapter with a condenser 5L, 4 neck RBF to, maltosyl chloride (CH₃ C₆ H₄ SO₂ Cl = TsCl) (745 g, 3.9 mol) and NBCH₂ CH₂ OH (450 g, 3.26 mol) and was 2 litre drying dichloro methane for filling. 547 ml (3.9 mol) added funnel to the support member, and filling the triethylamine, 0 °C marked on the specific already added the a reaction mixture. Reaction TLC/¹ H NMR monitoring a by and went on agitation at room temperature. 24 hours, quantization NMR analysis have been shown to been reaction is completed. Furthermore, reaction mixture and then 4L dichloro methane at dilution, 2L water, (2 × 1L) NaHCO₃ solution, (2 × 1L) and a washing of brine, Na₂ SO₄ and dried using, wherein the filtration of the slurry suspension, filtrate rotation and the¹ H NMR colorless purity > 95% by naturally tacky, and an oil (yield bath 110%)1064 g of crude product is obtained as (structure and agreement). Additional crude product, are employed in next reactor without purification.

EtCoumNB:it is bitter the wool well , nitrogen adapter a condenser, the a mechanical agitator and 12L, RBF to neck 4, 7-hydroxycoumarin (450 g, 2.77 mol), NMP drying 3.5 L, potassium polycarbonate (498.6 g, 3.6 mol), NBCH₂ CH₂ OTs (932.6 g, 3.19 mol) and 1L drying was to charge the NMP. The same circuit, is heated to 100 °C while agitating the mixture, was monitored by TLC/NMR. TLC/¹ H NMR 24 h monitoring indicating purchases the passenger after reaction is completed, the cooling room temperature reaction mixture. Furthermore, reaction the be quenched 50L 1N HCl, filtered hwang white solid as product, and to assure the hardware resource are compositions thereof, (5×4L) and rinsed with water, drying the 1394 g of crude product is obtained. 1394 g crude product for 4L dichloro methane was dissolved in the nonaqueous solvent. About 500 ml of and for separating water and removing; remaining dichloro methane solution then Na₂ SO₄ through the dry, wherein the filtration of the slurry suspension, and the 864 g of crude product is obtained. 864 g crude product of combining product and tank pilot 60 g, dichloro methane which, and adhered on a silica 1000 g, 0% to 25% EtOAc in cyclohexane having adaptation chromatograph through 4 kg silica gel electroelution. The fraction purified concentrate, by HPLC > 97% purity (fluffy) bright a nonstiffness a yellow solid as product of 508 g was calculated. Furthermore, product, 1.6L reflowed a heptane: toluene (4:1 ratio) from the to re-crystallize the 99.3% by HPLC purity bright white crystalline powder product 480 g (57% yield) is obtained;¹ H NMR the in accord.

-1-butyrate in the embodiment A14 . 4-nor [...]neel tree ethyl thread column (NBCH₂ CH₂ C≡CSiEt₃ (AkSiNB)) synthesis of

NBCH₂CH₂OMs: it is bitter the wool well , nitrogen adapter, the a mechanical agitator funnel and added 12L, RBF to neck 4, 5-(2-hydroxyethyl) norbornene (420 g, 3.03 mol), 4 L dichloro methane, and methane sheet excellent (CH₃ SO₂ C_l or MsCl) (369 g, 3.22 mol) was to charge the. By the addition of extra 500 ml dichloro methane CH₃ SO₂ C_l in rinse section. And marked on the specific to -16 ° C agitated mixture, triethylamine (371 g, 3.64 mol) of 1.5 time periods and over the dripping adding, during temperature are observed to 0 °C was added so as to raise the. The resulting slurry 4 time periods and over the after heating continues to 189 °C, continue with stirring, in a 2 L added water. After completion the addition of water, and phase is separated, extracted aqueous phase 2 L dichloro methane at. Combined dichloro methane extract (2 × 2 L) NaHCO₃ solution of 1600 ml and then cleaning after cleaning the to 1 N HCl, pH = 6 cleaning and permits observation of 2000 ml portions until an equivalent volume of saline rinsed with section. Then dichloro methane solution a dry, sodium sulfuric acid, wherein the filtration of the slurry suspension, rotation in order to carry out the method red liquid 612.5 g is obtained. NMR the in accord. 93.2% GC analysis layer on the basis of mesylate content. Because visible instability during distillation material is further or more refinement an attempt not been provided for.

NBCH₂CH₂B r: it is bitter the wool well , nitrogen adapter, the a mechanical agitator funnel and added reactor 22L, lithium bromide (369 g, 4.25 mol) of 2-4L and the support member, and filling the pen hit rice field , LiBr which agitates the until is dissolved, then 30 °C to solution to a warming section. Furthermore, 2-2 L of dissolved nor [...]in pen hit rice field (612.5 g, 2.83 mol) a LiBr solution after added with stirring, in a, additional 2L of the 2-pentanone more dilution (= 8 L total volume of cyclopentanone 2-). Furthermore, and reflux heating solution, white slurry has been observed on installed from being in an. 92 °C a password obtained when the user terminal, is left starting materials of less than 0.8% GC analysis show that purchases the passenger, reflux 1 hours, GC analysis is left on the starting materials have been shown to not. 27 °C by a mixture, by adding distilled water 4L him up mixture. And phase is separated, (2 × 2 L) ethyl which has a water phase extracted. Organic portions combines the, evaporated rotation power in less than 30 °C. Residue is rinsed using methane of 4 L as a solvent fractionation was transferred to a funnel. Product (2 × 1L) final and then cleaning [...] dicarboxylic sodium saturation be acquired until pH =7 1L brine cleaning section. Product sulfuric acid sodium dry, wherein the filtration of the slurry suspension, 440 g of filtrate rotation and the crude product is obtained (93.6% purity by GC). For crude product then 14 inch Vigreux column then wherein the n bit parallel data inputted vacuum distillation using been recovery are fraction: 1 . 16.9 °C (10 Torr)-42.8 °C (1.15 Torr), 20.6 g, 97.5% according to GC, according to NMR 2-pentanone no; 2 . 42 °C (0.83 Torr)-44.4 °C (0.33 Torr), 334.2 g, 98.0% according to GC; 3 . 32 °C (0.3 Torr)-44.3 °C (0.32 Torr), 93.5% according to 53 888000192388 8, dimers of more than 98.5% % 3.5% CPD dryer and control method thereof. The total yield of product purity exceeds 93% this solution is poured into a tender 407.8 g (71.6% yield).

NBCH₂CH₂C≡ CSiEt₃ (AkSiNB): 3L, 4 neck RBF it is bitter the wool well to, nitrogen adapter, mounted agitators in the mechanical funnel and added. In 800 ml RBF to drying THF [...] tree (128.4 g, 915 mmol) was for filling. Reaction mixture -78 ° C by a, 359 ml n-BuLi (hexane in 2.5M, 899 mmol) is slowly added to the polymerization reaction mixture to, 1 in -78 ° C adaptation stirring time. Then and warming to 0 °C reaction mixture, added in DMSO drying 640 ml to funnel NBCH₂ CH₂ Br (160 g, 795.6 mmol) was for filling. NBCH₂ CH₂ Br after added gradually solution, reaction mixture adaptation stirring time 2 and heating at room temperature. GC contents-by means of an analysis surface, at room temperature been reaction is completed after stirring time 2. 4L water and of quenching a reaction mixture, and then dilution in heptane 8L, (3 × 8L) water, (2 × 4L) and a washing of brine, Na₂ SO₄ and dried using, wherein the filtration of the slurry suspension, evaporated. GC analysis, 62% product and 27% a by-product crude product is (Et₃ SiCCSiEt₃) have been shown to containing. 178 g of product, glass helix 14 having packing " the capacitor through a column and distilled [...] tree Et₃ SiCCSiEt₃ separated the an evacuating a by-product. Product is a 99% in purity exceeds 0.20-0.21 mmHg (88.8 g, yield 43%)boiling point = 93-97.5 ° C been acquiring.

In the embodiment A15. NBCH₂ CH₂ C₆ H₄ DMMI (EtPhDMMINB) for manufacturing

Bromo phenyl -2, 3-dimethylmaleimide (BrC₆H₄DMMI): 1L RBF to magnetic stirring rod, nitrogen adapter mounted is a condenser. RBF to 600 ml glacial acetic acid in 4-bromine-aniline (150.1 g, 872 mmol) and dimethyl maleic anhydride (DMMA) (100 g, 792 mmol) was for filling. Reaction mixture and reflux time 6, identified TLC in 30% EtOAc in heptane. According to TLC, been reaction is completed, reaction mixture was during night. hwang white product formed by implanting solid as determined, wherein the filtration of the slurry suspension same adaptation rinsed with MeOH. Determination which EtOAc, NaHCO₃ adaptation cleaning solution. Organic layer Na₂ SO₄ through the dry, 99.7% purity by GC after concentrate having bromo phenyl -2, 3-dimethylmaleimide (BrC₆ H₄ DMMI, 169.8 g, 76.5% yield) is obtained.

NBCH₂CH₂C₆H₄DMMI (EtPhDMMINB): 3L, 4 neck RBF it is bitter the wool well to, nitrogen adapter a condenser, mounted agitators in the mechanical funnel and added. Zn to RBF (82.0 g, 1.26 mol), iodine (10.6 g, 0.04 mol) of inorganic 800 ml and (degassed) N-methylpyrrolidone (NMP) was for filling. Until the subsequent disappearance of said color red of iodine (about 2 ingredient) mixture adaptation stirring room temperature. Added in NMP of inorganic 100 ml to funnel NBCH₂ CH₂ Br (169 g, 0.84 mol) was for filling. NBCH₂ CH₂ Br adding solution is dripped, 3 mixture 80 °C time stirring section. Hydrolyzed a reaction mixture contents-by means of an analysis GC shown completions to the zinc added. Mixture by a 60 °C, BrC₆ H₄ DMMI (157 g, 0.56 mol) and Pd (PPh₃)₄ (51.8 g, 0.045 mol) a 60 °C an added. Furthermore, 80 °C reaction mixture in 30 minutes heating the time 2. Portion of specimen with a and be quenched 1N HCl and then EtOAc extraction of GC was monitored reaction by analyzing. 2 time 30 minutes after, the n bit parallel data inputted presence of only product 38.8% according to GC, thus, other 2 mol % Pd (PPh₃)₄ added, again 1 in 80 °C it does but stirring time, an observation apparent change in product not been provided for. Cool to such an room temperature reaction mixture, be quenched and 2L 1N HCl, in cyclohexane (2 × 4L) 50% EtOAc to extracted. Combined an organic phase, NaHCO₃, and a washing of brine, Na₂ SO₄ and dried using, wherein the filtration of the slurry suspension, evaporated. 200 g of silica and adhered on a 200 g product, 0% to 20% EtOAc in cyclohexane having 800 g silica gel eluted is chromatograph through. The fraction purified concentrate 94% purity by GC exceeds hwang white solid product (yield 17%)30.4 g was calculates a.

