NEW USE OF ORGANIC COMPOUNDS

RK 395,362 B the Erf'mdung concerns a procedure for the fight against Schnittwundparasiten on plants and/or the diseases (S chnittwundkrankheiten) these parasites with plants causes and preparations, which are suitable for such use. Schnittwundparasiten are Fungi or bacteria, which parasiüeren Sclmittwunden of wood-like plants, which can lead to loss or damage of such plants. An important Schnittwundparasit is Eutypa armenica, a Fungus of the family of the Ascomycetes, also Eutypa admits lata under the name (see B. Dubos et al., to Phytoma, Defense of the cultures, July August 1980, pages 13-15 and A. Bolay, revue Suisse de Vitie. Arboric. Hortic. 16, 265-273 (1984). The mushroom illness caused by E. lata is called in the following Eutypiose. Different connections such as Benoclanil, Bitertanol, Triadimenol, Triadimefon, Captafol, Pyracarbolid and in particular fungicides of the Benzimidazol Stmkturklasse such as Carbendazim were suggested and/or used for the fight against Schnittwundparasiten. These connections could not prevent however a dramatic spreading of these parasites. It was now found that the connections of the formula I c1 C - cH2 - N/“I R where X for H or CI and R for Butyl, 1-Cyclopropyl-ethyl or 1-Cyclopropyl-l-methyl-ethyl to stand, particularly well for the fight and/or prevention of Schnittwundkrankheiten are suitable. If R stands for Butyl, it means in particular n-butyl or tert. Butyl. Preferential connections of the formula I are the connection of the formula I where X for chlorine and R for n-butyl stand (Hexaconazol) and the connection of the formula I where X for H and R for 1-Cyclopropyl1 - methyl - ethyl stand (Cyproconazol). The connections of the formula I are used appropriately in free form or in the form of an acid addition salt acceptable in rural economy. The connections of the formula I are well-known fungicides. She was not suggested so far however for the fuel element “fighting of Schnittwundkrankheiten and/or the Eutypiose. The connections of the formula I and in particular Cyproconazol are particularly effective against schnittwundparasitierende Fungi and bacteria of perennial plants. So they can against Cylindrocarpon Mali on fruit trees, Cytospora cincta on Pfirsichbäumen, Erwinia amylovora on fruit trees, Pseudomonas syringae and spp. on Obstbaumen, Agrobaeterium tumefaciens on common grape vines, Erwinia vitivora on common grape vines, Stereum hirsutum on common grape vines and Eutypa lata on fruit trees and common grape vines to be inserted. The connections of the formula I can be used from there for the fight against Schnittwundkrankheiten in particular by Eutypiose, on perennial plants, be cut first during the vegetative rest period by the Obstoder the flower yield to increase and/or the yield quality improve. The invention concerns therefore a procedure for the fight against Schnittwundkrankheiten with plants, thereby characterized that one parasitize-ends Fungi effective quantity of a connection of the formula I to the cuts against appliziert. Examples by perennial plants according to the procedure according to invention to be treated can are fruit plants such as apricot, Mango, plum, Pfirsisch, apple, pear, cherry, Quitte, black one, red one or white currant, Walnuß, fig, Kakipflaume and elder, perennial gärmerische cultures, ornamental plants, rose cultures and in particular common grape vines. The connections of the formula I can and will appropriately in combination with other fungicides, e.g. with contact contacts such as Folpet, Thiram or copper fungicides, and in particular with Benzimidazol fungicides such as Benomyl and Carbendazim, in particular with Carbendazim, appliziert. Suitable bactericidal ones can be admitted likewise. Examples by bactericidal one, those in combination with the connections to be that-formally used know are organischeßakterizide wießlasticidin, Cycloheximid, Griseofulvin, Kanigamycin, Oxytettaylin, Streptomycin, Validamycin, Oxine copper, Nilrapyrin, Dithianon NaPyrion, Calvinphos, Flumequin undbakterizidequatemäre Ammoninmsalze wieCetyl trimethylammoniumchlorid. In the procedure according to invention the connections of the formula I, and/or their mixtures with other fungicides and/or bactericidal ones are used appropriately in form fungicides of a preparation. Such preparations know 395,362 B ME on actually well-known way, e.g. by mixing a connection of the ForAT! I and aUfälliger additional Wkkstoffe with suitable formulation aids such as solvents and if necessary further Zus, corrode like boundary surface-active substances, pigments, thick etc. to be