코티솔 결합 나노입자를 포함하는 저항변화 복합재료 및 이를 사용한 기억소자
The present invention refers to the resistance voltage change using the same memory device relates to the material, a composite dielectric material more particularly new configuration change in the resistance of the metal resistance-varying type using the same are disclosed. In the flash memory and the memory device reduces current electronic electricity most DRAM flow tides. One of flash memory includes an DRAM similarity with process, through a simple structure relatively easy and nonvolatile memory known as widely used as storage medium fine line width characterized etc.. However sub-a 30 nm increased difficulty and after deterioration and electrical properties, and it is a limit power consumption due to the high operating voltage viviparity, door number the slower operating speed as measured disclosed. The door number point element outputs the new memory non-volatile, low power, highly integrated, fast operation speed change ram (ReRAM) resistance or stability of the current extended etc.. The ReRAM sweep bias (bias sweep) using a memory read/write properties of a material resistance change is sensed as on/off, resistance change behavior (resistance switching behavior) according to unipolar switching (unipolar switching) and bipolar switching (bipolar switching) Chapters. For each modification behavior found generally but not clear the mechanism for resolving oxide dielectric breakdown (dielectric breakdown) unipolar switching is achieved due to the creation of a conductive path (conducting path) made known in that, in the case of bipolar switching behavior of oxygen in public (oxygen vacancy) n oxide due to Schottky barrier height change (schottky barrier height), etc. described essentially formed on oxygen deficient or (oxygen deficient phase). Further resistance-varying type diffusion (memristor) the possibility of use as a nonvolatile storage device and [su carrying on shoulder in the spotlight disclosed. [su[su] carrying on shoulder it shakes off memory (memory) state of the storage element (resistor) to register a previous words that both said substrate. Also when the direction of the current through immediately before [su[su] carrying on shoulder it shakes off power supply disconnected since it is domestic to produce the recovered amount memory state characterized by disclosed. [su[su] carrying on shoulder it shakes off register, capacitor and inductor as well as the electrical circuit of one of fundamental constituent of which have been confirmed, which is responsible for performing various [su[su] carrying on shoulder it shakes off generally register play a role in a neutral register similar but, unlike register according to modify a resistance in a direction and magnitude of the applied voltage can be, even if the web document with the resistance of the previous memory level shifter. Thus, using the same [su[su] carrying on shoulder it shakes off Terabit (terabit) memory, a circuit configuration enables a new logic circuit elements such as acetic acid and citric acid deficiency by neural network depends on the number of general outline and element, nanotechnology based on next generation memory field into the same. Various layers of the active layer of the existing method but [su carrying on shoulder and configured with a vacuum deposition method standpoint to applying the dielectric part. The present invention refers to new class number point in order to solve the aforementioned prior art door provided change in the resistance of composite material and a number of different using the same under public affairs pin is used. For the present invention is characterized by said resistance varying composite material, nose mote brush transition metal oxide nano particles dispersed in an insulating matrix chemically coupled characterized. The present invention refers to utilizing conventional transition metal oxide inside the nose mote brush resistance varying material as being dispersed in a matrix behind the neurotransmitter combining new resistance change composite material number under public affairs substrate. The, transition metal oxide is ZnO, TiO2 , Fe2 O3 And at least one material is selected from NiO and, matrix PVP, PMMA, selected from at least one material is preferably a PS and PVK. The nose mote brush is chemically bonded transition metal oxide nanoparticles through transition of metal oxide nano particles combined with structure formed on a surface of resin composition comprising nose mote brush Fresnels disclosed. A change in the resistance of the present invention constructed as a switching element among the operation according to the resistance change that composite material applied voltage exhibits characteristics of analog type. In addition, exhibits a unique characteristic of reduced hysteresis produces proportional increases voltage becomes higher. The, nose mote brush included in these properties in order to obtain the composite material is chemically bonded transition metal oxide nanoparticles ratio 0. 15 - 0. 