HETERO RING COMPOUND, AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING SAME
The specification is heterocyclic compound and including an electron transporting layer are disclosed. The means by which electrical energy using organic material generally organic light emitting phenomenon to light installed on the pipe body. Organic light emitting phenomena between an anode and a cathode and a solvent including conventional organic light emitting devices has a meshed structure. The organic compound layer is formed of organic light-emitting material in order to enhance stability and different multilayered structure of which is in many cases, e.g. hole injection layer, hole transport layer, light emitting layer, metal-containing fullerene, can be made with an or the like. Such an organic light-emitting device structure a voltage between two electrodes on the liquid crystal in the solution with holes, and the process is organic electronics is cathode, electrons are injected and when meeting the OLEDs (exciton) is formed, is equal to 1000 ppm when a light again falls into the ground state. Said development of novel materials such as organic light emitting continuously etc. required. The specification is heterocyclic compound and organic light emitting number including under public affairs substrate. The heterocyclic compound represented by formula 1 according to one embodiment state to specification number under public affairs substrate. [Formula 1] In said formula 1, R1 to R5 and R2 represent same or different hereinafter, are independently hydrogen; deuterium; nitrile group; nitro; hydroxy; carbonyl group; ester; for imide; amide group; a substituted or unsubstituted fluoroalkyl group; a substituted or unsubstituted cycloalkyl; substituted or a substituted or unsubstituted alkoxy group; a substituted or unsubstituted biting jade time; a substituted or unsubstituted alkyl mote jade time; substituted or nonsubstituted substituted biting mote jade time; a substituted or unsubstituted alkyl alcoholic beverage width time; substituted or nonsubstituted substituted biting alcoholic beverage width time; substituted or nonsubstituted substituted between the light-emitting; a substituted or unsubstituted silyl group; a substituted or unsubstituted boron to; a substituted or unsubstituted amine; a substituted or unsubstituted gun spin it will be biting; substituted or unsubstituted phosphine oxide; substituted or nonsubstituted a substituted aryl group; or a substituted or non-substituted alkoxy group, L1 is coupled directly; a substituted or unsubstituted it will be biting, [leyn; or substituted or unsubstituted heteroatoms and it will be biting, [leyn strangeness, Ar1 to amine substituted or unsubstituted; substituted or unsubstituted phosphine oxide; substituted or nonsubstituted a substituted aryl group; or a substituted or non-substituted alkoxy group, R1 r2 and positive numbers of 1 to 5 each, R3 is integer number of 1 to 4, R4 is 1 or 2 and, R5 is integer number of 1 to 3, R1 to r5 is separately in a plurality if, within a plurality of brackets on are same or hereinafter disclosed. In addition, the specification according to one embodiment state, number 1 electrode; having oppositely to said number 1 number 2 electrode; and said number 1 and number 2 electrode 1 with organic light emitting device including at least one layer of a solvent, said organic layer 1 layer or more of the heterocyclic compounds represented by said formula 1 will including organic light emitting number under public affairs substrate. The specification according to one embodiment the heterocyclic compound can be used as the material al of organic light-emitting state, an opening is formed in a light emitting element using the organic, low driving voltage and/or life characteristics of one of the first disclosed. Figure 1 shows a specification according to one embodiment invention organic light emitting devices (10) timing a are disclosed. Figure 2 shows a specification of another embodiment according to the invention organic light emitting devices (11) timing a are disclosed. Hereinafter, the specification more detailed as follows. The heterocyclic compound is represented by said formula 1 specification number under public affairs substrate. In the specification, that "comprising" when any portion of any components, particularly the opposite substrate under the outside number but without other components further can include other components which means that the other. In the specification, that the "on" position when any member other members, as well as any other elements member between the two members when joined to another member to if there is a comprises a unit. The specification substituents are described below in example but, limited to are not correct. The term "substituted" that the compounds other hydrogen atom coupled carbon atoms substituted International dispersing medium, substituted hydrogen atom locations position i.e., substituted substituted if possible location does not define, when 2 or more substituted, 2 or more substituents may be the same or different each other. The specification that the term "substituted or unsubstituted" in deuterium; for halogen; nitrile group; nitro; for imide; amide; carbonyl group; ester; hydroxy; a substituted or unsubstituted fluoroalkyl group; a substituted or unsubstituted cycloalkyl; substituted or a substituted or unsubstituted alkoxy group; a substituted or unsubstituted biting jade time; a substituted or unsubstituted alkyl mote jade time; substituted or nonsubstituted substituted biting mote jade time; a substituted or unsubstituted alkyl alcoholic beverage width time; substituted or nonsubstituted substituted biting alcoholic beverage width time; substituted or nonsubstituted substituted between the light-emitting; a substituted or unsubstituted silyl group; a substituted or unsubstituted boron to; a substituted or unsubstituted amine; a substituted or unsubstituted gun spin it will be biting; substituted or unsubstituted phosphine oxide; substituted or nonsubstituted a substituted aryl group; and a 1 or 2 or more selected from the group consisting of a substituted or unsubstituted substituted with reel ring crossroad inductive lost 2 or more substituents or substituted connected said example substituted during, or any substituted airway does not have a means other. For example, "2 or more substituents substituted connected" be bar code input mode using phenyl group. I.e., it will be an allyl-may be phenyl, substituted phenyl of 2 is connected can be interpreted. In the specification, Other substituted or coupling part for big. In the specification, the halogen fluorine, chlorine, bromine or iodine can be. In the specification, particularly but not limited to carbon number of imide, 1 to 30 carbon atoms preferably disclosed. Specifically to the compounds of the following structure such as but, limited to are not correct. In the specification, the amide nitrogen of amide hydrogen, 1 to 30 carbon atoms of straight, branched or dendrimeric polymer backbone chain of 6 to 30 carbon atoms can be substituted with allyl phenyl or benzyl ring. Specifically, compounds represented by formula but, limited to are not correct. The specification number but not limited particularly in carbonyl functional carbon, 1 to 30 carbon atoms preferably disclosed. Specifically to the compounds of the following structure such as but, limited to are not correct. In the specification, a process for 1 to 25 carbon atoms the ester oxygen of straight, branched or dendrimeric polymer backbone chain of 6 to 30 carbon atoms can be substituted with allyl phenyl or benzyl ring. Specifically, compounds represented by formula but, limited to are not correct. In the specification, and said the [sway[sway] will be straight or branched alkyl groups, particularly preferably 1 to 30 carbon but not limited in number. Specific examples include methyl, ethyl, propyl, n - propyl, isopropyl, butyl, n - butyl, isobutyl, tert - butyl, sec - butyl, 1 - methyl - butyl, 1 - ethyl - butyl, neopentyl, n - neopentyl, cyclopentyl isocyanate, neopentyl, tert - neopentyl, hexyl, n - hexyl, 1 - methyl neopentyl, cyclopentyl methyl 2 -, 4 - methyl - 2 - neopentyl, 3, 3 - dimethylbutyl, 2 - ethylbutyl, [heyp[heyp], n - [heyp[heyp], 1 - methyl hexyl, pen [thil methyl cycloalkyl, cyclo [heyk thread methyl, octyl, n - octyl, tert - octyl, 1 - methyl [heyp[heyp], 2 - ethylhexyl, 2 - propyl neopentyl, n - nonyl, 2, 2 - dimethyl [heyp[heyp], 1 - ethyl - propyl, 1, 1 - dimethyl - propyl, hexyl isocyanate, 2 - methyl neopentyl, cyclohexyl 4 - methyl, 5 - methyl hexyl is provided to be used, the pieces are not correct. In the specification, particularly but not limited to cycloalkyl, preferably 3 to 30 carbon atoms and, specifically cyclopropyl, cyclobutyl, cyclopentyl cycloalkyl, of sodium 3 - methyl, 2, 3 - dimethyl of sodium, cyclohexyl, methyl 3 - hour claw [heyk thread, methyl 4 - hour claw [heyk thread, 2, 3 - dimethyl hour claw [heyk thread, 3, 4, 5 - methyl hour claw [heyk thread tree, 4 a-tert - butyl hour claw [heyk thread, cyclo [heyp[heyp], cyclo-octyl is provided to be used, limited to are not correct. In the specification, said alkoxy group and at least one linear, branched or ring the [sway[sway] will be be. Alkoxy carbon number not limited specially but, preferably in 1 to 30 carbon atoms. Specifically, methoxy, ethoxy, n - propoxy, isopropoxy, i - propyl oxy, n - butoxy, isobutoxy, tert - butoxy, sec - butoxy, n - pen [thil jade city, neopentylglycol pen [thil jade city, ISO pen [thil jade city, Serial n -, 3, 3 - dimethyl butyl jade city, 2 - ethyl butyl jade city, n - jade [thil jade city, n - nonyloxy, n - it will be burnt oxy, benzyloxy, but it cuts the qualitative jade city like p - methyl, limited to are not correct. In the specification, the amine - NH2 ; Alkyl hydroxybutyrolactone; N - alkyl amine it will be biting; amine it will be biting; N - will be biting and hetero amine it will be biting; and new N - alkyl hetero amine it will be bitingbiting amine crossroad can be selected from the group consisting, particularly but not limited to carbon number, preferably in 1 to 30. Specific examples hydroxybutyrolactone methyl amine, dimethyl hydroxybutyrolactone, ethyl hydroxybutyrolactone, d ethyl amine, phenyl hydroxybutyrolactone, naphthylamine to, bi-phenyl amine, do not sprout three neel amine, 9 - methyl - do not sprout three neel amine, d phenyl amine, phenyl N - me [phu amine, d [thol reel amine, N - phenyl [thol reel amine, phenyl amine tree, N - phenyl at all phenyl amine; N - phenyl me [phu amine; phenyl or [phu[phu] amine-N -; N - me [phu[phu] base five [ley[ley] Neel amine; N - phenyl lung difficulty [thu[thu] Neel amine; phenyl lung difficulty [thu[thu] Neel amine-N -; N - phenyl [phul[phul] Base five [ley[ley] Neel amine; N - phenyl phenyl amine; N - lung difficulty [thu[thu] Neel [phul[phul] base five [ley[ley] Neel amine; phenyl [phul[phul] base five [ley[ley] Neel amine-N - is provided to be used, limited to are not correct. In the specification, the alkyl amine group substituted trianthracene the biting amine it crawls N N - alkyl amine and big. In the specification, it will be biting and hetero the