CATALYST COMPOSITION FOR INTERNAL COMBUSTION ENGINE

11-10-2017 дата публикации
Номер:
KR1020170110187A
Принадлежит:
Контакты:
Номер заявки: 00-16-102033782
Дата заявки: 22-03-2016

[1]

The present invention refers to relates to catalyst composition for an internal combustion engine, more particularly 2 - ethyl [heyk thread oh three reels telephone number as complexing improvement propylene glycol, metal nitrate compounds and polyvinyl alcohol by combustion for use gun-adjusted efficiency, thereby reducing exhaust gas of a diesel catalyst composition for internal combustion engine are disclosed.

[2]

Human information to particular industrial environment into a PET environment is only gradually and, in particular through the process solution looking for automobile exhaust gas pollution Korean traditional music has recognized one of serious social door number etc. a jacket pocket. 2010 years before players only when the death due to air pollution is aero-generator 320, this 4 times compared to name only 80 years of 2000 has been increased. According to dead person generated in Russian only 210 inside d reference Asia 2010 years air pollution and be directly related to which, degeneration of is fuel of a diesel exhaust gas and including air pollution, air pollution of the same is provided to vehicle emission gas is in the spotlight for the gate number [...] washbowls, etc. in America and Canada back is one last 1970's effective loaded in a cassette.

[3]

Door heats the number supplied by forward or backward, etc. such as number or number of freezer freezer fuel consumption ratio control device continuously developed. For example, biodiesel fuel including a fuel adding number including a ring for American Public Patent Notification number 2006/0201056 aliphatic nitrate techniques are described but, aliphatic nitrate compounds are a high degree of improving a cetane, toxic it is burnt without stability, causing environmental door number such as door number measured disclosed. In addition, the degree of reduction of 30 to 40% or higher have composition are also smoke States with my, 5 to 10% fuel consumption ratio control effect sends a disclosed. But collection and improving vehicle fuel consumption, environmental pollution and resources is significantly faster than the running speed out rate effect an embankment and the development of compositions are disclosed.

[4]

American Public Patent Notification number 2006/0201056 call

[5]

Thus, the present invention refers to said door of the existing method is such as to solve number point, cylinder mixer further head in silica, silica reordering, cylinder wall to prevent oil film formation between, it became the cow sword ingredient unburned hydrocarbon injector, intake valve, adhere to the intake manifold of an internal combustion engine cylinder while not clean as well as redox response is elicited near complete combustion in an internal combustion engine generating primary and secondary combustion that implement, environment-friendly engine while excellent combustion ignition of fuel within the fuel efficiency, exhaust gas of a diesel and thereby significantly reduces the number to which the pin is to reduce [...] catalyst composition for internal combustion engines.

[6]

The present invention according to purposes such as for an internal combustion engine for achieving said catalyst composition comprises 100 parts by weight of polyalkylene glycol 1 - 50 parts by weight of 2 - ethyl [heyk thread acetate as complexing improvement number, metal nitrate compound 1 ∼ 80 parts by weight of polyvinyl alcohol can be 1 ∼ 70 parts by weight.

[7]

In the present invention according to a catalyst composition for internal combustion engine, said polyalkylene glycol polyethylene glycol, polypropylene glycol and polybutylene glycol 1 be a selected from at least one.

[8]

Said polyalkylene glycol a weight average molecular weight 3,000 to 50,000 implementation being.

[9]

Said polyalkylene glycol is acyl, aldehyde, amine, epoxy [...], ISO at the time of knows sprouting,, american [tu maleimide, knit with phenyl car [lu sees sprouting,, five [lu urination [til d clear statement id, opinion blood drill, writing base hit [ley sprouting, [...], and succinic acid [swuk is sour sprouting, [...] 1 during one or more can be substituted.

[10]

In the present invention according to a catalyst composition for internal combustion engine, said metal nitrate compounds, the residual, potassium nitrate, barium nitrate, zinc nitrate, aluminum nitrate, magnesium nitrate, amyl nitrate and at least one selected from manganese nitrate be a 1.

[11]

In the present invention according to a catalyst composition for internal combustion engine, said polyvinyl alcohol a weight average molecular weight 2,000 ∼ 5,000 implementation being.

[12]

In the present invention according to a catalyst composition for internal combustion engine, ignition improver as alkane compounds can be further includes a number.

[13]

For an internal combustion engine for promoting conversion reaction of the present invention according to redox catalyst composition number, dispersion number, clean number, customer number, lubricating number, viscosity index improver number, number number 1 further comprises at least one of mineral oil distillate and oil can be improved.

[14]

In the present invention according to a catalyst composition for internal combustion engine, said redox number is for promoting conversion reaction of platinum, palladium, rhodium, cerium, column other [nem, organic germanium, titanium, silicon, tin, manganese, nickel and silver selected from at least one metal or metal compound be a 1.

[15]

In the present invention according to a catalyst composition for internal combustion engine, said dispersion number is barium, magnesium, calcium, boron, amine, imidazolin, polyalkyl succinimide, polyalkylamine and polyetheramine be a selected from at least one such as 1.

