NO_X REDUCTION DEVICE HAVING REGENERATING MEANS OF CONTAMINATED OXIDATION CATALYST
The present invention refers to an inflammable substance (one example, CO, HC), organic material, inorganic material nitric oxide and nitric oxide (NOx) included in the (one example, S, F-based compound) process effluent gases, combustible material in a stand-alone NOx selective reduction catalyst and oxidation catalyst oxidation catalyst reaction when processing a number, combustible material, which oxidation catalyst is deactivated due to organic material and inorganic material, nitrogen oxide oxidation catalyst industry association number, oxidation catalyst to nitrogen oxide reducing means is contaminated device are disclosed. For example, industry such as combustible contaminants generated on-site and exhaust CO HC oxidation catalyst which is used on a stand-alone number, a selective reduction catalyst (SCR) to nitrogen oxides (NOx) number is under or over a stand-alone. I.e. process effluent gas is oxygenated through CO and HC oxidation catalyst and, through the SCR NOx reduction treatment can be. However process included in the process exhaust gas depending on the type of organic material and inorganic material rapidly with an oxidation catalyst by trace amounts of carbon monoxide poisoning can be disclosed. The number can be a stand-alone NOx SCR started about 230 °C or more to maintain the temperature. Process according to process effluent temperature of a gas when a low, since the NOx number can be a stand-alone process effluent gas heating temperature is equal to the SCR. [...] oxidation catalyst under a high temperature condition in Edition data, wherein the organic material is resized to oxidation catalyst reactive number oxide from oxidation catalyst can be recovered. However in the case of inorganic material, oxidation catalyst to heat oxidation catalyst reactive recovery not only makeup. I.e. with an oxidation catalyst poisoning by oxidation of HC and CO can be undoped in oxidation catalysts in the conversion rate is recognized that multivalent number 1 under a high temperature condition number 1, number 2 levels than the number 1 is suddenly relieved by lowering blood killing by poison the conversion rate of an oxide inorganic material are disclosed. In this state simply solely through high temperature processing when the oxide catalyst, the conversion rate of oxidation due to poisoning by inorganic material under a high temperature condition number 1 again even ball number is number 1 and number 1 level restores performance than is to be coated. The inorganic materials does not stand-alone number on an oxidation catalyst, oxidation catalysts are lowering residual inorganic material selected from oxide catalyst mixture. The purpose of the invention a combustible material, organic material, inorganic material and NOx included in the process effluent gas organic material and inorganic material of active and inactive when the corrupted by the oxidation catalyst, an oxidation catalyst and hydrogen under a high temperature condition required by supplying contaminated oxidation catalyst means for effectively regenerate a [...] number included in the low NOx emission device are disclosed. In addition the purpose of the invention is process effluent gas number combustible material is formed to a stand-alone heat from organic material and inorganic material and a stand-alone process with catalyst oxide oxidation catalyst [...] number, the selective reduction catalyst is started to transfer the heat process effluent gas heating temperature continuous oxide catalyst reducing nitrogen oxide means is a number [...] device are disclosed. In the embodiment according to one of the present invention device is contaminated oxidation catalyst means for included in the low NOx emission, combustible material, organic material, inorganic material and nitrogen oxides included in the number 1 and a coolant temperature process effluent gas an orifice connected with a stand-alone said combustible material oxidation number oxidation catalyst oxidation catalyst top, and said oxidation catalyst in front of the oxidation catalyst tower connected to said plasma reactor generates said hydrogen containing synthesis gas by supplying oxidation catalysts comprising organic material and inorganic material [...] oxidation catalyst regeneration of said plasma reactor. In the embodiment according to one of the present invention included in the low NOx emission device includes means for contaminated oxidation catalyst, said oxidation catalyst temperature process effluent gas temperature higher than said number 1 number 2 connected to connect said selective reduction catalyst having the same number further comprises nitrogen oxides reduction catalyst can be contained in a stand-alone. In the embodiment according to one of the present invention device is contaminated oxidation catalyst means for included in the low NOx emission, said number 1 temperature process effluent gas supplied to said oxidation catalyst or an oxidation catalyst in said tube said bypassing said reduction catalyst tower supply valve further comprises selected so that the number 1 number. In said oxidation catalyst comprises a hot syngas comprising said plasma reactor is formed in said inorganic material can be reproduced so that volatile organic material and said number. Said catalyst temperature process effluent gas passing through said selective oxidation catalyst can be heated to a temperature triggered by said number 2. Laterally with respect to said plasma reactor supplied hydrocarbon fuel and air plasma reaction including generating a synthesis gas can be hydrogen. Said plasma reactor and the other one is fed into one side of the fuel supply unit includes a first insulation including synthesis gas with hydrogen cleaning grounded housing, said fuel inlet and said air supply opening disposed between the high voltage electrode can be applied. Said fuel supply opening and said discharge opening in said housing said plasma reactor air supply opening formed between said plasma reaction space can be further comprises communicating with the reforming catalyst. Said housing between said space and said plasma reactor said plasma reactor as fuel reforming catalyst inlet air additional feed ports can be feeding additional fuel and air. In the embodiment according to one of the present invention included in the low NOx emission device includes means for contaminated oxidation catalyst, said oxidation catalyst to bypass said oxidation catalyst further comprises said number 1 number the valve can be connected to connect bypass pins are bent. Disposed in parallel to said selective reduction catalyst by said oxidation catalyst tower also includes number 2 number valves selectively connected with tower number 1 and number 2 catalyst contained in catalyst, said oxidation catalyst in front of the pins are bent valve said number 1 number said number 2 catalyst tower with tower catalyst can be selectively connecting