08-05-2024 дата публикации
Номер: GB2624059A
A preparation method of a medium-entropy perovskite oxygen carrier comprising: 1) preparing an aqueous solution from metallic nitrate serving as a raw material, performing a coprecipitation reaction with at least one of aqueous ammonia solution, a sodium hydroxide aqueous solution or a sodium carbonate aqueous solution as a precipitant at a pH value of 9.5-10.5 to obtain a hydroxide precursor; and 2) obtaining a La3CoMnAIO9 medium-entropy perovskite oxygen carrier after stirring, standing, washing, drying and calcining. The metallic nitrate can be La(NO3)3.6H2O, Co(NO3)3.6H2O, a Mn(NO3)2 aqueous solution and Al(NO3)3.9H2O; with an ionic molar ratio of La:Co:Mn:Al of 3:1:1:1. The application of the medium-entropy perovskite oxygen carrier in a reaction of chemical-looping reforming of methane to hydrogen in a fluidized bed is also described, wherein: at a reduction stage, the oxygen carrier reacts with the methane under oxygen-free conditions, the methane is partially oxidized by lattice oxygen in the oxygen carrier to generate syngas, and the oxygen carrier is reduced; at the reoxidation stage, the oxygen carrier reacts with steam to obtain part of the lattice oxygen, generating hydrogen; and then the oxygen carrier is then further oxidized by air to be cyclically regenerated before reacting with methane.
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