09-09-2021 дата публикации
Номер: US20210275998A1
Some embodiments of the invention include inventive catalysts (e.g., catalysts of Formula (I)). Other embodiments include compositions comprising the inventive catalysts. Some embodiments include methods of using the inventive catalysts (e.g., in hydrofluorination of an organic compound). Further embodiments include methods for making the inventive catalysts. Additional embodiments of the invention are also discussed herein. 1. A catalyst selected from Formula (I){'br': None, 'i': 'x', 'resin-anion-HF\u2003\u2003(I)'} resin is an anion exchange resin,', {'sub': 4', '2', '4', '4', '4', '3', '3', '4', '3', '3', '4', '3', '2', '3', '3, 'sup': −', '−', '−', '−', '2−', '3−', '−', '−', '−', '−', '−', '−, 'anion is HSO, BzO, AcO, HPO, HPO, PO, MeSO, NO, ReO, CFSO, ClO, or CF(CF)SO, and'}, 'x is 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, or 25., 'wherein'}2. The catalyst of claim 1 , wherein the resin comprises a secondary ammonium group claim 1 , a tertiary ammonium group claim 1 , or a quaternary ammonium group.3. The catalyst of or claim 1 , wherein x is 5 claim 1 , 6 claim 1 , 7 claim 1 , 8 claim 1 , 9 claim 1 , 10 claim 1 , 11 claim 1 , 12 claim 1 , 13 claim 1 , 14 claim 1 , 15 claim 1 , 16 claim 1 , 17 claim 1 , 18 claim 1 , 19 claim 1 , or 20.4. The catalyst of any of - claim 1 , wherein x is 5 claim 1 , 10 claim 1 , or 15.5. The catalyst of any of - claim 1 , wherein the anion is HSO claim 1 , BzO claim 1 , AcO claim 1 , HPO claim 1 , HPO claim 1 , or PO.6. The catalyst of any of - claim 1 , wherein the anion is HSO.7. The catalyst of any of - claim 1 , wherein (1) the catalyst is resin-HSO-5HF claim 1 , resin-HSO-10HF claim 1 , or resin-HSO-15HF claim 1 , (2) the resin comprises a quaternary ammonium group or trimethylammonium claim 1 , or (3) both.8. A composition comprising the catalyst of any of - claim 1 , and a solvent.9. The composition of claim 8 , wherein the solvent is DCM (dichloromethane) claim 8 , DCE (1 claim ...
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