In the embodiment A16. Exo-nor [...] - [...] (exo-NBCH₂ CH₂ C₆ H₄ C≡CSiEt₃ (ArSiNB)) for manufacturing

[...] -norExo:

Nitrogen purged 5 neck glass jacket reactor 3 L, 400 ml of anhydride in DMF 1-bromo-4-urethral benzene (250 g, 884 mmol) and PdCl₂ (PPh₃)₂ (6.20 g, 8.84 mmol) to, nor [...] n (360 ml, 3.54 mmol), triethylamine (Et₃ N) (398 ml, 2.85mol) has added. 50 °C bath body is opened hot water having set-point was heating a reacted through. In internal reactant temperature 50 °C, formic acid (88%, 80 ml, 1.86mmol) through funnel is added by adding a stowed manner was the connection of a occurrence of exothermic reaction. Heating the solution, which agitates the time 50 °C 1.25 in, each ingredient 15 GC monitoring a sampled 1-bromo-4-urethral benzene is ensured a to have undergone an aspect reaction both. Reaction mixture cooled and, fractionation funnel transported to the, 470 ml of heptane in 500 ml of 10% HCl and extracted. Combination and water-based layers was discard. Combined organic layers of 5 g MgSO₄ and dried using, 30 minutes stirring section. Mixture through a column chromatography silica gel (200-425 Mesh) the n bit parallel data inputted to provide access to the filtration using, adaptation eluting in heptane same. Exo-nor [...] (169 g, yield 77%)of 0.2 Torr and main/secondary moment sections 90 °C raw material set in the pico-cell information purified through distillation. 62 g are cut distillation (> 80%), containing the n bit parallel data inputted 80 g (> 99%), colorless liquid was. is, a by-product the reaction impurities main in the sample, it n [...] nor by GCMS him been identified, (NB-NB) dimers of more than 98.5% %. Exo-nor [...] samples (> 99%)pure¹ H NMR the n bit parallel data inputted analyzed through, said structure and the values correspond literature.

Exo-NBCH₂CH₂C₆H₄C≡ CSiEt₃ (exo-ArSiNB):

Nitrogen purged 1 L 3 neck glass jacket reactor, [...] -nor exo-carboxy anhydrides of 750 ml in DMF (103.8 g, 0.417 mol) and tree [...] (70.2 g, 0.5 moles) to, d butyl amine (Bu2NH) (77.5 g, 0.6 mol), PdCl₂ (PPh₃)₂ (10.53 g, 0.015 mol), and copper (I) iodide (2.86 g, 0.015 mol) has added. 65 °C bath body is opened hot water having set-point was heating a reacted through. The established connection continues to solution is heated, in monitoring a GC time intervals and 3 27 65 °C exo-nor [...] both agitating time ensured a reaction to have undergone an aspect. Reaction mixture cooled and, 200 ml of 10% HCl and extracted in heptane of gram 410. Combination and water-based layers was discard. Combined organic layers through a column chromatography silica bed (200-425 Mesh) the n bit parallel data inputted to provide access to the filtration using, adaptation eluting in heptane same. Won of 122 g was containing exo-nor [...][...]. is, a by-product the reaction impurities main in the sample, dimers of more than 98.5% % acetylene by GCMS it Et₃ SiC≡C-C≡CSiEt₃ him been identified,. Won purified by distillation ray radiating property cannot be, one more time through a column chromatography using silica gel to adaptation eluting in heptane and reprocessing. Final materials (43 g, yield 35%)the light coloured thermoplastics (> 98% purity) was a yellow oil.¹ H NMR the end product combining of microscope and an exo-nor [...] it is found out that.

In the embodiment A17, epoxy [...] (EONB) for manufacturing

Metering pump mounting supply way tank (feed weigh tank) and divided-range pressure control scheme as device for providing, dedicated culvert unit is mounted is 1, 2-epoxy-9-octadecene (EPD) a jacket reactor (≥ 96% (31.5 kg)) was for filling. DCPD EPD and (DCPD) (≥ 98%) (9:1 molar ratio) of making and 4.32 kg of premix, was is filled with tank way supply. (3) nitrogen with a pressure/vacuum swing using a reactor head space oxygen is removed by inserting the non from, was so as to press the 5 psig using nitrogen. The same circuit, is heated to 210 °C hybrid reactor contents, 6 at a temperature over a period of time at a constant rate was metering premixes into reactor. Metered after completion addition, 25 °C rapidly cooling the hybrid reactor contents.

Reference a A table hereinafter: line and at the same time data publicly known heavy epoxy octyl norbornene (EONB) of reaction mixture, heating mantle antitumor agents having improved port (still pot), packed distillation column (of theoretical plates 3), reflux splitter, capacitor for water, concentrate receptacle and by means of a vacuum pump to a vacuum distillation setup was is filled with. Vacuum distillation system been adjusted to a desired set point, still teaching oil heated fluid obtained by heating a fluid port establishing conditions reflux in the distillation column. Once these conditions are been established, then reflux-splitter is made being activated in ratio and a return desired, an overhead receptor liquid from fractional distillation by removing periodically fraction was carried out to. Overhead liquid fraction using GC composition of decided to crack down on all. The ratio overhead stream reflux distillation composition of to influence been adjusted as needed. Initial overhead fraction are, cyclopentadienes mainly (CPD), DCPD (DCPD) and epoxy hexadecene (EPD) in "light" component was that is enriched in low. After removal of components "light", then intermediate purity EONB (≥ 92%)a dryer and control method thereof cyclopentadienes remaining [...]as many as hour claw counted tetra octyl and epoxy (CPDT) separated from the (EOTD). EOTD those a heavy part and other black water slurry to port steel for (heavies).. Once most of steel is EONB from residue port been the gap when the distillation process is terminated.

Reference a B table hereinafter: obtained from distillation number 1 number 2 pass distillation intermediate purity purity using EONB EONB (≥ 98%)were given the product.

Table A-distillation number 1 pass

Bath EONB charge of: 36.82 kg

Steel port temperature: EPD 95-100 °C EONB 130-140 °C

Overhead temperature: EPD 65-70 °C EONB 90-100 °C

System vacuum: EPD 2-3 mmHg EONB 0.15-0.20 mmHg

Reflux ratio: EPD 2:1 EONB 1:1

Table B-distillation number 2 pass

Intermediate purity EONB charge of: 6.66 kg

Steel port temperature: EONB 120-130 °C

Overhead temperature: EONB 89-92 ° C

System vacuum: EONB 0.10-0.20 mmHg

Reflux ratio: EONB 3:1

Norbornene (DHNMINB) for manufacturing [...] methyl encapsulated polishing agents in the embodiment A18 . 3, 4-

57.5 g of methylamine norbornene fluorotoluene (60.0 ml, 0.49 mol) of, approximately 290 g 3, 4- [...] anhydride dissolved in toluene (80.1 g, 0.40 mol) added with stirring, in a buck dropped manner. Bright brown solids are may have formed thereon. Was heating a mixture. The solid at between 65-95 °C a dense transparent brown solution is obtained. And reflux heating solution, time 6 [...] trap (8.6 g) remove the water circulates through the storage tank. Of breaking reaction mixture, naturally tacky, and very evaporator rotation a brown oil (170 g) was concentrated. Oil (80 g) portion, 5:1 of ethyl acetate and hexane as eluent mixture silica gels was purified by column chromatography. 25 that were to fraction 125 ml of. Combining 4-12 vice-ratios , rotation evaporator a viscous concentrated dry state using a yellow oil (19.7 g) is obtained.¹ H NMR DHNMINB microscope and an of product is a mixture of by.

In the embodiment A19. Norbornene [...]acetate (NBCH₂ GlyOAc) for manufacturing

5.51 kg the jade hour ethyl which will inform for initial charging of the of the into the reactor was heated to 210 °C. Dicyclopentadiene of 0.32 kg acetate and the jade hour ethyl which will inform 0.07 kg of premix and, a metering container is filled with, once metered reaches a reaction temperature is 5 time periods and over the put reactor sensed. Metering period at the expiry of, filling room temperature cooled and, it does, analyzed by GC, approximately 0.6% and 0.9% tetra as many as hour claw counted[...] cyclopentadienes dryer and control method thereof with [...] representing purchases the passenger 29% norbornene [...] acetate; remaining most the jade hour ethyl which will inform acetate is (all users' a GC area %). Norbornene [...] acetate to a column packing is obtained in tablets of base stock by vacuum distillation fractionation on been is agreed with the specific game. Overhead temperature 65 to 67 °C respect to purity the at least one range of 150 to 200 mTorr been embodiment is distillation. Approximately 80% is sucked into the nor [...] been recovery in purity greater than 99% (based upon the % GC area).

In the embodiment A20 . 2-propene-1-on, 1-(4-bicyclo [2.2.1] methylhept-5-n-2-methoxyphenyl)-3-(4-methoxyphenyl)-(MCHMNB)

4'-hydroxy-4-methoxychalcone: 10:8 1.8L mixture of methanol in water and sodium hydroxide (100g, 2.50mol) presymptomatic hydroxy 4-solution (136g, 1.00mol) has added. After 30 minutes at room temperature, added to the mixture for 4- [...] (136g, 1.00mol) for added. 16 time in bath oil 50 °C reaction mixture stirring section. Transparent yellow solution is obtained it been 30 minutes was stirring at room temperature. Dichloro methane and THF 1N HCl and 600 ml 1:1 mixture of aqueous solution (500 ml) by the addition of two layers 2 was to obtain. Organic layer saturation NaHCO₃ aqueous solution (300 ml × 2) and water (300 ml × 3) and a washing of, solids orange color was calculated in order to carry out the method. 300 ml of EtOAc to 2 times for the solid cleaning section. The resulting yellow solid was very dry in a vacuum. Yield 133g (52%).¹ H NMR (CDCl₃): δ3.85 (s, 3H), 6.93 (m, 4H), 7.47 (d, 1H), 7.50 (d, 2H), 7.75 (d, 1H), 7.96 (d, 2H).

2-propene-1-on, 1-(4-bicyclo [2.2.1] methylhept-5-n-2-methoxyphenyl)-3-(4-methoxyphenyl)-(MCHMNB): 200 ml of DMF in K₂ CO₃ (18.0g, 0.130mol) solution 4'-hydroxy-4-methoxychalcone (25.4g, 0.100mol) and bicyclo [2.2.1]-2-methylhept-5-n methyl trifluoromethane sulfonate (23.3g, 0.115mol) for added. In bath oil 100 °C 24 is reaction mixture adaptation stirring time. Orange color been is obtained suspension, it was stirring room temperature time 1. 1N HCl aqueous solution 300 ml of methane and of 300 ml by the addition of two layers 2 was to obtain. Adaptation rinsed by means of a a salt with the organic layer. Furthermore, NaHCO₃ aqueous solution (200 ml) and water (200 ml × 5) for evaporating the orange color was calculated solid. 300 ml of EtOAc to 2 times for the solid cleaning section. The resulting light coloured thermoplastics a yellow solid was very dry in a vacuum. Yield 16.0g (44%). Structure¹ H NMR (CDCl₃) have been determined by.