said number 1. Said plasma reactor number 3 number via the valve can be selectively connected to said number 1 catalyst catalyst tower with tower said number 2. In the embodiment according to one of the present invention included in the low NOx emission device includes means for contaminated oxidation catalyst, said oxidation catalyst in front of the tower with the number 1 number said oxidation catalyst temperature process effluent gas engaged with said number 1 top supply valve, and said oxidation catalyst tower behind said top portions are engaged with said number 2 with oxidation catalyst further comprises a number 2 number temperature process effluent gas valve. Said plasma reactor said number 2 number it is installed on the valve and a bypass valve connecting said number 1 number, said number 1 number of closed-loop (closed loop) valve and valve operation said number 2 number formed separated from each other by said number 1 to circulate temperature process effluent gas supplied air plasma reaction including generating a synthesis gas can be hydrogen. Said plasma reactor 10 - 100% of the air fed to the combustion equivalence ratio can be set. Said reduction catalyst tower also includes rear with said oxidation catalyst tower can be. the valve said number 1 number in said oxidation catalyst temperature process effluent gas supplied from said number 1 and engaged with the top tube, the valve said number 2 number in said oxidation catalyst reduction catalyst tower top temperature process effluent gas supplied said number 2 can be engaged with the mobile station. Said oxidation catalyst tower connected to said pipe and a coolant with said reduction catalyst tower also includes front, rear and a coolant heat exchanger installed can be said [...] said oxidation catalyst tower. Said number 1 number said valve in said oxidation catalyst temperature process effluent gas are fed to the reduction catalyst tower top said number 1 and engaged with the mobile station, said number 2 number the valve in said oxidation catalyst temperature process effluent gas supplied from a top heat exchanger side can be engaged with said number 2. The one in the embodiment according to of the present invention included in the low NOx emission device is contaminated oxidation catalyst means for, generated plasma reactor of high organic material and inorganic material by supplying hydrogen [...] oxidation catalysts, combustible material from oxidation catalyst number generated is a stand-alone heat volatilization while organic material and inorganic material or organic material and inorganic material through a stand-alone reacted with the number (a number (X) inorganic material in the form of special HnXm) oxidation process with catalyst substrate. In the embodiment of the present invention i.e. combustible material is formed to a stand-alone heat oxidation number is one oxide catalyst since additional heating means and temperature conditions without the use of oxidation catalyst in organic material and inorganic material can be a stand-alone from [...] effectively number. In addition, in the embodiment of the present invention is temperature process effluent gas after oxidation catalyst for regenerating one number 1 number 2 is supplied to the selective reduction catalyst is heated to a temperature process effluent and at least one gas is heated to a temperature process effluent gas is selected starting number 2 catalytic reduction catalyst to a temperature external causes. Figure 1 shows a device of the present invention number 1 in the embodiment according to oxidation catalyst also relates to a method for reducing nitrogen oxide means is contaminated configuration are disclosed. Figure 2 shows a cross-section 1 also applied to plasma reactor also shown are disclosed. Figure 3 shows a cross-section shown also applied to other plasma reactor 1 also are disclosed. Figure 4 shows a device of the present invention number 2 in the embodiment according to oxidation catalyst also relates to a method for reducing nitrogen oxide means is contaminated configuration are disclosed. Also included in the low NOx emission device of the present invention number 3 in the embodiment according to Figure 5 shows a contaminated oxidation catalyst means for it is shown a rivet is disclosed. Figure 6 shows a device of the present invention number 4 in the embodiment according to oxidation catalyst also relates to a method for reducing nitrogen oxide means is contaminated configuration are disclosed. Figure 7 shows a variant of the present invention number 4 in the embodiment according to oxidation catalyst means is also of contaminated nitrogen oxide reducing device shown a rivet is disclosed. Figure 8 shows a contaminated oxidation catalyst means for included in the low NOx emission device of the present invention number 5 in the embodiment according to also illustrates the configuration are disclosed. Figure 9 shows a plasma reactor applied to 8 also shown in cross-section also are disclosed. Figure 10 shows a contaminated oxidation catalyst means for included in the low NOx emission device of the present invention number 6 in the embodiment according to also shown a rivet is disclosed. Also included in the low NOx emission device of the present invention number 7 in the embodiment according to Figure 11 shows a contaminated oxidation catalyst means for it is shown a rivet is disclosed. Hereinafter, with reference to the drawing of the present invention in the embodiment for the present invention in the preface is provided to the person with skill in the art to detailed embodiment is hereinafter for 2000. However the present invention refers to several different taught herein can be embodied in the form of a in the embodiment is not limited to. In the present invention is described that is independent portion drawing unambiguously account for dispensed when the, same or similar component are identical in area to specification reference code is configured to receive. Figure 1 shows a device of the present invention number 1 in the embodiment according to oxidation catalyst also relates to a method for reducing nitrogen oxide means is contaminated configuration are disclosed. The reference also 1, contaminated oxidation catalyst means for included in the low NOx emission device number 1 in the embodiment according to (1) is, process effluent gas an orifice tube (10), a tube (10) is connected to the oxidation catalyst (21) containing an oxidation catalyst top (20), and hydrogen are hot synthesis gas comprising generating a plasma reactor (40) having a predetermined wavelength. Process effluent gas unite alarm is created in each process expelled, including hot process when, with NOx exhausted through the combustible material, contaminants such as organic material and inorganic material substance. For example, the CO and HC and combustible material, the inorganic material sulfur, comprises a fluorinated compound. A process for manufacturing a tube (10) entering the process effluent