Partially halogenated, hydroxylated fullerene and allergen adsorbent using the same

Provided are a novel fullerene derivative which can adsorb quickly and efficiently an allergen which may cause a pollen allergy without releasing the allergen again, does not contain a metal or the like which may cause a harmful effect to a human body, and is easily applicable, impregnable, or chemically bondable onto surface of various materials: and a process for producing the same. The fullerene derivative is characterized in that a halogen group and many hydroxyl groups are bonded directly to a fullerene nucleus. In the case that the halogen group is chlorine, the fullerene derivative can be synthesized by a partial hydroxylation of a chlorinated fullerene or a partial chlorination of a hydroxylated fullerene.

Fullerene Derivatives and Their Applications in Organic Photovoltaics

The present invention relates to new fullerene derivatives of formulae 1a-d, 2 and 3: method of synthesizing said derivatives, and applications thereof in organic photovoltaics, e.g., organic solar cells. In particular, the fullerene derivatives of the present invention are soluble in non-halogenated solvents such that an environmental-friendly and low-cost fabrication method for industrialization of solar cell based on the new fullerene derivatives is provided. An ink formulation for forming a thin film on a substrate of organic photovoltaics comprising at least one of the fullerene derivatives of the present invention is also provided. Greater than 3% power conversion efficiency of the organic solar cells (area=0.16 cm 2 ) formed based on the fullerene derivatives of the present invention with less pollution and lower cost in fabrication can be achieved in the present invention.

METHOD FOR FORMING RESIST UNDERLAYER FILM

A method forms a resist underlayer film that has high resistance to dry etching using a gas containing a fluorocarbon. A method for forming a resist underlayer film includes the steps of: applying to a substrate a resist underlayer film-forming composition containing a fullerene derivative in which one to six molecules of malonic acid diester of the following Formula (1): 2. The method for forming a resist underlayer film according to claim 1 , wherein the temperature in baking under the atmosphere is 750° C. or lower.3. The method for forming a resist underlayer film according to claim 1 , wherein an oxygen concentration under the atmosphere is 0.01 ppm to 100 ppm.4. The method for forming a resist underlayer film according to claim 1 , wherein the resist underlayer film-forming composition further contains a surfactant.5. A method for forming a pattern comprising the steps of:{'claim-ref': {'@idref': 'CLM-00001', 'claim 1'}, 'applying an intermediate layer-forming composition to the resist underlayer film formed by the method according to , followed by baking, to form a silicon-containing intermediate layer;'}forming a resist film on the silicon-containing intermediate layer;carrying out at least exposure and development for the resist film to form a resist pattern; anddry etching the silicon-containing intermediate layer using a gas containing a fluorocarbon through the resist pattern serving as a mask. The present invention relates to a method for forming a resist underlayer film used in a lithography process that is a film obtained from a composition containing a fullerene derivative as a solid content.In a lithography process for production of a semiconductor device, a technology of forming a resist pattern in a desired shape by providing a resist underlayer film before formation of a photoresist film has been known. The following Patent Documents 1 and 2 describe a resist underlayer film-forming composition prepared using a fullerene derivative. In the ...

CARBON ALLOTROPES

A nanoparticle or agglomerate which contains connected multi-walled spherical fullerenes coated in layers of graphite. In different embodiments, the nanoparticles and agglomerates have different combinations of: a high mass fraction compared to other carbon allotropes present, a low concentration of defects, a low concentration of elemental impurities, a high Brunauer, Emmett and Teller (BET) specific surface area, and/or a high electrical conductivity. Methods are provided to produce the nanoparticles and agglomerates at a high production rate without using catalysts. 1. A thermal cracking apparatus for thermally cracking a hydrocarbon feedstock process gas and forming carbon aggregates therefrom , the thermal cracking apparatus comprising:A longitudinal reaction zone through which the hydrocarbon feedstock process gas is flowed longitudinally; andan elongated heating element disposed longitudinally within the reaction zone, the hydrocarbon feedstock process gas flowing around the elongated heating element;and wherein during thermal cracking operations the elongated heating element is heated to a molecular cracking temperature to generate the reaction zone, and the hydrocarbon feedstock process gas is flowed at a flow rate and under a pressure at which heat from the elongated heating element thermally cracks the hydrocarbon feedstock process gas as it flows within the reaction zone into thermally cracked molecules, which form carbon aggregates, each carbon aggregate comprising at least two connected multi-walled spherical fullerenes coated in layers of graphene.2. The thermal cracking apparatus of claim 1 , wherein:a ratio of carbon to other elements, except H, in the carbon aggregates is greater than 99.9%.3. The thermal cracking apparatus of claim 1 , wherein:{'sup': −1', '−1, 'a Raman spectrum of the carbon aggregates using 532 nm incident light has a first Raman peak at about 750 cmand a second Raman peak at about 1580 cm, and'}a ratio of an intensity of the ...

Cyclohexadiene fullerene derivatives

The invention relates to novel fullerene derivatives, to methods for their preparation and educts or intermediates used therein, to mixtures and formulations containing them, to the use of the fullerene derivatives, mixtures and formulations as organic semiconductors in, or for the preparation of, organic electronic (OE) devices, especially organic photovoltaic (OPV) devices and organic photodetectors (OPD), and to OE, OPV and OPD devices comprising, or being prepared from, these fullerene derivatives, mixtures or formulations.

Method for producing fullerene derivative

(in formula (1), C* are each carbon atoms adjacent to each other for forming a fullerene skeleton, A is a linking group having 1-4 carbon atoms for forming a ring structure with two C*, in which a portion thereof may be a substituted or condensed group).

Process for the synthesis of [6,6]-phenyl-c61butyric acid pentyl ester (pc61bp)

A total green, eco-friendly process for the synthesis of new acceptor molecule [6,6]-phenyl-C 61 -butyric acid pentyl ester (PC61BP) in high yields is carried under aerobic conditions showing better performance as acceptor in organic solar cells. More importantly this process causes the low cost synthesis of PC61BP in good yield without involving harmful and costly catalysts or chemicals.

CARBON ALLOTROPES

A nanoparticle or agglomerate which contains connected multi-walled spherical fullerenes coated in layers of graphite. In different embodiments, the nanoparticles and agglomerates have different combinations of: a high mass fraction compared to other carbon allotropes present, a low concentration of defects, a low concentration of elemental impurities, a high Brunauer, Emmett and Teller (BET) specific surface area, and/or a high electrical conductivity. Methods are provided to produce the nanoparticles and agglomerates at a high production rate without using catalysts. 1. An apparatus , comprising:a reaction zone configured to receive a hydrocarbon gas;a heating element disposed within the reaction zone and configured to heat the hydrocarbon gas, the reaction zone configured to thermally crack the hydrocarbon gas at a cracking temperature; andan output coupled to the reaction zone, the output configured to output a plurality of carbon aggregates generated in response to thermally cracking the hydrocarbon gas at the cracking temperature.2. The apparatus of claim 1 , wherein the plurality of carbon aggregates has a ratio of carbon to other elements claim 1 , except Hydrogen claim 1 , greater than 99.9%.3. The apparatus of claim 1 , wherein any one or more of the plurality of carbon aggregates has a first Raman peak at approximately 750 cmand a second Raman peak at approximately 1580 cm.4. The apparatus of claim 1 , wherein any one or more of the plurality of carbon aggregates comprises one or more multi-walled spherical fullerenes.5. The apparatus of claim 1 , wherein any one or more of the plurality of carbon based aggregates has a dimension approximately between 10 microns and 500 microns.6. The apparatus of claim 1 , wherein the plurality of carbon aggregates includes one or more graphene-based layers or structures.7. The apparatus of claim 1 , wherein the plurality of carbon aggregates has a specific surface area approximately between 10 m/g and 200 m/g.8. The ...