In the embodiment A21. Nor [...] -3, 4-dimethyl -1H-pyrrole -2, 5-dione (NBCH₂ CH₂ DMMI) for manufacturing

[...] cyano: 1L, 4 neck RBF it is bitter the wool well to, nitrogen capacitor opening, agitators in the mechanical stopper and mounted. [...] chloro to RBF (120 g, 0.84 mol, 95.6% pure), NaCN and solid 400 ml DMSO (74.2 g, 1.51 mol) was for filling. NaCN by adding extra 20 ml DMSO in rinse section. Reaction mixture -90 °C time 72 stirring section. GC analysis of a specimen of said portion, all starting material is exhausted have been shown to been reaction has been completed. The cooling room temperature reaction mixture. Multi function cap water spilled on the box is provided approximately 200 ml, the dilution to 200 ml MTBE. Face toward a half-mirror member organic, aqueous layer extracted to (3×300 ml) MTBE. And combination with organic, aqueous of the cleaning, a, until it reaches a pH = 6 (3×500 ml) rinsed with tap water, to the section. MTBE night through sodium sulfate anhydride solution during dry, wherein the filtration of the slurry suspension, rotation is capable of vaporizing low vapor pressure, high vacuum time in bath temperature 50 °C 3 (0.94 torr) under drying by GC purity 95.8% 112 g (100% yield) is obtained. Proton NMR analysis where the materials have been shown to containing -1% MTBE. During the dense brown crude product was without further refinement for use during the next reactor. Data: DB5 column on GC analysis, emitter 30, 0.32 mm ID, 0.25 micro m film, in 25 °C/min 300 °C to 75 °C, in minutes, and 2 300 °C, injector temperature: 275 °C, detector temperature: 350 °C

Amino [...] : 3L, 4 neck RBF it is bitter the wool well to, nitrogen capacitor opening, agitators in the mechanical funnel and added mounted. pellets (LAH) lithium aluminum on RBF (67 g, 1.77 mol) which contains, 840 ml methyl-tert-butyl ether (MTBE) to mechanical during night is set in agitating section. Been thick paste is obtained, additional 200 ml of MTBE added to solution LAH a. The resulting dispersion methanol-ice bath was marked on the specific to the -5.5 °C. [...] cyano in 500 ml MTBE to funnel added (112 g, 0.84 mol) which contains, reaction temperature kept at less than -2 ° C dripping to such a speed that the added. (Attention: the reaction temperature, unreacted starting material the accumulation of potentially dangerous induction period of caused in order to avoid dropping -5 ° C less than drops is allowed to. not have to) time 1 time was added. Cooling [...] been removed, then 1.5 time periods and over the mixture the same circuit, is heated to 35 °C, GC analysis indicating including the step of starting materials when further 35 °C 30 minutes stirring section. -15 °C mixture (methanol/ice bath) by a, 125 ml distilled water of a very gradually adding 3 time 30 minutes, was kept at less than 0 °C temperature. Then also in the vacuum and dilution to 500 ml MTBE mixture, second water by the addition of 125 ml portion, whereby a free-flowing white solid as aluminum lithium and adaptation precipitation are a by-product. 10 minutes after stirring, lithium and aluminum and populating are a by-product, MTBE phase adaptation d cant (decanted). Additional residue aluminum lithium and after covered (2×500 ml) MTBE, mixing and, tightened and, a MTBE d cant section. MTBE d cant combination with and, after a dried using sodium sulfate, wherein the filtration of the slurry suspension, rotation is capable of vaporizing low vapor pressure, high vacuum (0.94 torr) 3 in 50 °C temperature bath under bright drying time a yellow viscous phase is an oil 104 g (90% yield) is obtained. GC analysis to exhibit purity 96.4% 2.9% DCPD.¹ H NMR analysis where the materials have been shown to containing -1% MTBE. The crude product is next process without further refinement, are employed in. Data: DB5 column on GC analysis, emitter 30, 0.32 mm ID, 0.25 micro m film, in 15 °C/min 300 °C to 75 °C, injector temperature: 275 °C, detector temperature: 350 °C, holding time: 5.280 ingredient.

NBCH₂CH₂DMMI: 3L, 4 neck RBF the, it is bitter the wool well , nitrogen opening connected to capacitor [...] trap, mounted agitators in the mechanical funnel and added. 600 ml RBF to dimethyl with stirring, in a and then are input, in toluene male from anhydride (DMMA, 92g, 0.73 mol) was are input, in. Dimethyl male from anhydride is toluene dissolved in a admixture during 14 °C was cooled to. Mixture to the surface of the solution 25 °C him up. Added 100 ml to funnel [...] amino fluorotoluene (104 g, 0.73 mol, 96.4% pure) was turned on, 15 minutes added by a non-contacting method. Additional 130 ml toluene is added in the amino [...] rinsing and drying, the replaced by stopper funnel added. The n bit parallel data inputted heating terminal requests the 50 °C mixture, has been observed on-based precipitate thick white. Mixture heated attention 30 minutes (to avoid excessive-bubble) and reflux, the reflux time 2. The n bit parallel data inputted observing transparent solution, in trap [...] 13.1 ml was the recovery of water (99.5% theoretical). GC analysis, been reaction is completed (7.8 factor 1.8% DCPD and 94.9% product with a unknown 1.7%)have been shown to. Reaction mixture cooled and room temperature, transferred to a multi function cap 5 L and, concentrated in the evaporator on rotation. For crude product is on evaporator from twisting during time 5 75 °C bath temperature high vacuum (0.94 torr) under additional dry, a turbid orange color naturally tacky, and 179 g is obtained crude product as an oil. GC analysis, high vacuum in the after drying of the crude product to 1.8% and 0.3% DCPD purity 97.4% with a unknown have been shown to randomly choosing. 179 g of a silica 179 g product of lead ball and separates the lead gel, heptane (8L), heptane in 2% EtOAc (2L), heptane in 2.5% EtOAc (2L), heptane in 3% EtOAc (4L) 5% EtOAc (1L) in heptane and having 500 g silica gel eluted adaptation chromatograph through. The fraction purified concentrate, 99.8% purity by GC colorless naturally tacky, and an oil (91% yield) was 163.5 g product as calculates a.¹ H NMR and mass spectrum structure and in accord. Data: DB5 column on a GC analysis embodiment, emitter 30, 0.32 mm ID, 0.25 micro m film, in 15 °C/min 300 °C to 75 °C, in minutes, and 2 300 °C, injector temperature: 275 °C, detector temperature: 350 °C, holding time: 11.893 ingredient.

In the embodiment A22: nor [...] -3, 4-dimethyl -1H-pyrrole -2, 5-dione, (NBCH₂ CH₂ CH₂ DMMI)

[...] cyano: 1L, 4 neck RBF it is bitter the wool well to, nitrogen capacitor opening, agitators in the mechanical stopper and mounted. [...] chloro to RBF (100 g, 0.64 mol), NaCN and solid 300 ml DMSO (43.8 g, 0.89 mol) was for filling. NaCN by adding extra 20 ml DMSO in rinse section. Reaction mixture -80 °C time 2 stirring section. GC analysis of a specimen of said portion, all starting material is exhausted have been shown to been reaction has been completed. The cooling room temperature reaction mixture. Multi function cap water spilled on the box is provided approximately 200 ml, the dilution to 100 ml MTBE. Face toward a half-mirror member organic, aqueous layer extracted to (3×200 ml) MTBE. And combination with organic, aqueous of the cleaning, a, until it reaches a pH = 6 (3×500 ml) rinsed with tap water, to the section. MTBE night through sodium sulfate anhydride solution during dry, wherein the filtration of the slurry suspension, rotation is capable of vaporizing low vapor pressure, by GC purity 99.3% 93.5 g (99.5% yield) is obtained. NMR analysis where the materials have been shown to containing -1% MTBE. For crude product is without further refinement, the third to eo during next reactor. Data: DB5 column on a GC analysis embodiment, emitter 30, 0.32 mm ID, 0.25 micro m film, in 25 °C/min 300 °C to 75 °C, in minutes, and 2 300 °C, injector temperature: 275 °C, detector temperature: 350 °C

Amino [...] : 3L, 4 neck RBF it is bitter the wool well to, nitrogen capacitor opening, agitators in the mechanical funnel and added mounted. pellets LAH to RBF (50.6 g, 1.33 mol) which contains, during night to 800 ml MTBE mechanical is set in agitating section. Due to this loss in part of solvent thick paste been is obtained. Additional 200 ml of MTBE added, the resulting dispersion methanol-ice bath was marked on the specific to the -6 °C. [...] cyano in 500 ml MTBE to funnel added (93.5 g, 0.635 mol) which contains, reaction temperature is greater than a -5 ° C but less than -2 ° C maintains a tension quantity added dripping at a rate which ensures. The addition [...] cyano 1 time been made. Cooling [...] been removed, then 1.5 time periods and over the mixture the same circuit, is heated to 35 °C, GC analysis indicating including the step of starting materials when further 35 °C 30 minutes stirring section. -15 °C mixture (methanol/ice bath) by a, 150 ml distilled water of a very gradually adding 3 time 30 minutes, was kept at less than 0 °C temperature. Then also in the vacuum and dilution to 250 ml MTBE mixture, second water by the addition of 250 ml portion, whereby a free-flowing white solid as aluminum lithium and adaptation precipitation are a by-product. 10 minutes after stirring, lithium and aluminum and populating are a by-product, MTBE phase d cant section. Additional residue aluminum lithium and after covered 500 ml MTBE, mixing and, tightened and, a MTBE d cant section. MTBE d cant combination with and, after a dried using sodium sulfate, wherein the filtration of the slurry suspension, colorless and the rotation an oil naturally tacky, and 92 g (95.8% yield) is obtained. Exhibit purity 99.7% GC analysis.¹ H NMR analysis where the materials have been shown to containing -1% MTBE. Is NB (CH₂)₃ NH₂ the crude product, are employed in next process without further refinement. Data: DB5 column on a GC analysis embodiment, emitter 30, 0.32 mm ID, 0.25 micro m film, in 15 °C/min 300 °C to 75 °C, injector temperature: 275 °C, detector temperature: 350 °C, holding time: 6.225 ingredient.

