08-11-2012 дата публикации
Номер: US20120283487A1
Tungsten carbide catalysts are used in preparation of ethylene glycol by hydrogenating degradation of cellulose. The catalyst includes tungsten carbide as main catalytic active component, added with small amount of one or more transition metals such as nickel, cobalt, iron, ruthenium, rhodium, palladium, osmium, iridium, platinum, and copper as the second metal, supported on one or more porous complex supports such as active carbon, alumina, silica, titanium dioxide, silicon carbide, zirconium oxide, for conversion of cellulose to ethylene glycol. The catalyst realizes high efficiency, high selectivity, and high yield in the conversion of cellulose to ethylene glycol at the temperature of 120-300° C., hydrogen pressure of 1-10 MPa, and hydrothermal conditions. Compared to the existing industrial synthetic method of ethylene glycol using ethylene as feedstock, the invention has the advantages of using renewable raw material resources, environment friendly process, and excellent atom economy. 1. A method of catalytic degradation of cellulose , comprising:obtaining a mixture comprising cellulose, water, and a catalyst;placing the mixture in a reactor filled with hydrogen; andkeeping the mixture at an elevated temperature for a certain reaction time,{'sub': 'x', 'wherein the catalyst has a formula A-WC/B, in which component A represents one or more metallic elements chosen from nickel, cobalt, iron, ruthenium, rhodium, palladium, osmium, iridium, platinum, and copper, and WxC represents tungsten carbide, wherein 1≦x≦2, and'}component B is a porous support chosen from active carbon, alumina, silica, titanium oxide, silicon carbide, zirconium oxide, and mixtures thereof.2. The method of claim 1 , wherein a total loading of A-WxC in said catalyst is 2-85 wt % claim 1 , in which the loading of component A is 0.05-30 wt % and the loading of tungsten is 1-80 wt %.3. The method of claim 2 , wherein the loading of tungsten is 10-60 wt % and the loading of component A is 0.1-5 ...
Подробнее