gas output for adjusting a process number 1 holds the temperature level. Oxidation catalyst (21) is an oxidizing catalyst deposited top (20) communication at, process effluent gas to the flow of, oxidation catalyst (21) front inlet process effluent gas to a stand-alone number after combustible material oxidation catalysis, process effluent gas oxidation catalyst (21) to the rear of a luminescent substrate. Oxidation catalyst (21) includes a process effluent gas contaminants such as organic material and inorganic material is active by poisoning may cause a decrease in disclosed. The, plasma reactor (40) is created in oxidation catalyst (21) is formed in forwardly of the included high temperature (for example, 350 °C or more) syngas oxidation catalyst (21) is supplied to the oxidation catalyst (21) can be reproduced. I.e. hot synthesis gas comprising hydrogen oxidation catalyst (21) and combustible material oxidation number in a stand-alone, or volatilized inorganic material layer and the catalyst in the catalyst surface coupling reactions with hydrogen (21) number encoded volatile organic material and inorganic material in a poisoning. Oxidation catalyst (21) after regeneration, oxidation catalyst top (20) deburring process effluent gas temperature higher number 2 number 1 (for example, 222 °C) temperature (for example, 255 °C) discharge rearwardly while maintaining level with each other. Figure 2 shows a cross-section 1 also applied to plasma reactor also shown are disclosed. The reference 2 also, plasma reactor (40) is electrically grounded is housing (41), and housing (41) (V) is embedded in the voltage applying electrode (42) comprises. Housing (41) comprises a housing (41) on one side of the fuel supply opening (43) and an air supply opening (44) with, one side of the discharge port (45) contact with each other. The fuel supply opening (43) and an air supply opening (44) each discharge gap (G) to supply the fuel and air, discharge port (45) is configured and produced reaction including synthesis gas discharge 25. Electrode (42) air can be supplied to a fuel cell stack housing (41) with of inflow side can be. As one example, electrode (42) is the fuel supply opening (43) and an air supply opening (44) disposed thereon between. The housing (41) in a state in which a ground electrode (42) application voltage (V), electrode (42) and the housing (41) an arc is generated between the discharge gap (G), using CLK3 supplied fuel and air plasma reaction. The LNG fuel including hydrogen orgin hydrocarbon fuel such as hydrogen can be used. Housing (41) the fuel supply opening (43) and an air supply opening (44) in the delivery port (45) plasma between reaching the reaction space (S) with each other. The electrode (42) and the housing (41) established between discharge gaps (G) arc in a plasma reaction space (S) produce a hot synthesis gas including hydrogen and diffusion in plasma reactor. Housing (41) of a plasma formed extended reaction space (S) to ensure good plasma reaction, discharge port (45) causes high temperature hydrogen and synthesis gas can be blown through. Process effluent gas is created in industrial processes, electronics (10) can be continuously fed in high flow rate through. Plasma reactor (40) partial oxidation reaction is the plasma reaction to produce hydrogen in a short time since most hydrogen oxidation catalyst (21) can be supplied. In partial oxidation reaction product of a plasma reaction space (S) discharge port (45) hot through the sawing substrate. The heating step 500 to 600 °C or more hydrogen containing synthesis gas is generated without oxidation catalyst (21) can be supplied. I.e. plasma arc-shaped in a plasma reactor (40) in plasma reaction space (S) can be formed in relatively high temperature conditions. Plasma reactor (40) including the synthesis gas produced in a hydrogen oxidation catalyst top (20) catalyst for oxidation of (21) feed. Simultaneously, electronics (10) number 1 temperature process effluent gas entering the oxidation catalyst (21) via a discharge therefrom. The process effluent gas [...] organic material and inorganic material by oxidation catalyst (21) is 300 to 600 °C or more hydrogen including exposed under a high temperature condition syngas recycled substrate. I.e. [...] oxidation catalyst (21) of organic material and inorganic material at a high temperature (X) set up in the form of coupled oxidation catalyst or catalyst surface hydrogen and HnXm main body (21) separated from, number encoded wetting ability. Oxidation catalyst (21) after regeneration, oxidation catalyst top (20) deburring process effluent gas to a temperature above the temperature level number 1 number 2 heated substrate. Figure 3 shows a cross-section shown also applied to other plasma reactor 1 also are disclosed. The reference also 3, plasma reactor (60) includes a reforming catalyst (61) can be further comprises. I.e. reforming catalyst (61) includes a housing (641) of the fuel supply opening (43) and air supply opening (44) in the delivery port (45) formed between a plasma reaction space (S) communicates with a. Reforming catalyst (61) due to further induce a reforming reaction catalyst collects, plasma can be to reduce the power to the rotation. The electrodes produce hydrogen (42) and voltage (V) applied to the energy can be reduced, process effluent gas industry the processing capacity can be increased number oxide contaminants. Plasma reactor (60) includes a housing (641) plasma reaction space (S) and reforming catalyst (61) as fuel between the feed opening (643) additional air feed opening (644) by feeding additional fuel and air receives further, plasma reaction space (S) capable of more extended and vented in plasma. Further extending the plasma reforming catalyst (61) activate reformation reactions are fed to reforming catalyst further reforming catalyst (61) can be contacted with one surface reforming action. I.e. plasma reaction space (S) and reforming catalyst (61) is configured and formed in reaction and, discharge port (45) through a large amount of hot hydrogen and synthesis gas is cleaned and rinsed the mixer can be a strong industrial processes. In the embodiment hereinafter of the present invention various other in mammals are also described. Number 1 in the embodiment described in the embodiment in comparison with and long description omitted and have different configuration of the same configuration are disclosed therein. Figure 4 shows a device of the present invention number 2 in the embodiment according to oxidation catalyst also relates to a method for reducing nitrogen oxide means is contaminated configuration are disclosed. The reference also 4, contaminated oxidation catalyst means for reducing nitrogen oxide included in device number 2 in the embodiment according to, valve number 1 number (V1) is a tube (10) in industrial processes which are mounted in the frame (10) enters the oxidation catalyst top (20) further comprises a temperature process effluent gas path number 1 