NBCH₂CH₂CH₂DMMI: 3L, 4 neck RBF the, it is bitter the wool well , nitrogen opening connected to capacitor [...] trap, mounted agitators in the mechanical funnel and added. 500 ml RBF to dimethyl with stirring, in a and then are input, in toluene male from anhydride (DMMA, 76.7g, 0.60 mol) was are input, in. Dimethyl male from anhydride is toluene dissolved in a admixture during 14 °C was cooled to. Mixture to the surface of the solution 25 °C him up. Added 100 ml to funnel [...] amino fluorotoluene (92 g, 0.60 mol) was turned on, 15 minutes added by a non-contacting method. Additional 100 ml toluene is added in the amino [...] rinsing and drying, the replaced by stopper funnel added. The n bit parallel data inputted heating terminal requests the 53 °C mixture, has been observed on white-based precipitate. Mixture heated attention 20 minutes (to avoid excessive-bubble) and reflux, the reflux time 3. The n bit parallel data inputted observing transparent solution, 10.7 ml water in trap [...] that were of (98.2% theoretical). GC analysis, been reaction is completed (0.95% DMMA product and 98.2%)have been shown to. Reaction mixture cooled and room temperature, transferred to a multi function cap 5 L and, concentrated in the evaporator on rotation. Crude product is 50 °C on evaporator from twisting during a single night bath temperature high vacuum (0.94 torr) under additional dry, naturally tacky, and a yellow bright 122 g is obtained crude product as an oil. GC analysis, 98.8% purity of the crude product of the main is have been shown to randomly choosing 0.68% DMMA as an impurity. 122 g 122 g product of a silica gel of lead ball and separates the lead, heptane (4L), heptane in 2% EtOAc (4L), heptane in 2.5% EtOAc (4L) 3% EtOAc (4L) in heptane and having through 360 g eluting silica gel chromatograph section. The fraction purified concentrate, 100% purity by GC colorless naturally tacky, and an oil (yield 73.2%)was 115 g product as calculates a.¹ H NMR and mass spectrum structure and in accord. Data: DB5 column on a GC analysis embodiment, emitter 30, 0.32 mm ID, 0.25 micro m film, in 15 °C/min 300 °C to 75 °C, in minutes, and 2 300 °C, injector temperature: 275 °C, detector temperature: 325 °C, holding time: 12.634 ingredient.

In the embodiment A23. A tri-cyclo [4.2.1.02, 5] non-7-4-trifluoro -3, 3, 4-n (perfluoro (3-methyl -1, 4-thieno-benzodiazepine formulation)) (DiOxoTCN)

Nor [...] n (77 g, 0.84 mol) and process for producing perfluoro (3-or 5-methyl -3, 6-(pentafluorophenyl)-1-thieno-benzodiazepine formulation [...] -1-n (93 g, 0.21 mol) in a 250 ml glass vial and premix, transfer the 0.5 L stainless steel reactor. Is sealed reactor, 24 with stirring, in a under nitrogen blanket was heated to 190 °C time. Cool to such an ambient temperature in reactor, reaction mixture (169 g) rotating by evaporation concentrated and the crude product 140 g were given the. Crude product is fractionally distilled the GC in purities of at least 87% by area percent exceeds 65 g desired product (yield 57%)were given the.

In the embodiment A24. A tri-cyclo [4.2.1.0^2,5] non-7-(purple base Oro phenyl methyl) 4-trifluoro -3, 3, 4-n) (PFBTCN)

Nor [...] n (1.2 g, 0.013 mol) and [...] 3-(pentafluorophenyl)-1-n (0.99 g, 0.0033 mol) and premix in vial glass, and glass insert is mounted the transfer reactor of stainless steel. Is sealed reactor, the heated to 190 °C time 24. Cool to such an ambient temperature in reactor, reaction mixture for identification product gas chromatography (GC) and gas chromatography-mass analyzer (GC-MS) the analyzed by. Reaction mixture the desired product in the reaction mixture by means of of GC area percent 45.6% induces an electromotive voltage.

In the embodiment A25. Synthetic norbornenemidifiers targeting tetra oxa tetra

8-liters stainless steel reactor vapour-sterilisable 3.75 kg (18.4 mol) allyl TEG was to charge the ether. ' Agitation, reactor air to vent and to impede the flow was 5 psig (padded) adding nitrogen. 200 °C initiates heated, when 200 °C of the central core is surrounded by, 3.75 at this temperature reactor the period of time. During this time a, 0.06 kg (0.3 mol) allyl triethylene glycol ether and 0.21 kg (1.6 mol) DC claw pen hit diene mixture at a constant speed of 1.19 g/min added reactor. Added at the expiry, cool to such an ambient temperature in reactor, the emission. GC by an area as measured, the filling material identified components: 75% allyl triethylene glycol ether, and 23% tetra oxa tetra midifiers targeting norbornene insistence. Distilled filling, 98% (GC area) comprising a generally plane-an analytical result exceeds 0.4 kg tetra oxa tetra midifiers targeting nor [...] has generated.

In the embodiment A26. Synthetic norbornenethe jade company it plays but Neel tree

8-liters stainless steel reactor vapour-sterilisable 3.4 kg (21.2 mol) allyl was to charge the ether diethylene glycol. ' Agitation, air reactor 5 psig was adding nitrogen to vent and to impede the flow. 200 °C initiates heated, when 200 °C of the central core is surrounded by, at this temperature reactor 4.25 the period of time. During this time a, 0.06 kg (0.4 mol) allyl diethylene glycol ether and 0.24 kg (1.8 mol) DC claw pen hit diene mixture at a constant speed of 1.17 g/min added reactor. Added at the expiry, cool to such an ambient temperature in reactor, the emission. GC by an area as measured, the filling material identified components: 72% allyl diethylene glycol ether, and 26% tree the jade company it plays but Neel norbornene insistence. Distilled filling, 99% (GC area) comprising a generally plane-an analytical result exceeds 0.5 kg tree the jade company it plays but Neel nor [...] has generated.

In the embodiment A27. Synthesis of norbornene(NBTODD) midifiers targeting tetra oxa tetra

8-liters stainless steel reactor vapour-sterilisable 3.75 kg (18.4 mol) allyl TEG was to charge the ether. ' Agitation, reactor air to vent and to impede the flow was 5 psig (padded) adding nitrogen. 200 °C initiates heated, when 200 °C of the central core is surrounded by, 3.75 at this temperature reactor the period of time. During this time a, 0.06 kg (0.3 mol) allyl triethylene glycol ether and 0.21 kg (1.6 mol) DC claw pen hit diene mixture at a constant speed of 1.19 g/min added reactor. Added at the expiry, cool to such an ambient temperature in reactor, the emission. GC by an area as measured, the filling material identified components: 75% allyl triethylene glycol ether, and 23% tetra oxa tetra midifiers targeting norbornene insistence. Distilled filling, 98% (GC area) comprising a generally plane-an analytical result exceeds 0.4 kg tetra oxa tetra midifiers targeting nor [...] has generated.

B: for polymer synthesis

In each tickets provided hereinafter, specifically is not referred alternatively, a catalyst, and the amount of each monomer reported as gram (g) the pair of input nodes wherein ; (%) percent yield is reported as and, molecular weight (M_w), ratio M_w/M_n as PDI (polydispersity index) and¹ H NMR composition mole of the polymer determined by (A/B/C or A/B) is the report.

For each B1-B5 embodiment examples, specific indicative of the amount of monomer, stirring rod included in the to the vial the toluene and methyl ethyl ketone mixture of (12.8 ml and 72.9 ml each) was dissolved in the nonaqueous solvent. B6 to, monomer and catalyst both was dissolved in toluene-trifluoro ααα anhydride (98.4 ml and 6.3 ml each). To the vial nitrogen sparging remaining oxygen is removed by inserting the non was and sealing. Table 1 in catalyst, (η6-toluic) Ni (C₆ F₅)₂ (hereinafter, NiAr^f) amount of nitrogen purged glove box toluene (5 ml) was dissolved in the nonaqueous solvent.

In the embodiment B1. MeOAcNB and DMMIMeNB copolymerization

The same circuit, is heated to 45 °C monomer solution, said catalyst mixture described he infused a to the vial into the heated. 17 with stirring, in a solution and temperature maintaining time, then the cooling room temperature. Residual removing the catalyst and, excess ethanol the reaction mixture, adaptation using an isotropic polymer by oneself out to get through the sub. By filtration after isolated as far as polymers by, a 60 °C same was very dry.

In the embodiment B2. BuNB and DMMIMeNB copolymerization

The same circuit, is heated to 45 °C monomer solution, said catalyst mixture described he infused a to the vial into the heated. 1.5 with stirring, in a solution and temperature maintaining time, then the cooling room temperature. Residual removing the catalyst and, excess 75/25 acetone/methanol mixture to pourable adaptation using an isotropic polymer by sub. By filtration after isolated as far as polymers by, a 65 °C same was very dry.

In the embodiment B3. DecNB and DMMIMeNB copolymerization

The same circuit, is heated to 45 °C monomer solution, said catalyst mixture described he infused a to the vial into the heated. 1.5 with stirring, in a solution and temperature maintaining time, then the cooling room temperature. Residual removing the catalyst and, excess 75/25 acetone/methanol mixture to pourable adaptation using an isotropic polymer by sub. By filtration after isolated as far as polymers by, a 65 °C same was very dry.

In the embodiment B4. DMMIMeNB are either a homopolymer of

The same circuit, is heated to 45 °C monomer solution, said catalyst mixture described he infused a to the vial into the heated. 1.5 with stirring, in a solution and temperature maintaining time, then the cooling room temperature. Residual removing the catalyst and, excess 75/25 acetone/methanol mixture to pourable adaptation using an isotropic polymer by sub. By filtration after isolated as far as polymers by, a 65 °C same was very dry.

In the embodiment B5. FPCNB are either a homopolymer of

The same circuit, is heated to 45 °C monomer solution, said catalyst mixture described he infused a to the vial into the heated. 1.5 with stirring, in a solution and temperature maintaining time, then the cooling room temperature. Residual removing the catalyst and, excess 75/25 acetone/methanol mixture to pourable adaptation using an isotropic polymer by sub. By filtration after isolated as far as polymers by, a 65 °C same was very dry.

In the embodiment B6. C8AcNB are either a homopolymer of

The same circuit, is heated to 45 °C monomer solution, said catalyst mixture described he infused a to the vial into the heated. 1.5 with stirring, in a solution and temperature maintaining time, then the cooling room temperature. Residual removing the catalyst and, excess 75/25 acetone/methanol mixture to pourable adaptation using an isotropic polymer by sub. By filtration after isolated as far as polymers by, a 65 °C same was very dry.

B7-B19 examples for each embodiment, in table 2 hereinafter NBC₄ F₉ (in in the embodiment B13 NBCH₂ C₆ F₅) amount of, stirring rod included in the to the vial the toluene trifluoro anhydride (B8 and B9 in trifluoro toluene and toluene) was dissolved in the nonaqueous solvent amount indicative of the of. To the vial nitrogen sparging remaining oxygen is removed by inserting the non was and sealing. B11, B12 and B17-B19 to embodiment examples, DANFABA (dimethyl [...] tetrakis (pentafluorophenyl) borate) and (acetonitrile) bis ([...] -butyl t) palladium (acetate) tetrakis (purple base Oro phenyl) borate (Pd 1394) indicative of the amount of, and disperse non-miscible bi but after caprolactam added to the vial prior to sealing. B13-16 and B7-B10 respect to embodiment examples, catalyst NiAr^f of amount indicative of the nitrogen purged glove box toluene dissolved to the amount indicative of the of, he infused a to the vial sealed. 17-19 and 12 respect to embodiment examples, catalyst instead he infused a indicative of the amount of formic acid. Table 2 the in addition each polymer yield-(%) as well as available M_w and provides PDI.