received. The Appllkation of such preparations to the cuts should take place with largest care, so that all cuts are essentially treated. The preparations should in addition also a sufficient Hafffestigkeit exhibit, so that they will not abgewaehen from rains and also thereby them as agents for free bruises against infections to protect to be able. Sprayoder S deaf applications might not always lead to the desired results. A more appropriate and more effective kind of application is with the help of one building-decays Reschere (designated herein briefly than Banmschere), which by a container provided isL the one preparation of the desired Aküvsnbstanz (EN) contains, and to which container the formulation is removed during cutting, on one or both shears blade anfgebraeht and over a suitable surface from it distributed. Different containers equipped with such device are from the literature admit (e.g. see the FR-A1-8510206). The formulations suggested so far for such kind of application possess however all certain-eight-hurry like unsuitable viscosity, insufficient adhesive strength etc. The available invention concerns formulations, which are suitable particularly well for the application by means of above-defined pruning shears. These preparations contained a) an effective quantity for the fight against Sehnittwundparasiten of suitable fungicide and/or bactericidal, and b) an oily, thixotropes, hydrophobes, non-phytotoxic medium and is water-free. The expression, thixotrop " refers to in medium, which is viscous, if in peace and is liquid, if under the influence of mechanical forces, e.g. by vibrating or if under pressure. The oily, thixotrope, hydrophobe, non-phytotoxic medium consists essentially of a nichtphytotoxisehen, hydrophoben oil and one not phytotoxisehen, thixotropen additive. The nieht phytotoxic, hydrophobe oil can e.g. be a mineral oil, a vegetable oil, an animal oil, a synthetic oil, or a mixture of it. Examples of suitable mineral oils are vaseline and paraffin oil. Examples of suitable vegetable oils sindErdnu -, Croton, coffee, Rizinns, almond, walnuß, Palm, coconut, flax, poppy, olive, Traubenkeruen, sesam, hemp, corn germ, Sonnenblnmen, soy bean, rape, and BaumwollesamenOl, as well as mixtures of it. Examples of suitable animal oils are Fischöle, Kabeljauleberöl, seal oil, whale oil and ox leg oil. Examples of suitable synthetic oils are hydrogenated oils or mixtures of it with a epoxydierten vegetable oil or with mixtures of epoxydierten vegetable oils. Further examples more suitably hydrophoben oils cover dessikante oils and silicone oils. Preferably a Mineral61, in particular Paraff'm61, becomes or a if necessary epoxydiertes vegetable oil or a mixture of such vegetable oils epoxydierten if necessary uses. If the hydrophobe oil is a vegetable oil, or a derivative of it, is preferably the vegetable oil Sonnenblumen61 or corn germ oil. The thixotrope additive is appropriately a thick, which forms a thixotropes, oily, hydrophobes, not phytotoxisehes medium with the hydrophoben oil. The thick can be natural, artificial, semi synthetic or synthetic origin. Examples of suitable natural thick cover Magnesiumhydroxid, Bentonittone and colloidal silica. Example of suitable thick of animal origin are Eialbumin, blood albumin, Kasein, bone glue and skin glue. Examples of suitable thick of vegetable origin cover stärkehaltige products such as corn strength and vegetable rubbers such as Gummiarabikum, Xanthangummi, Tragantgnmmi, carob flour rubber and from Cyamopsis tetragonolaba won rubber. Examples more suitably more artificially or semi synthetic thick are received modified strength products like acid-modified strength, oxidized strength, easily veruetzte strength by reaction with Ethylenoxid, verätherte strength, carboxmethylierte strength, methylierte strength, hydroxyethylierte strength, strength dismantling products, verätherte cellulose such as Methylzellulose, Carboxymethylzellulose, Methylhydroxyethylzellulose, Hydroxyethylzellulose and Hydroxypropylmethylzellulose. Example-suitable of synthetic thick being polymere products wiePolyvinylalkoholeundPolyacrylsäure. Particularly suitable thick are inorganic thick, in particular colloidal silica, preferably pyrogene colloidal silica. The weight ratio between the thixotropen additive and the hydrophoben oil lies appropriately between 0.1 • 99,9 and 1: 9, in particular between 0.5: 99.5 and 1: 15, preferably between 1: 99 and 1: RKs 395,362 B of examples of fungicides active substances, which thixotropen themselves according to invention for the formulation to that preparation form are suitable, are