GERUSTSTOFFHALTIGE DETERGENT MIXTURE

It istbekannt that one receives a increased Relnigungskraft and/or white degree maintenance with the additive of stand materials to that and/or the active synthetic Detergenskomponenten of detergent mixtures, and zw. even if the used washing solution a smaller quantity of the active Detergens contains D n. Cleaning strength is the ability of a solution of the Detergenszusammensetzung for the distance of dirt from fabrics. By white degree maintenance the ability of a washing solution is to be understood to prevent suspended dirt to the Abscheldung on the fabric during the washing process. The expression “Detergenswirkung”, how it is used in the context of the invention, covers both cleaning strength and Weißgradaufrechterhalümg. Stand material effects sindim observed connection with different inorganic salts, like alkali metal carbonates, - bicarbonate, - borate, - phosphates and - sflikate. The best inorganic stand materials are the water-soluble polyphosphates and in particular the water-soluble Pyrophosphate of and tripolyphosphates. Used of this will sodium tripolyphosphate as Gerüststoffam most frequent in firm Waschmi elmischungen. With the beginning of the liquid Wascbm water-soluble Pyrophosphate ttelmischungen is generally preferred, because the tripolyphosphates show the tendency towards the hydrolysis in aqueous solution at long storage periods, whereby something Pyrophosphat and something orthophosphate is formed, welch' a latter less effective Gerüstsboff represents and under other disadvantages a harmful effect on the softness of the treated fabrics shows. Also sometimes in liquid beginnings potassium salts of inorganic stand materials are used, whereby by the advantage of their larger solubility use is made. The kind of the stand material effect is clarified not completely. A connection between the ability of a stand material seems for plasticizing the water, which is used for the beginning by washing solution to exist, and the improved results regarding cleaning strength, which will receive, if the Gerüstsboff is used. Have themselves however not all materials, which work opposite harden-forming Kalziumund magnesium ions in an educated manner, when satisfying stand materials proved. In addition useful stand material effects with the most effective stand materials can be determined above and below the point, with soft the stand material in the Wasehlösung in stoichiometric portions regarding the water hardness are present. gungsproduktenwerdenVerbindungen in many Wasch-und pure, like sodium tripolyphosphate, applied, which bind and prevent Kalziumund magnesium ions in solution complex, Trade Union of German Employees it Reinigungswirkungdes the surface-active Mißels affect disturbing. Another way to reach practically the same consists of falling the calcium and magnesium using different water-soluble inorganic compounds the anions, which with calcium and in a smaller paint with magnesium relatively insoluble precipitations form, contained. Examples of anions, which form precipitations with calcium and magnesium, are the carbonate, Silikatund AIurn nations. One of the main problems with the precipitation-forming stand materials, as they are descriptive above, is the separation of the formed precipitation on the washed fabrics. This is in particular then feeling, if colored fabrics are washed. Usual dirt suspending means, like Natriumcarboxymethylcellulose, are not qualified, the separation by the above Gerüstsü) ffe formed precipitations on colored fabrics, in particular after repetitive washing to prevent. Phosphatgerüstsboffe, which form a complex with the hardness ions, prevent this problem, but it now as wünschensweß proved to omit phosphates in Waschund Reinigungsmit±elprodukten. Eutrophikation represents a natural procedure, which is oderFIüssenwesentlich for the maintenance of the life in lakes, in order to make the growth possible of the plants in the water and to supply fodder for the fish world in such a way. One that principal interest validity today that excessive or accelerated Eutrophikation. A too strong plant growth in lakes and rivers leads to a consumption from the fish-needed Sauersboffs, whereby the correct ecological equilibrium in these waters is disturbed. This excessive Eutrophikation is caused by the excessive nutrients, which arrive in lakes and rivers. The phosphates, which are to be found in most generally used firm Waschund Reinigungsmißelmischungen, represent such nutrients. Phosphates as such cause however no excessive Eutrophikation. Also different nutrients, like carbon and nitrogen, must be present. The combination of the nutrients stimulates that plant growth in lakes and rivers. A goal of the invention is it to create biologically degradable Waschund ReinigungsmitteImischnngen those is phosphorus-free, since the presence of this element in lakes and rivers can contribute to the excessive or accelerated Eutrophikation. Principal purpose of the invention is thereby the creation of a stand material system, with which fällend a working stand material is used, and thus the precipitation in the measure to modify that the separation of the precipitation on the fabrics which can be washed is prevented. ZieI of the invention