METHOD FOR PRODUCING FULLERENE DERIVATIVE

This method for producing a fullerene derivative is a method for producing a fullerene derivative having a partial structure shown by formula (1) by reacting a predetermined halogenated compound and two carbon atoms adjacent to each other for forming a fullerene skeleton in a mixed solvent of an aromatic solvent and an aprotic polar solvent having a C═O or S═O bond in the presence of at least one metal selected from the group comprising manganese, iron, and zinc; 2. The method for producing a fullerene derivative according to claim 1 , wherein the linking group with 1 to 4 carbon atoms for A is partially substituted by an aromatic group claim 1 , a heteroaromatic group claim 1 , an alkoxycarbonyl group or an alkylidene group.3. The method for producing a fullerene derivative according to claim 1 , wherein the linking group with 1 to 4 carbon atoms for A partially forms a condensed-ring structure or a polycyclic structure including an aromatic ring or a heteroaromatic ring with an aromatic ring or a heteroaromatic ring.4. The method for producing a fullerene derivative according to claim 1 , wherein the aprotic polar solvent is one or more of the group consisting of dimethyl sulfoxide (DMSO) and dimethylformamide (DMF).5. The method for producing a fullerene derivative according to claim 1 , wherein the aromatic solvent is o-dichlorobenzene.6. The method for producing a fullerene derivative according to claim 1 , wherein the halogen atom (X) is Br.7. The method for producing a fullerene derivative according to claim 1 , wherein the metal is Mn claim 1 , and the aprotic polar solvent is DMF.8. The method for producing a fullerene derivative according to claim 1 , wherein the metal is Fe claim 1 , and the aprotic polar solvent is DMSO.9. The method for producing a fullerene derivative according to claim 1 , wherein the metal is Mn or Zn claim 1 , and the aprotic polar solvent is DMSO. The present invention relates to a method for producing a fullerene derivative.The ...

CARBON ALLOTROPES

A nanoparticle or agglomerate which contains connected multi-walled spherical fullerenes coated in layers of graphite. In different embodiments, the nanoparticles and agglomerates have different combinations of: a high mass fraction compared to other carbon allotropes present, a low concentration of defects, a low concentration of elemental impurities, a high Brunauer, Emmett and Teller (BET) specific surface area, and/or a high electrical conductivity. Methods are provided to produce the nanoparticles and agglomerates at a high production rate without using catalysts. 1. A carbon aggregate comprising:at least two connected multi-walled spherical fullerenes; andlayers of graphene coating the connected multi-walled spherical fullerenes.2. The carbon aggregate of claim 1 , wherein:a ratio of carbon to other elements, except H, in the carbon aggregate is greater than 99.9%.3. The carbon aggregate of claim 1 , wherein:{'sup': −1', '−1, 'a Raman spectrum of the carbon aggregate using 532 nm incident light has a first Raman peak at approximately 1350 cmand a second Raman peak at approximately 1580 cm; and'}a ratio of an intensity of the first Raman peak to an intensity of the second Raman peak is from 0.9 to 1.1.4. The carbon aggregate of claim 1 , wherein:the multi-walled spherical fullerenes do not comprise a seed particle or a void at the center of the multi-walled spherical fullerenes.5. The carbon aggregate of claim 1 , wherein:a diameter across the carbon aggregate is from 10 microns to 500 microns.6. The carbon aggregate of claim 1 , wherein:the ratio of graphene to multi-walled spherical fullerenes in the carbon aggregate is from 10% to 80%.7. The carbon aggregate of claim 1 , wherein:{'sup': 2', '2, 'a Brunauer, Emmett and Teller (BET) specific surface area of the carbon aggregate is from 10 m/g to 200 m/g.'}8. The carbon aggregate of claim 1 , wherein:a plurality of the carbon aggregates are compressed into a pellet, and the pellet has an electrical conductivity ...

Anisotropic nanoparticle compositions and methods

A method for synthesizing a medicinal, nutraceutical, or food fullerene composition, including providing anisotropy in polar and non-polar C60 fullerene hemispheres to create one face of C60 fullerene having a small number of OH-groups clustered to the polar face; providing an amount of a polyhydroxylated fullerene from C60 fullerene; and blending the amount of the polyhydroxylated fullerene with an acceptable ionomer or an acceptable carrier or both. The polyhydroxylated fullerene includes fullerol-'x′ and the amount includes 200 ppm or 500 ppm, wherein ‘x’ is less than 22. The acceptable ionomer includes honey, or a mixture of 3% by wt. sucrose, 1% by wt. proline, 0.2% by wt. magnesium citrate, and 1% by wt. beta-cyclodextrin. The acceptable carrier includes water or a gelatin. A stent, a medical bandage, medical packing material, medical drainage material, acupuncture support, topical ointment, or suture material is impregnated with an anisotropic polyhydroxylated fullerene for antimicrobial action.

Fullerene mixtures for use in organic electronic devices

The invention relates to novel mixtures of substituted fullerenes, to their use in organic electronic (OE) devices, especially organic photovoltaic (OPV) devices and organic photodetectors (OPD), and to OE, OPV and OPD devices comprising these fullerene mixtures.

COMPOSITIONS AND METHODS FOR AMELIORATING CNS INFLAMMATION, PSYCHOSIS, DELIRIUM, PTSD OR PTSS

The invention provides compositions and methods for ameliorating, treating, reversing or preventing pathology or inflammation in the central nervous system (CNS), or the brain, caused or mediated by NFkB, IL-6, IL-6-R, NADPH oxidase (Nox), and/or superoxide and/or hydrogen peroxide production by a NADPH oxidase, including for example ameliorating, treating, reversing or preventing schizophrenia, psychosis, delirium, e.g., post-operative delirium, drug-induced psychosis, psychotic features associated with frailty syndrome (FS), aging, depression, dementias; traumatic war neurosis, post traumatic stress disorder (PTSD) or post-traumatic stress syndrome (PTSS), Amyotrophic Lateral Sclerosis (ALS, or Lou Gehrig's Disease), and/or Multiple Sclerosis (MS). The invention also provides methods for purifying a C60 fullerene, C(tris malonic acid C60) or malonic acid derivatives. 111-. (canceled)12. A method of:decreasing superoxide and/or hydrogen peroxide levels in a cell, or,inhibiting or decreasing the level of activation or activity of an NFkB, an IL-6, an IL-6-R, or an NADPH oxidase, comprising(a) providing a C60 malonic acid derivative,{'sub': '3', 'wherein optionally the C60 malonic acid derivative is or comprises a Ctris malonic acid C60 fullerene or a C60 macrocyclic malonate derivative,'}and optionally the malonate is functionalized with a halide atom, or malonate ester groups are replaced by alkyne groups, optionally as a dialkynylmethanofullerene; and(b) administering the C60 malonic acid derivative to the cell, wherein optionally the administering is in vitro or in vivo.13. The method of claim 12 , wherein administering the C60 malonic acid derivative in vivo to an individual in need thereof treats claim 12 , ameliorates claim 12 , slows the progress of or reverses: a schizophrenia; a psychosis; a delirium claim 12 , optionally a post-operative delirium; a drug-induced psychosis or a psychotic feature; frailty syndrome (FS) claim 12 , a cognitive impairment claim ...

Fullerene derivative and method for manufacturing a fullerene derivative

Disclosed is a fullerene derivative represented by the following formula (1): wherein FLN is a fullerene backbone, R 1 is a substituted or non-substituted alkyl group with a carbon number less than or equal to 24, and Ar 1 is a substituted or non-substituted aryl group with a carbon number less than or equal to 24.

Water-soluble fullerene, process for producing the same, antioxidant composition and external composition

A water-soluble fullerene characterized by being at least one hydroxylated fullerene comprising a fullerene core and, bonded thereto, over 30 hydroxyls (OH), which water-soluble fullerene exhibits a desirable water solubility, having a high active oxygen scavenging potency and can exhibit reduced shade. Further, there is provided a process for mass production thereof in a simple and easy and also efficient manner at low cost. Still further, there are provided an antioxidant composition and external composition comprising the water-soluble fullerene.

Fullerene compounds for solar cells and photodetectors

Amorphous fullerene derivatives and their use in organic electronic devices that include the fullerene derivative as the electron acceptor component in the device's active layer.

