04-07-2019 дата публикации
Номер: US20190201974A1
Принадлежит:
The present invention relates to a method and an apparatus for coating large area solid substrates with metal based alloys or compounds by contacting the substrate surface with an unoxidised metal powders formed by in situ reaction of a metal halide and a reducing agent. The method is suitable for coating large area substrates such as flakes, powder, beads, and fibres with metal based alloys or compounds starting from low-cost chemicals such as metal chlorides. The method is particularly suited for production of substrates coated with metals, alloys and compounds based on Zn, Sn, Ag, Co, V, Ni, Cr, Fe, Cu, Pt, Pd, Ta, Nb, Rh, Ru, Mo, Os, Re and W. 1. A method for depositing metal-based coatings on a particulate substrate , including:a) mixing the particulate substrate with an uncoated metal-based powder to form a mixture; the metal-based powder being formed by exothermically reducing a precursor powder comprising a chloride or sub-chloride of one or more of Zn, Sn, Ag, Co, V, Ni, Cr, Fe, Cu, Pt, Pd, Ta, Nb, Rh, Ru, Mo, Os, Re and W by contacting with a reducing agent; andb) heating the mixture to produce a coating on said particulate substrate.2. The method according to claim 1 , wherein said mixing occurs concurrently with the formation of the uncoated metal-based powder3. The method according to claim 1 , wherein the reducing agent is selected from one or more of Na claim 1 , K claim 1 , Ca claim 1 , Mg claim 1 , or Al.4. The method according to claim 1 , wherein the metal chloride is selected from chlorides claim 1 , fluorides claim 1 , bromides or iodides.5. The method for forming a coating on a substrate according to claim 1 , comprising:immersing a substrate powder in a reactant mixture comprising an uncoated metallic powder and metal chlorides and a reducing agent and optionally any coating additives, and heating the resulting mixture at temperatures between 400° C. and 800° C. to induce reactions between the substrate surface and the said mixture and form a ...
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