In the embodiment B7. NBC₄ F₉ are either a homopolymer of

Then stirring and at ambient temperature monomer solution, he infused a to the vial mixture catalyst. While agitating the mixture and temperature maintaining time 2, then added to the vial a distilled water of 2 ml. Residual catalyst removal, and methanol after precipitation of polymers into, isolates polymer, 70-80 °C a was very dry.

In the embodiment B8. NBC₄ F₉ are either a homopolymer of

Then stirring and 60 °C monomer solution, he infused a to the vial mixture catalyst. While agitating the mixture and temperature maintaining time 1.5, a distilled water of 2 ml then added to the vial. Residual catalyst removal, and methanol after precipitation of polymers into, isolates polymer, 70-80 °C a was very dry.

In the embodiment B9. NBC₄ F₉ are either a homopolymer of

Then stirring and 60 °C monomer solution, he infused a to the vial mixture catalyst. While agitating the mixture and temperature maintaining time 1.5, a distilled water of 2 ml then added to the vial. Residual catalyst removal, and methanol after precipitation of polymers into, isolates polymer, 70-80 °C a was very dry.

In the embodiment B10. NBC₄ F₉ are either a homopolymer of

Then stirring and 60 °C monomer solution, he infused a to the vial mixture catalyst. While agitating the mixture and temperature maintaining time 1.5, a distilled water of 2 ml then added to the vial. Residual catalyst removal, and methanol after precipitation of polymers into, isolates polymer, 70-80 °C a was very dry.

In the embodiment B11. NBC₄ F₉ are either a homopolymer of

Then stirring time adaptation in 90 °C monomer solution 16. Residual catalyst removal, and 90/10 methanol/water after precipitation of polymers into, isolates polymer, 70-80 °C a was very dry.

In the embodiment B12. NBC₄ F₉ are either a homopolymer of

Then stirring time adaptation in 90 °C monomer solution 16. Residual catalyst removal, and 90/10 methanol/water after precipitation of polymers into, isolates polymer, 70-80 °C a was very dry.

In the embodiment B13. NBCH₂ C₆ F₅ are either a homopolymer of

Then stirring and at ambient temperature monomer solution, he infused a to the vial mixture catalyst. Agitating the mixture while temperature maintaining and 5 minutes, then added to the vial a distilled water of 2 ml. Residual catalyst removal, and methanol after precipitation of polymers into, isolates polymer, 70-80 °C a was very dry.

In the embodiment B14-16. NBC₄ F₉ are either a homopolymer of

Then stirring and in 65 °C for solutions monomer, catalyst he infused a to the vial mixtures. Mixtures 2, which has the temperature time. Residual catalyst removal, and methanol into polymers after of non-magnetic material, isolates polymers, 70-80 °C a was very dry.

In the embodiment B17-19. NBC₄ F₉ are either a homopolymer of

90 °C for solutions monomer then stirring and, he infused a to the vial mixtures catalyst. Mixtures, which has the temperature time 16. Residual catalyst removal, and 90/10 methanol/water into polymers after of non-magnetic material, isolates polymers, 70-80 °C a was very dry.

For each B20-B41 embodiment examples, amount of monomer in table 3 hereinafter, indicative of the dissolved hereinafter to the amount of solvent, stirring the charging to the vial the rod (B31 organic reactions to been is used). Sparging the nitrogen into the reactor/vial remaining oxygen is removed by inserting the non was and sealing. Catalyst NiAr^f of amount indicative of the nitrogen purged glove box toluene of dissolved to the amount indicative of the, sealed he infused a vial/reactor. Table 3 the in addition each composite obtained for the polymer as well as the yields at M_w and provides PDI.

In the embodiment B20-21. NBC₄ F₉ DMMIMeNB and polymerization of

Monomer solutions (B20 to 60.0 g toluene and B21 to 75.0 g) stirring and at ambient temperature, he infused a to vial to catalyst solutions. B20 mixture while agitating and temperature maintaining time 3, a distilled water of 2 ml then added to the vial. B21 reaction mixture, which has the temperature time 16. Residual catalyst removal, and methanol into polymers after of non-magnetic material, isolates polymers, 70-80 °C a was very dry.

In the embodiment B22. NBC₄ F₉ DMMIMeNB and polymerization of

Monomer solution (toluene (56.3 g) and trifluoroalkyl toluene (18.8g)) which agitates the at ambient temperature, he infused a to the vial catalyst solutions are. While agitating the mixture, which has the temperature time 16. Residual catalyst removal, and methanol after precipitation of polymers into, isolates polymer, 70-80 °C a was very dry.

In the embodiment B23. NBCH₂ C₆ F₅ DMMIMeNB and polymerization of

Monomer solution (toluene 60.0 g) stirring and at ambient temperature, he infused a to the vial catalyst solutions are. While agitating the mixture and temperature maintaining time 2, then added to the vial a distilled water of 2 ml. Residual catalyst removal, and methanol after precipitation of polymers into, isolates polymer, 70-80 °C a was very dry.

In the embodiment B24. NBC₄ F₉ PPVENBB and polymerization of

Monomer solution (trifluoro toluene (40.0 g), toluene (32.0 g) and methyl ethyl ketone (8.0g)) for 45 °C which agitates the in, he infused a to the vial catalyst solutions are. Mixture 16, which has the temperature time. Residual catalyst removal, and methanol after precipitation of polymers into, isolates polymer, 70-80 °C a was very dry.

In the embodiment B25. NBC₄ F₉ MeCoumNB and polymerization of

Monomer solution (trifluoro toluene (75 g)) for 55 °C which agitates the in, he infused a to the vial catalyst solutions are. Mixture 16, which has the temperature time. Residual catalyst removal, and methanol after precipitation of polymers into, isolates polymer, 70-80 °C a was very dry.

In the embodiment B26-B29. MeOCinnNB and DecNB or BuNB polymerization of

Monomer solutions (toluene (103.8 g) and methyl ethyl ketone (18.3 g)) which agitates the at ambient temperature, he infused a to vial to catalyst solutions. Mixtures with stirring, in a, which has the temperature time 16. Residual catalyst removal, and methanol into polymers after of non-magnetic material, isolates polymers, 70-80 °C a was very dry.

In the embodiment B30. Polymerization of PhIndNB DecNB and

Monomer solution (toluene (68.0 g) and methyl ethyl ketone (12.0 g)) for 50 °C which agitates the in, he infused a to the vial catalyst solutions are. Mixture 16, which has the temperature time. Residual catalyst removal, and methanol after precipitation of polymers into, isolates polymer, 70-8 °C a was very dry.

In the embodiment B31. Polymerization of DMMIMeNB BuNB and

Monomer solution (toluene (488 g) and methyl ethyl ketone (90.0 g)) for 45 °C which agitates the in, he infused a to the vial catalyst solutions are. 3 mixture, which has the temperature time. Residual catalyst, after removal, product, each 50/50 ethanol/i-butanol mixture with the objects in the zero two placement 2, 2 2-placements of [...] solvent was exchanged.

In the embodiment B32-33. Polymerization of OctNB or HexNB DMMIMeNB and

Monomer solutions ((98.0 g) and methyl ethyl ketone (18.0 g)) for 45 °C which agitates the in, he infused a to vial to catalyst solutions. Mixtures, which has the temperature time 3. Residual catalyst removal, and polymers into methanol/water 95/5 after of non-magnetic material, isolates polymers, 60-70 °C a was very dry.

In the embodiment B34-37. DMMIMeNB, polymerization of AkSiNB DecNB and

Monomer solutions (toluene (76.5 g) and methyl ethyl ketone (13.5 g)) which agitates the at ambient temperature, he infused a to vial to catalyst solutions. Mixtures, which has the temperature time 45. Residual catalyst removal, and methanol into polymers after of non-magnetic material, isolates polymers, 65-70 °C a was very dry.

In the embodiment B38-39. DMMIMeNB, DecNB, polymerization of NBTODD and

Monomer solutions (toluene (63.8 g) and methyl ethyl ketone (11.3 g)) for 45 °C which agitates the in, he infused a to vial to catalyst solutions. Mixtures, during and time 3.5 to B38 B39 to 16, which has the temperature time. Residual catalyst removal, and methanol into polymers after of non-magnetic material, isolates polymers, 70 °C a was very dry.

In the embodiment B40-41. DMMIMeNB, NBCH₂ C₆ F₅ polymerization of MeOAcNB and

Monomer solutions (toluene (195 g)) for 45 °C which agitates the in, he infused a to vial to catalyst solutions. 4.75 mixtures, which has the temperature time. Residual catalyst removal, and polymers into methanol/water 95/5 after of non-magnetic material, isolates polymers, 70 °C a was very dry.

For each B42-B47 embodiment examples, amount of monomer in table 4 hereinafter, indicative of the dissolved hereinafter to the amount of solvent, stirring the charging to the vial the rod. Sparging the nitrogen into the reactor/vial remaining oxygen is removed by inserting the non was and sealing. Catalyst NiAr^f of amount indicative of the nitrogen purged glove box toluene of dissolved to the amount indicative of the, sealed he infused a vial/reactor. Table 4 the in addition each composite obtained for the polymer as well as the yields at M_w and provides PDI.

In the embodiment B42. DMMIMeNB, DecNB, polymerization of NBXOH and

Table 4 amount of monomer in hereinafter, stirring rod included in the to the vial the toluene and methyl ethyl ketone mixture of (12.75 ml and 65.02 ml each) was dissolved in the nonaqueous solvent. To the vial nitrogen sparging remaining oxygen is removed by inserting the non was and sealing. Table 4 catalyst in NiAr^f amount of nitrogen purged glove box toluene (2.59 ml) was dissolved in the nonaqueous solvent. Monomer monomer solution then the same circuit, is heated to 45 °C solution, catalyst solutions are heated to the vial he infused a. While agitating the mixture and temperature maintaining time 5, same then the cooling room temperature. Residual catalyst removal, and methanol after precipitation of polymers into, isolates polymer, a 60 °C was very dry.

In the embodiment B43. DMMIMeNB, DecNB, polymerization of NBXOH and

Table 4 amount of monomer in hereinafter, stirring rod included in the to the vial the toluene and methyl ethyl ketone mixture of (12.03 ml and 59.76 ml each) was dissolved in the nonaqueous solvent. To the vial nitrogen sparging remaining oxygen is removed by inserting the non was and sealing. Table 4 catalyst in NiAr^f amount of nitrogen purged glove box toluene (4.07 ml) was dissolved in the nonaqueous solvent. The same circuit, is heated to 45 °C monomer solution then, catalyst solutions are heated to the vial he infused a. While agitating the mixture and temperature maintaining time 16, same then the cooling room temperature. Residual catalyst removal, and methanol after precipitation of polymers into, isolates polymer, a 60 °C was very dry.