[16]

In the present invention according to a catalyst composition for internal combustion engine, said cleaning number is chosen amongst the vice-reel neel nose [heyk it buys already [tu orgin compounds, poly vice-reel neel amine orgin compounds, surfactants number, polyolefin, polyamine, butadiene styrene copolymer, at least one selected from 1 be a succinimide and [swuk new already [tu pulley this year.

[17]

In the present invention according to a catalyst composition for internal combustion engine, said anti-wear number is phosphorus, zinc, molybdenum disulfide, ethylene propylene copolymer, market [sway region family s reel [lu amine, selected from at least one male [ik s reel [lu be a fluorine compound and styrene copolymer 1.

[18]

In the present invention according to a catalyst composition for internal combustion engine, said lubrication number is polyethylene, benzyl amine, zinc phosphate, neel the [khey which it will know [swuk new it buys, number surfactants, at least one selected from stearic acid and poly polyisobutenyl 1 be a.

[19]

In the present invention according to a catalyst composition for internal combustion engine, said viscosity index improver number is chosen methacrylate, 1 be a selected from at least one agent containing the esterification reaction and polyacrylate.

[20]

In the present invention according to a catalyst composition for internal combustion engine, said number of ethylene-vinyl acetate copolymer (EVA) or mineral oil distillate, polyvinyl pyrrolidone, paraffin chloride naphthalene condensation water and at least one selected from paraffin chloride 1 be a phenol condensation water.

[21]

In the present invention according to a catalyst composition for internal combustion engine, said improved planetary number is a polyphosphoric acid, fat family oh wheat outer reel alcohol, amide, amine selected from at least one of stearic it buys the butyl writing [ley phosphoric acid mono writing scherrer id and triacetyl be a 1.

[22]

The present invention according to a catalyst composition for the internal combustion engine, cylinder mixer further head in silica, silica reordering, cylinder wall to prevent oil film formation between, it became the cow sword ingredient unburned hydrocarbon injector, intake valve, intake manifold of an internal combustion engine cylinder not adsorbed while clean as well as slurry to a harmful substance, and reducing, excellent combustion process the stable combustion for use gun smoothly flow tides.

[23]

In the embodiment of the present invention Figure 1 shows a catalyst compositions also by one of flow diagram represents a surface mounted internal combustion engine combustion in processing components are disclosed. Figure 2 in the embodiment 1 and comparison example 1 uses a catalyst composition of a fuel is used indicating characteristics of a suction manifold are disclosed. Figure 3 in the embodiment 1 ∼ 4 uses a catalyst composition of a fuel is used indicating characteristics of a suction manifold are disclosed. Figure 4 comparison example 2 ∼ 3 uses a catalyst composition of a fuel is used indicating characteristics of a suction manifold are disclosed. In the embodiment 1 and comparison example 1 of Figure 5 uses a catalyst composition having indicating fuel for vehicle engines of atomization are disclosed. Figure 6 in the embodiment 1 and comparison example 1 uses a catalyst composition of fuel in the fuel chamber indicating carbon contamination state are disclosed.

[24]

Advantages and features of the present invention, achieve the appended drawing method and an electronic component connected to the reference surface with specifically carry activitycopyright will in the embodiment. However the present invention refers to hereinafter are limited to the disclosure in the embodiment in different but can be implemented in various forms, in the embodiment of the present invention disclosure to only the are completely, to complete the present invention of the invention is provided to a target number for informing a person with skill in the art categories in which ball, defined by category of the present invention refers to claim only disclosed.

[25]

In the absence of other definitions, all terms used in the specification is provided to the present invention (including the techniques and the treatment) is in common sense can be understood to a person with skill in the art to can be used are disclosed. It is apparent that a term generally used in a pre-defined are not specially defined is not ideally or overly interpreted.

[26]

Hereinafter, the present invention according to a catalyst composition for internal combustion engine for detailed as follows.

[27]

The present invention according to catalyst composition for an internal combustion engine gasoline, via, LPG engine in a combustion for an internal combustion engine consisting in complexing resin layers, the ejected material hydrocarbon (HC), carbon monoxide (CO), nitrogen oxides (NOX ) Optimized to effectively reduce harmful gas in a combined ratio are disclosed.

[28]

More particularly, the present invention according to catalyst composition for an internal combustion engine 100 parts by weight of polyalkylene glycol 1 - 50 parts by weight of 2 - ethyl [heyk thread acetate as complexing improvement number, metal nitrate compound 1 ∼ 80 parts by weight of polyvinyl alcohol can be 1 ∼ 70 parts by weight.

[29]

Said 2 - ethyl [heyk thread acetate fuel combustion, ignition delay is performed generates free radical (free radical) coating, help serve as suspension engine, engine fuel within by properly the complexed fuel efficiency, exhaust gas of a diesel and thereby generates a signal of the circuit 22a..

[30]

Said polyalkylene glycol polyethylene glycol, polypropylene glycol and polybutylene glycol 1 may be selected from at least one, preferably a poly propylene glycol are disclosed.

[31]

Said polyalkylene glycol a weight average molecular weight 3,000 to 50,000 in bigger, it does not burn well in said combustion if the whole preferably range between carbon sludge or the like.

