02-05-2019 дата публикации
Номер: US20190127555A1
Process for the modification of a surface of a solid substrate comprising treatment of the surface with (i) a solution comprising an organoborane-amine complex and a polymer and subsequently with (ii) a polymerizable compound (herein referred to as “monomer”) and optionally a deblocking agent 1. A process for modifying surface of a solid substrate , the process comprising treating the surface with(i) a solution comprising an organoborane-amine complex and a polymer and, subsequently,(ii) a polymerizable compound and, optionally, a deblocking agent.2. The process of claim 1 , wherein the organoborane-amine complex has a structure of formula (I){'br': None, 'sub': 1', '2', '3', '4', '5', '6, 'RRRB—NRRR\u2003\u2003(1),'}{'sub': 1', '2', '3', '1', '2', '3, 'wherein R, Rand Rare each independently an alkyl group, a cycloalkyl group, an alkyl or cycloalkyl group substituted with a heteroatom, an alkylamino group, an aryl group, a heteroaryl group, an alkoxy group or an aryloxy group, with the proviso that at least one of R, Rand Ris an alkyl or aryl group, and'}{'sub': 4', '5', '6', '4', '5', '6, 'R, Rand Rare each independently hydrogen, an alkyl group, a cycloalkyl group, a substituted alkyl group, an alkoxy group, an alkylamino group, an aryl group or a heteroaryl group, with the proviso that not more than two of R, Rand Rare simultaneously hydrogen, or'}{'sub': 4', '5', '6, 'NRRRis a heterocyclic aliphatic or aromatic amine, optionally comprising at least one heteroatom selected from the group consisting of N, O, S and P.'}3. The process of claim 1 , wherein the organoborane-amine complex is a trialkylborane-amine complex.4. The process of claim 1 , wherein the polymer is a polyalkylenoxide claim 1 , a polyalkyleneglycol claim 1 , a polycaprolactone claim 1 , a polyvinyllactone claim 1 , a polyvinyllactame or a mixture thereof.5. The process of claim 1 , wherein the polymer is a polyethyleneglycol or a polyvinylpyrrollidone.6. The process of claim 1 , wherein the ...
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