Methanofullerenes

适用作自由基清除剂的高级富勒烯

化学官能化的富勒烯作为自由基清除剂适用于各种应用中。这些化学官能化的富勒烯提供了保持富勒烯笼的高固有自由基清除效率以及容易地合成化学和物理特性被合乎需要改变的富勒烯衍生物和单个异构体的优点。此外，它们基于常用的中间产物化学且中间产物可以容易地被官能化并适于各种需要。

亚甲基富勒烯衍生物及使用其的光电转换器件

提供一种新型亚甲基富勒烯衍生物，其可作为有机半导体材料用于电子器件如有机FET和电致发光器件或者太阳能电池。具体地提供由通式(I)表示的亚甲基富勒烯衍生物，其特征在于 13 C-NMR中C 2 和C 2′ 的化学位移值的平均值为80.10ppm以上，C 2 和C 2′ 为存在于富勒烯(FL)上的并键合至C 1 的碳原子。 在通式(1)中，FL为富勒烯；X 1 和X 2 各自为芳族烃基或烷基等；C 2 和C 2′ 为存在于FL上并与C 1 键合的碳原子；和n为1至10的整数。

Patterning method, chemically-amplified resist composition, and resist film

고감도, 고해상성, 우수한 러프니스 성능, 및 우수한 드라이 에칭 내성을 동시에 만족함과 아울러 또한 현상 시간 의존성이 우수한 패턴 형성 방법으로서 (가) (A) 산 분해성기를 갖는 풀러렌 유도체와, (B) 활성광선 또는 방사선의 조사에 의해 산을 발생하는 화합물과, (C) 용제를 함유하는 화학증폭형 레지스트 조성물에 의해 막을 형성하는 공정, (나) 상기 막을 노광하는 공정, 및 (다) 유기 용제를 포함하는 현상액을 사용하여 현상하는 공정을 포함하는 네거티브형 패턴 형성 방법을 제공한다. (A) a fullerene derivative having an acid-decomposable group, (B) an actinic ray-curable resin composition comprising (A) a fullerene derivative having an acid-decomposable group, and (C) a step of forming a film by a chemically amplified resist composition containing a solvent, (B) a step of exposing the film, and (C) a step of exposing the film to a developing solution containing an organic solvent And a step of developing the light-emitting layer by using the light-emitting layer.

富勒烯衍生物

本发明涉及式I的富勒烯衍生物，含有它们的混合物和配制剂，富勒烯衍生物、混合物和配制剂作为有机半导体而用于电子器件，尤其是有机光伏(OPV)器件和有机光电探测器(OPD)的用途或用于制备电子器件，尤其是有机光伏(OPV)器件和有机光电探测器(OPD)的用途，以及包含这些富勒烯衍生物、混合物或配制剂或由这些富勒烯衍生物、混合物或配制剂所制得的电子器件。

Membrane with anti-viral properties

A condom with anti-viral properties is made by Langmuir-Blodgett coating onto latex rubber of 1 mole part C60 fullerene and 4 mole parts arachidic acid.

Fullerene derivative production method, fullerene derivative, proton conductor, and electrochemical device

Cyclohexadiene fullerene derivatives

The invention relates to novel fullerene derivatives, to methods for their preparation and educts or intermediates used therein, to mixtures and formulations containing them, to the use of the fullerene derivatives, mixtures and formulations as organic semiconductors in, or for the preparation of, organic electronic (OE) devices, especially organic photovoltaic (OPV) devices and organic photodetectors (OPD), and to OE, OPV and OPD devices comprising, or being prepared from, these fullerene derivatives, mixtures or formulations.

Fused bis-aryl fullerene derivatives

The invention relates to novel fullerene derivatives, to methods for their preparation and educts or intermediates used therein, to mixtures and formulations containing them, to the use of the fullerene derivatives, mixtures and formulations as organic semiconductors in, or for the preparation of, organic electronic (OE) devices, especially organic photovoltaic (OPV) devices and organic photodetectors (OPD), and to OE, OPV and OPD devices comprising, or being prepared from, these fullerene derivatives, mixtures or formulations.

Fullerene derivatives

The invention relates to fullerene derivatives of formula I, to mixtures and formulations containing them, to the use of the fullerene derivatives, mixtures and formulations as organic semiconductors in, or for the preparation of, electronic devices, especially organic photovoltaic (OPV) devices and organic photodetectors (OPD), and to electronic devices comprising, or being prepared from, these fullerene derivatives, mixtures or formulations.

Fullerene derivatives for organic semiconductors

The invention relates to fullerene derivatives of formula I, to mixtures and formulations containing them, to the use of the fullerene derivatives, mixtures and formulations as organic semiconductors in, or for the preparation of, electronic devices, especially organic photovoltaic (OPV) devices and organic photodetectors (OPD), and to electronic devices comprising, or being prepared from, these fullerene derivatives, mixtures or formulations.

Fullerene derivatives

Fullerene derivatives, as well as related compositions, photovoltaic cells, systems, and methods, are disclosed.

Water-soluble fullerene, method for producing the same, antioxidant composition, and external composition

フラーレン核に３０を超える数の水酸基（ＯＨ）を結合している水酸化フラーレンのうちの少くとも１種であることを特徴とする水溶性フラーレンとし、良好な水溶性を示し、高い活性酸素消去能を有するとともに、淡色を呈することのできる、水溶性フラーレンを提供するとともに、簡便に効率的に低いコストで大量合成することのできる方法と、上記水溶性フラーレンの抗酸化組成物、そして外用組成物をも提供する。 A water-soluble fullerene characterized by being at least one of hydroxylated fullerenes having more than 30 hydroxyl groups (OH) bonded to a fullerene nucleus, exhibiting good water solubility and high active oxygen scavenging. A water-soluble fullerene capable of exhibiting a light color and having a function, and a method capable of simply and efficiently synthesizing a large amount at low cost, an antioxidant composition of the water-soluble fullerene, and a composition for external use Also provide things.

Water-soluble functionalized fullerenes

Provided herein are water-soluble, functionalized fullerenes, and processes for producing water-soluble, functionalized fullerenes. The process includes sulfonating a fullerene in an acidic solution comprising sulfuric acid to produce a sulfonated fullerene, isolating the sulfonated fullerene from the acidic solution without neutralizing the acidic solution, reacting the sulfonated fullerene with hydrogen peroxide to form a reaction product, and isolating a polyhydroxylated fullerene from the reaction product produced from reacting the sulfonated fullerene with the hydrogen peroxide. The process of producing water-soluble fullerenes further includes functionalizing a polyhydroxylated fullerene with one or more pendant functional groups by reacting the polyhydroxylated fullerene with one or more functional group precursors.

Enhancement of electron scavenging by water-soluble fullerenes

Polyhydroxyfullerenes (PHFs) having enhanced electron scavenging capabilities have a ratio of non-hydroxyl functional groups to hydroxyl functional groups that is less than or equal to 0.3. When combined with a semiconductor photocatalyst, such as titanium dioxide nanoparticles, the PHFs provide a photocatalyst for degradation of chemical and biological contaminates with an efficiency of at least twice that of titanium dioxide nanoparticles free of PHFs. The PHFs are included in these catalysts at a weight ratio to titanium dioxide of about 0.001 to about 0.003, whereas significantly lower and higher ratios do not achieve the highly improved photodegradation capability. PHFs outside of the desired structure are shown to be of little value for photodegradation, and can be inhibiting to the photocatalytic activity of TiO 2 . The enhanced electron scavenging PHFs can be employed as a component of materials for solar cells, field effect transistors, and radical scavengers.

Water-soluble functionalized fullerenes

Provided herein are water-soluble, functionalized fullerenes, and processes for producing water-soluble, functionalized fullerenes. The process includes sulfonating a fullerene in an acidic solution comprising sulfuric acid to produce a sulfonated fuUerene, isolating the sulfonated fullerene from the acidic solution without neutralizing the acidic solution, reacting the sulfonated fullerene with hydrogen peroxide to form a reaction product, and isolating a polyhydroxylated fullerene from the reaction product produced from reacting the sulfonated fullerene with the hydrogen peroxide. The process of producing water-soluble fullerenes further includes functionalizing a polyhydroxylated fullerene with one or more pendant functional groups by reacting the polyhydroxylated fullerene with one or more functional group precursors.

Water-soluble functionalized fullerenes

Provided herein are water-soluble, functionalized fullerenes, and processes for producing water-soluble, functionalized fullerenes. The process includes sulfonating a fullerene in an acidic solution comprising sulfuric acid to produce a sulfonated fullerene, isolating the sulfonated fullerene from the acidic solution without neutralizing the acidic solution, reacting the sulfonated fullerene with hydrogen peroxide to form a reaction product, and isolating a polyhydroxylated fullerene from the reaction product produced from reacting the sulfonated fullerene with the hydrogen peroxide. The process of producing water-soluble fullerenes further includes functionalizing a polyhydroxylated fullerene with one or more pendant functional groups by reacting the polyhydroxylated fullerene with one or more functional group precursors.