is to be also created it, Waschund cleaning agent system, which results in an effective Gerüststoffwlrkung einschlieffiich the removal of essentially all Kalziumund magnesium ions in the Wasehlösung. In addition aims invention on creation of Wasch-und Reinlgungsmi elmischungen off, biologically degradable, nich¢phosphorhältige stand material mixtures contained, which in Waßserlösungen within comprehensive concentration range effective are, since the conditions, on which the Haushaltswäsehe takes place, in very strong measure vary due to individual and örtlinher conditions. A goal of the invention is it also to obtain an intensified stand material effect in particular in Hochleisümgswaschmißelmisehungen. The understanding goals are achieved according to invention by creation of gerüststoffhältigen detergent mixtures, existing lm substantial out: a) 5 to 96 Gew. - % of an organic surface-active Miguels from the group anlonischer, nichtionischer, zwißerionischer and ampholytiseher Detergentien as well as their mixtures, b) 95 to 5 Gew. - it % of a mixture from i) an inorganic, fällend working stand material carbonate, Silikatund of aluminate salts and their mixtures water-soluble from the group,) a precipitation modifier, which prevents i. the Büdung of a Fäilung visible with the unarmed eye during 5 min verhindertund 2. setting the formed visible precipitation off from the solution during 20 min, if the Fällungsmodifiziermißel with a Endkenzentratlon of 0, 01 thread - % under the following conditions is present: a solution with a pH value of 10, a solution temperature of 52°C and the following composition of the solution at the beginning of the test: 0, 24 g/1Härteionen with a molar ratio from calcium to magnesium of 3: 1; 0, 05 thread - % fällend working stand material, Gewfchtsverhältnis Natriumcarbonat to Sllikat 1: 1, whereby sodium silicate a SiO2: 1Na2 O-relationship of 2, 0 exhibits; and 0.025 thread - % oberfläohenaktives MißeI with a relationship of Natriumdodeeylbenzolsulfonat: Sodium Ig¢riäthoxysulfonat of 1: 1, whereby the Gewichtsantell the stand material to the Modifi iermittel within the range of 1000: 1 to 1: 1 lies and the relationship of surface-active means: Stand material 20: 1 to 1: 20 amounts to, while the precipitation modifier from the group of the following connections is selected: Mellithsäure; Xylotrihydroxyglutarsäure; Cyclopen n-ois, cis, ois tetracarbonsäure; Polyacrylsäure (middle molecular weight about 3500); Addition product from Polyvinyläthyläther (Molgewioht 4000) and 20% Malelnsäure; Addition product from PL glycol (Molgewieht 1000) - and 10% maleic acid diacetat; Additinnsprodukt from PL glycol (molar weight 600) - and 40% maleic acid diacetat; Addition product from Pentaerythritäthylenoxyd (Molgewieht 4000) - and 40% maleic acid tetraacetat; Additinnsprodukt from Polyä hylenoxyd (20 molecules) - and 32.5% maleic acid spermölalkoholaoetat; Ä hylentetraoarbonsäure; Polyallylsuccinat; HexakaliumcyclopentadienidpenLacarboxylat; Isobutylenmaleinsäureeopolymere; 2, 3.4, 5 - tetrahydrofurane cis, ice, ice teLraoarbuns£ure; Carboxymethylstärke (Substiü tionsgrad 0, 8) 1 Carboxymethylstärke (Substitntionsgrad 1, 7); polyearboxymethylierte Diearboxylstärke (Substitntionsgrad about 2, 8); Sodium salt of Carboxymethylcellulose (Substitutinnsgrad 2, 0) 1 Carboxymefl yldextran (Substi0ationsgrad 2.0) i of propylene maleic acid copolymers; zweisäurige cellulose; oarboxymethyliertes Natriumalginat; Natrlumpolymaleinat (molar weight 2500) i Natriumalginat; Aerylsäure Hydroxyäfhylmaleat copolymers (Gewiohtsverhältnis 70: 30); Polymethacrylsäure; 1: 1 styrene maleic acid copolymers; Polyvinylsulfat; Hexane atrium salt of 1,1, 3.3, 5, 5-Pentanhexaearbonsäure. The-water-soluble salts of the inorganic, fällend working stand materials cover the Alkallmetu] lsalze, like potassium, Lithiumund of sodium salts. The preferential salts are Kaliumund of sodium salts, like Natriumearbonat, - aluminate and - silicate, and potassium carbonate, - aluminate and - silicate. The above description of the radio ion test for a precipitation modifier is necessary because of the completely unforeseeable nature of the connections, which correspond to the test. First that jedwedes means, which is suitable for the Komplexblldung by calcium in solution should be effective, but is not this was accepted not the case. From table 1 of the example 1 that Natriumbfsulfit is well work-cash, however calcium or magnesium does not follow at all complex binds. If this characteristic of the modification of the precipitation of harden-forming ions would stand in relationship with the ability of the Komplexbildung of any given connection, then the relative achievement, which is indicated in the example and according to which Xylotrihydroxyglutarsäure is superior Cyelopentan cis, to ice, ice tetracarbonsäure, welch' the latters again the Mellithsäure is superior, straight would have turned around, if their rank were considered as Komplexblldner, according to which the Melli would be hsäure first, Cyolopentan cis, ice, the cis tetracarbonsäure next and the Xylotrihydroxyglutarsäure the latter. Furthermore is to be considered, chB both Polymaleinsäure and Polyacrylsäure with the molecular weight indicated in example 1 a