selects. Number 1 number i.e. valve (V1) is number 1 temperature process effluent gas oxidation catalyst (21) or oxidation catalyst supply (21) to bypass the number encoded. Valve number 1 number (V1) is oxidation catalyst (21) capable of reproducing process effluent gas bypass. To this end, bypass tube (50) while, bypass tube (50) is oxidation catalyst (21) to bypass oxidation catalyst (21) in front of the tube (10) connected to the oxidation catalyst (21) to the back of the top oxidation catalyst (20) coupled with each other. Valve number 1 number (V1) includes a frame (10) and a bypass tube (50) of supporting shaft as the, number 1 oxidation catalyst temperature process effluent gas flow (21) selects the front or rear. Plasma reactor (40) includes a valve (V1) of number 1 number while the posterior oxidation catalyst (21) in front of the oxidation catalyst top (20) coupled with each other. The bypass valve (V1) is the number 1 number number to process effluent gas tube (50) when a bypass, plasma reactor (40) is configured and generates a synthesis gas including hydrogen is provided oxidation catalyst (21) are supplied to a. The, bypass tube (50) and valve (V1) is number 1 number it (10) number 1 temperature process effluent gas entering the oxidation catalyst (21) does not pass through and evacuated from the causes. Process effluent gas when high flow rate of [...], number 1 number it is deflected towards the periodic valve (V1) (10) the oxidation catalyst (21) selectively are connected to front and back of. The plasma reactor (40) is a synthesis gas comprising hydrogen and hydrogen are periodically operating the oxidation catalyst (21) periodically supplied. The [...] oxidation catalyst (21) is periodically regenerated is can be. Also included in the low NOx emission device of the present invention number 3 in the embodiment according to Figure 5 shows a contaminated oxidation catalyst means for it is shown a rivet is disclosed. The reference also 5, contaminated oxidation catalyst means for included in the low NOx emission device number 3 in the embodiment according to (3) oxidation catalyst is number 1 in the embodiment to the configuration of the top (20) selective reduction catalyst (SCR) connected (31) reduction catalyst having the top (30) results are. Oxidation catalyst (21) after regeneration, oxidation catalyst top (20) deburring process effluent gas temperature higher number 2 number 1 (for example, 222 °C) temperature (for example, 255 °C) holds the level. The selective reduction catalyst (31) has oxidation catalyst (21) after playing, number 2 temperature process effluent gas temperature triggered by supplying heated to a temperature can be disclosed. Selective reduction catalyst (31) includes a reduction catalyst top (30) communication at, selective reduction catalyst (31) front inlet temperature process effluent gas temperature triggered by temperature and number 2, number 2 temperature levels of process effluent gas a stand-alone NOx reduction number 2000. The selective reduction catalyst (31) without the use of heating means included is the number 2 temperature process effluent gas effectively number can be a stand-alone NOx. Selective reduction catalyst (31) connects the inlet temperature process effluent gas temperature triggered by temperature and number 2, process effluent gas effectively without separate heating means a stand-alone NOx reduction number 2000. The contaminated nitrogen oxide catalyst for NOx reduction device means is number 3 in the embodiment (3) is oxidation catalyst (21) via reaction of oxidation at 9 °C CO 1000 ppm per degree temperature rise can be enabling process effluent gas. Process effluent gas even when high flow rate of [...], number 3 in the embodiment means is nitrogen contamination of catalyst for NOx reduction device (3) comprises a process effluent gas heating without heating the entire part by simultaneously without requiring large causes such as large burner energy facility. Figure 6 shows a device of the present invention number 4 in the embodiment according to oxidation catalyst also relates to a method for reducing nitrogen oxide means is contaminated configuration are disclosed. The reference also 6, number 4 in the embodiment according to contaminated oxidation catalyst means for included in the low NOx emission device (4) is, number 3 in the embodiment to the configuration of the number 2 in the embodiment having a low number 1 number of valve (V1) and bypass tube (50) further comprises. I.e. number 4 in the embodiment according to contaminated oxidation catalyst means for included in the low NOx emission device (4) includes a process effluent gas an orifice tube (10), a tube (10) is connected to the oxidation catalyst (21) containing an oxidation catalyst top (20), oxidation catalyst top (20) selective reduction catalyst (SCR) connected (31) reduction catalyst having the top (30), process effluent gas path number 1 number selecting valve (V1), and hydrogen are hot synthesis gas comprising generating a plasma reactor (40) having a predetermined wavelength. A process for manufacturing a tube (10) entering the process effluent gas output for adjusting a process number 1 holds the temperature level. Oxidation catalyst (21) front inlet process effluent gas to a stand-alone number after combustible material oxidation catalysis, process effluent gas oxidation catalyst (21) to the rear of a luminescent substrate. Plasma reactor (40) is created in oxidation catalyst (21) is formed in forwardly of the included high temperature (for example, 350 °C or more) syngas oxidation catalyst (21) is supplied to the oxidation catalyst (21) can be reproduced. I.e. hot synthesis gas comprising hydrogen oxidation catalyst (21) and combustible material oxidation number in a stand-alone, or volatilized inorganic material layer and the catalyst in the catalyst surface coupling reactions with hydrogen (21) number encoded volatile organic material and inorganic material in a poisoning. Oxidation catalyst (21) after regeneration, oxidation catalyst top (20) deburring process effluent gas temperature higher number 2 number 1 (for example, 222 °C) temperature (for example, 255 °C) holds the level. The selective reduction catalyst (31) has oxidation catalyst (21) after playing, number 2 temperature process effluent gas temperature triggered by supplying heated to a temperature can be disclosed. Selective reduction catalyst (31) includes a reduction catalyst top (30) communication at, selective reduction catalyst (31) front inlet temperature process effluent gas temperature triggered by temperature and number 2, number 2 temperature levels of process effluent gas a stand-alone NOx reduction number 2000. The selective reduction catalyst (31) without the use of heating means included is the number 2 temperature process effluent gas effectively number can be a stand-alone NOx. It includes a valve (V1) number 1 number (10) in industrial processes which are mounted in the frame (10) enters the oxidation