biting amine it crawls N N - aryl and heterocyclic amine to amine group substituted trianthracene big. In the specification, and to the big N N - alkyl hetero the biting amine it crawls biting amine giga substituted amine group to alkyl amine. In the specification, alkyl hydroxybutyrolactone, N - alkyl amine it will be biting, alkyl mote jade time, alcoholic beverage width time alkyl, the alkyl group of the aforementioned alkyl example hetero amine it will be biting N - alkyl such as disclosed. Specifically mote jade timemote jade time alkyl include methyl, ethyl mote jade time, tert - butyl mote jade time, [heyk thread mote jade time, jade [thil mote jade time at sea, include alkyl alcoholic beverage width time melter chamber, ethyl alcoholic beverage width time, profile alcoholic beverage width time, butyl alcoholic beverage width time is provided to be used, the pieces are not correct. In the specification, and said neel the [khey which it will know it crawls straight or branched the [sway[sway] will be, particularly but not limited to carbon number, preferably 2 to 30 in. Specific examples are vinyl, 1 - propenyl, pro-phenyl isocyanate, 1 - butenyl, 2 - butenyl, 3 - butenyl, 1 - neel pen reel, neel pen reel 2 -, 3 - neel pen reel, 3 - methyl - 1 - butenyl, 1, 3 - buta to d neel, allyl, 1 - phenyl vinyl - 1 - yl, 2 - phenyl vinyl - 1 - yl, 2, 2 - diphenylvinyl - 1 - yl, 2 - phenyl - 2 - (naphthyl - 1 - yl) vinyl - 1 - yl, 2, 2 - bis (diphenyl - 1 - yl) vinyl - 1 - yl, hemp cloth neel steel, is provided to be used [su mote [ley neel, limited to are not correct. In the specification, methyl thread reelthread reel specifically tree, tree [thil it will be recorded, the d methyl it will be recorded t - butyl, vinyl the d methyl it will be recorded, profile the d methyl it will be recorded, tree phenyl thread reel, the d phenyl it will be recorded, phenyl silyl group is provided to be used, the pieces are not correct. In the specification, the boron - BR100 R101 Can have a, said R100 And R101 Assigns the same and or different hereinafter, are independently hydrogen; deuterium; halogen; nitrile group; or a substituted or unsubstituted cycloalkyl group of 3 to 30 only annularity multi annularity C12; 1 to 30 C12 of straight or branched chain substituted or unsubstituted alkyl group; or a substituted or unsubstituted aryl group of 6 to 30 only annularity multi annularity C12; and a substituted or unsubstituted hetero with allyl 2 to 30 selected from the group consisting of C12 or multi annularity only annularity can be. In the specification, phosphine oxide specifically d phenyl gun spin oxide, the resulting [phu gun spin oxide is provided to be used, the pieces are not correct. In the specification, particularly but not limited to aryl, preferably 6 to 30 carbon atoms which, said multi annularity one or only annularity be aryl. It is an allyl said carbon number but not limited particularly when trianthracene only annularity, 6 to 30 carbon atoms preferably disclosed. Specifically only annularity aryl group include phenyl, phenyl-, but like phenyl, limited to are not correct. It is an allyl carbon number but not limited particularly when said trianthracene electrically. 10 to 30 carbon atoms preferably disclosed. Specifically polycyclic aryl group include me [phu, do not sprout three Neel, lung difficulty [thu reel, tree phenyl, fine [ley neel, lung day [ley[ley] Neel, vinyl [ley neel, three neel cryo, but like the flue five [ley neel, limited to are not correct. In the specification, process for preparation thereof said neel five [ley it crawls can be substituted, can be joined together to form adjacent ring. Process for preparation thereof when said five [ley neel gigas substituted, , , , , and Can be like. Only, limited to are not correct. In the specification, corresponding to "adjacent" substituents substituted atoms and directly connected atoms substituted substituent, close best conformation corresponding substituent substituted, substituents substituted atoms means value in other substituents can be substituted. For example, benzene ring substituted in ortho (ortho) position substituted 2 of the same carbon aliphatic ring substituents of substituted 2 "adjacent" can be interpreted into each other. In the specification, biting jade time, biting mote jade time, biting alcoholic beverage width time, N - alkyl amine it will be biting, N - aryl such as example of the aforementioned allylgun spin it will be bitingwill be biting and hetero amine it will be biting and 2000. Specifically biting jade time include lung stipendiary time, toe reel jade time p -, m - toe reel jade time, 3, 5 - dimethyl - lung stipendiary time, 2, 4, 6 - tri methyl lung stipendiary time, lung stipendiary time p a-tert - butyl, 3 - bi-phenyl jade time, 4 - bi-phenyl jade time, me [phu[phu] jade time 1 -, 2 - me [phu[phu] jade time, 4 - methyl - 1 - me [phu[phu] jade time, 5 - methyl - 2 - me [phu[phu] jade time, inside [thu[thu] reel jade time 1 -, 2 - inside [thu[thu] reel jade time, 9 - inside [thu[thu] reel jade time, lung difficulty [thu[thu] reel jade time 1 -, 3 - lung difficulty [thu[thu] reel jade time, 9 - lung difficulty [thu[thu] reel jade time at sea, mote jade timebiting mote jade time include phenyl, 2 - methyl phenyl mote jade time, such as 4 a-tert - butyl phenyl mote jade time which, alcoholic beverage width timebiting alcoholic beverage width time include benzene, p - toluene alcoholic beverage width time is provided to be used, the pieces are not correct. In the specification, examples substituted or nonsubstituted substituted mono amine it will be biting amine it will be biting, diaryl reel amine substituted or unsubstituted, or a substituted or unsubstituted triazoles reel amine giga 2000. Only annularity it will be an allylamine it will be biting and during said aryl, polycyclic it will be an allyl be. 2 or more including only annularity the biting amine it crawls trianthracene said aryl, polycyclic aryl, polycyclic aryl group or only annularity group can be simultaneously. For example, the aryl of said aforementioned allylamine it will be biting example can be selected. In the specification, is not hetero aryl carbon atom, including 1 or more hetero atoms provided, specifically said heteroatoms O, N, S and Se atoms containing at least one selected from the group consisting 1 or similar can be. Carbon number not limited specially but, preferably 2 to 30 carbon atoms which, said hetero aryl or multi annularity one be only annularity. For hetero ring include thiophene, [phyu[phyu] [la_nil[la_nil], to pyrrole, imidazole reel, it will become sleepy thiazole, oxazole it will become sleepy, oxadiazole reel, [til[til] pyridazinone, bi-blood [til, pyrimido [til[til], neel triazole, triazole it will become sleepy, arc [til[til], will be and it will keep pyridazinone, pyrazole neel, [khwi[khwi] glow Neel, quinacridone-based neel it will doze, the [khwi stipend neel it will live, it will keep phthalides, pyrido pyrimido [til[til], pyrido pyrazole neel, pyrazole roh neel antagonist activity, ISO [khwi[khwi] glow Neel, indole reel, cover it will become sleepy, the jade company it will become sleepy benzimidazole, benzthiazole already will be and it will become sleepy, benzo the mote oh it will become sleepy, benzo car it will become sleepy, benzo mote five pen, dibenzo mote five pen, benzo [phyu[phyu] [la_nil[la_nil], lung difficulty [ssu raleigh neel (phenanthroline), thia it will become sleepy, ISO the jade company it will become sleepy, oxadiazole reel, d oh it will become sleepy thiazole, benzo the mote oh it will become sleepy, lung looking old oh it will keep and dibenzo [phyu[phyu] [la_nil[la_nil] is provided to be used, the pieces are not correct. In the specification, a substituted or unsubstituted heterocyclic amine it will be biting mono hetero amine it will be biting examples, a d hetero amine it will be biting a substituted or unsubstituted, or a substituted or unsubstituted hetero biting amine giga tree 2000. Said heteroaryl group including 2 or more hetero trianthracene hetero the biting amine it crawls only annularity, polycyclic heteroaryl group, heterocyclic group or polycyclic heteroaryl group only annularity can be simultaneously. For example, said hetero aryl can be selected from a variety of the aforementioned hetero allyl example during amine it will be biting. In the specification, such as example of hetero allyl example comprises the above-described heterocyclic alkyl hetero amine it will be bitingwill be biting and hetero amine it will be biting and N - N - allyl 2000. In the specification, it will be biting and [leyn it crawls 2 i.e. aryl phosphate binding site that are formed in the two big. Each of the inside and the outside are formed in the number 2 and comprises the above-described allylunder the outside description can be applied. In the specification, it will be biting and [leyn it crawls hetero aryl phosphate binding site that are formed in the two big 2 i.e. hetero. Each of the inside and the outside are formed in the number 2 and comprises the above-described heterocyclic allylunder the outside description can be applied. The specification according to one embodiment state, represented by formula 2 is displayed either said formula 1 to 5. [Formula 2] [Formula 3] [Formula 4] [Formula 5] In said formula 2 to 5, R1 to R5, r1 Ar1 r5, L1 and to the definition of the formula 1 and are the same. The specification according to one embodiment state, JPO said formula 1 represented by formula 6. [Formula 6] In said formula 6, L1 and Ar1 are the same and the definition of the formula 1. The specification according to one embodiment state, represented by said formula 1 formula 7 to 10 is displayed either. [Formula 7] [Formula 8] [Formula 9] [Formula 10] In said formula 7 to 10, L1 and Ar1 are the same and the definition of the formula 1. The specification according to one embodiment state, in said formula 1, L1 is coupled directly; it will be biting, [leyn; it will be biting, [leyn or heteroaryl groups among others. The specification according to one embodiment state, in said formula 1, L1 is coupled directly; to a substituted or unsubstituted phenylene; substituted or unsubstituted back phenyl reel [leyn[leyn]; substituted or nonsubstituted substituted me [phu[phu]; substituted or nonsubstituted substituted phenyl [leyn[leyn]; substituted or unsubstituted phenyl [leyn quarter; substituted or nonsubstituted substituted do not sprout three neel [leyn; a substituted or unsubstituted neel five [ley[ley] [leyn[leyn] and process for preparation thereof; a substituted or unsubstituted lung difficulty [thu[thu] Neel [leyn[leyn]; fine [ley[ley] Neel [leyn[leyn] substituted or unsubstituted; substituted or unsubstituted phenyl [ley neel [leyn tree; a substituted or unsubstituted it will become sleepy, [leyn[leyn] cover among others. The specification according to one embodiment state, in said formula 1, L1 is coupled directly; for phenylene ;-phenyl reel [leyn[leyn]; me [phu[phu]; phenyl [leyn[leyn]; quarter phenyl [leyn; do not sprout three neel [leyn; the flue neel five [ley[ley] [leyn[leyn]; lung difficulty [thu[thu] Neel [leyn[leyn]; fine [ley[ley] Neel [leyn[leyn]; tree phenyl [ley neel [leyn; or cover it will become sleepy, [leyn[leyn] among others. The specification according to one embodiment state, in said formula 1, L1 is a structure can be a one, a textile fabric are not correct. The specification according to one embodiment state, in said formula 1, L1 is coupled directly; for phenylene; do not sprout three neel [leyn; or cover it will become sleepy, [leyn[leyn] among others. The specification according to one embodiment state, in said formula 1, diaryl substituted or unsubstituted Ar1 reel amine; a substituted or unsubstituted d hetero amine it will be biting; substituted or unsubstituted silyl group; substituted or unsubstituted phosphine oxide; substituted or nonsubstituted a substituted aryl group; and substituted or unsubstituted heteroatoms selected from the group consisting with allyl. The specification according to said formula 1 state in one embodiment, Ar1 is substituted or unsubstituted phenyl; substituted or unsubstituted back phenyl; substituted or nonsubstituted substituted lung difficulty [thu neel; substituted or nonsubstituted substituted me [phu; a substituted or unsubstituted phenyl; a substituted or unsubstituted five [ley neel and process for preparation thereof; a substituted or unsubstituted do not sprout three Neel; a substituted or unsubstituted three neel cryo; substituted or unsubstituted phenyl quarter; a substituted or unsubstituted [su[su] endurance ratio [phul[phul] base five [ley[ley] Neel; substituted or unsubstituted [ley neel fine; substituted or unsubstituted tree phenyl [ley[ley] Neel; substituted or a substituted or unsubstituted vinyl [ley neel; substituted or unsubstituted triazoles neel; a substituted or unsubstituted pyrimidone [til[til]; substituted or unsubstituted [til[til] sealed by a partition; a substituted or unsubstituted [khwi[khwi] glow Neel; a substituted or unsubstituted quinacridone-based neel it will doze; a substituted or unsubstituted benzo [khwi[khwi] glow Neel; substituted or nonsubstituted substituted lung difficulty [ssu raleigh neel; the [khwi stipend neel it will live a substituted or unsubstituted; substituted or nonsubstituted substituted dibenzo [phyu[phyu] [la_nil[la_nil]; substituted or nonsubstituted substituted dibenzo mote five pen; a substituted or unsubstituted benzo my [phu[phu] toe [phyu[phyu] [la_nil[la_nil]; a substituted or unsubstituted benzo my [phu[phu] toe mote five pen; dimethyl substituted or unsubstituted gun spin oxide; a substituted or unsubstituted d phenyl gun spin oxide; a substituted or unsubstituted polioviral [phu gun spin oxide; substituted or nonsubstituted substituted benzazepines the jade company it will become sleepy; a substituted or unsubstituted benzo the mote oh it will become sleepy; substituted or nonsubstituted substituted benzazepines already will be and it will become sleepy; substituted or unsubstituted phenyl thread reel tree; a substituted or unsubstituted lung looking old oh it will keep; a substituted or unsubstituted lung stipendiary limbs neel; unsubstituted thiophene substituted or unsubstituted for; a substituted or unsubstituted d phenyl amine; a N - me [phu amine substituted or unsubstituted phenyl; substituted or nonsubstituted substituted N - phenyl at all phenyl amine; a lung difficulty [thu[thu] Neel amine N - substituted or unsubstituted phenyl; substituted or unsubstituted N - a-phenyl or [phu[phu] amine; positioning a substituted or unsubstituted phenyl amine; a substituted or unsubstituted-phenyl lung difficulty [thu[thu] Neel amine N -; a substituted or unsubstituted polioviral [phu[phu] amine; a substituted or unsubstituted N - quarter phenyl [phul[phul] base five [ley[ley] Neel amine; a substituted or unsubstituted N - phenyl [phul[phul] base five [ley[ley] Neel amine; a substituted or unsubstituted-phenyl phenyl amine N -; a-substituted or unsubstituted phenyl [phul[phul] base five [ley[ley] Neel amine N -; a [phul[phul] Base five [ley[ley] Neel amine N - substituted or unsubstituted phenyl; substituted or nonsubstituted substituted N - me [phu[phu] base five [ley[ley] Neel amine; a substituted or unsubstituted N - lung difficulty [thu[thu] Neel [phul[phul] base five [ley[ley] Neel amine; a substituted or unsubstituted transducer base five [ley[ley] Neel amine; a phenyl amine N - substituted or unsubstituted phenyl; substituted or nonsubstituted phenyl car amine it will become sleepy N - substituted; a substituted or unsubstituted-phenyl car amine it will become sleepy N -; a it cuts nephew amine it will become sleepy N - substituted or unsubstituted phenyl; substituted or unsubstituted N - a-the phenyl it cuts nephew amine it will become sleepy; substituted or unsubstituted five [ley[ley] Neel car amine it will become sleepy N - a process for preparation thereof; a substituted or unsubstituted benzo-car it will become sleepy; substituted or nonsubstituted substituted dibenzo car it will become sleepy; substituted or unsubstituted it will become sleepy cover; a substituted or unsubstituted ; A substituted or unsubstituted ; And selected from the group consisting of medication is to formula a, - - - - Through said L1 is coupled to the big area of the formula 1. [Formula a] In said formula a, X1 to X12 through and that is coupled to one of either said L1 formula 1, and on the other are same or hereinafter, R2 and R3 are independently; a substituted or unsubstituted fluoroalkyl group; substituted or nonsubstituted a substituted aryl group; or a substituted or unsubstituted aryl group may be a heterocycle, a substituted or unsubstituted ring are connected to each other adjacent groups are formed on the substrate. The specification according to one embodiment state, in said formula a, X1 to X12 through and that is coupled to one of either said L1 formula 1, remaining hydrogen are disclosed. The specification according to one embodiment state, in said formula a, X11 and X12 are each connected only annularity multi annularity hydrocarbon ring of 6 to 20 carbon atoms or a substituted or unsubstituted form. The specification according to one embodiment state, in said formula a, X11 and X12 are each connected only annularity multi annularity hydrocarbon ring of 6 to 10 carbon atoms or a substituted or unsubstituted form. The specification according to one embodiment state, in said formula a, X11 and X12 are each connected to form a substituted or unsubstituted benzene ring. The specification according to one embodiment state, in said formula a, X11 and X12 are connected to each other and form a benzene ring. The specification according to one embodiment state, in said formula 1, Ar1 is phenyl; phenyl-; lung difficulty [thu neel; me [phu; phenyl; five [ley neel and process for preparation thereof; do not sprout three Neel; three neel cryo; quarter phenyl; [su[su] endurance ratio [phul[phul] base five [ley[ley] Neel; [ley neel fine; tree phenyl [ley[ley] Neel; vinyl [ley neel; triazole neel; pyrimido [til[til]; [til[til] pyridazinone; [khwi[khwi] glow Neel; quinacridone-based neel it will doze; benzo [khwi[khwi] glow Neel; lung difficulty [ssu raleigh neel; the [khwi stipend neel it will live; dibenzo [phyu[phyu] [la_nil[la_nil]; dibenzo mote five pen; benzo my [phu[phu] toe [phyu[phyu] [la_nil[la_nil]; benzo my [phu[phu] toe mote five pen; dimethyl gun spin oxide; d phenyl gun spin oxide; the resulting [phu gun spin oxide; the jade company it will become sleepy benzimidazole; the mote oh it will become sleepy benzo; already will be and it will become sleepy benzimidazole; tree phenyl thread reel; lung looking old oh it will keep; lung stipendiary limbs neel; for thiophene; d phenyl amine; N - phenyl me [phu amine; N - phenyl at all phenyl amine; N - phenyl lung difficulty [thu[thu] Neel amine ;-N - phenyl or [phu[phu] amine; moreover phenyl amine; phenyl lung difficulty [thu[thu] Neel amine-N -; the resulting [phu[phu] amine; quarter phenyl [phul[phul] base five [ley[ley] Neel amine N -; N - phenyl [phul[phul] base five [ley[ley] Neel amine ;-N - phenyl phenyl amine; phenyl [phul[phul] base five [ley[ley] Neel amine-N -; a substituted or unsubstituted phenyl N - [phul[phul] Base five [ley[ley] Neel amine; N - me [phu[phu] base five [ley[ley] Neel amine; N - lung difficulty [thu[thu] Neel [phul[phul] base five [ley[ley] Neel amine; transducer base five [ley[ley] Neel amine; N - phenyl phenyl amine; N - phenyl car amine it will become sleepy; phenyl car amine it will become sleepy-N -; N - phenyl it cuts nephew amine it will become sleepy ;-N - the phenyl it cuts nephew amine it will become sleepy; five [ley neel car it will become sleepy, oh N - it pushes and process for preparation thereof; benzo car it will become sleepy; dibenzo car it will become sleepy; cover it will become sleepy; ; ; ; ; ; ; ; ; ; ; ; ; ; And Selected from the group consisting of, the Ar1 deuterium; for fluorine; nitrile; methyl; view [thil t -; phenyl; phenyl-; me [phu; the flue five [ley neel; lung difficulty [thu neel; cover it will become sleepy; benzo car it will become sleepy; [til[til] pyridazinone; triazole neel; tree phenyl [ley[ley] Neel; pyrimido [til[til]; [khwi[khwi] glow Neel; dibenzo [phyu[phyu] [la_nil[la_nil]; dibenzo mote five pen; already will be and it will become sleepy benzamide; benzo the mote oh it will become sleepy; the jade company it will become sleepy benzimidazole; for thiophene; dimethyl gun spin oxide; d phenyl gun spin oxide; [phu gun spin oxide copolymer; tree methyl thread reel; tree phenyl thread reel; d phenyl amine; moreover phenyl amine; N - phenyl at all phenyl amine; N - phenyl me [phu amine; phenyl or [phu[phu] amine-N -; N - me [phu[phu] base five [ley[ley] Neel amine; N - phenyl lung difficulty [thu[thu] Neel amine; phenyl lung difficulty [thu[thu] Neel amine-N -; N - phenyl [phul[phul] Base five [ley[ley] Neel amine; N - phenyl phenyl amine; N - lung difficulty [thu[thu] Neel [phul[phul] base five [ley[ley] Neel amine; phenyl [phul[phul] base five [ley[ley] Neel amine-N -; and Selected from the group consisting of 1 or more can be substituted or unsubstituted. Formula 1 is coupled to said L1 portion through said - - - - big. The specification according to one embodiment state, in said formula 1, the following Ar1 [A provided 1] to [A-a 5] is displayed either. [A provided 1] [A provided 2] [A provided 3] [A-a 4] [A-a 5] In formula - - - coupled to said L1 portion through said formula 1 is big. The specification according to one embodiment state, in said formula 1, the alkyl group or a substituted or unsubstituted hetero with allyl Ar1 amine it will be biting; with allyl substituted or nonsubstituted substituted N - will be biting and hetero amine it will be biting; with allyl substituted phosphine oxide; alkyl or with allyl substituted or nonsubstituted a substituted aryl group; or heteroatoms with allyl substituted or unsubstituted aryl group. The specification according to one embodiment state, in said formula 1, the alkyl group substituted with N - Ar1 flue five [ley neel phenyl amine; N - neel five [ley at all phenyl amine substituted with alkyl and process for preparation thereof; a substituted or unsubstituted hetero with allyl at all phenyl amine N - phenyl; substituted or unsubstituted hetero with allyl a d phenyl amine; moreover