certain complex education ability have, how only Polyacry! - acid as a FällungsmodifiziermiHel works. The test indicated in example 1 was used, in order the ability of the specified connections to the ModifizierungderHärtefällungin WaschmiHelmischungen, which contains according to invention used a stand material system, to determine. B e i s p i el 1: An attempt, which shows the effectiveness of different gerüststoffhältiger mixtures for the use in the detergent mixtures in accordance with the invention, was implemented with application of the following procedure: 1. one usable the according to invention FäIlungsmodifiziermittel is added, in order a solution with a final concentration of 0, 01 thread - % to form; 2. the pH value of the solution is stopped by addition by sodium hydroxide to a value of 10; 3. gleichzeitigwirdauseinerVorratslösungbei 52oc one-close admitted as follows, in order to stop the desired final concentration; Hardness ions (1VIolverhältnis calcium: Magnesium 3: 1), fällend working stand material (weight ratio Natriumcarbonat: Sodium silicate, where chs sie2: Na2 0-Verhältmis 2, 0 is, 1: 1), and surface-active means (Natriumdodecylbenzolsulfonat: Natriumtalgtriäthoxysulfonat in the relationship 1: 1). The final concentrations were: Hardness = 0, 24 g/l; Stand material mixture = 0, 05 thread - tons; and surface-active means = 0.025 thread - tons; 4, those 1 min gerührtund ö - a time long observes, in order to determine a developing of precipitation. Superior-precipitation-modifier-result in during one of period of more than 30 min no turbidity, while the group of excellent FällungsmodifiziermiHel prevents the turbidity during one period of 30 min; Precipitation modifiers, which form a gloomy solution after 15 min, will become as good designated and those, which form a gloomy solution after 5 min, as moderate responded. The turbidity of the solution is determined as follows: A completely clear solution after 30 min is excellent, an optimal solution forms a very pale-blue colloidal dispersion in the 30 min, does not become however not cloudy. Other solutions with indicated the u time border cloudy or exhibit a milchiges appearance, while bad solutions result in set off precipitations shortly after the addition the carbonate/silicate stand of offes. In table 1 are as FällungsmodifiziermiHe! in the context of the invention usable connections and their achievement with the test descriptive above aforementioned. Table 1: FäqlungsmodifiziermiHel: Mellithsäure Cyclopenhan cis, ice, eistetraoarbonsäure Xylot rfhydroxyglutars äure (Xylarsäure) Polyaorylsäure (middle molecular weight about 3500) sodium silicate of 1,1, 3, 3, 5, 5-Penhgnhexacarbonsäure using weak turbidity: clearly clearly ascertainable precipitation: (C) clearly during the duration of the Versuchszeßraumes (30 min) clearly during the duration of the attempt period (30 min) table 1 (Fortseezung): F ällungsmodifiziermittel: (A) Additionsproduke of Polyvinyläthyläther (Molgewiche 4000) and 20% maleic acid Addieionsproduke of PL glycol (Molgewlehe 1000) - dtaceße and 10% maleic acid Addleionsproduke of PL glycol (IVIolgewicht 600) - dlaeetat and 40% maleic acid Addieionsprodukt of P enta it ythrieäfllyl enoxyd (Molgewieht 4000) - tetraaoeßt and ö maleic acid addition product of PL oxide (20 molecules) - spermölalkoho aceta and 32, 5% maleic acid Äthylentetracarbonsäure Polyallylsuccinat Hexakaliumeyelopentadiamidcarboxylat Isobutylenmaleinsäurecopolymere 2, 3, 4, 5-Tetrahydrofuran-cis, ice, cisteeraearbonsäure using of weak turbidity: ] acre clearly ldar clearly clearly clearly clearly clearly clearly ascertainable F ällung: (C) clearly during the duration of the Versuchszei of area (30 min) clearly during the duration of the attempt tent area (30 min) clearly during the duration of the attempt period (30 min) clearly during the duration of the attempt period (30 min) clearly during the duration of the Versuchszeßraumes (30 min) clearly during the duration of the attempt tent area (30 min) clearly during the duration of the attempt tent area (30 min) clearly during the duration DOS of attempt period (30 min) clearly during the duration of the Versuchszeleraumes (30 min) table 1 (continuation): F ällungsmodifiziermittel: (A) Carboxymethylstärke, substitution degree of 0, 8 Carboxymetäylstärke, Substituüonsgrad 1, 7 polycarboxymethyleierte Dicarboxylstärke, substitution degree of about 2, 8 sodium salt of Carboxymethylcellulose, substitution degree of 2, 0 Carboxymethyldextran, substitution degrees of 2, 0 P ropylen/Maleins äur eCopolymere zweisäurige cellulose (diacid cellulose) carboxymethyliertes sodium silicate Natriumpolymaleinsäure (Molgewlcht 2500) Natriumalginat acrylic acid/HydroxyäthylmaleatC of opolymer e in the relationship 70: Polymethacrylsäure using schwaeher turbidity: ascertainable precipitation: (e) clearly r lar L acre RST [clearly > 30 clearly during the duration of the attempt period (30 min) clearly during the duration of the attempt period (30 min) > 30 > 30 > 30 clearly during the duration of the attempt period (30 min) clearly in the relationship 1:1 Polyvinylsulfat äureCopolymere during S jrol/Maleins duration of the attempt period (30 min) clearly clearly during the duration of the attempt period (30 