10-11-2022 дата публикации
Номер: US20220356151A1
Disclosed are a variety of amphoteric compounds containing a quaternary nitrogen group, a covalently bound counterion, and an ester or amide group. These amphoteric compounds can be advantageously prepared via a chemoenzymatic green process, and exhibit good surfactant properties. 2PseudomonasCandida antarctica.. The process according to claim 1 , wherein the enzyme is a lipase from sp or3. The process according to claim 1 , wherein the alkylating agent is selected from the group consisting of sodium chloroacetate claim 1 , 1 claim 1 ,3-propanesultone claim 1 , 1 claim 1 ,4-butanesultone claim 1 , sodium 2-chloroethanesulfonate claim 1 , sodium 3-chloro-2-hydroxypropanesulfonate claim 1 , 1 claim 1 ,2-ethylene sulfate claim 1 , 1 claim 1 ,3-propylene sulfate claim 1 , 3-bromopropanesulfate claim 1 , sodium chloromethylphosphonate claim 1 , sodium 3-chloro-2-hydroxypropylphosphate claim 1 , sodium 2-chloroethylphosphate claim 1 , sodium 3-chloro-2-propylphosphate claim 1 , sodium 2-chloroethoxyethylphosphate claim 1 , sodium 2 claim 1 ,3-epoxypropylphosphate claim 1 , and sodium 4-chlorobutylphosphate.4. The process according to claim 1 , wherein Ris substituted with a hydroxyl group.5. The process according to claim 1 , wherein{'sub': 6', '20', '6', '18', '6', '18', '3', '8, 'R is selected from the group consisting of C-Calkyl, C-Calkenyl, C-Cdienyl, and C-Ccycloalkyl;'}{'sup': '1', 'sub': 3', '4, 'Ris a C-Calkylene group;'}{'sup': 2', '3, 'sub': 1', '6', '1', '6, 'Rand Rare each independently selected from the group consisting of C-Calkyl and C-Calkenyl;'}{'sup': '4', 'Ris selected from the group consisting of methylene, ethylene, propylene, butylene, and hydroxypropylene;'}X is O or NH; and{'sup': −', '−', '−, 'sub': 2', '3, 'Yis CO or SO.'}6. The process according to claim 1 , wherein{'sub': 6', '20', '6', '18', '6', '18, 'R is selected from the group consisting of C-Calkyl, C-Calkenyl, and C-Cdienyl;'}{'sup': '1', 'Ris 1,3-propylene or 1,4-butylene;'}{'sup': 2', ...
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