15-08-2013 дата публикации
Номер: US20130211023A1
The present invention relates to a supported catalyst for olefin polymerization to which a novel transition metal compound and a co-catalyst compound are bound, and a preparation method for polyolefin using the supported catalyst. The transition metal compound bound to the catalyst of the present invention provides high activity for olefin-based monomers in heterogeneous reaction as well as in homogeneous system. Particularly, a polyolefin with higher molecular weight can be prepared by using the supported catalyst containing the transition metal compound bound to a support, rather than using the novel transition metal compound in a non-supported status, or the conventional transition metal compound in a supported or non-supported status. 2. The supported catalyst for olefin polymerization as claimed in claim 1 , wherein M is titanium (Ti) claim 1 , zirconium (Zr) claim 1 , or hafnium (Hf);{'sup': 1', '2, 'Qand Qare independently methyl or chlorine;'}{'sup': 1', '2', '3', '4', '5, 'R, R, R, R, and Rare independently hydrogen or methyl; and'}{'sup': 6', '7', '8', '9', '10', '11', '12', '13, 'R, R, R, R, R, R, R, and Rare independently hydrogen.'}3. The supported catalyst for olefin polymerization as claimed in claim 2 , wherein at least one of Rand Ris methyl; and Ris methyl.4. The supported catalyst for olefin polymerization as claimed in claim 1 , wherein the co-catalyst compound is at least one selected from the group consisting of compounds represented by the following formula 6 claim 1 , 7 claim 1 , or 8:{'br': None, 'sup': '61', 'sub': 'a', '—[Al(R)—O]—\u2003\u2003[Formula 6]'}{'sup': '61', 'sub': 1', '20', '1', '20, 'wherein Ris independently a halogen radical, a C-Chydrocarbyl radical, or a halogen-substituted C-Chydrocarbyl radical; and'} {'br': None, 'sup': '71', 'sub': '3', 'D(R)\u2003\u2003[Formula 7]'}, 'a is an integer of 2 or above,'}{'sup': '71', 'sub': 1', '20', '1', '20, 'claim-text': {'br': None, 'sup': +', '−', '+', '−, 'sub': 4', '4, '[L-H][Z(A)] ...
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