Способ биокаталитической анаэробной трансформации экстрактов из нефти и нефтяных фракций, содержащих химически окисленные соединения серы

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СПОСОБ ПОЛУЧЕНИЯ 4-АМИНО-3-ХИНОЛИНКАРБОНИТРИЛОВ

Изобретение относится с способу получения 4-амино-3-хинолинкарбонитрила, включающему: а) сочетание аминосоединения с цианоуксусной кислотой и кислотным катализатором с получением цианоацетамида; b) конденсирование цианоацетамида со стадии а с анилином, спиртовым растворителем и триалкилортоформиатом с получением 3-амино-2-цианоакриламида и с) сочетание 3-амино-2-цианоакриламида с оксихлоридом фосфора в ацетонитриле, бутиронитриле, толуоле или ксилоле, необязательно в присутствии катализатора, с получением 4-амино-3-хинолинкарбонитрила. Также описывается способ (вариант) получения 4-амино-3-хинолинкарбонитрила, способ получения 7-аминотиено[3,2-b]пиридин-6-карбонитрила и способ получения цианоацетамида. 4 н. и 20 з.п. ф-лы.

СПОСОБ АЛКИЛИРОВАНИЯ, КАТАЛИЗИРУЕМОГО ЖИДКОЙ КИСЛОТОЙ

Изобретение относится к способу катализируемого кислотой алкилирования. Способ включает взаимодействие олефина и изопарафина или ароматического соединения в присутствии жидкокислотного катализатора и поверхностно-активного вещества в зоне реакции алкилирования, работающей в условиях реакции алкилирования, с образованием реакционной смеси, содержащей продукт алкилирования, при этом поверхностно-активное вещество имеет растворимость при 25°C, равную 0,5 мас.% или меньше, в олефине, изопарафине, жидкокислотном катализаторе и продукте алкилирования, причем реакционная смесь содержит фазовую систему типа Winsor III. Бинепрерывная фаза, образующаяся между фазами углеводорода и жидкой кислоты при добавлении поверхностно-активного вещества, облегчает и ускоряет катализируемые жидкой кислотой реакции алкилирования, включая реакцию алкилирования для получения моторного топлива. 1 н. и 8 з. п. ф-лы, 1 ил., 7 пр.

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Гетерогенный катализатор жидкофазного окисления органических соединений

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Катализаторы реакций восстановительного дебромирования бромированных фенолов

Изобретение относится к применению пирилиевых и четвертичных ароматических гетероциклических солей, способных при их восстановлении к образованию при комнатной температуре электроноизбыточных радикалов, используемых в качестве катализаторов реакций восстановительного дебромирования бромированных фенолов. Технический результат изобретения заключается в использовании органических гетероциклических солей в качестве высокоактивных, доступных, экологически безвредных катализаторов для восстановительного дебромирования бромированных фенолов, обеспечивающих протекание процесса дегалоидирования в мягких и пожаробезопасных условиях с возможностью дальнейшего использования продуктов дебромирования. 1 пр.

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Изобретение относится к установке предварительного образования катализатора олигомеризации этилена. Описана установка предварительного образования катализатора олигомеризации этилена, содержащая:первую емкость с первым впускным отверстием для газа, содержащую раствор сокатализатора и модификатора; вторую емкость с вторым впускным отверстием для газа, содержащую соединение хрома и лиганд; смеситель, соединенный трубопроводами с первой и второй емкостями, причем каждый трубопровод имеет клапан-регулятор расхода, который независимо представляет собой тепловой массовый расходомер или расходомер Кориолиса; причем смеситель соединен посредством трубопровода, имеющего клапан-регулятор расхода, с реактором олигомеризации; причем каждое впускное отверстие для газа соединено с первой емкостью и со второй емкостью, и причем первая емкость, вторая емкость, смеситель и клапаны-регуляторы расхода, по меньшей мере частично находятся в корпусе с регулируемой температурой; причем клапаны-регуляторы расхода ...

Способ получения фотокатализатора реакции разложения воды на основе молекулярно-допированного нитрида углерода

Изобретение относится к фотокатализаторам реакции разложения воды на химических производствах, специализирующихся на тонком и основном органических синтезах, а также на предприятиях в области водородной энергетики. Способ получения фотокатализатора реакции разложения воды на основе молекулярно-допированного нитрида углерода, при котором предварительно определяют величину навесок меламина и 4-аминобензо[с][1,2,5]тиадиазола или 4-аминобензо[с][1,2,5]селенадиазола в соответствии с заданными массой фотокатализатора и степенью допирования, навески перетирают до получения гомогенизированной смеси, затем смесь в закрытом крышкой тигле помещают в муфельную печь с инертной атмосферой, нагревают со скоростью 3°С/мин до температуры 550°С, выдерживают в течение одного часа, охлаждают до комнатной температуры, затем полученный материал извлекают из печи, перетирают, засыпают в открытый тигель, помещают в печь и осуществляют повторный нагрев в атмосферном воздухе со скоростью 3°С/мин до температуры 550 ...

СПОСОБ ПОЛУЧЕНИЯ МОНТЕЛУКАСТА И ПРОМЕЖУТОЧНЫЕ СОЕДИНЕНИЯ, ИСПОЛЬЗУЕМЫЕ В НЕМ

Настоящее изобретение относится к способу получения монтелукаста формулы (I), применяемого в качестве ингибитора биосинтеза лейкотриенов для лечения астмы. Способ включает стадии: (а) взаимодействия галогенфосфатного соединения формулы (V) с диольным соединением формулы (IV) в растворителе в присутствии основания с образованием фосфатного соединения формулы (III); и (б) объединения фосфатного соединения формулы (III) с соединением тиокарбоновой кислоты формулы (II) в растворителе в присутствии основания: ! ! ! !где R представляет собой Н или Na; R1 представляет собой Н, метил или этил; R2 представляет собой метил, этил или фенил; Х представляет собой галоген; Y представляет собой серу или кислород. Технический результат - разработка нового способа получения монтелукаста или его натриевой соли высокой степени чистоты с высоким выходом. 2 н. и 9 з.п. ф-лы.

КАТАЛИТИЧЕСКАЯ КОМПОЗИЦИЯ, СПОСОБЫ ЕЕ ПОЛУЧЕНИЯ И ПРИМЕНЕНИЕ В СПОСОБЕ ПОЛИМЕРИЗАЦИИ

Предложены каталитические композиции для полимеризации и способы получения указанных композиций. Описан способ получения каталитической композиции для полимеризации олефинов, включающий: осуществление контакта катализатора на подложке с жирным амином в жидком носителе с образованием суспензии из катализатора на подложке и жирного амина в жидком носителе; причем указанный жирный амин по существу не содержит мелкодисперсного неорганического материала; и высушивание указанной суспензии с образованием по существу свободно сыпучего порошка, и отличающийся тем, что указанный жирный амин представлен формулой (R1)xN(R2OH)y, где R1представляет собой углеводородный радикал, содержащий от 8 до 40 атомов углерода; R2представляет собой углеводородный радикал, содержащий от 1 до 8 атомов углерода; и х принимает значение 1 или 2 и х+у=3; и указанный катализатор на подложке содержит одно или более металлоценовых соединений, выбранных из: (пентаметилциклопентадиенил)(пропилциклопентадиенил)МХ2,(тетраметилциклопентадиенил ...

НОВЫЙ СПОСОБ ПОЛУЧЕНИЯ 3-ФТОРОСОДЕРЖАЩИХ ХИНОЛИНОВ

... 1. Способ получения 3-фторсодержащих хинолинов общей формулы (I) где R1, R2, R3 и R4, идентичные или различные, представляют собой атом фтора; линейный, разветвленный или циклический алкильный радикал, возможно замещенный от одного до трех атомами фтора, группой OR5, в которой R5 представляет собой линейный или разветвленный алкильный радикал, атом водорода или защитную группу гидроксильного радикала; или группой NR'R'', в которой R' и R'', идентичные или различные, представляют собой линейный или разветвленный алкильный радикал, атом водорода или защитную группу аминорадикала; группу OR6, в которой R6 представляет собой атом водорода, защитную группу фенола или линейный или разветвленный алкильный радикал, возможно замещенный от одного до трех атомами фтора, группой OR5 или группой NR'R'', описанными выше; группу NR'1R''1, в которой R'1 и R''1 имеют значения R' и R'' или представляют собой линейный или разветвленный алкильный радикал, замещенный от одного до трех атомами фтора, группой ...

КАТАЛИТИЧЕСКИЕ КОМПОЗИЦИИ ДЛЯ СЕЛЕКТИВНОЙ ДИМЕРИЗАЦИИ ЭТИЛЕНА

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КАТАЛИЗАТОРЫ ДЛЯ ПОЛУЧЕНИЯ АКРИЛОВОЙ КИСЛОТЫ ИЗ МОЛОЧНОЙ КИСЛОТЫ ИЛИ ЕЕ ПРОИЗВОДНЫХ В ЖИДКОЙ ФАЗЕ

Изобретение относится к расплавленному солевому катализатору для получения акриловой кислоты, производных акриловой кислоты или их смесей, содержащему ионную жидкость (ИЖ) и кислоту; причем указанная ИЖ имеет катион фосфония и бромидный анион (Br); при этом указанная кислота растворима в указанной ИЖ и выбрана из группы, состоящей из кислоты Льюиса, кислоты Бренстеда и их смесей; причем указанная кислота Льюиса выбрана из группы, состоящей из CaBr, MgBr, AlBr, CuBrи их смесей; и при этом указанная кислота Бренстеда имеет pKменее 5 в воде при 25 °C. Технический результат заключается в увеличении выхода акриловой кислоты, производных акриловой кислоты или их смесей. 13 з.п. ф-лы, 3 табл., 140 пр.

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Установка, способ и катализатор осушки и очистки газообразного углеводородного сырья от сероводорода и/или меркаптанов

КОМПОЗИЦИЯ, ПРОПИТАННАЯ МАСЛОМ И ПОЛЯРНОЙ ДОБАВКОЙ, ПРИГОДНАЯ В КАТАЛИТИЧЕСКОЙ ГИДРОПЕРЕРАБОТКЕ УГЛЕВОДОРОДОВ, СПОСОБ ИЗГОТОВЛЕНИЯ ТАКОГО КАТАЛИЗАТОРА И СПОСОБ ПРИМЕНЕНИЯ ТАКОГО КАТАЛИЗАТОРА

... 1. Композиция, содержащая: материал носителя, который содержит предшественник активного металла, углеводородное масло и полярную добавку, имеющую дипольный момент, по меньшей мере, 0,45, где массовое отношение упомянутого углеводородного масла к полярной добавке находится в диапазоне вплоть до 10:1 (верхняя граница), и где упомянутый материал носителя затем обрабатывают газом, содержащим водород.2. Композиция, содержащая: материал носителя, содержащий металлический компонент из раствора соли металла, углеводородное масло и полярную добавку, имеющую дипольный момент, по меньшей мере, 0,45, где массовое отношение упомянутого углеводородного масла к полярной добавке находится в диапазоне вплоть до 10:1 (верхняя граница).3. Композиция по п.1 или 2, где упомянутая полярная добавка имеет точку кипения в интервале от 50°С до 275°С.4. Композиция по п.1 или 2, где упомянутую полярную добавку выбирают из группы гетеросоединений, состоящей из гетеросоединений.5. Композиция по п.4, где упомянутая группа ...

СПОСОБ ПОЛУЧЕНИЯ ПРОИЗВОДНЫХ АМИНОБЕНЗОИЛБЕНЗОФУРАНА

... 1. Способ получения производных 5-аминобензоилбензофурана общей формулы:в которой Rозначает водород или алкильную группу, и Rозначает водород, алкильную группу, алкокси или диалкиламиноалкокси, отличающийся тем, что восстанавливают производное 5-нитробензофурана общей формулыв которой Rи Rимеют значения, указанные выше, с помощью агента переноса водорода, в присутствии палладия на угле в качестве катализатора и в простом эфире или смеси простых эфиров в качестве растворителя, что дает желаемые соединения.2. Способ получения производных сульфонамидобензофурана общей формулы:а также их фармацевтически приемлемых солей, в которой Rозначает водород или алкильную группу, Rозначает водород, алкильную группу, алкокси или диалкиламиноалкокси, и Rозначает алкильную группу, отличающийся тем, что:а) восстанавливают производное 5-нитробензофурана общей формулы:в которой Rи Rимеют те же значения, что и раньше, с помощью агента переноса водорода, в присутствии палладия на угле в качестве катализатора ...

Hydrocracken von Schwerölen in Gegenwart einer Eisen-Kohle-Aufschlämmung

VERFAHREN ZUR HERSTELLUNG EINES ALKALIMETALL-LAKTAMSALZES.

Harnstoff-Supersäuresalze und ihre Verwendung als Härtungskatalysatoren für Epoxidharze.

Hochfahrschritte für ionenflüssigkeitskatalysierte Kohlenwasserstoff-Umwandlungsverfahren

Verfahren zum Betreiben einer chloraluminat-ionenflüssigkeitskatalysierten Alkylierungsanlage, wobei das Verfahren umfassta) Entfernen von Luft und freiem Wasser aus mindestens einem Abschnitt der Anlage;b) Einbringen von mindestens einem Reaktanten in den mindestens einen Abschnitt der Anlage;c) Rezirkulieren des mindestens einen Reaktanten durch den mindestens einen Abschnitt der Anlage und zwar über mindestens eine Beschickungstrocknereinheit bis der mindestens eine Reaktant beim Austritt aus dem mindestens einen Abschnitt der Anlage einen Wassergehalt von oder unter einem Schwellenwert etwa 10 ppm aufweist; undd) Einbringen eines Chloraluminat-Ionenflüssigkeitskatalysators in einen Reaktor der Anlage nach Schritt c).

Bis(Trifluoromethanesulfonyl)Ethyl-bearing compound and acid catalyst and method for preparing same

PRODUCING DIETHYLENETRIAMINE

Process for preparing ethylene glycol

Ethylene glycol is prepared by a process in which ethylene oxide is extracted from an aqueous solution with near-critical or super-critical carbon dioxide. Thereafter an ethylene oxide-carbon dioxide-water mixture is contacted with a catalyst to form ethylene carbonate, which is then hydrolyzed to ethylene glycol in the presence of the same catalyst. The ethylene glycol is separated as product and the carbon dioxide and the catalyst are recycled.

Catalysts for the decomposition of lignin, method for the preparation of alcohols and organic acids,methods for the preparation of lignin-decompositi on products, catalysts for the decomposition of aromatic hydrocarbons, method for releasing hydrogenions, as well as porphyrin.

Manufacture of thioethers in liquid phase.

PRODUCTION OF CRYSTALLINE TRIBROMOSTYRENE

CATALYTIC COMPOSITION FOR ALKENE-CARBON MONOXIDE POLYMERISATION

Process for the preparation of dihydropyrrole derivatives

The present invention provides stereoselective processes for the preparation of compounds of formula (I) wherein P is phenyl, naphthyl, a 6-membered heteroaryl group containing one or two nitrogen atoms as ring members, or a 10-membered bicyclic heteroaryl group containing one or two nitrogen atoms as ring members, and wherein the phenyl, naphthyl and heteroaryl groups are optionally substituted; R ...

Hydroisomerization and selective hydrogenation of feedstock in ionic liquid-catalyzed alkylation

A process for producing alkylate comprising contacting a first hydrocarbon stream comprising at least one olefin having from 2 to 6 carbon atoms which contains 1,3-butadiene and 1-butene with a hydroisomerization catalyst in the presence of hydrogen under conditions favoring the simultaneous selective hydrogenation of 1,3-butadiene to butenes and the isomerization of 1-butene to 2-butene and contacting the resulting stream and a second hydrocarbon stream comprising at least one isoparaffin having from 3 to 6 carbon atoms with an acidic ionic liquid catalyst under alkylation conditions to produce an alkylate is disclosed.

Processes and intermediates for making a JAK inhibitor

This invention relates to processes and intermediates for making {1-{1-[3-fluoro-2-(trifluoromethyl)isonicotinoyl]piperidin-4-yl}-3-[4-(7H-pyrrolo[2,3-d]pyrimidin-4-yl)-1H-pyrazol-1-yl]azetidin-3-yl}acetonitrile, useful in the treatment of diseases related to the activity of Janus kinases (JAK) including inflammatory disorders, autoimmune disorders, cancer, and other diseases.

PREPARATION OF ISOBUTENE BY DISSOCIATION OF MTBE

The invention relates to a method for producing isobutene by cracking MTBE, wherein the following steps are carried out: a) MTBE synthesis; reacting isobutene-containing hydrocarbon mixtures (II) with methanol (III), contained in one or more methanol-containing streams (VIII, IX), on acidic ion exchangers obtaining a stream (IV) containing MTBE and TBA, b) MTBE separation; separating a stream (V) containing MTBE and TBA from stream (IV) by means of distillation, c) MTBE cracking; cracking the stream (V) on a heterogenic catalyst in the gas phase, thus obtaining a stream (VI) which contains at least isobutene, methanol, MTBE, water, and optionally TBA, d) isobutene separation; separating the stream (VI) by means of distillation, thus obtaining a stream (VII) containing more than 50 mass % of the amounts of methanol, TBA, and water contained in stream (VI), and a stream (XVII) containing isobutene, e) water separation; separating, water from the stream (VII) to below 1 mass % by means of ...

POLYCARBONATE POLYOL COMPOSITIONS AND METHODS

In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of CO2 and epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having two or more sites that can initiate polymerization. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of -OH end groups and a high percentage of carbonate linkages. The compositions are further characterized in that they contain polymer chains having an embedded polyfunctional moiety linked to a plurality of individual polycarbonate chains.

SOLID ALKYLARYL PHOSPHITE COMPOSITIONS AND METHODS FOR MANUFACTURING SAME

The invention is directed to various alkylaryl phosphite compositions that ideally are suitable for use as secondary antioxidants in polymers. In one aspect, the phosphite composition comprises a tris(monoalkylaryl)phosphite in an amount from 51 to 95 weight percent; and at least one of: a bis(monoalkylaryl)dialkylaryl phosphite; a bis(dialkylaryl)monoalkylaryl phosphite; and a tris(dialkylaryl) phosphite. The inventive phosphite composition is a solid at ambient conditions. The invention also relates to alkylate compositions and processes for forming such alkylate compositions and such phosphite compositions.

MOTOR FUEL ALKYLATION CATALYST AND PROCESS FOR THE USE THEREOF

... "NOVEL MOTOR FUEL ALKYLATION CATALYST AND PROCESS FOR THE USE THEREOF" A novel hydrocarbon alkylation catalyst is disclosed comprising a mineral acid and an ether component. A process for utilizing the novel catalyst is also disclosed.

METHOD FOR PREPARING AZOXYSTROBIN INTERMEDIATES

The present invention provides a method for preparing azoxystrobin intermediates, comprising reacting compound A and dichloropyrimidine in the presence of a trimethylamine catalyst with the addition of a sodium methoxide solution in methanol or the addition of sodium methoxide and methanol separately to produce a mixture of compound B and compound C. Azoxystrobin intermediate compound B and compound C are synthesized from compound A in the present invention, which is catalyzed by using a trimethylamine catalyst, allowing the reaction to have high efficiency and high yield. In addition, the trimethylamine catalyst has a low boiling point and thus can be easily recycled so that the ammoniacal nitrogen content in wastewater can be reduced, and the difficulties and high costs for wastewater processing can be also reduced. The recycled trimethylamine catalyst can be reused in preparing intermediate compound B, which also has a high catalytic effect and can also achieve a high product yield.

METHOD FOR PRODUCING SPIROOXINDOLE DERIVATIVE

The present invention is intended to provide a method for efficiently producing and providing a compound having a spirooxindole skeleton, for example, a compound having a spirooxindole skeleton and having antitumor activity that inhibits the interaction between Mdm2 protein and p53 protein, or an intermediate thereof, using an asymmetric catalyst. A compound having an optically active tricyclic dispiroindole skeleton is efficiently obtained through a catalytic asymmetric 1,3-dipolar cycloaddition reaction using ketimine as a reaction substrate and using a chiral ligand and a Lewis acid.

INTEGRATED BUTANE ISOMERIZATION AND IONIC LIQUID CATALYZED ALKYLATION PROCESSES

Integrated isomerization and ionic liquid catalyzed alkylation processes may comprise integrating ionic liquid alkylation and n-butane isomerization using a common distillation unit for separating an n-butane containing fraction from at least one of an alkylation hydrocarbon phase from an ionic liquid alkylation reactor and an isomerization hydrocarbon stream from an isomerization unit. The n-butane containing fraction may undergo isomerization to provide an isomerization reactor effluent comprising the isomerization hydrocarbon stream. An isobutane containing fraction, separated from at least one of the alkylation hydrocarbon phase and the isomerization hydrocarbon stream, may be recycled from the distillation unit to the ionic liquid alkylation reactor.

COMPOSITIONS AND CATALYST SYSTEMS OF METAL PRECURSORS AND OLEFINIC DILUENTS

A system and method for preparing and using a metal precursor diluent composition are described. The composition includes a metal precursor, and about 18% to about 80 % by weight of an olefinic diluent having between 6 and 18 carbon atoms. Such compositions may be used in oligomerization catalyst systems.

CATALYST FOR THE DECOMPOSITION OF LIGNIN, METHOD FOR THE PREPARATION OF ALCOHOLS AND ORGANIC ACIDS, METHOD FOR THE PREPARATION OF LIGNIN-DECOMPOSITION PRODUCTS, CATALYST FOR THE DECOMPOSITION OF AROMATIC HYDROCARBONS, METHOD FOR RELEASING HYDROGEN TONS, AS WELL AS PORPHYRIN

A catalyst for degrading lignin and a catalyst for degrading an aromatic hydrocarbon, each of which contains a porphyrin. A solution containing an alkali compound is added to lignin, a catalyst for degrading lignin is allowed to act on the resulting lignin-alkali compound solution as needed, which is irradiated with light as needed, or a catalyst for degrading lignin is allowed to act on lignin as needed, which is irradiated with light, whereby alcohols and organic acids are separated. A degradation product generated when the alcohols and organic acids are separated is recovered, and also hydrogen ions are released. A porphyrin having a catalytic function of converting lignin into alcohols and organic acids, a porphyrin having a catalytic function of degrading a compound containing an aromatic hydrocarbon in which an oxygen atom is bound to carbon which forms a benzene ring, or a porphyrin obtained by culturing Escherichia coli that cannot express a gene ypjD (b2611) due to mutation.

NOVEL CATALYST MIXTURES

Catalysts that include at least one catalytically active element and one helper catalyst are disclosed. The catalysts may be used to increase the rate, modify the selectivity or lower the overpotential of chemical reactions. These catalysts may be useful for a variety of chemical reactions including, in particular, the electrochemical conversion of CO2. Chemical processes and devices using the catalysts are also disclosed, including processes to produce CO, OH-, HCO-, H2CO, (HC02)-, H2C02, CH3OH, CH4, C2H4, CH3CH2OH, CH3COO, CH3COOH, C2H6, O2, H2, (COOH)2, or (COO-)2, and a specific device, namely, a CO2 sensor.

ALKYLATION PROCESS USING PHOSPHONIUM-BASED IONIC LIQUIDS

A process for making an alkylate is presented. The process includes mixing an isoparaffin stream with an olefin stream in an alkylation reactor. The alkylation reactor includes a catalyst for performing the reaction. The catalyst is an ionic liquid that is a quaternary phosphonium based ionic liquid, and the reaction is performed at or near ambient temperatures.

NOVEL CATALYST MIXTURES

Catalysts that include at least one catalytically active element and one helper catalyst are disclosed. The catalysts may be used to increase the rate, modify the selectivity or lower the overpotential of chemical reactions. These catalysts may be useful for a variety of chemical reactions including, in particular, the electrochemical conversion of CO2. Chemical processes and devices using the catalysts are also disclosed, including processes to produce CO, OH-, HCO-, H2CO, (HC02)-, H2C02, CH3OH, CH4, C2H4, CH3CH2OH, CH3COO, CH3COOH, C2H6, O2, H2, (COOH)2, or (COO-)2, and a specific device, namely, a CO2 sensor.