RA; n) > clearly during the duration of the attempt period (30 min) the part by weight fällend of the working stand material to the Fällungsmodifiziermißel is appropriate for 30 within the range of 1000: 1 to 1: 1. A preferential Anteilsberelch amounts to 500: I to 2: 1. With the preferential Ausf'dhrungsform the invention the preferential ModtfiziermIttel is the following: Mellithsäure, Xylarsäure, Polyacrylsäure, the Addltionsprodukt of Polyä'thylenglykol (molecular weight 600) - and 40% maleic acid, the Natrinmsalz of Carboxymethylcellulose with a Substttutionsgrad of 2, 0, propylene/maleic acid copolymers and Polyvinylsulfat diacetat. In the gerüststoffhältigen detergent mixtures according to invention the following organic synthetic Detergentien can be used. A) Anioni Seifenund synthetic Nichtseffen Detergentten. This class of Detergentien covers usual Alkalimetallseffen, like the sodium, potassium, Ammoniumund Alkylolammoniumsalze of higher Feßsäuren, which contain about 8 to approximately 24 carbon atoms and preferably about 10 to approximately 20 carbon atoms. Suitable Feßsäuren can from naüirlichen sources, as for example from esters of vegetable or animal origin (e.g. Palmöl, Kokoenußöl, Babassuöl, SojabohnenöI, castor-oil, tallow, Walund Fischölen, fats, Schmalz and their mixtures) erhaltenwerden.DieFeßsäuren can also synthetically be manufactured (e.g. by oxidation of oil or through Hych ierung of Carbon monoxide in the Fischer Tropsch procedure). Resinic acids are suitable, like rosins, and such resinic acids in TallöI. Naphthensäuren are also suitable. Natriumund Kaliumseffen can by direct Verseffung of the fats and oil or by neutralization of the free Feßsäuren, which are manufactured in a separate manufacturing process, to be won. Natriumund Kalinmsalze of the mixtures of fatty acids, which come from coconut oil and tallow, is particularly useful, i.e. Natriumund Kaliumtalgund coconut soap. This class of Detergentien covers also water-soluble salts, in particular the alkali metal gases of organic Sehwefelsäurereaktionsprodukte, which exhibit an alkyl residue with approximately 8 to approximately 22 carbon atoms and a Sulfonsäureoder sulfuric acid ester remainder in their molecular structure. (Of the expression “AlkyI” wirdaueh derAlkylabschnißhöherer ecyl radicals covers). Examples of this group of synthetic Detergentien, which elmischungen a part of the preferential stand offhältigen Waschund Reiuignngsmit in accordance with the invention form, are the Natriumoder of potassium alkyl sulfates, in particular those, which by sulfating the higher of alcohols (with Cs - 8 - carbon atoms) to be received, which will receive by reduction of the Glyceride of the Talgoder of coconut oil; Natriumoder Kalinmalkylbenzolsulfonate, in which the alkyl group about 9 to approximately 15 carbon atoms in geradsinniger or verzweigtkettiger configuration, e.g. that one of the type described in the USA patent specifications No. 2.220.099 and No. 2.477.383 anthält (geradkettige LINE NR alkylbenzenesulfonates are particularly valuable, where the alkyl groups exhibit on the average about 13 carbon atoms and some below as C13 äthersulfonate, in particular such ethers of häherer alcohols, which are derived from Talgund coconut oil; Natriumkokoenußölfeßsäuremonoglyceridsulfonate of and sulfates; Natriumoder of potassium salts of sulfuric acid esters of the reaction product of a mol of a higher Fettalkohols (e.g. Talgoder coconut oil alcohol) and for instance 1bis 6 mole ethylen oxide; Natriumoder Kailumsalze of alkyl phenol ethylen oxide ether sulfate with etwalbis about 10 units ethylen oxide for each molecule and in which the alkyl residues about 8 to approximately 12 carbon atoms contain. Another class suitable anienischer organic Detergentien, which are useful in the context of the invention besenders, covers salts of 2-Aeyloxyalkan-l-sul onsäuren. These salts have the general formula O tl OCR2 I Ri-CH CH2 SOù M where g 1 alkyl with 9 to 23 carbon atoms (with the two carbon atoms a group of alkanes forming); R2 alkyl with 1 to 8 carbon atoms; and M a salt-forming remainder mean. The salt screen end remainder of M in the structural formula indicated above a water-soluble-making cation is and can e.g. an alkali metal cation (e.g. Sodium, potassium, lithium), Ammoniumoder of substituießes Ammoninmkation, its. Special examples of substituted Ammoninmkatlonen cover methyl, Dimethylund Trimethylammeniumkationen and quaternäre AmInoniumkationen, like Tetramethylammoninmund Dimethylpiperidiniumkationen, and such, which are derived from alkyl amines, like Äthylamhn, Diäthylamin, - 8 - Nro331946 tri ethyl amine” mixtures the same and such. Special examples für/3-Acyloxyalkan-l-sulfenate or alternatively 2-Acyloxyalkan-l-sulfonate, which are usable in the context of the invention, in order to obtain superior cleaning results on essentially neutral wash conditions, cover sodium salt of 2-Acetoxy the ridecan l sulfonsäure; the potassium salt of 2-Propionyloxy etradeaau l sul ensäure; the Lithinmsalz of 2-Butanoyloxytetradeean-1sulfonsäure the sodium salt of 2-Penüsmoyloxypentadeoau-l-sulfonsäure; the sodium salt of 2-Aceboxyhexadeoan-l-sulfonsäure; the potassium salt of 2-Octaucyloxytetradecan-l-sulfensäure; the sodium