catalyst top (20) further comprises a temperature process effluent gas path number 1 selects. Number 1 number i.e. valve (V1) is number 1 temperature process effluent gas oxidation catalyst (21) or oxidation catalyst supply (21) to bypass the number encoded. Valve number 1 number (V1) is oxidation catalyst (21) capable of reproducing process effluent gas bypass. Bypass tube (50) is oxidation catalyst (21) to bypass oxidation catalyst (21) in front of the tube (10) connected to the oxidation catalyst (21) to the back of the top oxidation catalyst (20) coupled with each other. Valve number 1 number (V1) includes a frame (10) and a bypass tube (50) of supporting shaft as the, number 1 oxidation catalyst temperature process effluent gas flow (21) selects the front or rear. Plasma reactor (40) includes a valve (V1) of number 1 number while the posterior oxidation catalyst (21) in front of the oxidation catalyst top (20) coupled with each other. The bypass valve (V1) is the number 1 number number to process effluent gas tube (50) when a bypass, plasma reactor (40) is configured and generates a synthesis gas including hydrogen is provided oxidation catalyst (21) are supplied to a. The process effluent gas [...] organic material and inorganic material by oxidation catalyst (21) is 300 to 600 °C or more hydrogen including exposed under a high temperature condition syngas recycled substrate. I.e. [...] oxidation catalyst (21) of organic material and inorganic material at a high temperature (X) set up in the form of coupled oxidation catalyst or catalyst surface hydrogen and HnXm main body (21) separated from, number encoded wetting ability. Process effluent gas when high flow rate of [...], number 1 number it is deflected towards the periodic valve (V1) (10) the oxidation catalyst (21) selectively are connected to front and back of. The plasma reactor (40) is a synthesis gas comprising hydrogen and hydrogen are periodically operating the oxidation catalyst (21) periodically supplied. The [...] oxidation catalyst (21) is periodically regenerated is can be. Oxidation catalyst (21) after regeneration, oxidation catalyst top (20) deburring process effluent gas temperature higher than number 1 number 2 heating temperature level are selected catalytic reduction catalyst (31) are fed to an, selective reduction catalyst (31) to a temperature higher starting temperature. Selective reduction catalyst (31) connects the inlet temperature process effluent gas temperature triggered by temperature and number 2, process effluent gas effectively without separate heating means a stand-alone NOx reduction number 2000. The contaminated oxidation catalyst means for included in the low NOx emission device number 4 in the embodiment (4) is oxidation catalyst (21) via reaction of oxidation at 9 °C CO 1000 ppm per degree temperature rise can be enabling process effluent gas. Process effluent gas even when high flow rate of [...], number 4 in the embodiment means is nitrogen contamination of catalyst for NOx reduction device (4) includes a process effluent gas heating without heating the entire part by simultaneously without requiring large causes such as large burner energy facility. Figure 7 shows a variant of the present invention number 4 in the embodiment according to oxidation catalyst means is also of contaminated nitrogen oxide reducing device shown a rivet is disclosed. The reference also 7, number 4 in the embodiment of inventions contamination catalyst means is nitrogen oxide reducing device (401) is oxidation catalyst top (220) into a plurality of number 1 catalyst top (201) and number 2 catalyst top (202) is formed on the substrate. Number 1 catalyst top (201) and number 2 catalyst top (202) is arranged in parallel, valve (V22) catalytic reduction catalyst selected by number 2 number (31) can be selectively coupled. Valve number 1 number (V21) is number 1, number 2 oxidation catalyst (121, 221) disposed in front of a tube (10) to number 1, number 2 catalyst top (201, 202) are connected to selectively. The number number 1 number (V21) it along an opposite side of the valve (10) via the number 1 temperature process effluent gas is number 1, number 2 catalyst top (201, 202) of number 1, number 2 oxidation catalyst (121, 221) can be selectively supplying. Valve number 2 number (V22) is number 1, number 2 oxidation catalyst (121, 221) of disposed behind the liquid crystal, number 1, number 2 catalyst top (201, 202) selectively selective reduction catalyst (31) are connected to. (V22) along an opposite side of the valve number 2 number number number 1, number 2 catalyst top (201, 202) of number 1, number 2 oxidation catalyst (121, 221) number 2 temperature process effluent gas via the selective reduction catalyst (31) can be selectively supplying. Plasma reactor (40) includes a valve (V21) while the posterior number 1 number of number 1, number 2 oxidation catalyst (121, 221) in front of the selective reduction catalyst (31) is attached with a number 1 catalyst top (201) and number 2 catalyst top (202) selectively connected thereto. The number 3 number number (V23) plasma reactor along an opposite side of the valve (40) is installed in a hot hydrogen containing synthesis gas is number 1, number 2 catalyst top (201, 202) of number 1, number 2 oxidation catalyst (121, 221) can be selectively supplying. For example, number 2 oxidation catalyst (221) when is [...], number 2 oxidation catalyst (221) is reproduced, number 1 oxidation catalyst (121) includes a number of exhaust gas temperature raising the temperature of the surface of combustible matter into a stand-alone oxidation catalysis, the temperature elevated temperatures selective reduction catalyst (31) is a stand-alone NOx selective catalytic reduction reaction number 2000. I.e. it is number 1 number (V21) valve (10) number 1 a catalyst top (201) connected to selected, number 1 number 1 catalyst temperature process effluent gas top (201) number 1 are supplied to the oxidation catalyst (121) to about in. The valve includes a number 1 number 2 number (V22) catalyst top (201) reduction catalyst top (30) connected to, number 2 supplied to the process effluent gas temperature reduction catalyst top (30) are supplied to the selective reduction catalyst (31) in reduction. The valve is number 3 number (V23) in a plasma reactor (40) [...] a number 2 oxidation catalyst (221) connected to selected, hydrogen containing synthesis gas is number 2 oxidation catalyst (221) number 2 supplied to the oxidation catalyst (221) followed by a number pre-organic material and inorganic material stationary substrate. In addition, number 1 oxidation catalyst (121) when the [...], number 1 oxidation catalyst (121) is reproduced, number 2 oxidation catalyst (221) has a number of exhaust gas temperature raising the temperature of the surface of combustible matter into a stand-alone oxidation catalysis, the temperature elevated temperatures selective reduction catalyst (31) is a stand-alone NOx selective catalytic reduction reaction number 