sulfur; Benzimidazolderivate such as Benomyl, Carbendazim and thiabendazol, Thiophanate such as Ethylthiophanat and Methylthiophanat; Dithiocarbamatderivate such as Thiram and Maneozeb; Phthalimidderivate such as Captan, Folpet and Captafol; Ergosterol bio-synthesis Inhibitore, for example such, which belong to the general class of the Pyrimidine like Fenarimol, Triarimol and Nuarimol, such to the general class of the Morpholine geh& EN such as Dodemorph, Tridemorph and Fenpropimorph, such to the general class of the Imidazole belong like Prochloraz, ¥inconazol, to Triflumizol and ImaTzlil, such to the general class of the Pyridine belong like Pyrifenox and Buthiobat, such to the general class of the Triazole belong like Hexac naz to F usi az Eta naz Triadimef n Triadimen Pr pi naz Di h butraz Bitertan Penc naz Flutriafol and 2 (4-Chlorphenyl) - 3-cyclopropyl-l (1H-1,2,4-triazol-l-yl) - butan-2-ol (Cyproconazol); Copper fungicide how/as copper (II) carbonate, copper (left) calcium sulfate, copper (II) calcium oxychlorid, Tetrakupfer0I) oxyehlorid, Burgunder Misehung, Bordeaux mixture, Cu20, copper (II) hydroxide, copper (II) oxychlorid and copper complexes as [cu-n (CH2CH2OH) 3] (OH) 2, [cu (NH2CH2CH2NH2) 2] SO4 and mixtures of such fungicides. Examples of bactericidal active substances, which are suitable for the formulation for the erfindungsgemäfien thixotropen preparation form, are the bactericidal one, which were enumerated above and into combination with the connections of the formula I in the procedure according to invention to be used to be able. Preferential preparations in accordance with the invention contain as active substance a copper fungicide such as copper (IDoxychlorid or copper (II) sulfate (e.g. in the Tetrakupfer (II) - tri calcium form), Benomyl, Carbendazim, Thiram, Folpet, Ergosterol bio-synthesis inhibitors, in particular those the Triazol Slrukturklasse, preferably connections of the formula I, at most prefer Hexaconazol or Cyproeonazol, in the special Cyproconazol, and mixtures of these active substances. Particularly preferential preparations are preparations the Carbendazim, Thiram, Folpet and if necessary a copper fungicide and/or a bactericidal such as Cetyltrimethylammoninmchlorid contained, as well as preparations, which Hexaconazol prefers or, more Cyproconazol if necessary contained in combination with Carbendazim. , Thixotropen preparations according to invention and the hydrophoben contain appropriately from 0.5 to 10 weight percentage, in particular from 1 to 5 weight percentage at active substance. The hydrophoben, thixotropen formulations according to invention can contain further additives, e.g. Coloring materials, in order to examine Verteilungder preparation for the cuts, boundary surface-active substances, so that the formulation takes the whole Schnittwundfläche off, additional solvents, antifreeze, anti-oxidising agent etc. Formulations according to invention and the thixotropen exhibit appropriately a viscosity from 200 to 1500, in particular from 500 to 1200, preferably from 800 to 1000 cp. They are appliziert as a thin layer and so that the formulation covers the cut over its whole surface. Formulations according to invention and the thixotropen form, immediately after application a hydrophobe layer, which protects the active substances from washing. Besides have the formulations according to invention, the one pflanzUches oil as hydrophobes oil contain the advantage that they promote the penetration of the active substance (if systemically) to the plants. In the following examples, which describe the invention, parts and per cent are Gewiehtsteile and/or. Weight percentage. Example 1 parts of a connection of the formula I, e.g. 2 (4-Chlorphenyl) - 3-cyclopropyl1 - (1 H1,2,4-triazol1-yl) - butan2-ol, are mixed more finely with 4 parts, synthetic silica, 3 parts of Natriumlaurylsulfat, 7 parts Ligninsulfonat, 66 parts finely distributed kaolin and I0 parts of Diatomeenerde, and the mixture becomes husbands, until the middle particle size amounts to about 5 Micron. In such a way received wettable powder is verdünnnt before the application with water to a Brühe, which can be appliziert as spray. Example of 2 parts of a connection of the formula I are mixed with 10 parts of an emulsifying agent and 80 parts isopropanol. The emulsion concentrate is diluted before the application for desired concentration. Example 3 a part of 2 (4-Chlorphenyl) - 3-cyclopropyl-l (1H-1,2,4-tfiazol-l-yl) butan-2-ol becomes husbands to the middle particle size about 1 Micron amounts to. 97 parts Sonnenblumenöl are then admitted under strong