20% by weight preferably range. Diffusion by the present invention, lower electrode; said lower electrode is formed on, combined with transition metal oxide nano particles dispersed in a matrix nose mote brush insulating composite material that an active layer; and said upper electrodes consists of the active layer. The, transition metal oxide is ZnO, TiO2 , Fe2 O3 And at least one material is selected from NiO and, matrix PVP, PMMA, selected from at least one material is preferably a PS and PVK. The nose mote brush is chemically bonded transition metal oxide nanoparticles through transition of metal oxide nano particles combined with structure formed on a surface of resin composition comprising nose mote brush Fresnels disclosed. This diffusion resistance change layer active layer serving as a resistance-varying type memory device may be, in particular a change in the resistance component of the active layer serving as the gate be a nonvolatile memory element. In order active part with a nose mote brush these properties is chemically bonded transition metal oxide nanoparticles ratio 0. 15 - 0. 20% by weight preferably range. In addition, active layer has a thickness of not more than 200 nm are pleasant, if active layer has a thickness of 200 nm is less than the active layer can be digital as to operate are disclosed. The such resistance-varying type of memory device manufacturing method, the steps of providing a substrate; said substrate surface to form a lower electrode; forming said resistance form above the lower electrode; and forming an upper electrode being change layer said resistance, said resistance by forming the form above, transition metal oxide nanoparticles chemically coupling nose mote brush; said nose mote brush alkali matrix material dissolving solvent combined with transition metal oxide nanoparticles; said nose mote brush combined with transition metal oxide nanoparticles and applying said matrix material being dissolved in the solution of the lower electrode; and said steps characterized in that it consists in vaporizing the solvent. The, transition metal oxide nanoparticles nose mote brush adhesive composition comprises a hydroxyl group has been chemically coupling surface of metal oxide nano particles is formed, preferably having a terminal is attached to the nose mote brush carried out. A step for forming a transition metal oxide nanoparticles surface adhesive composition comprises a hydroxyl (- OH) on the surface of the transitional metal oxide nanoparticles generated behind hydroxy group can be carried out using succinic anhydride or glycol aldehyde route. In addition, transition metal oxide nanoparticles having a terminal formed on a surface of attaching process is preferably carried out through treatment with EDC/NHS nose mote brush. The transition metal oxide is ZnO, TiO2 , Fe2 O3 And at least one material is selected from NiO and, matrix PVP, PMMA, selected from at least one material is preferably a PS and PVK. In another aspect of the present invention while having the simulation element by, [su carrying on shoulder (memristor) elements configured as (neuromorphic device) while having the simulation element, said non-volatile storage element in the range of 0.1 [su carrying on shoulder element characterized. The remaining component in the embodiment of non-volatile storage element while having the simulation for a permanent storage use other techniques can be applied without a specific number external grudge number description dispensed to each other. The present invention refers to constructed as described above, by combining transition metal oxide dispersed in a matrix behind nose mote brush, analog characteristic has a reverse proportional hysteresis behavior of overlapped with a unique composite material using a reduced number under public affairs indicating that a new resistance change can be equal to or less than. Soda lime glass substrate of the present invention using the diffusion resistance-varying type characteristics and/or nonvolatile characteristics under public affairs number storage element can be equal to or less than. [Su carrying on shoulder while having the non-volatile storage element of the present invention corresponding to the simulation can be further including as equal to or less than. Figure 1 shows a mimetic indicating memory device structure according to an embodiment of the present invention also are disclosed. According to Figure 4 of the present invention in the embodiment 2 also exhibits a ZnO nanoparticles and nose mote brush that is chemically bonded to the process. In the embodiment of Figure 5 the measured I a-V curve the metal are disclosed. Figure 6 measured I a-V curve comparing the metal embodiments are disclosed. The present invention according to in the embodiment detailed with reference to the attached drawing as follows. Figure 1 shows a mimetic indicating memory device structure according to an embodiment of the present invention also are disclosed. The storage element in the embodiment substrate (100) a lower electrode (200) and the active layer (300) and an upper electrode (400) sequentially stacked structure and, encoded number tank are sequentially formed on them. The, active layer (300) is a transition metal oxide nanoparticles as nano-trap which stores electrical charge combining insulating material dispersed in a matrix neurotransmitter nose mote brush consists of changing the composite material. In the embodiment Following the first method, the high pressure liquid coolant feed material was an active layer number. Selecting ZnO nanoparticles which stores electrical charge nano as traps, ZnO nanoparticles is a nose mote brush that is chemically bonded to him. Compatibilized 14 nm particles with a size ZnO nanoparticles provided the deflection, the nose mote brush adrenal cortex hormone secreted in response to various stresses ( ) And, in the embodiment was used