24-02-2022 дата публикации
Номер: US20220059262A1
Принадлежит:
A two-step diffusion method for preparing high-performance dual-main-phase sintered mischmetal-iron-boron magnet belongs to the preparing technical field of rare earth permanent magnet materials. The compositions of the two main phase alloys are RE-Fe—B (RE is Nd or Pr) and (Nd, MM)-Fe—B (MM is mischmetal), respectively. First, PrHoFe strip-casting alloy is used as a diffusion source. Next, a PrHo-rich layer is uniformly coated on the surface of (Nd, MM)-Fe—B hydrogen decrepitation powders. The higher anisotropic fields of PrFeB and HoFeB are used to improve the coercivity. Then, the ZrCu strip-casting alloy is used as a diffusion source. A Zr-rich layer is uniformly coated on the surface of the powders after the first-step diffusion, which prevents the growth of the MM-rich main phase grains during the sintering process and the inter-diffusion between the two main phases, thus obtains high coercivity. 1. A two-step diffusion method for preparing high-performance dual-main-phase sintered mischmetal-iron-boron magnet , wherein the high-performance dual-main-phase sintered mischmetal-iron-boron magnet comprises a Pr/NdFeB main phase A and a (E , Nd)FeB main phase B , hydrogen decrepitation coarse powders of the main phase B is subjected to two-step rotating diffusion treatment , then mixed with hydrogen decrepitation coarse powders of the main phase A , a mass ratio of the main phase A to the main phase B is 1:9-5:5 with the sum being 10;{'sub': x', '100-x-y-z', 'y', 'z', 'a', '1-a', 'x', '100-x-y-z', 'y', 'z, 'wherein nominal composition of the main phase A is Pr/NdFeMB(wt. %), and nominal composition of the main phase B is [ENd]FeMB(wt. %), where E is mischmetal, and mass percent of each component is Ce: 48-58%, La: 20-30%, Pr: 4-6%, and Nd: 15-17%; M is one or more of Nb, Ti, V, Co, Cr, Mn, Ni, Zr, Ga, Ag, Ta, Al, Au, Pb, Cu, Si, x, x1, y, z satisfies the following relationships: 0≤a≤1, 25≤x≤35, 0.5≤y≤3, 0.3≤z≤1.5;'}the two-step diffusion method comprising the ...
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