salt of 2-Acetoxyheptadecan-l-sulfonsäure; the lithium salt of 2-Acetoxyoctadecan-l-sulfonsäure; the potassium salt of 2-Acetoxynenadecan-l-sulfonsäure; the sodium salt of 2-Acetoxyuncosan-l-sulfensäure; the sodium salt of 2-Propionyloxydocosau-l-stflfonsäure as well as the isomers of it. It preferred - Acyloxyalkan l sulfonatsalze for the use in the context of the invention are the AIkalimetallsalze of - Acetoxyalkau l sulfonsäuren which correspond to the above general formula, where Rl is a AlIrylrest with 12 to 16 carbon atoms; these salts are out preferred by the Staudpunkt of their excellent ReinigunBseigenschaften and their easy availability. Typical examples of described the above - Ace oxyalkansul onate are descriptive in the literature; thus for example in the Belgian patent specification No. 650. 323 the production of certain 2-AcyIoxyalkausulfonsäuren is indicated. Described in the USA Patentsehrfften No. 2.094.451 and No. 2.086.215 determined salt of - Acetoxyalkansulfensäuren. On these literature places in the context of the invention as revealing purchase is taken. A preferential class aniunischer organic Detergentien are die/3-Alkyloxyalkansulfenate. These connections have the following general formula OR2 H I I RiO-SO3MI H H where RI a geradkeßige alkyl group with 6 to 0 carbon atoms; R2 a low alkyl group with 1 to 3 carbon atoms; and NI a salt-forming remainder, as it is descriptive above, mean. Special examples of /3-Alkyloxyalkansulfonate or alternatively 2-Alkyloxyalkan-l-sulfenate, which are usable in the Ribben of the Erfinaung, in order to obtain superior Reinigungsund Weißgraawerte on household conditions, cover: KaIium - methoxydee ausulfonat, sodium - methoxy ridecausui onat, Kalium-/3 -, Natrium-/3 äthoxytetradecylsulfonat - isopropoxyhaxadecylsulfonat, lithium - save. butoxytetradecylsulfonat, sodium - and Arùmonium methoxyoctadecylsulfonat - ne-propoxydodecylsulfonat. Other synthetic anionische Detergentien, which is usable in the context of the invention, is the AlkyIäthersulfate. These materials have the general formula RO (C2 H40) xSO3 M where R a A1kyloder alkenyl residue with I0 to 20 Koldenstoffatomen; x i to 30 and IVf a salzbfldendes Kafion that ddinießen above kind mean. A1kyläthereulfate in accordance with the invention is condensation products of ethylen oxide and univalent A1koholen with i0 to 20 Kohlenstoffa omen. Preferably R exhibits 14 to 18 Kohlenstoffafome. A1kohole knows itself of protecting, e.g., coconut oil or tallow, derives, or can be synthetic. Laurylalkohol and geradkettige alcohols, which are derived from the tallow, are preferred in the context of the invention. Such A1kohole is converted with I to 30, in particular 6 mol portions ethylen oxide and the developing mixture of molecular species, which exhibits 6 mole ethylen oxide per mol alcohol for example on the average, is sulfated and neutralized. Special examples of alkyl ether sulfates in accordance with the invention are lylenglykoläthersulfat Natriumkokosnußalkylät; LithinmtalgalkyItriäthylenglykoläthersulfat and Natriumtalgalkylhexaoxyäthylensulfat. Within the framework invention on reason of the excellent Reinlgungseigenschaften and the easy availability - the Alkalimeta becomes] lkokosnußund Talgn] ky! oxyäthyIenä sulfates with on the average 1 to 10 Oxy'äthylenabschnitten prefers. The alkyl ether sulfates in accordance with the invention are well-known connections and are in the USA Patentsehrfft No. 3.332” 876 besehrieben, on which in the context of the invention as revealing purchase is taken. Further examples anioniseher synthetic Niehtseifendetergentien, which invention-in accordance with-ate under verwanderen term falls, are the reaction product of Feßsäuren, which are neutralized with sodium hydroxide with Isäthtonsäure verestert and, whereby see the fatty acids for example from the coconut oil to derive; Natriumoder of potassium salts of the Fcttsäureamids of Methyltaurtd, where the fatty acids are derived from coconut oil for example. Other anionisehe synthetisehe Detergentlen of this kind is in the USA PatentsehriftenNr. 2,486,921; No. 2,486,922; and No. 2.396.278 besehrieben. Further examples anioniseher, synthetiseher Nichtseifendetergentlen, which fall under the definition according to invention, are the connections, which contain 2 anionisehe functional groups. These are called dianionisehe Detergentlen. Suitable ones dianionisehe Detergentien are the Disulfonate, Disulfate or mixtures the same, which can be veransehaultekt by the following formulas: R (SO) 2 NI2, R (SO4) 2 M2, R (SO3) (so4) M 2, where R is a acyclische aliphatic group of hydrocarbons with 15 to 20 carbon atoms and M stands for a wasserlöslichrnachendes cation, for example C is-20 - Dinatrium-1, 2-alkyldisulfate, C is-20 - Dikalium-1, 2-alkyldisulfonate or - disulfate, Dinatrinm-1, 9-hexadecyldisu] fate, C is-20 - Dinatrium-1,2-alkyldisulfonate, Dinatrium-1,9-stearyldisulfate and 6,10O ctadecyldisulfate. aliphatiseheAbsehniß the Disulfate or Disulfonate is generally essentially linear, which under other reasons is desired, because thereby the Detergensverbindung the desired characteristics of the biological degradableness are lent. The wasserlösliehmaehenden cations cover the usual, in the area of the