In the embodiment B44. Polymerization of DMMIMeNB PPVENB and

Table 4 amount of monomer in hereinafter, stirring rod included in the to the vial the toluene trifluoro anhydride (49.13 ml) was dissolved in the nonaqueous solvent. To the vial nitrogen sparging remaining oxygen is removed by inserting the non was and sealing. Table 4 catalyst in NiAr^f glove box purged nitrogen amount of toluene trifluoro anhydride (7.50 ml) was dissolved in the nonaqueous solvent. Monomer solution to hold the room temperature, he infused a to the vial catalyst solutions are. Mixture adaptation stirring time 1. Residual catalyst removal, and methanol after precipitation of polymers into, isolates polymer, a 60 °C was very dry.

In the embodiment B45. Polymerization of DMMIMeNB PPVENB and

Table 4 amount of monomer in hereinafter, stirring rod included in the to the vial the toluene trifluoro anhydride (56.15 ml) was dissolved in the nonaqueous solvent. To the vial nitrogen sparging remaining oxygen is removed by inserting the non was and sealing. Table 4 catalyst in NiAr^f glove box purged nitrogen amount of toluene trifluoro anhydride (7.50 ml) was dissolved in the nonaqueous solvent. Monomer solution to hold the room temperature, he infused a to the vial catalyst solutions are. Mixture adaptation stirring time 1. Residual catalyst removal, and methanol after precipitation of polymers into, isolates polymer, a 60 °C was very dry.

In the embodiment B46. Polymerization of MeOCinnNB BuNB and

Table 4 amount of monomer in hereinafter, stirring rod included in the to the vial the toluene (140.7 ml) and ethyl acetate (25.3 ml) was dissolved in the nonaqueous solvent mixture of. To the vial nitrogen sparging remaining oxygen is removed by inserting the non was and sealing. Table 4 catalyst in NiAr^f amount of nitrogen purged glove box toluene (9.69 ml) was dissolved in the nonaqueous solvent. The heated to 45 °C monomer solution. Furthermore, pouring the of a reaction vessel in a catalyst solutions, agitating the mixture adaptation (45 °C, 3 time). Residual catalyst removal, and acetone and methanol (75:25) after precipitation of polymers into mixture of, isolates polymer, a 60 °C was very dry.

In the embodiment B47. EtCoumNB are either a homopolymer of

In nitrogen purged glove box, in hereinafter table 4 amount of monomer, included to the vial the rod stirring of anhydrous dichloroethane (21.9 ml) was dissolved in the nonaqueous solvent. Table 4 catalyst in NiAr^f amount of nitrogen purged glove box toluene (1.61 ml) was dissolved in the nonaqueous solvent. The heated to 45 °C monomer solution. Furthermore, pouring the of a reaction vessel in a catalyst solutions, agitating the mixture adaptation (45 °C, 3 time).

For each B48-B55 embodiment examples, amount of monomer in table 5 hereinafter, indicative of the dissolved hereinafter to the amount of solvent, stirring the charging to the vial the rod. Sparging the nitrogen into the reactor/vial remaining oxygen is removed by inserting the non was and sealing. Catalyst NiAr^f, (η⁶-toluene) Ni (C₆ F₅)₂ of amount indicative of the nitrogen purged glove box toluene of dissolved to the amount indicative of the, sealed he infused a vial/reactor. In addition the 5 table each composite obtained for the polymer as well as the yields at M_w and provides PDI.

In the embodiment B48-B53. DecNB or BuNB DMMIMeNB one polymerization of

Table 5 amount of monomer in hereinafter, stirring rod vial mounting comprised in toluene (170 g) and methyl ethyl ketone (31 g) was dissolved in the nonaqueous solvent. Vial remaining sparging nitrogen to oxygen is removed by inserting the non was and sealing. Table 5 catalyst in NiAr^f amount of nitrogen purged glove box toluene (7-9 g) was dissolved in the nonaqueous solvent. The same circuit, is heated to 45 °C for solutions monomer then, he infused a to vial to catalyst solutions. 1-2 mixtures, which has the temperature time. Residual catalyst removal, and methanol into polymers after of non-magnetic material, isolates polymers, 70 °C a was very dry.

In the embodiment B54-B55. Polymerization of DCPD BuNB and

Table 5 amount of monomer in hereinafter, stirring rod vial mounting comprised in toluene (30 g) was dissolved in the nonaqueous solvent. Vial remaining sparging nitrogen to oxygen is removed by inserting the non was and sealing. Glove box in, [Li (OEt₂)_2.5] [B (C₆ F₅)₄] (LiFABA) (Boulder Scientific Company, Mead, CO) (0.009 g) added to a vial. -1 (1.85g) hexene then added to a vial. The vial are heated to 80 °C. Vial in toluene to 2 g in table 5 amount of (allyl) palladium (tree [...]) added a (trifluoro acetate). Mixtures, which has the temperature time 17. After cooling reaction mixture, them THF (150 ml) to the dilution. A using methanol isolates polymer, a 70 °C was very dry.

For each B56-B63 embodiment examples, hereinafter table 6 in the support member, and filling the to the vial reacting an amount of monomer, 29 g of the toluene and 166 g of methyl ethyl ketone was dissolved in the nonaqueous solvent. Vial then remaining sparging nitrogen to oxygen is removed by inserting the non was and sealing. Each catalyst in 6 the table for experiments NiAr^f amount indicative of the of is representative of an amount of a toluene was dissolved in the nonaqueous solvent. 6 table hereinafter for the synthesis each polymer obtained as well as the yields at M_w, PDI provides ratio repeating unit.

In the embodiment B56-B57. Polymerization of MGENB DecNB and

Then stirring and in 40 °C of monomer solutions, catalyst solutions to vial to he infused a. Mixtures, which has the temperature time 3. Residual catalyst removal, and methanol after precipitation of polymers into, isolates polymer, 80 °C a was very dry.

In the embodiment B58-B59. Polymerization of MGENB BuNB and

Then stirring and in 40 °C of monomer solutions, catalyst solutions to vial to he infused a. Mixtures, which has the temperature time 3. Residual catalyst removal, and methanol after precipitation of polymers into, isolates polymer, 80 °C a was very dry. 6 table hereinafter for the synthesis each polymer obtained as well as the yields at M_w and M_w/M_n provides.

In the embodiment B60-B61. Polymerization of EONB DecNB and

Then stirring and in 40 °C of monomer solutions, catalyst solutions to vial to he infused a. Mixtures, which has the temperature time 3. Residual catalyst removal, and methanol after precipitation of polymers into, isolates polymer, 80 °C a was very dry.

In the embodiment B62-B63. Polymerization of MGENB BuNB and

Then stirring and in 40 °C of monomer solutions, catalyst solutions to vial to he infused a. Mixtures, which has the temperature time 3. Residual catalyst removal, and methanol after precipitation of polymers into, isolates polymer, 80 °C a was very dry.

Experiment for each B64-B78 are, hereinafter table 7 amount of monomer in, stirring rod was mounted a reaction to the vial filling. Monomer (are) a respective experiments solvent represents an amount of particles having a diameter of, nitrogen sparging remaining oxygen is removed by inserting the non was and sealing. Table 7 catalyst in NiAr^f amount of, nitrogen purged glove box toluene (or other indicative of the solvent) was dissolved in the nonaqueous solvent amount of. 7 table hereinafter for the synthesis each polymer obtained as well as the yields at M_w and provides PDI.

In the embodiment B64-B67. FHCNB, FPCNB, are either a homopolymer of PPVENB FOCHNB and

Each of monomer, was dissolved in toluene trifluoro amount indicative of the. Then at room temperature for solutions which agitates the, trifluoro toluene catalyst solutions to vial to he infused a. During night at room temperature, which has the mixtures. Residual catalyst removal, and methanol into polymers after of non-magnetic material, isolates polymers, 80 °C a was very dry.

In the embodiment B68-B69. Polymerization of MeCoumNB DecNB and

For each experiments, monomer are dissolved with a toluene/ethyl acetate to, during catalyst was dissolved in toluene. Which agitates the solutions monomer then, the same circuit, is heated to 45 °C, he infused a to vial to catalyst solutions. 45 °C mixtures during night stirring section. Residual catalyst removal, and acetone into polymers after of non-magnetic material, isolates polymers, 90 °C a was very dry.

In the embodiment B70-B73. EtCoumNB and a DecNB or BuNB polymerization of

For each experiments, monomer are with a toluene/methylethylketone and fluorotoluene catalyst was dissolved in the nonaqueous solvent. Then monomer solutions at room temperature for which agitates the, he infused a to vial to catalyst solutions. Stirring room temperature during night adaptation mixtures. Residual catalyst removal, and acetone into polymers after of non-magnetic material, isolates polymers, 50 °C a was very dry.

In the embodiment B74-B75. Polymerization of EtCoumNB DecNB and

For each experiments, monomer are with a toluene/methylethylketone and fluorotoluene catalyst was dissolved in the nonaqueous solvent. Which agitates the solutions monomer then, the same circuit, is heated to 45 °C, he infused a to vial to catalyst solutions. 45 °C mixtures during night stirring section. Residual catalyst removal, and acetone into polymers after of non-magnetic material, isolates polymers, 90 °C a was very dry.

In the embodiment B76. Polymerization of EtCoumNB BuNB and

For each experiments, ethyl acetate and toluene/are monomer catalyst fluorotoluene was dissolved in the nonaqueous solvent. Which agitates the solutions monomer then, the same circuit, is heated to 45 °C, he infused a to vial to catalyst solutions. 45 °C mixtures during night stirring section. Residual catalyst removal, and acetone into polymers after of non-magnetic material, isolates polymers, 90 °C a was very dry.

In the embodiment B77. Polymerization of MeCoumNB PPVENB and

For each experiments, monomer are with a toluene/trifluoro toluene and trifluoroalkyl fluorotoluene catalyst was dissolved in the nonaqueous solvent. Which agitates the solutions monomer then, the same circuit, is heated to 45 °C, he infused a to vial to catalyst solutions. Mixtures are was 45 °C during night. Residual catalyst removal, and heptane into polymers after of non-magnetic material, isolates polymers, 70 °C a was very dry.

In the embodiment B78. Polymerization of MIENB DecNB and

Table 7 amount of monomer in hereinafter, stirring rod are included the pressurized reactors a toluene (51 g) and ethanol (0.51 g) was dissolved in the nonaqueous solvent. The nitrogen into the reactor sparging remaining oxygen is removed by inserting the non was and sealing. In glove box, DANFABA (0.048 g) added to a reactor. Is sealed reactor, and so as to press the 10 psig using ethylene, the heated to 80 °C. Reactor 7 table fluorotoluene in 3 g of amount of (allyl) palladium (tree [...]) added a (trifluoro acetate). Mixtures, which has the temperature time 17. Cooling and residual catalyst, after removal, acetone using isolates a polymer, a 70 °C was very dry.

