29-08-2013 дата публикации
Номер: US20130221445A1
Принадлежит:
Provided are devices and methods utilizing TiN and/or TaN films doped with Si, Al, Ga, Ge, In and/or Hf. Such films may be used as a high-k dielectric cap layer, PMOS work function layer, aluminum barrier layer, and/or fluorine barrier. These TiSiN, TaSiN, TiAlN, TaAlN, TiGaN, TaGaN, TiGeN, TaGeN, TiInN, TaInN, TiHfN or TaHfN films can be used where TiN and/or TaN films are traditionally used, or they may be used in conjunction with TiN and/or TaN. 1. An integrated circuit transistor device comprising:a high-k dielectric layer disposed over a channel; anda metal nitride layer over the high-k dielectric layer, the metal nitride layer selected from TiSiN, TaSiN, TiAlN, TaAlN, TiGaN, TaGaN, TiGeN, TaGeN, TiInN, TaInN, TiHfN and TaHfN.2. The integrated circuit transistor device of claim 1 , wherein the metal nitride layer is in contact with the high-k dielectric layer.3. The integrated circuit transistor device of claim 1 , further comprising one or more intermediate layers between the high-k dielectric layer and the metal nitride layer.4. The integrated circuit transistor device of claim 1 , wherein a layer comprising aluminum overlies the metal nitride film.5. The integrated circuit transistor device of claim 1 , wherein the metal nitride layer is formed by atomic layer deposition and has a thickness having a range of about 2 Angstroms to about 200 Angstroms.6. The integrated circuit transistor device of claim 5 , wherein the metal nitride layer has a thickness having a range of about 5 Angstroms to about 100 Angstroms.7. The integrated circuit transistor device of claim 6 , wherein the metal nitride layer comprises TiSiN.8. A method of forming an integrated circuit transistor device with a metal gate claim 6 , the method comprising:providing a substrate comprising a high-k dielectric layer; andexposing the substrate to a first precursor comprising Ti or Ta, a second precursor comprising an ammonia source, and a third precursor comprising a Si, Al, Ga, Ge, In or Hf ...
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