phenyl amine; d it cuts trillion [phyu [la_nil amine N - phenyl; phenyl d it cuts trillion [phyu [la_nil amine-N -; d it cuts trillion mote five pen amine N - phenyl; phenyl d it cuts trillion mote five pen amine-N -; with allyl-substituted or substituted or unsubstituted N - phenyl car amine it will become sleepy; with allyl substituted phosphine oxide; phenyl; bi-phenyl; me [phu; phenyl; and process for preparation thereof substituted with alkyl having five [ley neel; tree phenyl [ley[ley] Neel; with allyl substituted or unsubstituted [til[til] sealed by a partition; a substituted or unsubstituted pyrimidone [til[til] with allyl; substituted or unsubstituted triazoles with allyl neel; dibenzo [phyu[phyu] [la_nil[la_nil]; dibenzo mote five pen; with allyl substituted or a substituted or unsubstituted quinacridone-based it will become sleepy; the [khwi it will tease; benzo car it will become sleepy; cover with allyl substituted or unsubstituted it will become sleepy; or with allyl substituted or nonsubstituted already will be and it will become sleepy substituted benzazepines among others. The specification according to one embodiment state, in said formula 1, five [ley neel phenyl amine N - Ar1 is methyl substituted and process for preparation thereof; flue neel five [ley at all phenyl amine group substituted N -; dibenzo [phyu[phyu] [la_nil[la_nil], or a substituted or unsubstituted phenyl N - dibenzo mote five pen crossroadat all phenyl amine; dibenzo [phyu[phyu] [la_nil[la_nil], or dibenzo mote five pen crossroad d phenyl amine substituted substituted or nonsubstituted; moreover phenyl amine; d it cuts trillion [phyu [la_nil amine N - phenyl; phenyl d it cuts trillion [phyu [la_nil amine-N -; d it cuts trillion mote five pen amine N - phenyl; phenyl d it cuts trillion mote five pen amine-N -; phenyl or a substituted or unsubstituted-a-N - phenyl car amine it will become sleepyphenyl crossroad; substituted phenyl phosphine oxide; phenyl; phenyl-; me [phu; phenyl; five [ley neel group substituted for preparation thereof; tree phenyl [ley[ley] Neel; [til[til] sealed by a substituted or unsubstituted phenyl group; or a substituted or unsubstituted pyrimidone [til[til] analogs of phenyl; phenyl, bi-phenyl, and 1 selected from the group consisting of a substituted or unsubstituted neel me [phu crossroad or triazoles; dibenzo [phyu[phyu] [la_nil[la_nil]; dibenzo mote five pen; phenyl, a substituted or unsubstituted phenyl or a quinacridone-me [phu crossroad it will become sleepy; the [khwi it will tease; benzo car it will become sleepy; phenyl, bi-phenyl, or a substituted or unsubstituted it will become sleepy cover me [phu crossroad; or phenyl groups substituted or nonsubstituted already will be and it will become sleepy substituted benzazepines among others. The specification according to one embodiment state, said formula 1 is a compound selected from the composers. The specification according to one embodiment state, represented by the general formula 1 by said formula 1 heterocyclic core structures can be bath but number, a textile fabric are not correct. [General formula 1] In said general formula 1, and the definition of the formula 1 Ar1 and L1 are the same. The specification according to one embodiment state, number 1 electrode; having oppositely to said number 1 number 2 electrode; and said number 1 and number 2 electrode 1 with organic light emitting device including at least one layer of a solvent, said organic layer 1 aforementioned heterocyclic compound including at least one layer is an organic light emitting number under public affairs substrate. The specification according to one embodiment state, the specification may also be used but multi organic monolayer structure, 2 at least one layer of organic layer can be laminated multi-layer structure. For example, organic light emitting device of the present invention organic matter as a hole injection layer, hole transport layer, electron blocking layer, light emitting layer, hole blocking layer, metal-containing fullerene, including electronic electronic implantation layer may have like structure. However of organic light-emitting structure is supported by a large number of organic layers or less can be without limit. For example, the specification also 1 and 2 such as shown in the structure of the organic light emitting device of structure but there is also a textile fabric are not correct. 1 also substrate (20) number 1 on electrode (30), a light emitting layer (40) and number 2 electrode (50) sequentially stacked organic light emitting device (10) structure is exemplified in the nanometer range. Said Figure 1 the specification according to one embodiment state organic light-emitting an exemplary structure and, other organic layer contains hollow beads can. Substrate also 2 (20) number 1 on electrode (30), hole injection (60), hole (70), a light emitting layer (40), alkali metal-containing fullerene (80), with an (90) and number 2 electrode (50) sequentially stacked organic light emitting structure of example in the nanometer range. Said Figure 2 the specification state according to an exemplary embodiment of structure and, other organic layer contains hollow beads can. The specification according to one embodiment state, a chemical formula and said organic compound layer is formed, said hole comprises a heterocyclic compound represented by said formula 1 [song[song] layer. The specification according to one embodiment state, electronic interception layer comprising said organic compound layer is formed, said electronic interception layer comprise a heterocyclic compound represented by said formula 1. The specification according to one embodiment state, electronic transporting bed and said organic compound layer is formed, said alkyl group comprises a heterocyclic compound represented by said formula 1. The specification according to one embodiment state, said organic compound layer is formed and a light emitting layer, said light-emitting layer comprises a heterocyclic compound represented by said formula 1. The specification according to one embodiment state, said organic compound layer is formed and a light emitting layer, said light-emitting layer comprises a heterocyclic compound represented by said formula 1 as removed. The specification of embodiment in the condition, said organic compound layer is formed including a heterocyclic compound represented by said formula 1 host, other organic compounds, can be metal or metal compound comprising with a dopant. Said at least one selected from 1 or more for example can be a dopant compound, a textile fabric are not correct. The specification according to one embodiment state, said organic compound layer is formed hole injection layer, hole transport layer, light emitting layer, with an alkali metal-containing fullerene and further comprises at least one layer 1 can be selected from the group consisting. The organic layer 1 n-heterocyclic oxidation layer the specification specification an organic light emitting device, i.e., a compound represented by said formula 1 inhibitors including number under the outside sugar known material and method technical field the number bath 1308. Said case including a plurality of organic solvent, said organic compound layer is formed can be made of the same material or other. For example, the specification of organic light-emitting device on the substrate electrode number 1, number 2 and number can be the whole electrode layer by depositing high pressure liquid coolant. At this time sputtering method (sputtering) or physical vapor deposition (PVD: physical Vapor Deposition) method such as electron beam evaporation (e-a beam evaporation) using, number 1 depositing a metal film on the substrate or conductive metal oxides or alloys thereof is formed, on the hole injection layer, hole transport layer, layer is formed on the organic light-emitting layer and electron transport layer including, the used number tank number 2 thereon by depositing a material which can be can be disclosed. In addition such method, organic layer from number 2 electrode material on a substrate, the substrate electrode material can be organic light emitting pattern on the number 1. In addition, the organic heterocyclic compound represented by said formula 1 morning fair number of applicable organic layer can be formed by solution coating technique as well as. Wherein, solution coating technique the circular spin coating, dip coating, doctor steam turbines, inkjet printing, screen printing, spraying, roll coating will but, only and not limited to these. The specification according to one embodiment state, and said number 1 electrode is an anode, anode are said number 2 are disclosed. The specification of another embodiment according to the state, and anode are said number 1, said number 2 the anode electrode are disclosed. Said positive electrode material based on organic hole injection layer to a group including the optical cable preferably smooth. The anode material used in the present invention specific examples vanadium, chromium, copper, zinc, flexible or alloys thereof; zinc oxide, indium oxide, indium tin oxide (ITO), indium zinc oxide (IZO) such as metal oxide; ZnO: Al or SnO2 : Combination of metal oxide such as Sb; poly (3 - methyl thiophene), poly [3, 4 - (ethylene - 1, 2 - dioxy) thiophene] (PEDOT), polyaniline conductive polymer such as polypyrrole and is provided to be used, these exclusively are not correct. The whole structure of the optical cable to said anode material for electronic injection hereinafter the workfunction of a preferably small material. Anode material specific examples include magnesium, calcium, sodium, potassium, titanium, indium, yttrium, lithium, gadolinium, aluminum, is, a metal such as tin and zinc or an alloy thereof; or LiF/Al LiO2 /Al, such as Mg/Ag multilayer structure material is provided to be used, these exclusively are not correct. The latter title implantation layer said hole injecting electrode hole injection, hole injection hole transporting ability to anodes holes in title injector effect, light emitting layer or a light emitting material having excellent hole injection effect, generated in a light emitting layer with an electron injection material or to prevent movement of the excitons release, in addition, a compound preferably thin film forming capability. HOMO (highest occupied molecular orbital) of positive-electrode material in between the peripheral hole of a filler material is preferably al HOMO work function and. Specific examples include metal porphyrin (porphyrin) hole injection material, thiophene oligomer, arylamine-based organic, organic-based process the nitrile [heyk it buys oh character tree phenyl [leyn, quinacridone (quinacridone) based organic, organic-perylene (perylene), polyaniline and polythiophene-based conductive polymer is provided to be used and anthraquinone, these exclusively are not correct. From hole to hole to receive said light-emitting layer hole transport [song[song] layer hole injection layer, hole transport title either as an anode or hole injection layer receives from hole transporting light emitting layer stores material converted into large hole on an suitable material. Specific