in a commercially available nose mote brush. ZnO nanoparticles chemically nose mote brush for coupling, such as a hydroxyl group (- OH) on the surface of the ZnO nanoparticles also 2 first order to generate H ZnO nanoparticles2 O2 Surface-treated substrate. Such as a gel layer 3, carboxyl (- COOH) on the surface of the ZnO nanoparticles using succinic anhydride (succinic anhydride) in reacting to produce other. The, using route can be carboxyl to produce aldehyde (glutaldehyde) glycol. Finally also 4 such as, EDC/NHS ZnO nanoparticles by treatment with an adhesive tape having a terminal EDC (1 a-ethyl-a 3 - (3 dimethylaminopropyl) carbodiimide) allocated to store and nose mote brush attached by replacing the same, nose mote brush chemically coupled ZnO nanoparticles and copiers. The procedure combined with ZnO nanoparticles with nose mote brush prepared by the number THF solvent (tetrahydrofuran) was dissolved PVP. The nose mote brush for connecting coupling number combined with ZnO nanoparticles and PVP (1, 6 a-Bis(trichlorosilyl) hexane) powder has a transparent conductive layer, the PVP solution 2. 0% by weight ZnO nanoparticles combined with nose mote brush and 0. 20% by weight are disclosed. And the following order number was also 1 change in the resistance of-type storage element structure such as high pressure liquid coolant. First 0. 7 mm thickness glass substrate (100) along an upper surface (200) as a 200 nm thickness ITO coating, coated ITO nose mote brush surface combined with ZnO nanoparticles and PVP dissolved after spin-coating solvent is evaporated with 300 nm thickness of active layer (300) came into. Finally active layer (300) vapor deposition process on the surface of the upper electrode layer thickness that is at least ten evaporation Al 150-a 200 nm (400) was used. Said storage element prepared by the number to an electric properties were measured progress. The, comparison example nose mote brush ZnO nanoparticles not combine the same procedure number storage element prepared by the number was high pressure liquid coolant. In the embodiment of Figure 5 shows a measured I a-V curve and therefore the metal, the metal compared to the measured I a-V curve 6 embodiments are disclosed. As shown, 2 is the resistance of memory elements are all applied voltage gradually changes the resistance change that-type storage element exhibits the properties of analog type can be confirmed. The embodiments of resistance-varying type diffusion (hysterisis) is overlapped with the hysteresis comparing male general reduced due to which noise is very large while at the same time exhibiting all the voltages can be confirmed. The ejected in the embodiment produces proportional increase of the voltage change in the resistance of-type storage element exhibiting a hysteresis than keeping hysteresis comparing specific embodiments of decreasing while noise has almost no, as in the embodiment of the non-volatile memory elements being a [su carrying on shoulder and side surfaces of such tendency may be by a goniophotometer. This hysteresis characteristic is exposed functional groups known in response to stimulate human hormone-stress with work nose mote brush similar disclosed. The storage element in the embodiment multi-EEPROM device with [su carrying on shoulder is applied, using only two electrodes 2 2 terminal (2 a-terminal) in a very simple arrangement of [su carrying on shoulder element is under or over. In the embodiment according to the MLS [su[su] carrying on shoulder while having the simulation element comprising a non-volatile memory element of (neuromorphic device) can be applied as a [su carrying on shoulder, while having the simulation for the remaining component in the embodiment of non-volatile storage element in respect of the use of other techniques can be applied without a specific number external grudge number description dispensed to each other. Herein as shown with prior, the hormone acting as a storage element in the embodiment indicated hysteresis characteristic pertains with work and similar, while having the characteristic by presenting these properties even when simulating while having the simulation element or a built for hereinafter can be achieved. A more preferred embodiment the present invention through described but, in the embodiment of the present invention is to avoid a technical idea illustratively described above which, within a range that the technical idea of the present invention various changes from a heavy person with skill in the art sacrificial vertical if understand it will rain. In the embodiment of the present invention scope of protection the claim has a plane orientation must be interpreted by a rather than in a natural, technical idea of the present invention also in a range equal to the range of all rights will be interpreted. 