[32]

Said polyalkylene glycol is acyl, aldehyde, amine, epoxy [...], ISO at the time of knows sprouting,, american [tu maleimide, knit with phenyl car [lu sees sprouting,, five [lu urination [til d clear statement id, opinion blood drill, writing base hit [ley sprouting, [...], and succinic acid [swuk is sour sprouting, [...] 1 during one or more can be substituted.

[33]

100 parts by weight of 1 - 50 parts by weight of said polyalkylene glycol is 2 - ethyl [heyk thread acetate, preferably 10 - 35 parts by weight of the multimers, 1 parts by weight of a complexing agent can fall without-is below desired, exceeds 50 parts by weight of black carbon sludge into a liquefied gas upon degradation at high temperatures is advantageous for WIPO.

[34]

Said metal nitrate and hereinafter for data for the industrially inexpensive, particularly without requiring special reaction equipment, in addition to metal nitrate number can be [...] hereinafter for number under reaction conditions and high pressure liquid coolant, high thermal stability since, even when a high temperature atmosphere aside in long-term (for example 10 years ∼ 10 years), includes a plurality of decomposition at high speed such as not suitable for use.

[35]

Said metal nitrate compounds, the residual, potassium nitrate, barium nitrate, zinc nitrate, aluminum nitrate, magnesium nitrate, amyl nitrate and at least one selected from manganese nitrate be a 1.

[36]

100 parts by weight of said metal nitrate compounds are 2 - ethyl [heyk thread acetate 1 ∼ 80 parts by weight, preferably 5 ∼ 30 parts by weight of the multimers, 1 parts by weight of harmful matter is below without reducing its ability to be away preferably, 80 parts by weight of the desired diameter in excess exceeds a negative polarity number isn't very sharp.

[37]

Said polyvinyl alcohol is, vinyl alcohol monomer unit mainly including polymer, in particular vinyl acetate polymer or vinyl trifluoro acetate polymer, vinyl formate polymer, thermosetting resin polymer, other polymers such as vinyl ether polymer for producing tris trough t - butyl vinyl ether polymer esters obtained by hydrolyzing (influence) products as saying, preferably 70 mole % or more and a degree of influence, and excellent chemical resistance, weight polymer material that has excellent mechanical strength.

[38]

In the present invention according to a catalyst composition for internal combustion engine, said polyvinyl alcohol a weight average molecular weight 2,000 ∼ 5,000 implementation being.

[39]

100 parts by weight of said polyvinyl alcohol is 2 - ethyl [heyk thread acetate 1 ∼ 70 parts by weight, preferably 20 - 50 parts by weight of the other party, said out-complexing can fall advantageous for WIPO.

[40]

The present invention according to catalyst composition comprises alkane compounds from drug-ignition for an internal combustion engine can be as much as.

[41]

Said alkane compound combustion is satisfactory, or wax (wax) component hard component rich in less specific gravity. Said alkane compounds, particularly it is a vice-reel kinds and defining is performed, propylene and isobutylene 1 be a selected from at least one.

[42]

The gunpowder and preferably less than 1 parts by weight of said alkane compound engine is constructed without, exceeds 70 parts by weight of excessive knocking transfers may adversely affect the internal combustion engine be advantageous uninhabitable.

[43]

For an internal combustion engine for promoting conversion reaction of the present invention according to redox catalyst composition number, dispersion number, clean number, customer number, lubricating number, viscosity index improver number, number number 1 further comprising at least one mineral oil distillate and oil can be improved during normal usage.

[44]

Said number is promoting redox reaction, excess air number words preventing rising of temperature and high ignition power and recovery function, N1 compound NO protect holes formed piston cylinderx To convert to a size suitable for reducing the nitrogen and oxygen, the oxygen thus generated on CO CO again in response2 Whereas, O2 Unimpeded by NOx Can be selectively reducing, NOx Number well! ratio very high effect.

[45]

I.e., promoting said number detrimental materials exiting the internal combustion engine rapidly oxide redox reaction, reduction reaction cause compounds, redox reaction promoting said number is, without specifically limiting, for example platinum, palladium, rhodium, cerium, column other [nem, organic germanium, titanium, silicon, tin, manganese, selected from at least one metal or metal compound be a nickel and silver 1.

[46]

Said platinum, palladium and rhodium metal catalyst itself can be a methacrylate group, chlorine and combining same ion state using the compound of the catalyst can be largely elevated height, diameter than metal using only ensure number can be inserted, said platinum, palladium and rhodium in combination with the shape of the chlorine compounds, platinum chloride, palladium chloride, be a rhodium chloride and sodium citrate. In particular, platinum is chloride when heavy fast toward the neutral distilled water dilution to sealed to and to, said platinum chloride, palladium chloride, rhodium chloride and sodium citrate stock preferably the form of a hydride and, specifically, platinum chloride stock cargo (H2 PtCl2 6H2 O), palladium chloride stock cargo (PdCl2 6H2 O) rhodium chloride or odor of cargo (RhCl3 6H2 O) implementation being. In hydrated form stock when, upon dilution to ionized distilled water effective to shorten the time required functions as a catalyst are disclosed.

