05-04-2012 дата публикации
Номер: US20120083127A1
A method for forming a fine pattern on a substrate includes providing a substrate including a material with an initial pattern formed thereon and having a first line width, performing a self-limiting oxidation and/or nitridation process on a surface of the material and thereby forming an oxide, a nitride, or an oxynitride film on a surface of the initial pattern, and removing the oxide, nitride, or oxynitride film. The method further includes repeating the formation and removal of the oxide, nitride, or oxynitride film to form a second pattern having a second line width that is smaller than the first line width of the initial pattern. The patterned material can contain silicon, a silicon-containing material, a metal, or a metal-nitride, and the self-limiting oxidation process can include exposure to vapor phase ozone, atomic oxygen generated by non-ionizing electromagnetic (EM) radiation, atomic nitrogen generated by ionizing or non-ionizing EM radiation, or a combination thereof. 1. A pattern forming method comprising:providing a substrate including a material with an initial pattern formed thereon and having a first line width;performing a self-limiting oxidation, nitridation, or oxidation and nitridation process on a surface of the material inside a process chamber of a processing apparatus and thereby forming an oxide, nitride, or oxynitride film on a surface of the initial pattern, wherein the self-limiting oxidation, nitridation, or oxidation and nitridation process includes exposing the surface of the material to vapor phase ozone, atomic oxygen generated by non-ionizing electromagnetic (EM) radiation, atomic nitrogen generated by ionizing or non-ionizing EM radiation, or a combination thereof; andremoving the oxide, nitride, or oxynitride film,wherein the pattern forming method is arranged to repeatedly perform formation of the oxide, nitride, or oxynitride film and removal of the oxide, nitride, or oxynitride film so as to form an second pattern having a ...
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