Experiment for each B79-B86 are, hereinafter table 8 amount of monomer in, stirring rod was mounted a reaction to the vial filling. Monomer (are) a respective experiments solvent represents an amount of particles having a diameter of, nitrogen sparging remaining oxygen is removed by inserting the non was and sealing. Table 8 catalyst in NiAr^f amount of, nitrogen purged glove box toluene (or other indicative of the solvent) was dissolved in the nonaqueous solvent amount of. 8 table hereinafter for the synthesis each polymer obtained as well as the yields at M_w, PDI and discovery of monomers provide ratios of the repeat units.

In the embodiment B79-B81. Polymerization of DMMIMeNB PENB and

Table 8 amount of monomer in hereinafter, stirring rod included in the to the vial the toluene and methyl ethyl ketone mixture of (83.4 ml and 15.4 ml each) was dissolved in the nonaqueous solvent. To the vial nitrogen sparging remaining oxygen is removed by inserting the non was and sealing. Table 9 catalyst in NiAr^f amount of nitrogen purged glove box toluene (4.5 ml) was dissolved in the nonaqueous solvent. The same circuit, is heated to 45 °C monomer solution then, catalyst solutions are heated to the vial he infused a. While agitating the mixture and temperature maintaining time 1.5, then the cooling room temperature. Residual catalyst removal, and 75/25 acetone/methanol into after precipitation of polymers, isolates polymer, a 65 °C was very dry.

In the embodiment B82-B83. Polymerization of DMMIMeNB MeNB and

Table 8 amount of monomer in hereinafter, stirring rod included in the to the vial the toluene and methyl ethyl ketone mixture of (15.2 ml and 81.3 ml each) was dissolved in the nonaqueous solvent. To the vial nitrogen sparging remaining oxygen is removed by inserting the non was and sealing. Table 8 catalyst in NiAr^f amount of nitrogen purged glove box toluene (5.6 ml) was dissolved in the nonaqueous solvent. The same circuit, is heated to 45 °C monomer solution then, catalyst solutions are heated to the vial he infused a. While agitating the mixture and temperature maintaining time 1.5, then the cooling room temperature. Residual catalyst removal, and 75/25 acetone/methanol into after precipitation of polymers, isolates polymer, a 65 °C was very dry.

In the embodiment B84. Polymerization of DMMIMeNB NB and

Table 8 amount of monomer in hereinafter, stirring rod included in the to the vial the toluene and methyl ethyl ketone mixture of (14.8 ml and 79.4 ml each) was dissolved in the nonaqueous solvent. To the vial nitrogen sparging remaining oxygen is removed by inserting the non was and sealing. Table 8 catalyst in NiAr^f amount of nitrogen purged glove box toluene (4.9 ml) was dissolved in the nonaqueous solvent. The same circuit, is heated to 45 °C monomer solution then, catalyst solutions are heated to the vial he infused a. While agitating the mixture and temperature maintaining time 1.5, then the cooling room temperature. Residual catalyst removal, and 75/25 acetone/methanol into after precipitation of polymers, isolates polymer, a 65 °C was very dry.

In the embodiment B85-B86. Polymerization of DMMIMeNB TD and

Table 8 amount of monomer in hereinafter, stirring rod included in the to the vial the toluene and methyl ethyl ketone mixture of (17.5 ml and 88.7 ml each) was dissolved in the nonaqueous solvent. To the vial nitrogen sparging remaining oxygen is removed by inserting the non was and sealing. Table 8 catalyst in NiAr^f amount of nitrogen purged glove box toluene (3.8 ml) was dissolved in the nonaqueous solvent. The same circuit, is heated to 45 °C monomer solution then, catalyst solutions are heated to the vial he infused a. While agitating the mixture and temperature maintaining time 1.5, then the cooling room temperature. Residual catalyst removal, and 75/25 acetone/methanol into after precipitation of polymers, isolates polymer, a 65 °C was very dry.

In the embodiment B87. DHNMINB polymerization of

DHNMINB (5.50 g, 0.0180 mol), toluene (34.1 ml) and ethyl acetate (11.2 ml) a, magnetic stirring rod 100 ml glass having added to the vial. Bi (rubber septum) a septum rubber caprolactam was and a sealing surface of the seal. Mixture nitrogen sparging was 30 minutes. The heated to 45 °C while agitating the mixture. Into the solution, dissolved in 1 ml of the toluene NiAr^f (0.087 g, 0.18 mmol) a added. 3 mixture was stirring temperature time. Packages are manufactured at having the viscosity which it gives solution, using an isotropic polymer of solids from solutions, the adaptation. Mixture cooled and, was filter a solid from a reaction mixture. GPC: M_w = 77600 ; M_n = 39200 ; M_w/M_n = 1.98.

In the embodiment B88 . 50/50 NBCH₂ GlyOAc DMMIMeNB and polymerization of

DMMINB (26.6 g, 0.115 mol), NBCH2GlyOAc (24.18 g, 0.115 mol), toluene (190 ml) and methyl ethyl ketone (38 ml) a, magnetic stirring a 500 ml added to bottle cap crimp glass. Was bottle having rubber a septum and a sealing surface of the seal. Mixture nitrogen sparging was 30 minutes. The heated to 45 °C while agitating the mixture. Into the solution, dissolved in 8.7 ml of the toluene NiAr^f (0.744 g, 0.00153 mol) a added. While agitating the mixture and temperature maintaining time 1.5, then the cooling room temperature. Residual catalyst removal, and methanol after precipitation of polymers into, isolates polymer, a 60 °C was very dry. GPC: M_w = 47200, M_n = 27900, M_w/M_n = 1.69. Composition (¹ H NMR) = 46/54 DMMINB/NBCH₂ GlyOAc. Yield = 76.8%.

In the embodiment B89 . 25/75 NBCH₂ GlyOAc DMMIMeNB and polymerization of

DMMINB (39.9 g, 0.173 mol), NBCH₂ GlyOAc (12.1 g, 0.0.0575 mol), toluene (195 ml) and methyl ethyl ketone (39 ml) a, magnetic stirring a 500 ml added to bottle cap crimp glass. Was bottle having rubber a septum and a sealing surface of the seal. Mixture nitrogen sparging was 30 minutes. The heated to 45 °C while agitating the mixture. Into the solution, dissolved in 8.7 ml of the toluene NiAr^f (0.744 g, 0.00153 mol) a added. While agitating the mixture and temperature maintaining time 1.5, then the cooling room temperature. Residual catalyst removal, and methanol after precipitation of polymers into, isolates polymer, a 6 °C was very dry. GPC: M_w = 53900, Mn = 30900, M_w/M_n = 1.74. Composition (¹ H NMR) = 69/31 DMMINB/NBCH₂ GlyOAc. Yield = 83%.

In the embodiment B90-B91. MCHMNB polymerization of

Table 9 amount of monomer in hereinafter, stirring a to the vial included in the dichloro methane (66.5 ml) was dissolved in the nonaqueous solvent. To the vial nitrogen sparging remaining oxygen is removed by inserting the non was and sealing. Table 9 catalyst in NiAr^f amount of nitrogen purged glove box toluene (1.8 ml) was dissolved in the nonaqueous solvent. The same circuit, is heated to 45 °C monomer solution then, catalyst solutions are heated to the vial he infused a. While agitating the mixture and temperature maintaining time 16, then the cooling room temperature. Hereinafter for the synthesis each 9 table DMAc HPLC in conversion of the polymer determined by PDI and Mw parties as well as provides.

In the embodiment B92-B93. A tri-cyclo [4.2.1.02, 5] non-7-4-trifluoro -3, 3, 4-n (perfluoro (3-methyl -1, 4-thieno-benzodiazepine formulation)) (DiOxoTCN) polymerization of

Amount of monomer in 10 table hereinafter, stirring rod included in the to the vial the toluene trifluoro anhydride (20.0 g) was dissolved in the nonaqueous solvent. To the vial nitrogen sparging remaining oxygen is removed by inserting the non was and sealing. Table 10 catalyst in NiAr^f glove box purged nitrogen amount of toluene trifluoro anhydride (B92 to 1.0 g to 2.0 g and B93) was dissolved in the nonaqueous solvent. Stirring and in 45 °C monomer solution then, catalyst solutions are heated to the vial he infused a. While agitating the mixture, which has the temperature time 18. Residual catalyst removal, and methanol after precipitation of polymers into, isolates polymer, 70-80 °C a was very dry. Each 10 table hereinafter obtained for regioselective synthesis provides yield of the polymer.

In the embodiment B94. DMMINB, NBCH₂ C₆ F₅ polymerization of MeOAcNB and

NBCH₂ C₆ F₅ (16.7 g), DMMIMeNB (11.3 g) MeOAc (2.03 g) and a, of the proper size reaction vial toluene (146.5 g) was dissolved in the nonaqueous solvent. Fluorotoluene NiAr^f solution of, are added to the monomer solution, 25 °C stirring section. 3 mixture, which has the temperature time. Residual catalyst removal, and methanol after precipitation of polymers into, isolates polymer, a 60 °C was very dry. The 11 table hereinafter for regioselective synthesis as well as yield of the polymer obtained M_w, M_w/M_n and provides polymer composition.

In the embodiment B95-B96. DMMIMeNBand NBTODDcopolymerization

B95 and B96 for each embodiment examples, table 12 amount of monomer specific in, stirring rod included in the to the vial the toluene and methyl ethyl ketone mixture of (13.5 ml and 73.6 ml each) was dissolved in the nonaqueous solvent. To the vial nitrogen sparging remaining oxygen is removed by inserting the non was and sealing. Table 12 in catalyst NiAr^f amount of nitrogen purged glove box toluene (3.8 ml) was dissolved in the nonaqueous solvent. Catalyst solutions are, are added to the monomer solution, the resulting monomer and catalyst mixtures with stirring, in a temperature maintaining time and 5, then the cooling room temperature. Residual removing the catalyst and, excess n-heptane reaction mixture adaptation using an isotropic polymer by oneself out to get through the sub. By filtration after isolated as far as polymers by, a 55 °C was very dry. 12 table hereinafter each for regioselective synthesis as well as yield of the polymer obtained M_w, M_w/M_n and discovery of monomers provide ratios of the repeat units.

In the embodiment B97. DMMIMeNBand NBTONcopolymerization

12.72g (0.055 mol) of DMMIMeNBand and 12.45g (0.055 mol) of for NBTON, stirring rod included in the to the vial the toluene and methyl ethyl ketone mixture of (94.4 ml and 18.7 ml each) was dissolved in the nonaqueous solvent. Bi is sealed caprolactam, nitrogen sparging remaining oxygen is removed by inserting the non, the heated to 45 °C. 0.356 g catalyst NiAr^f nitrogen purged glove box toluene (4.2 ml) was dissolved in the nonaqueous solvent. Catalyst solutions are, are added to the monomer solution, the resulting monomer and catalyst mixtures 2 with stirring, in a and temperature maintaining time, then the cooling room temperature. Residual removing the catalyst and, excess methanol reaction mixture adaptation using an isotropic polymer by oneself out to get through the sub. By filtration after isolated as far as polymers by, 60 °C a was very dry. % Yield: 57%. Final analysis: Mw = 65461, Mw/Mn = 1.57, = 46/54 DMMINB/NBTON a composition by 13C NMR.