100: substrate 200: lower electrode 300: active layer 400: upper electrode The present invention refers to change in the resistance of composite material relates to new class, nose mote brush is chemically bonded transition metal oxide nano particles dispersed in an insulating matrix characterized. In addition the present invention by diffusion, lower electrode; said lower electrode is formed on, combined with transition metal oxide nano particles dispersed in a matrix nose mote brush insulating composite material that an active layer; and said upper electrodes consists of the active layer. The present invention refers to, transition metal oxide dispersed in a matrix behind nose mote brush by combining, analog characteristic has a reverse proportional hysteresis behavior of overlapped with the unique composite material using a reduced number under public affairs indicating that a new resistance change can be equal to or less than. In addition soda lime glass substrate of the present invention using the diffusion resistance-varying type characteristics and/or nonvolatile characteristics under public affairs number storage element can be equal to or less than. [Su carrying on shoulder while having the non-volatile storage element of the present invention corresponding to the simulation can be further including as equal to or less than. Nose mote brush is chemically bonded transition metal oxide nano particles dispersed in an insulating matrix, the greater the voltage becomes higher hysteresis characteristics produces proportional characterized by decreasing the resistance change that composite material. According to Claim 1, said transition metal oxides ZnO, TiO2 , Fe2 O3 A NiO and selected from at least one material is characterized in that the resistance change that composite material. According to Claim 1, said matrix is PVP, PMMA, PS and PVK a selected from at least one material is characterized in that the resistance change that composite material. According to Claim 1, said nose mote brush is chemically bonded transition metal oxide nano particles formed on a surface of said transition metal oxide nanoparticles characterized through nose mote brush resin composition comprising combined with the resistance change that composite material. According to Claim 1, a change in the resistance switching element among the analog type change in the resistance of said resistance change composite material is characterized in that the resistance change that composite material properties. Back number According to Claim 1, said nose mote brush is chemically bonded transition metal oxide nanoparticles ratio 0. 15 - 20% by weight range the resistance change that composite material characterized. Lower electrode; is formed on said lower electrode, transition metal oxide nano particles dispersed in a matrix chemically coupled nose mote brush insulating composite material that an active layer; and a top electrode that is formed on which said active layer, said active layer voltage becomes higher the greater the hysteresis characteristics and a memory element which produces proportional reducing characterized. According to Claim 8, said transition metal oxides ZnO, TiO2 , Fe2 O3 Characterized in that at least one material is selected from NiO and a memory element which. According to Claim 8, said matrix is PVP, PMMA, and PVK PS selected from at least one material is characterized in that a memory element which. According to Claim 8, said nose mote brush is chemically bonded transition metal oxide nano particles formed on a surface of said transition metal oxide nanoparticles combined with resin composition comprising a memory element which characterized through nose mote brush. According to Claim 8, said side surfaces of said resistance-varying type memory element serving as a resistance change layer active layer characterized by a memory element which. According to Claim 8, characterized in that the side surfaces of said non-volatile memory element and a memory element which. According to Claim 8, said active part with a nose mote brush is chemically bonded transition metal oxide nanoparticles ratio 0. 15 - 20% by weight range and a memory element which characterized. According to Claim 14, characterized in that said active layer has a thickness of 200 nm or more and a memory element which. Forming a lower electrode; said active layer of the lower electrode; and forming said active layer being an upper electrode, said active layer by forming, hydroxyl group (- OH) on the surface of the transition metal oxide nanoparticles generated using transition metal oxide nanoparticles surface behind said adhesive composition comprises a hydroxyl aldehyde route using succinic anhydride or glycol region is formed, a terminal nose mote brush obtained, transition metal oxide nanoparticles chemically coupling nose mote brush; said nose mote brush alkali matrix material dissolving solvent combined with transition metal oxide nanoparticles; said nose mote brush combined with transition metal oxide nanoparticles and applying said matrix material being dissolved in the solution of the lower electrode; and said vaporizing the solvent comprising the step of manufacturing method characterized in that it consists of memory device. Back number Back number According to Claim 16, said transition metal oxide nanoparticles having a terminal formed on a surface of nose mote brush plate is attached to the EDC/NHS treatment process carried out of memory device manufacturing method characterized. According to Claim 16, said transition metal oxides ZnO, TiO2 , Fe2 O3 NiO and selected from at least one material is of a memory element which characterized in that the manufacturing method. According to Claim 16, said PVP matrix, PMMA, and PVK PS selected from at least one material is of a memory element which characterized in that the manufacturing method. [Su carrying on shoulder (memristor) elements while having the simulation element configured as (neuromorphic device), non-volatile storage element in the range of 0.1 [su carrying on shoulder element claim 13 characterized while having the simulation element.