Verfahren zur Herstellung von Essigsäure-isopropenylester.

Verfahren zur Herstellung von siliciumorganischen Verbindungen

Process for the preparation of 1-(2-allyloxyphenoxy)-3-isopropyl- amino-2-propanol

... 1-(2-Allyloxyphenoxy)-3-isopropylamino-2-propanol, known for the treatment of cardiovascular disease conditions, e.g. cardiac arrhythmias and elevated blood pressure, of the formula and its salts is prepared by converting the 2,3-dihydroxypropoxy group in the compound of the formula or a salt thereof, into the allyloxy group by reaction with phosphorus triiodide, and, if desired, converting the free compound obtained into a salt or converting a salt obtained into the free compound or another salt.

METHOD FOR PREPARING ETHYLENE GLYCOL.

With double (trifluoromethyl sulfonyl) ethyl compounds and acid catalyst and method of manufacturing the same

Isomerization of an olefin by displacement of the double bond, uses a composition comprising a Bronsted acid and ionic liquid containing an organic cation as catalyst/solvent

Un procédé d'isomérisation de la double liaison des oléfines utilise comme catalyseur et comme solvant une composition comprenant au moins un acide de Bronsted, noté HB, dissous dans un milieu liquide ionique comprenant au moins un cation organique Q+ et un anion A-, cette composition étant telle que lorsque A et B sont identiques, le rapport molaire de l'acide de Bronsted sur le liquide ionique est inférieur à 1/1.

PROCESS OF PRODUCTION OF METHYLIMINOBISDIALKYLACETAMIDE

A METHOD FOR PRODUCING DIETHYLENETRIAMINE FROM THE MONOETHANOLAMINE

NOVEL SELENOPHENE MONOMER AND SYNTHESIS METHOD THEREOF, AND CONJUGATED OLIGOMER SYNTHESIZED FROM SELENOPHENE MONOMER AND SYNTHESIS METHOD THEREOF

The present invention relates to a novel selenophene monomer, and a synthesis method thereof; and a conjugated oligomer synthesized from the selenophene monomer, and a synthesis method thereof. One object of the present invention is to provide a selenophene monomer having a novel structure with a pi-conjugated structure, synthesized from a selenophene derivative, and a synthesis method thereof; and a conjugated oligomer which has desirable electrical characteristics and high solubility in organic solvents, and thus may be applied in various technical fields by synthesizing the novel selenophene monomer in a trimeric form, and a synthesis method thereof. The novel selenophene monomer according to the present invention has a structure that is extremely convenient for use in the synthesis of a conjugated oligomer in a trimeric form or polymerization with various molecules via electrochemical reaction, and thus may be utilized as a monomer capable of readily synthesizing new oligomers or polymers ...

베타 치환 감마 나이트로 다이싸이오에스터 화합물의 합성방법, 이에 의해 제조된 베타 치환 감마 나이트로 다이싸이오에스터 화합물, 이로부터 유도된 신규한 감마아미노산 화합물 및 베타 치환 감마 아미노 부티르산 화합물의 제조방법

... 감마 나이트로 다이싸이오에스터 화합물(γ-nitro dithioester compound)의 합성 방법이 개시된다. 감마 나이트로 다이싸이오에스터 화합물은 물 또는 무기염 수용액 내에서 염기를 포함하는 촉매의 존재 하에 베타 위치에 두 개의 탄소 함유 치환기를 가지는 나이트로 알킨 화합물(β,β-Disubstituted nitroalkene compound)과 다이싸이오말로네이트 화합물(dithiomalonate compound)을 마이클 반응(Michael reaction)시켜 합성될 수 있고, 합성된 감마 나이트로 다이싸이오에스터 화합물은 베타 위치에 두 개의 탄소 함유 치환기를 가진다.

CONTROLLED MORPHOLOGY HIGH ACTIVITY POLYOLEFIN CATALYST SYSTEM

composição útil no hidroprocessamento de uma matéria-prima de hidrocarboneto

Processo para produzir catalisadores fluorados

OLIGOMERIZATION CATALYST SYSTEM AND PROCESS FOR OLIGOMERIZING OLEFINS

... 63Among other things, this disclosure provides an olefin oligomerization system and process, the system comprising; a) a transition metal compound, b) a pyrrole compound having independently-selected Cl to C18 is organyl groups at the 2- and 5-positions, wherein at least one of the organyl group alpha-carbon atoms attached to the 2- and 5-positions of the pyrrole compound is a secondary carbon atoms; and c) a metal alkyl. For example, the 2,5-diethylpyrrole (2,5-DEP)-based catalyst systems can afford a productivity increases over unsubstituted pyrrole catalyst, systems, non-2,5-disubstituted catalyst systems, and 2,5-dimethylpyrrole (2,5-DMP) catalyst systems.(Figure 1) ...

PHOSPHORAMIDITE DERIVATIVES IN THE HYDROFORMYLATION OF UNSATURATED COMPOUNDS

FUNCTIONALIZATION OF ORGANIC MOLECULES USING METAL-ORGANIC FRAMEWORKS (MOFS) AS CATALYSTS

The disclosure provides for catalytic multivariate metal organic frameworks and methods of use thereof.

Encapsulated hydrophilic compounds

The present invention relates to capsules for encapsulating functional agents, such as flavors, fragrances, pharmaceuticals, vitamins, etc. The capsules are suitable for the encapsulation of hydrophobic as well as hydrophilic substances. The capsules include a micro-organism, a matrix component and the encapsulatable material, wherein the latter comprises the functional agent or agents. The invention further relates to a process for manufacturing the capsules and to food products containing the capsules.

METHOD AND SYSTEM FOR FORMING PLUG AND PLAY OXIDE CATALYSTS

An oxide catalyst is formed by vaporizing a quantity of at least one precursor material or catalyst material thereby forming a vapor cloud. The vapor cloud is quenched forming precipitate nanoparticles. The nanoparticles are impregnated onto supports. The supports are able to be used in existing heterogeneous catalysis systems. A system for forming oxide catalysts comprises means for vaporizing a quantity of at least one precursor material or at least one catalyst material, quenching the resulting vapor cloud and forming precipitate nanoparticles. The system further comprises means for supports with the nanoparticles.

Use of tin catalysts for the production of polyurethane coatings

The present invention relates to the use of specific inorganic Sn(IV) for the production of polyisocyanate polyaddition products from a) at least one aliphatic, cycloaliphatic, araliphatic and/or aromatic polyisocyanate, b) at least one NCO-reactive compound, c) at least one thermolatent inorganic tin-containing catalyst, d) optionally further catalysts and/or activators other than c), e) optionally fillers, pigments, additives, thickeners, antifoams and/or other auxiliary substances and additives, wherein the ratio of the weight of the tin from component c) and the weight of component a) is less than 3000 ppm when component a) is an aliphatic polyisocyanate and less than 95 ppm when component a) is an aromatic polyisocyanate, wherein as thermolatent catalysts cyclic tin compounds of formula I, II or III: wherein n>1, are used.

Supported activator

This invention relates to supported activators comprising the product of the combination of an ion-exchange layered silicate, an organoaluminum compound, and a heterocyclic compound, which may be substituted or unsubstituted. This invention further relates to catalyst systems comprising catalyst compounds and such activators, as well as processes to polymerize unsaturated monomers using the supported activators. For the purposes of this patent specification and the claims thereto, the term "activator" is used interchangeably with the term "co-catalyst", the term "catalyst" refers to a metal compound that when combined with an activator polymerizes olefins, and the term "catalyst system" refers to the combination of a catalyst and an activator with or without a support. The terms "support" or "carrier", for purposes of this patent specification, are used interchangeably and are any ion-exchange layered silicates.

СПОСОБЫ ПОЛУЧЕНИЯ КАТАЛИЗАТОРА С ИСПОЛЬЗОВАНИЕМ ГИДРАТИРОВАННЫХ РЕАГЕНТОВ

Данное раскрытие относится к композициям предварительного катализатора. Раскрывается композиция предварительного катализатора для полимеризации олефинов, содержащая: а) носитель из диоксида кремния, содержащий диоксид кремния, в котором количество диоксида кремния находится в диапазоне от 70% мас. до 95% мас. в расчете на общую массу носителя из диоксида кремния, и при этом носитель из диоксида кремния содержит от 0,1% мас. до 20% мас. воды; b) хромсодержащее соединение, в котором количество хрома находится в диапазоне от 0,1% мас. до 5% мас. от количества диоксида кремния; c) титансодержащее соединение, одну или более карбоновых кислот, где количество титана находится в диапазоне от 0,1% мас. до 20% мас. от количества диоксида кремния; и при этом эквивалентное молярное отношение титана в титансодержащем соединении к одной или нескольким карбоновым кислотам находится в диапазоне от 1:1 до 1:4; и d) один или более кислых фенолов, где эквивалентное молярное отношение титансодержащего соединения ...

СПОСОБ ПОЛУЧЕНИЯ 5-(АЛЬФА-ГАЛОГЕНАЦЕТИЛ)-8-(ЗАМЕЩЕННЫЙ ОКСИ)-(1Н)-ХИНОЛИН-2-ОНОВ

Настоящее изобретение относится к способу получения 5-(α-галогенацетил)-8-окси-(1Н)-хинолин-2-онов или их защищенных форм, включающий: (а) взаимодействие (i) 8-гидрокси-(1Н)-хинолин-2-она с ацилирующим агентом и кислотой Льюиса с получением при этом 5-ацетил-8-гидрокси-(1Н)-хинолин-2-она или (ii) 8-гидрокси-(1Н)-хинолин-2-она с ацилирующим агентом с получением при этом 8-ацетокси-(1Н)-хинолин-2-она и обработку in situ(в момент получения) 8-ацетокси-(1Н)-хинолин-2-она кислотой Льюиса с получением при этом 5-ацетил-8-гидрокси-(1Н)-хинолин-2-она; (б) взаимодействие 5-ацетил-8-гидрокси-(1Н)-хинолин-2-она, полученного на стадии (а), с соединением формулы RL в присутствии основания и растворителя с получением при этом 5-ацетил-8-окси-(1Н)-хинолин-2-она или его защищенной формы, где R означает защитную группу и L означает отщепляемую группу, и (в) взаимодействие 5-ацетил-8-окси-(1Н)-хинолин-2-она или его защищенной формы с галогенирующим агентом в присутствии растворителя с получением при этом ...

ИОННАЯ ЖИДКОСТЬ, АДДУКТ И СПОСОБЫ ИХ ПОЛУЧЕНИЯ

Изобретение относится к способу получения ионной жидкости. Способ включает следующие стадии: a) приведение по меньшей мере одного акцептора электронной пары в контакт с по меньшей мере одним донором электронной пары с образованием аддукта, причем молярное соотношение акцептора электронной пары и донора электронной пары варьируется приблизительно от 1:1 до 1:5, при этом донор электрона выбран из группы, включающей в себя фосфин, амид, алкилсульфоксид, сложный эфир и спирт, или любую их комбинацию; и b) приведение аддукта в контакт с по меньшей мере одним акцептором электронной пары с получением ионной жидкости, причем молярное соотношение аддукта и акцептора электронной пары варьируется приблизительно от 1:1 до 1:6. Также предложены способ получения аддукта, ионная жидкость, аддукт и применение ионной жидкости. Изобретение позволяет упростить способ получения ионной жидкости. 5 н.п. и 10 з.п. ф-лы, 17 пр.

КОМПЛЕКС ИОННАЯ ЖИДКОСТЬ-РАСТВОРИТЕЛЬ, ЕГО ПРИГОТОВЛЕНИЕ И ПРИМЕНЕНИЯ

Настоящее изобретение относится к комплексу ионная жидкость - растворитель, содержащему катионы и анионы и приготовленному в присутствии растворителя, к способу получения комплекса ионная жидкость - растворитель, а также к способу получения линейного алкилбензола, с использованием комплекса ионная жидкость - растворитель. Комплекс ионная жидкость - растворитель, для катализирования реакций, представлен формулой I, [UMX]S, в которой [UMX] представляет собой ионную жидкость, а S представляет собой органический растворитель; в которой U представляет собой катион, выбранный из группы, содержащей амид, фосфин и окись фосфина; [MX] представляет собой анион; в котором M представляет собой металл, выбранный из группы, содержащей Al, Fe, Zn, Mn, Mg, Ge, Cu и Ni; X представляет собой галоген, выбранный из группы, содержащей F, Cl, Br и I; а i и j представляют собой величины от 1 до 6. Способ получения комплекса ионная жидкость - растворитель содержит действия: a) добавление органического растворителя ...

УСОВЕРШЕНСТВОВАННАЯ ПРОКАТАЛИТИЧЕСКАЯ КОМПОЗИЦИЯ И СПОСОБ ЕЕ ПОЛУЧЕНИЯ

Изобретение относится к катализаторам полимеризации олефинов. Заявлен способ галогенирования предшественника прокатализатора полимеризации олефинов, который включает галогенирование предшественника прокатализатора в присутствии замещенного ароматического фенилендиэфира при температуре, от приблизительно 90°C до менее чем или равной приблизительно 100°C. Ароматический фенилендиэфир имеет структуру (I)в которой группы R-Rявляются одинаковыми или различными, каждая группа из R-Rвыбрана из группы, состоящей из атома водорода, галогена, углеводородной группы, содержащей от 1 до 20 атомов углерода, и алкоксигруппы, содержащей от 1 до 20 атомов углерода, и их сочетаний, и где по меньшей мере одна из групп R-Rне является водородом. Прокаталитическая композиция Циглера-Натта имеет индекс селективности менее 2,5 и включает магниевый компонент, титановый компонент и замещенный ароматический фенилендиэфир. Заявлена также прокаталитическая композиция, полученная указанным способом. Настоящие прокаталитические ...

СПОСОБ ПОЛУЧЕНИЯ ФТОРИРОВАННЫХ КАТАЛИЗАТОРОВ

В настоящем изобретении описан способ получения фторированного каталитически активного соединения, каталитических композиций, и способов полимеризации, включающих такое соединение. Способ получения фторированного каталитически активного соединения включает контактирование металлоценового компонента катализатора с фторированной неорганической солью, в течение времени, достаточного для получения фторированного металлоценового компонента катализатора, такого как описанный в следующем примере: где R представляет собой замещающие группы, выбранные из группы, включающей алкилы C1-С10 в конкретном предпочтительном варианте, р представляет собой 0 или целое число от 1 до 5. Фторированную неорганическую соль в конкретном предпочтительном варианте описывают как соединение, которое генерирует фторид-ионы при контактировании с разбавителем, по крайней мере на 50 мас.% состоящем из воды. Технический результат - увеличение выхода продукта, высокая производительность фторированного каталитически активного ...

ПОЛУЧЕНИЕ ЗАМЕЩЕННЫХ ФЕНИЛЕН АРОМАТИЧЕСКИХ СЛОЖНЫХ ДИЭФИРОВ

Изобретение относится к способу получения 5-трет-бутил-3-метил-1,2-фенилен дибензоата, включающему взаимодействие в реакционных условиях 5-трет-бутил-3-метилкатехина (ВМС) с триэтиламином и соединением, выбранным из группы, состоящей из ароматической карбоновой кислоты и производного ароматической карбоновой кислоты, где производное ароматической карбоновой кислоты представляет собой ароматический ацилгалогенид, ароматический ангидрид, соль ароматической карбоновой кислоты или любую их комбинацию; и где ароматическая карбоновая кислота представляет собой бензойную кислоту; и образование композиции, содержащей 5-трет-бутил-3-метил-1,2-фенилен дибензоат (BMPD). Также разработаны пути получения синтетического предшественника 5-трет-бутил-3-метил-1,2-фенилен дибензоата. Этот предшественник представляет собой 5-трет-бутил-3-метилкатехин. Простой и экономичный способ позволяет получить продукт со значительным выходом. 9 з.п. ф-лы, 2 ил., 6 пр.

УДАРОПРОЧНЫЙ ПРОПИЛЕНОВЫЙ СОПОЛИМЕР И СПОСОБ ЕГО ПОЛУЧЕНИЯ

Изобретение относиться к способу получения ударопрочного пропиленового сополимера с низким содержанием летучих органических соединений, композиции на основе ударопрочного пропиленового сополимера и изделия на его основе. Способ включает контактирование, в условиях полимеризации, пропилена с каталитической композицией, в состав которой входит замещенный 1,2-ароматический фенилендиэфир, в первом реакторе полимеризации. Образованный в первом реакторе активный полимер на основе пропилена контактирует в условиях полимеризации во втором реакторе, по меньшей мере, с одним олефином. При этом образованный во втором реакторе ударопрочный пропиленовый сополимер содержит замещенный 1,2-ароматический фенилендиэфир. Полученный по изобретению ударопрочный пропиленовый сополимер обладает высокой скоростью истечения расплава и низким содержанием летучих соединений. 3 н. и 7 з.п. ф-лы, 4 табл.

ПОЛИМЕР НА ПРОПИЛЕНОВОЙ ОСНОВЕ, ИЗДЕЛИЯ И СПОСОБ ИХ ПОЛУЧЕНИЯ

Изобретение относится к композиции полимеров на пропиленовой основе и способу их получения. Способ полимеризации включает введение пропилена и необязательно по меньшей мере одного другого олефина в условиях проведения полимеризации в контакт с композицией катализатора, содержащей замещенный фениленароматический сложный диэфир. Получение полимера на пропиленовой основе, характеризующегося модулем упругости при изгибе, большим чем 260 кфунт/дюйм(1793 МПа) согласно определению в соответствии с документом ASTM D 790. Полимерная композиция для получения формованных изделий содержит пропиленовый гомополимер, характеризующийся модулем упругости при изгибе, большим чем 260 кфунт/дюйм(1793 МПа) согласно определению в соответствии с документом ASTM D 790, и замещенный фениленароматический сложный диэфир, выбранный из группы, состоящей из замещенного 1,2-фенилендибензоата, 3-метил-5-трет-бутил-1,2-фенилендибензоата и 3,5-диизопропил-1,2-фенилендибензоата. Технический результат - использование улучшенной ...

СПОСОБ ПОЛУЧЕНИЯ КАТАЛИЗАТОРА ДЕПЕРОКСИДИРОВАНИЯ

Изобретение относится к способу получения катализатора депероксидирования алкилгидропероксида, содержащего хром в состоянии окисления 6+ в качестве основного каталитического элемента. Предлагаемый способ включает следующие этапы: растворение в воде хромового ангидрида; добавление к водному раствору хромового ангидрида третичного спирта, содержащего по меньшей мере 4 атома углерода и углеводородный растворитель; осуществление реакции спирта и хромового ангидрида при температуре от 20 до 40°C путем помещения реакционной среды в условия пониженного давления, чтобы отогнать воду; извлечение катализатора в виде сложного эфира хромовой кислоты в растворе углеводородного растворителя. Данный способ позволяет получать стабильный раствор катализатора депероксидирования алкилгидропероксида с очень хорошей производительностью и высоким выходом. 14 з.п. ф-лы, 3 пр.

САМООГРАНИЧИВАЮЩАЯСЯ КАТАЛИТИЧЕСКАЯ СИСТЕМА С РЕГУЛИРУЕМЫМ СООТНОШЕНИЕМ АЛЮМИНИЯ И SCA И СПОСОБ

Настоящее изобретение относится к стереоселективым композициям на основе катализатора Циглера-Натта и реакции полимеризации с их использованием. Описана каталитическая композиция, включающая одну или несколько композиций прокатализатора Циглера-Натта, содержащих одно или несколько соединений переходных металлов и один или несколько внутренних доноров электронов в виде эфиров ароматической дикарбоновой кислоты; один или несколько алюминийсодержащих сокатализаторов; агент для контроля за селективностью (SCA), включающий смесь (i) первого алкоксисилана и второго алкоксисилана и (ii) сложного эфира С-С-алифатической кислоты; и молярное соотношение алюминия и суммарного SCA составляет от 0,5:1 до 4:1. Технический эффект - каталитическая композиция улучшает продуктивность полимеризации и норму выработки полимера. Каталитическая композиция является самозатухающей. 8 з.п. ф-лы, 15 табл., 10 ил.

Pt-СОДЕРЖАЩАЯ РЕГЕНЕРИРУЕМАЯ КАТАЛИТИЧЕСКАЯ СИСТЕМА И СПОСОБ ГИДРОСИЛИЛИРОВАНИЯ НЕПРЕДЕЛЬНЫХ СОЕДИНЕНИЙ С ЕЁ ИСПОЛЬЗОВАНИЕМ

Изобретение относится к каталитической химии. Предложена регенерируемая Pt-содержащая каталитическая система для гидросилилирования непредельных соединений, состоящая из платинового предкатализатора, выбранного из PtCl2, K2PtCl4, K[(H2C=CH2)PtCl3], PtCl4, H2PtCl6, K2PtCl6, Pt(PPh3)4, Pt2(dvtms)3, и полиола, такого как этиленгликоль, полиэтиленгликоль или глицерин, получаемая смешиванием предкатализатора и полиола при 20-60°С и интенсивном перемешивании на воздухе при атмосферном давлении. Также изобретеение относится к способу гидросилилирования непредельных соединений с использованием Pt-содержащей каталитической системы. Технический результат - создание регенерируемой Pt-содержащей каталитической системы для гидросилилирования, активность которой превышает активность аналогов не менее, чем в 103-104 раз, сокращение времени и снижение температуры гидросилилирования широкого круга непредельных соединений. 2 н.п. и 4 з.п. ф-лы, 3 таб., 94 пр.

КАТАЛИТИЧЕСКАЯ КОМПОЗИЦИЯ, СПОСОБЫ ПОЛУЧЕНИЯ И ПРИМЕНЕНИЕ В СПОСОБЕ ПОЛИМЕРИЗАЦИИ

Предложены каталитические композиции для полимеризации и способы получения указанных композиций. Описана каталитическая композиция, содержащая по меньшей мере один катализатор полимеризации на подложке, причем указанная каталитическая композиция модифицирована по меньшей мере одним жирным амином, причем указанный жирный амин содержит менее 2% по массе мелкодисперсного неорганического материала, причем указанный по меньшей мере один жирный амин представлен формулой : (R)N(ROH)где Rпредставляет собой углеводородный радикал, содержащий от 8 до 40 атомов углерода; Rпредставляет собой гидрокарбиленовый бирадикал, содержащий от 1 до 8 атомов углерода; и х принимает значение 1 или 2 и х+у=3; и причем указанный катализатор на подложке содержит одно или более металлоценовых соединений, выбранных из: (пентаметилциклопентадиенил)(пропилциклопентадиенил)МХ, (тетраметилциклопентадиенил)(пропилциклопентадиенил)МХ,(тетраметилциклопентадиенил)(бутилциклопентадиенил)МХ, MeSi(инденил)МХ,MeSi(тетрагидроинденил ...

КАТАЛИТИЧЕСКИЕ КОМПОЗИЦИИ ДЛЯ СЕЛЕКТИВНОЙ ДИМЕРИЗАЦИИ И ПОЛИМЕРИЗАЦИИ ЭТИЛЕНА

Изобретение относится к каталитической композиции для полимеризации алкена, включающей: титанат формулы Ti(OR), где все R одинаковые или разные и каждый R обозначает углеводородный остаток, где углеводородный остаток представляет собой алкильную группу или арильную группу; модификатор катализатора на основе простого эфира и алюминоксан, при этом алюминоксан представляет собой метилалюминоксан, модифицированный метилалюминоксан или комбинацию, их содержащую, и дополнительное алюминийорганическое соединение, которое отличается от метилалюминоксана и от модифицированного метилалюминоксана, где модифицированный метилалюминоксан представляет собой сополимер, содержащий повторяющиеся звенья MeAlO и повторяющиеся звенья RAlO, где Rобозначает Суглеводородный остаток. Также изобретение относится к способу получения полимера. Используемый катализатор обладает улучшенной жизнеспособностью и временем инициирования. 2 н. и 12 з.п. ф-лы, 3 пр., 3 табл., 2 ил.

Применение материала на основе безметального электрокатализатора для получения молекулярного водорода из воды в присутствии органических солей

Изобретение относится к применению материала на основе безметального электрокатализатора, представляющего собой акридин, 9-фенил-акридин или N-метил-9-фенилакридин, адсорбированный на углеродном материале, для получения молекулярного водорода из воды в присутствии органических солей. Используемый материал является синтетически доступным и термодинамически устойчивым. 5 ил., 1 табл.