[47]

Said cerium (cerium) and column it burns it went over, it can be used as metal itself, cerium oxide, used in the form [...] oxide may be filled. Excellent oxygen adsorption and releasing capabilities of a cerium column it burns it went over said hydrocarbon, carbon monoxide, harmful substances such as nitrogen oxides reducing power for further enhancing the activity of said ignition improver for excellent oxidation number can be.

[48]

Said organic germanium formula (GeCH2 CH2 COOH)2 O3 To, the effect is preferably 40 to 48% in purity, in particular 42. 8% or most effective mm., the 802.11a packets not one number. A large amount of metal for said water soluble organic germanium cation followed by oxidative prevent, oxygen supply could be bonded each other. In addition, radiation energy to emit light properties when organic germanium thus, more augment strong oxidation force which could be bonded each other.

[49]

In the present invention according to a catalyst composition for internal combustion engine, said dispersion number is included in the lubricant oil insoluble materials and unburned carbide dispersed inside engine sludge and prevents agglomeration of the contaminant, and neutralize acidic substance has a predetermined, said dispersion number is particularly limiting free, barium, magnesium, calcium, boron, amine, imidazolin, polyalkyl succinimide, polyalkylamine and polyetheramine be a 1 selected from at least one.

[50]

The present invention according to the wetting ability of reinforced concrete slab billion injection nozzle for an internal combustion engine catalyst composition number or number, and vaporizer intake valve, injector components such as unburned carbon tied for attachment and anti-necessary-can be further includes clean number. After addition of clean number when added with lubricating number, or lubricate a number adding on preferably simultaneously. In an engine is operating in said high temperature clean number forming of prevention and reduce, prevent low temperature state where it generating and deposits, engine around dust particles is deposited inside to form a strong affinity material, serve as a wafer action sludge and and [ni [su creation adjustment, is particularly kinds and defining is performed, for example poly the vice-reel neel nose [heyk it buys already [tu orgin compounds, poly vice-reel neel amine orgin compound, number surfactants, polyolefin, polyamine, butadiene styrene copolymer, at least one selected from 1 be a succinimide and [swuk new already [tu pulley this year.

[51]

In the present invention according to a catalyst composition for internal combustion engine, said metallic corrosion with an anti-wear number of moisture on the entire structure including billion softening and number, for preventing generation of sword as a matter of material used, in addition, chemically reacts with the metal surface to form a passivation and, the movable part can slide relative to each other to function and minimizes wear of the week.

[52]

Said number is for preventing wear, particularly defining is performed, for example, phosphorus, zinc and molybdenum disulfide, ethylene propylene copolymer, market [sway region family s reel [lu amine, selected from at least one male [ik s reel [lu be a fluorine compound and styrene copolymer 1.

[53]

In the present invention according to a catalyst composition for internal combustion engine, said lubrication number is polyethylene, benzyl amine, zinc phosphate, neel the [khey which it will know [swuk new it buys, number surfactants, at least one selected from stearic acid and poly polyisobutenyl 1 be a.

[54]

In the present invention according to a catalyst composition for internal combustion engine, said viscosity index improver according to number and viscosity of oil temperature change is change, the use of a viscosity to enhance [...], without specifically limiting kinds and is, for example, poly methacrylate, 1 be a selected from at least one agent containing the esterification reaction and polyacrylate.

[55]

In the present invention according to a catalyst composition for internal combustion engine, said lubricating mineral oil distillate number is added calculated as required fluidity for crossing the crystal form of wax can be used to pull down the pour point, determining paraffin (wax) and preventing the occurrence of the deposition at a low temperature, the fluidity of the fine-reducing component via [...] (wax) and, said paraffin is dispersed to interfere determination growth and agglomerated fuel may pass through the fuel filter which each, injector, nozzle, suction valve, throttle body, intake manifold to prevent deposits in the event that the number of industry role, limiting kinds and particularly is free, for example ethylene-vinyl acetate copolymer, polyvinyl pyrrolidone, paraffin chloride naphthalene condensation water and at least one selected from paraffin chloride 1 be a phenol condensation water.

[56]

In the present invention according to a catalyst composition for internal combustion engine, said improved planetary number includes friction reducing voiced to improve and has, as a compound having a polar groups [...] molecular weights large molecules, metal the surface network to reduce friction can be formed at the Lotus adsorption network, without specifically limiting the kinds and the ratio of phosphoric acid for example, fat family oh wheat outer reel alcohol, amide, and at least one selected from stearic it buys the butyl writing [ley phosphoric acid mono writing scherrer id be a triacetyl amine 1.