examples arylamine-based organic, conductive polymer, and conjugated portion portion is provided to be used for the polymerization of the block copolymer are shown, these exclusively are not correct. Said electron blocking layer from the metal layer into the light-emitting layer is connected past the hole injection layer of prolonging the life and efficiency by preventing layer and improve, if necessary publicly known hole injection layer between a light emitting layer for forming bit lines are produced with the aid of suitable can be. Title and the electrons from said organic layer organic light emitting materials that emit light of visible region by combining each transport receives as a material which can be, for good quantum efficiency preferably fluorescent or phosphorescent material. Specific examples 8 - hydroxy quinoline - aluminum complex (Alq3 ); Carbazole compounds; dimerization (dimerized styryl) styryl compounds; BAlq; 10 - hydroxy benzo quinoline - metal compound; benzoxazole, benzothiazole and benzimidazole-based compound; poly (p - phenylene vinylene) (PPV) blended with polymer; spiro (spiro) compound; polyfluorenes, base [pu is provided to be used, these exclusively are not correct. Said light-emitting layer host material and dopants can be material. Condensation aromatic cyclic derivative or heterocyclic ring-containing compound etc. host material. Specifically condensation aromatic cyclic derivatives include anthracene derivatives, pyrene derivatives, naphthalene derivatives, pentacene derivatives, phenanthrene compound, fluoranthene compound at sea, heterocyclic ring-containing compounds include carbazole derivatives, dibenzo furan derivatives, ladder furan compounds, pyrimidine derivatives is provided to be used, is not limited. Said dopant materials include aromatic amine derivatives, [su reel amine compounds, boron complex, fluoranthene compound, metal complex etc.. Specifically aromatic amine derivatives include substituted or unsubstituted having a condensation aromatic cyclic derivatives as the biting amino it will raise, the biting amino it will raise with pyrene, anthracene, cleaning compound, such as peripheral [phul[phul] Column [theyn[theyn] which, styryl amine compounds include substituted or nonsubstituted substituted in biting amine has been substituted compound of at least 1 biting vinyl giga, aryl group, silyl group, alkyl, 1 or 2 substituents at the at least one selected from the group consisting of cycloalkyl and biting amino crossroad is substituted with substituted or nonsubstituted. Specifically styryl amine, styryl diamine, styryl tree amine, styryl tetra amine is provided to be used, is not limited. In addition, metal complexes the iridium complexes, platinum complex is provided to be used, is not limited. A light-emitting layer of hole blocking layer are injected from said hole injection layer is connected past the layer film is formed of life and efficiency can be improved and an imaging device, if necessary publicly known for forming bit lines are produced with the aid of an electron injection layer between a light emitting layer can be suitable. Said light-emitting layer receives electrons from the electron transport material include electronic transporting bed with an electronic transporting electrons from the cathode to the latter serving as electron transport material include good injection consisting of a material which can be moving a receives as, greater mobility for electrons suitable material. Specific examples of 8 - hydroxyquinoline Al complexes; Alq3 Including complex; organic radical compound; hydroxy Petioles - metal complex is provided to be used, these exclusively are not correct. As used electron transport layer according to a conventional technique can be use with any desired materials. In particular, examples of suitable cathode material is formed on the aluminum layer or sliver layer with conventional material that followed. Specifically cesium, barium, calcium, ytterbium and samarium and, in each case aluminum layer or sliver layer 369. Said electronic implantation layer electrode electrons from the latter, and capable of transporting electrons, cathode electron injector effect, light emitting layer or a light emitting material has excellent injector effect, preventing to hole injection layer produced generated in a light emitting layer, in addition, a compound preferably thin film forming capability. Specifically fluorenone, do not sprout the [khwi roh die methane, die lung roh [khwi rice field, profound pyrans, oxazole, oxadiazole, triazole, imidazole, vinyl [leyn the tetra car luck thread it buys, five [ley neel it was burnt pregabalin methane, magnetron inside [thu like their derivatives, metal complex compound and nitrogenous 5 membered ring derivatives is provided to be used, is not limited. Said metal complex compound as 8 - hydroxy hour [khwi[khwi] it teases but the toe lithium, bis (8 - hydroxy hour [khwi[khwi] it teases but the toe) zinc, bis (8 - hydroxy hour [khwi[khwi] it teases but the toe) copper, bis (8 - hydroxy hour [khwi[khwi] it teases but the toe) manganese, tris (8 - hydroxy hour [khwi[khwi] it teases but the toe) aluminum, tris (2 - methyl - 8 - hydroxy hour [khwi[khwi] it teases but the toe) aluminum, tris (8 - hydroxy hour [khwi[khwi] it teases but the toe) gallium, bis (10 - hydroxy benzo the [khwi[khwi] it teases but the toe) beryllium, bis (10 - hydroxy benzo the [khwi[khwi] it teases but the toe) zinc, bis (2 - methyl - 8 - the [khwi[khwi] it teases but the toe) gallium chloro, bis (2 - methyl - 8 - the [khwi[khwi] it teases but the toe) gallium (o - cresol toe), bis (2 - methyl - 8 - the [khwi[khwi] it teases but the toe) (1 - naphthol toe) aluminum, bis (2 - methyl - 8 - the [khwi[khwi] it teases but the toe) (2 - naphthol toe) gallium is provided to be used, is not limited. The specification according to materials used in the first and second formed at each-emitting, backlit or be a two-sided light emitting type. The specification according to one embodiment state, the organic heterocyclic compound represented by said formula 1 in addition organic solar cells or organic transistor can be included. Hereinafter, the specification specifically account for example in the embodiment detailed the on-sensors other. However, the specification according to in the embodiment are various other shape can be, the specification range of the intervening in the embodiment are not limited to below interpreted. The specification with average knowledge in the embodiment of art are to the specification to more fully describe which ball number are disclosed. A compound by 1, compound A, B, C, D, A provided 1, B provided 1, C-a 1 and a high pressure liquid coolant D-a 1 his number. [Compound 1] <Number attainments 1>compound 1 number of bath Nitrogen atmosphere 500 ml round bottom cap to formula A (10g, 22. 62mmol), di ([1, 1' a-biphenyl] provided 4 a-yl) amine (7. 63g, 23. 76mmol) to a entire Xylene 210 ml after sodium tert-a butoxide (2. 61g, 27. 15mmol) adding, Bis (tri - MS [M + H]+ =728 <Number attainments 2>compound 2 number of bath Nitrogen atmosphere 500 ml round bottom cap to formula B (10g, 22. 62mmol), N a-phenyl-a ' [ 1,1 non-biphenyl] provided 4 a-amine (5. 82g, 23. 76mmol) to a entire Xylene 170 ml after sodium tert-a butoxide (2. 61g, 27. 15mmol) adding, Bis (tri - MS [M + H]+ =652 <Number attainments 3>compound 3 number of bath Nitrogen atmosphere 500 ml round bottom cap to formula C (10g, 22. 62mmol), N - ([1, 1 'a-biphenyl] provided 4 a-yl) - [1, 1' a-biphenyl] provided 2 a-amine (7. 63g, 23. 76mmol) to a entire Xylene 210 ml after sodium tert-a butoxide (2. 61g, 27. 15mmol) adding, Bis (tri - MS [M + H]+ =728 <Number attainments 4>compound 4 number of bath Nitrogen atmosphere 500 ml round bottom cap to formula D (10g, 22. 62mmol), N - ([1, 1' a-biphenyl] provided 4 a-yl) - 9, 9 a-dimethyl-a 9H-a fluoren provided 2 a-amine (8. 58g, 23. 76mmol) to a entire Xylene 220 ml after sodium tert-a butoxide (2. 61g, 27. 15mmol) adding, Bis (tri - MS [M + H]+ =768 <Number attainments 5>compound 5 number of bath Nitrogen atmosphere 500 ml round bottom cap to compound C-a 1 (10. 09g, 33. 13mmol), 9 a-bromo-a 10 a-phenylanthracene (10g, 30. 12mmol) after an aqueous potassium carbonate to a 240 ml tetrahydrofuran mixable entire 2M (120 ml) added, tetrakis - (triphenyl phosphine) palladium (0. 19g, 0. 17mmol) having been added 8 heating at a stirring-gate. It is a stand-alone water layer and magnesium sulfate anhydride in a solvent at ambient temperature number and to 220 ml ethyl acetate cream is recrystallised compound 5 (15. 77g, 72%) number was a high pressure liquid coolant. MS [M + H]+ =661 <Number attainments 6>compound 6 number of bath Nitrogen atmosphere 500 ml round bottom cap to compound B provided 1 (10. 09g, 33. 13mmol), 9 a-bromo-a 10 a-phenylanthracene (10g, 30. 12mmol) after an aqueous potassium carbonate to a 240 ml tetrahydrofuran mixable entire 2M (120 ml) added, tetrakis - (triphenyl phosphine) palladium (0. 19g, 0. 17mmol) having been added 8 heating at a stirring-gate. It is a stand-alone water layer and magnesium sulfate anhydride in a solvent at ambient temperature number is recrystallised compound 6 to 260 ml ethyl acetate cream and (17. 56g, 80%) number was a high pressure liquid coolant. MS [M + H]+ =661 <Number attainments 7>compound 7 number of bath Nitrogen atmosphere 500 ml round bottom cap to compound D-a 1 (22. 49g, 41. 20mmol), 2 a-chloro-a 4, 6 a-diphenyl-a 1, 3, 5 a-triazine (10g, 37. 45mmol) after an aqueous potassium carbonate to a 280 ml tetrahydrofuran mixable entire 2M (140 ml) added, tetrakis - (triphenyl phosphine) palladium (1. 30g, 1. 12mmol) having been added 4 heating at a stirring-gate. It is a stand-alone water layer and magnesium sulfate anhydride in a solvent at ambient temperature number is recrystallised compound 7 to ethyl acetate cream and 340 ml (15. 77g, 72%) number was a high pressure liquid coolant. MS [M + H]+ =640 <Number attainments 8>compound 8 number of bath Nitrogen atmosphere 500 ml round bottom cap to compound C-a 1 (17. 51g, 32. 07mmol), 2 - ([1, 1' a-biphenyl] provided 4 a-yl) - 4 a-chloro-a 6 a-phenyl-a 1, 3, 5 a-triazine (10g, 29. 15mmol) after an aqueous potassium carbonate to a 280 ml tetrahydrofuran mixable entire 2M (140 ml) added, tetrakis - (triphenyl phosphine) palladium (1. 30g, 1. 12mmol) having been added 4 heating at a stirring-gate. It is a stand-alone water layer and magnesium sulfate anhydride in a solvent at ambient temperature number is recrystallised compound 8 in 260 ml tetrahydrofuran mixable and cream (15. 47g, 67%) number was a high pressure liquid coolant. MS [M + H]+ =716 <Number attainments 9>compound 9 number of bath Nitrogen atmosphere 500 ml round bottom cap to compound A provided 1 (17. 51g, 32. 07mmol), 2 - ([1, 1' a-biphenyl] provided 4 a-yl) - 4 a-chloro-a 6 a-phenyl-a 1, 3, 5 a-triazine (10g, 29. 15mmol) after an aqueous potassium carbonate to a 280 ml tetrahydrofuran mixable entire 2M (140 ml) added, tetrakis - (triphenyl phosphine) palladium (1. 30g, 1. 12mmol) having been added 3 heating at a stirring-gate. It is a stand-alone water layer and magnesium sulfate anhydride in a solvent at ambient temperature number 310 ml tetrahydrofuran mixable and the cream is recrystallised compound 9 (15. 