СПОСОБ КАРБОНИЛИРОВАНИЯ С ДОБАВЛЕНИЕМ ПРОСТРАНСТВЕННО-ЗАТРУДНЕННЫХ ВТОРИЧНЫХ АМИНОВ

... 1. Способ карбонилирования, в соответствии с которым по меньшей мере одно карбонилируемое монооксидом углерода соединение взаимодействует с монооксидом углерода в присутствии комплексного катализатора металла VIII побочной группы Периодической системы элементов, содержащего в качестве лиганда фосфорорганическое соединение, отличающийся тем, что карбонилирование осуществляют в присутствии пространственно-затрудненного вторичного амина, обладающего общей структурной формулой (I): ! , ! в которой Ra, Rb, Rc, Rd, Re и Rf означают одинаковые или разные углеводородные остатки, которые могут быть соединены друг с другом. ! 2. Способ по п.1, отличающийся тем, что в качестве вторичного амина используют амин со структурой 2,2,6,6-тетраметилпиперидина (II): ! . ! 3. Способ по п.1 или 2, отличающийся тем, что в качестве вторичного амина используют по меньшей мере одно из соединений со структурными формулами (IIb)-(IIg): ! , ! ! с n, означающим число от 1 до 20, ! , ! ! с n, означающим число от 1 до ...

ИОННЫЕ ЖИДКОСТИ НА ФОСФОНИЕВОЙ ОСНОВЕ И КАТАЛИЗАТОРЫ АЛКИЛИРОВАНИЯ, ИХ СОДЕРЖАЩИЕ

... 1. Галогеналюминатное соединение четвертичного фосфония формулы (I)(I)в которой R-Rпредставляют собой одинаковые алкильные группы,Rотличается от R-Rи выбран из С-Салкилов; аX представляет собой галоген.2. Соединение формулы (I) по п. 1, отличающееся тем, что каждый из R-Rпредставляет собой С-Салкил.3. Соединение формулы (I) по п. 2, отличающееся тем, что каждый из R-Rсодержит 4 атома углерода.4. Соединение формулы (I) по п. 1, отличающееся тем, что Rсодержит от 5 до 8 атомов углерода.5. Соединение формулы (I) по п. 4, отличающееся тем, что Rпредставляет собой гексил.6. Соединение формулы (I) по любому из п.п. 1-5, отличающееся тем, что его выбирают из группы, состоящей из трипропилгексилфосфоний-AlX, трибутилпентилфосфоний-AlX, трибутилгексилфосфоний-AlX, трибутилгептилфосфоний-AlX, трибутилоктилфосфоний-AlX, трибутилнонилфосфоний-AlX, трибутилдецилфосфоний-AlX, трибутилундецилфосфоний-AlXи трибутилдодецилфосфоний-AlX, где X выбирают из группы, состоящей из F, Cl, Br и I.7. Соединение формулы ...

ОЛИГОМЕРИЗАЦИЯ АЛЬФА-ОЛЕФИНОВ С ПРИМЕНЕНИЕМ КАТАЛИТИЧЕСКИХ СИСТЕМ МЕТАЛЛОЦЕН-ТСК И ПРИМЕНЕНИЕ ПОЛУЧЕННЫХ ПОЛИАЛЬФАОЛЕФИНОВ ДЛЯ ПОЛУЧЕНИЯ СМАЗЫВАЮЩИХ СМЕСЕЙ

... 1. Способ олигомеризации, включающий:a) осуществление контакта C-Сальфа-олефинового мономера с каталитической системой, содержащей:1) металлоцен,2) первый активатор, содержащий химически обработанный твердый оксид; и3) второй активатор, содержащий алюминийорганическое соединение формулы Al(Х)(Х)где Xнезависимо представляет собой С-Сгидрокарбил, Xнезависимо представляет собой галогенид, гидрид или С-Сгидрокарбоксид, а n представляет собой число от 1 до 3; иb) образование олигомерного продукта в условиях олигомеризации.2. Способ олигомеризации по п.1, отличающийся тем, что указанный металлоцен содержит металлоцен формулы XXXXM, гдеМпредставляет собой Ti, Zr, Hf, V, Nb, Ta, Cr, Mb или W,Xи Xпредставляют собой замещенные или незамещенные пи-связанные η-лиганды возможно соединенные связывающей группой, иXи Xнезависимо представляют собой галогенид гидрид С-Сгидрокарбоксид С-Сгидрокарбил или С-Cтригидрокарбилсилокси.3. Способ олигомеризации по п.1, отличающийся тем, что указанный металлоцен имеет ...

КОМПОЗИЦИЯ КАТАЛИЗАТОРА СО СМЕШАННЫМ АГЕНТОМ, РЕГУЛИРУЮЩИМ СЕЛЕКТИВНОСТЬ, И СПОСОБ ПОЛИМЕРИЗАЦИИ, ИСПОЛЬЗУЮЩИЙ ЕЕ

... 1. Композиция катализатора, включающая: ! композицию прокатализатора Циглера-Натта, содержащую титан, магний и внутренний донор электронов; ! сокатализатор и ! смешанный внешний донор электронов (С-ВДЭ), включающий агент, ограничивающий активность (АОА), первый агент, регулирующий селективность (АРС1), который содержит алкоксисилан, и второй агент, регулирующий селективность (АРС2), выбираемый из группы, состоящей из алкоксисилана, простого диэфира и диалкоксибензола, причем молярное соотношение АРС1:АРС2 составляет от 0,1:1 до 1,0:1, молярное отношение между совокупного АРС к АОА составляет менее чем 1,0, и композиция катализатора представляет собой самоограничивающуюся композицию катализатора. ! 2. Композиция катализатора по п.1, где АРС1 включает соединение, выбираемое из группы, состоящей из диметоксисилана, диметоксисилана, имеющего, по меньшей мере, одну вторичную алкильную группу, диметоксисилана, имеющего, вторичную аминогруппу, непосредственно связанную с атомом кремния, и их комбинаций ...

СПОСОБ ПОЛУЧЕНИЯ КАТАЛИТИЧЕСКОЙ КОМПОЗИЦИИ ДЛЯ ОЛИГОМЕРИЗАЦИИ ЭТИЛЕНА И СООТВЕТСТВУЮЩЕЕ УСТРОЙСТВО ДЛЯ ПРЕДВАРИТЕЛЬНОГО ПОЛУЧЕНИЯ КАТАЛИТИЧЕСКОЙ КОМПОЗИЦИИ

... 1. Способ получения каталитической композиции для олигомеризации этилена, содержащий стадии:a) получения первого раствора в первом растворителе путем смешивания со-катализатора и модификатора, где со-катализатор выбирают из триалкилалюминия, алкил алюминий сесквихлорида, диалкилалюминий хлорида, алкилалюминий дихлорида, где алкил предпочтительно представляет собой метил, этил, изопропил или изобутил, метилалюмоксана (MAO) или их смесей, и где модификатор выбирают из аммониевых или фосфониевых солей типа [HE]X, [HER]X, [HER]Х, [HER]Х или [ER]Х или HX или RX, где E=N или P, X=Cl, Br или I, a R = алкил, циклоалкил, ацил, арил, алкенил, алкинил или соответствующие мостиковые ди-, три- или полифрагменты, либо аммониевые или фосфониевые соли на основе циклических аминов;b) добавления к первому раствору, полученному на стадии a), соединения хрома и лиганда с получением второго раствора; иc) необязательно, перемешивания второго раствора, полученного на стадии b) в течение промежутка времени продолжительностью ...

СПОСОБ АЛКИЛИРОВАНИЯ ПРИ ИСПОЛЬЗОВАНИИ ИОННЫХ ЖИДКОСТЕЙ НА ФОСФОНИЕВОЙ ОСНОВЕ

... 1. Способ алкилирования изопарафинов, включающий:пропускание изопарафина, содержащего от 2 до 10 атомов углерода, в реактор алкилирования; ипропускание олефина, содержащего от 2 до 10 атомов углерода, в реактор алкилирования, где реактор алкилирования функционирует в условиях проведения реакции и содержит катализатор в виде ионной жидкости на фосфониевой основе для проведения реакции между олефином и изопарафином с получением алкилата, где ионная жидкость на фосфониевой основе представляет собой галогеналюминат четвертичного фосфония, который содержит органический катион на фосфониевой основе и неорганический анион и обладает структурой в форме PhR1R2R3R4, где R1, R2 и R3 включают идентичные алкильные группы, а алкильная группа R4 содержит, по меньшей мере, на 1 атом углерода больше, чем алкильная группа R1.2. Способ по п. 1, где ионную жидкость на фосфониевой основе выбирают из группы, состоящей из трибутилгексилфосфоний-AlHa, трипропилгексилфосфоний-AlHa, трибутилметилфосфоний-AlHa, трибутилпентилфосфоний-AlHa ...

УСОВЕРШЕНСТВОВАННАЯ ПРОКАТАЛИТИЧЕСКАЯ КОМПОЗИЦИЯ И СПОСОБ ЕЕ ПОЛУЧЕНИЯ

... 1. Способ, включающий:галогенирование предшественника прокатализатора в присутствии замещенного ароматического фенилендиэфира при температуре менее 115°C; иобразование прокаталитической композиции с индексом селективности менее 2,5.2. Способ по п.1, включающий галогенирование предшественника прокатализатора при температуре от приблизительно 90°C до менее чем или равной приблизительно 100°C.3. Способ по п.1, включающий образование прокаталитической композиции, содержащей от приблизительно 0 мас.% до приблизительно 2,3 мас.% продукта разложения.4. Способ, включающий:первое галогенирование предшественника прокатализатора в присутствии замещенного ароматического фенилендиэфира с образованием промежуточного прокатализатора;второе галогенирование промежуточного прокатализатора при второй температуре, превышающей первую температуру; иобразование прокаталитической композиции с индексом объемной плотности от приблизительно 0,28 до приблизительно 0,5.5. Способ по п.4, включающий получение частиц ...

СПОСОБЫ РЕЦИРКУЛЯЦИИ КАТАЛИТИЧЕСКИХ КОМПОЗИЦИЙ ДЛЯ ГАЛОГЕНИРОВАНИЯ АРОМАТИЧЕСКОГО КОЛЬЦА

... 1. Способ извлечения и повторного использования катализатора галогенирования в цикле, включающий (А) приведение в контакт ароматического соединения с хлором или бромом в присутствии каталитической композиции, содержащей, по меньшей мере, одну соль, содержащую металл группы 4-13, металл лантаноид или металл актиноид и, по меньшей мере, один органический противоион, образованный от органической кислоты с рКа относительно воды 0 или выше, и, по меньшей мере, одно сероорганическое соединение, с образованием первой смеси продуктов, содержащей монохлорированное или монобромированное ароматическое соединение и галогенид металла группы 4-13, галогенид металла лантаноида или галогенид металла актиноида; (В) выделение указанного галогенида металла из указанной первой смеси продуктов; и (С) приведение в контакт, по меньшей мере, части указанного галогенида металла и ароматического соединения с хлором или бромом и, по меньшей мере, одним сероорганическим соединением с образованием второй смеси продуктов ...

СПОСОБ ПОЛУЧЕНИЯ ДИГИДРОПИРРОЛЬНЫХ ПРОИЗВОДНЫХ

... 1. Способ получения соединения формулы Iгде Р представляет собой фенил, нафтил, 6-членную гетероарильную группу, содержащую один или два атома азота в качестве кольцевых членов, или 10-членную бициклическую гетероарильную группу, содержащую один или два атома азота в качестве кольцевых членов, и где фенил, нафтил и гетероарильные группы необязательно замещены;Rпредставляет собой хлордифторметил или трифторметил;Rпредставляет собой необязательно замещенный арил или необязательно замещенный гетероарил;n равно 0 или 1;включающий(a-i) реакцию соединения формулы IIгде P, Rи Rявляются таковыми, как определено для соединения формулы I;с нитрометаном в присутствии хирального катализатора для получения соединения формулы IIIгде P, Rи Rявляются таковыми, как определено для соединения формулы I; и(a-ii) восстановительную циклизацию соединения формулы III для получения соединения формулы I; или(b-i) реакцию соединения формулы IIгде P, Rи Rявляются таковыми, как определено для соединения формулы I;с ...

KATALYTISCHER KONDENSATIONSPROZESS FUER ORGANISCHE CARBONSAEUREANHYDRIDE.

PORÖSES ORGANISCH/METALLISCHES VERBUNDMATERIAL

Verfahren zur Herstellung von ungesättigten Ethern.

Startup procedures for ionic liquid catalyzed hydrocarbon conversion processes

Methods for starting and operating ionic liquid catalyzed hydrocarbon conversion processes and systems to provide maximum process efficiency, system reliability and equipment longevity may include: purging air and free water from at least a portion of the system; introducing at least one reactant into the at least a portion of the system; and re-circulating the at least one reactant through the at least a portion of the system, via at least one feed dryer unit, until the at least one reactant exiting the at least a portion of the system has a water content at or below a threshold value, prior to the introduction of an ionic liquid catalyst and/or additional reactant(s) and feeds into the system.

PRODUCTION OF MONOCARBOXYLIC ACIDS

... 1276326 Carbonylation catalysts MONSANTO CO 15 Aug 1969 [15 Aug 1968] 40884/69 Addition to 1234641 Heading B1E [Also in Division C2] Catalysts comprising rhodium or iridium compounds with halogens or halogen containing substances as promotors are used in the preparation of monocarboxylic acids or esters by reacting carbon monoxide with an alcohol or halide (see Division C2). The catalyst may be in solution (liquid phase operation) or solid (vapour phase operation). The halogen may be present as a salt or co-ordination compound of the rhodium and iridium or supplied as hydrogen, alkyl, aryl, metal, ammonium, phosphonium, arsonium and stibonium halides. Inert supports such as alumina, activated carbon, clays, silica-alumina ceramics are used. Examples describe the use of rhodium chloride, [Rh(CO) 2 Cl 2 ) 2 , [Ir(CO) 2 Cl] 2 , [Rh(CO) 2 Br] 2 and Rh(PÏ 3 ) 3 Cl with hydrogen iodide as promotor, Rh(P° 3 ) 2 CoCl with methyl iodide and Rh(NO 3 ) 3 .2H 2 O with calcium iodide as promotor, and ...

PROCEDURE FOR THE PRODUCTION OF PARTIAL HYDROLYSATES OF METAL-ORGANIC CONNECTIONS OR TRANSITION METAL CATALYSTS IMMOBILIZED ON INERT SUBSTRATES

DOUBLE METAL CYANIDE CATALYSTS (DMC) WITH KRONENETHERN, PROCESS TO YOUR PRODUCTION AND USES

A PROCEDURE FOR the PRODUCTION OF 5 (HALO ACETYL) - 8 (SUBSTITUTED OXY) - (1H) - CHINOLIN-2-ONEN

VERFAHREN ZUR HERSTELLUNG DES 1-(2-ALLYLOXYPHENOXY)-3-ISOPROPYLAMINO-2-PROPANOLS UND SEINER SALZE

PROCEDURE FOR THE PRODUCTION OF GLYCIDYLESTERN

Antistaining sheet

Disclosed is an antistaining sheet including a base material sheet and an antistaining layer formed on the base material sheet. The antistaining layer includes a photocatalyst and a thermoplastic resin to be decomposed by the photocatalyst, and thus has a self-collapsing property. The antistaining layer is stronger in self-collapsing property in the surface portion thereof than in the interior portion.

Intermediates in the enantioselective synthesis of 3-(aminomethyl)-5-methyl-hexanoic acid

(S)-(+)-3-(aminomethyl)-5-methyl-hexanoic acid or (S)-pregabalin is an anticonvulsive drug. In addition to its use as an anticonvulsive agent, pregabalin has also been indicated as a medicament in the treatment of anxiety, neuropathic pain and pain in patients with fibromyalgia. Provided herein are thioester intermediates in the synthesis of and processes for the synthesis of 3-(aminomethyl)-5-methyl-hexanoic acid in the (R) or (S) configuration.

Organic chlorohydrosilane and method for preparing them

Provided is an organic chlorohydrosilane, a useful starting material for preparing silicon polymers and a method for preparing the same. More particularly, the present invention enables the synthesis of various novel organic chlorohydrosilanes in high yield by an exchange reaction between an Si—H bond of a chlorosilane which can be obtained in an inexpensive and easy manner and an Si—Cl bond of an another organic chlorosilane using a quaternary organic phosphonium salt compound as a catalyst. Since the catalyst can be recovered after its use and reused, the present invention is very economical and thus effective for mass-producing silicon raw materials.

Solution polymerization process and procatalyst carrier systems useful therein

A procatalyst carrier system which includes one or more paraffinic solvents, one or more paraffin-insoluble procatalysts, and optionally one or more cocatalysts wherein the carrier system is in the form of a slurry is provided. Also provided is a process including selecting one or more paraffin-insoluble organometallic procatalysts; adding the one or more procatalysts to a sufficient quantity of paraffinic solvent to form a slurry of the one or more procatalysts in the paraffinic solvent; introducing one or more first cocatalysts into a polymerization reactor; and introducing the slurry into the polymerization reactor; a reaction product of the process and articles made from the reaction product.

Imprinted Biomimetic Catalysts for Cellulose Hydrolysis

The present disclosure describes methods and biomimetic catalysts useful for hydrolyzing glucose polymers, such as cellulose, and oligomers, such as cellobiose, to glucose for the subsequent production of ethanol.

Process for the dehydration of aqueous bio-derived terminal alcohols to terminal alkenes

A method and apparatus for dehydrating bio-1-alcohols to bio-l-alkenes with high selectivity. The bio-1-alkenes are useful in preparing high flashpoint diesel and jet biofuels which are useful to civilian and military applications. Furthermore, the bio-1-alkenes may be converted to biolubricants useful in the transporation sector and other areas requiring high purity/thermally stable lubricants.

Oil and polar additive impregnated composition useful in the catalytic hydroprocessing of hydrocarbons, a method of making such catalyst, and a process of using such catalyst

A composition that comprises a support material having incorporated therein a metal component and impregnated with both hydrocarbon oil and a polar additive. The composition that is impregnated with both hydrocarbon oil and polar additive is useful in the hydrotreating of hydrocarbon feedstocks, and it is especially useful in applications involving delayed feed introduction whereby the composition is first treated with hot hydrogen, and, optionally, with a sulfur compound, prior to contacting it with a hydrocarbon feedstock under hydrodesulfurization process conditions.

Method for producing formic acid

An object of the present invention is providing a method for producing formic acid under mild reaction conditions and by a simple procedure. As a means for achieving the object, the method for producing formic acid of the present invention is characterized by a reaction between carbon dioxide and hydrogen in the presence of an ionic liquid. According to the present invention, it is possible to generate formic acid effectively, because the method does not require that carbon dioxide be brought into a supercritical state and because no basic substances are required to be added to the reaction system.

Methods for monitoring ionic liquids using vibrational spectroscopy

Methods for monitoring ionic liquids using vibrational spectroscopy may involve contacting an infrared (IR) transmissive medium with the ionic liquid, recording an IR spectrum of the ionic liquid, and quantifying at least one chemical characteristic of the ionic liquid based on the IR spectrum. The IR spectrum may be recorded ex situ or in situ. Methods for controlling ionic liquid catalyzed processes are also disclosed, wherein a condition of the ionic liquid may be determined during such processes based on IR spectral analysis of the ionic liquid.

Magnesium halide adducts, catalyst components and catalysts comprising the same, and preparation processes thereof

A magnesium halide adduct is provided, comprising at least one compound of the formula MgXY, at least one compound of the formula ROH, methanol, at least one modifying agent chosen from DOE and o-hydroxy benzoates, and optionally water. Also provided herein are a catalyst component comprising the magnesium halide adduct, a catalyst for olefin polymerization comprising the catalyst component; the respective processes for preparing the magnesium halide adduct and the catalyst component; use of the magnesium halide adduct for preparing the catalyst component, use of the catalyst component in a catalyst for olefin polymerization and use of the catalyst in olefin polymerization; and a process of olefin polymerization.

Process for the conversion of aromatic nitro compound into amines

A process for hydrogenating an aromatic nitro compound according to the invention comprises providing a hydrogen gas stream and a liquid aromatic nitro compound stream; providing a fixed bed catalytic reactor having an inflow side and an outflow side; feeding to the inflow side, the hydrogen gas stream and the liquid aromatic nitro compound stream; converting the hydrogen gas and the aromatic nitro compound into an aromatic amine, thereby providing a reactor effluent comprising the aromatic amine and water; evacuating the reactor effluent from the reactor at the outflow side of the reactor; wherein an inert solvent or water is fed to the inflow side of the reactor at a molar ratio of moles inert solvent or water to moles hydrogen is more than 1.

Frustrated Lewis Pair Compositions

A compound having the formula (I) where each of R 1 , R 2 , R 3 and R 4 is independently C 6 -C 18 aryl-, C 5 -C 8 cycloalkyl-, C 6 -C 18 aryl having at least one C 1 -C 20 alkyl substituent, C 5 -C 8 cycloalkyl having at least one C 1 -C 20 alkyl sυbstituent, C 4 -C 20 branched alkyl-, C 16 -C 20 linear alkyl-, RO—, —NRR′, —PRR′, —SR, fluoro substituted forms thereof, and perfluoro forms thereof: and R 5 is C 6 -C 18 aryl-, C 5 -C 8 cycloalkyl-, C 6 -C 18 aryl having at least one C 1 -C 20 alkyl substituent, C 5 -C 8 cycloalkyl having at least one C 1 -C 20 alkyl substituent, C 3 -C 20 branched alkyl-, C 2 -C 30 linear alkyl-, fluoro substituted forms thereof, and perfluoro forms thereof; where R and R′ are each independently C 6 -C 18 aryl-, C 5 -C 8 cycloalkyl-, C 6 -C 18 aryl having at least one C 1 -C 20 alkyl substituent, C 5 -C 8 cycloalkyl having at least one C 1 -C 20 alkyl substituent, C 4 -C 20 branched alkyl-, C 2 -C 30 linear alkyl-, fluoro substituted forms thereof, and perfluoro forms thereof; A is N, P, S, or O with the proviso that when A is S, R 2 is a nullity; and M is B, Al, Ga or In.

Propylene-based polymer, articles, and process for producing same

Disclosed are propylene-based polymer compositions and processes for producing same. Polymerization with an improved catalyst composition provides a propylene-based polymer with improved stiffness.

Hydroisomerization and selective hydrogenation of feedstock in ionic liquid-catalyzed alkylation

A process for producing alkylate comprising contacting a first hydrocarbon stream comprising at least one olefin having from 2 to 6 carbon atoms which contains 1,3-butadiene and 1-butene with a hydroisomerization catalyst in the presence of hydrogen under conditions favoring the simultaneous selective hydrogenation of 1,3-butadiene to butenes and the isomerization of 1-butene to 2-butene and contacting the resulting stream and a second hydrocarbon stream comprising at least one isoparaffin having from 3 to 6 carbon atoms with an acidic ionic liquid catalyst under alkylation conditions to produce an alkylate is disclosed.

Supported metal catalysts

The present invention relates to supported metal catalysts, wherein the catalysts are modified by at least one amine, a method for the preparation thereof and hydrogenation processes utilising the supported metal catalysts.