[57]

In the present invention according to a catalyst composition for internal combustion engine, said redox reaction promoting number, clean number, dispersion number, customer number, lubricating number, viscosity index improver number, and oil content of improved distillate number number must therefore in conventional publicly known content but, preferably the content of 100 parts by weight of said catalyst composition for promoting conversion reaction of said redox number, bigger 1 ∼ 150 parts by weight of an, said not-resistant without redox reaction out preferably, the content of said catalyst composition 100 parts by weight of said cleaning number, 1 ∼ 80 parts by weight of an bigger, said blended amount out too most, not be able to meet the same comprises a styrofoam, engine exhaust gas NO oppositex , PM and aldehydes like danger does not advantageous for increasing, the content of said catalyst composition 100 parts by weight of said dispersion number, 0. 1 ∼ 50 parts by weight of an bigger, with carbonization copolymer lubricant oil insoluble materials included in said unburned out number not distributed as does not preferably, said catalyst composition 100 parts by weight of the content of said anti-wear number 1 ∼ 200 parts by weight of an bigger, said corrosion metal out easily, oxidation-billion number generated of a sword as a matter of material such as door number may be returned to point, the content of 100 parts by weight of said catalyst composition said lubricating number 0. 1 ∼ 80 parts by weight of an bigger, said m is price reduced to sulfide can be turned into high fluidity of fuel out does not desired, said viscosity index improver number 100 parts by weight of said catalyst composition the content of 1 - 50 parts by weight of an bigger, according to said desired temperature change out oil viscosity may be greater change without, said catalyst composition 100 parts by weight of the content of said mineral oil distillate number 1 - 50 parts by weight of an bigger, pour points without desired can be too high, the content of said catalyst composition 100 parts by weight of 1 - 30 parts by weight of an improved number said planetary bigger, preferably oil sufficiently due isn't very sharp.

[58]

Hereinafter, the present invention through a detailed but in the embodiment, the present invention they are not 802.11a packets by number in the embodiment.

[59]

In the embodiment 1

[60]

2 - ethyl [heyk thread acetate 30 parts by weight of 100 parts by weight of polypropylene (weight average molecular weight: 10,000), 8 parts by weight of polyvinyl alcohol (weight average molecular weight: 3,000) zinc nitrate catalyst composition have number 30 parts by weight of a high pressure liquid coolant, as by adding 6 parts by weight of 100 parts by weight of said catalyst composition number column other [nem, poly [...] 3 parts by weight, 5 parts by weight of barium, in 10 parts by weight, 5 parts by weight and a polyisobutenyl, 5 parts by weight of a metal salt of stearic it buys the butyl writing [ley phosphoric acid mono writing scherrer id polyvinyl pyrrolidone 5 parts by weight of distilled water and mixing the number of catalyst composition carried on each solution was high pressure liquid coolant. Catalyst composition prepared by the number remains mounted on the engine, safety after the ejected material content of 150 km/h gradually raised to the operation by a long time. At this time, star rack [su year 2006 used vehicle has a vehicle bed, via using as fuel (diesel), and a control 135,753 km min 2,497 cc exhaust gas is accumulated. Method and device for each of the results is idling ASM were measured.

[61]

In the embodiment 2

[62]

2 - substituted ethyl [heyk thread acetate 100 parts by weight of polypropylene (weight average molecular weight: 5,000) 30 parts by weight of the giga which it will know, 8 parts by weight of zinc nitrate, polyvinyl alcohol (weight average molecular weight: 3,000) 30 parts by weight of a high pressure liquid coolant number have catalytic composition, as by adding 6 parts by weight of 100 parts by weight of said catalyst composition number column other [nem, 3 parts by weight of poly vice-reel neel amine, polyamine 1 parts by weight, 5 parts by weight of barium, in 10 parts by weight, 5 parts by weight of poly polyisobutenyl, 5 parts by weight of polyvinyl pyrrolidone 5 parts by weight of a metal salt of stearic it buys the butyl writing [ley phosphoric acid mono writing scherrer id carried on each solution of distilled water and mixing the catalyst composition number was high pressure liquid coolant. An apparatus using identical conditions as in the embodiment 1, catalyst composition prepared by the number remains mounted on the engine, safety after the ejected material content of 150 km/h gradually raised to the operation by a long time.

[63]

In the embodiment 3

[64]

2 - substituted ethyl [heyk thread acetate 100 parts by weight of polypropylene (weight average molecular weight: 10,000) 30 parts by weight of amine, 8 parts by weight of zinc nitrate, polyvinyl alcohol (weight average molecular weight: 3,000) 30 parts by weight of a high pressure liquid coolant number have catalytic composition, as by adding 6 parts by weight of 100 parts by weight of said catalyst composition number column other [nem, 3 parts by weight of poly vice-reel neel amine, polyamine 1 parts by weight, 5 parts by weight of barium, in 10 parts by weight, 5 parts by weight of poly polyisobutenyl, 5 parts by weight of polyvinyl pyrrolidone 5 parts by weight of a metal salt of stearic it buys the butyl writing [ley phosphoric acid mono writing scherrer id carried on each solution of distilled water and mixing the catalyst composition number was high pressure liquid coolant. An apparatus using identical conditions as in the embodiment 1, catalyst composition prepared by the number remains mounted on the engine, safety after the ejected material content of 150 km/h gradually raised to the operation by a long time.