47g, 67%) number was a high pressure liquid coolant. MS [M + H]+ =716 <Number attainments 10>compound 10 number of bath Nitrogen atmosphere 500 ml round bottom cap to compound A provided 1 (17. 52g, 28. 42mmol), 2 - (4 a-bromophenyl) - 4, 6 a-diphenyl-a 1, 3, 5 a-triazine (10g, 25. 84mmol) after an aqueous potassium carbonate to a 280 ml tetrahydrofuran mixable entire 2M (140 ml) added, tetrakis - (triphenyl phosphine) palladium (1. 30g, 1. 12mmol) having been added 6 heating at a stirring-gate. It is a stand-alone water layer and magnesium sulfate anhydride in a solvent at ambient temperature number 310 ml tetrahydrofuran mixable and the cream is recrystallised compound 10 (17. 23g, 85%) number was a high pressure liquid coolant. MS [M + H]+ =716 <Number attainments 11>compound 11 number of bath Nitrogen atmosphere 500 ml round bottom cap to compound A provided 1 (17. 52g, 28. 42mmol), 2 - (3 a-bromophenyl) - 4, 6 a-diphenyl-a 1, 3, 5 a-triazine (10g, 25. 84mmol) after an aqueous potassium carbonate to a 280 ml tetrahydrofuran mixable entire 2M (140 ml) added, tetrakis - (triphenyl phosphine) palladium (1. 30g, 1. 12mmol) having been added 6 heating at a stirring-gate. It is a stand-alone water layer and magnesium sulfate anhydride in a solvent at ambient temperature number is recrystallised compound 11 in 290 ml tetrahydrofuran mixable and cream (16. 95g, 83%) number was a high pressure liquid coolant. MS [M + H]+ =716 <Number attainments 12>compound 12 number of bath Nitrogen atmosphere 500 ml round bottom cap to compound C-a 1 (20. 02g, 36. 67mmol), 2 a-chloro-a 4 a-phenylquinazoline (8. 0g, 33. 33mmol) after an aqueous potassium carbonate to a 260 ml tetrahydrofuran mixable entire 2M (130 ml) added, tetrakis - (triphenyl phosphine) palladium (1. 16g, 1. 00mmol) having been added 4 heating at a stirring-gate. It is a stand-alone water layer and magnesium sulfate anhydride in a solvent at ambient temperature number is recrystallised compound 12 in 230 ml tetrahydrofuran mixable cream and (21. 45g, 67%) number was a high pressure liquid coolant. MS [M + H]+ =613 <Number attainments 13>compound 13 number of bath Nitrogen atmosphere 500 ml round bottom cap to compound B provided 1 (17. 52g, 28. 42mmol), 4 - (3 a-bromophenyl) - 2, 6 provided diphenylpyrimidine (10g, 25. 84mmol) after an aqueous potassium carbonate to a 280 ml tetrahydrofuran mixable entire 2M (140 ml) added, tetrakis - (triphenyl phosphine) palladium (1. 30g, 1. 12mmol) having been added 6 heating at a stirring-gate. It is a stand-alone water layer and magnesium sulfate anhydride in a solvent at ambient temperature number 310 ml tetrahydrofuran mixable and the cream is recrystallised compound 13 (16. 95g, 83%) number was a high pressure liquid coolant. MS [M + H]+ =715 <Number attainments 14>compound 14 number of bath Nitrogen atmosphere 500 ml round bottom cap to compound A provided 1 (17. 52g, 28. 42mmol), N - (4 a-bromophenyl) - N a-phenyl-a ' [ 1,1 non-biphenyl] provided 4 a-amine (10g, 25. 84mmol) after an aqueous potassium carbonate to a 280 ml tetrahydrofuran mixable entire 2M (140 ml) added, tetrakis - (triphenyl phosphine) palladium (1. 30g, 1. 12mmol) having been added 6 heating at a stirring-gate. It is a stand-alone water layer and magnesium sulfate anhydride in a solvent at ambient temperature number 310 ml tetrahydrofuran mixable and the cream is recrystallised compound 14 (17. 23g, 85%) number was a high pressure liquid coolant. MS [M + H]+ =728 <Number attainments 15>compound 15 number of bath Nitrogen atmosphere 500 ml round bottom cap to compound D-a 1 (9. 33g, 17. 09mmol), N - ([1, 1' a-biphenyl] provided 4 a-yl) - N - (4 a-bromophenyl) - 9, 9 a-dimethyl-a 9H-a fluoren provided 2 a-amine (8. 0g, 15. 53mmol) after an aqueous potassium carbonate to a 280 ml tetrahydrofuran mixable entire 2M (140 ml) added, tetrakis - (triphenyl phosphine) palladium (1. 30g, 1. 12mmol) having been added 8 heating at a stirring-gate. It is a stand-alone water layer and magnesium sulfate anhydride in a solvent at ambient temperature number is recrystallised compound 15 to 180 ml tetrahydrofuran mixable cream and (9. 44g, 66%) number was a high pressure liquid coolant. MS [M + H]+ =844 <Number attainments 16>compound 16 number of bath Nitrogen atmosphere 500 ml round bottom cap to compound C-a 1 (10. 92g, 20. 01mmol), N - (4 a-bromophenyl) - 9, 9 a-dimethyl-a N a-phenyl-a 9H-a fluoren provided 2 a-amine (8. 0g, 18. 18mmol) after an aqueous potassium carbonate to a 280 ml tetrahydrofuran mixable entire 2M (140 ml) added, tetrakis - (triphenyl phosphine) palladium (1. 30g, 1. 12mmol) having been added 8 heating at a stirring-gate. It is a stand-alone water layer and magnesium sulfate anhydride in a solvent at ambient temperature number is recrystallised compound 16 to 180 ml tetrahydrofuran mixable cream and (12. 23g, 80%) number was a high pressure liquid coolant. MS [M + H]+ =768 <Number attainments 17>compound 17 number of bath Nitrogen atmosphere 500 ml round bottom cap to compound B provided 1 (17. 52g, 28. 42mmol), N - ([1, 1 'a-biphenyl] provided 4 a-yl) - N - (4 a-bromophenyl) - [1, 1' a-biphenyl] provided 4 a-amine (10g, 25. 84mmol) after an aqueous potassium carbonate to a 280 ml tetrahydrofuran mixable entire 2M (140 ml) added, tetrakis - (triphenyl phosphine) palladium (1. 30g, 1. 12mmol) having been added 6 heating at a stirring-gate. It is a stand-alone water layer and magnesium sulfate anhydride in a solvent at ambient temperature number 310 ml tetrahydrofuran mixable and the cream is recrystallised compound 17 (17. 23g, 85%) number was a high pressure liquid coolant. MS [M + H]+ =804 <Number attainments 18>compound 18 number of bath Nitrogen atmosphere 500 ml round bottom cap to compound A provided 1 (17. 52g, 28. 42mmol), 9 - (4 a-bromophenyl) - 9H-a carbazole (10g, 25. 84mmol) after an aqueous potassium carbonate to a 280 ml tetrahydrofuran mixable entire 2M (140 ml) added, tetrakis - (triphenyl phosphine) palladium (1. 30g, 1. 12mmol) having been added 6 heating at a stirring-gate. It is a stand-alone water layer and magnesium sulfate anhydride in a solvent at ambient temperature number 310 ml tetrahydrofuran mixable and the cream is recrystallised compound 18 (17. 23g, 85%) number was a high pressure liquid coolant. MS [M + H]+ =650 <Number attainments 19>compound 19 number of bath Nitrogen atmosphere 500 ml round bottom cap to compound A provided 1 (10. 09g, 18. 49mmol), 3 a-bromo-a 9 - (4, 6 a-diphenyl-a 1, 3, 5 a-triazin-a 2 a-yl) - 9H-a carbazole (8. 0g, 16. 81mmol) after an aqueous potassium carbonate to a 350 ml tetrahydrofuran mixable entire 2M (175 ml) added, tetrakis - (triphenyl phosphine) palladium (1. 30g, 1. 12mmol) having been added 2 heating at a stirring-gate. It is a stand-alone water layer and magnesium sulfate anhydride in a solvent at ambient temperature number 310 ml tetrahydrofuran mixable and the cream is recrystallised compound 19 (16. 47g, 90%) number was a high pressure liquid coolant. MS [M + H]+ =805 <Number attainments 20>compound 20 number of bath Nitrogen atmosphere 500 ml round bottom cap to compound A provided 1 (13. 50g, 24. 72mmol), (4 a-bromophenyl) diphenylphosphine oxide (8. 0g, 22. 47mmol) after an aqueous potassium carbonate to a 260 ml tetrahydrofuran mixable entire 2M (130 ml) added, tetrakis - (triphenyl phosphine) palladium (0. 78g, 0. 67mmol) having been added 4 heating at a stirring-gate. It is a stand-alone water layer and magnesium sulfate anhydride in a solvent at ambient temperature number 270 ml tetrahydrofuran mixable and the cream is recrystallised compound 20 (11. 18g, 66%) number was a high pressure liquid coolant. MS [M + H]+ =685 <Experiment example 1 - 1> ITO (indium tin oxide) glass substrate coated with a thin film coating has a thickness of 1,000 Å is executed to his cleaning which melts a number cells in distilled water. At this time, cells include Fischer yarn number (Fischer co.) O2 article number, number 2 (Filter) mixed with distilled water (Millipore co.) include Miller gun [e company to exhaust as well as a filter article in distilled water. A 30 minutes 10 minutes after washing the reservoir 2 to ultrasonic ITO periodical repetition of abortion. After the end of the cleaning distilled water, isopropyl alcohol, acetone, and dried by washing after been conveyed to plasma cleaner for an ultrasonic number of methanol. In addition, oxygen plasma into said 5 minutes after cleaning the substrate using vacuum deposition with respect to the brush. The process for the preparation of a formula prepared ITO transparent electrode to a thickness of over 500 Å by thermal vacuum deposition oh character tree phenyl [leyn nitrile (hexaazatriphenylene; HAT) weight percent hole-injecting layer. Transporting said hole injection hole on substances to compound 4 - 4' - bis [N - (1 - naphthyl) - N - phenylamino] biphenyl (NPB) vacuum depositing a chemical formula (300 Å) weight percent. Then, said hole selectively depositing 100 Å thickness membrane over a vacuum electronic interception layer compound 1 weight percent. Then, a generally downwardly facing surface such as on a membrane over said electronic blocking thickness 300 Å by vacuum deposition to form a luminescent layer BD BH weight ratio was 25:1. Said light emitting layer on said compound and said compound a 1:1 weight ratio ET1 LiQ (Lithium Quinolate) vacuum deposition to a thickness of 300 Å electron injection and transport layer weight percent. Lithium fluoride (LiF) sequentially on said electron injection and transporting 2,000 Å thickness is lower than the aluminum cathode 12 Å thickness on weight percent. During the organic speed 0. 4 - 0. 7 Å / sec have maintaining, the second lithium cathode flow 0. 