Detergensteehnik admitted cations, i.e. the ions of the alkali metals and the alkaline earth metals as well as that other metals of the groups of IIA,] eat, llIA, IVA and IVB of the Pertodensystems, exceptionally offered. The preferential water-soluble-making cations are those of the sodium or potassium. This dianionisehen Detergentien is more near in brit. Patentschriß No. 1.151.392 described. Wei of ereßeispieleanionisohersynthetisoher Niehtselfendetergentten, those under this term in accordance with the invention traps, be-being that Irish action product of fatty acids, which is neutralized with sodium hydroxide with Isäthlonsäure verestert and, whereby for example the fatty acids are derived from coconut oil; Natriumoder of potassium salts of the fat ureamids of Methyltaurld, where the fatty acid is derived from coconut oil for example. Other anionische synthetic Detergentien of this kind is in the USA patent specifications No. 2,486,921; No. 2,486,922; and No. 2.396.278 besehrleben. Further anionische synületisehe Detergentien of than Succinamate designated class covered. This class covers such oberflächenakttve means, as Dinatrlum N oetadecylsulfosuecinamat; Tetranatrium n (1, 2-diearboxyäthyl) - N-oetadeeylsulfosueeinamat; Diamylester of Natriumsulfobernsteinsäure; Dlhexylester of Natriumsulfobernsteinsäure and Dioetylester of Natrinmsulfobernsteinsäure. Other suitable antonische Detergentien, which is usable in the context of the invention, is Olefinsulfoaate, which exhibit 12 to 24 carbon atoms. The expression “Olefinsulfonate” is not used in the context of the invention, in order to designate connections, those by sulphonation of A-Olefin mitBels-- complex sulfur tri oxide and to be received it knows following neutralization of the sour Reaktlonsmisehung under such conditions that Sultone, which formed with the reaction under education of the appropriate Hydroxyalkansulfonate hydrolyze become. The Schwefeltrloxyd can be förmig liquid or gas - and becomes usually, wermgleich not necessarily, with inert Verdünnungsmittelu, for example if it is used in liquid form, by liquid SO2, chlorinated hydrocarbons etc., or, if it is used in gaseous form, by air, nitrogen, gaseous SO 2 etc. dilutes. The CR-Olefine, from which the Olefinsulfonate is derived, are Monoolefine with 12 to 24 carbon flavours, preferably 14 to 16 KolRenstoffatomen. Preferably they are geradkettlge Olefine. Examples of suitable 1-Olefineumfassen 1-Dodecen; 1-Tetradeeen; 1-Hexadecen; 1-Octadeeen; 1-Eleosen and 1-Tetracosen. Except the genuine Alkensulfonaten and a portion Hydroxyalkansulfonaten can contain the Olefinsulfona e as a function of the Reaktionsbedlngangen, which portions of the Reak more ionsteünehmer, the kind of the Ausgangsolefine and impurities in the Olefinausatz and of Nebenrea ions lVIaterialien during the sulphonation procedure small quantities other, like Alkendisulfonate. A special anionisches Detergens, which is likewise for use in the context of the invention as excellently proven h t, more near in the USA patent specification No. 3.332.880 described. B) Niehtionisehe synthetic Detergentien. Nichtioni synthetic Detergentien can be generally defined as connections, be formed those by the condensation of groups of alkyl oxides (hydrophüer kind) with an organic hydrophoben compound, which can be aliphatic or alkyl-aromatic nature. The length of the hydropMlen or Polyoxyalkylenrestes, which is condensed with a special hydrophoben group, can be stopped easily under education of a water-soluble connection, which exhibits gewünschf the n equilibrium degree between hydrophilic and hydrophoben elements. For example a well-known class nichtienischer synthetic Detergentien at the 1VLarkt under the trade name “Pluronic” is available. These connections are formed by condensation of ethylen oxide with a hydrophoben base, that results from condensation of propylene oxide with propylene glycol. The hydrophobe section of the molecule, which results in the Wasserunlösltchkeit, has a molecular weight of approximately 1500 to 1800. The addition of Polyox the Flüssigkeitscharak it fäthylenresten the product to is in addition-point-maintained to this hydrophoben section leads to the increase the water solubility of the molecule as a whole and, at which the Polyoxyäthylengehalt constitutes about 50% of the Geasmtgewichts of the condensation product. Other suitable nichtionische synthetic Detergentien cover: 1.Die Polyä'thylenoxydkondensatevon A] kylphenolen, e.g. the condensation products of alkene ylphenolen, a A] the kylgruppe with 6 to 12 Koh] enstoffatomen in either geradkeßiger or verzweigtkettiger configuration exhibiting, with ethylen oxide, whereby ethylen oxide in quantities is present, which correspond to 5 to 25 mole ethylen oxide per mol alkyl phenol. The alkyl substituent in such connections kanu for example derived from polymerized propylene, Diisobutylen, Octen or Nonen its. 2. That Detergentien, which are derived from the condensation from ethylen oxide with the product, which develops with the reaction of propylene oxide and ethylen diamine. For example connections are satisfying, the 40 to 80 Gew. - % Polyoxyäthylen contained and a molecular weight of 5000 to 11000 exhibit, and which develop with the reaction of groups of ethylen oxides with a hydrophoben base, which the reaction product of Äthylendiam! u and surplus propylene oxide represent, whereby the base exhibits a molecular weight in the group order of 2500 and 3000. 