METHOD AND SYSTEM FOR FORMING PLUG AND PLAY METAL CATALYSTS

A metal catalyst is formed by vaporizing a quantity of metal and a quantity of carrier forming a vapor cloud. The vapor cloud is quenched forming precipitate nanoparticles comprising a portion of metal and a portion of carrier. The nanoparticles are impregnated onto supports. The supports are able to be used in existing heterogeneous catalysis systems. A system for forming metal catalysts comprises means for vaporizing a quantity of metals and a quantity of carrier, quenching the resulting vapor cloud and forming precipitate nanoparticles comprising a portion of metals and a portion of carrier. The system further comprises means for impregnating supports with the nanoparticles. 1. A method of making a metal catalyst comprising:a. providing a quantity of nanoparticles, wherein at least some of the nanoparticles comprise a first portion comprising catalyst material bonded to a second portion comprising a carrier;b. providing a quantity of supports; andc. combining the supports with the nanoparticles.2. The method of wherein the supports comprise pores and voids.3. The method of wherein the catalyst material comprises any among a list of at least one metal claim 1 , at least one metal alloy claim 1 , and any combination thereof.4. The method of wherein providing a quantity of nanoparticles comprises:a. loading a quantity of catalyst material and a quantity of carrier into a plasma gun in a desired ratio;b. vaporizing the quantity of catalyst material and quantity of carrier thereby forming a vapor cloud; andc. quenching the vapor cloud, thereby forming a quantity of nanoparticles.5. The method of wherein the carrier comprises an oxide.6. The method of wherein the oxide comprises silica claim 5 , alumina claim 5 , yttria claim 5 , zirconia claim 5 , titania claim 5 , ceria claim 5 , baria claim 5 , and any combination thereof.7. The method of wherein combining the supports with the nanoparticles comprises:a. suspending the nanoparticles in a solution, thereby forming a ...

SOLID BASE CATALYST AND METHOD FOR MAKING AND USING THE SAME

A solid base catalyst having a carrier, an organic base, and an inorganic base. Both of the organic base and inorganic base are loaded on the carrier. The solid base catalyst is especially suitable for the synthesis of 4-Aminodiphenylamine (4-ADPA). 1. A solid base catalyst comprisingan organic base,an inorganic base; anda carrier,wherein the organic base is chemically bound to the carrier, and the inorganic base is adsorbed in the carrier.2. The solid base catalyst of claim 1 , wherein the organic base is methylamine claim 1 , ethylamine claim 1 , cyclohexylamine claim 1 , aniline claim 1 , phenyl diamine claim 1 , dodecyl trimethyl ammonium chloride claim 1 , trimethyl benzyl ammonium chloride claim 1 , tetramethyl ammonium chloride claim 1 , tetramethyl ammonium bromide claim 1 , tetramethyl ammonium hydroxide claim 1 , tetraethyl ammonium hydroxide claim 1 , tetrapropyl ammonium hydroxide claim 1 , tetrabutyl ammonium hydroxide claim 1 , tetramethyl ammonium hydroxide claim 1 , benzyl trimethyl ammonium hydroxide claim 1 , benzyl triethyl ammonium hydroxide claim 1 , 4-dimethylamino pyridine claim 1 , crown ether claim 1 , or a mixture thereof.3. The solid base catalyst of claim 1 , wherein the organic base is tetramethyl ammonium hydroxide or tetraethyl ammonium hydroxide.4. The solid base catalyst of wherein the inorganic base is potassium hydroxide claim 1 , sodium hydroxide claim 1 , calcium hydroxide claim 1 , cesium hydroxide claim 1 , aluminum hydroxide claim 1 , sodium methoxide claim 1 , sodium ethoxide claim 1 , potassium methoxide claim 1 , potassium ethoxide claim 1 , or a mixture thereof.5. The solid base catalyst of claim 1 , wherein the inorganic base is potassium hydroxide or sodium hydroxide.6. The solid base catalyst of claim 1 , wherein the carrier is alumina claim 1 , silica gel claim 1 , diatomite claim 1 , molecular sieve claim 1 , macroporous adsorption resin claim 1 , or a mixture thereof.7. The solid base catalyst of claim 6 , wherein ...

Chiral Heterogeneous Catalyst for Assymmetric Nitroaldol Reaction

The present invention relates to the preparation of highly efficient chiral heterogeneous catalyst for asymmetric nitroaldol reaction, wherein Henry reactions of various aldehydes such as aromatic, aliphatic, α,β-unsaturated aldehydes, alicyclic aldehydes and nitroalkenes were carried out to produce optically active β-nitroalcohols in high yield, with moderate to excellent enantioselectivity (ee up to >99%) in presence of a base and an optically active chiral heterogeneous catalyst. 2. A chiral heterogeneous catalyst of formula 1 as claimed in claim 1 , wherein mesoporous silica used is selected from the group consisting of silica gel claim 1 , Mobile Crystalline Materials (MCM-41) claim 1 , Santa Barbara Amorphous (SBA-15) and Meso Cellular Foams (MCF) having porosity in the range of 30 to 120 Å.3. A chiral heterogeneous catalyst of formula 1 as claimed in claim 1 , wherein catalysts of formula 1 are represented as (S)-aminopropyl alcohol-copper-support-41 claim 1 , (R)-aminopropyl alcohol-copper-support-41 claim 1 , (S)-aminopropyl alcohol-copper-support-15 claim 1 , (R)-aminopropyl alcohol-copper-support-15 claim 1 , (S)-aminopropyl alcohol-copper-support-MCF claim 1 , (R)-aminopropyl alcohol-copper-support-Mesocellular Foams (MCF) claim 1 , (S)-aminopropyl alcohol-copper-support-Mesocellular Foams (MCF) claim 1 , (R)-aminopropyl alcohol-copper-support-Mesocellular Foams (MCF) claim 1 , (S)—N-methyl aminopropyl alcohol-copper-support-41 claim 1 , (R)—N-methyl aminopropyl alcohol-copper-support-41 claim 1 , (S)—N claim 1 ,N′-dimethyl aminopropyl alcohol-copper-support-41 claim 1 , (S)—N claim 1 ,N′-dimethyl aminopropyl alcohol-copper-support-15 claim 1 , (S)—N-methyl aminopropyl alcohol-copper-support-15 claim 1 , (S)-aminopropyl alcohol-copper-support-silicagel and (R)-aminopropyl alcohol-copper-support-silicagel.4. A process for the preparation of chiral heterogeneous catalyst of formula 1 as claimed in claim 1 , wherein the said process comprises of steps:i. ...

Magnetic Nanoparticle-Supported Glutathione as a Sustainable Organocatalyst

This invention relates to the use of nano-organocatalysts, and, more specifically, to the use of magnetic nanomaterial-supported organocatalysts. It is an object of the present invention to provide “green” catalysts and protocols. According to one embodiment of the invention, a nano-organocatalyst in the form of a magnetic nanomaterial-supported organocatalyst is provided. According to other embodiments of the invention, glutathione and cysteine are provided as organocatalysts and magnetic nanomaterial-supported glutathione and magnetic nanomaterial-supported cysteine are provided for use as nano-organocatalysts. According to another embodiment of the invention, a method of using a recyclable magnetic nanomaterial-supported organocatalyst using a totally benign aqueous protocol, without using any organic solvent in the reaction or during the workup, is provided. According to a further embodiment of the invention, a recyclable magnetic nanomaterial-supported organocatalyst for various organocatalytic reactions, including but not limited to Paal-Knorr reactions, aza-Michael addition and pyrazole synthesis, is provided. 1. A nano-organocatalyst comprising a magnetic nanomaterial-supported organocatalyst , wherein an organocatalyst comprises a compound having a thiol group and wherein the organocatalyst is anchored to a magnetic nanomaterial through the thiol group.2. The nano-organocatalyst of claim 1 , wherein the organocatalyst is selected from the group consisting of glutathione and cysteine.3. The nano-organocatalyst of claim 1 , wherein the magnetic nanomaterial is selected from the group consisting of nano-ferrite claim 1 , nano-nickel ferrite claim 1 , nano-cobalt ferrite claim 1 , nano-iron claim 1 , and nano-cobalt and their bimetallic derivatives.4. A nano-organocatalyst comprising magnetic nanomaterial-supported glutathione claim 1 , wherein glutathione is anchored to magnetic nanomaterial. The present application is a division of commonly assigned U.S. ...

Nanoparticles and nanoparticle compositions

The invention provides multivalent surface-crosslinked micelle (SCM) particles, crosslinked reverse micelle (CRM) particles, and methods of making and using them. The SCM particles can be used, for example, to inhibit a virus or bacteria from binding to a host cell. The inhibition can be used in therapy for the flu, cancer, or AIDS. The CRM particles can be used, for example, to prepare metal nanoparticles or metal alloy nanoparticles, or they can be used in catalytic reactions.

Accelerator Mixture for Peroxide Hardener and Two-Component Mortar System Containing Same

An accelerator mixture for peroxide hardeners, in particular an accelerator mixture for an organic peroxide-curing resin mixture, a two-component mortar system containing the same for chemical fastening and use of the same for chemical fastening of anchoring elements in boreholes are disclosed. Using a mixture of bis-N-substituted p-toluidines with bis-N-substituted anilines or bis-N-substituted m-toluidines, it is possible to provide a mortar composition for chemical fastening of anchoring elements in boreholes, which will have an improved low-temperature curing and improved load ratings at high temperatures with an extended gel time. 2. The accelerator mixture according to claim 1 , wherein the main accelerator (I) is N claim 1 ,N-bis(2-hydroxyethyl)-p-toluidine claim 1 , N claim 1 ,N-bis(2-hydroxypropyl)-p-toluidine or an ethoxylated or propoxylated derivative thereof.3. The accelerator mixture according to claim 1 , wherein the co-accelerator (II) is N claim 1 ,N-diethylaniline claim 1 , N claim 1 ,N-bis(2-hydroxyethyl)aniline claim 1 , N-ethyl-N-hydroxyethylaniline claim 1 , N claim 1 ,N-bis(2-hydroxyethyl)-m-toluidine or N claim 1 ,N-bis(2-hydroxypropyl)-m-toluidine.4. The accelerator mixture according to claim 3 , wherein the main accelerator (I) is N claim 3 ,N-bis(2-hydroxypropyl)-p-toluidine and the co-accelerator (II) is N claim 3 ,N-bis(2-hydroxyethyl)-m-toluidine.5. The accelerator mixture according to claim 1 , wherein a molar ratio of the main accelerator (I) to the co-accelerator (II) is 3:1.6. A resin mixture claim 1 , comprising:a radically polymerizable compound;{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'an accelerator according to ; and'}optionally an inhibitor and a reactive diluent.7. The resin mixture according to claim 6 , wherein the main accelerator (I) is N claim 6 ,N-bis(2-hydroxypropyl)-p-toluidine and the co-accelerator (II) is N claim 6 ,N-bis(2-hydroxyethyl)-m-toluidine.8. The resin mixture according to claim 6 , wherein a ...

SULFOXIDATION CATALYSTS AND METHODS AND SYSTEMS OF USING SAME

Catalysts amenable to oxidizing sulfur compounds and systems and methods of using these catalysts to effect the removal of sulfur from crude oil and crude oil distillates are disclosed. The catalyst is disposed with a titanyl moiety which serves to selectively coordinate sulfur compounds and affect their oxidation. The titanyl may be bound within a polymer or on the surface of a polymer or on the surface or in the pores of an inorganic support. The resulting oxidized sulfur compounds are readily separated from the initial crude oil or crude oil distillate streams by traditional separation techniques arrayed as described in the systems and methods disclosed. 1. A catalytic sulfoxidation reagent comprising:a phase transfer agent/solvent{'sub': m', 'm', 'n, 'a catalyst comprising a metal complex represented by the general formula MO(OR), wherein M is a metal complex; R is carbon group having at least 3 carbon atoms, where at each occurrence R may individually be a substituted alkyl group containing at least one OH group, a substituted cycloalkyl group containing at least one OH group, a substituted cycloalkylalkyl group containing at least one OH group, a substituted heterocyclyl group containing at least one OH group, or a heterocyclylalkyl containing at least one OH group; and the subscripts m and n may each independently be integers between about 1 and about 8; and'}an oxidant dissolved in the phase transfer agent/solvent.2. The reagent of wherein the catalyst comprises:bis(polyol)oxotitanium(IV);wherein the catalyst is selected from the group consisting of bis(glycerol)oxotitanium(IV), bis(ethyleneglycol)oxotitanium(IV), bis(erythritol)oxotitanium(IV), bis(sorbitol)oxotitanium(IV), and mixtures thereof.3. The reagent of claim 1 , wherein the catalyst is dissolved in the phase transfer agent/solvent.4. The reagent of claim 1 , wherein M is titanium and/or zirconium. This application is a continuation of U.S. application Ser. No. 12/933,898 filed Sep. 22, 2010 ...

OPTICALLY ACTIVE AMMONIUM SALT COMPOUND, PRODUCTION INTERMEDIATE THEREOF, AND PRODUCTION METHOD THEREOF

An optically active bisbenzyl compound or a racemic bisbenzyl compound represented by formula (2) that has axial chirality. An optically active azepine derivative or a racemic azepine derivative represented by formula (3). Methods of producing an optically active quaternary ammonium salt compound represented by formula (8). This is a divisional of application Ser. No. 11/817,585 filed Sep. 25, 2009, which is a National Stage application of PCT/JP2006/304091 filed Mar. 3, 2006, and claims the benefit of Japanese Patent Application Nos. 2005-059694 and 2005-192757 filed Mar. 3, 2005 and Jun. 30, 2005. The entire disclosures of the prior applications are hereby incorporated by reference herein in their entirety.The present invention relates to a compound of an optically active quaternary ammonium salt which is useful as a chiral phase transfer catalyst and more specifically, relates to a novel optically active quaternary ammonium salt, and an intermediate and production method for producing said compound.Priority is claimed on Japanese Patent Applications No. 2005-059694, filed Mar. 3, 2005, and No. 2005-192757, filed Jun. 30, 2005, the contents of which are incorporated herein by reference.Many compounds regarding optically active spiro quaternary ammonium salts have been known to date. Examples thereof include the compound described in Patent document 1 and represented by the following formulaand the compound described in Patent document 3, and the documents disclose that these compounds perform extremely effectively as a phase transfer catalyst for synthesizing optically active α-amino acids regardless of being natural or not. However, the optically active Spiro quaternary ammonium salts described in these documents are expensive since they are constituted from two kinds of binaphthyl derivatives having different substituents, and thus they are not necessarily satisfactory for industrial use.Moreover, the compound represented by the following formula is described in ...

CATALYTIC COMPOSITION AND PROCESS FOR THE SELECTIVE DIMERIZATION OF ISOBUTENE

Catalytic composition comprising at least one Brønsted acid, designated HB, dissolved in a non-aqueous liquid medium of general formula QA, in which Q represents an organic cation and A represents an anion, said composition also comprising an additive QA in which Q represents an organic cation containing at least one alcohol function and A represents an anion. The invention also relates to an isobutene dimerization process using the catalytic composition. 1. Catalytic composition comprising at least one Brønsted acid , designated HB , dissolved in a non-aqueous liquid medium of general formula QA , in which Q represents an organic cation and A represents an anion , said composition also comprising an additive QAin which Q represents an organic cation comprising at least one alcohol function and A represents an anion.2. Catalytic composition according to claim 1 , in which the anion A or A is chosen from the following anions: tetrafluoroborate claim 1 , tetraalkylborates claim 1 , hexafluorophosphate claim 1 , hexafluoroantimonate claim 1 , alkylsulphonates claim 1 , arylsulphonates claim 1 , perfluoroalkylsulphonates claim 1 , fluorosulphonate claim 1 , sulphates claim 1 , phosphates claim 1 , perfluoroacetates claim 1 , perfluoroalkylsulphonamides claim 1 , fluorosulphonamides claim 1 , perfluoroalkylsulphomethides and carboranes claim 1 , Aand A being identical or different.3. Catalytic composition according to claim 1 , in which Q represents a quaternary ammonium and/or a quaternary phosphonium and/or a trialkylsulphonium claim 1 , and Qrepresents a quaternary ammonium and/or a quaternary phosphonium and/or a trialkylsulphonium comprising at least one alcohol function claim 1 , and Aor Arepresent any anion known to be non-coordinating and capable of forming a liquid salt below 150° C.5. Catalytic composition according to claim 4 , in which the quaternary ammonium and/or phosphonium cation Q is chosen from the group formed by N-butylpyridinium claim 4 , N- ...

CATALYTIC COMPOSITION CONTAINING AN ACID FUNCTION AND A PROCESS FOR THE SELECTIVE DIMERIZATION OF ISOBUTENE

Catalytic composition comprising at least one non-aqueous ionic liquid medium of general formula QA, in which Q represents an organic cation and A represents an anion, and at least one ionic component of general formula QA, in which Q represents an organic cation comprising at least one sulphonic acid or carboxylic acid function, and A represents an anion. The invention also relates to an isobutene dimerization process using the catalytic composition. 1. Catalytic composition comprising at least one non-aqueous ionic liquid medium of general formula QA , in which Q represents an organic cation and A represents an anion , and at least one ionic component of general formula QA , in which Q represents an organic cation comprising at least one sulphonic acid or carboxylic acid function , and A represents an anion.2. Catalytic composition according to claim 1 , in which the anion A or A is chosen from the following anions: tetrafluoroborate claim 1 , tetraalkylborates claim 1 , hexafluorophosphate claim 1 , hexafluoroantimonate claim 1 , alkylsulphonates claim 1 , arylsulphonates claim 1 , perfluoroalkylsulphonates claim 1 , fluorosulphonate claim 1 , sulphates claim 1 , phosphates claim 1 , perfluoroacetates claim 1 , perfluoroalkylsulphonamides claim 1 , fluorosulphonamides claim 1 , perfluoroalkylsulphomethides and carboranes claim 1 , A and A being identical or different.3. Catalytic composition according to claim 1 , in which Q represents a quaternary ammonium and/or a quaternary phosphonium and/or a trialkylsulphonium claim 1 , and Q represents a quaternary ammonium and/or a quaternary phosphonium and/or a trialkylsulphonium comprising at least one sulphonic acid or carboxylic acid function claim 1 , and A or A represent any anion known to be non-coordinating and capable of forming a liquid salt below 150° C.5. Catalytic composition according to claim 4 , in which the quaternary ammonium and/or phosphonium cation Q is chosen from the group formed by N- ...

Electrocatalysts For Carbon Dioxide Conversion

Electrocatalysts for carbon dioxide conversion include at least one catalytically active element with a particle size above 0.6 nm. The electrocatalysts can also include a Helper Catalyst. The catalysts can be used to increase the rate, modify the selectivity or lower the overpotential of electrochemical conversion of CO. Chemical processes and devices using the catalysts also include processes to produce CO, HCO, HCO, (HCO), HCO, CHOH, CH, CH, CHCHOH, CHCOO, CHCOOH, CH, (COOH), or (COO), and a specific device, namely, a COsensor. 1. A catalyst for the electrochemical conversion of COinto useful products comprising at least one catalytically active element wherein said catalytically active element is in the form of supported or unsupported particles and the particles of the at least one catalytically active element have an average size between 0.6 nm and 100 nm.2. The catalyst of claim 1 , wherein the average particle size is between about 0.6 nm and 40 nm.3. The catalyst of wherein the average particle size is between about 0.6 nm and 20 nm.4. The catalyst of wherein the average particle size is between about 0.6 nm and 10 nm.5. The catalyst of further comprising a Helper Catalyst.6. The catalyst of wherein said catalytically active element comprises at least one of V claim 1 , Cr claim 1 , Mn claim 1 , Fe claim 1 , Co claim 1 , Ni claim 1 , Cu claim 1 , Zr claim 1 , Nb claim 1 , Mo claim 1 , Ru claim 1 , Rh claim 1 , Pd claim 1 , Ag claim 1 , Cd claim 1 , W claim 1 , Re claim 1 , Ir claim 1 , Pt claim 1 , Au claim 1 , Hg claim 1 , Pb claim 1 , and Bi.7. The catalyst of wherein said products comprise at least one of the following: CO claim 1 , HCO claim 1 , HCO claim 1 , (HCO) claim 1 , HCO claim 1 , CHOH claim 1 , CH claim 1 , CH claim 1 , CHCHOH claim 1 , CHCOO claim 1 , CHCOOH claim 1 , CH claim 1 , (COOH)and (COO).8. The catalyst of wherein said reaction products comprising one of CO or HCOOH.9. The catalyst of wherein said catalytically active element ...

IRIDIUM CATALYSTS FOR CARBONYLATION

A solid catalyst comprising an effective amount of iridium and at least one second metal selected from gallium, zinc, indium and germanium associated with a solid support material is useful for vapor phase carbonylation to produce carboxylic acids and esters from alkyl alcohols, esters, ethers or ester-alcohol mixtures. The iridium and at least one second metal are deposited on a support material. In some embodiments of the invention, the catalyst is useful for vapor phase carbonylation. 1. A carbonylation catalyst comprising an effective amount of iridium and at least one second metal selected from gallium , zinc , indium and germanium wherein the iridium and the at least one second metal are associated with a solid support material.2. The carbonylation catalyst according to wherein the solid support material is selected from pumice claim 1 , alumina claim 1 , silica claim 1 , silica-alumina claim 1 , magnesia claim 1 , diatomaceous earth claim 1 , bauxite claim 1 , titania claim 1 , zirconia claim 1 , clays claim 1 , magnesium silicate claim 1 , silicon carbide claim 1 , zeolites claim 1 , ceramics claim 1 , carbon and combinations of two or more of the foregoing.3. The carbonylation catalyst of wherein the solid support material comprises activated carbon.4. The carbonylation catalyst of wherein the catalyst includes from about 0.01 weight percent to about 10 weight percent each of the iridium and the at least one second metal.5. The carbonylation catalyst of wherein the catalyst includes from about 0.1 weight percent to about 3 weight percent each of the iridium and the at least one second metal.6. The carbonylation catalyst of wherein the molar ratio of the at least one second metal to iridium is from about 0.1:1 to about 10:1.7. The carbonylation catalyst of wherein the molar ratio of the at least one second metal to iridium is from about 0.5:1 to about 5:1.8. The carbonylation catalyst of claim 1 , further comprising at least one vaporous halogen promoting ...

Oxidation Catalyst for Hydrocarbon Compound, and Method and Apparatus for Producing Oxide of Hydrocarbon Compound Using Same

According to the first embodiment of the present invention, an oxide of a hydrocarbon compound can be produced with high yield and high productivity by oxidizing the hydrocarbon compound with molecular oxygen in the co-presence of an N-hydroxy compound, such as methyl ethyl ketone or N-hydroxysuccinimide, and a phosphate ester, such as dibutyl phosphate. According to another embodiment of the present invention, an oxide of a hydrocarbon compound can be produced with high yield by using an oxidation catalyst that comprises an oxime compound, such as methyl ethyl ketone. According to another embodiment of the present invention, an alcohol and/or a ketone can be produced with high yield by oxidizing the hydrocarbon compound at a temperature of 160° C. or less, and by decomposing the resulting hydroperoxide, for example, in a unit having an inner surface formed by a material from which no transition metal ion is generated.

CATALYSTS CONTAINING N-HETEROCYCLIC CARBENES FOR ENANTIOSELECTIVE SYNTHESIS

Novel N-heterocyclic carbene ligand precursors, N-heterocyclic carbene ligands and N-heterocyclic metal-carbene complexes are provided. Metal-carbene complexes comprising N-heterocyclic carbene ligands can be chiral, which are useful for catalyzing enantioselective synthesis. Methods for the preparation of the N-heterocyclic carbene ligands and N-heterocyclic metal-carbene complexes are given. 2. The N-heterocyclic carbene ligand precursor of claim 1 , wherein said compound of Formula (I) comprises a racemic mixture claim 1 , an enantiomerically enriched compound claim 1 , or an enantiomerically pure compound.3. The N-heterocyclic carbene ligand precursor of claim 1 , wherein said compound of Formula (I) is a bis-N-heterocyclic carbene ligand precursor wherein n is 1 and R is other than NRR.5. The N-heterocyclic carbene ligand precursor of claim 1 , wherein said compound of Formula (I) is a bis-N-heterocyclic carbene ligand precursor wherein n is 0 and R is other than NRR.7. The N-heterocyclic carbene ligand precursor of claim 1 , wherein said compound of Formula (I) is a mono-N-heterocyclic carbene ligand precursor wherein n is 0 and one R is NRR.9. The N-heterocyclic carbene ligand precursor of claim 1 , wherein a carbon-hydrogen bond other than that of the carbon between the two nitrogens of R is replaced with an alkylene or oxyalkylene unit bridged with a polymer or polymeric resin.10. A method of making an N-heterocyclic carbene ligand precursor according to comprising the steps of:providing a trans-9,10-dihydro-9,10-ethanoanthracene compound; andtransforming said trans-9,10-dihydro-9,10-ethanoanthracene compound into said N-heterocyclic carbene ligand precursor.11. The method of claim 10 , wherein said trans-9 claim 10 ,10-dihydro-9 claim 10 ,10-ethanoanthracene compound is an ester derived from trans-9 claim 10 ,10-dihydro-9 claim 10 ,10-ethanoanthracene-11 claim 10 ,12-dimethanol and wherein said step of transforming comprises performing at least one ...