3 Å / sec, the aluminum is 2 Å / sec when the deposition of an engine speed, the vacuum deposition 2 x10-7 - 5 x10-6 Holding torr, small organic light emitting-gate number. Example 1 - 2><experiment Experiment 1 - 1 example 1 2 instead of a component in an electronic blocking said said compound in the range of 0.1 and the same method-gate organic light-emitting element 1 - 1 example experiment number under the outside small number. Example 1 - 3><experiment Experimental example 1 - 1 to 1 instead of said component in said electronic blocking experiment number 1 - 1 and example 3 compound in the range of 0.1 under the outside same method small number-gate organic light-emitting element. Example 1 - 4><experiment Experimental example 1 - 1 to 1 instead of said component in said electronic blocking experiment number 1 - 1 in the range of 0.1 and the same method example 4 compound under the outside small number-gate organic light-emitting element. Example 1 - 5><experiment Example 14 instead of a component in an electronic blocking said experiments 1 - 1 and 1 - 1 example experiment number 1 said compound in the range of 0.1 under the outside same method-gate organic light-emitting element smaller number. Example 1 - 6><experiment Example 15 instead of a component in an electronic blocking said experiments 1 - 1 and 1 - 1 example experiment number 1 said compound in the range of 0.1 under the outside same method-gate organic light-emitting element smaller number. Example 1 - 7><experiment Example 16 instead of a component in an electronic blocking said experiments 1 - 1 and 1 - 1 example experiment number 1 said compound in the range of 0.1 under the outside same method-gate organic light-emitting element smaller number. Example 1 - 8><experiment Example 17 instead of a component in an electronic blocking said experiments 1 - 1 and 1 - 1 example experiment number 1 said compound in the range of 0.1 under the outside same method small organic light-emitting element-gate number. Example 1 - 9><experiment Example 18 instead of a component in an electronic blocking said experiments 1 - 1 and 1 - 1 example experiment number 1 said compound in the range of 0.1 under the outside same method-gate organic light-emitting element smaller number. Comparison example 1 - 1>< Example 1 a composite component in an electronic blocking said experiments 1 - 1 to 1 - 1 instead of the compound of example number in the range of 0.1 and EB1 under the outside said small organic light-emitting element number-gate the same experiment method. Comparison example 1 - 2>< Example 1 a composite component in an electronic blocking said experiments 1 - 1 and 1 - 1 instead of the compound of example number in the range of 0.1 to EB2 under the outside said small organic light-emitting element number-gate the same experiment method. Experimental example 1 - 1 to 1 - 9, comparison example 1 - 1 and 1 - 2 it became work when the number by blue light emission current, the results of table 1 are obtained. As in said table 1, the specification according to said formula 1 heterocyclic compound represented by the side of the organic light emitting device prepared by the number in the case of electronic blocking, of organic light-emitting efficiency, exhibits excellent characteristics in voltage and/or stability. The specification according to said formula 1 compounds are represented by said formula 1 inhibitors 1 - 1 and comparison example 1 - 2 comparison example core of similar structure from the upper container and the side of the organic light emitting device prepared by the number than electronic blocking compounds of low voltage, high efficiency characteristics other. The result of said table 1, the specification according to said formula 1 heterocyclic compound represented by the electronic barrier capability is also used for capable of excellent applicable to organic light-emitting device. <Experiment example 2 - 1 to 2 - 9> Example 1 - 1 to 1 - 1 to 1 - 9 instead of said hole in said experiment example experiment 1 said component in an electronic blocking compounds of NPB and methods using a number in the range of 0.1 and has identically experiment under the outside instead of the compound of the TCTA was. Comparison example 2 - 1>< Example 1 compound in said experiments 2 - 1 to 2 - 1 in the range of 0.1 and said compound of example experiment number under the outside HT 1 instead of the organic light-emitting element smaller number-gate the same method. Comparison example 2 - 2>< Experimental example 2 - 1 in the range of 0.1 to 1 HT 2 instead of said compound in said example 2 - 1 compound of the organic light-emitting element and the same method experiment number under the outside small number-gate. Experimental example 2 - 1 to 2 - 9, 2 - 1 and 2 - 2 example number by comparing it became work when the blue light emission current, obtained the results of table 2. Said as in table 2, the specification according to said formula 1 heterocyclic compound represented by the side of the organic light emitting device prepared by the number in the case of hole, said formula 1 comparison example 2 - 1 and comparison example 2 - 2 about the upper container containing fullerene compounds of structure and the side of the organic light emitting device prepared by the number than of organic light-emitting efficiency, exhibits excellent characteristics in voltage and/or stability. The result of said table 2, the present invention is excellent in the ability of hole transporting compounds are applicable to other organic light emitting element is also used for capable of. The result of said table 1, 2, the present invention is excellent in the ability to other compounds to electronic barrier capability as well as hole transport is also used for capable of applicable to organic light emitting element. <Comparison example 3 - 1> In a method conventionally known compounds prepared by the number number attainments sublimation membrane after positive number, such as the green luminescent organic element number method for his high pressure liquid coolant. ITO glass substrate coated with a thin film coating has a thickness of 1,000 Å (ndium tin oxide) is executed to his cleaning which melts a number cells in distilled water. At this time, cells include Fischer yarn number (Fischer co.) O2 article number, number 2 (Filter) mixed with distilled water (Millipore co.) include Miller gun [e company to exhaust as well as a filter article in distilled water. A 30 minutes 10 minutes after washing the reservoir 2 to ultrasonic ITO periodical repetition of abortion. After the end of the cleaning distilled water, isopropyl alcohol, acetone, and dried by washing after been conveyed to plasma cleaner for an ultrasonic number of methanol. In addition, oxygen plasma into said 5 minutes after cleaning the substrate using vacuum deposition with respect to the brush. The ITO transparent electrode prepared by using CBP on host, m a-MTDATA (60 nm)/TCTA (80 nm)/CBP + 10% Ir (ppy)3 (300 nm)/BCP (10 nm)/Alq3 (30 nm)/LiF (1 nm)/Al (200 nm) organic EL element Fe or order number was high pressure liquid coolant. M non-MTDATA, TCTA, Ir (ppy)3 , The structure of the CBP and BCP for each such as disclosed. Example 3 - 1><experiment Said compound 7 in example 3 instead of a number in the range of 0.1 under the outside CBP said experiment example experiment 3 small organic light-emitting element and the same method-gate number. Example 3 - 2><experiment Example 3 a number in the range of 0.1 and instead of said compound in said experiment example experiment 3 under the outside CBP compound 8 the same method small number-gate organic light-emitting element. Example 3 - 3><experiment Example 3 a number in the range of 0.1 and instead of said compound in said experiment example experiment 3 under the outside CBP compound 9 the same method small number-gate organic light-emitting element. Example 3 - 4><experiment Example 3 a number in the range of 0.1 and 10 instead of said compound in said experiment example experiment 3 under the outside CBP compound the same method small number-gate organic light-emitting element. Example 3 - 5><experiment Example 3 a number in the range of 0.1 instead of said compound in said experiment example experiment 3 under the outside CBP compound 11 and the same method small number-gate organic light-emitting element. Example 3 - 6><experiment Example 3 a number in the range of 0.1 and instead of said compound in said experiment example experiment 3 under the outside CBP compound 13 the same method small number-gate organic light-emitting element. Example 3 - 7><experiment Said compound in example 19 instead of a number in the range of 0.1 experiment 3 CBP said compound and organic light-emitting element the same method example 3 experiment under the outside small number-gate. Comparison example 3 - 2>< Said compound in comparison example 3 - 1 in the range of 0.1 to CBP compound of example 3 - 1 compares the number under the outside GH 1 instead of said organic light-emitting element and the same method small number-gate. Comparison example 3 - 3>< Said compound in comparison example 3 - 1 in the range of 0.1 to CBP compound of example 3 - 1 compares the number under the outside GH 2 instead of said organic light-emitting element and the same method small number-gate. Experiment 3 - 1 to 3 - 7 and comparison example 3 - 1 to 3 - 3 example it became work when the number by blue light emission current, obtained the results of table 3. As in said table 3, the specification according to said formula 1 heterocyclic compound represented by the O3 3 - 1 to 3 - 7 example experiment of green luminescent organic region is removed using CBP comparison example 3 - 1 and 3 - 2 and 3 - 3 core of said formula 1 compounds of similar structure from upper container comparison example host material by using organic light-emitting device prepared by the number representing the system current efficiency and making sure that the capable of driving voltage and is excellent in performance. Substituted triazine, substituted pyrimidines having said compounds are green luminescent organic devices suitable can be unworkable. <Experiment example 4 - 1 and 4 - 2> In a method conventionally known compounds prepared by the number number attainments sublimation membrane after positive number, such as the red organic light emitting element number method for his high pressure liquid coolant. ITO glass 2 mm × 2 mm sized to cathode-gate after cleaning. Substrate is mounted on the vacuum chamber base pressure 1 × 10-6 DNTPD torr is to expose the organic matter on said ITO (700 Å), α-a NPB (300 Å), the present invention compound prepared by the number by host 12 or compounds as 19 (90 wt %) using, for doping (piq)2 Ir (acac) (10 wt %) time stamp a detachable (300 Å) and, Alq3 (350 Å), LiF (5 Å), Al (1,000 Å) order it does, film, 0. In 4 mA to be measured is made. Said DNTPD, α-a NPB, (piq)2 Alq Ir (acac) and3 Of structures may be as follows. Comparison example 4 - 1>< Said compounds in said experiment example 4 - 1 in the range of 0.1 and 12 removed instead of a number equal to the CBP under the outside said small number-gate organic light-emitting element 4 - 1 example experiment method. Said experiment example 4 - 1, 4 - 2 and comparison example 4 - 1 by number prepared by the organic light emitting elements, voltage, current density, luminance, have shown to result table 4 for measuring transmissibility and their service life. T95 useless initial luminance (5000nit) thereon is reduced to 95% in big time. As said in table 4, the specification according to said formula 1 compound represented by example 4 - 1 and 4 - 2 O3 inhibitors removed experiment example 4 - 1 using conventional red organic light emitting element of red organic light emitting element than CBP compared current efficiency, and L2 indicating in making sure that the capable of superior performance. Substituted triazine, substituted quinazolines having a suitable can be removing said compounds are red light emitting organic devices. Example 5 - 1><experiment Said alkyl group in said experiment example 1 - 1 is used instead of compound 7 ET1, instead a number in the range of 0.1 and 1 said component in an electronic blocking compound of the example 1 - 1 the same method TCTA under the outside said experiment number-gate organic light-emitting element small. Example 5 - 2><experiment Said alkyl group in example 5 - 1 in the range of 0.1 to 7 said experiment number 5 - 1 and the experiment example 8 instead of compound compound under the outside said small organic light-emitting element number-gate the same method. Example 5 - 3><experiment Example 