[65]

In the embodiment 4

[66]

2 - ethyl [heyk thread acetate 30 parts by weight of 100 parts by weight of polyethylene glycol, 8 parts by weight of manganese nitrate, polyvinyl alcohol (weight average molecular weight: 3,000) 30 parts by weight of a high pressure liquid coolant number have catalytic composition, as by adding 6 parts by weight of 100 parts by weight of said catalyst composition number column other [nem, poly [...] 3 parts by weight, 5 parts by weight of barium, in 10 parts by weight, 5 parts by weight of poly polyisobutenyl, 5 parts by weight of a metal salt of stearic it buys the butyl writing [ley phosphoric acid mono writing scherrer id polyvinyl pyrrolidone 5 parts by weight of distilled water and mixing the number of catalyst composition carried on each solution was high pressure liquid coolant. Catalyst composition prepared by the number remains mounted on the engine, safety after the ejected material content of 150 km/h gradually raised to the operation by a long time. At this time, used vehicle, 1997 year SONATA III 1. 8 vehicle, using gasoline as fuel (gasoline), the accumulated exhaust gas and a control 171,274 km min 1,796 cc. Method and device for each of the results is idling ASM were measured.

[67]

Comparison example 1

[68]

The catalyst composition is not [...] number and mounting, an apparatus using identical conditions as in the embodiment 1, after the ejected material content of 150 km/h speed gradually raised to the operation by a long time.

[69]

Comparison example 2

[70]

2 - ethyl [...] (weight average molecular weight: 10,000) 30 parts by weight of 100 parts by weight of polypropylene, 8 parts by weight of zinc nitrate, polyvinyl alcohol (weight average molecular weight: 3,000) 20 parts by weight of a high pressure liquid coolant number have catalytic composition, as by adding 6 parts by weight of 100 parts by weight of said catalyst composition number column other [nem, poly [...] 3 parts by weight, 5 parts by weight of barium, in 10 parts by weight, 5 parts by weight of poly polyisobutenyl, 5 parts by weight of a metal salt of stearic it buys the butyl writing [ley phosphoric acid mono writing scherrer id polyvinyl pyrrolidone 5 parts by weight of distilled water and mixing the number of catalyst composition carried on each solution was high pressure liquid coolant. An apparatus using identical conditions as in the embodiment 1, catalyst composition prepared by the number remains mounted on the engine, safety after the ejected material content of 150 km/h gradually raised to the operation by a long time.

[71]

Comparison example 3

[72]

Polypropylene glycol does not [...] number equal to the number in the embodiment 1 and catalyst compositions have high pressure liquid coolant, an apparatus using identical conditions as in the embodiment 1, catalyst composition prepared by the number remains mounted on the engine, safety after the ejected material content of 150 km/h gradually raised to the operation by a long time.

[73]

Comparison example 4

[74]

Weight average molecular weight of 1,000 weight average molecular weight of 10,000 in polypropylene glycol and polypropylene glycol instead of in the catalyst composition in the range of 0.1 [...] number equal to the number in the embodiment 1 and have high pressure liquid coolant, an apparatus using identical conditions as in the embodiment 1, catalyst composition prepared by the number remains mounted on the engine, safety after the ejected material content of 150 km/h gradually raised to the operation by a long time.

[75]

Comparison example 5

[76]

Polyvinyl alcohol [...] number equal to the number in the embodiment 1 and the catalyst composition does not have high pressure liquid coolant, an apparatus using identical conditions as in the embodiment 1, catalyst composition prepared by the number remains mounted on the engine, safety after the ejected material content of 150 km/h gradually raised to the operation by a long time.

[77]

Comparison example 6

[78]

30 parts by weight of 100 parts by weight of polyvinyl alcohol instead of the number equal to the number have [...] catalyst composition in the embodiment 1 and high pressure liquid coolant, an apparatus using identical conditions as in the embodiment 1, catalyst composition prepared by the number remains mounted on the engine, safety after the ejected material content of 150 km/h gradually raised to the operation by a long time.

[79]

Comparison example 7

[80]

30 parts by weight to 70 parts by weight of polypropylene (weight average molecular weight: 10,000) in the embodiment 1 and instead use a number equal to the number [...] catalyst compositions have high pressure liquid coolant, an apparatus using identical conditions as in the embodiment 1, catalyst composition prepared by the number remains mounted on the engine, safety after the ejected material content of 150 km/h gradually raised to the operation by a long time.

[81]

CO (%)1)HC (ppm)2)NOx (Ppm)3)Excess air rate (%)4)
In the embodiment 11. 02/0. 9147/2072770. 97
In the embodiment 21. 01/0. 9150/2083050. 97
In the embodiment 31. 01/0. 8132/1972570. 99
In the embodiment 41. 02/0. 8131/180268
Comparison example 12. 32/2. 4257/4622,0450. 91
Comparison example 21. 5/1. 3211/3581,7910. 93
Comparison example 32. 1/2. 5274/3572,3570. 91
Comparison example 41. 3/1. 5172/1839320. 95
Comparison example 52. 7/2. 5266/4502,1210. 91
Comparison example 61. 01/1. 0205/2371,4300. 96
Comparison example 71. 27/1. 31187/2158750. 97

[82]

Main) 1) the carbon monoxide density discharge permission criteria 1. 21/1. About 2% hereinafter.

[83]

2) hydrocarbon concentration about the discharge permission criteria 190/220 ppm hereinafter.

[84]

3) the nitrogen oxide concentration of about 1,310 ppm hereinafter discharge permission criteria.