2000. I.e. it is number 1 number (V21) valve (10) number 2 a catalyst top (202) connected to selected, number 1 number 2 catalyst temperature process effluent gas top (202) number 2 are supplied to the oxidation catalyst (221) to about in. Valve number 2 number is number 2 (V22) catalyst top (202) reduction catalyst top (30) connected to, number 2 supplied to the process effluent gas temperature reduction catalyst top (30) are supplied to the selective reduction catalyst (31) in reduction. The valve is number 3 number (V23) in a plasma reactor (40) [...] a number 1 oxidation catalyst (121) connected to selected, hydrogen containing synthesis gas is number 1 oxidation catalyst (121) number 1 supplied to the oxidation catalyst (121) followed by a number of special pre-organic material and inorganic material to each other. The number 2 in the embodiment means is nitrogen oxide reducing contamination catalyst device (2) includes a number 1 or number 2 oxidation catalyst (221, 121) while reproducing a number 1 or number 2 catalyst top (201, 202) of number 1 or number 2 oxidation catalyst (121, 221) number 1 temperature process effluent gas continuously through combustible material and a stand-alone catalytic oxidation action number, high temperatures generated is the selective reduction catalyst (31) can be a stand-alone NOx through a number. In addition number 2 or number 1 oxidation catalyst (221, 121) then selectively reproducing, number 1, number 2 catalyst top (201, 202) number 2 temperature levels of process effluent gas discharged selective reduction catalyst (31) are fed to an, selective reduction catalyst (31) to a temperature higher starting temperature. The selective reduction catalyst (31) connects the inlet temperature process effluent gas to a temperature sufficiently elevated and triggered by a number 2, process effluent gas is substantially effect without separate heating means can be a stand-alone NOx reduction number. Process effluent gas even when high flow rate of [...], contaminated oxidation catalyst means for included in the low NOx emission device number 2 in the embodiment according to (2) the overall number 1 is temperature process effluent gas without heating the banner without requiring large equipment such as large burner energy, unlike process effluent gas does not bypass discharge on number 1 in the embodiment. Figure 8 shows a contaminated oxidation catalyst means for included in the low NOx emission device of the present invention number 5 in the embodiment according to also illustrates the configuration degrees and, also applied to the plasma reactor cross-section shown in Figure 9 8 are disclosed. 8 and 9 may also reference the, number 5 in the embodiment according to contaminated oxidation catalyst means for included in the low NOx emission device (5) in, oxidation catalyst top (320) is a tube (10) is connected to, reduction catalyst top (30) includes a catalytic oxidation top (320) with behind-coupled with each other. Valve number 1 number (V31) includes a catalytic oxidation top (320) is provided in front of the, valve number 2 number (V32) includes a catalytic oxidation top (320) to the front of the combined with each other. It is number 1 number (V31) valve (10) oxidation catalyst in top (320) and engaged with the number 1 are fed to a temperature process effluent gas, valve number 2 number (V32) is oxidation catalyst top (320) reduction catalyst in top (30) further comprises a number 2 d2. temperature process effluent gas. Bypass tube (350) is oxidation catalyst top (320) to oxidation catalyst bypass (321) in front of the tube (10) and a valve (V31) connected by intervening to number 1 number, oxidation catalyst (321) at the rear of oxidation catalyst top (320) to number 2 number (V32) is attached with a valve connected thereto. Plasma reactor (340) pass line electronics (350) on force is removed. The number 1, number 2 number along an opposite side of the valve (V31, V32) number, process effluent gas is number 1, number 2 number has a cooling inlet and outlet valve (V31, V32) temporarily, oxidation catalyst (321) on plasma reactor (340) pass line electronics (350) and number 1, closed-loop (closed loop) through valve (V31, V32) number 2 number and form. I.e. plasma reactor (340) is usable in a temperature process effluent gas supplied air circulating number 1 separated from each other by hydrogen plasma reaction including synthesis gas circulation generating reaction chamber. Plasma reactor (340) included is supplied without pressure sensor (fresh air), number 1 gradually heated to a temperature of high process effluent gas driven process are to receive a supply of exhaust gas for temperature rise can be to save fuel. But, to closed-loop plasma reactor (340) occurred when running, so that continuing to supply gas to combustion region and the concentration of oxygen since resulting. The general burner using closed circuit when possible, resulting in the presence of carboxylic acid is operable. However number 5 in the embodiment of plasma reactor (340) is possible even when closed, plasma reactor (340) 10 - 100% of the gas introduced into the combustion flame can be maintaining an oxygen concentration of 14 degree equivalence ratio. The number 5 in the embodiment includes a plasma reactor (340) is operated to sufficiently produce the hydrogen containing synthesis gas oxidation catalyst (321) to an oxidation catalyst supplied to the circulation (321) is oxidized catalytically combustible material and a stand-alone number, oxidation catalyst (321) selectively reproducing occurring on blood poison catalyst reduction catalyst (31) can be a stand-alone NOx in sufficient number. To this end, plasma reactor (340) housing (341) of and moved in a process effluent includes a supply port (343) pass line electronics (350) is connected to the valve (V32) number 1 number 2 number circle gradually heated to a temperature hot process effluent gas housing (341) supplied into. The circulating process effluent gases and air supply opening (344) (receiver) using air being supplied into the partially, grounded housing (341) applied electrode voltage (V) (342) of one another between which an arc plasma reaction to cause plasma reaction space (S) deformable cladding layer. Thereby, housing (341) other potato inlet (345) is configured and reaction space (S) is formed in a synthesis gas as a plasma produced from a reaction comprising a bypass tube (350) to discharge, valve number 1 number (V31) via oxidation catalyst (321) supplied back to causes. Number 5 in the embodiment means is nitrogen contamination catalyst for NOx reduction device (5) organic material and inorganic material is [...] oxidation catalyst (321) oxidation catalyst while reproducing a top (320) catalyst for oxidation of (321) continuously number 1 through further heated process effluent gas temperature NOx selective reduction catalyst (31) in which a selective reduction reaction can be a stand-alone number. In addition oxidation catalyst (321) after regeneration, number 1, number 2 number (V31, V32) number by an opposite side of the valve, bypass tube (350) and is blocked, oxidation catalyst top (320) number 2 exhaust temperature levels of process effluent gas selective reduction catalyst (31) are fed to an, selective reduction catalyst (31) to a temperature higher starting temperature. The selective reduction catalyst (31) connects the inlet temperature process effluent gas to a temperature sufficiently elevated to triggered by a number 2, number 2 temperature process effluent gas separate heating means can be a stand-alone NOx without effect is substantially reduced number. Figure 10 shows a contaminated oxidation catalyst means for included in the low NOx emission device of the present invention number 6 in the embodiment according to also shown a rivet is disclosed. 