17-06-2021 дата публикации
Номер: US20210179842A1
Автор:
BI Fuyong,
Hu Huijie,
Li Dezhan,
LIU Zhenjie,
QlAO Jinliang,
Shao Qing,
Song Wenbo,
YIN Hua,
Yuan Hao,
Zhang Jie,
Zhang Shijun,
Zhang Xiaomeng
Принадлежит:
A microspheric ionomer having a cross-linked structure, a preparation method therefor, applications thereof, and a preparation system thereof. The ionomer comprises structure units A represented by formula (1), structure units B represented by formula (2), and a cross-linking structure provided by a cross-linking agent, M being separately selected from H, a metal cation, and a straight chain, a saturated alkyl of branched or ring-shaped C-C, R being H or a methyl; and metal cations are introduced to part of structure units A in the ionomer. The ionomer shows an outstanding effect on nucleation of PET, serves as a nucleating agent for PET modification, so as to obtain a corresponding PET composition. A system and method for continuously preparing maleic acid ester ionomer microspheres and cross-linked maleic acid ionomer microspheres, so as to achieve continuous preparation, washing and separation of ionomer microspheres, effectively stabilizes the separation effect, and avoids frequent start and stop operations of a centrifuge. 2. The ionomer according to claim 1 , wherein the molar content of the metal cation in the ionomer comprises 10-120% of the total molar amount of structure unit A in the ionomer.3. The ionomer according to claim 1 , wherein the cross-linking degree of the ionomer is ≥65%.4. The ionomer according to claim 1 , wherein the ionomer has an average particle size of 150 to 2000 nm.5. The ionomer according to claim 1 , wherein the molar ratio between the structure unit A and the structure unit B is 100:(100-120).6. The ionomer according to claim 1 , wherein the molar ratio between the structure unit A and the cross-linking structural unit is 100:(1-40).7. The ionomer according to claim 1 , wherein the cross-linking agent is selected from divinylbenzene and an acrylate cross-linking agent containing at least two acrylate groups claim 1 , wherein the structural formula of the acrylate groups is: —O—C(O)—C(R′)═CH claim 1 , with R′ being H or C-Calkyl.8. ...
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