agitating, followed of 2 parts of pyrogener, colloidal silica, and one agitates to a homogeneous mixture is kept further. It remains a fine, hydrophobe, thixotrop dispersion. RK 395,362 B B¢ispM 4 one proceeds as in example 3 descriptive, used however paraffin oil or Malskeim61 instead of Sonnenblumenöl. Example one proceeds as however in example 3 descriptive, used Carbendazim instead of the Triazols as active substance. Example i one proceeds as however in example 5 descriptive, used paraffin oil instead of Sonnenblumenöl. Example 7 one proceeds as however in example 5 descriptive, used corn germ oil instead of Sonnenblumen61. Example 8 one proceed as however in everyone of the examples 5 to 7 descriptive, used Folpet instead of Carbendazim. Beisiel 9 one proceeds as in everyone of the examples 5 to 7 beschweben, used however Benomyl instead of CarbendaTim. Example one proceed like descriptive in everyone of the examples 5 to 7, uses however Methylthiophanat stattCarbendazim. Example 11 one proceeds as however in everyone of the examples 5 to 7 descriptive, used Thiram instead of Carbendazim. Example 12 one proceeds as however in everyone of the examples 5 to 7 descriptive, used Hexaconazol instead of Carbendazim. Beisoiel 13 one proceeds as however in everyone of the examples 5 to 7 descriptive, used a part 30: 230: 430 of mixture of Carbendazim: Thiram: Folpet or 75: 500 of mixture of Carbendzzlm: Eolpet or one: 375 of mixture of Carbendazim: Captan instead of Carbendazim. Example 14 one proceeds as however in everyone of the examples 5 to 7 descriptive, used 1 part of one 1.25: 1 mixture of Carbendazim: Cyproconazol instead of Carbendazim. Example a part of Carbendazim (100%) becomes with 4 parts copper (II) sulfate (a Tetrakupfer (II) - tri calcium connection containing 27% copper) husbands to the middle particle size about 1 Micron amounts to. Then, under violent agitating 93,8 parts paraffin oil and 1,2 parts are admitted more pyrogener, to colloidal silica, and one continues to agitate, until a homogeneous mixture develops. In such a way received fine hydrophobe, thixotrope dispersion has a viscosity of 900 cp. Example 16 one proceeds as however in example 15 descriptive, used Sonnenblumenöl or corn germ oil instead of paraffin oil. Beisoiel 17 one proceeds as in example 15 or 16 descriptive, used however Folpet, Benomyl or a part 230: 30: 430 of mixture of Thiram: Carbendazim: Folpet instead of Carbendazim. Example 18 a part of Carbendazim (100%) and 2 parts copper (II) oxychlorid containing 57% active substance become husbands to the middle Teilchengröl3e about 1 Micron amount to. Then under strong agitating 95 parts paraffin oil and afterwards 2 parts pyrogene, colloidal silica are admitted. One agitates to a homogeneous, hydrophobe, thixotrope mixture is kept further. RK 395,362 B example 19 one proceeds as however in example 18 descriptive, used Sonnenblumenöl or mark germ oil instead of Paraff'möl. Example one proceeds as in example 18 or 19 descriptive, used however Folpet, Benomyl or 1 part 230: 30: 430 of mixture of Thiram: Carbendazim: Folpet instead of Carbendazim. Beisvie121 1 part of Carbendazim (100%), 2 parts copper (II) oxychlorid (containing 57% copper) and 0.5 parts of Cetyltrimethylammoniumchlorid are then admitted to husbands to the middle particle size for instance I Micron amount to under strong agitating of 95,3 parts of Paraff'möl, followed of 1.2 parts pyrogener, colloidal Käeselerde. One agitates further and receives a homogeneous, hydrophobe, thixolxope mixture. Example 22 one proceeds as in example 21 besehrieben, used however Sonnenblurnenöl or corn germ oil instead of paraffin oil. Beisoie123 one proceeds as in example 21 or 22 describes, used however a part of Folpet, Benomyl or one: 230: 430 of mixture of Carbenazim: Thiram: Folpet instead of Carbendazim. Example 24 common grape vines cut with a Rebschere, which is provided by a device for the simultaneous treatment of cuts, e.g. as in the FR-A1-8510206 or WO-A1-8600229 besehrieben. The device essentially consists of a container provided by a valve, which contains the formulation in accordance with example 3 or 4. During cutting the Rzmulierung is appliziert by the container on the shears blade and from there on the longing CCIT wounds. The formulation remains intact on the cuts during a longer time period despite bad weather conditions and protects the wounds from parasites such as Eutypa lata. The formulations are replaced to example in example 24 in accordance with example 3 or 4 by each of the formulations in accordance with example 5 to 23. Similarly good results are obtained.