10 also reference surface, contaminated oxidation catalyst means for included in the low NOx emission device number 6 in the embodiment according to (6) in, selective reduction catalyst (71) reduction catalyst having the top (70) includes a catalytic oxidation top (320) with the front of the frame (10) is connected thereto. Oxidation catalyst top (320) connected to the rear of the rear frame (11) reduction catalyst on top (70) connected to the front of the tube (10) to a heat exchanger (80) a semiconductor device is provided. Heat exchanger (80) is oxidation catalyst top (320) number 2 temperature process effluent gas heated in the heat tube (10) by transferring, electronics (10) number 1 number 2 temperature process effluent gas temperature supplied to the higher temperature level. Valve number 1 number (V31) includes a frame (10) via a reduction catalyst top (70) oxidation catalyst in top (320) and engaged with the number 1 are fed to a temperature process effluent gas, rear frame (11) is an oxidizing catalyst deposited top (320) and at the heat exchanger (80) side 2 temperature process effluent gas supplied. (V31) along an opposite side of the valve number 1 number number, oxidation catalyst (321) is plasma reactor (40) or reduction catalyst top (70 coupled with each other. I.e. plasma reactor (40) including a fuel and air plasma reaction generates hydrogen synthesis gas supplied. Hydrogen containing synthesis gas sufficiently and even as high as oxidation catalyst (321) via the oxidation catalyst (321) is oxidation catalysis and combustible material into a stand-alone number, can be regenerated while the selective reduction catalyst (31) number in a stand-alone NOx to process effluent gas temperature level number 2 sufficiently heated. Synthesis gas heated process effluent gas oxidation catalyst including top (320) rear tube (11) at a, heat exchanger (80) through a tube (10) to heat transfer thereto. Electronics (10) number 1 temperature process effluent gas is supplied to the heat exchanger (80) encoded number 2 by heat transmitted from the temperature level reactions. Transition temperature process effluent gas temperature level number 2 selective reduction catalyst (31) are fed to an, selective reduction catalyst (31) to a temperature higher starting temperature. The selective reduction catalyst (31) is number 2 temperature process effluent gas separate heating means can be a stand-alone NOx without effect is substantially reduced number. Also included in the low NOx emission device of the present invention number 7 in the embodiment according to Figure 11 shows a contaminated oxidation catalyst means for it is shown a rivet is disclosed. The reference also 11, number 7 in the embodiment according to contaminated oxidation catalyst means for included in the low NOx emission device (7) in, valve number 1 number (V31) includes a frame (10) via a reduction catalyst top (70) oxidation catalyst in top (320) and engaged with the number 1 are fed to a temperature process effluent gas, valve number 2 number (V32) is oxidation catalyst top (320) rear frame (11) and heat exchanger (80) side temperature process effluent gas supplied d2. number 2. Number 1, number 2 number along an opposite side of the valve (V31, V32) number, oxidation catalyst (321) on plasma reactor (340) pass line electronics (350) and form through closed-loop (closed loop). I.e. plasma reactor (340) is usable in a number 1 and a separate air circulating temperature process effluent gas supplied to the hydrogen plasma reaction including synthesis gas circulation generating reaction chamber. Hydrogen containing synthesis gas sufficiently and even as high as oxidation catalyst (321) as it circulates in the intermediate layer and the metal catalyst (321) is a stand-alone number faster and combustible material to oxidation catalysis, can be regenerated while the selective reduction catalyst (31) number in a stand-alone NOx to process effluent gas temperature level number 2 sufficiently heated. Synthesis gas heated process effluent gas oxidation catalyst including top (320) rear tube (11) at a, heat exchanger (80) through a tube (10) to heat transfer thereto. Electronics (10) number 1 temperature process effluent gas is supplied to the heat exchanger (80) encoded number 2 by heat transmitted from the temperature level reactions. Transition temperature process effluent gas temperature level number 2 selective reduction catalyst (31) are fed to an, selective reduction catalyst (31) achieved more rapidly to a temperature higher starting temperature. The selective reduction catalyst (31) is number 2 temperature process effluent gas separate heating means can be a stand-alone NOx without effect is substantially reduced number. Or more of the present invention preferred embodiment through is described but, on of the drawings and detailed description of the invention is not limited to claim the present invention refers to the preface is elastically deformed and in addition of the present invention variously in the range and the range of possible embodiment of course have disclosed. 1, 2, 3, 4, 401, 5, 6, 7: number of special device 10, 11, 50: electronics 20, 220, 320: top oxidation catalyst 21, 321: oxidation catalyst 30, 70: reduction catalyst top 31, 71: selective reduction catalyst 40, 60, 340: plasma reactor 41, 341, 641: housing 42, 342: electrode 43: fuel supply opening 44, 344: air supply opening 45: discharge port 50, 350: bypass tube 80: heat exchanger 121, 221: number 1, number 2 oxidation catalyst 201, 202: number 1, number 2 catalyst top 343: process effluent includes a supply port 643: additional fuel supply opening 644: additional air supply opening G: discharge gap S: plasma reaction space V: voltage V1, V21, V31: valve number 1 number V22, V32: valve number 2 number V23: valve number 3 number The present invention aims to provide a NO_x reduction device having a regenerating means of a contaminated oxidation catalyst, which effectively regenerate an oxidation catalyst by supplying necessary high temperature conditions and hydrogen when regenerating the inertness of an oxidation catalyst contaminated by an organic substance and an inorganic