21-11-2019 дата публикации
Номер: US20190355953A1
Принадлежит:
LG CHEM, LTD.
A functional binder and a separator including the functional binder, in which the separator includes a porous polyolefin substrate and an organic-inorganic hybrid porous coating layer formed on at least one surface of the substrate and configured to include a mixture of inorganic particles and a binder compound, thus increasing binder-inorganic material adhesion and substrate-binder adhesion while preventing internal shorting from occurring by performing self-healing of damage to the separator, enhancing the adhesion of the separator to a cathode and an anode, and withstanding the dissolution of a transition metal of a cathode material. The binder contains 10 wt % or more of a hydroxyl group per molecule thereof. 1. A battery separator , comprising:(a) a polyolefin-based substrate; and(b) an active layer comprising a mixture of inorganic particles and a binder, wherein the inorganic particles in the active layer are connected and fixed to each other by the binder, and a porous structure is formed due to an interstitial volume between the inorganic particles,wherein the active layer is present as a coating on at least one region selected from the group consisting of (a) a surface of the substrate, and (b) a portion of pores in the substrate, andthe binder contains 10 wt % or more of a hydroxyl group per molecule thereof.2. The battery separator of claim 1 , wherein the binder includes at least one selected from among tannic acid claim 1 , pyrogallic acid claim 1 , amylose claim 1 , amylopectin claim 1 , and xanthan gum.3. The battery separator of claim 1 , wherein the binder is a mixture of1) at least one selected from among tannic acid, pyrogallic acid, amylose, amylopectin, and xanthan gum, and2) at least one selected from among polyvinylidene fluoride-co-hexafluoropropylene, polyvinylidene fluoride-co-trichloroethylene, polymethylmethacrylate, polyacrylonitrile, polyvinylpyrrolidone, polyvinylacetate, polyethylene-co-vinyl acetate, polyethylene oxide, cellulose ...
Подробнее