GROUP 4 METAL COMPOUND CONTAINING THIOPHENE-FUSED CYCLOPENTADIENYL LIGAND DERIVED FROM TETRAQUINOLINE DERIVATIVE AND OLEFIN POLYMERIZATION USING THE SAME

The present invention relates to a novel ligand derived from a tetrahydroquinoline derivative, and a transition metal compound prepared using the ligand, where an amido ligand is linked to an ortho-phenylene ligand to form a condensed ring and a 5-membered cyclic pi-ligand linked to the ortho-phenylene ligand is fused with a heterocyclic thiophene ligand. Compared with the catalysts not fused with a heterocyclic thiophene ligand, the transition metal compound of the present invention as activated with a co-catalyst has higher catalytic activity in olefin polymerization and provides a polymer with higher molecular weight. 2. The transition metal compound as claimed in claim 1 , wherein M is titanium (Ti) claim 1 , zirconium (Zr) claim 1 , or hafnium (Hf);{'sup': 1', '2, 'Qand Qare independently methyl or chlorine;'}{'sup': 1', '2', '3', '4', '5, 'R, R, R, R, and Rare independently hydrogen or methyl; and'}{'sup': 6', '7', '8', '9', '10', '11', '12', '13, 'R, R, R, R, R, R, R, and Rare independently hydrogen.'}4. The precursor for transition metal compound as claimed in claim 3 , wherein R claim 3 , R claim 3 , R claim 3 , R claim 3 , and Rare independently hydrogen or methyl; and{'sup': 6', '7', '8', '9', '10', '11', '12', '13, 'R, R, R, R, R, R, R, and Rare independently hydrogen.'}6. The method as claimed in claim 5 , wherein R claim 5 , R claim 5 , R claim 5 , R claim 5 , and Rare independently hydrogen or methyl; and{'sup': 6', '7', '8', '9', '10', '11', '12', '13, 'R, R, R, R, R, R, R, and Rare independently hydrogen.'}8. The catalyst composition as claimed in claim 7 ,{'sup': 1', '2', '3', '4', '5', '6', '7', '8', '9', '10', '11', '12', '13, 'wherein in the formula 1, R, R, R, R, and Rare independently hydrogen or methyl, and R, R, R, R, R, R, R, and Rare independently hydrogen;'}{'sup': '61', 'in the formula 6, Ris methyl;'}{'sup': 71', '71, 'in the formula 7, D is aluminum, and Ris methyl or isobutyl; or D is boron, and Ris pentafluorophenyl; and'}{'sup': +', ...

Modified catalyst supports

The invention covers a supported catalyst system prepared according to a process comprising the following step: i). impregnating a silica-containing catalyst support having a specific surface area of from 150 m 2 /g to 800 m 2 /g, preferably 280 m 2 /g to 600 m 2 /g, with one or more titanium compounds of the general formula selected from R n Ti(OR′) m and (RO) n Ti(OR′) m , wherein R and R′ are the same or different and are selected from hydrocarbyl groups containing from 1 to 12 carbon and halogens, and wherein n is 0 to 4, m is 0 to 4 and m+n equals 4, to form a titanated silica-containing catalyst support having a Ti content of at least 0.1 wt % based on the weight of the Ti-impregnated catalyst support wherein the supported catalyst system further comprises an alumoxane and a metallocene.

Method for preparing polypropylene using transition metal compound containing thiophene-fused cyclopentadienyl ligand

The present invention relates to a preparation method for polypropylene that comprises polymerizing a propylene monomer in the presence of a catalyst comprising a novel transition metal compound. Using the novel transition metal compound as a catalyst, the preparation method for polypropylene according to the present invention can not only acquire high catalytic activity for polymerization to achieve high efficiency of the process but allow it to easily control the fine-structure characteristics of the polymer, thereby providing polypropylene having desired properties with ease.

Hydrolysis of used ionic liquid catalyst for disposal

We provide a process and apparatus for preparing a used catalyst for disposal, comprising: a. hydrolyzing a used ionic liquid catalyst comprising an anhydrous metal halide to produce a hydrolyzed product; and b. separating the hydrolyzed product into a liquid phase and a solid phase; wherein the liquid phase comprises a non-water-reactive aqueous phase and a hydrocarbon phase; and wherein the solid phase comprises a solid portion of the hydrolyzed product, that is not water reactive. A vessel is used for the hydrolyzing and a separator is used for the separating.

Compositions containing fluorine substituted olefins and methods and systems using same

Disclosed are the use of fluorine substituted olefins, including tetra- and penta-fluoropropenes, in a variety of applications, including in methods of depositing catalyst on a solid support, methods of sterilizing articles, cleaning methods and compositions, methods of applying medicaments, fire extinguishing/suppression compositions and methods, flavor formulations, fragrance formulations and inflating agents.

NOVEL PHASE TRANSFER CATALYSTS

Compounds of formula (I): wherein Rto R, and X are defined herein. Also disclosed are methods of making and using these compounds. 2. The compound of claim 1 , wherein Ris identical to R claim 1 , Ris identical to R claim 1 , Ris identical to R claim 1 , and Ris identical to R.3. The compound of claim 2 , wherein all the carbon atoms to which R claim 2 , R claim 2 , R claim 2 , and Rare attached have an R or S configuration.4. The compound of claim 3 , wherein all the carbon atoms to which R claim 3 , R claim 3 , R claim 3 , and Rare attached have an R configuration claim 3 , or all of them have a S configuration.5. The compound of claim 4 , wherein each of R claim 4 , R claim 4 , R claim 4 , and R claim 4 , independently claim 4 , is aryl or heteroaryl.6. The compound of claim 4 , wherein Rand R claim 4 , together with the two carbon atoms to which they are attached claim 4 , form C-Ccycloalkyl; and Rand R claim 4 , together with the two carbon atoms to which they are attached claim 4 , form C-Ccycloalkyl.7. The compound of claim 4 , wherein each of R claim 4 , R claim 4 , R claim 4 , and R claim 4 , independently claim 4 , is C-Calkyl.9. The compound of claim 1 , wherein Ris identical to R claim 1 , each of Rand Ris H claim 1 , and Ris identical to R.10. The compound of claim 9 , wherein all the carbon atoms to which Rand Rare attached have an R or S configuration.11. The compound of claim 10 , wherein each of Rand R claim 10 , independently claim 10 , is aryl or heteroaryl.12. The compound of claim 10 , wherein each of R claim 10 , R claim 10 , R claim 10 , and R claim 10 , independently claim 10 , is C-Calkyl.13. The compound of claim 1 , wherein Ris identical to R claim 1 , each of Rand Ris H claim 1 , and Ris identical to R.14. The compound of claim 13 , wherein all the carbon atoms to which Rand Rare attached have an R or S configuration.15. The compound of claim 14 , wherein each of Rand R claim 14 , independently claim 14 , is aryl or heteroaryl.16. The ...

Fluoroalkylation Methods And Reagents

A method of forming a fluorinated molecular entity includes reacting in a reaction mixture an aromatic halide, copper, a fluoroalkyl group, and a ligand. The aromatic halide includes an aromatic group and a halogen substituent bonded to the aromatic group. The ligand includes at least one group-V donor selected from phosphorus and an amine. The overall molar ratio of copper to aromatic halide in the reaction mixture is from 0.2 to 3. The method further includes forming a fluoroalkylarene including the aromatic group and the fluoroalkyl group bonded to the aromatic group. A composition, which may be used in the method, consists essentially of copper, the fluoroalkyl group, and the ligand, where the molar ratio of copper to the fluoroalkyl group is approximately 1.

PROCESS FOR PREPARATION OF SUPPORTED CATALYSTS AND USE OF THE CATALYST FOR THE ESTERIFICATION OF FREE FATTY ACIDS IN VEGETABLE OIL

Process for preparation of a supported catalyst based on hydroxylated inorganic material selected from the group consisting of silica (SiO), alumina (ALO), titania (TiO), zirconia (ZrO), lanthanum oxide (LaO) or mixtures thereof, characterized in that the hydroxylated inorganic material is contacted with organosilicon compounds selected from the group consisting of Formula 1 i.e., [(RO)Si—[O—(RO)Si]—O—Si(RO)] or Formula 2 i.e., (RO)—Si—R—S—R—Si—(RO)with R being alkyl and Rbeing a linear or branched alkylene having from 1 to 5 carbon atoms and y being an integer from 1 to 3. 111-. (canceled)12. A process for the preparation of a supported catalyst based on hydroxylated inorganic material selected from the group consisting of silica (SiO) , alumina (ALO) , titania (TiO) , zirconia (ZrO) , lanthanum oxide (LaO) or mixtures thereof , which comprises contacting the hydroxylated inorganic material with at least one organosilicon compound selected from the group consisting of Formula 1 and Formula 2{'br': None, 'sub': y', 'y', 'y', 'y, '[(RO)Si—[O—(RO)Si]—O—Si(RO)]\u2003\u2003Formula 1'}{'br': None, 'sub': y', '2-4', 'y, 'sup': 1', '1, '(RO)—Si—R—S—R—Si—(RO)\u2003\u2003Formula 2'}with R being alkyl,{'sup': '1', 'Rbeing a linear or branched alkylene having from 1 to 6 carbon atoms and'}y being identical or different and is an integer from 1 to 3.13. The process according to claim 12 , wherein the treatment of the hydroxylated inorganic material with an organosilicon compound is of the Formula 1 claim 12 , and is accompanied or followed by a treatment with an organosilicon compound of Formula 3{'br': None, 'sub': y', '3', 'x, 'sup': 1', '−, '[(RO)Si—R—SO]zM \u2003\u2003Formula 3'}with R being alkyl,{'sup': '1', 'Rbeing a linear or branched alkylene having from 1 to 6 carbon atoms,'}y being identical or different and is an integer from 1 to 3x being an integer from 1 to 4,{'sup': +', '+, 'sub': '4', 'M being H, NH or a metal ion with a valence between 1 and 4 and'}z being an ...

Process unit for flexible production of alkylate gasoline and distillate

A process unit, comprising: a) an alkylation reactor; and b) a control system that enables the alkylation reactor to be operated in an alkylate mode and in a distillate mode; wherein the alkylation reactor can switch back and forth from operating in the alkylate mode to the distillate mode.

Preparation of a solid catalyst system

Process for the preparation of a solid catalyst system comprising the steps of generating an emulsion by dispersing a liquid clathrate in a solution wherein (i) the solution constitutes the continuous phase of the emulsion and (ii) the liquid clathrate constitutes in form of droplets the dispersed phase of the emulsion, solidifying said dispersed phase to convert said droplets to solid particles and optionally recovering said particles to obtain said catalyst system, wherein the liquid clathrate comprises a lattice being the reaction product of aluminoxane, an organometallic compound of a transition metal of Group 3 to 10 of the Periodic Table (IUPAC 2007) or of an actinide or lanthanide, and a further compound being effective to form with the aluminoxane and the organometallic compound the lattice, and a guest being an hydrocarbon compound, and the solution comprises a silicon fluid and a hydrocarbon solvent.

ENANTIOSELECTIVE ORGANIC ANHYDRIDE REACTIONS

Disclosed herein is enantioselective synthetic method comprising reacting an enolisable C-Corganic anhydride with a second compound selected from the group consisting of an aldehyde, a ketone, an aldimine, a ketimine or a Michael Acceptor in the presence of a bifunctional organocatalyst. The reaction may find particular utility in the enantioselective synthesis of medicinally relevant heterocycles, such as dihydroisocoumarins and dihydroisoquinolinones. 1. An enantioselective synthetic method comprising the step of:{'sub': 4', '50, 'reacting an enolisable C-Corganic anhydride with a second compound selected from the group consisting of an aldehyde, a ketone, an aldimine, a ketimine or a Michael Acceptor in the presence of a bifunctional organocatalyst.'}4. A method according to claim 1 , wherein the enolisable C-Corganic anhydride is a cyclic anhydride.14. A compound according to claim 10 , wherein the compound is immobilised on a solid phase support or a magnetic nanoparticle. The present invention relates to asymmetric synthesis, and in particular the field of asymmetric catalysis. Disclosed herein are a number of novel catalysts for promoting highly useful synthetic transformations between organic anhydrides and aldehydes, ketones, and α,β-unsaturated electrophiles. The transformations of the present invention allow access to densely functionalised products in high enantiomeric excess.Privileged structures are molecular frameworks exhibited in natural products and medicinal compounds that show therapeutic activity at number of different receptor or enzyme targets. Accordingly, facile enantioselective synthetic routes to such structures are valuable and are in constant demand.Two such privileged structures are Dihydroisocoumarins (A) and Dihydroisoquinolinones (B). The asterisks denote carbon atoms that are chiral. Given the effect the chirality of these stereogenic carbons may have on the activity of these molecules, controlling the absolute stereochemistry of ...

OXYGEN REDUCTION CATALYST AND ELECTROCHEMICAL CELL

An oxygen reduction catalyst of an embodiment includes: a stack of single-layer graphenes; and a phosphorus compound, wherein some of carbon atoms of the graphenes are replaced by nitrogen atoms, and the phosphorus compound has a peak of phosphorus 2orbital of 133.0 to 134.5 eV in X-ray photoelectron spectrum. 1. An oxygen reduction catalyst comprising:a stack of single-layer graphenes; anda phosphorus compound, whereinsome of carbon atoms of the grapheneare replaced by nitrogen atoms, andthe phosphorus compound has a peak of phosphorus 2p orbital of 133.0 to 134.5 eV in X-ray photoelectron spectrum.2. An oxygen reduction catalyst comprising:a stack of single-layer graphenes; anda phosphorus compound, whereinsome of carbon atoms of the graphenes are replaced by nitrogen atoms, anda peak of phosphorus 2p orbital of the phosphorus compound is shifted by 1.0 to 2.5 eV toward a high-energy side from a peak of phosphorus 2p orbital of tetra-n-butylphosphonium bromide in X-ray photoelectron spectrum.3. The catalyst according to claim 1 , wherein the phosphorus compound is oligophosphate or polyphosphate.4. The catalyst according to claim 1 , further comprising iron or cobalt.5. The catalyst according to claim 1 , further comprising platinum.6. The catalyst according to claim 2 , wherein the phosphorus compound is oligophosphate or polyphosphate.7. The catalyst according to claim 2 , further comprising iron or cobalt.8. The catalyst according to claim 2 , further comprising platinum.9. An electrochemical cell comprising:a positive electrode;a negative electrode;a proton conductive film held between the positive electrode and the negative electrode; anda power supply applying voltage to the positive electrode and the negative electrode, whereinthe positive electrode or negative electrode includes an oxygen reduction catalyst including a stack of single-layer graphenes and a phosphorus compound, andsome of carbon atoms of the graphenes in which are replaced by nitrogen atoms ...

Bleach catalysts

The present invention relates to specific acylhydrazone compounds, their use as oxidation catalysts and to a process for removing stains and soil on textiles and hard surfaces. The compounds are substituted with a specific cyclic ammonium group adjacent to the acyl group. Further aspects of the invention are compositions or formulations comprising such compounds.

CATALYST SYSTEMS AND THEIR USE FOR METATHESIS REACTIONS

Novel catalyst systems for metathesis reactions, in particular for the metathesis of nitrile rubber, which contain a specific addition of boric acid compounds. 3. The process according to claim 2 , wherein Xand Xare identical or different and are each hydrogen claim 2 , halogen claim 2 , pseudohalogen claim 2 , straight-chain or branched C-C-alkyl claim 2 , C-C-aryl claim 2 , C-C-alkoxy claim 2 , C-C-aryloxy claim 2 , C-C-alkyldiketonate claim 2 , C-C-aryldiketonate claim 2 , C-C-carboxylate claim 2 , C-C-alkylsulphonate claim 2 , C-C-arylsulphonate claim 2 , C-C-alkylthiol claim 2 , C-C-arylthiol claim 2 , C-C-alkylsulphonyl or C-C-alkylsulphinyl radicals.4. The process according to claim 2 , wherein Xand Xare identical or different and are each halogen claim 2 , benzoate claim 2 , C-C-carboxylate claim 2 , C-C-alkyl claim 2 , phenoxy claim 2 , C-C-alkoxy claim 2 , C-C-alkylthiol claim 2 , C-C-arylthiol claim 2 , C-C-aryl or C-C-alkylsulphonate.5. The process according to claim 2 , wherein Xand Xare identical and are each fluorine claim 2 , chlorine claim 2 , bromine or iodine claim 2 , CFCOO claim 2 , CHCOO claim 2 , CFHCOO claim 2 , (CH)CO claim 2 , (CF)(CH)CO claim 2 , (CF)(CH)CO claim 2 , PhO (phenoxy) claim 2 , MeO (methoxy) claim 2 , EtO (ethoxy) claim 2 , tosylate (p-CH—CH—SO) claim 2 , mesylate (2 claim 2 ,4 claim 2 ,6-trimethylphenyl) or CFSO(trifluoromethane-sulphonate).6. The process according to claim 2 , wherein the two ligands L are each claim 2 , independently of one another claim 2 , a phosphine claim 2 , sulphonated phosphine claim 2 , phosphate claim 2 , phosphinite claim 2 , phosphonite claim 2 , arsine claim 2 , stibine claim 2 , ether claim 2 , amine claim 2 , amide claim 2 , sulphoxide claim 2 , carboxyl claim 2 , nitrosyl claim 2 , pyridine claim 2 , thioether or imidazolidine (“Im”) ligand.12. The process according to or claim 2 , wherein Xand Xin the general formula (B) are identical and are each fluorine claim 2 , chlorine claim 2 , ...

Electrocatalytic alkenes and alkynes dimerizations and trimerizations

The present disclosure relates generally to carbon to carbon coupling processes, and more specifically, to dimerization or trimerization by electrocatalysis of alkenes and alkynes at room temperature.

PHOTOCATALYST-COATED OBJECT AND PHOTOCATALYST COATING LIQUID FOR SAME

A photocatalyst-coated body includes: a base containing an organic component; and a transparent photocatalyst layer provided on the base, wherein the photocatalyst layer comprises, based on 100% by mass of the whole photocatalyst layer, photocatalyst particles being 1% by mass or more and 20% by mass or less, inorganic oxide particles being 50% by mass or more and less than 89% by mass, and a dried product of a silicone emulsion being more than 10% by mass and less than 50% by mass, and the silicone emulsion is formed of a silicone represented by an average composition formula: RSiOwherein R represents an alkyl or phenyl group; and 2≦a<4. Such photocatalyst-coated body suffers less from flow streak-derived appearance defects; and excels in various properties, especially in a harmful gas decomposition capability and weathering resistance, particularly while effectively preventing the corrosion of an organic base. 1. A photocatalyst-coated body comprising: a base containing an organic component; and a transparent photocatalyst layer provided on the base , whereinthe photocatalyst layer comprises, based on 100% by mass of the whole photocatalyst layer,photocatalyst particles being 1% by mass or more and 20% by mass or less,inorganic oxide particles being 30% by mass or more and less than 89% by mass, anda dried product of a silicone emulsion being more than 10% by mass and less than 50% by mass, and{'sub': a', '(4-a)/2, 'the silicone emulsion comprises a silicone represented by an average composition formula: RSiOwhere R represents an alkyl or phenyl group; and 2≦a<4.'}2. The photocatalyst-coated body according to claim 1 , wherein the silicone emulsion has a glass transition temperature of above 60° C.3. The photocatalyst-coated body according to claim 1 , wherein the photocatalyst particles are titanium oxide particles.4. The photocatalyst-coated body according to claim 1 , wherein the inorganic oxide particles are silica particles.5. The photocatalyst-coated body ...

Triazolium Carbene Catalysts and Stereoselective Bond Forming Reactions Thereof

Provided herein are triazolium carbine catalysts useful for asymmetric hydration, fluorination, and deuteration, and processes for their preparation. Also provided are synthetic reactions in which these catalysts are used, in particular, in stereoselective formation of carbon-chlorine, carbon-hydrogen, carbon-fluorine, and carbon-deuterium bonds. 2. The compound of wherein the counter ion X is selected from the group consisting of BF claim 1 , Cl claim 1 , PF claim 1 , BPh claim 1 , and RBF.3. A composition comprising a compound of formula (I) according to claim 1 , a proton donor claim 1 , and a base.5. The method of claim 4 , wherein the aldehyde is an enal.6. The method of claim 4 , wherein the aldehyde is a α claim 4 ,α-dichloro aldehyde or an α-chloro α-fluoro aldehyde.8. The method of wherein claim 4 , the asymmetric hydration results in an enantiomeric excess of the respective α-deuterio carboxylic acid claim 4 , α-deuterio-α-chloro carboxylic acid or α-deuterio-α-fluoro carboxylic acid.9. The method of further comprising contacting the aldehyde with an additive selected from phase transfer reagents claim 4 , salts claim 4 , and brine.11. The method of claim 10 , wherein the aldehyde is an enal.12. The method of claim 10 , wherein the aldehyde is a α claim 10 ,α-dichloro aldehyde or an α-chloro α-fluoro aldehyde.14. The method of claim 10 , wherein the drug analog is an α-fluoroenal and the asymmetric hydration forms an α-fluoro carboxylic acid.15. The method of claim 10 , wherein the asymmetric hydration results in an enantiomeric excess of the respective drug analog.17. The method of claim 16 , wherein the aldehyde is an enal.18. The method of claim 16 , wherein the aldehyde is a α claim 16 ,α-dichloro aldehyde or an α-chloro α-fluoro aldehyde.20. The method of claim 4 , wherein the base is selected from the group consisting of KCO claim 4 , NaHCO claim 4 , KHPO claim 4 , NaCO claim 4 , KPO claim 4 , EtN claim 4 , DIPEA claim 4 , DBU claim 4 , DBN claim 4 , ...

SYNTHESIS OF PHOSPHITYLATED COMPOUNDS USING A QUATERNARY HETEROCYCLIC ACTIVATOR

A method for preparing a phosphitylated compound comprising the step of:—reacting a hydroxyl containing compound with a phosphitylating agent in the presence of an activator having the formula (I) wherein R=alkyl, cycloalkyl, aryl, aralkyl, heteroalkyl, heteroaryl R, R=either H or form a 5 to 6-membered ring together. X, X=independently either N or CH Y=H or Si(R), with R=alkyl, cycloalkyl, aryl, aralkyl, heteroalkyl, heteroaryl B=deprotonated acid. The hydroxyl containing compound is preferably a sugar moiety or a nucleoside or an oligomer derived therefrom. 118-. (canceled)21. The method of claim 19 , wherein said hydroxyl containing compound comprises a sugar moiety.22. The method of claim 19 , wherein said hydroxyl containing compound is a nucleoside or an oligomer derived therefrom.23. The method of claim 19 , wherein said hydroxyl containing compound is a 5′-O-protected nucleoside having a 3′-hydroxyl group or a 3′-O-protected nucleoside having a 5′-hydroxyl group.24. The method of claim 19 , wherein said activator is prepared in-situ and used without purification.26. The method of claim 25 , wherein claim 25 , prior to said reaction step claim 25 , said corresponding base is brought into contact with said hydroxyl containing compound and said phosphitylating agent and an acid HB is added.28. The method of claim 19 , wherein said phosphitylating agent is 2-cyanoethyl-N claim 19 ,N claim 19 ,N′ claim 19 ,N′-tetraisopropylphosphorodiamidite.29. The method of claim 19 , wherein B is selected from the group consisting of trifluoroacetate claim 19 , dichloroacetate claim 19 , mesylate claim 19 , triflate claim 19 , o-chlorophenolate claim 19 , and mixtures thereof.30. A phosphoramidite prepared according to the method of claim 19 , wherein said phosphoramidite is selected from the group consisting of adenosine phosphoramidite; cytosine phosphoramidite; guanosine phosphoramidite; uracil phosphoramidite; desoxyadenosine phosphoramidite; desoxyguanosine ...