substance in process exhaust gases containing combustible materials, organic materials, inorganic materials and NO_x. The NO_x reduction device having a regenerating means of a contaminated oxidation catalyst, according to an embodiment of the present invention, comprises: an oxidation catalyst tower having a built-in oxidation catalyst connected to a pipe for circulating the process exhaust gas at a first temperature containing combustible materials, organic materials, inorganic materials and NO_x to oxidize and remove the combustible materials; and a plasma reactor connected to the oxidation catalyst tower in front of the oxidation catalyst to generate synthesis gas containing hydrogen through a plasma reaction and supplying the synthesis gas to the oxidation catalyst to regenerate the oxidation catalyst poisoned with the organic materials and the inorganic materials. COPYRIGHT KIPO 2017 Combustible material, organic material, inorganic material and nitrogen oxides included in the number 1 and a coolant temperature process effluent gas an orifice connected with a stand-alone said combustible material oxidation number oxidation catalyst oxidation catalyst top; and said oxidation catalyst in front of the oxidation catalyst tower connected to said plasma reactor generates hydrogen containing synthesis gas by supplying said oxidation catalysts including organic material and inorganic material [...] contaminated oxidation catalyst means for said oxidation catalyst for regenerating plasma reactor including the low NOx emission device. According to Claim 1, said oxidation catalyst temperature process effluent gas temperature higher than said number 1 number 2 connected to connect said selective reduction catalyst having the further including a stand-alone number nitrogen oxides reduction catalyst contained in contaminated oxidation catalyst means for included in the low NOx emission device. According to Claim 2, said number 1 temperature process effluent gas supplied to said oxidation catalyst or an oxidation catalyst in said tube said bypassing said reduction catalyst tower supply selected so that the number 1 number further including valve contaminated oxidation catalyst means for included in the low NOx emission device. According to Claim 2 or Claim 3, said selective oxidation catalyst temperature process effluent gas passing through said catalyst to a temperature triggered by said number 2 it became and it was imbrued oxidation catalyst means for included in the low NOx emission device. According to Claim 1, said plasma reactor is fed into the fuel supply unit includes a first insulation and the other one which crawls side hydrogen is contained in the synthesis gas cleaning ground with one side of the housing, said fuel inlet and said air supply opening and an electric voltage is applied between the electrode including contaminated oxidation catalyst means for included in the low NOx emission device. According to Claim 5, said fuel supply opening and said discharge opening in said housing said plasma reactor plasma reaction space formed between said air supply port communicating with the further including reforming catalyst contaminated oxidation catalyst means for included in the low NOx emission device. According to Claim 6, said plasma reactor said housing between said space and said plasma reactor fuel and air as fuel reforming catalyst inlet air additional feed ports contaminated nitrogen oxide reducing means is an additional oxidation catalyst device. According to Claim 3, said oxidation catalyst to bypass said number 1 number the valve connecting said oxidation catalyst tower further including bypass pins are bent contaminated oxidation catalyst means for included in the low NOx emission device. According to Claim 3, said oxidation catalyst tower with arranging in a row number 2 number said selective reduction catalyst by valves disposed to selectively connected with tower number 1 and number 2 catalyst contained in catalyst, said oxidation catalyst in front of the pins are bent valve said number 1 number said number 2 catalyst tower with tower contaminated oxidation catalyst means for selectively connecting said number 1 catalyst including the low NOx emission device. According to Claim 9, said plasma reactor catalyst with tower via the valve selectively connecting said number 1 number 3 number said number 2 catalyst tower it became and it was imbrued oxidation catalyst means for included in the low NOx emission device. According to Claim 2, said oxidation catalyst in front of the tower with the number 1 number said oxidation catalyst temperature process effluent gas engaged with said number 1 top supply valve, and said oxidation catalyst tower behind said oxidation catalyst temperature process effluent gas engaged with said number 2 with the number 2 number outputted from the top further including valve means is contaminated oxidation catalyst device reducing nitrogen oxide. According to Claim 11, said plasma reactor said number 2 number it is installed on the valve and a bypass valve connecting said number 1 number, said number 1 number of closed-loop (closed loop) valve and valve operation said number 2 number formed separated from each other by said number 1 to circulate temperature process effluent gas supplied air plasma reaction including synthesis gas generating hydrogen contaminated oxidation catalyst means for included in the low NOx emission device. According to Claim 12, said plasma reactor 10 - 100% of the air fed to the combustion equivalence ratio set it became and it was imbrued oxidation catalyst means for included in the low NOx emission device. According to Claim 11, said oxidation catalyst tower behind it became and it was imbrued with oxidation catalyst means for said reduction catalyst tower also includes device included in the hydraulic control system. According to Claim 14, said valve in said number 1 number the oxidation catalyst temperature process effluent gas and engaged with said number 1 are fed to it's top, said number 2 number said valve in said oxidation catalyst temperature process effluent gas supplied said number 2 the reduction catalyst tower top contaminated nitrogen oxide reducing means is engaged with the oxidation catalyst device. According to Claim 11, said oxidation catalyst tower connected to said pipe and a coolant with said reduction catalyst tower also includes front, rear and a coolant heat exchanger installed it became and it was imbrued [...] said oxidation catalyst means for said oxidation catalyst tower including the low NOx emission device. According to Claim 16, the valve said number 1 number in said oxidation catalyst temperature process effluent gas are fed to a reduction catalyst tower top and engaged with said number 1, said number 2 number the valve in said oxidation catalyst temperature process effluent gas are fed to a heat exchanger side engaged with said number 2 top contaminated oxidation catalyst means for included in the low NOx emission device.