3. The condensation product of aliphatic A], which 8 to 22 Koh] enstoffatome in either geradkettiger or verzweigtkeßiger configuration koholen exhibit, with ethylen oxide, e.g. a coconut alcohol - ethylen oxide condensate, which exhibits 5 to 30 mole ethylen oxide per mol coconut alcohol, whereby the Kokosnußalkoholfrak has ion 10 to 14 carbon atoms. 4. Nichtioni Detergentien, including NonylphenoI, which is condensed with either 10 or 30 moles ethylen oxide per mol phenol, and which Kondeneationsprodukte of coconut alcohol with on the average either 5, 5 or 15 moles ethylen oxide per mol alcohol, and the Kandensationsprodukt of 15 moles ethylen oxide with I mol of Trideeanol. Andereßeispiele cover Dodecylphenol, which is condensed with 12 moles ethylen oxide for each MoI lOhenoI; Dinonylphenol, which is condensed with 15 moles ethylen oxide per mol phenol; Dodecylmercaptan, which is condensed with 10 moles ethylen oxide for each Mo Mercaptan; to (N-2-HydroxyäthyI) - lauramid; Nonylphenol, which is condensed with 20 moles Äthylenoxydje mol of Nonylphenol; Myristylalkohol, which is condensed with 10 moles ethylen oxide per mol of Myristylalkohol; Lauramid, which is condensed with 15 moles ethylen oxide per mol of Lauramid; and Diisooctylphenol, which is condensed with 15 moles ethylen oxide. A Detergens with the general formula RtR2 R3 N > O BmCnoxydde ergens), where g 1 represents an alkyl group, the 10 to 28 carbon atoms, 0 to 2 hydroxyl groups and 0 to for instance ether connections enth t, whereby at least one remainder of g 1 is present the one alkyl group with 10 to 18 carbon atoms and represents 0 ether connections; and each of the remainders of R2 and R3 independently of other A] kylreste or hydroxyalkyl remainders with 1 to 3 Koh] enstoffatomen symbolizes. Special examples of Amluoxyddetergenhten cover: Dhnethyldodecylaminoxyd, Dimethyltetradecylaminoxyd, Äthylmethyltstradeoylaminoxyd, Cetyldimethylaminoxyd, Dime hylstearylaminoxyd, Ce yläthylpropylaminoxyd, Di thyldodecylaminoxyd, Diäthyltetradecylamlnoxyd, Dipropyldodecylaminoxyd, bls (2Hydroxyäthyl) - dodeoylaminoxyd, to (2-Hydroxyä hyl) - 3-dodecoxy-l-hydroxypropylaminoxyd, (2-Hydroxypropyl) - mefliyltetradeoylaminoxyd, Dimethyloleylaminoxyd, dimethyl (2-hydroxydodeoyl) - amlnoxyd and the appropriate Deoyl, Hexadeoylund Oetadeeylhomologen of the above connections. 6. A Detergens with the general formula o t Ri…. S R2 (Sulfoxyddetergens), where RI means a A1kylrest with to 28 carbon atoms, 0 to 5 ether connections and 0 to 2 Hydroxylsubstätuenten, whereby at least one remainder of g 1 is an alkyl residue, which contains 0 Ätaherbindungen and exhibits 10 to 18 carbon atoms, and where R2 means an alkyl rust, which 1 to 3 carbon atoms enfiaält and 1 to 2 hydroxyl groups can contain. Examples of this Sulfoxyddetergentien are: Octadecylmethylsulfoxyd, Dodeeylmethylsulfoxyd, Tetradecylmethylsulfoxyd, 3-Hydroxytridecylmethylsulfoxyd, 3-Methoxytridecylmethylsulfoxyd, 3-Hydroxy-4dodecoxybutylmethylsulfoxyd, OetadecyI-2-hydroxyäthylsulfoxyd and Dodecyläthylsulfoxyd. C) Ampholytisehe synthetic Detergentien. Ampholyti synthetic Detergentien can be described generally as derivatives more aliphatiseher or aliphatic derivatives of heterooyelischer secondary and tertiary amines, in which the aliphatic remainder can be verzweigtkettig geradke industrial union or and where one of the aliphaUsehen substituents 8 to 18Kohlenstoffatome contains and at least a anionisehe water-solve-borrow-making group, e.g. Carboxy, a Sulfo or a Sulfato. Examples of connections, which fall under this definition are Natrium-8 (dodecylamino) - proplonat, Natrinm-3 (dodeoylamino) -, Natrium-2 (dodecylamino) propane l sulfonat - ethyl sulfate, Natrlum-2 (dimsthylamino) - octadecanoat, Dinatrinm-3 (N-carboxymethyldodeeylamlno) - propane l sulfonat, Dinatriumoetadeeyliminodiacetat, sodium - 1-earboxymethyl2-undeeylimida zol and Nat rium n, N-to (- hydroxyäfiayl) -2 - sulfato-3-dodeooxypropylamin. D) Zwltterloni synthetic Detergentien. Zwißerioni synthetic Detergentien can be generally described as derivatives aliphatic quaternärer Ammonium-und Phosphoniumoder of tertiary Sulfoniumverbindungen, in which the katlonische atom part of a hetero-cyclic ring can to be and in which the aliphatic remainder geradkeLtg or be verzweigtkettig kùnn, where one of the aliphatic substituents contains 3 to 18 carbon atoms and at least an aliphatic substituent contains a wasserlösllchmachende anionische group, e.g. Carboxy, a Sulfo or a Sulfato. Examples of connections, which fall under this definition, are 3 (N, N-Dirnethyl-N-hexadecylammonio) - 2-hydroxypropan-l-sulfonat, 3 (N, N-Dimethyl-N-hexadecylammonio) - propan-1sulfonat, 2 (N, N-Dimethyl-N-dodecylammonio) - acet t, 3 (N, N-Dimethyl-N-dodeeylammonio) - proplonat, 2 - (N, NDimethyl n - octadeo ylammonio) - ethyl sulfate, 2 - (S-methyl-S-terL hexadecylsulfonio) - ethane l sulfonat, 3 (S-methyl-S-dodecylsulfonio) - propionat, 4 (S-methyl-S-tetradecylsulfonio) -, 1 (2-Hydroxyäthyl) butyrat - 2-undecylimidazolium-l-acetat, 2 (Trimethylammonio) - oetadeeanoat and 3 [N, N-to (2-Hydroxyäthyl) - N - oetadecylammonio] - 2-hydroxypropan-l-sulfonat. Some this Detergentien are descriptive in the following USAPatentsohriften: No. 2,129,264; No. 2.178, 3S3 No. 2.774, 786; No. 2.813.898 and No. 2,828,332. Segenund the anionisehen, nichtionischen and zwittertonlsohen Nichtseffendetergentien, as they are mentioned above, can be used as only surface-active means, or those, ¢erschiedenen example ability with derpraktisohenAusf'ührung the invention in mixture eLugese time become. The above Be4ö posting covers only special illustrations of the numerous oberfläohenaktiven means, which can find in the context of the invention application. Understanding Waschund ReinigungsmRtelmisehungen can be verarbeltet to the arbitrary different forms desired in the trade by compositions, for example grains, flakes, liquids and tablets. The specific effect gerüststoffhältigen Waschund Reinigungsmißelmisehungen in accordance with the r - in certain measure as a function of the relationship Aktl'¢ detergens to stand material mixture in given Waschund Reinlgungsmittelmischung will vary. A further variation is given by the strength of the washing solutions, which is used by different housewives. In addition Variationenhinslchtlioh temperature and Sohmutzbeladungen result as between washing processes. Furthermore the degree of hardness of the water used for the beginning of the Wasehlösungen will likewise contribute to differences regarding the cleaning strength and Weißgradaufrechtvrhalbmgsergebntsse. Finally will different fabrics in somewhat different way to different Waschund Reinigungsmi elmischungen to respond. The best type for Waschund Reinigungsmt elmischungen for use in the household a mixture would be theoretical, which guarantees excellent Reinigungsund Weißgraddufrechterhaltungsergebntsse on the very different cleaning conditions. Gerüststoffhälttgen Waschund Reinigungsmittelmisehungen in accordance with the invention is particularly valuable in this regard. Into the gerüetstoffhältigen Waschr i contained mixtures from anorganisehem, fällend working stand material and precipitation modifier elmisehungen are very effective and can be generally used, in order to obtain same Detergenswirkung with a smaller total quantity of the stand material, related to the total quantity of the active Detergensbestandtefls, in accordance with the invention. Particularly favorable degrees of the stand material activity can be obtained during the practical execution of the invention with conditions vo Detergensakivbestandteil to Gerüsistoffmischung, the 10: 1 to 1: 10 amounts to. The detergent mixtures according to invention become usually for special purposes different additives containing. Thus sow foam amplifiers, Sehaumunterdrücker, Anttkorrosionsmi know el, anti-speech position means, germizide means, antibacterial means, coloring materials, fluorescence materials, Parfums, enzymes and such enfJaalten, without impairing the basic knowing characteristics of the invention. During the production of liquid Waschmittelmisvhungen Wasseroder alcohol carrier or mixtures of the two zusarnrnen with öslichkeitsverbessernden means and such, as actually admits, can be used. This form position no place-no-eat-cross-setting-eating cross-setting that invention GDR, but falls only under the mixtures according to invention, which consist imwesentlichen of organic oberfläehenaktiven Besfmndteilen and a mixture of anorganisehem, fällend working stand material and Fällungsmodifiziermi el. The Waschmi elmisohungen in accordance with the invention is preferably used, in order to adjust in aqueous washing solution a ptt Weß within the pH range from 7 to 12. The optimal stand material effects are received within this range. Wash temperatures lie usually FM range from 27 to 93°C. The fabric after washing are preferably rinsed and getroeknet. The invention wfrd by the following example continues to illustrate: B e i s p i e 1 2: A firm Hochleisbmgs Waschund Reinigungsmittelmisehung is set according to the following data, where the percentage figures weight percentage bedehnten: 25% 5% 25% 25% 10% remainder sodium salt of sulfuric acid esters of the Reaktionsproduk0es of a mol tallow alcohol mlt 1 to 6 moles Ä ylenoxyd; Hexane atrium salt of Benzolh acarbonsäure Natriumcarbonat sodium silicate (relationship SiO2/Na20 = 2, 0) Natrinmsulfat humidity. No Fhoreszenzstoffe or Antiredepositionsml is used el. The sodium salt of the sulfuric acid esters of the reaction product a mole a tallow alcohol with 1 to 6 moles ethylen oxide was selected as syn etisches surface-active Mißel of high cleaning strength. The stand material mixture resulted in out drawn Komplexbildungsund Weißgradaufreehterhalümgseigenschaften in the comparison with the conditions - pool of broadcasting corporations stand material sodium tripolyphosphate in the case of application of the same alone in one otherwise equal compound Waschund Reinigungsmit2elmisehung. The portion of 5% hexane atrium salt of the benzene hexadecimal carbonic acid can be replaced by the following connections: Cyolopenf on-cis, ice, ice tetracarbonsäure; Xylarsäure; Adipic acid; water-soluble Polyacrylsäure and Hexanatrium-1,1, 3, 3, 5, 5-pentanhexacarboxylat.