Process for producing alpha-hydroxyketone compound

An object of the present invention is to produce an α-hydroxyketone compound easily and effectively. Provided is a process for producing an α-hydroxyketone compound comprising a stirring step of stirring one or more aldehyde compounds or polymers thereof in the presence of a base and an imidazolinium salt represented by the formula (1): wherein R 1 and R 2 each independently represent a hydrogen atom, an alkyl group optionally having a substituent or an aryl group optionally having a substituent, or R 1 and R 2 are bound to each other to form a ring together with carbon atoms to which they bind, R 3 and R 4 each independently represent an aryl group having one or more electron withdrawing groups, and X − represents an anion.

Method for producing fuel cell electrode catalyst, fuel cell electrode catalyst, and uses thereof

A method for producing a fuel cell electrode catalyst, including: a step (1) of mixing at least a metal compound (1), a nitrogen-containing organic compound (2), a compound (3) containing fluorine and at least one element A selected from the group consisting of boron, phosphorus, and sulfur, and a solvent to obtain a catalyst precursor solution, a step (2) of removing the solvent from the catalyst precursor solution, and a step (3) of heat-treating a solid residue, obtained in the step (2), at a temperature of 500 to 1100° C. to obtain an electrode catalyst; a portion or the entirety of the metal compound (1) being a compound containing, as a metal element, at least one transition metal element M1 selected from the elements of group 4 and group 5 of the periodic table; and at least one of the compounds (1), (2), and (3) having an oxygen atom.

Use of supported ionic liquid phase (silp) catalyst systems in the hydroformylation of olefin-containing mixtures to aldehyde mixtures with a high content of aldehydes unbranched in the 2 position

The present invention provides a composition comprising: a) an inert porous support material, b) an ionic liquid, c) a metal selected from group 9 of the Periodic Table of the Elements, d) a phosphorus-containing organic ligand, e) at least one organic amine. The present invention further provides a process for hydroformylating olefin-containing hydrocarbon mixtures to aldehydes with addition of the inventive composition as a catalytically active composition, wherein: a) the water content of the olefin-containing hydrocarbon mixture is adjusted to not more than 20 ppm, b) the content of polyunsaturated compounds in the olefin-containing hydrocarbon mixture is adjusted to not more than 3000 ppm, c) a molar ratio of organic amines according to claims 10 - 13 to phosphorus-containing organic ligands according to claims 8 - 9 of at least 4:1 is established, d) a molar ratio of phosphorus-containing organic ligands according to claims 8 - 9 to rhodium of at least 10:1 is established.

QUATERNARY AMMONIUM SALT

A quaternary ammonium salt represented by formula () 2. The quaternary ammonium salt according to claim 1 , wherein the quaternary ammonium salt represented by formula (5) is an optically active compound based on the asymmetric carbon atom of C*.3. The quaternary ammonium salt according to claim 1 , wherein both Rand Rin formula (5) are a methyl group.4. The quaternary ammonium salt according to claim 1 , wherein both Rand Rin formula (5) are a methyl group.5. The quaternary ammonium salt according to claim 1 , wherein Rin formula (5) is an ethyl group claim 1 , a butyl group claim 1 , a hexyl group claim 1 , an octyl group claim 1 , a 2-phenylethyl group claim 1 , or a p-tolyl group.7. The production method according to the claim 6 , wherein the quaternary ammonium salt represented by formula (5) and the cyclopropane compound represented by formula (3) are both optically active.8. The quaternary ammonium salt according to claim 2 , wherein both Rand Rin formula (5) are a methyl group.9. The quaternary ammonium salt according to claim 2 , wherein both Rand Rin formula (5) are a methyl group.10. The quaternary ammonium salt according to claim 3 , wherein both Rand Rin formula (5) are a methyl group.11. The quaternary ammonium salt according to claim 2 , wherein Rin formula (5) is an ethyl group claim 2 , a butyl group claim 2 , a hexyl group claim 2 , an octyl group claim 2 , a 2-phenylethyl group claim 2 , or a p-tolyl group.12. The quaternary ammonium salt according to claim 3 , wherein Rin formula (5) is an ethyl group claim 3 , a butyl group claim 3 , a hexyl group claim 3 , an octyl group claim 3 , a 2-phenylethyl group claim 3 , or a p-tolyl group.13. The quaternary ammonium salt according to claim 4 , wherein Rin formula (5) is an ethyl group claim 4 , a butyl group claim 4 , a hexyl group claim 4 , an octyl group claim 4 , a 2-phenylethyl group claim 4 , or a p-tolyl group. The present invention relates to a quaternary ammonium salt and a method for producing ...

PREPARATION OF POLYISOCYANATES HAVING ISOCYANURATE GROUPS AND THEIR USE

The present invention relates to a novel process for preparing polyisocyanates having isocyanurate groups by a partial trimerization of (cyclo)aliphatic diisocyanates in the presence of at least one trimerization catalyst from the group of ammonium salts of lactames and to the use of the thus obtainable polyisocyanates having isocyanurate groups as a polyisocyanate component in polyurethane coatings. 1. A process for preparing isocyanurate-containing polyisocyanates , the process comprising at least partly trimerizing at least one (cyclo)aliphatic diisocyanate in the presence of at least one trimerization catalyst comprising at least one salt comprising a tetrasubstituted ammonium cation and an anion of a lactam.3. The process according to claim 2 , wherein Rto Rare independently selected from the group consisting of methyl claim 2 , ethyl claim 2 , 2-hydroxyethyl claim 2 , 2-hydroxypropyl claim 2 , n-propyl claim 2 , isopropyl claim 2 , n-butyl claim 2 , sec-butyl claim 2 , tert-butyl claim 2 , pentyl claim 2 , hexyl claim 2 , heptyl claim 2 , octyl claim 2 , 2-ethylhexyl claim 2 , nonyl claim 2 , decyl claim 2 , dodecyl claim 2 , phenyl claim 2 , α- or β-naphthyl claim 2 , benzyl claim 2 , cyclopentyl and cyclohexyl.4. The process according to claim 2 , wherein a sum of carbon atoms in the radicals Rto Ris at least 11.5. The process according to claim 2 , wherein Ris selected from the group consisting of methylene claim 2 , 1 claim 2 ,2-ethylene claim 2 , 1 claim 2 ,3-propylene claim 2 , 1 claim 2 ,3-butylene claim 2 , 1 claim 2 ,4-butylene claim 2 , 1 claim 2 ,5-pentylene claim 2 , 1 claim 2 ,5-hexylene claim 2 , 1 claim 2 ,6-hexylene claim 2 , 1 claim 2 ,8-octylene claim 2 , 1 claim 2 ,10-decylene claim 2 , 1 claim 2 ,12-dodecylene claim 2 , 2-oxa-1 claim 2 ,4-butylene claim 2 , 3-oxa-1 claim 2 ,5-pentylene and 3-oxa-1 claim 2 ,5-hexylene.6. The process according to claim 1 , wherein the ammonium cation is selected from the group consisting of tetraoctylammonium ...

MONOCHLOROSILANE, PROCESS AND APPARATUS FOR THE PREPARATION THEREOF

The invention relates to a process for preparing monochlorosilane by reaction of monosilane and dichlorosilane in the presence of a catalyst. In the process of the invention, monochlorosilane is formed by comproportionation of monosilane and dichlorosilane. The invention further relates to the use of the monochlorosilane produced and also a plant for carrying out the process. 1. A process for preparing monochlorosilane , the process comprising reacting monosilane and dichlorosilane in the presence of a catalyst to form monochlorosilane.2. The process according to claim 1 , wherein the monosilane and the dichlorosilane are comproportionated in the presence of the catalyst.3. The process according to claim 2 , wherein the comproportionation occurs with a defined molar ratio of monosilane to dichlorosilane.4. The process of claim 1 , wherein monochlorosilane is formed from monosilane and dichlorosilane in a continuous process.5. The process of claim 1 , wherein monosilane and dichlorosilane are fed separately claim 1 , in admixture or in countercurrent into a reaction region.6. The process of claim 2 , wherein the comproportionation occurs claim 2 , in a reaction region of a reactor.7. The process of claim 1 , wherein at least part of a crude product is separated in at least one downstream thermal separation into monochlorosilane claim 1 , monosilane claim 1 , dichlorosilane and optionally trichlorosilane and/or tetrachlorosilane.8. The process of claim 1 , wherein formation of trichlorosilane and/or tetrachlorosilane is substantially suppressed.9. The process of claim 1 , wherein monosilane and/or dichlorosilane present after the reaction and optionally a thermal separation process step are returned claim 1 , in each case independently or in admixture claim 1 , as starting materials to a reaction region.10. The process of claim 1 , wherein the catalyst is supported.11. The process of claim 1 , wherein the catalyst comprises an aminoalkoxysilane or a hydrolysis and/or ...

Iodoarene derivative, method for manufacturing optically active spirolactone compound by using the same, and method for manufacturing optically active cycloadduct

An optically active spirolactone compound is highly enantioselectively produced by using an iodoarene derivative which can be synthesized easily and which is not racemized easily. A hypervalent iodine compound precursor (iodoarene derivative) which was able to be designed flexibly was synthesized from 2,6-dihydroxyiodoarene by using 1,2-aminoalcohol as a chiral source in short steps, a hypervalent iodine compound was prepared in a reaction system (in situ) by using a catalyst quantity of the resulting precursor in the presence of a stoichiometric quantity of m-CPBA, and a spirolactonization reaction of 3-(1-hydroxy-2-naphthyl)propionic acid was induced. As a result, a corresponding spirolactone compound was obtained at a high enantiomeric excess.

Alkylation Process Using Phosphonium-Based Ionic Liquids

A process for making an alkylate is presented. The process includes mixing an isoparaffin stream with an olefin stream in an alkylation reactor. The alkylation reactor includes a catalyst for performing the reaction. The catalyst is an ionic liquid that is a quaternary phosphonium based ionic liquid, and the reaction is performed at or near ambient temperatures.

Alkylation Process Using Phosphonium-Based Ionic Liquids

A process for making an alkylate is presented. The process includes mixing an isoparaffin stream with an olefin stream in an alkylation reactor. The alkylation reactor includes a catalyst for performing the reaction. The catalyst is an ionic liquid that is a quaternary phosphonium based ionic liquid, and the reaction is performed at or near ambient temperatures.

Alkylation Process Using Phosphonium-Based Ionic Liquids

A process for making an alkylate is presented. The process includes mixing an isoparaffin stream with an olefin stream in an alkylation reactor. The alkylation reactor includes a catalyst for performing the reaction. The catalyst is an ionic liquid that is a quaternary chloroaluminate based ionic liquid, and the reaction is performed at or near ambient temperatures.

Cross-Linked Carbon Nanotube Networks

The present invention relates to a method for the production of cross-linked carbon nanotube networks which are selected from aerogels and xerogels with improved performance and characteristics thereof. The invention is also concerned with carbon nanotube networks which are selected from aerogels and xerogels produced by such processes and uses thereof. 1. A method of producing a carbon nanotube network which is selected from an aerogel and a xerogel comprising the steps of:a) dispersing carbon nanotubes in a solvent compatible with said carbon nanotubes;b) cross-linking said carbon nanotubes using functional groups already present on the carbon nanotubes or with a linking molecule comprising at least two functional sites capable of reacting with the surface of said carbon nanotubes, to form a covalently cross-linked gel network; andc) removing said solvent to give a cross-linked carbon nanotube network which is selected from an aerogel and a xerogel with a solvent content of less than 10%.2. The method according to claim 1 , wherein said carbon nanotubes are oxidised carbon nanotubes and wherein said cross-linking is carried out by direct reaction between the surface oxides on the nanotube surface.3. The method according to claim 1 , wherein said carbon nanotubes are oxidised carbon nanotubes and wherein said cross-linking is carried out with a linking molecule selected from the group consisting of alkyl diamines claim 1 , aromatic diamines claim 1 , alkyl diols claim 1 , aromatic diols claim 1 , polyols claim 1 , bis-sodium alkoxides claim 1 , dicarboxylic acids claim 1 , di acid chlorides claim 1 , di siloxane halides and di siloxane alkoxides.4. The method according to claim 2 , wherein said surface oxides are selected from the group consisting of hydroxide claim 2 , carboxylate claim 2 , lactone claim 2 , hydroxyl claim 2 , quinone claim 2 , carboxylic acid groups claim 2 , and mixtures thereof.5. The method according to claim 1 , wherein said cross-linking is ...

ISOMERISATION CATALYST

The present invention relates to a process for preparing menthol isomers by selective rearrangement of stereoisomers of menthol or mixtures thereof in the presence of ruthenium-containing supported catalysts doped with or comprising alkaline earth metal alkoxides, and to the catalysts themselves. 1. Catalyst comprising ruthenium applied to a support material , the support material being aluminium oxide , characterized in thatthe catalyst comprises at least one alkaline earth metal alkoxylate oris obtainable by reacting a catalyst comprising ruthenium applied to a support material, the support material being aluminium oxide, with at least one alkaline earth metal alkoxylate.2. Catalyst according to claim 1 , characterized in that the aluminium oxide used as the support material has a BET surface area of at least 100 m/g.3. Catalyst according to or claim 1 , characterized in that the ruthenium content is 0.1 to 35% by weight.5. Catalyst according to claim 4 , characterized in that the alkaline earth metal alkoxylates used are those of the formula (I) in whichM is barium.6. Catalyst according to any of to claim 4 , characterized in that the amount of the alkaline earth metal alkoxylate which is used for preparation of the inventive catalyst is selected such that the molar ratio of ruthenium to alkaline earth metal is 30:1 to 1:30.7. Use of the catalysts according to any of to for isomerization of stereoisomers of menthol or mixtures of such stereoisomers.8. Process for isomerizing stereoisomers of menthol or mixtures of such stereoisomers in the presence of a catalyst according to any of to .9. Process according to claim 8 , characterized in that d claim 8 ,l-menthol is prepared by catalytic isomerization of stereoisomers of menthol or mixtures of these stereoisomers.10. Process according to claim 8 , characterized in that(+)-menthol (D-menthol) is isomerized to (−)-neomenthol or(−)-menthol (L-menthol) to (+)-neomenthol or(+)-isomenthol to (−)-neoisomenthol or(−)- ...

FENTON REACTION CATALYST PRODUCED USING REDUCING ORGANIC SUBSTANCE AS RAW MATERIAL

To develop a Fenton reaction catalyst that can maintain divalent iron stably for a long period of time, can utilize trivalent iron or metallic iron, which is an inexpensive iron-supplying source, by converting into divalent iron, and is harmless to the human body and the environment, provided is a Fenton reaction catalyst, including, as an active component, a reaction product obtained by mixing a specific reducing organic substance (e.g., ascorbic acid, a polyphenol-containing plant component, or a plant dry distillation liquid component) with an iron-supplying source at a predetermined ratio in the presence of water. Also provided are a sterilization method, a pollutant degradation method, and a luminescence method based on chemiluminescence, which involve using the Fenton reaction catalyst. 1. A Fenton reaction catalyst , comprising , as an active component , a reaction product obtained by mixing reducing organic substances with an iron-supplying source in the presence of water under any one of the following conditions (A) to (C):(A): a condition where the reducing organic substance is ascorbic acid; and the ascorbic acid is mixed in a molar amount of 0.01 to 5 times that of an iron element supplied from the iron-supplying source;(B): a condition where the reducing organic substance is a reducing organic substance contained in a polyphenol-containing plant; and the polyphenol-containing plant is mixed in an amount of 0.01 to 1,000 g in terms of a polyphenol with respect to 1 mol of an iron element supplied from the iron-supplying source; and(C): a condition where the reducing organic substance is a reducing organic substance contained in a plant dry distillation liquid; and the plant dry distillation liquid is mixed in an amount of 0.1 to 200 kg in terms of a stock solution with respect to 1 mol of an iron element supplied from the iron-supplying source.2. The Fenton reaction catalyst according to claim 1 , wherein the iron-supplying source is a trivalent iron ...

Production of catalytically active activated carbons

The invention is directed to a method for preparing catalytically active activated carbon, to catalytically active activate carbon obtainable by the method, and to the use of the catalytically active activated carbon. The method of the invention method comprises the steps of: i) mixing charcoal with one or more organic nitrogen-containing compounds, said nitrogen-containing compounds comprising, next to a first nitrogen atom, at least two or more further heteroatoms selected from the group consisting of nitrogen and oxygen, wherein said further heteroatoms have a lone pair; ii) drying the mixture obtained in step i); iii) activating the dried mixture using steam, thereby producing catalytically active activated carbon.

METAL OXIDE-PLATINUM COMPOUND CATALYST AND METHOD FOR PRODUCING SAME

The present invention relates to a metal oxide-platinum compound catalyst comprising 5 to 95 parts by weight of a metal oxide and 95 to 5 parts by weight of platinum as the balance. The platinum has a form to reticulately cover at least a part of a particle of the metal oxide. The wires constituting the platinum mesh have an average wire diameter of 5 nm or smaller. 1. A metal oxide-platinum composite catalyst , comprising:5 to 95 parts by weight of a metal oxide; and95 to 5 parts by weight of platinum as the balance,wherein the platinum has a form to reticulately cover at least a part of a particle of the metal oxide; andwires constituting the platinum mesh have an average wire diameter of 5 nm or smaller.2. The metal oxide-platinum composite catalyst according to claim 1 ,wherein a fluoro group-containing compound or an alkyl group-containing compound is adsorbed on a surface of the metal oxide, or a reaction product of the compound with the metal oxide is formed thereon.3. The metal oxide-platinum composite catalyst according to claim 1 ,wherein the metal oxide is one or two or more metal oxides selected from silica, zirconia and ceria.4. The metal oxide-platinum composite catalyst according to claim 1 ,wherein the metal oxide-platinum composite catalyst has a surface having an average contact angle to water of 15 degrees or larger.5. A method for manufacturing a metal oxide-platinum composite catalyst claim 1 , comprising:a dispersion step of dispersing 5 to 95 parts by weight of a metal oxide in a dispersion medium;a dissolution step of dissolving chloroplatinic acid in a solvent containing ethylenediamine so that 95 to 5 parts by weight of platinum is contained as the balance to the metal oxide;a raw material solution preparation step of mixing the metal oxide dispersion solution obtained by the dispersion step and the chloroplatinic acid solution obtained by the dissolution step to thereby prepare a raw material solution;a spray step of spraying the raw ...

Extracted conjunct polymer naphtha

We provide an extracted conjunct polymer naphtha ( 45 ), comprising a hydrogenated conjunct polymer naphtha, from a used ionic liquid catalyst, having a final boiling point less than 246° C. (475° F.), a Bromine Number of 5 or less, and at least 30 wt % naphthenes. We also provide a blended alkylate gasoline ( 97 ) comprising the extracted conjunct polymer naphtha ( 45 ), and integrated alkylation processes to make the extracted conjunct polymer naphtha ( 45 ) and the blended alkylate gasoline ( 97 ). We also provide a method to analyze alkylate products, by determining an amount of methylcyclohexane in the alkylate products ( 80 ).

Hydrogen recycle and hydrogen cloride recovery in an alkylation process

We provide an alkylation process, comprising: separating and recycling a hydrogen gas and a hydrogen chloride from an offgas of a hydrogenation reactor; wherein the hydrogen gas is recycled to the hydrogenation reactor; and wherein the hydrogen chloride is recycled to an alkylation reactor. We also provide an alkylation process unit for performing this process.

Methods to Store Transition Metal Organophosphorous Ligand Based Catalysts

The catalyst solution used in a hydroformylation process is prepared for storage by first reducing its acid concentration and/or water content, and then storing the solution under a blanket of syngas and/or an inert gas. Alternatively, or in addition to, the catalyst solution can be stored with an aqueous buffer comprising materials that will neutralize and/or absorb the acid species within the catalyst solution. 2. The method of in which the acid concentration is reduced by one or more of extraction claim 1 , base addition and precipitation.3. The method of in which the water content of the catalyst solution is reduced to no more than 0.8 wt %.5. The method of in which the aqueous buffer solution comprises at least one of a substituted amine or an epoxide.6. The method of in which the catalyst solution is stored with the aqueous buffer solution as a separate phase in contact with the catalyst solution.7. The method of in which the catalyst solution and aqueous buffer solution are stored in a mixed and agitated state.8. The method of in which the catalyst solution is stored under a blanket of syngas.9. The method of in which the catalyst solution is stored under a blanket of an inert gas.10. The method of in which the catalyst solution is stored under a blanket of syngas in combination with one or more inert gases.11. The method of in which the catalyst solution is stored within equipment of the hydroformylation process.12. The method of in which the catalyst solution is stored outside of the equipment of the hydroformylation process.13. The method of in which the transition metal of the hydroformylation catalyst is rhodium.14. The method of in which the acidic species include aldehyde-phosphonic and phosphoric acids.15. The method of in which the catalyst solution is stored under a blanket of syngas.16. The method of in which the catalyst solution is stored under a blanket of an inert gas.17. The method of in which the catalyst solution is stored under a blanket of ...

SULFONATED CARBON SILICA COMPOSITE MATERIAL AND A PROCESS FOR THE PREPARATION THEREOF

The present invention relates to a novel sulfonated carbon silica (SCS) composite material and a process for the preparation thereof. The synthesized SCS composite material on calcination yields the hierarchical mesoporous silica (MS) and further finds application as catalyst in two industrially important reactions namely phenol butylation and glycerol acetalization. 16.-. (canceled)7. A process of preparing a Sulfonated carbon silica (SCS) composite comprising:(a) gradually mixing a saccharide with a silica source and a sulfuric acid to form a reaction mixture, wherein a ratio between saccharide and the silica source is in the range of about 0.385 to about 4.25 and a quantity of the sulphuric acid is in the range of 0.234 to 1.020 M;(b) allowing a hydrolyzing reaction to progress in the mixture reaction by maintaining the reaction mixture at a temperature in the range of about 298 K to 320 K for a period in the range of about 2 to about 5 hours to effect hydrolyzation thereby to obtain a gel;(c) treating the gel thus obtained in step (b) at a temperature in the range of about 350 K to about 423 K for a period in the range of about 12 hours to about 18 hours to obtain a bulk solid mass; and(d) heating the bulk solid mass as obtained in (c) at a temperature in range of about 473 K to about 573 K for a period in the range of about 4 hours to about 8 hours under nitrogen gas to obtain the sulfonated carbon silica (SCS) composite.8. The process according to claim 7 , wherein step (c) comprises treating the gel as obtained in step (b) inside a Teflon-lined autoclave at a temperature in the range of about 350 K to about 423 K for a period in the range of about 12 hours to about 18 hours to obtain bulk solid mass.9. The process according to claim 7 , further comprising washing the sulfonated carbon silica composite at least once.10. The process according to claim 9 , further comprising drying the sulfonated carbon silica composite.11. The process according to claim 9 , ...

METHOD FOR PREPARING 5-CHLOROMETHYL-2-FURFURAL USING GALACTAN DERIVED FROM SEAWEED IN TWO COMPONENT PHASE

The present disclosure relates to an acid catalyst composition for producing 5-chloromethyl-2-furfural from galactan derived from seaweed and a method for producing 5-chloromethyl-2-furfural from galactan derived from seaweed on a two component phase using the acid catalyst, the acid catalyst composition for producing 5-chloromethyl-2-furfural from galactan derived from seaweed including organic solvent and dilute hydrochloric acid, a concentration of the dilute hydrochloric acid being 4N to 8N (normal). 1. An acid catalyst composition for producing 5-chloromethyl-2-furfural from galactan derived from seaweed , the composition comprising:an organic solvent and dilute hydrochloric acid,wherein a concentration of the dilute hydrochloric acid is 4N to 8N (normal).2. The acid catalyst composition according to claim 1 ,wherein the dilute hydrochloric acid is 30 to 200 parts by weight of 100 parts by weight of the organic solvent.3. The acid catalyst composition according to claim 1 ,wherein the organic solvent is halogenated hydrocarbon solvent.4. The acid catalyst composition according to claim 3 ,wherein the halogenated hydrocarbon solvent is at least one of Dichloromethane, Chloroform, 1,2-Dichloroethane or 1,1,2-Trichloroethane.5. The acid catalyst composition according to claim 1 ,wherein the galactan is 10 g to 300 g in 1 L of the dilute hydrochloric acid.6. The acid catalyst composition according to claim 1 ,wherein the galactan comprises agarose.7. A method for producing 5-chloromethyl-2-furfural from galactan derived from seaweed in two-component phase claim 1 , the method comprising:mixing the galactan, a first organic solvent and dilute hydrochloric acid to produce a mixture; andreacting the mixture by heating to produce a reactant.8. The method according to claim 7 , further comprising:adding distilled water and a second organic solvent to the reactant;removing the first and the second organic solvent from the reactant;dissolving dichloromethane in the ...