5 - 1 in the range of 0.1 to 7 instead of compound 9 in said component in said experiment number the alkali metal-containing fullerene same method small number-gate organic light-emitting element and said under the outside example experiment 5 - 1. Example 5 - 4><experiment Said experiment example 5 - 1 in the range of 0.1 and 10 instead of a component in an alkali metal-containing fullerene said in the experiment number 5 - 1 example 7 compound under the outside said organic light-emitting element smaller number-gate the same method. Example 5 - 5><experiment Example 5 - 1 in the range of 0.1 to 7 instead of compound 11 in said component in said experiment number the alkali metal-containing fullerene same method small number-gate organic light-emitting element and said under the outside example experiment 5 - 1. Example 5 - 6><experiment Example 5 - 1 in the range of 0.1 to 7 instead of compound 13 in said component in said experiment number under the outside the alkali metal-containing fullerene same method-gate organic light-emitting element and said experiment example 5 - 1 small number. Example 5 - 7><experiment Said alkyl group in example 5 - 1 in the range of 0.1 to 7 said experiment number 5 - 1 example 19 instead of the compound compound the same small number-gate organic light-emitting element and said under the outside experiment method. Example 5 - 8><experiment Said alkyl group in example 5 - 1 in the range of 0.1 to 20 said experiment number 5 - 1 and the experiment example 7 compound instead of compound under the outside said small organic light-emitting element number-gate the same method. Example 5 - 1><comparison Example 7 compound of alkali metal-containing fullerene component in said in said experiments 5 - 1 to 5 - 1 example experiments a number in the range of 0.1 under the outside ET2 instead of said organic light-emitting element and the same method small number-gate. Example 5 - 2><comparison Example 7 compound of alkali metal-containing fullerene component in said in said experiments 5 - 1 to 5 - 1 example experiments a number in the range of 0.1 under the outside ET3 instead of said organic light-emitting element and the same method small number-gate. Example 5 - 1 to 5 - 8 said experiments, 5 - 1 and 5 - 2 with respect to the organic light emitting device prepared by the number by comparison example, voltage, current density, luminance, measuring 5 to table shown to result transmissibility and longevity. Experiment result, the specification according to said formula 1 5 - 1 to 5 - 8 heterocyclic compound represented by the alkali metal-containing fullerene example 5 - 1 and 5 - 2 comparison example experiment using organic light emitting device of multi than current efficiency, making sure that the capable of representing driving voltage and is excellent in performance. Or more of the present invention preferred embodiment through (electronic blocking, hole, covering green, red covering, alkali metal-containing fullerene) is described but, is not limited to within range of the detailed description of the invention the present invention refers to claim on the deformed variously in embodiment and engaged in addition of the invention into the same category. 10, 11: organic light emitting device 20: substrate 30: number 1 electrode 40: light emitting layer 50: number 2 electrode 60: hole injection layer 70: hole 80: alkali metal-containing fullerene 90: with an The present specification relates to a hetero ring compound, and to an organic light-emitting device including the same. The hetero ring compound is represented by chemical formula 1. The hetero ring compound according to an aspect of the present specification can be used as a material of an organic material layer of an organic light-emitting device. By using the hetero ring compound, efficiency is improved in an organic light-emitting device. Also, a low driving voltage can be ensured, and/or lifespan properties can be improved. COPYRIGHT KIPO 2017 A heterocyclic compound represented by the formula 1: [formula 1] In said formula 1, R1 to R5 and R2 represent same or different hereinafter, are independently hydrogen; deuterium; nitrile group; nitro; hydroxy; carbonyl group; ester; for imide; amide group; a substituted or unsubstituted fluoroalkyl group; a substituted or unsubstituted cycloalkyl; substituted or a substituted or unsubstituted alkoxy group; a substituted or unsubstituted biting jade time; a substituted or unsubstituted alkyl mote jade time; substituted or nonsubstituted substituted biting mote jade time; a substituted or unsubstituted alkyl alcoholic beverage width time; substituted or nonsubstituted substituted biting alcoholic beverage width time; substituted or nonsubstituted substituted between the light-emitting; a substituted or unsubstituted silyl group; a substituted or unsubstituted boron to; a substituted or unsubstituted amine; a substituted or unsubstituted gun spin it will be biting; substituted or unsubstituted phosphine oxide; substituted the substituted or unsubstituted aryl group; or a substituted or non-substituted alkoxy group, L1 is coupled directly; a substituted or unsubstituted it will be biting, [leyn; or substituted or unsubstituted heteroatoms and it will be biting, [leyn strangeness, to amine substituted or unsubstituted Ar1; substituted or unsubstituted phosphine oxide; substituted or nonsubstituted a substituted aryl group; or a substituted or non-substituted alkoxy group, which is used in 1 to 5 and r2 r1 integer, integer number of 1 to 4 is r3, is 1 or 2 and r4, r5 is integer number of 1 to 3, when r1 to r5 is separately in a plurality, within a plurality of brackets on are same or hereinafter disclosed. According to Claim 1, represented by said formula 1 formula 2 to 5 displayed either a non-heterocyclic compound: [formula 2] [Formula 3] [Formula 4] [Formula 5] In said formula 2 to 5, R1 to R5, r1 Ar1 r5, L1 and to the definition of the formula 1 and are the same. According to Claim 1, said L1 is coupled directly; it will be biting, [leyn; or heteroaryl is it will be biting, [leyn[leyn] origination mild condition. According to Claim 1, said Ar1 amine it will be biting carbon of the alkyl group or a substituted or unsubstituted hetero with allyl; substituted or unsubstituted N - a with allyl will be biting and hetero amine it will be biting; with allyl substituted phosphine oxide; alkyl or with allyl substituted or nonsubstituted a substituted aryl group; or a substituted or unsubstituted heteroaryl it is an allyl with allyl is mild condition. According to Claim 1, said formula 1 is a compound selected from the bus electrodes mild condition: Number 1 electrode; having oppositely to said number 1 number 2 electrode; and said number 1 and number 2 electrode 1 or 2 with organic light emitting device including at least one layer of a solvent, said organic layer 1 layer or more of claim 1 to 5 including terms heterocyclic compound is either an organic light emitting device. According to Claim 6, said organic compound layer is formed comprising a chemical formula, [song[song] layer said heterocyclic compound is an organic light emitting device including said hole. According to Claim 6, electronic interception layer comprising said organic compound layer is formed, said heterocyclic compound is an organic light emitting device including said electronic interception layer. According to Claim 6, said organic compound layer is formed and a light emitting layer, said light-emitting layer including said heterocyclic compound is an organic light emitting device. According to Claim 6, said organic compound layer is formed and a light emitting layer, said light-emitting layer including an organic light emitting device as said heterocyclic compound is removed. According to Claim 6, electronic transporting bed and said organic compound layer is formed, said alkyl group including said heterocyclic compound is an organic light emitting device. Compound (electronic blocking) Voltage (V @ 10 mA/cm2 ) Efficiency (cd/A @ 10 mA/cm2 ) Transmissibility (x, y) Experimental example 1 - 1 Compound 1 3. 63 6. 45 (0. 138, 0. 127) Experiment example 1 - 2 Compound 2 3. 61 6. 46 (0. 139, 0. 127) Experiment example 1 - 3 Compound 3 3. 62 6. 38 (0. 138, 0. 126) Experiment example 1 - 4 Compound 4 3. 65 6. 37 (0. 138, 0. 127) Experiment example 1 - 5 Compound 14 3. 66 6. 35 (0. 137, 0. 126) Experiment example 1 - 6 Compound 15 3. 84 6. 13 (0. 137, 0. 126) Experiment example 1 - 7 Compound 16 3. 83 6. 12 (0. 137, 0. 127) Experiment example 1 - 8 Compound 17 3. 82 6. 08 (0. 136, 0. 126) Experiment example 1 - 9 Compound 18 3. 81 6. 07 (0. 137, 0. 126) Comparison example 1 - 1 EB1 4. 65 5. 46 (0. 136, 0. 127) Comparison example 1 - 2 EB2 4. 87 5. 23 (0. 136, 0. 127) Compound (hole) Voltage (V @ 10 mA/cm2 ) Efficiency (cd/A @ 10 mA/cm2 ) Transmissibility (x, y) Experimental example 2 - 1 Compound 1 3. 35 5. 42 (0. 136, 0. 126) Experimental example 2 - 2 Compound 2 3. 44 5. 23 (0. 136, 0. 126) Experimental example 2 - 3 Compound 3 3. 41 5. 28 (0. 136, 0. 127) Experimental example 2 - 4 Compound 4 3. 31 5. 40 (0. 136, 0. 126) Experimental example 2 - 5 Compound 14 3. 32 5. 3/ (0. 136, 0. 127) Experimental example 2 - 6 Compound 15 3. 44 5. 22 (0. 136, 0. 126) Experimental example 2 - 7 Compound 16 3. 54 5. 1/ (0. 136, 0. 127) Experimental example 2 - 8 Compound 17 3. 51 5. 25 (0. 136, 0. 126) Experimental example 2 - 9 Compound 18 3. 53 5. 1 * (0. 137, 0. 126) Comparison example 2 - 1 HT 1 4. 11 4. 53 (0. 136, 0. 127) Comparison example 2 - 2 HT 2 4. 35 4. 32 (0. 136, 0. 127) Compound (host) Voltage (V @ 10 mA/cm2 ) Efficiency (cd/A @ 10 mA/cm2 ) EL peak (nm) Comparison example 3 - 1 CBP 7. 62 35. 32 516 Experimental example 3 - 1 Compound 7 6. 60 44. 93 517 Experimental example 3 - 2 Compound 8 6. 56 45. 24 516 Experimental example 3 - 3 Compound 9 6. 61 44. 72 517 Experimental example 3 - 4 Compound 10 6. 59 44. 75 518 Experimental example 3 - 5 Compound 11 6. 68 44. 41 517 Experimental example 3 - 6 Compound 13 6. 53 44. 63 517 Experimental example 3 - 7 Compound 19 6. 57 44. 60 517 Comparison example 3 - 2 GH 1 7. 25 38. 52 517 Comparison example 3 - 3 GH 2 7. 36 38. 41 516 Classification Host Dopant Voltage Luminance (V) CIEx (cd/m2) CIEy T95 (hr) Experiment example 4 - 1 Compound 12 [(Piq)2 Ir (acac)] 4. 4 1860 0. 673 0. 326 465 Experiment example 4 - 2 Compound 19 [(Piq)2 Ir (acac)] 4. 2 1950 0. 674 0. 325 445 Comparison example 4 - 1 CBP [(Piq)2 Ir (acac)] 5. 7 1420 0. 670 0. 331 280 Compound Voltage (V @ 10 mA/cm2 ) Efficiency (cd/A @ 10 mA/cm2 ) Transmissibility (x, y) Experiment example 5 - 1 Compound 7 3. 98 4. 91 (0. 138, 0. 127) Experiment example 5 - 2 Compound 8 3. 75 5. 15 (0. 139, 0. 122) Experiment example 5 - 3 Compound 9 3. 86 5. 04 (0. 138, 0. 126) Experiment example 5 - 4 Compound 10 3. 85 4. 92 (0. 138, 0. 127) Experiment example 5 - 5 Compound 11 3. 89 4. 65 (0. 137, 0. 129) Experiment example 5 - 6 Compound 13 3. 95 4. 64 (0. 138, 0. 128) Experiment example 5 - 7 Compound 19 3. 90 4. 62 (0. 138, 0. 129) Experiment example 5 - 8 Compound 20 3. 96 4. 55 (0. 136, 0. 128) Comparison example 5 - 1 ET2 4. 22 3. 95 (0. 136, 0. 130) Comparison example 5 - 2 ET3 4. 43 3. 87 (0. 136, 0. 128)
