21-05-2015 дата публикации
Номер: US20150141546A1
Принадлежит:
The present invention relates to a pre-paint composite comprising an aqueous slurry of TiOparticles and attached and unattached polymeric binder, and a sufficient amount of a secondary alcohol ethoxylate of the formula CHO(CHCHO)H to give 35 to 90 weight percent attachment of polymeric binder to the TiOparticles, based on the weight of total polymeric binder in the pre-paint composite, where x is from 15 to 50; and the O(CHCHO)H group is bonded to a CH group on the CHchain. The present invention also relates to a coatings composition containing the composite as well as a process for preparing the pre-paint composite and the coatings composition. 1. A process for preparing a pre-paint composite comprising the steps of: [{'sub': '2', 'i) an aqueous dispersion of TiOparticles and an adsorbing sulfur acid functionalized polymer;'}, 'ii) an anionic surfactant;', 'iii) sodium styrene sulfonate; and', 'iv) a redox initiator system;, 'a) contacting together a mixture ofto form a first composite intermediate; then i) methyl methacrylate or styrene or a combination thereof;', {'sub': 1', '10, 'ii) a C-Calkyl acrylate; and'}, 'iii) a carboxylic acid containing monomer under emulsion polymerization conditions;, 'b) contacting under emulsion polymerization conditions the first composite intermediate with a first monomer emulsion comprisingto form a second composite intermediate; then i) styrene or methyl methacrylate or a combination thereof;', {'sub': 1', '10, 'ii) a C-Calkyl acrylate;'}, 'iii) carboxylic acid containing monomer; and', {'sub': 10-15', '22-32', '2', '2', 'x, 'iv) a secondary alcohol ethoxylate of the formula CHO(CHCHO)H;'}], 'c) contacting the second composite intermediate with a second monomer emulsion comprising{'sub': 2', '2', '2', 'x', '10-15', '22-32, 'to form an aqueous dispersion of TiOparticles with incomplete attachment of polymeric binder; where x is from 15 to 50 and the O(CHCHO)H group is bonded to a CH group on the CHchain.'}2. The process of ...
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