Bis(Trifluoromethanesulfonyl)Ethyl-Bearing Compound and Acid Catalyst, and Method for Preparing Same

A bis(trifluoromethanesulfonyl)ethyl group-bearing compound represented by the following formula [1], [2] or [3]

Catalytic Article for Decomposing Volatile Organic Compound and Method for Preparing the Same

A catalytic article for decomposition of a volatile organic compound includes a porous support body, a plurality of active centers formed on the support body and adapted for catalytic decomposition of the volatile organic compound, and a plurality of capture centers bound to the support body. Each of the active centers is composed of one of a noble metal, a transition metal oxide, and the combination thereof. Each of the capture centers includes at least one functional group that is adapted for attracting or binding the volatile organic compound. A method for preparing the catalytic article is also disclosed.

Process for producing 1,3-butadiene by dimerizing ethylene and dehydrogenating the butenes obtained

The present invention describes a process for the production of 1,3-butadiene from ethylene by dimerizing ethylene into butenes using homogeneous catalysis and dehydrogenating the butenes obtained.

REACTIVE EXTRACTION PROCESS FOR REGENERATION OF AMINE-BASED SOLVENTS USED FOR CARBON DIOXIDE CAPTURE

A method for recovery of impurities and/or degradation products and/or heat-stable salts from amine-based solvents used for capture of C0from gas streams. The method comprises recovering C0from a C0-enriched amine-based solvent thereby producing a lean amine-based solvent, contacting and mixing together the lean amine-based solvent with a reaction composition comprising a phase-change catalyst and a diluent, thereby producing a first organic phase comprising the impurities and/or degradation products and/or heat-stable salts and a first aqueous phase comprising the lean amine-based solvent, separating the first organic phase and the first aqueous phase; and separately recovering the first organic phase and the first aqueous phase. The organic phase can be regenerated by intermixing with a NaOH solution to form an organic phase comprising therein the reaction composition and and an aqueous phase comprising the NaOH solution with the impurities and/or degradation products and/or heat-stable salts. 1. A one-stage method for recovery of impurities and/or degradation products and/or heat-stable salts from spent amine-based solvents used for capture of COfrom gas streams , the method comprising:{'sub': 2', '2, 'recovering COfrom a spent CO-enriched amine-based solvent thereby producing a lean amine-based solvent;'}contacting and mixing together the lean amine-based solvent with a reaction composition comprising a phase-change catalyst and a diluent, thereby producing a first organic phase comprising the impurities and/or degradation products and/or heat-stable salts and a first aqueous phase comprising a purified lean amine-based solvent;separating the first organic phase and the first aqueous phase; andseparately recovering the first organic phase and the first aqueous phase.2. The one-stage method of claim 1 , additionally comprising a step of recycling the purified lean amine-based solvent for capturing COfrom a gas stream.3. The one-stage method of claim 1 , ...

NON-IONIC DEEP EUTECTIC MIXTURES FOR USE AS SOLVENTS AND DISPERSANTS

Use of a non-ionic deep eutectic mixture consisting of A and B, A being R1R2N—CO—NR3R4 and B being selected from the group consisting of R5R6N—CO—CH3 and R7R8N—CO—NR9R10, and wherein each of R1-R10 is independently H, CH3 or alkyl, as a solvent or dispersant in chemical synthesis, material synthesis or fabrication, chemical or enzymatic catalysis, food, cosmetic or pharmaceutical formulation, separation or partitioning, heat transfer, and as detergents or cleaners, as well as such mixtures, is disclosed. 1. A method comprising using a non-ionic deep eutectic mixture consisting of A and B , A being RRN—CO—NRRand B being selected from the group consisting of RRN—CO—CHand RRN—CO—NRR , and wherein each of R-Ris independently H , CH3 or alkyl , as a solvent or dispersant in chemical synthesis , material synthesis or fabrication , chemical or enzymatic catalysis , food , cosmetic or pharmaceutical formulation , separation or partitioning , heat transfer , and as detergents or cleaners.2. The method according to claim 1 , wherein B is RRN—CO—CH claim 1 , wherein Rand Rare CHor alkyl claim 1 , R claim 1 , R claim 1 , and Rare H claim 1 , and Ris H or CHor alkyl.3. The method according to claim 1 , wherein B is RRN—CO—NRR claim 1 , wherein Rand Ris H or CHor alkyl claim 1 , Rand Ris H claim 1 , Ris CHor alkyl claim 1 , Ris H claim 1 , and Rand Ris H or CHor alkyl.4. The method according to claim 1 , wherein the mixture contains 30-80% by weight of A and 70-20% by weight of B.5. The method according to claim 1 , wherein the melting point of the mixture is 8-99° C. claim 1 , such as 8-71° C. claim 1 , such as 12-46° C.6. The method according to claim 1 , wherein Ris CH claim 1 , Rand Ris H and Ris H or CH.7. The method according to claim 6 , wherein B is RRN—CO—CH claim 6 , Ris H claim 6 , and Ris CHor H claim 6 , preferably CH.8. The method according to claim 7 , wherein the mixture contains 70-80% by weight of A and 30-20% by weight of B.9. The method according to claim 6 , ...

CATALYZED AND GREEN PROCESS OF MALATHION

The present invention relates to an improved synthesis of malathion. The presence of an acid facilitates the reaction between O,O-dimethyldithiophosphoric acid (O,O-DMDTPA) and maleate and leads to excellent product yield in shorter reaction time with fewer impurities. 1. A method of producing malathion , comprising reacting O ,O-dimethyldithiophosphoric acid (O ,O-DMDTPA) with diethyl maleate in the presence of an acid.2. The method of claim 1 , further comprising claim 1 , prior to reacting the O claim 1 ,O-dimethyldithiophosphoric acid (O claim 1 ,O-DMDTPA) with the maleate claim 1 ,(a) mixing the O,O-dimethyldithiophosphoric acid (O,O-DMDTPA) with the acid to form a mixture; and(b) adding the diethyl maleate to the mixture.3. The method of claim 2 , wherein the temperature of step (a) is controlled at between about 5 and about 20° C.4. The method of claim 2 , wherein the temperature of step (b) is controlled at between about 10 and about 25° C.5. The method of claim 2 , wherein the temperature is controlled at between about 20 and about 50° C. after completing the addition of the diethyl maleate to the mixture.6. The method of claim 2 , wherein the temperature is controlled at between about 35 and about 45° C. after completing the addition of the diethyl maleate to the mixture.7. The method of claim 1 , wherein the acid ranges from about 0.1% to about 20% in the mixture of step (a) by weight.8. The method of claim 1 , wherein the acid ranges from about 1% to about 10% in the mixture of step (a) by weight.9. The method of claim 1 , wherein the acid is hydrochloric acid or sulfuric acid.10. The method of claim 1 , wherein the acid is hydrochloric acid having a concentration ranging from about 20% to about 37% by weight claim 1 , or sulfuric acid having a concentration ranging from about 70% to about 98% by weight.11. The method of claim 1 , wherein the acid consists essentially of saturated hydrochloric acid.12. The method of claim 1 , wherein the molar ratio ...

COMPOSITION HAVING AN ACTIVE METAL OR PRECURSOR, AN AMINE COMPONENT AND A NON-AMINE CONTAINING POLAR ADDITIVE USEFUL IN THE CATALYTIC HYDROPROCESSING OF HYDROCARBONS, A METHOD OF MAKING SUCH CATALYST, AND A PROCESS OF USING SUCH CATALYST

A composition that comprises a support material that is loaded with an active metal or metal precursor, an amine component, and a non-amine containing polar additive. The composition is useful in the hydroprocessing of hydrocarbon feedstocks. The composition is prepared by incorporating a metal solution into a support material followed by incorporating therein an amine component and a non-amine containing polar additive. 1. A method of making a composition , wherein said method comprises: incorporating a metal-containing solution into a support material to provide a metal-incorporated support material; and incorporating both an amine component and a non-amine containing polar additive into said metal-incorporated support material to thereby provide an impregnated composition comprising said support material , said amine component , and said non-amine containing polar additive.2. A method as recited in claim 1 , further comprising: contacting said impregnated composition under suitable hydrogen treatment conditions with hydrogen to thereby provide a hydrogen-treated composition.3. A method as recited in claim 2 , wherein prior to said incorporating of said amine component and said non-amine containing polar additive into said metal-incorporated support material claim 2 , said metal-incorporated support material is dried so as to contain a volatiles content in the range of from 3 to 20 wt. % LOI.4. A method as recited in claim 1 , wherein the weight ratio of said non-amine containing polar additive to said amine component is in the range of upwardly to 10:1; wherein said amine component is selected from the group of compounds consisting of ether amine compounds claim 1 , alkyl amine compounds claim 1 , and amine oxide compounds; and wherein said amine compound has a molecular weight greater than 160 and a flash point of at least 80° C.5. A method as recited in claim 4 , wherein said amine component is an ether amine compound.6. A method as recited in claim 5 , wherein ...

CATALYST COMPOSITIONS FOR SELECTIVE DIMERIZATION OF ETHYLENE

A catalyst composition comprises an inert hydrocarbon solvent, having dissolved therein a titanate of the formula Ti(OR)wherein each R is the same or different, and is a hydrocarbon residue, and an organic aluminum compound, wherein a molar ratio of the organic aluminum compound and any alkene present in the catalyst composition is greater than one. 1. A catalyst composition , comprising: [{'sub': '4', 'a titanate of the formula Ti(OR)wherein each R is the same or different, and is a hydrocarbon residue, and'}, 'an organic aluminum compound,, 'an inert hydrocarbon solvent, having dissolved therein'}wherein a molar ratio of the organic aluminum compound and any alkene present in the catalyst composition is greater than one.2. The composition of claim 1 , wherein the titanate is pre-treated with the inert hydrocarbon solvent in the absence of the aluminum compound.3. The catalyst composition of claim 1 , wherein the inert hydrocarbon solvent is an alkane or an aromatic hydrocarbon.4. The catalyst composition of claim 1 , wherein the ratio of aluminum to titanium in the catalyst composition is about 1:1 to about 40:1.5. The catalyst composition of claim 1 , further comprising a catalyst modifier claim 1 , wherein the catalyst modifier is an amine claim 1 , an ether claim 1 , a silicate claim 1 , a silazane claim 1 , a fluorinated hydrocarbon claim 1 , or a combination comprising at least one of the foregoing.6. The catalyst composition according to claim 1 , wherein one or more of the following conditions is met:the content of compounds comprising a carbon chain of more than 20 carbon atoms is less than 0.1 wt. %, based on the total weight of the catalyst composition; orthe content of a polymer comprising 5 or more repeat units is less than 0.1 wt. %, based on the total weight of the catalyst composition.7. The catalyst composition according to claim 1 , wherein{'sub': 4', '4', '4, 'the titanate is Ti(O-butyl), Ti(O-n-alkyl), Ti(O-n-butyl), or a combination comprising ...

Catalysts for Producing Isocyanurates from Isocyanates

The invention relates to a method for producing isocyanurates and isocyanurate-containing polyurethanes, comprising the step of reacting an isocyanate in the presence of a catalyst. 1. A process for producing isocyanurates and isocyanurate-containing polyurethanes comprising reacting an isocyanate in the presence of a catalyst ,wherein:the catalyst comprises the product of the reaction of a thiol group containing carboxylic acid with an alkali metal, alkaline earth metal, scandium-group or lanthanoid base,wherein the reaction is performed in the absence of compounds comprising tin or lead,wherein the degree of deprotonation of the catalyst is ≧50% to ≦100% and the H atoms present in carboxyl groups as well as the carboxylate groups and the H atoms present in thiol groups as well as the thiolate groups are considered when calculating the degree of deprotonation.2. The process as claimed in claim 1 , wherein the thiol group containing carboxylic acid comprises a thiol group and a carboxyl group.3. The process as claimed in claim 2 , wherein the thiol group containing carboxylic acid is selected from the group consisting of 2-mercaptoacetic acid claim 2 , 3-mercaptopropionic acid claim 2 , 4-mercaptobutyric acid claim 2 , thiosalicylic acid claim 2 , and combinations of any thereof.4. The process as claimed in claim 1 , wherein the degree of deprotonation of the catalyst is ≧70% to ≦100% and the H atoms present in carboxyl groups as well as the carboxylate groups and the H atoms present in thiol groups as well as the thiolate groups are considered when calculating the degree of deprotonation.5. The process as claimed in claim 1 , wherein the base for deprotonating the catalyst precursor is selected from the group consisting of an alkali metal claim 1 , alkaline earth metal claim 1 , scandium-group or lanthanoid hydride claim 1 , an alkali metal claim 1 , alkaline earth metal claim 1 , scandium-group or lanthanoid alkoxide or an alkali metal claim 1 , alkaline earth ...

Rh-C3N4 HETEROGENEOUS CATALYST FOR PREPARING ACETIC ACID BY CARBONYLATION REACTION

This invention relates to a catalyst for use in the preparation of acetic acid through a methanol carbonylation reaction using carbon monoxide, and particularly to a heterogeneous catalyst represented by Rh/C 3 N 4 configured such that a complex of a rhodium compound and 3-benzoylpyridine is immobilized on a carbon nitride support.

HYDROCARBON PROCESSES USING HALOMETALLATE IONIC LIQUID MICRO-EMULSIONS

A process utilizing a micro-emulsion is described. The micro-emulsion formed by contacting an ionic liquid, a co-solvent, a hydrocarbon, an optional surfactant, and an optional catalyst promoter to form the micro-emulsion. The micro-emulsion comprises a hydrocarbon component comprising the hydrocarbon and an ionic liquid component comprising the ionic liquid. The ionic liquid comprises a halometallate anion and a cation. The co-solvent has a polarity greater than a polarity of the hydrocarbon. The ionic liquid is present in an amount of 0.05 wt % to 40 wt % of the micro-emulsion. A product mixture comprising a product is produced in a process zone containing the micro-emulsion. 1. A process utilizing a micro-emulsion comprising: 'contacting an ionic liquid, a co-solvent, a hydrocarbon, an optional surfactant, and an optional catalyst promoter to form the micro-emulsion, the micro-emulsion comprising a hydrocarbon component comprising the hydrocarbon and an ionic liquid component comprising the ionic liquid, the ionic liquid comprising a halometallate anion and a cation, the co-solvent having a polarity greater than a polarity of the hydrocarbon, the ionic liquid being present in an amount of 0.05 wt % to 40 wt % of the micro-emulsion; and', 'forming the micro-emulsion comprisingproducing a product mixture in a process zone containing the micro-emulsion, the product mixture comprising a product.2. The process of wherein the hydrocarbon comprises an isoparaffin having from 4 to 10 carbon atoms; and wherein producing the product mixture in the process zone comprises passing an olefin having from 2 to 8 carbon atoms to the process zone containing the micro-emulsion claim 1 , the process zone being operated at alkylation reaction conditions to react the olefin and the isoparaffin to generate the product mixture and wherein the product comprises an alkylate.3. The process of further comprising:altering a composition of the product mixture to destroy the micro-emulsion; ...

Method for producing trichlorosilane

In order to produce high-purity trichlorosilane by removing methyldichlorosilane from a mixture (S) containing methyldichlorosilane (CH 3 HSiCl 2 ), tetrachlorosilane (SiCl 4 ), and trichlorosilane (HSiCl 3 ) in the method for producing trichlorosilane of the present invention, a procedure is employed in which chlorine atoms are redistributed between methyldichlorosilane and tetrachlorosilane through catalytic treatment for conversion into trichlorosilane and methyltrichlorosilane (CH 3 SiCl 3 ). Methyldichlorosilane (boiling point: 41° C.) having a boiling point close to that of trichlorosilane (boiling point: 32° C.) to be purified is converted into methyltrichlorosilane (boiling point: 66° C.) having a higher boiling point through redistribution of chlorine atoms between methyldichlorosilane and tetrachlorosilane, achieving easy removal of impurities.

PROCESS FOR THE SELECTIVE DIMERISATION OF ETHYLENE TO 1-BUTENE

The invention concerns a process for the selective dimerization of ethylene to 1-butene employing a catalytic composition comprising at least one alkoxy or aryloxy titanium compound, at least one additive selected from ether type compounds and at least one aluminium compound. 1. A process for the selective dimerization of ethylene to 1-butene using a catalytic composition comprising at least one alkoxy or aryloxy titanium compound , at least one additive selected from ether type compounds and at least one aluminium compound , in which the molar ratio between the additive and the alkoxy or aryloxy titanium compound is strictly more than 10 and the molar ratio between the aluminium compound and the alkoxy or aryloxy titanium compound is strictly more than 4.2. The process according to claim 1 , in which the molar ratio between the additive and the alkoxy or aryloxy titanium compound of the catalytic composition is in the range 11 to 19.3. The process according to claim 1 , in which the molar ratio between the aluminium compound and the alkoxy or aryloxy titanium compound of the catalytic composition is in the range 5 to 15.4. The process according to claim 1 , in which the alkoxy titanium compound has the general formula [Ti(OR)] claim 1 , in which R is a linear or branched alkyl radical containing 2 to 30 carbon atoms.5. The process according to claim 1 , in which the aryloxy titanium compound has the general formula [Ti(OR′)] claim 1 , in which R′ is an aryl radical which may or may not be substituted with alkyl claim 1 , aryl or aralkyl groups containing 2 to 30 carbon atoms.6. The process according to claim 1 , in which the aluminium compound is selected from the group formed by hydrocarbylaluminium compounds claim 1 , tris(hydrocarbyl)aluminium compounds claim 1 , chlorine-containing or bromine-containing hydrocarbylaluminium compounds and aluminoxanes.7. The process according to claim 6 , in which the aluminium compound is selected from the group formed by ...

Catalytic composition and process for the selective dimerization of ethylene to 1-butene

The invention describes a catalytic composition obtained by interaction of an alkyl titanate on the one hand with a preformed mixture of an alkylaluminium and a Lewis base on the other hand. The invention also describes the use of said composition in a process for the selective dimerization of ethylene to 1-butene.

METHOD FOR PRODUCING GOLD NANOPARTICLES IN PLANTS AND GOLD NANOPARTICLES PRODUCED

The present invention relates to the field of nanotechnology, more specifically to the production of gold nanoparticles (AuNPs) from plant extracts derived from leaves, stems, seeds, flowers, fruits or latex from plant species such as and , in which naturally occurring biocatalysts are possessed by these plants. The invention also relates to the gold nanoparticles obtained from said plants as well as to said natural biocatalysts. 1. Method to obtain gold nanoparticles from plants , said method comprised the steps of:a) obtaining an extract from the plant;b) heating said extract;c) eliminating the insoluble material from said extract;d) mixing under appropriate conditions the extract soluble material with a substrate comprising a gold salt; ande) Recovering the gold nanoparticles from said mixture.2. Method according to claim 1 , wherein said extract from a plant is an aqueous extract.3. Method according to claim 2 , wherein the aqueous extract is obtained by maceration from any part of the plant selected from seeds claim 2 , steams claim 2 , flowers claim 2 , leaves claim 2 , fruits claim 2 , latex or a combination thereof.4. Method according to claim 1 , wherein said extract is heated until boiling between 1 and 10 minutes.5. Method according to claim 1 , wherein the insoluble material is eliminated by filtration.6. Method according to claim 1 , wherein said gold salt is HAuCl.3HO.7. Method according to claim 1 , wherein said appropriate conditions include continuously mixing the soluble extract with the substrate comprising the gold salt for 0.5 to 12 hours claim 1 , at a temperature between 25-27° C.8. Method according to claim 1 , wherein the gold nanoparticles are recovered from said mixture by means of a step selected from low speed centrifugation and sedimentation on standing of the mixture for at least 1 hour.9Colliguaja salicifolia, Pittosporum undulatum, Acca sellowiana, Ugni molinaeColliguaja integerrima.. Method according to claim 1 , wherein said plant ...

Photoredox-Catalyzed Direct C-H Functionalization of Arenes

The invention generally relates to methods of making substituted arenes via direct C—H amination. More specifically, methods of making para- and ortho-substituted arenes via direct C—H amination are disclosed. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention. 2. The method of claim 1 , wherein the electron donating group is selected from —OH claim 1 , —SH claim 1 , —NH claim 1 , C1-C8 alkyl claim 1 , C1-C8 alkoxy claim 1 , C1-C8 thioalkoxy claim 1 , C1-C8 alkylamino claim 1 , (C1-C8)(C1-C8) dialkylamino claim 1 , —OC(═O)R claim 1 , —NHC(═O)R claim 1 , and Ar;{'sup': 6', '7, 'wherein each of Rand Ris independently selected from C1-C8 alkyl; and'}{'sup': '2', 'wherein Aris selected from aryl and heteroaryl and substituted with 0, 1, 2, or 3 groups independently selected from halogen and C1-C8 alkyl.'}3. The method of claim 1 , wherein Z is F.48-. (canceled)12. (canceled)13. The method of claim 1 , wherein the fluoride is selected from ammonium fluoride claim 1 , cesium fluoride claim 1 , and triethylamine hydrofluoride.1415-. (canceled)16. The method of claim 1 , wherein the oxidant is molecular oxygen.17. The method of claim 1 , wherein the oxidant is 2 claim 1 ,2 claim 1 ,6 claim 1 ,6-tetramethyl-1-piperidinyloxy radical (TEMPO).1820-. (canceled)21. The method of claim 1 , wherein Z is —CN.29. The method of claim 1 , wherein the compound is isotopically-labeled.30. The method of claim 25 , wherein the compound contains a radioactive isotope.31. The method of claim 1 , wherein the compound is not isotopically-labeled. This application is a continuation of U.S. application Ser. No. 15/826,092, filed Nov. 29, 2017, which is a continuation of International Application No. PCT/US2016/035549 with an international filing date of Jun. 2, 2016, which claims priority to U.S. Provisional Application No. 62/170,632 filed on Jun. 3, 2015, the contents of which are incorporated ...

NATURAL GAS LIQUID UPGRADING BY IONIC LIQUID CATALYZED ALKYLATION

We provide a process, comprising: 1. A process for making one or more middle distillate alkylate products , comprising:a. dehydrogenating a natural gas feedstock comprising saturated hydrocarbons in a dehydrogenation reactor to produce a mixture comprising one or more olefins and one or more unconverted paraffins;b. without further purification or modification other than mixing with an isoparaffin, sending the mixture to a single alkylation reactor that is not thermally coupled with the dehydrogenation reactor;c. alkylating the one or more olefins with the isoparaffin in the single alkylation reactor, using an ionic liquid catalyst, to produce the one or more alkylate products; andd. distilling the one or more alkylate products and collecting a bottoms distillation fraction that is a middle distillate blending component having a sulfur level of 50 wppm or less and a Bromine number less than 1.2. The process of claim 1 , wherein the natural gas feedstock comprises paraffins in the range of from C2 to C6 paraffins.3. The process of claim 1 , wherein the natural gas feedstock is one of a C2 claim 1 , a C3 claim 1 , a C4 claim 1 , a C5 claim 1 , or a C6 paraffin.4. The process of claim 1 , wherein the mixture comprises from 30 to 80 wt % of the one or more unconverted paraffins.5. The process of claim 1 , wherein the one or more alkylate products are selected from the group consisting of an alkylate gasoline claim 1 , an alkylate jet fuel claim 1 , an alkylate diesel fuel claim 1 , and mixtures thereof.6. The process of claim 1 , wherein the isoparaffin is isobutane claim 1 , isopentane claim 1 , an isohexane claim 1 , or a combination thereof.7. The process of claim 1 , wherein a molar ratio of the isoparaffin to the one or more olefins in the single alkylation reactor is from 4:1 to 12:1.8. The process of claim 1 , wherein a molar ratio of the isoparaffin to the one or more olefins in the single alkylation reactor is adjusted to change a boiling range of the one or ...