Cyclohexadiene fullerene derivate

本发明涉及新型富勒烯衍生物，其制备方法和其中使用的离析物或中间体，包含它们的混合物和配制剂，富勒烯衍生物、混合物和配制剂作为有机半导体在有机电子(OE)器件，尤其是有机光生伏打(OPV)器件和有机光检测器(OPD)中或用于它们的制备的用途，以及包含或者由这些富勒烯衍生物、组合物或配制剂制备的OE、OPV和OPD器件。

Fused bis-aryl fullerene derivatives

The invention relates to novel fullerene derivatives, to methods for their preparation and educts or intermediates used therein, to mixtures and formulations containing them, to the use of the fullerene derivatives, mixtures and formulations as organic semiconductors in, or for the preparation of organic electronic (OE) devices, especially organic photovoltaic (OPV) devices and organic photodetectors (OPD), and to OE, OPV and OPD devices comprising, or being prepared from, these fullerene derivatives, mixtures or formulations.

Method for producing fullerene derivative

Metal-encapsulated fullerene derivative and method for producing the same

Stabilising vinyl monomers against uncontrolled polymerisation

Therapeutic malonic acid/acetic acid C60 tri-adducts of buckminsterfullerene and methods related thereto

Disclosed and claimed herein are e, e, e malonic acid/acetic acid tri-adducts of buckminsterfullerene of the general formula C 60 R 3 , wherein each R is independently selected from groups of the formula ═CR 1 R 2 wherein each R 1 and R 2 is independently selected from the group consisting of —H and —COOH, provided, however, that at least one of the R 1, s and R 2, s is a hydrogen. Processes for preparing and uses of the same for treating neuronal injury and for life-extension are also disclosed and claimed herein.

Fullerene derivatives, a process for their preparation and their use

Abstract of the disclosure Fullerene derivatives, a process for their preparation, and their use A process for preparing a methano-bridged fullerene derivative is described wherein a fullerene or fullerene derivative is reacted with a phosphorus ylide in an inert organic solvent at a temperature of from -78 to 180°C. Process products of the formula (II), (II) in which the symbols and indices have the following meanings: F: is a fullerene radical of the formula C20 + 2m, with m = 2 to 100; R4: is H, CH3, -phenyl or R5; R5: is a straight-chain or branched (with or without an asymmetric carbon atom) C2-C20-alkyl group, where one or more non-adjacent CH2 groups can be replaced by -C?C, -CH=CH-, -O-, -S-, -COO-, -OOC-, -SiR?-, -CO-, phenylenediyl or cyclohexylenediyl, and where one or more hydrogen atoms can be replaced by F, Cl, Br, I, OH or a tetrahydropyranyloxy group, or R4 and R5 together are =C=X with X being O, S, NR3 or (O-R3)2: R3: is phenyl or C1-C12-alkyl; n: is from 1 to 6; are novel. Compounds according to the invention and prepared in accordance with the invention are suitable for use in optoelectrical units.

Homo- and hetero-polyamino acid fullerene c60 derivatives, method for preparing them and based pharmaceutical compositions

FIELD: medicine, pharmaceutics. SUBSTANCE: invention refers to homo- and hetero-polyaminoacid fullerene derivatives of formula C 60 (H) x {NH(CH 2 ) n COO-} x {NH 3   + (L)COOH} x , wherein n - 2-5, x - 3, L = -(CH 2 ) m , wherein m = 1-5, or -CO(CH 2 ) k CH(NH 2 )-, wherein k = 1-2, which show activity against herpes virus, hepatitis C virus, influenza viruses of various nature, HIV, as well as anticancer and antipsoriatic activity. EFFECT: developing the method for preparing said homo- and hetero-polyaminoacid fullerene derivatives and based pharmaceutical compositions. 7 cl, 19 tbl, 8 ex РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) 2 458 914 (13) C1 (51) МПК ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ C07C C07C A61K A61P A61P A61P A61P 229/50 227/14 31/197 31/16 31/18 31/22 35/00 (2006.01) (2006.01) (2006.01) (2006.01) (2006.01) (2006.01) (2006.01) ИЗОБРЕТЕНИЯ К ПАТЕНТУ Приоритет(ы): (22) Дата подачи заявки: 01.02.2011 (73) Патентообладатель(и): Раснецов Лев Давидович (RU) (45) Опубликовано: 20.08.2012 Бюл. № 23 вируса гепатита С, вирусов гриппа различной природы, ВИЧ, а также противоопухолевой и противопсориатической активностью. Изобретение относится также к способу получения указанных гомо- и гетерополиаминокислотных производных фуллерена и фармацевтическим композициям на их основе. 3 н. и 4 з.п. ф-лы, 19 табл., 8 пр. (57) Реферат: Изобретение относится к гомо- и гетерополиаминокислотным производным фуллерена формулы C6 0(H)x{NH(CH2)nCOO ‐}x{NH3 + (L)COOH}x, где n=2-5, х=3, L=-(CH2)m, где m=15, либо -СО(CH2)kCH(NH2)-, где k=1-2, которые обладают активностью против вируса герпеса, R U 2 4 5 8 9 1 4 (54) ГОМО- И ГЕТЕРО-ПОЛИАМИНОКИСЛОТНЫЕ ПРОИЗВОДНЫЕ ФУЛЛЕРЕНА C6 0, СПОСОБ ИХ ПОЛУЧЕНИЯ И ФАРМАЦЕВТИЧЕСКИЕ КОМПОЗИЦИИ НА ИХ ОСНОВЕ Ñòð.: 1 ru C 1 C 1 Адрес для переписки: 603000, г.Нижний Новгород, ул. Костина, 4, офис 310, Л.Д. Раснецову 2 4 5 8 9 1 4 (56) Список документов, цитированных в отчете о поиске: RU 2236852 C1, 27.09.2004. RU 2316320 C1, 10.02. ...

Fullerenol c60 and method of its obtaining from glycerin

FIELD: chemistry. SUBSTANCE: invention can be applied in production modifiers of epoxy composites, microbiocides with anti-HIV activity, which do not demonstrate cytotoxicity, and anditoxidant additives to cosmetic preparations. Fullerenol C60 is obtained by catalytic dehydration of glycerin with heating. As catalyst applied are glucose, fullerene, fullerenol. Formed reaction water, allyl alcohol and acrolein are distillated. Dehydration is carried out until solid phase of black colour is formed and volume of reaction solution is reduced to 20-25% of initial glycerin volume. Formed fullerenol C60 is separated from diluted by water reaction solution in form of solution of sodium or ammonia salt by addition of alkali or ammonia, filtered from synthesis byproduct-water-insoluble carbon. Filtrate is acidified by sulfuric acid to pH 6.5, and precipitated in the process of acidification sediment, which represents fullerenol C60, is filtered and washed with water from unreacted glycerin, remains of allyl alcohol, acrolein, sodium or ammonia sulphate, which are formed in the process of acidification. Filtered sediment of dark-brown colour, representing fullerenol C60, is dried at temperature 70-90 °C. Additional purification is carried out by recrystallisation from alcohol. Fullerenol C60 is soluble in water and alcohol. EFFECT: elaboration of method of fullerenol C60 obtaining. 7 cl, 1 dwg, 3 ex РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) 2 497 751 (13) C2 (51) МПК C01B 31/02 (2006.01) B82B 3/00 (2006.01) B82Y 40/00 (2011.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ Приоритет(ы): (22) Дата подачи заявки: 28.12.2011 (73) Патентообладатель(и): Козеев Евгений Александрович (RU) (43) Дата публикации заявки: 10.07.2013 Бюл. № 19 R U (24) Дата начала отсчета срока действия патента: 28.12.2011 (72) Автор(ы): Козеев Евгений Александрович (RU), Козеев Александр Алексеевич (RU), Иванова Людмила Владимировна (RU) (21)(22) Заявка: 2011154053/05, ...

Functionalized carbon materials

This invention relates to carbon materials, such as a fullerene molecule or a curved carbon nanostructure, that are functionalized by addition chemistry performed on surface C—C double bond.