[85]

4) excess air rate of permission criteria is 0. 90 ∼ 1. 10 that would yield.

[86]

Said seen in table 1, in the case of in the embodiment 1 ∼ 4, carbon monoxide, hydrocarbon and nitrogen oxide concentration exhaust permission criteria hereinafter catalyst composition for the internal combustion engine both as conditions or, in the case of comparison example 1 to 3 and 5, said carbon monoxide, hydrocarbon and permission criteria as both catalyst composition for an internal combustion engine exceeds a concentration of the nitrogen oxides discharged state for a predetermined be drinkable.

[87]

In addition, in the case of comparison example 4 the content of the hydrocarbon and nitrogen oxides or discharge permission criteria of hereinafter, carbon monoxide content of 1. 3/1. The carbon monoxide density to discharge permission criteria exceeding 5%, hydrocarbon and satisfies a criterion or discharge concentration value is acceptable concentration of the nitrogen oxides, carbon monoxide density discharge does not satisfy the permission criteria can be know.

[88]

In addition, in the case of comparison example 6 in the case of carbon monoxide, but carbon monoxide discharge permission criteria is satisfied, the concentration of the nitrogen oxides hydrocarbon and does not satisfy the discharge permission criteria can be know.

[89]

In addition. In the case of comparison example 7 discharge permission criteria satisfied but the concentration of the nitrogen oxides and hydrocarbons, the concentration of carbon monoxide can be know does not satisfy the discharge permission criteria.

[90]

Experiment example 1: Suction manifold of Contamination

[91]

2 ∼ 4 comparison example 1 ∼ 3 uses a catalyst composition having a fuel is used in the embodiment 1 ∼ 4 and is also of indicating characteristics of a suction manifold is provided, in the embodiment 1 ∼ 4 contaminants the cleaning the intake manifold is not attached to a pollutant such as but, in the case of comparison example 1 have the pretreatment device is very severe, for example in the case of comparison example 1 or less than 2 ∼ 3 comparison, contaminants present can be know.

[92]

Experiment example 2: vehicle engines operating

[93]

In the embodiment 1 and comparison example 1 of Figure 5 uses a catalyst composition is provided fuel for vehicle engines of atomization state, for example in the case of vehicle engines of carbon contamination by impurities 1 compared with very weakly pressed against each other in the combustion while spray, in the case of vehicle engines of impurities in the embodiment 1 by cleaning to clean carbon contaminants pressed against each other in combustion chemical reaction efficiency can be reduced and discharged into the soot loading into a number would know.

[94]

I.e., suction valve around carbon, sludge of the engine oil is deposited as the substance such as fuel atomization, the non-uniform fuel particles is sequentially, scan exposure rate m bits using the off-gas of the combustion cylinders of the engine out of the hydrocarbon and carbon monoxide in addition established durability can be know.

[95]

Experiment example 3: operating combustion chamber

[96]

Figure 6 shows a comparison example 1 and also of a fuel is used within a combustion chamber in the embodiment 1 uses a catalyst composition having carbon due to contamination state provided in indicating, in the case of comparison example 1 carbon contaminated revealing the combustion chamber and, in the embodiment 1 in the case of carbon to the combustion chamber not revealing the secret number and wetting ability as a nozzle from clogging billion number, uniformly supplied fuel particles (mist) state and the speed of scan exposure while sprayed through the atomizer, the metal plates being overlapped output high exhaust gas simultaneously mixing the generation and nights.

[97]

Experiment example 4: integrated inspection result

[98]

Bovine, during, a fuel (gasoline or LPG) catalyst composition of large vehicle in the embodiment 1 is installed, a distance (100 ∼ 300Km) travelling through a, plurality of vehicle inspecting office smoke in pre specified traffic safety comonomers (carbon quantity), output, fuel consumption integrated vehicle performance such as inspection result, in the case of said in the embodiment 1, the comparison example 1 uses a catalyst composition than not, an intelligent vehicle exhausts carbon (soot) average 36. 5% reduced and, 19. 7% rod, 14. The output of 7% gliomas and synergistic effect, and to have shown the results of table 2.

[99]

Vehicle (type) Quantity (to) Average flex Fuel Fuel saving rate (average: %) Gas discharged (carbon, soot) (average)
Convection 7 8. 2Via 19. 31(Ps)- 14 - 25% reducing smoke permission criteria contrast output reference contrast. 7% improved
Truck (25t↑)19 5. 117. 45
During, small truck 8 8. 617. 66
Gasoline amount 12 5. 9Gasoline 24. 37, Carbon monoxide (CO) 15 contrast permission criteria. 7% reduction, hydrocarbon (HC) permission criteria contrast 22. 63% reduction, nitrogen oxide (NOX) permission criteria contrast 82. 67% reduction
LPG vehicle 12 4. 9LPG 19. 59

[100]

Experiment example 5

[101]

In the embodiment 1 to embodiment experiments using fuel of catalyst composition including such as his.

[102]

1) exhaust gas

[103]

Vehicle via data analysis results, wherein the 25% exhaust gas opening reference value, in the embodiment 1 uses a catalyst composition of fuel is not high, a measured exhaust gas exhausts has been reduced to 5%.

