10-01-2019 дата публикации
Номер: US20190010398A1
Принадлежит:
The present invention relates to an etching composition, an etching method, and a method of preparing a semiconductor device using the same, and more particularly, to an etching composition comprising a compound capable of selectively removing a nitride film with a high selectivity while minimizing an etch rate of the oxide film, and a method of preparing a semiconductor device comprising an etching process using the etching composition. 2. The etching composition of claim 1 , wherein Rto Rare selected from the group consisting of hydrogen claim 1 , halogen claim 1 , hydroxy group and C-Calkyl group claim 1 , at least one of Rto Ris hydroxy group claim 1 ,{'sub': 4', '1', '5, 'Ris selected from the group consisting of hydrogen, halogen and C-Calkyl group,'}{'sub': 1', '5', '6', 'm, 'Xis —(C(R)(R))—,'}m is 0 to 1, and{'sub': 5', '6', '1', '5, 'Rand Rare each independently hydrogen or C-Calkyl group.'}3. The etching composition of claim 2 , wherein all of Rto Rare hydroxy groups.4. The etching composition of claim 3 , wherein the compound represented by Formula 1 is at least one selected from the group consisting of (2-(pyridin-4-yl)propan-2-yl)silanetriol claim 3 , (3-pyridin-4-yl)pentan-3-yl)silarietriol claim 3 , (3 claim 3 ,5-dimethylpyridin-4-yl)silanetriol and (2-(3 claim 3 ,5-dimethylpyridin-4-yl)propan-2-yl)silanetriol.5. The etching composition of claim 1 , which comprises 80 to 90% by weight of phosphoric acid and 0.1 to 3% by weight of the compound represented by Formula 1.6. The etching composition of claim 1 , further comprising an additive for improving etch rate.7. A method of etching a semiconductor device claim 1 , comprising etching a film selected from the group consisting of a silicon nitride film claim 1 , a silicon oxide film and combinations thereof claim 1 , by using the etching composition of . The present invention relates to an etching composition and a method of etching by using the same, and more particularly, to an etching composition ...
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