Fullerene derivatives, their production method and their use

Organic field effect transistor, useful in electronic circuit, comprises a semiconducting layer partially containing a fullerene derivative with a carbon cluster and a substituent bound to the carbon cluster over a cyclopropane ring

Organic field effect transistor comprises a semiconducting layer partially containing at least a fullerene derivative (I), which is composed of a carbon cluster with 60-960C-atoms, preferably 60-70C-atoms, and at least a substituent that is bound to the carbon cluster over a cyclopropane ring. Organic field effect transistor comprises a semiconducting layer partially containing at least a fullerene derivative of formula (I), which is composed of a carbon cluster with 60-960C-atoms, preferably 60-70C-atoms, and at least a substituent that is bound to the carbon cluster over a cyclopropane ring. F1>a carbon cluster; E1>, E2>COOR, COR, CONRR1>, P(O)(OR)2 or SO2R; R, R1>one or more substituted aliphatic H-, SH-, S-alkyl, SS-alkyl, NH-OH- or COOH-terminated group with 1-20C, preferably 1-12C, in which up to three CH2-unit is substituted by O, S or NR2>, an aromatic H-, SH-, S-alkyl, SS-alkyl, NH-, OH- or COOH-terminated group with phenyl, benzyl, naphthyl, anthracenyl or pyrenyl, an unbranched, optionally one or more substituted aliphatic terminal-group with 1-20C linked with a liquid-crystalline promoter containing a rigid molecular unit (aromatic or cycloaliphatic group e.g. phenyl, biphenyl, anthracenyl, pyrazinyl, cyclohexyl or cholesteryl), a polarizable group e.g. COO, CONH, CH=N, N=N, NO=N, CH=CH, CH=CH-CH=N, C-C-triple bond, followed by a rigid molecular unit (aromatic or cycloaliphatic group example, phenyl, biphenyl, cyclohexyl, cholesteryl), linked with a terminal-group such as alkyl, alkoxy, OCO-alkyl, COO-alkyl, OCOO-alkyl, CN, halo, NO2, or the liquid-crystalline promoter consists of one of the aforementioned rigid molecular units that are linked with one of the aforementioned polarizable groups, or the liquid-crystalline promoter comprising two successive rigid molecular units that are linked with one of the terminal-group, where all types of liquid-crystalline promoter such as alkyl, alkoxy, OCO-alkyl, COO-alkyl, OCOO-alkyl terminal- ...

Higher fullerenes useful as radical scavengers

Chemically functionalized fullerenes are useful in various applications as radical scavengers. These chemically functionalized fullerenes offer the advantages of preservation of the high innate radical scavenging efficiency of the fullerene cage and ease of synthesis of fullerene derivatives of desirably altered chemical and physical properties and single isomers. Further, they are based on a common intermediate chemistry and intermediates can be easily functionalized and tailored to various requirements.

Improved fullerene derivatives and related materials, methods and devices

The invention relates to improved fullerene derivatives, to methods for their synthesis and any educts or intermediates used in such methods, to compositions and formulations containing fullerene derivatives, to the use of the fullerene derivatives, compositions and formulations in, or for the preparation of, organic electronic (OE) devices like for example organic photovoltaic (OPV) devices or organic photodetectors (OPD), and to OE, OPV and OPD devices comprising, or being prepared from, these fullerene derivatives, compositions or formulations.

Therapeutic malonic acid/acetic acid c60 tri-adducts of buckminsterfullerene and methods related thereto

Disclosed and claimed herein are e,e,e malonic acid/acetic acid tri-adduct of buckminsterfullerene of the general formula C60R3, wherein each R is independently selected from groups of the formula -CR1R2 wherein each R1 and R2 is independently selected from the group consisting of -H and -COOH, provided, however, that at least one of the R1,s and R2,s is a hydrogen. Processes for preparing and uses of the same for treating neuronal injury and for life-extension are also disclosed and claimed herein.

Covalently functionalized nanodiamond-based maldi matrices and methods of use thereof

The present disclosure relates to functionalized nanodiamonds comprising at least one MALDI matrix covalently bonded to a nanodiamond and compositions comprising the same. The present disclosure also relates to methods of performing matrix-assisted laser desorption/ionization-mass spectrometry (MALDI-MS), for example on small molecules, using matrices comprising at least one MALDI matrix covalently bonded to a nanodiamond.

Isomer selective synthesis of methanofullerenes

[6,6]-Phenyl C 71 butyric acid derivatives (C 70 -PCBR 3 ) having a selectivity of greater than 95 wt % of the α-isomer are provided by reacting fullerene C 70 with a dialkyl sulfonium tetrafluoroborate having the formula:

Method and apparatus for cracking of a process gas

A nanoparticle or agglomerate which contains connected multi-walled spherical fullerenes coated in layers of graphite. In different embodiments, the nanoparticles and agglomerates have different combinations of: a high mass fraction compared to other carbon allotropes present, a low concentration of defects, a low concentration of elemental impurities, a high Brunauer, Emmett and Teller (BET) specific surface area, and/or a high electrical conductivity. Methods are provided to produce the nanoparticles and agglomerates at a high production rate without using catalysts.

Organic photodetector of dark current with reduction

一种有机光检测器，其包含第一电极、第二电极、和介于所述电极之间的光敏有机层，所述光敏有机层包含给体化合物和受体化合物，其特征在于所述受体化合物的LUMO能级浅于富勒烯衍生物PCBM的LUMO能级。

Sulphur-containing fullerene derivatives and method for production thereof

FIELD: chemistry. SUBSTANCE: invention relates to sulphur-containing fullerene derivatives of general formula , where X denotes a negative charge (-) which is localised on the fullerene backbone, or a hydrogen atom (H) or a chlorine atom (Cl), where in general formula 1, the fragment S-R 1 is defined as a residue of thio acid or ester thereof, which is bound to the fullerene backbone through a sulphur atom as shown graphically in formula 1, and R 1 has the formula XCOOR; X is a linear or branched alkylene (C n H 2n ; n=1-20) radical; R is a hydrogen atom (H), a linear or branched alkyl (C n H 2n+1 ; n=1-20), an alkenyl (C n H 2n-1 n=1-20) or alkynyl radical (C n H 2n-3 ; n=1-20); is a residue of an amide of thio acid which is bound to the fullerene backbone through a sulphur atom as shown graphically in formula 1, where R 1 has the formula XCONRR'; X is a linear or branched alkylene (C n H 2n ; n=1-20) radical; R and R' are hydrogen atoms or linear or branched alkyl (C n H 2n+1 ; n=1-20) radicals; a thiol residue, where R 1 is a hydrogen atom or a linear or branched alkyl (C n H 2n+1 n=1-20) radical or a saturated (C n H 2n-2 ; n=3-8) ring; a fragment of general formula -S(CH 2 ) n SR, bound to the fullerene backbone thorugh a sulphur atom as shown graphically in formula 1, where R is a hydrogen atom or a linear or branched alkyl (C n H 2n+1 ; n=1-20), alkenyl (C n H 2n-1 ; n=1-20) or alkynyl radical (C n H 2n-3 ; n=1-20), as well as a saturated (C n H 2n-2 ; n=3-8), unsaturated (C n H 2n-4 ; n=5-8, C n H 2n-6 ; n=5-8, C n H 2n-8 ; n=8) or an aromatic ring; a fragment of general formula -S(CH 2 ) n NRR or -S(CH 2 ) n N + RR'R"X", which is bound to the fullerene backbone through a sulphur atom as shown graphically in formula 1, where R, R and R" are hydrogen atoms or linear or branched alkyl (C n H 2n+1 n=1-20) radicals; as well as saturated (C n H 2n-2 ; n=3-8) rings; X" is any anion. The invention also relates to a method of producing ...

Polysubstituted fullerenes and their preparation (C-2608)

One embodiment of the present invention is directed to polysubstituted fullerene moieties having a plurality of substituents thereon, selected from the group consisting of hydroxy, oxide, nitro, amino, organocarboxy, amide, and mixtures thereof. Another embodiment is directed toward the preparation of the novel polysubstituted fullerenes. The method of forming polysubstituted fullerenes comprises contacting fullerenes with an electrophilic reagent such as nitronium ion or an organic peracid. When the electrophilic agent is nitronium ion, the fullerene is further contacted with a nucleophilic reagent. Polysubstituted fullerenes comprise a fullerene moiety selected from fullerenes or mixtures thereof having a plurality of substituents thereon. The polysubstituted fullerenes are particularly useful as cross-linking agents in polymers and/or as core building blocks of star polymers.

