12-03-2015 дата публикации
Номер: US20150071849A1
Systems and methods for the formation of carbon-based nanostructures are generally described. In some embodiments, the nanostructures may be formed on a nanopositor. The nanopositor can comprise, in some embodiments, at least one of metal atoms in a non-zero oxidation state and metalloid atoms in a non-zero oxidation state. For example, the nanopositor may comprise a metal oxide, a metalloid oxide, a metal chalcogenide, a metalloid chalcogenide, and the like. The carbon-based nanostructures may be grown by exposing the nanopositor, in the presence or absence of a growth substrate, to a set of conditions selected to cause formation of carbon-based nanostructures on the nanopositor. In some embodiments, metal or metalloid atoms in a non-zero oxidation state are not reduced to a zero oxidation state during the formation of the carbon-based nanostructures. In some cases, metal or metalloid atoms in a non-zero oxidation state do not form a carbide during the formation of the carbon-based nanostructures. 169-. (canceled)70. A method of growing carbon-based nanostructures , comprising:exposing a solid carbon-based nanostructure precursor to a nanopositor comprising at least one of metal atoms in a non-zero oxidation state and metalloid atoms in a non-zero oxidation state under conditions causing the formation of carbon-based nanostructures.71. The method of claim 70 , wherein the solid carbon-based nanostructure precursor comprises at least one of coal claim 70 , coke claim 70 , amorphous carbon claim 70 , unpyrolyzed organic polymers claim 70 , partially pyrolyzed organic polymers claim 70 , diamond claim 70 , graphite.72. The method of claim 70 , wherein the nanopositor comprises a metal oxide.73. The method of claim 72 , wherein the nanopositor comprises at least one of a zirconium oxide claim 72 , a silicon oxide claim 72 , an aluminum oxide claim 72 , a titanium oxide claim 72 , an yttrium oxide claim 72 , a hafnium oxide claim 72 , a tantalum oxide claim 72 , a ...
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