07-09-2017 дата публикации
Номер: US20170253681A1
Автор:
Dong Jinyong,
FU Wenxin,
Guo Jing,
Li Chuncheng,
Lin Xuechun,
MA Yongmei,
SHEN Heng,
Sun Wenhua,
Xu Jian,
Zhao Ning,
ZHU Tang
Принадлежит:
The present invention provides a composition for 3D printing, a process for preparing the same and an article thereof. By the solidifying method of UV irradiation, 3D printing is implemented. During said implementation, there is no need of high temperature heating, thus energy consumption is reduced, and there is no need for special solvent, thus harm to the environment is reduced. Meanwhile, the present invention uses micro-nano powder as the main material and polymer resin as adhesive, and at the same time, adds irradiation sensitizer. After electron beam irradiation, the polymer resin forms three-dimensional crosslinked network, thereby the strength, heat resistance and chemical resistance are improved after resin adhesion. Additionally, the present invention, by the addition of UV crosslinking agent, and by UV irradiation, cross-links the unsaturated resin after extrusion in 3D printing to form three-dimensional network structure, thus greatly improves the heat resistance, chemical resistance and mechanical strength of the shaping material, and makes the unsaturated resin have broader application prospects in 3D printing material. 1. A composition for 3D printing comprising the following components:photosensitive monomer: 100 parts by weight,photoinitiator: 1 to 3 parts by weight,micro-nano powder: 1 to 30 parts by weight,crosslinking agent: 1 to 30 parts by weight,toughening agent: 1 to 10 parts by weight, andpigment: 5 to 10 parts by weight;wherein the photosensitive monomer is monofunctional acrylate which is in liquid state at room temperature.2. The composition according to claim 1 , wherein the monofunctional acrylate which is in liquid state at room temperature is one or more selected from the group consisting of methyl methacrylate claim 1 , ethyl methacrylate claim 1 , propyl methacrylate claim 1 , isopropyl methacrylate claim 1 , benzyl methacrylate claim 1 , lauryl methacrylate and acrylate derivatives;preferably, the photoinitiator is alkylphenones, ...
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