Methanofullerenes

本披露涉及新颖的亚甲基富勒烯衍生物，由其制备的负型光致抗蚀剂组合物以及使用它们的方法。这些衍生物、它们的光致抗蚀剂组合物以及方法对于使用例如紫外线辐射、超越极端紫外线辐射、极端紫外线辐射、X射线和带电粒子射线的精细图案处理是理想的。

Therapeutic malonic acid/acetic acid C60 tri-adducts of buckminsterfullerene and methods related thereto

Disclosed and claimed herein are e,e,e malonic acid/acetic acid tri-adduct of buckminsterfullerene of the general formula C 60 R 3 , wherein each R is independently selected from groups of the formula —CR 1 R 2 wherein each R 1 and R 2 is independently selected from the group consisting of —H and —COOH, provided, however, that at least one of the R 1 's and R 2 's is a hydrogen. Processes for preparing and uses of the same for treating neuronal injury and for life-extension are also disclosed and claimed herein.

Higher fullerenes useful as radical scavengers

Photoelectric conversion element and manufacturing method thereof

光電変換素子１０は、第１の電極３０と第２の電極８０との間に、電子輸送層４０、伝導帯下端エネルギー調整層５０、光電変換層６０および正孔輸送層７０がこの順で狭持された構造を有する。伝導帯下端エネルギー調整層５０は、例えば炭酸セシウムで形成されている。また、電子輸送層４０は、酢酸亜鉛で形成されている。 In the photoelectric conversion element 10, the electron transport layer 40, the conduction band bottom energy adjustment layer 50, the photoelectric conversion layer 60, and the hole transport layer 70 are narrowed in this order between the first electrode 30 and the second electrode 80. It has a held structure. The conduction band lower end energy adjustment layer 50 is made of, for example, cesium carbonate. The electron transport layer 40 is made of zinc acetate.

Condensed double-aryl fullerene derivate

Sulfur-containing derivatives of fullerenes and the method of their production

1. Серосодержащие производные фуллеренов общей формулы 1, а именно: ! ! где в общей формуле 1 Х означает, но не ограничивается: ! - отрицательный заряд («-»), локализованный на фуллереновом каркасе, или ! - атом хлора (-Cl), присоединенный к углеродному каркасу, или ! - нитрогруппа (-NO2) или нитратная группа (-ONO2), присоединенная к углеродному каркасу, или ! - атом водорода (-Н), линейный или разветвленный алкильный (CnH2n+1; n=1-20), алкенильный (CnH2n-1; n=1-20) или алкинильный радикал (CnH2n-3; n=1-20), присоединенный к фуллереновому каркасу, или ! - алкоксильный O-R или тиолатный фрагмент S-R, присоединенный к фуллереновому каркасу, где R - атом водорода или линейный или разветвленный алкильный (CnH2n+1; n=1-20), алкенильный (CnH2n-1; n=1-20) или алкинильный радикал (CnH3n-3; n=1-20), или ! - остаток тиокислоты -S(CH2)nCOOH или ее эфира -S(CH2)nCOOR, или амида -S(CH2)nCONR1R2, присоединенный к фуллереновому каркасу, где n=1-20, а R, R1 и R2 - атомы водорода или линейные или разветвленные алкильные (CmH2m+1; n=1-20), алкенильные (CmH2m-1; n=1-20) или алкинильные (CmH2m-3; n=1-20) радикалы; ! где в общей формуле 1 фрагмент SR1 описывается, но не ограничивается нижеследующими определениями: ! - остаток тиокислоты или ее сложного эфира, где R1 имеет вид XCOOR; Х - линейный или разветвленный алкиленовый (CnH2n; n=1-20), алкениленовый (CnH2n-2; n=1-20) или алкиниленовый (CnH2n-4; n=1-20) радикал, а также насыщенный (CnH2n-2; n=3-8), ненасыщенный (CnH2n-4; n=5-8, CnH2n-6; n=5-8, CnH2n-8; n=8) или ароматический цикл; R - атом водорода (-Н), линейный или разветвленный алкильный (CnH2n+1; n=1-20), алкенильный (CnH2n-1; n=1-20) или алкинильный радикал (CnH2n-3; n=1-20); ! - остаток амида тиокислоты, где R1 имеет вид XCONRR'; Х - линейный или разветвленный алкиленовый (CnH2n; n=1-20), алкениленовый (CnH2n-2; n=1-20) или алкиниленовый (CnH2n-4; n РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) 2011 111 783 (13) A (51) МПК C07C C07C C07C C07C 321/22 323/22 319/12 323/52 (2006.01) ( ...

Golden mean harmonized water and aqueous solutions

A composition of mater comprising a harmonized cluster of water molecules with Fibonacci chains between them and ordered water molecules based on hydrogen bonds that each water molecule interacts with three other water molecules having a magnetic spectra as shown in FIG. 13 or FIG. 14.

E-isomeric fullerene derivatives

An E-isomeric fulleropyrrolidine compound of formula (I): (see formula I) is disclosed. Also disclosed is a method for preparing and polymers prepared from such a compound.

Covalently functionalized nanodiamond-based maldi matrices and methods of use thereof

The present disclosure relates to functionalized nanodiamonds comprising at least one MALDI matrix covalently bonded to a nanodiamond and compositions comprising the same. The present disclosure also relates to methods of performing matrix-assisted laser desorption/ionization-mass spectrometry (MALDI-MS), for example on small molecules, using matrices comprising at least one MALDI matrix covalently bonded to a nanodiamond.

Cyclohexadiene fullerene derivatives

The invention relates to novel fullerene derivatives, to methods for their preparation and educts or intermediates used therein, to mixtures and formulations containing them, to the use of the fullerene derivatives, mixtures and formulations as organic semiconductors in, or for the preparation of, organic electronic (OE) devices, especially organic photovoltaic (OPV) devices and organic photodetectors (OPD), and to OE, OPV and OPD devices comprising, or being prepared from, these fullerene derivatives, mixtures or formulations.

Amino fullerene, preparation method and method for preparing modified titanium carbide nanosheet by using amino fullerene

一种氨基富勒烯、制备方法以及利用其制备改性碳化钛纳米片的方法，涉及功能有机分子设计与合成、纳米改性添加剂的制备技术领域。碳铝钛在氟化锂和盐酸的作用下，经过刻蚀反应生成碳化钛沉淀，然后再加入去离子水，经过超声离心得到碳化钛纳米片悬浮液；在富勒烯球体上引入伯胺活性基，然后调节pH至弱酸性，使氨基富勒烯生成铵盐；氨基富勒烯铵盐通过静电引力与碳化钛作用，生成氨基富勒烯改性碳化钛纳米片。该氨基富勒烯改性碳化钛纳米片利用带正电荷的富勒烯铵盐与碳化钛通过静电引力作用，使富勒烯铵盐可以有效地吸附在碳化钛表面，阻止其团聚。可应用于光催化有机反应、润滑油添加剂、金属加工液添加剂及阻燃材料添加剂等领域。

E-isomer fullerene derivative

(57)【要約】 （修正有） 【課題】抗腫瘍剤の細胞障害性を増大させる立体特異的 なＰＤＴ（フォトダイナミック療法）増感剤を開発。 【解決手段】式(I)のフラーロピロリジン化合物のＥ異 性体が開示される。また、およびこのような化合物から 製造されたポリマーが開示される。

Method and apparatus for preparing functionalized graphene and functionalized graphene

Methanofullerene derivatives and photoelectric conversion devices using same

The present invention provides a novel methanofullerene derivative applicable as an organic semiconductor material in electronics devices such as organic FETs and electroluminescence devices and solar cells, represented by formula (I) wherein the average value of 13 C-NMR chemical shift values of carbons C 2 and C 2′ on FL, bonded to C 1 is 80.10 ppm or greater, wherein FL represents fullerenes, X1 and X2 are each an aromatic hydrocarbon, an alkyl group or the like, C 2 and C 2′ are carbon atoms on FL, bonded to C 1 , and n is an integer of 1 to 10.

Golden mean harmonized water and aqueous solutions

本发明公开了一种物质的组合物，如图13或图14所示，其包含在它们之间具有斐波那契链的水分子的协调团和基于与每个水分子与具有磁化光谱的三个其它的其它水分子相互作用的氢键的规则水分子。

Improved fullerene derivatives and related materials, methods and devices

Phase transfer catalyst and process for producing poly(fullerene hydroxide)

Disclosed is a phase transfer catalyst which enables to synthesize a poly(fullerene hydroxide) having a pale color, excellent antioxidant ability and a high water-solubility, has no nitrogenated functional group other than a hydroxy group and having no impurity such as a sodium salt remaining therein, from a raw material fullerene directly, without passing through a water-insoluble fullerene hydroxide or a hydrogenated fullerene, in an one-step reaction with high efficiency. Also disclosed is a process for producing a poly(fullerene hydroxide). Specifically disclosed is a phase transfer catalyst for use in a two-liquid-phase catalytic reaction between a solution of a raw material fullerene in an organic solvent and an aqueous hydrogen peroxide for the production of a poly(fullerene hydroxide), which comprises a quaternary ammonium salt represented by the general formula: (R)4NX [wherein R's independently represent a hydrocarbon group; and X represents an anion].