[104]

2) stability test

[105]

In the embodiment 1 of catalyst composition including fuel air ratio changes by changing the capacity of a constant pressure state and, mixed combustion to be purified point embodiment test result to find a proper size, speed per hour 20km ∼ 150km, very stable without fluctuation in 1500 ∼ 2000rpm has been confirmed.

[106]

3) measuring may be distressing to

[107]

The determination of the noise have for measuring auditory directly, using test result via vehicle, starting after a timed, trembling and noise and it will keep going down, making sure that the 150 km or more even when the acceleration of the speed per hour and enhance settled invariably become trembling and were.



[1]

The present invention relates to a catalyst composition for an internal combustion engine, which includes 2-ethylhexylacetate, polyalkylene glycol, a metal nitrate compound, and polyvinyl alcohol as an ignitability improving agent, thereby improving the ignitability of fuel and improving the fuel efficiency, so as to reduce the smoke of exhaust gas.

[2]

COPYRIGHT KIPO 2017

[3]

[4]

  • (AA) Air cleaner filter
  • (BB) Catalyst composition
  • (CC) Fuel (C_16H_34)(C_8H_18)
  • (DD) Inhalation
  • (EE) Exhaust
  • (FF) Fuel
  • (GG) Air
  • (HH) Mixed gas



2 - ethyl [heyk thread acetate 1 - 50 parts by weight of 100 parts by weight of polyalkylene glycol, metal nitrate compound 1 ∼ 80 parts by weight of polyvinyl alcohol 1 ∼ 70 parts by weight of characterized including catalyst composition for an internal combustion engine.

According to Claim 1, said polyalkylene glycol polyethylene glycol, polypropylene glycol and polybutylene glycol is at least one selected from 1 characterized in that the catalyst composition for an internal combustion engine.

According to Claim 1, characterized in said polyalkylene glycol a weight average molecular weight 3,000 to 50,000 catalyst composition for an internal combustion engine.

According to Claim 1, said polyalkylene glycol is acyl, aldehyde, amine, epoxy [...], ISO at the time of knows sprouting,, american [tu maleimide, knit with phenyl car [lu sees sprouting,, five [lu urination [til d clear statement id, opinion blood drill, writing base hit [ley sprouting, [...], characterized in that at least one [swuk is sour sprouting, [...] and succinic acid substituted 1 during catalyst composition for an internal combustion engine.

According to Claim 1, said metal nitrate compounds, the residual, potassium nitrate, barium nitrate, zinc nitrate, aluminum nitrate, magnesium nitrate, amyl nitrate and nitric acid 1 is at least one selected from manganese characterized catalyst composition for an internal combustion engine.

According to Claim 1, alkane compounds characterized further including catalyst composition for an internal combustion engine.

According to Claim 1, promoting number redox reaction, dispersion number, clean number, customer number, lubricating number, viscosity index improver number, number 1 characterized further including at least one of improved distillate number and oil-based catalyst composition for an internal combustion engine.

According to Claim 7, said redox number is for promoting conversion reaction of platinum, palladium, rhodium, cerium, column other [nem, organic germanium, titanium, silicon, tin, manganese, nickel and silver 1 selected from at least one metal or metal compound which is characterized in that the catalyst composition for an internal combustion engine.

According to Claim 7, said dispersion number is barium, magnesium, calcium, boron, amine, imidazolin, polyalkyl succinimide, polyalkylamine and polyether amine catalyst composition for internal combustion engine characterized in that.

According to Claim 7, said clean number is chosen amongst the vice-reel neel nose [heyk it buys already [tu orgin compounds, poly vice-reel neel amine orgin compounds, surfactants number, polyolefin, polyamine, butadiene styrene copolymer, selected from at least one succinimide and [swuk new already [tu pulley this year 1 is characterized in that the catalyst composition for an internal combustion engine.

According to Claim 7, customer number is said phosphorous, zinc, molybdenum disulfide, ethylene propylene copolymer, market [sway region family s reel [lu amine, selected from at least one fluorine compound and styrene copolymer 1 male [ik s reel [lu is characterized in that the catalyst composition for an internal combustion engine.

According to Claim 7, said lubricating number is polyethylene, benzyl amine, zinc phosphate, neel the [khey which it will know [swuk new it buys, number surfactants, at least one selected from stearic acid and poly polyisobutenyl 1 is characterized in that the catalyst composition for an internal combustion engine.

According to Claim 7, said viscosity index improver number is chosen methacrylate, dimethyl polysiloxane and polyacrylate is selected from at least one characterized in that the catalyst composition for an internal combustion engine 1.

According to Claim 7, said number or mineral oil distillate is ethylene-vinyl acetate copolymer, polyvinyl pyrrolidone, paraffin chloride is selected from at least one phenol condensation water condensation water and naphthalene paraffin chloride 1 characterized in that the catalyst composition for an internal combustion engine.

According to Claim 7, said improved planetary number is a polyphosphoric acid, fat family oh wheat outer reel alcohol, amide, amine is at least one selected from stearic it buys the butyl writing [ley phosphoric acid mono writing scherrer id and triacetyl 1 characterized in that the catalyst composition for an internal combustion engine.