Enhanced regio-selectivity in glycol acylation

A method for acid-catalyzed acylation of an isohexide is described. The method involves a reaction of an isohexide and an excess of carboxylic acid in the presence of a Lewis acid or a Brønsted acid catalyst. One or more Lewis acid or Brønsted acid can facilitate conversion of isohexides to their corresponding mono and diesters with a pronounced greater regio-selectivity of exo-OH over endo-OH of the isohexide in the product. Particular catalytic acid species include zirconium chloride (ZrCl 4 ) and phosphonic acid (H 3 PO 3 ), which manifest a ratio of exo:endo regioselectivity of about 5.0≠3:1 and about 4.00.3:1, respectively.

PROCESS FOR THE EPOXIDATION OF PROPENE TO PROPYLENE OXIDE

A continuous process for the preparation of propylene oxide, comprising providing a liquid feed stream comprising propene, hydrogen peroxide, methanol, water, at least one dissolved potassium salt of hydroxyethylidenediphosphonic acid, and optionally propane; passing the liquid feed stream provided in (i) into an epoxidation reactor comprising a catalyst comprising a titanium zeolite of structure type MFI, and subjecting the liquid feed stream to epoxidation reaction conditions in the epoxidation reactor, obtaining a reaction mixture comprising propylene oxide, methanol, water, and the at least one dissolved potassium salt of hydroxyethylidenediphosphonic acid, and optionally propane; removing an effluent stream from the epoxidation reactor, the effluent stream comprising propylene oxide, methanol, water, at least a portion of the at least one potassium salt of hydroxyethylidenediphosphonic acid, and optionally propane. 1. A continuous process for preparing propylene oxide , the process comprising:(i) passing a liquid feed stream, comprising propene, hydrogen peroxide, methanol, water, at least one dissolved potassium salt of hydroxyethylidene diphosphonic acid, and optionally propane, into an epoxidation reactor comprising a catalyst comprising a titanium zeolite of structure type MFI, and subjecting the liquid feed stream to epoxidation reaction conditions in the epoxidation reactor, to obtain a reaction mixture comprising propylene oxide, methanol, water, and the at least one dissolved potassium salt of hydroxyethylidene diphosphonic acid, and optionally propane; and(ii) removing an effluent stream from the epoxidation reactor, the effluent stream comprising propylene oxide, methanol, water, at least a portion of the at least one potassium salt of hydroxyethylidenediphosphonic acid, and optionally propane.2. The process of claim 1 , wherein the molar ratio of potassium relative to phosphorus in the at least one potassium salt of hydroxyethylidene diphosphonic ...

Preparation method for chlorophenoxycarboxylate

Provided is a method for producing a chlorophenoxycarboxylate, comprising the following steps of: a phenoxycarboxylate under actions of a catalyst A and a catalyst B performing a selective chlorination of a chlorinating agent at a 2-position and/or a 4-position to obtain the chlorophenoxycarboxylate; the catalyst A is a Lewis acid; and the catalyst B has the following structure: R1′—S—R2′. The present disclosure redesigns the process route, and finely screens the catalyst and the chlorinating agent, thereby effectively improving the chlorination selectivity while avoiding the loss of the active ingredient, and the content of the obtained chlorophenoxycarboxylate can reach more than 98.5%, and the yield can reach more than 99%.

Processes for the preparation of a diarylthiohydantoin compound

Disclosed are processes and intermediates for the preparation of compound (X), which is currently being investigated for the treatment of prostate cancer.

ASYMMETRIC SYNTHESIS OF FUNAPIDE

This invention is directed to asymmetric synthesis of funapide, which is useful for the treatment and/or prevention of sodium channel-mediated diseases or conditions, such as pain. 2. The method of wherein the suitable intramolecular cyclization conditions comprise the use of a phosphine reagent.3. The method of wherein the compound of formula (G) is treated to the suitable intramolecular cyclization conditions in the absence of an azodicarboxylate ester.4. The method of wherein the phosphine reagent is chlorodiphenylphosphine.5. The method of wherein the suitable deprotection conditions comprise treating the compound of formula (G) in a polar aprotic solvent with an aqueous acid solution.7. The method of wherein the catalyst is a thiourea-substituted quinine or hydroquinine derivative.9. The method of wherein the suitable C—C bond formation conditions comprise suspending the compound of formula (F) in an organic solvent and combining the suspension of the compound of formula (F) with an inorganic base.12. The method of wherein the suitable protecting conditions comprise treating the compound of formula (E) with an oxygen-protecting group provider in an polar aprotic solvent in the presence of a base.14. The method of wherein the suitable dehydroxylation conditions comprise acid-promoted dehydroxylation of the compound of formula (D) followed by reduction with an appropriate silane or siloxane.16. The method of wherein the compound of formula (D) is isolated from the reaction mixture by crystallization under suitable crystallization conditions.17. The method of wherein the suitable N-alkylation conditions comprise reductive amination conditions in the presence of an aldehyde and a reducing agent.18. The method of wherein the suitable coupling conditions comprise treating the compound of formula (C) with the reaction mixture to form the compound of formula (D) in the absence of a Grignard reagent. The present invention is directed to improved methods of preparing ...

POLYCYCLOOLEFIN MONOMERS AND CATALYST ACTIVATED BY COMPOUND CAPABLE OF GENERATING PHOTOACID AS 3D PRINTING MATERIALS

Embodiments in accordance with the present invention encompass compositions containing a latent catalyst and a compound capable of generating a Bronsted acid with a counterion capable of coordinating and activating the latent catalyst along with one or more monomers which undergo ring open metathesis polymerization (ROMP) when said composition is exposed to a suitable radiation to form a three-dimensional (3D) object. The catalyst system employed therein can be sensitive to oxygen and thus inhibits polymerization in ambient atmospheric conditions. The three-dimensional objects made by this process exhibits improved mechanical properties, particularly, high distortion temperature, impact strength, elongation to break, among others. Accordingly, compositions of this invention are useful as 3D inkjet materials for forming high impact strength objects of various sizes with microscale features lower than 100 microns, among various other uses. 2. The composition according to claim 1 , wherein said composition comprising first and second monomer of formula (I) distinct from each other and one of said first and second monomers having a viscosity below 50 centipoise claim 1 , and wherein said first monomer is completely miscible with said second monomer to form a clear solution.3. The composition according to claim 1 , wherein said composition comprising a monomer of formula (I) wherein m is 1 and each of R claim 1 , R claim 1 , Rand Rare hydrogen.4. The composition according to claim 3 , wherein said composition comprising a compound of formula (IV) where Ris hydrogen.5. The composition according to claim 1 , wherein said composition comprising first and second monomer of formula (I) distinct from each other claim 1 , wherein said first monomer is of formula (I) wherein m is 1 and each of R claim 1 , R claim 1 , Rand Rare hydrogen; and wherein said second monomer is of formula (I) wherein m is 0 claim 1 , Ris decyl and each of R claim 1 , Rand Rare hydrogen.8. The ...

LAMINATING ADHESIVES USING POLYESTER FROM TRANSESTERIFICATION OF POLYLACTIC ACID WITH NATURAL OILS

A specific mixture of polyols, at least one of which contains the transesterification product of the polymer polylactic acid with natural oils. The mixture of polyols can be used as one component of a two-component adhesive for laminating flexible packaging. The other component comprises an isocyanate-functionalized compound. The two components are combined before use and the resulting adhesive can be used to bond films to form a flexible packaging material. 1. An isocyanate reactive component for reaction with an isocyanate functionalized component to form a two-component laminating adhesive , comprising:a transesterification product of a reaction mixture comprising polymeric polylactic acid and at least one natural oil; anda high OH functionality polyol product.2. The isocyanate reactive component of wherein the reaction mixture comprises polymeric polylactic acid claim 1 , at least one natural oil and a diol having a molecular weight of about 50 to about 2000 daltons.3. The isocyanate reactive component of wherein the reaction mixture comprises:polylactic acid present in an amount of from 50 to 85 weight percent based on a total weight of the reaction mixture;at least one natural oil present in an amount of from 13 to 30 weight percent based on the total weight of the reaction mixture;a diol present in an amount of from 2 to 36 weight percent based on the total weight of the reaction mixture; andoptionally, a transesterification catalyst.4. The isocyanate reactive component of having a renewable content in the range of at least 70%.5. The isocyanate reactive component of having a viscosity of 3 claim 1 ,000 to 20 claim 1 ,000 cps at 25° C.6. The isocyanate reactive component of any of wherein the high OH functionality polyol product has at least about two primary hydroxyl groups and at least about two secondary hydroxyl groups.7. The isocyanate reactive component of wherein the natural oil is castor oil and/or soybean oil.8. A two-component adhesive for ...

HIERARCHICAL MAGNETIC NANOPARTICLE-ENZYME MESOPOROUS ASSEMBLIES EMBEDDED IN MACROPOROUS SCAFFOLDS

A hierarchical catalyst composition comprising a continuous or particulate macroporous scaffold in which is incorporated mesoporous aggregates of magnetic nanoparticles, wherein an enzyme is embedded in mesopores of the mesoporous aggregates of magnetic nanoparticles. Methods for synthesizing the hierarchical catalyst composition are also described. Also described are processes that use the recoverable hierarchical catalyst composition for depolymerizing lignin remediation of water contaminated with aromatic substances, polymerizing monomers by a free-radical mechanism, epoxidation of alkenes, halogenation of phenols, inhibiting growth and function of microorganisms in a solution, and carbon dioxide conversion to methanol. Further described are methods for increasing the space time yield and/or total turnover number of a liquid-phase chemical reaction that includes magnetic particles to facilitate the chemical reaction, the method comprising subjecting the chemical reaction to a plurality of magnetic fields of selected magnetic strength, relative position in the chemical reaction, and relative motion. 122.-. (canceled)23. A method for epoxidation reactions of alkenes , the method comprising reacting alkenes in the presence of oxygen with a hierarchical catalyst composition comprising a continuous macroporous scaffold in which is incorporated self-assembled mesoporous aggregates of magnetic nanoparticles containing an oxygen-transfer enzyme embedded in mesopores of said mesoporous aggregates of magnetic nanoparticles , to produce an alkene oxide.24. The method of claim 23 , wherein said oxygen-transfer enzyme is a chloroperoxidase or a lipase.2539.-. (canceled)40. The method of claim 23 , further comprising magnetic particles claim 23 , not belonging to said mesoporous aggregates of magnetic nanoparticles claim 23 , embedded in said continuous macroporous scaffold.41. The method of claim 23 , wherein said continuous macroporous scaffold has a polymeric composition.42 ...

PROCESS FOR THE ASYMMETRIC OXIDATION OF ORGANIC COMPOUNDS WITH PEROXIDES IN THE PRESENCE OF A CHIRAL ACID CATALYST

The present invention relates to a process for the asymmetric oxidation of nucleophilic organic compounds, particularly metal-free, with peroxide compounds in the presence of a chiral Brønsted acid catalyst. In one detail, the present invention relates to a process for enantioselective sulfoxidation of thiocompounds with peroxide compounds in the presence of a chiral imidodiphosphate catalyst. In another detail, the present invention relates to a process for enantioselective sulfoxidation of thiocompounds with peroxide compounds in the presence of a chiral phosphoric acid catalyst. 116-. (canceled)18. A process according to claim 17 , wherein the organic compound is a thioether R—S—R.19. The process according to claim 17 , wherein the peroxide R—OOH is selected from hydrogen peroxide claim 17 , aliphatic or aromatic hydroperoxide claim 17 , aliphatic or aromatic percarboxylic acid having a Cto Cstraight chain claim 17 , branched chain or cyclic aliphatic or Cto Caromatic hydrocarbons claim 17 , optionally having one or more unsaturated bonds claim 17 , C-C-heterocycloalkyl or Cto Caromatic hydrocarbon and partially arene-hydrogenated forms claim 17 , each hydrocarbon optionally being substituted claim 17 , or mixtures thereof.23. A process according to claim 22 , wherein claim 22 , in such formula (III) claim 22 ,{'sup': 1', '4, 'sub': 1', '20', '3', '8', '6', '20', '1', '20', '3', '8', '6', '20, 'Rto R, respectively may each be selected from Cto Cstraight chain, branched chain or cyclic aliphatic hydrocarbons, optionally having one or more unsaturated bonds, C-C-heterocycloalkyl or Cto Caromatic hydrocarbon and partially arene-hydrogenated forms, each hydrocarbon optionally being substituted by one or more groups selected from Cto Cstraight chain, branched chain or cyclic aliphatic hydrocarbons, optionally having one or more unsaturated bonds, C-C-heterocycloalkyl or Cto Caromatic hydrocarbon and partially arene-hydrogenated forms, and'}W may be selected from ...

Sulfur-contaminated ionic liquid catalyzed alklyation

A sulfur-contaminated ionic liquid catalyst is provided comprising 300 to 20,000 wppm of sulfur from a contaminant, wherein the catalyst is a chloroaluminate and it alkylates olefin and isoparaffin to make an alkylate gasoline blending component having a FBP below 221° C. A process is provided for making the alkylate gasoline blending component, comprising: a. feeding olefin feed comprising greater than 80 wppm of sulfur contaminant to a chloroaluminate ionic liquid catalyst, to make a sulfur-contaminated catalyst; and b. alkylating olefin feed with isoparaffin to make the alkylate gasoline blending component. A method to construct a refinery alkylation unit is provided comprising installing an ionic liquid alkylation reactor having an inlet that feeds a pure coker LPG olefin. An alkylation process exclusively utilizing coker LPG olefins is also provided.

MODIFYING ORGANOALUMINUM CO-CATALYSTS FOR IMPROVED PERFORMANCE

Processes of making catalyst compositions are provided. In an exemplary embodiment, the processes include modifying an organoaluminum compound with a modifier that decreases the initial reducing strength of the organoaluminum compound, where the modifier can be an ether, an anhydride, an amine, an amide, a silicate, a silyl ether, a siloxane, an ester, a carbonate, a urea, a carbamate, a sulfoxide, a sulfone, a phosphoramide, or a combination thereof. The processes further include adding a transition metal complex to the mixture of the organoaluminum compound and the modifier; and obtaining a catalyst composition including the organoaluminum compound and the transition metal complex. 1. A process of making a catalyst composition , comprising:treating an organoaluminum compound with a modifier that decreases the initial reducing strength of the organoaluminum compound, wherein the modifier is selected from the group consisting of ethers, anhydrides, amines, amides, silicates, silyl ethers, siloxanes, esters, carbonates, ureas, carbamates, sulfoxides, sulfones, phosphoramides, silanes, and acetals;adding a transition metal complex to the mixture of the organoaluminum compound and the modifier; andobtaining a catalyst composition comprising the organoaluminum compound and the transition metal complex.2. The process of claim 1 , wherein the transition metal complex comprises at least one of the metals of Groups IV-B claim 1 , V-B claim 1 , VI-B claim 1 , and VIII of the Periodic Table.3. The process of claim 1 , wherein the organoaluminum compound is triethylaluminum.4. The process of claim 1 , wherein the modifier a monoether claim 1 , or wherein the ether is a diether.5. process of claim 1 , wherein the transition metal complex is not mixed with a catalyst modifier prior to adding the transition metal complex to the mixture of the organoaluminum compound and the modifier.6. The process of claim 1 , wherein the transition metal complex is diluted in a solvent claim 1 , ...

PHOTOCATALYTIC DEGRADATION OF SUGAR

Systems having at least one photonic antenna molecule and at least one catalyst for degrading a sugar to degradation products using light energy are disclosed. Also disclosed are the devices and methods that use the systems for photocatalytically degrading a sugar into degradation products. 1. A system for photocatalytically degrading a sugar , the system comprising:at least one photonic antenna molecule; andat least one catalyst;wherein the photonic antenna molecule is capable of collecting a light energy and transferring the light energy to the catalyst; andwherein the catalyst is capable of degrading the sugar to produce at least one degradation product.2. The system of claim 1 , wherein the photonic antenna molecule is selected from the group consisting of 5-hydroxytryptamine claim 1 , an acridine claim 1 , an Alexa Fluor® dye claim 1 , an ATTO dye claim 1 , a BODIPY® dye claim 1 , Coumarin 6 claim 1 , a CY dye claim 1 , DAPI claim 1 , an ethidium compound claim 1 , a Hoechst dye claim 1 , Oregon Green claim 1 , rhodamine claim 1 , a compound comprising Ru(bpy) claim 1 , a compound comprising (Pt(pop)) claim 1 , a YOYO dye claim 1 , and a SeTau dye.3. The system of claim 1 , wherein the photonic antenna molecule is fluorescein.4. The system of claim 1 , wherein the catalyst is a metal nanoparticle.5. The system of claim 4 , wherein the metal nanoparticle comprises a metal selected from the group consisting of ruthenium claim 4 , palladium claim 4 , gold claim 4 , silver claim 4 , nickel claim 4 , tungsten claim 4 , molybdenum claim 4 , gallium claim 4 , iridium claim 4 , rhodium claim 4 , osmium claim 4 , copper claim 4 , cobalt claim 4 , iron claim 4 , and platinum claim 4 , or a mixture thereof.6. The system of claim 4 , wherein the metal nanoparticle comprises a lanthanide.7. The system of claim 4 , wherein the metal nanoparticle comprises a metal selected from the group consisting of platinum claim 4 , nickel claim 4 , and europium.8. The system of claim 5 , ...

HYDROPROCESSING CATALYST, PREPARATION METHOD THEREOF AND USE OF SAME

The invention relates to a hydrocarbon hydroprocessing catalyst comprising a support based on at least one refractory oxide, at least one metal from group VIII and at least one metal from group VIB. The inventive catalyst is characterized in that it also comprises at least one organic compound having formula (I) or (II): 2. The activated catalyst as claimed in claim 1 , wherein the organic compound of formula (I) or (II) is selected from alkyl ortho-phthalates claim 1 , alkyl isophthalates claim 1 , alkyl terephthalates claim 1 , malonic acid esters claim 1 , adipic acid esters claim 1 , glutaric acid esters claim 1 , 1 claim 1 ,6-dioxacyclodecane-2 claim 1 ,5-dione claim 1 , dimethyl 2-(methoxymethyl)-succinate claim 1 , dibutyl itaconate claim 1 , diethyl 2 claim 1 ,3-diacetylsuccinate claim 1 , dimethyl cyclohexane-1 claim 1 ,4-dicarboxylate claim 1 , dimethyl 3 claim 1 ,3′-dithiodipropionate claim 1 , glycerol triacetate claim 1 , propylene glycol diacetate claim 1 , ethylene glycol dimethacrylate and pentaerythritol tetrakis(3-mercaptopropionate).3. The activated catalyst as claimed claim 1 , wherein the number of carbon atoms separating the two groups >C═O of formulae (I) and (II) is equal to 1 claim 1 , 2 or 4.4. The activated catalyst as claimed in claim 3 , wherein the organic compound of formula (I) is a C-Cdialkyl succinate.5. The activated catalyst as claimed in claim 1 , wherein the catalyst comprises at least 0.001 mol of at least one organic compound per mole of metals of groups VIB and VIII.6. The activated catalyst as claimed in claim 5 , wherein the catalyst comprises from 0.001 to 10 mol of at least one organic compound per mole of metals of groups VIB and VIII.8. The method as claimed in claim 7 , wherein the catalyst comprising a carrier based on at least one refractory oxide claim 7 , at least one metal of group VIII in the oxide state and at least one metal of group VIB in the oxide state is a regenerated catalyst.9. The method as claimed in ...

Improved glycol acylation process with water-tolerant metal triflates

A method for acid-catalyzed acylation of an isohexide is described. The method can enable direct alcohol acylation with carboxylic acids. In particular, the method involves reacting an isohexide and an excess of carboxylic acid, in the presence of a water-tolerant Lewis acid catalyst. Water-tolerant Lewis acid catalysts can furnish relatively high diester yields (e.g., ≧55%-60%) at lower catalyst loads. This feature, among others, is highly desirable for cost savings, and can improve process economics.

METHOD FOR PRODUCING HYDROGEN GAS FROM FORMIC ACID

A method for producing A hydrogen gas from formic acid, characterized in that at least one heterogeneous catalyst is used to transform the formic acid into hydrogen gas. The at least one heterogeneous catalyst contains heterogenised ruthenium. According to a first aspect of the invention, the at least one heterogeneous catalyst contains at least one hydrophilic phosphine ligand which is m-TPPTS (meta-trisulfonated triphenylphosphine). The at least one heterogeneous catalyst is preferably obtained by mixing an aqueous solution of RuClwith hydrophilic phosphine, firstly activated by carrying out a homogeneous reaction with formic acid and by adding at least one solid structure. 113-. (canceled)14. A method of producing hydrogen gas from formic acid , the method comprising:using at least one heterogeneous catalyst to transform formic acid to hydrogen gas.15. The method according to claim 14 , further comprising the at least one heterogeneous catalyst containing heterogenised ruthenium.16. The method according to claim 14 , further comprising the at least one heterogeneous catalyst containing at least one hydrophilic phosphine ligand.17. The method according to claim 16 , further comprising using m-TPPTS (meta-trisulfonated triphenylphosphine) as the at least one hydrophilic phosphine ligand.18. The method according to claim 14 , further comprising obtaining the at least one heterogeneous catalyst by mixing an aqueous solution of RuClwith hydrophilic phosphine claim 14 , firstly activated by carrying out a homogeneous reaction with formic acid and by adding at least one solid structure.19. The method according to claim 14 , further comprising the at least one heterogeneous catalyst containing silica modified with phosphine ligands.20. The method according to claim 19 , further comprising preparing linkers from parent bromoalkenes and coupled with PPhnucleophile and the ligand is covalently bonded to the silica surface and the ruthenium phosphine complex is anchored in a ...

Improved Methods and Systems for Photo-Activated Hydrogen Generation

Systems and methods for providing alternative fuel, in particular hydrogen photocatalytically generated by a system comprising photoactive nanoparticles and a nitrogenase cofactor are provided. In one aspect, the system includes a water soluble cadmium selenide nanoparticle (CdSe) surface capped with mercaptosuccinate (CdSe-MSA) and a NafY.FeMo-co complex comprising a NafY protein and an iron-molybdenum cofactor (FeMo-co), wherein the CdSe-MSA and NafY.FeMo-co complex are present in about 1:2 to 1:10 molar ratio. 1. A system for photocatalytically producing hydrogen gas , comprising:a water soluble cadmium selenide nanoparticle (CdSe) surface capped with mercaptosuccinate (CdSe-MSA); anda NafY.FeMo-co complex comprising a NafY protein and an iron-molybdenum cofactor (FeMo-co);wherein the CdSe-MSA and NafY.FeMo-co complex are present in about 1:2 to 1:10 molar ratio.2. The system of claim 1 , wherein the CdSe-MSA and the NafY.FeMo-co complex are present in about 1:2 claim 1 , 1:3 claim 1 , 1:4 or 1:5 molar ratio.3. The system of claim 1 , further comprising sodium dithionite for providing protons and electrons.4. The system of claim 3 , wherein the dithionite salt is provided at a concentration of about 2 mM to 1 M claim 3 , or about 2-100 mM claim 3 , or about 2-10 mM.5. The system of claim 3 , further comprising an additional proton source such as ascorbic acid claim 3 , acetic acid claim 3 , citric acid claim 3 , and carbon dioxide.6. The system of claim 1 , wherein the system is capable of photocatalytically producing hydrogen gas for an extended period of about 5-90 days claim 1 , 10-72 days or 39-72 days.7. The system of claim 1 , wherein the system is kept under anaerobic conditions.8Azotobacter vinelandii.. The system of claim 1 , wherein the NafY protein is derived from9. The system of claim 1 , wherein the FeMo-co is derived from a molybdenum-iron (MoFe) protein.10Azotobacter vinelandii.. The system of claim 9 , wherein the MoFe protein is derived from11. A ...