Fullerene phenolic ester analog derivative and its preparation method and application

本发明公开了式(Ⅰ)所示的富勒烯酚酯类衍生物及其制备方法。利用优化的Friedel‑Crafts烷基化反应，以六氯富勒烯、酚酯为原料，合成得到了富勒烯酚酯类衍生物。该富勒烯衍生物可作为一种新型富勒烯安定剂在固体火箭推进剂中获得应用。 式中：R＝‑H，‑CH 3 ，‑CH 3 CH 2 ，‑CH(CH 3 ) 2 ，‑CH 2 CH 2 CH 3 ，‑CH 2 CH 2 CH 2 CH 3 。

Methanofullerene derivative and photoelectric transducer obtained by using the same

【課題】有機ＦＥＴ、ＥＬ素子、太陽電池などに応用可能な新規メタノフラーレン誘導体を提供する。 【解決手段】下記一般式（Ｉ）で表わされるメタノフラーレン誘導体で、Ｃ １ に結合するＦＬ上の炭素Ｃ ２ とＣ ２’ の 13 Ｃ−ＮＭＲケミカルシフト値の平均値が８０．１０ｐｐｍ以上であることを特徴とするメタノフラーレン誘導体。 （式（Ｉ）において、ＦＬはフラーレン類、Ｘ １ 、Ｘ ２ は、芳香族炭基、アルキル基等、Ｃ ２ およびＣ ２’ はＣ １ が結合したＦＬ上の炭素原子であり、ｎは１〜１０の整数。） 【選択図】なし

Fullerene derivatives

本发明涉及式I的富勒烯衍生物，含有它们的混合物和配制剂，富勒烯衍生物、混合物和配制剂作为有机半导体而用于电子器件，尤其是有机光伏(OPV)器件和有机光电探测器(OPD)的用途或用于制备电子器件，尤其是有机光伏(OPV)器件和有机光电探测器(OPD)的用途，以及包含这些富勒烯衍生物、混合物或配制剂或由这些富勒烯衍生物、混合物或配制剂所制得的电子器件。

Synthesis method of 1- fullerene pyrrolidine derivative

本发明公开了一种1‑[60]富勒烯吡咯烷衍生物的合成方法，属于富勒烯衍生物的合成技术领域。本发明的技术方案要点为：以过渡金属铁盐为催化剂，在氧化‑还原的中性状态下富勒烯C 60 与γ,δ‑不饱和肟酯类化合物反应，最终合成结构稀有的氮原子与碳笼直接相连的1‑富勒烯吡咯烷类衍生物。本发明生产工艺简单，环境友好，底物适用范围广，具有较高的产率，适用于规模的合成与制备。

Functionalization of nanoscale articles including nanotubes and fullerenes

High efficiency fullerene-based radical scavengers

Chemically functionalized fullerenes are useful in various applications as radical scavengers. These chemically functionalized fullerenes offer the advantages of preservation of the high innate radical scavenging efficiency of the fullerene cage and ease of synthesis of fullerene derivatives of desirably altered chemical and physical properties and single isomers. Further, they are based on a common intermediate chemistry and intermediates can be easily functionalized and tailored to various requirements.

FULLERENOL C60 AND THE METHOD OF ITS PRODUCTION FROM GLYCERINE

1. Фуллеренол С60, представляющий собой растворимый в воде, спирте и некоторых других полярных растворителях продукт каталитической дегидратации глицерина.2. Фуллеренол С60 по п.1, где глицерин соответствует ГОСТу 6259-75.3. Фуллеренол С60 по п.1, где катализатор представляет собой глюкозу.4. Фуллеренол С60 по п.1, где катализатор представляет собой фуллерен.5. Фуллеренол С60 по п.1, где катализатор представляет собой фуллеренол.6. Метод получения фуллеренола С60, при котором глицерин с катализатором нагревают, образующиеся в процессе синтеза реакционную воду, аллиловый спирт и акролеин отгоняют, процесс дегидратации проводят до образования твердой фазы черного цвета и заканчивают при уменьшении объема реакционного раствора до 20-25% от первоначального объема глицерина; фуллеренол С60 выделяют из разбавленного реакционного раствора в виде раствора натриевой или аммиачной соли добавлением в него щелочи или аммиака; раствор натриевой или аммиачной соли фильтруют от нерастворимого в воде углерода, побочного продукта синтеза, фильтрат подкисляют серной кислотой до рН 6,5, а выпавший при подкислении осадок, представляющий собою фуллеренол С60, отфильтровывают и промывают водой от непрореагировавшего глицерина, остатков аллилового спирта, акролеина, сульфата натрия или аммиака, образующихся при подкислении, и других побочных продуктов синтеза; отфильтрованный осадок темно-коричневого цвета фуллеренола С60 сушат при температуре 70-90°С, а при необходимости дополнительной очистки, его перекристаллизовывают из спирта.7. Метод по п.6, где содержание катализатора в глицерине составляет 0,05-0,10% от массы глицерина.8. Метод по п.6, при которо

Cyclohexadiene fullerene derivatives

본 발명은, 신규의 풀러렌 유도체, 이의 제조 방법 및 이에 사용되는 임의의 유리체(edduct) 또는 중간체; 이들을 함유하는 혼합물 및 제형; 이들 풀러렌 유도체, 혼합물 및 제형의 유기 전자(OE) 장치, 특히 유기 광전변환(OPV) 장치 및 유기 광검출기(OPD)의 유기 반도체로서 또는 이들의 제조를 위한 용도; 및 이들 풀러렌 유도체, 혼합물 또는 제형을 포함하거나 또는 이들로부터 제조되는 OE, OPV 및 OPD 장치에 관한 것이다. The present invention provides a novel fullerene derivative, a method for preparing the same, and any edduct or intermediate used therein; Mixtures and formulations containing them; The use of these fullerene derivatives, mixtures and formulations of organic electronic (OE) devices, in particular organic photoelectric conversion (OPV) devices and organic photodetectors (OPD) as organic semiconductors or for their manufacture; And OE, OPV and OPD devices comprising or prepared from these fullerene derivatives, mixtures or formulations.

Fullerene derivative, process for production of same, and allergen adsorbent comprising same

Disclosed are: a novel fullerene derivative which can adsorb an allergen that causes hay fever within a short time and with high efficiency and does not re-release the allergen, and which does not contain a metal or the like that has any adverse influence on human bodies, and can be applied onto, can penetrate into or can be chemically bound to surfaces of various materials readily; and a process for producing the fullerene derivative. The fullerene derivative is characterized in that a halogen group and many hydroxy groups are bound directly to a fullerene core. When the halogen group is a chlorine, the derivative can be synthesized by the partial hydroxylation of a chlorinated fullerene or the partial chlorination of a hydroxylated fullerene.

Photodynamic inactivation of viruses

In a process for the inactivation of enveloped viruses in a biological fluid buckminsterfullerene (C 60 ) is used as a photosensitizer. In a photodynamic processes singlet oxygen is generated which is the active agent for the inactivation of viruses present in the fluid. The process comprises the following steps: contacting of a solution or dispersion of material derived from the human body or from the bodies of animals with buckminsterfullerene as a photosensitizer; saturation of the solution or dispersion with oxygen; and irradiation of the solution or dispersion with visible or invisible light for activating the oxygen into the singlet state until viruses contained in the solution or dispersion are inactivated. This virus inactivation is specially suitable for protein solutions, e.g. bovine serum albumin, BSA or plasma products of human origin.

Functionalized nanodiamonds as delivery platforms for nucleic acids

The present application relates to functionalized nanodiamonds, to complexes comprising a functionalized nanodiamond reversibly bound to a nucleic acid and to compositions comprising such functionalized nanodiamonds and complexes. In particular, the functionalized nanodiamonds comprise at least one basic amino acid covalently linked to a nanodiamond. The present application also includes methods and uses of the complexes and compositions, for example for delivering a nucleic acid to a cell.