C: manufacturing intermediate layer

Said in the embodiment are, according to the present invention, gate insulator layer in device OFET commonly used as dielectric layers positioned on a sidewall of the, described the manufacture of intermediate layer. Film formation on upper the same in intermediate layer be subsequent layers facing adhesion is determined by a measure of contact angle. (Surface energy that is correlated) generally module is installed under the adhesive contact angle correlation.. Therefore, in the art for the adhesive material, is described as a positive history molecules of attractive force between. The intensity of attraction is determined by energy of a surface of a material, the contact angle can be determined by a measure of. Generally, ground in a lower contact angle, . becomes higher surface energy. Surface energy becomes higher surface, molecules and manpower is greater, resulting in a lower surface energy surface, is carried out, the amount of manpower is weaker. Therefore, lower contact angle (therefore longer high surface energy) indicating against the surface to be cleaned, is useful as the it possible to ensure a good adhesion of subsequent layers can be.

Is not referred alternatively, in contact angle ranges hereinafter in the embodiment, with software for analyzing DSA1 DSA 10 Kruss Srop Shape. is computed using the analysis system. Deionization (DI) number of droplets, to range l micro 5-100 volume of syringe (syringe) arranged on the sample through. And then an Image of the drops of capturing and software, DSA1 implemented in software circle fitting method (circle fitting method) by the calculated contact angle.

In the embodiment C1. NBCH₂ C₆ F₅/DMMIMeNBcopolymer intermediate layer

2-in the embodiment B23 in copolymer from [...] NBCH₂ C₆ F_5/ DMMIMeNB (50/50) solution of 2.4% w/w, CYTOP^TM 809M pre-glass substrate coated with is spin-coated. In upper structure thereof DI 83-87 contact angle ranges measured number is range. The for later reference, a contact angle of at layer CYTOP 809M plane DI measuring number, has also been found the range 112-118.

In the embodiment C2. NBCH₂ C₆ F₅/DMMINB/MeOAcNB polymer intermediate layer

2-in the embodiment B94 in terpolymer from [...] NBCH₂ C₆ F_5/ DMMIMeNB/MeOAcNB (47/40/13) of 2.4% w/w solution, glass substrate coated with pre-CYTOP 809M is spin-coated. Structure thereof upper DI in number but range 80 measured contact angle ranges, plane CYTOP 809M layer to contact angle measured number DI 112-118 is range.

In the embodiment C3. NBCH₂ C₆ F₅/DMMIMeNB and MeOAcNB/DMMIMeNB copolymermixture (1:1) intermediate

Copolymer from in the embodiment B23 in MAK NBCH₂ C₆ F_5/ DMMIMeNB (50/50) MeOAcNB/DMMIMeNB (50/50) copolymer from in the embodiment B1 and a 1:1 mixture of 2.4% w/w solution, glass substrate coated with pre-CYTOP 809M is spin-coated. Structure thereof upper DI in number but range 75-77 measured contact angle ranges, plane CYTOP layer to contact angle measured number DI 112-118 is range.

In the embodiment C4. NBCH₂ C₆ F₅/DMMIMeNB and MeOAcNB/DMMIMeNB copolymermixture (1:2) intermediate

Copolymer from in the embodiment B23 in MAK NBCH₂ C₆ F₅/DMMIMeNB (50/50) MeOAcNB/DMMIMeNB (50/50) copolymer from in the embodiment B1 and a 1:2 mixture solution of 2.4% w/w, CYTOP^TM 809M pre-glass substrate coated with is spin-coated. Structure thereof upper DI in number but range 70 measured contact angle ranges, plane CYTOP layer to contact angle measured number DI 112-118 is range.

In the embodiment C5. NBCH₂ C₆ F_5/ DMMIMeNB and NBCH₂ GlyOAc/DMMIMeNBcopolymer mixture (1:1) intermediate

Copolymer from in the embodiment B23 in MAK NBCH₂ C₆ F₅/DMMIMeNB (50/50) in the embodiment B88 and a copolymer from NBCH₂ GlyOAc/DMMI (54/46) of 2.4% w/w solution 1:1 mixture, glass substrate coated with pre-CYTOP 809M is spin-coated. Structure thereof upper DI in number but range 70 measured contact angle ranges, plane CYTOP layer to contact angle measured number DI 112-118 is range.

C6-C15in the embodiment. Other, interlayers comprising those agents

Different nose Polymer and terpolymer using manufacturing as described in the embodiment C1 and an intermediate layer consisting of embodiment for the contact angle measurement. Table 13 to abstract the result to the computer of the hereinafter.

C15.in the embodiment NBCH₂ C₆ F₅homopolymer intermediate

Made of a homopolymer of during MAK NBCH₂ C₆ F₅ solution of 2.4% w/w, CYTOP^TM 809M pre-glass substrate coated with is spin-coated. Upper structure thereof in measured contact angle ranges only intelligence DI number 97, plane CYTOP layer to contact angle measured number DI 112-118 is range.

C16.in the embodiment NBCH₂ C₆ F₅intermediate mixture copolymer NBTODD/DMMIMeNB homopolymers and

Made of a homopolymer of during MAK NBCH₂ C₆ F₅ NBTODD/DMMINB (50/50) copolymer and 1:1 mixture solution of 2.4% w/w, CYTOP^TM 809M pre-glass substrate coated with is spin-coated. Upper structure thereof in measured contact angle ranges only intelligence DI number 63, plane CYTOP layer to contact angle measured number DI 112-118 is range.

C17.in the embodiment NBCH₂ C₆ F₅homopolymers and NBCH₂ OCH₂ CH₂ OAc/DMMIMeNBintermediate mixture copolymer

Made of a homopolymer of during MAK NBCH₂ C₆ F₅ and copolymer NBCH₂ OCH₂ CH₂ OAc/DMMINB (56/44) 1:1 mixture solution of 2.4% w/w, CYTOP^TM 809M pre-glass substrate coated with is spin-coated. Upper structure thereof in measured contact angle ranges only intelligence DI number 67, plane CYTOP layer to contact angle measured number DI 112-118 is range.

C18.in the embodiment NBCH₂ C₆ F₅intermediate mixture copolymerMeOAcNB/DMMI homopolymers and

Made of a homopolymer of during MAK NBCH₂ C₆ F₅ MeOAcNB/DMMINB (50/50) copolymer and 1:1 mixture solution of 2.4% w/w, CYTOP^TM 809M pre-glass substrate coated with is spin-coated. Upper structure thereof in measured contact angle ranges only intelligence DI number 71, plane CYTOP layer to contact angle measured number DI 112-118 is range.

C19-C21in the embodiment. NBCH₂ C₆ F₅, interlayers comprising those agents of mixtures PMMA homopolymers and

Polymers homodyne NBCH₂ C₆ F₅ and PMMA (M_w 15,000, Sigma-Aldrich is at) in various proportions are melted in 2.4% w/w MAK into acquires solution. Solution, CYTOP^TM MAK pre-glass substrate coated with is spin-coated. Using number DI in upper structure thereof it was determined that contact angle. Table 14 to abstract the result to the computer of the hereinafter. Plane CYTOP layer to contact angle measured number DI 112-118 is range.

C22.in the embodiment NBCH₂ C₆ F₅/DMMIMeNB and DMMIMeNB/NBTON copolymermixture (1:1) intermediate

Copolymer from in the embodiment B23 in MAK NBCH₂ C₆ F_5/ DMMIMeNB (50/50) and a in the embodiment B97 NBTON (52/48)/ DMMIMeNB copolymer from 2.4% w/w solution of 1:1 mixture, glass substrate coated with pre-CYTOP 809M is spin-coated. Structure thereof upper DI in number but range 58-60 measured contact angle ranges, plane CYTOP layer to contact angle measured number DI 112-118 is range.

The in the embodiment C1-C22, the present invention according to by intermediate insulator layer, which is applied, intermediate layers compared to insulating layer plane not, contact angle can be significantly reduced, thus improved adhesive and slippery surface energy exhibits may be increased.

D: device manufacturing

Prepare silk fibroin fibre OFET gate top portion as follows. Coning 1737 glass substrate, in 70 °C and ultrasonically treating a 3% Decon90 in 30 minutes, water 2 times cleaning and, after ultrasonically treating a in MeOH, spin coater on. judged to be dried is dried by pinch-off. Gold having a thickness 30 nm device having source and drain electrodes in in order to carry out the method on the substrate, channel L = 50 m and W = 1000 micro m generates micro. Substrate surface treatment preparations for Lisicon^TM M001 (Merck KGaA available from, Darmstadt, Germany) and miunutes 1 to, isopropyl alcohol cleaning and, spin coater on. judged to be dried is dried by pinch-off. On the substrate processing said OSC formulations Lisicon^TM S1036 (Merck KGaA available from, Darmstadt, Germany) after to the spindle, is annealing minutes on hot plate 100 °C 1. CYTOP^TM (FC-43 9% in, Asahi) and a dielectric layer a cooled substrate is spin-and (500 rpm and 2000 rpm 10 seconds 20 seconds), the heating on hot plate 100 °C 2 minutes. Intermediate from a solution, 2.4% MAK in is is spin-a cooled substrate from a solution. Furthermore, etching tub 30 nm, inserted into the tube to intermediate layer as gate electrode. For electrical characteristics, cable is disposed on the probe station samples, via probe head Suess PH100 semiconductor to the Agilent 4155C. Then equations using the same are mobile and saturated in linear VD =-5V and VD =-60V. calculation.

Wherein L and W and, length and width of a channel, Cox = dielectric capacitance [F/cm²], ID = drain current, absolute value of square root sqrt ID = ID, VG = gate voltage, is VD = drain voltage.

In the embodiment D1. In the embodiment including OFET intermediate C1

Prepared in the embodiment C1 of S1036 encompasses an intermediate layer with a device made representatively transition curve been are measured, 20 minutes after VG =-40V also electrical stress in VD =-40V and 7 and to present on, device for electronically properties not seen in the effect of an intermediate layer.

In the embodiment D2. In the embodiment including OFET intermediate C2

Prepared in the embodiment C1 of S1036 encompasses an intermediate layer with a device made representatively transition curve been are measured, 20 minutes after VG =-40V also electrical stress in VD =-40V and 8 and to present on, device for electronically properties not seen in the effect of an intermediate layer.

Embodiment examples the D2 and D1, transistor devices including intermediate the present invention according to that is stable under electrical stress that a certification.

C section in D and are in the embodiment, the present invention according to intermediate in organic field effect transistor, which is applied by gate insulator layer, without adverse effect on transistor performance organic semiconductor relative the material of the insulator while maintaining orthogonal solubility characteristics, insulator is applied on top of a layer of another toward adhesion and surface energy increasing the exhibits may be.