29-01-2015 дата публикации
Номер: US20150030846A1
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To improve the single crystallinity of a stacked film in which a ZrOfilm and a YOfilm are stacked or a YSZ film. A crystal film includes a Zr film and a stacked film in which a ZrOfilm and a YOfilm formed on the Zr film are stacked, and has a peak half-value width when the stacked film is evaluated by X-ray diffraction being 0.05° to 2.0°. 1. A crystal film comprising:a Zr film; and{'sub': 2', '2', '3, 'a stacked film in which a ZrOfilm and a YOfilm are stacked or a YSZ film, formed on said Zr film,'}wherein a peak half-value width when said stacked film or the YSZ film is evaluated by X-ray diffraction is 0.05° to 2.0°.2. The crystal film according to claim 1 , wherein thickness of said Zr film is 0.2 nm to 30 nm.3. The crystal film according to claim 1 , wherein said stacked film or said YSZ film is an oriented film oriented in (100).4. The crystal film according to claim 1 , wherein said crystal film is formed on a substrate having a (100) crystal plane.5. The crystal film according to claim 1 , wherein:on said stacked film or said YSZ film, a Pt film oriented in (100) is formed; anda peak half-value width when said Pt film is evaluated by X-ray diffraction is 0.05° to 2.0°.6. The crystal film according to claim 5 , wherein:dielectric film is formed on said Pt film; and{'sub': '3', 'said dielectric film is represented by a general formula ABO, being a film containing a perovskite material, A including at least one element selected from the group consisting of Al, Y, Na, K, Rb, Cs, La, Sr, Cr, Ag, Ca, Pr, Nd, Bi and an element of the lanthanum series in the periodic table, B including at least one element selected from the group consisting of Al, Ga, In, Nb, Sn, Ti, Ru, Rh, Pd, Re, OSirPt, U, Co, Fe, Ni, Mn, Cr, Cu, Mg, V, Nb, Ta, Mo and W, or being a film containing a bismuth layered-structure ferroelectric crystal having a structure in which a bismuth oxide layer and a perovskite-type structure block are stacked alternately, said perovskite-type structure block ...
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