C84 fullerenes and derivatives thereof as radical scavengers

Chemically functionalized fullerenes are useful in various applications as radical scavengers. These chemically functionalized fullerenes offer the advantages of preservation of the high innate radical scavenging efficiency of the fullerene cage and ease of synthesis of fullerene derivatives of desirably altered chemical and physical properties and single isomers. Further, they are based on a common intermediate chemistry and intermediates can be easily functionalized and tailored to various requirements.

Golden mean harmonized water and aqueous solutions

A composition of mater comprising a harmonized cluster of water molecules with Fibonacci chains between them and ordered water molecules based on hydrogen bonds that each water molecule interacts with three other water molecules having a magnetic spectra as shown in FIG. 13 or FIG. 14.

C84 fullerenes and derivatives thereof as radical scavengers

Chemically functionalized fullerenes are useful in various applications as radical scavengers. These chemically functionalized fullerenes offer the advantages of preservation of the high innate radical scavenging efficiency of the fullerene cage and ease of synthesis of fullerene derivatives of desirably altered chemical and physical properties and single isomers. Further, they are based on a common intermediate chemistry and intermediates can be easily functionalized and tailored to various requirements.

Carboxyfullerenes and methods of use thereof

The instant invention is a method for increasing a metazoan's lifespan, comprising administering a carboxylated derivative of a C 60 fullerene. The instant invention further is a process for extending a metazoan's lifespan by administering a superoxide dismutase-mimetic as well as a composition comprising a superoxide dismutase-mimetic. Further, the instant invention comprises a pharmaceutical composition comprising carboxyfullerenes having x pairs of adjacent carbon atoms bonded to two carbons of the C 60 sphere wherein said adjacent carbon atom is further bonded to two groups of the general formula —COOH and —R, wherein R is independently selected from the group consisting of —COOH and —H, and wherein x is at least 1. A further embodiment is a non-metal containing composition which can catalytically eliminate two biologically reactive species. Another embodiment is a method of enhancing elimination of reactive oxygen species in eukaryotic cells by contacting cells with a superoxide dismutase mimetic.

Methanofullerene derivatives and photoelectric conversion elements using same

The present invention provides a novel methanofullerene derivative applicable as an organic semiconductor material in electronics devices such as organic FETs and electroluminescence devices and solar cells, represented by formula (I) wherein the average value of 13 C-NMR chemical shift values of carbons C 2 and C 2' on FL, bonded to C 1 is 80.10 ppm or greater, wherein FL represents fullerenes, X1 and X2 are each an aromatic hydrocarbon, an alkyl group or the like, C 2 and C 2 , are carbon atoms on FL, bonded to C 1 , and n is an integer of 1 to 10.

Fused bis-aryl fullerene derivatives

The invention relates to novel fullerene derivatives, to methods for their preparation and educts or intermediates used therein, to mixtures and formulations containing them, to the use of the fullerene derivatives, mixtures and formulations as organic semiconductors in, or for the preparation of, organic electronic (OE) devices, especially organic photovoltaic (OPV) devices and organic photodetectors (OPD), and to OE, OPV and OPD devices comprising, or being prepared from, these fullerene derivatives, mixtures or formulations.

Method for producing fullerene derivative

Disclosed is a method for simply producing fullerene 1,3-dioxolane with high yield. Specifically, fullerene 1,3-dioxolane is produced by reacting a fullerene oxide with a carbonyl compound in the presence of a catalyst.

Fused bis-aryl fullerene derivatives

본 발명은, 하기 화학식 I의 신규의 풀러렌 유도체, 이의 제조 방법 및 이에 사용되는 유리체(educt) 또는 중간체; 이들을 함유하는 혼합물 및 제형; 상기 풀러렌 유도체, 혼합물 및 제형의 유기 전자(OE) 장치, 특히 유기 광기전력(OPV) 장치 및 유기 광검출기(OPD)의 유기 반도체로서 또는 이들의 제조를 위한 용도; 및 상기 풀러렌 유도체, 혼합물 또는 제형을 포함하거나 또는 이들로부터 제조되는 OE, OPV 및 OPD 장치에 관한 것이다.

Anisotropic nanoparticle compositions and methods

A method for synthesizing a medicinal, nutraceutical, or food fullerene composition, including providing anisotropy in polar and non-polar C60 fullerene hemispheres to create one face of C60 fullerene having a small number of OH-groups clustered to the polar face; providing an amount of a polyhydroxylated fullerene from C60 fullerene; and blending the amount of the polyhydroxylated fullerene with an acceptable ionomer or an acceptable carrier or both. The polyhydroxylated fullerene includes fullerol-'x' and the amount includes 200 ppm or 500 ppm, wherein 'x' is less than 22. The acceptable ionomer includes honey, or a mixture of 3% by wt. sucrose, 1% by wt. proline, 0.2% by wt. magnesium citrate, and 1% by wt. beta-cyclodextrin. The acceptable carrier includes water or a gelatin. A stent, a medical bandage, medical packing material, medical drainage material, acupuncture support, topical ointment, or suture material is impregnated with an anisotropic polyhydroxylated fullerene for antimicrobial action.

Methanofullerenes

The present disclosure relates to novel methanofullerene derivatives, negative-type photoresist compositions prepared therefrom and methods of using them. The derivatives, their photoresist compositions and the methods are ideal for fine pattern processing using, for example, ultraviolet radiation, beyond extreme ultraviolet radiation, extreme ultraviolet radiation, X-rays and charged particle rays.

Dimeric carbon materials and their use in organic photovoltaic devices

Carbon material of general structure (I) A-C(=O)-O-B-O-C(=0)-A' (I) wherein A and A' which may be the same or different are derived from fullerene or fullerene derivatives and B is a C 1 -C 30 divalent linker. Higher homologues of said carbon material having respectively one central linker of type B and, attached thereto, three or four fullerene or fullerene derivatives of type A. Compositions comprising such materials and their use in organic photovoltaic devices.

Golden mean harmonized water and aqueous solutions

A composition of mater comprising a harmonized cluster of water molecules with Fibonacci chains between them and ordered water molecules based on hydrogen bonds that each water molecule interacts with three other water molecules having a magnetic spectra as shown in FIG. 13 or FIG. 14.

Fullerene derivative, fullerene derivative production method, deposit, film, and electronic device

フラーレン誘導体は、式（１）又は式（２） （ここで、Ａｒは、置換又は非置換の芳香族環であり、＊は、フラーレンコアとの連結点の炭素原子であり、Ｘは、Ｏ、Ｓ、Ｓｅ、又はＴｅであり、Ｒは、有機基である。）の構造を有する。

Fullerene derivative, fluororesin composition, and lubricant

A fullerene derivative of the present invention has a fullerene skeleton and a plurality of perfluoropolyether chains in a molecule, wherein the perfluoropolyether chains are bonded to the fullerene skeleton via methano groups, and a lubricant and fluororesin composition of the present invention contain the derivative.

Fullerene derivative and method for producing same

一种富勒烯衍生物的制造方法，其特征在于，使富勒烯、有机金属试剂(A)以及铜化合物(B)进行反应，所述有机金属试剂(A)包括B、Al、Zn、Sn、Pb、Te、Ti、Mn、Zr或Sm。

Compositions comprising supercritical carbon dioxide and metallic compounds

Methods of increasing the solubility of a base in supercritical carbon dioxide include forming a complex of a Lewis acid and the base, and dissolving the complex in supercritical carbon dioxide. The Lewis acid is soluble in supercritical carbon dioxide, and the base is substantially insoluble in supercritical carbon dioxide. Methods for increasing the solubility of water in supercritical carbon dioxide include dissolving an acid or a base in supercritical carbon dioxide to form a solution and dissolving water in the solution. The acid or the base is formulated to interact with water to solubilize the water in the supercritical carbon dioxide. Some compositions include supercritical carbon dioxide, a hydrolysable metallic compound, and at least one of an acid and a base. Some compositions include an alkoxide and at least one of an acid and a base.

Patent RU2020119061A3

Process for producing fullerene derivative

The present invention provides a method for producing a fullerene derivative, comprising the organic group addition step B in which an organic group is further added by reacting at least a basic compound and a halogen compound with a fullerene derivative, which is obtained by addition of a hydrogen atom and an organic group in the organic group addition step A, in which an organic group is added by reacting at least a Grignard reagent and a polar substance with a fullerene or fullerene derivative.